title: Layered inorganic-organic clay-like nanocomposites rearrange to form silsesquioxanes on acid treatment.
abstract: The formation of talc-like compounds by the condensation of organotrialkoxy silanes with magnesium hydroxide has been recently reported. These represent layered hybrid nanomaterials that have a layer thickness of around 1 nm, have organic moieties covalently linked to the layer surfaces, and are called "organoclays." We show that such compounds are sensitive to acid treatment. When a phenylclay is treated with hydrochloric acid, magnesium leaches out, destroying the layered structure. The extent to which magnesium is leached out is a function of the time of the acid treatment and the concentration of the acid used. Magnesium leaches out rapidly when the concentration of acid used to treat the phenyl-clay is higher, and the extent of structural magnesium that is leached out is also higher for higher acid concentrations. Removal of the magnesium rearranges the structure of the phenyl-clay to form oligomeric phenylsilsesquioxanes. FTIR and NMR suggest that the silsesquioxanes formed by acid treatment of the phenyl-clay comprise a mixture of ladderlike and cagelike structures.
authors.affiliation: Polymer Science and Engineering Division, National Chemical Laboratory, Pune 411008, India. guru@poly.ncl.res.in
authors.forename: Guruswamy
authors.initials: G
authors.lastname: Kumaraswamy
authors.forename: Yogesh
authors.initials: Y
authors.lastname: Deshmukh
authors.forename: Vikrant V
authors.initials: VV
authors.lastname: Agrawal
authors.forename: P
authors.initials: P
authors.lastname: Rajmohanan