One-dimensional silver(I) chain of lacunary alpha-Keggin anions.
A novel chain-like silver polyoxotungstophosphate is formed when Ag(I) metal centres, exhibiting an unusual eight-coordination fashion, bridge a monolacunary [PW11O39]7- anion to four bridging mu2-oxygen atoms of a neighbouring lacunary alpha-Keggin anion.
Nogueira
Helena I S
HI
Department of Chemistry, CICECO, University of Aveiro, 3810-193, Aveiro, Portugal. helena@dq.ua.pt
Paz
Filipe A Almeida
FA
Teixeira
Paula A F
PA
Klinowski
Jacek
J