title: Solid or liquid? Solidification of a nanoconfined liquid under nonequilibrium conditions.
abstract: There has been a long-standing debate about the physical state and possible phase transformations of confined liquids. In this report, we show that a model-confined liquid can behave both as a Newtonian liquid with very little change in its dynamics and as a pseudosolid, depending solely on the rate of approach of the confining surfaces. Thus, the confined liquid does not exhibit any confinement-induced solidification in thermodynamic equilibrium. Instead, solidification is induced kinetically when the two confining surfaces are approached with a minimum critical rate. This critical rate is surprisingly slow (on the order of 6 A/s), explaining the frequent observation of confinement-induced solidification.
authors.affiliation: Department of Physics and Astronomy, Wayne State University, 666 West Hancock, Detroit, MI 48201, USA.
authors.forename: Shivprasad
authors.initials: S
authors.lastname: Patil
authors.forename: George
authors.initials: G
authors.lastname: Matei
authors.forename: Ahmet
authors.initials: A
authors.lastname: Oral
authors.forename: Peter M
authors.initials: PM
authors.lastname: Hoffmann