Exploring two-state reactivity pathways in the cycloaddition reactions of triplet methylene.
Spin forbidden 1,2-cycloadditions of triplet methylene to alkenes have been theoretically studied as an example of the two-state reactivity paradigm in organic chemistry. The cycloadditions of triplet methylene to ethylene and the (E)- and (Z)-2-butene isomers show spin inversion after the transition state and therefore with no effect on the reaction rate. A local analysis shows that while triplet methylene addition to alkenes leading to the formation of a biradical intermediate is driven by spin polarization, the ring closure step to yield cyclopropane is a pericyclic process. We have found that at the regions in the potential energy surface where the spin crossover is likely to occur, the spin potential in the direction of increasing spin multiplicity, mu(+)(s), tends to equalize the one in the direction of decreasing spin multiplicity, mu(-)(s). This equalization facilitates the spin transfer process driven by changes in the spin density of the system.
Pérez
Patricia
P
Departamento de Ciencias Químicas, Facultad de Ecología y Recursos Naturales, Universidad Andrés Bello, República 275, Santiago, Chile.
Andrés
J
J
Safont
V S
VS
Contreras
Renato
R
Tapia
O
O