{Bis(3,5-Di-tert-butyl-2-oxidobenzyl)[2-(N,N-dimethylamino)ethyl]amine-kappa(4)N,N',O,O'}zinc(II) and {bis(3-tert-butyl-5-methyl-2-oxidobenzyl)[2-(N,N-dimethylamino)ethyl]amine-kappa(4)N,N',O,O'}(tetrahdyrofuran)zinc(II).
The title zinc(II) complexes, [Zn(C(34)H(54)N(2)O(2))], (II), and [Zn(C(28)H(42)N(2)O(2))(C(4)H(8)O)], (III), were obtained as monomeric 1:1 complexes, in contrast with the calcium complexes supported by the same ligand class. Complex (II) crystallizes with two independent molecules in the asymmetric unit, which have similar geometric parameters. The donor atoms in (II) form a distorted trigonal-pyramidal arrangement around the zinc centre. Complex (III) contains a coordinated tetrahydrofuran molecule, resulting in a five-coordinate trigonal-bipyramidal arrangement around the Zn atom. The electron density provided by the coordination of this tetrahydrofuran molecule elongates the Zn-O and Zn-N bonds by approximately 0.07 and 0.10 A, respectively, in comparison with (II). Neither (II) nor (III) is active as an epsilon-caprolactone polymerization catalyst. The data presented here demonstrate that Zn may bind both an ONNO ligand and an additional oxygen-based ligand. The lack of activity is thus not due to steric hinderance at the metal atom.
Howard
Ruth H
RH
School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich NR4 7TJ, England.
Bochmann
Manfred
M
Wright
Joseph A
JA
D002118:Calcium / Q000737:chemistry*; D006576:Heterocyclic Compounds, 4 or More Rings / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
D006576:Heterocyclic Compounds, 4 or More Rings; D009942:Organometallic Compounds; D015032:Zinc; D002118:Calcium