title: Second-order Møller-Plesset evaluation of the bond length alternation of several series of linear oligomers.
abstract: We investigate, at the second-order Møller-Plesset level, the bond length alternation of 30 series of increasingly long linear oligomers for a total of more than 250 compounds, polyacetylene, polymethineimine, polyphosphinoborane, polyaminoborane, polyphosphazene, etc., for which, often for the first time, an accurate estimate of the polymeric bond length alternation is given. The variations induced either by chemical substitution of the backbone atoms or conformational modifications are discussed. Only three polymers present a large bond length alternation (>0.03 A). Systematic basis set effects have been unravelled, i.e., MP2/6-311G(2d) always overshoots the bond length alternation. Best estimates of the bond length alternation are provided for more than a dozen of polymers.
authors.affiliation: Laboratoire de Chimie Théorique Appliquée, Facultés Universitaires Notre-Dame de la Paix, rue de Bruxelles, 61, B-5000 Namur, Belgium. denis.jacquemin@fundp.ac.be
authors.forename: Denis
authors.initials: D
authors.lastname: Jacquemin
authors.forename: Antoine
authors.initials: A
authors.lastname: Femenias
authors.forename: Henry
authors.initials: H
authors.lastname: Chermette
authors.forename: Jean-Marie
authors.initials: JM
authors.lastname: André
authors.forename: Eric A
authors.initials: EA
authors.lastname: Perpète