title: Preparation and photoluminescence properties of Y2SiO5:Eu3+ nanocrystals.
abstract: The sol-emulsion-gel method is used for the preparation of about 5-7 nm size Eu2O3 doped and coated Y2SiO5 nanoparticles at 1300 degrees C. Here, we report the role of surface coating, dopant concentration and temperature of heating on the modification of crystal structure and the photoluminescence properties of Y2SiO5:Eu3+ nanocrystals. It is found that photoluminescence properties are sensitive to the crystal structure which is again controlled by surface coating, concentration and heating temperature. The decay times are 0.76, 1.14, 1.23 and 1.40 ms for 0.25, 0.5, 1.0 and 2.5 mol% Eu2O3 doped Y2SiO5 nanocrystals prepared at 1100 degrees C (X1-Y2SiO5). However, in X2-Y2SiO5 crystal phase (at 1300 degrees C) the average decay times are 1.05, 1.35, 1.55 and 1.60 ms for 0.25, 0.5, 1.0 and 2.5 mol% Eu2O3 doped Y2SiO5 nanocrystals, indicating the photoluminescence properties depend on both the crystal structure and the concentration of ions. The emission intensity of the peak at 612 nm (5D0-->7F2) of the Eu3+-ions is found to be sensitive to the doping and surface coating of Y2SiO5 nanocrystals. The decay times are 1.55 and 1.70 ms for 1300 degrees C heated 1.0 mol% Eu2O3 doped and coated Y2SiO5 nanocrystals, respectively. Our analysis suggests that the site symmetry of ions plays a most important role in the modification of radiative relaxation mechanisms and as a result on the overall photoluminescence properties.
authors.affiliation: Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032, India. msap@iacs.res.in
authors.forename: Pushpal
authors.initials: P
authors.lastname: Ghosh
authors.forename: Suparna
authors.initials: S
authors.lastname: Sadhu
authors.forename: Amitava
authors.initials: A
authors.lastname: Patra
mesh_terms: D003460:Crystallization / Q000379:methods*; D005063:Europium / Q000737:chemistry*; D008027:Light; D049449:Luminescence; D008422:Materials Testing; D049329:Nanostructures / Q000737:chemistry* / Q000528:radiation effects / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods; D010316:Particle Size; D010777:Photochemistry / Q000379:methods*; D017640:Silicates / Q000737:chemistry* / Q000528:radiation effects; D013499:Surface Properties; D015019:Yttrium / Q000737:chemistry* / Q000528:radiation effects
chemical_list: D017640:Silicates; C028301:yttrium silicate; D005063:Europium; D015019:Yttrium