title: N- and P-channel transport behavior in thin film transistors based on tricyanovinyl-capped oligothiophenes.
abstract: We report the structural and electrical characterization of thin films of organic semiconductor molecules consisting of an oligothiophene core capped with electron-withdrawing tricyanovinyl (TCV) groups. X-ray diffraction and atomic force microscopy of evaporated films of three different TCV-capped oligothiophenes showed that the films were highly crystalline. Electrical transport was measured in thin film transistors employing silver source and drain contacts and channel probes to correct for contact resistance. Three compounds exhibited n-channel (electron) conduction consistent with cyclic voltametry data that indicated they undergo facile reduction. Maximum electron mobilities were 0.02 cm2/V.s with an on/off current ratio of 10(6). A fourth end-capped molecule, TCV-6T-TCV, which had six thiophene rings, exhibited both p- and n-channel transport. Overall, these results confirm that substitution of oligothiophene cores with electron-withdrawing groups is a useful strategy to achieve electron-transporting materials.
authors.affiliation: Department of Chemical Engineering and Materials Science, University of Minnesota, 421 Washington Avenue SE, Minneapolis, Minnesota 55455, USA.
authors.forename: Xiuyu
authors.initials: X
authors.lastname: Cai
authors.forename: Michael W
authors.initials: MW
authors.lastname: Burand
authors.forename: Christopher R
authors.initials: CR
authors.lastname: Newman
authors.forename: Demetrio A
authors.initials: DA
authors.lastname: da Silva Filho
authors.forename: Ted M
authors.initials: TM
authors.lastname: Pappenfus
authors.forename: Mamoun M
authors.initials: MM
authors.lastname: Bader
authors.forename: Jean-Luc
authors.initials: JL
authors.lastname: Brédas
authors.forename: Kent R
authors.initials: KR
authors.lastname: Mann
authors.forename: C Daniel
authors.initials: CD
authors.lastname: Frisbie