HPLC retention behaviors of pi-electron rich compounds on Ni2+- and Cu2+-phthalocyanine derivatives bound to silica gels in polar eluents.
The effect of the central metal of columns packed with silica gels binding Ni(2+)- and Cu(2+)-phthalocyanine derivatives (Ni-and Cu-PCS(D)s) on the retention behavior of poly-aromatic-hydrocarbons (PAHs) thereof in a polar eluent was examined. The retention factors of PAHs on the Ni- and Cu-PCS(D)s in 80% methanol showed a good linear correlation. The Cu-PCS(D) column exhibited the pi-pi interactions for PAHs, while the Ni-PCS(D) column exhibited the pi-d interactions for PAHs in addition to the pi-pi interaction for PAHs. Further, an investigation of the retention behavior of anthracene derivatives having different substituents revealed that the Ni- and Cu-PCS(D) columns could recognize the differences of substituents only in a polar eluent.
Tsukamoto
Ikuko
I
Faculty of Medicine, Kagawa University, Ikenobe, Miki-cho, Kagawa 761-0793, Japan.
Saito
Madoka
M
Yamane
Minako
M
Kawata
Kenji
K
Kitamura
Yuji
Y
Kitamura
Youji
Y
Mifune
Masaki
M
Saito
Yutaka
Y
Haginaka
Jun
J
D002851:Chromatography, High Pressure Liquid; D003300:Copper / Q000737:chemistry*; D004583:Electrons; D005782:Gels; D007211:Indoles / Q000737:chemistry*; D054833:Isoindoles; D000432:Methanol / Q000737:chemistry*; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry*; D013499:Surface Properties
D005782:Gels; D007211:Indoles; D054833:Isoindoles; D009942:Organometallic Compounds; D012822:Silicon Dioxide; D003300:Copper; D009532:Nickel; C013647:phthalocyanine; D000432:Methanol