New type of bonding formed from an overlap between pi aromatic and pi C=O molecular orbitals stabilizes the coexistence in one molecule of the ionic and neutral meso-ionic forms of imidazopyridine.
New bis(imidazo)pyridine dye has been synthesized and tested as a potential photoinitaitor for free-radical polymerization induced with the visible emission of an argon ion laser. The X-ray analysis based on data collected at 170 and 130 K, as well as density functional theory (DFT) calculations, revealed the presence of two different forms of imidazopyridine rings within the same molecule. These two forms of the same moiety had not only different geometries but different electronic structures as well. One of the imidazopyridine rings was in the ionic form, while the other was in the meso-ionic form. DFT calculations provided an explanation for such an observed phenomena. The averaging of ionic and meso-ionic forms of imidazopyridine rings within the same molecule is hindered because of an attractive interaction between them. Analysis of electronic density revealed that, indeed, a new type of bonding is formed as the result of an overlap between pi aromatic and pi C=O molecular orbitals. This bonding, like the hydrogen bond, is primarily of electrostatic character, and its energy was estimated at 3.5 kcal/mol.
Hoffmann
Marcin
M
Faculty of Chemistry, Adam Mickiewicz University, Grunwaldzka 6, 60-780 Poznan, Poland. hoffmann@man.poznan.pl
Plutecka
Agnieszka
A
Rychlewska
Urszula
U
Kucybala
Zdzislaw
Z
Paczkowski
Jerzy
J
Pyszka
Ilona
I
D001965:Bromides / Q000737:chemistry; D004583:Electrons; D006860:Hydrogen Bonding; D007093:Imidazoles / Q000737:chemistry*; D007477:Ions; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D008958:Models, Molecular; D008968:Molecular Conformation; D011725:Pyridines / Q000737:chemistry*; D011789:Quantum Theory; D055672:Static Electricity; D013696:Temperature; D014961:X-Ray Diffraction; D014965:X-Rays
D001965:Bromides; D007093:Imidazoles; D007477:Ions; D011725:Pyridines