Solvothermal in situ ligand synthesis through disulfide cleavage: 3D (3,4)-connected and 2D square-grid-type coordination polymers.
Two novel coordination polymers, Cu3(4-pyt)3 (1) and Co(4-pyt)2 (2) (4-pyt = pyridine-4-thiolate), have been synthesized by in situ generation of a 4-pyt ligand from a 4,4'-dithiodipyridine precursor through reductive cleavage of the disulfide bond under solvothermal conditions. 1 and 2 exhibit a three-dimensional (3,4)-connected network and a two-dimensional square-grid-type structure, respectively.
Han
Lei
L
Department of Chemistry, University of California, Riverside, CA 92521, USA.
Bu
Xianhui
X
Zhang
Qichun
Q
Feng
Pingyun
P
D015392:Chemistry, Inorganic / Q000379:methods*; D004220:Disulfides / Q000737:chemistry; D006358:Hot Temperature; D008024:Ligands; D008956:Models, Chemical; D008958:Models, Molecular; D008968:Molecular Conformation; D011108:Polymers / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D013440:Sulfides / Q000737:chemistry; D013696:Temperature
D004220:Disulfides; D008024:Ligands; D011108:Polymers; D013440:Sulfides