title: Configuration-specific synthesis of the facial and meridional isomers of tris(8-hydroxyquinolinate)aluminum (Alq3).
abstract: Treatment of AlO(OH) with 3 equiv of 8-hydroxyquinolinol in refluxing deionized water provided the meridional and facial isomers of tris(8-hydroxyquinolinate)aluminum (Alq3) with good yields as solid deposits after 1 and 90 h, respectively. X-ray diffraction and solid-state 13C NMR studies revealed that mer-Alq3 is formed in the early stage of the reaction and then gradually converts to fac-Alq3, which is thermodynamically less stable, although no existence of a catalyst substance is implied.
authors.affiliation: Department of Applied Chemistry, Kanagawa University, Yokohama 221-8686, Japan.
authors.forename: Ryo
authors.initials: R
authors.lastname: Katakura
authors.forename: Yoshihiro
authors.initials: Y
authors.lastname: Koide