Radical reactions with 2-bromobenzylidene group, a protecting/radical-translocating group for the 1,6-radical hydrogen transfer reaction.
[Structure: see text] The 2-bromobenzylidene group, designed as a novel protecting/radical-translocating (PRT) group, proved to be effective for an unusual 1,6-hydrogen transfer reaction. Using this PRT group, 4-branched ribose derivatives were stereoselectively prepared.
Sakaguchi
Natsumi
N
Graduate School of Pharmaceutical Sciences, Hokkaido University, Kita-12, Nishi-6, Kita-ku, Sapporo 060-0812, Japan.
Hirano
Shinpei
S
Matsuda
Akira
A
Shuto
Satoshi
S
D001597:Benzylidene Compounds / Q000737:chemistry*; D006842:Hydrocarbons, Brominated / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D012266:Ribose / Q000031:analogs & derivatives* / Q000138:chemical synthesis*
D001597:Benzylidene Compounds; D006842:Hydrocarbons, Brominated; D012266:Ribose