Toward chiral sum-frequency spectroscopy.
Chiral sum-frequency (SF) spectroscopy that measures both the real and the imaginary components of the SF spectral response was demonstrated for the first time. It was based on interference of the SF signal with a dispersionless SF reference. Solutions of 1,1'-bi-2-naphthol (BN) were used as model systems, and their chiral SF spectra over the first exciton-split transitions were obtained. Chiral spectra are useful for determination of absolute configuration and conformation of chiral molecules.
Ji
Na
N
Department of Physics, University of California at Berkeley and Materials Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720, USA.
Ostroverkhov
Victor
V
Belkin
Mikhail
M
Shiu
Ying-Jen
YJ
Shen
Yuen-Ron
YR
D008968:Molecular Conformation; D009284:Naphthols / Q000737:chemistry; D012680:Sensitivity and Specificity; D012996:Solutions / Q000737:chemistry; D013057:Spectrum Analysis / Q000379:methods*
D009284:Naphthols; D012996:Solutions; C412332:1,1'-bi-2-naphthol