Crystal structure, physical properties and HRTEM investigation of the new oxonitridosilicate EuSi2O2N2.
The new layered oxonitridosilicate EuSi(2)O(2)N(2) has been synthesized in a radio-frequency furnace at temperatures of about 1400 degrees C starting from europium(III) oxide (Eu(2)O(3)) and silicon diimide (Si(NH)(2)). The structure of the yellow material has been determined by single-crystal X-ray diffraction analysis (space group P1 (no. 1), a=709.5(1), b=724.6(1), c=725.6(1) pm, alpha=88.69(2), beta=84.77(2), gamma=75.84(2) degrees ,V=360.19(9)x10(6) pm(3), Z=4, R1=0.0631, 4551 independent reflections, 175 parameters). Its anionic Si(2)O(2)N(2) (2-) layers consist of corner-sharing SiON(3) tetrahedra with threefold connecting nitrogen and terminal oxygen atoms. High-resolution transmission electron micrographs indicate both ordered and disordered crystallites as well as twinning. Magnetic susceptibility measurements of EuSi(2)O(2)N(2) exhibit Curie-Weiss behavior above 20 K with an effective magnetic moment of 7.80(5) mu(B) Eu(-1), indicating divalent europium. Antiferromagnetic ordering is detected at 4.5(2) K. EuSi(2)O(2)N(2) shows a field-induced transition with a critical field of 0.50(5) T. The four crystallographically different europium sites cannot be distinguished by (151)Eu Mössbauer spectroscopy. The room-temperature spectrum is fitted by one signal at an isomer shift of delta=-12.3(1) mm s(-1) subject to quadrupole splitting of DeltaE(Q)=-2.3(1) mm s(-1) and an asymmetry parameter of 0.46(3). Luminescence measurements show a narrow emission band with regard to the four crystallographic europium sites with an emission maximum at lambda=575 nm.
Stadler
Florian
F
Department Chemie und Biochemie, Lehrstuhl für Anorganische Festkörperchemie, Ludwig-Maximilians-Universität München, Butenandtstrasse 5-13 (D), 81377 Münich, Germany.
Oeckler
Oliver
O
Höppe
Henning A
HA
Möller
Manfred H
MH
Pöttgen
Rainer
R
Mosel
Bernd D
BD
Schmidt
Peter
P
Duppel
Viola
V
Simon
Arndt
A
Schnick
Wolfgang
W