title: C-O bond cleavage of benzophenone substituted by 4-CH2OR (R = C6H5 and CH3) with stepwise two-photon excitation.
abstract: The C-O bond cleavage from benzophenone substituted with 4-CH2OR (p-BPCH2OR, 1-3), such as p-phenoxymethylbenzophenone (1, R= C6H5) and p-methoxymethylbenzophenone (2, R= CH3), occurred by a stepwise two-photon excitation during two-color, two-laser flash photolysis. On the other hand, no C-O bond cleavage occurred from p-hydroxymethylbenzophenone (3, R = H). The first 355-nm laser excitation of 1-3 generates p-BPCH2OR in the lowest triplet excited state (T1) which has an absorption at 532 nm. When p-BPCH2OR(T1) is excited with the second 532-nm laser to p-BPCH2OR in the higher triplet excited state (T(n)), the C-O bond cleavage occurred within the laser flash duration of 5 ns. The quantum yields of the C-O bond cleavage during the second 532-nm laser irradiation were found to be 0.015 +/- 0.007 and 0.007 +/- 0.003 for 1 and 2, respectively. Although these values are low, the diminishing 1(T1) or 2(T1) was found to convert, in almost 100% yield, to phenoxyl (C6H5O*) and p-benzoylbenzyl (BPCH2*) radicals or methoxyl (CH3O*) and BPCH2* radicals, respectively. The T(n) excitation energy, the energy barrier along the potential surface between the T(n) states and product radicals, and delocalization of the T(n) state molecular orbital including BP and CH2OR (R = C6H5, CH3, H) moieties are important factors for the occurrence of the C-O bond cleavage. It is found that the C-O bond cleavage and production of free radicals, such as BPCH2*, C6H5O*, and CH3O*, can be performed by a stepwise two-photon excitation. The present study is an example in which the chemical reactions can be selectively initiated from the T(n) state but not from the S1 and T1 states.
authors.affiliation: The Institute of Scientific and Industrial Research (SANKEN), Osaka University, Mihogaoka 8-1, Ibaraki, Osaka 567-0047, Japan.
authors.forename: Xichen
authors.initials: X
authors.lastname: Cai
authors.forename: Masanori
authors.initials: M
authors.lastname: Sakamoto
authors.forename: Minoru
authors.initials: M
authors.lastname: Yamaji
authors.forename: Mamoru
authors.initials: M
authors.lastname: Fujitsuka
authors.forename: Tetsuro
authors.initials: T
authors.lastname: Majima