Enantioselective synthesis of allenic esters via an ylide route.
Pseudo-C2-symmetric chiral phosphorus ylides have been designed and synthesized for the enantioselective preparation of allenic esters, and up to 92% ee has been achieved.
Li
Chuan-Ying
CY
State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China.
Sun
Xiu-Li
XL
Jing
Qing
Q
Tang
Yong
Y