title: Laboratory studies of butane nucleation on organic haze particles: application to Titan's clouds.
abstract: Titan, Saturn's largest satellite, has a thick nitrogen/methane atmosphere with various hydrocarbons present in minor amounts. Recent observations suggest that CH4 may condense to form clouds near the moon's tropopause. Titan's methane cloud formation is probably triggered by a sequential nucleation of hydrocarbons onto Titan's haze material as tropospheric convection occurs due to differential heating of the surface or as the haze settles through the lower stratosphere. To better constrain Titan's cloud formation mechanism, investigations of the nucleation of several hydrocarbons will be necessary. Butane was chosen for this study because it has a relatively high freezing point and is estimated to be present at 200 part per billion levels. If this amount of butane were to condense on each haze particle, a visible cloud would be observed. Laboratory measurements at T = 125 K were performed to determine the relative ease of solid butane nucleation onto laboratory-produced tholin particles having an elemental composition of C5H5N, and solid films of hexane and acetonitrile. We find that butane nucleation onto the haze particles requires a relatively high saturation ratio of S > 1.30. Because butane nucleation is difficult, it may occur on only a very small subset of the total haze particles available. Such selective nucleation of butane would lead to those particles becoming coated with significant amounts of butane. Requiring a high saturation ratio for butane nucleation will reduce the optical depth of butane clouds by a factor of 100 because the particles will be fewer in number for a given condensed mass.
authors.affiliation: Department of Chemistry and Biochemistry, University of Colorado, Boulder, Colorado 80309, USA.
authors.forename: Daniel B
authors.initials: DB
authors.lastname: Curtis
authors.forename: David L
authors.initials: DL
authors.lastname: Glandorf
authors.forename: Owen B
authors.initials: OB
authors.lastname: Toon
authors.forename: Margaret A
authors.initials: MA
authors.lastname: Tolbert
authors.forename: Christopher P
authors.initials: CP
authors.lastname: McKay
authors.forename: Bishun N
authors.initials: BN
authors.lastname: Khare
mesh_terms: D000097:Acetonitriles / Q000737:chemistry; D001273:Atmosphere Exposure Chambers; D002073:Butanes / Q000737:chemistry*; D005118:Extraterrestrial Environment / Q000737:chemistry*; D006586:Hexanes / Q000737:chemistry; D008567:Membranes, Artificial; D008855:Microscopy, Electron, Scanning; D052638:Particulate Matter; D018539:Saturn; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature
chemical_list: D000097:Acetonitriles; D002073:Butanes; D006586:Hexanes; D008567:Membranes, Artificial; D052638:Particulate Matter; C046888:butane; C032159:acetonitrile