Reductive carbodiazenylation of nonactivated olefins via aryl diazonium salts.
[Structure: see text] The reduction of aryl diazonium salts in the presence of nonactivated olefins provides rapid entry to carbodiazenylation products. The regioselective functionalization of double bonds is achieved in a one-pot process starting from aniline derivatives. Carboamination of olefins is possible via a two-step carbodiazenylation-hydrogenation sequence in which one aniline equivalent is recovered.
Heinrich
Markus R
MR
Lehrstuhl für Organische Chemie 1, Technische Universität München, Lichtenbergstr. 4, D-85747 Garching, Germany. markus.heinrich@ch.tum.de
Blank
Olga
O
Wölfel
Sabrina
S