A highly reduced vanadium(III/IV) polyoxovanadate comprising an octavanadyl square-prism surrounding a dimetallic vanadium(III) fragment.
The synthesis, crystal structure and preliminary magnetic studies are reported for a very highly reduced, VIV8VIII2, polyoxo(alkoxo)vanadate with a unique square prismatic topology.
Laye
Rebecca H
RH
School of Chemistry, The University of Manchester, Manchester M13 9PL, UK, and CCLRC Daresbury Laboratory, Daresbury, Cheshire WA4 4AD, UK.
Wei
Qiang
Q
Mason
Pamela V
PV
Shanmugam
Maheswaran
M
Teat
Simon J
SJ
Brechin
Euan K
EK
Collison
David
D
McInnes
Eric J L
EJ