title: CH stretching vibrational overtone spectra of 1,3,5,7-cyclooctatetraene and 1,1,1-trichloroethane.
abstract: Local mode frequencies, omega, and anharmonicities, omegax, are obtained from the delta upsilon(CH) = 2-7 spectral regions of 1,3,5,7-cyclooctatetraene (COT) and 1,1,1-trichloroethane. In 1,1,1-trichloroethane omega and omega x are used in conjunction with ab initio potential energy surfaces to calculate local mode anharmonicity-torsion coupling terms, delta(omega x), and frequency-torsion coupling terms, delta(omega). Blue-shifting of sterically hindered CH oscillators in 1,1,1-trichloroethane indicates nonbonded, through-space intramolecular interactions with Cl. Multiple, complex Fermi resonances are observed in 1,1,1-trichloroethane and in COT between local mode states and local mode/normal mode combination states. Intensities of vibrational overtone transitions are calculated in the range delta upsilon(CH) = 3-9 using ab initio dipole moment functions and the harmonically coupled anharmonic oscillator (HCAO) model. HCAO intensities are compared to experimental intensities at delta upsilon(CH) = 3.
authors.affiliation: Department of Chemistry, University of Guelph, Guelph, Ontario N1G 2W1, Canada.
authors.forename: Michael W P
authors.initials: MW
authors.lastname: Petryk
authors.forename: Bryan R
authors.initials: BR
authors.lastname: Henry