DFT/TDDFT studies of the geometry, electronic structure and spectra of (12S)-1,4,7,10-tetraazadicyclo[10,3,0]-pentadecane-3,11-dione and its derivatives.
The FT-Raman and UV-visible spectra of (12S)-1,4,7,10-tetraazadicyclo[10,3,0]-pentadecane-3,11-dione and its derivatives were obtained and discussed. The harmonic vibrational wavenumbers and the corresponding Raman scattering activities in their electronic ground-states were calculated at the DFT-B3LYP/6-31G(d) level of theory. The calculated wavenumbers were then scaled and compared with the experimental values. The 7-(2,4-dinitrophenyl)-(12S)-1,4,7,10-tetrazadicyclo[10,3,0]-pentadecane-3,11-dione derivative has mainly an amide (II) character, while the others have an amide (I) character. Moreover, the different substituents do not cause a significant shift of the vibrational mode of the macrocyclic plane. The electronic vertical excitation energy and the oscillator strength were determined with the help of TDDFT calculations and by employing pure (BLYP) and hybrid (B3LYP, B3P86, and mPW1PW91) functionals together with the 6-31G(d) basis set. The BLYP functional reproduces the UV-vis absorption spectra better than the B3LYP, B3P86, or mPW1PW91 hybrid functionals. A dimolecular model, which considers hydrogen-bonded structures, proved that strong inter- and intramolecular hydrogen bonds are present in these compounds. Due to the transannular effect, the UV-vis absorption spectrum of macrocyclic dioxotetraamines is completely different from that of single amide compounds.
Li
Wei
W
College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072, PR of China.
Wang
Yi-Bo
YB
Pavel
Ioana
I
Yuan
Quan
Q
Ye
Yong
Y
Fu
En-Qin
EQ
Luo
Ming-Dao
MD
Hu
Ji-Ming
JM
Kiefer
Wolfgang
W
D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000737:chemistry*; D004583:Electrons; D047029:Lactams, Macrocyclic / Q000737:chemistry*; D015394:Molecular Structure; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman; D014732:Vibration
C519992:(12S)-1,4,7,10-tetraazadicyclo(10,3,0)-pentadecane-3,11-dione; D019086:Bridged Bicyclo Compounds, Heterocyclic; D047029:Lactams, Macrocyclic