title: Photoinduced intramolecular electron-transfer processes in [60]fullerene and N,N-Bis(biphenyl)aniline molecular systems in solutions.
abstract: Photoinduced intramolecular charge-separation and charge-recombination processes in covalently connected C(60)-(spacer)-bis(biphenyl)aniline (C(60)-sp-BBA) and C(60)-((spacer)-bis(biphenyl)aniline)(2) (C(60)-(sp-BBA)(2)) have been studied by time-resolved fluorescence and transient absorption methods. Since a flexible alkylthioacetoamide chain was employed as the spacer, the folded structures in which the BBA moiety approaches the C(60) moiety were obtained as optimized structures by molecular orbital calculations. The observed low fluorescence intensity and the short fluorescence lifetime of the C(60) moiety of these molecular systems indicated that charge separation takes place via the excited singlet state of the C(60) moiety in a quite fast rate and high efficiency even in the nonpolar solvent toluene, which was a quite new observation compared with reported dyads with different spacers. From the absorption bands at 880 and 1000 nm in the nanosecond transient absorption spectra, generations of C(60)(.-)-sp-BBA(.+) and C(60)(.-)-(sp-BBA(.+))(sp-BBA) were confirmed. The rates of charge separation and charge recombination for C(60)-(sp-BBA)(2) are faster than those for C(60)-sp-BBA, suggesting that one of the BBA moieties approaches the C(60) moiety by pushing another BBA moiety because of the flexible spacers.
authors.affiliation: Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, Katahira 2-1-1, Aoba-ku, Sendai, 980-8577, Japan.
authors.forename: Atula S D
authors.initials: AS
authors.lastname: Sandanayaka
authors.forename: Kei-ichiro
authors.initials: K
authors.lastname: Ikeshita
authors.forename: G Abraham
authors.initials: GA
authors.lastname: Rajkumar
authors.forename: Yoshio
authors.initials: Y
authors.lastname: Furusho
authors.forename: Yasuyuki
authors.initials: Y
authors.lastname: Araki
authors.forename: Toshikazu
authors.initials: T
authors.lastname: Takata
authors.forename: Osamu
authors.initials: O
authors.lastname: Ito