Mulliken-Hush analysis of a bis(triarylamine) mixed-valence system with a N...N distance of 28.7 A.
An organic mixed valence compound with a spacer length of 25 unsaturated bonds separating two amine redox centres was synthesised and the electron transfer behaviour was investigated in the context of a Mulliken-Hush analysis in order to estimate the longest redox centre separation for which an intervalence charge transfer band can be observed.
Heckmann
Alexander
A
Institute of Organic Chemistry, University of Würzburg, Am Hubland, D-97074 Würzburg, Germany. lambert@chemie.uni-wuerzburg.de.
Amthor
Stephan
S
Lambert
Christoph
C