Orthogonal packing of enantiomerically pure helical silver coordination networks.
The combination of the chiral tecton based on the (R)-6,6'-dibromo-1,1'-binaphthyl moiety bearing two isonicotinoyl groups with AgX (X = BF4-, CF3SO3-, PF6-) leads to the formation of enantiomerically pure helical strands with orthogonal packing in the rare space group I2(1)3.
Jouaiti
Abdelaziz
A
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université Louis Pasteur, F-67000 Strasbourg, France.
Hosseini
Mir Wais
MW
Kyritsakas
Nathalie
N
Grosshans
Phlippe
P
Planeix
Jean-Marc
JM