title: Synthesis of the phenoxonium cation of an alpha-tocopherol model compound crystallized with non-nucleophilic [B(C6F5)4]- and (CB11H6Br6)- anions.
abstract: The phenoxonium cation of a vitamin E model compound has been crystallized using the non-nucleophilic carborane and tetrakis(pentafluorophenyl)borate counteranions. The crystal structures confirm the assignment of the unusually stable phenoxonium cation and indicate that there is a substantial shortening of the carbon-oxygen bond lengths of the para-carbon atoms in the phenolic ring and a substantial increase of the carbon-oxygen bond length at the quaternary carbon. The crystallographic data are in excellent agreement with structural predictions from molecular orbital calculations.
authors.affiliation: Research School of Chemistry, Australian National University, Canberra, ACT 0200, Australia.
authors.forename: Stephen B
authors.initials: SB
authors.lastname: Lee
authors.forename: Anthony C
authors.initials: AC
authors.lastname: Willis
authors.forename: Richard D
authors.initials: RD
authors.lastname: Webster