Influence of solvent and counter ion on complexes of 2,5-bis(2-pyridyl)-1,3,4-oxadiazole with iron (II) and (III) studied by electrospray ionization mass spectrometry.
The effect of solvent and counter ion on the complexes of 2,5-bis(2-pyridyl)-1,3,4-oxadiazole (1) with Fe+2 and Fe+3 has been studied by electrospray ionization mass spectrometry (ESI/MS). As expected, upon ESI conditions the metal reduction proceeds, but it can be deduced that complexes with Fe+2 are favored over those with Fe+3. When methanol is used as solvent, the formation of complexes of stoichiometry 2:1 and 1:1 with counter ion attached (monovalent anion) is favored, for example, [1(2)+FeCl]+ ion. The use of methanol/water (1/1) as solvent favors the formation of complexes of stoichiometry 2:1 and 3:1, namely doubly charged [1(2)+Fe]+2 and [1(3)+Fe]+2 ions. The complexes containing anion of oxidative properties (ClO4-, NO3-), when the higher cone voltage is applied, yield unusual species [1n+FeOm]+ (n=1, 2; m=1, 2). The use of divalent counter ion (SO4(-2)) resulted in formation of complexes containing two iron cations, namely [1n+Fe2SO4]+2 (n=2, 3, 4) ions. These ions can be regarded as Fe-1 complexes bridged by a sulfate anion.
Frański
Rafał
R
Adam Mickiewicz University, Faculty of Chemistry, Grunwaldzka 6, 60-780 Poznań, Poland. franski@main.amu.edu.pl