title: Deposition of gold nanoparticles onto thiol-functionalized multiwalled carbon nanotubes.
abstract: Gold nanoparticles were deposited on the surface of multiwalled carbon nanotubes (MWNTs) functionalized with aliphatic bifunctional thiols (1,4-butanedithiol, 1,6-hexanedithiol, 1,8-octanedithiol, and 2-aminoethanethiol) through a direct solvent-free procedure. Small gold particles, with a narrow particle size distribution around 1.7 nm, were obtained on 1,6-hexanedithiol-functionalized MWNTs. For MWNTs functionalized with the aminothiol, the average Au particle size was larger, 5.5 nm, apparently due to a coalescence phenomenon. Gatan image filter (GIF) observations show that sulfur is at the nanotube surface with a non-homogeneous distribution. A higher sulfur concentration was observed around the gold nanoparticles' location.
authors.affiliation: Centro de Ciencias Aplicadas y Desarrollo Tecnológico, Universidad Nacional Autónoma de México (UNAM), Circuito Exterior S/N Ciudad Universitaria, A. P. 70-186, C.P. 04510 México D.F., Mexico. zanela@aleph.cinstrum.unam.mx
authors.forename: Rodolfo
authors.initials: R
authors.lastname: Zanella
authors.forename: Elena V
authors.initials: EV
authors.lastname: Basiuk
authors.forename: Patricia
authors.initials: P
authors.lastname: Santiago
authors.forename: Vladimir A
authors.initials: VA
authors.lastname: Basiuk
authors.forename: Edgar
authors.initials: E
authors.lastname: Mireles
authors.forename: Iván
authors.initials: I
authors.lastname: Puente-Lee
authors.forename: José M
authors.initials: JM
authors.lastname: Saniger