Adsorbable organic halogens (AOXs) in solid residues from hazardous and clinical waste incineration.
Trace concentrations of a variety of chemicals remain in solid residues following combustion even in properly designed and operated incinerators. In the present study, the adsorbable organic halogen (AOX) levels of the solid residues, i.e., bottom ash, fly ash, and filter cake, were investigated during a 82-day of continuous operation of a Hazardous and Clinical Waste Incinerator. The distribution of halogens in the waste input prior to the incineration was also determined. The AOX levels measured in bottom ash, fly ash and filter cake were in the range of 0.014-1.879, 0.012-0.263, and 0.004-0.062 mg-Cl(-)/kg, respectively. The AOX levels are significantly low in the fly ash and filter cake due to the post-combustion process in the incinerator. At the end of the 82 days, the total AOX output in the bottom ash, fly ash, and filter cake were 571, 3.71, and 6.26 g, respectively. The partitioning of the total AOX in solid residues was 98.28, 0.64, and 1.08% for the bottom ash, fly ash and filter cake, respectively. This shows that the bottom ash is more contaminated with AOX than the other two residues.
Durmusoglu
Ertan
E
Department of Environmental Engineering, University of Kocaeli, Kocaeli, 41040, Turkey. ertan@kou.edu.tr
Bakoglu
Mithat
M
Karademir
Aykan
A
Kirli
Lale
L
D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D060729:Coal Ash; D006256:Hazardous Waste; D006846:Hydrocarbons, Halogenated / Q000032:analysis*; D017745:Incineration / Q000295:instrumentation / Q000379:methods; D008506:Medical Waste; D052638:Particulate Matter
D060729:Coal Ash; D006256:Hazardous Waste; D006846:Hydrocarbons, Halogenated; D008506:Medical Waste; D052638:Particulate Matter; D002244:Carbon