Structural characterisation of a diprotonated ligand lanthanide complex--a key intermediate in lanthanide ion association and complex dissociation pathways.
The X-ray structure is reported of a diprotonated Gd(III) tetra-aqua complex of the ligand 1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane (DOTAM), a thermodynamic intermediate in metal ion association and dissociation pathways.
Stenson
Philip A
PA
Department of Chemistry, Durham University, South Road, Durham, UKDH1 3LE.
Thompson
Amber L
AL
Parker
David
D
D000081:Acetamides / Q000138:chemical synthesis*; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D018360:Crystallography, X-Ray; D005682:Gadolinium / Q000737:chemistry; D006573:Heterocyclic Compounds, 1-Ring / Q000138:chemical synthesis*; D007700:Kinetics; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008024:Ligands; D013816:Thermodynamics; D014867:Water / Q000737:chemistry
C522450:1,4,7,10-tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane; D000081:Acetamides; D006573:Heterocyclic Compounds, 1-Ring; D028581:Lanthanoid Series Elements; D008024:Ligands; D014867:Water; D005682:Gadolinium