title: Diversity synthesis using the complimentary reactivity of rhodium(II)- and palladium(II)-catalyzed reactions.
abstract: Rhodium(II)-catalyzed reactions of aryldiazoacetates can be conducted in the presence of iodide, triflate, organoboron, and organostannane functionality, resulting in the formation of a variety of cyclopropanes or C-H insertion products with high stereoselectivity. The combination of the rhodium(II)-catalyzed reaction with a subsequent palladium(II)-catalyzed Suzuki coupling offers a novel strategy for diversity synthesis.
authors.affiliation: Department of Chemistry, University at Buffalo, State University of New York, Buffalo, New York 14260, USA.
authors.forename: Aiwu
authors.initials: A
authors.lastname: Ni
authors.forename: Jessica E
authors.initials: JE
authors.lastname: France
authors.forename: Huw M L
authors.initials: HM
authors.lastname: Davies
mesh_terms: D002384:Catalysis; D003508:Cycloheptanes / Q000138:chemical synthesis*; D006846:Hydrocarbons, Halogenated / Q000138:chemical synthesis*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D010165:Palladium / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
chemical_list: D003508:Cycloheptanes; D006846:Hydrocarbons, Halogenated; D009942:Organometallic Compounds; D010165:Palladium; D012238:Rhodium