title: Electrochemical behavior of poly(ferrocenyldimethylsilane-b-dimethylsiloxane) films.
abstract: The electrochemical behavior of poly(ferrocenyldimethylsilane-b-dimethylsiloxane) (PFDMS-b-PDMS) films deposited on a glassy carbon electrode was investigated by means of cyclic voltammetry (CV). The influences of the solvent, film thickness, temperature, and PDMS block length in PFDMS-b-PDMS on the electrode process were discussed. It was found that in 0.1 M aqueous LiClO(4) the electrochemical processes of the films on a glassy carbon electrode were complex and have a low rate of electron transport and mass diffusion. The kinetic parameters obtained indicated that the electrode process was controlled by both the electrode reaction and mass diffusion.
authors.affiliation: State Key Lab of Polymer Reaction Engineering, Zhejiang University, Hangzhou 310027, People's Republic of China.
authors.forename: Tao
authors.initials: T
authors.lastname: Chen
authors.forename: Li
authors.initials: L
authors.lastname: Wang
authors.forename: Guohua
authors.initials: G
authors.lastname: Jiang
authors.forename: Jianjun
authors.initials: J
authors.lastname: Wang
authors.forename: Xiaochen
authors.initials: X
authors.lastname: Dong
authors.forename: Xuejie
authors.initials: X
authors.lastname: Wang
authors.forename: Junfeng
authors.initials: J
authors.lastname: Zhou
authors.forename: Chiliang
authors.initials: C
authors.lastname: Wang
authors.forename: Wei
authors.initials: W
authors.lastname: Wang