State-correlation matrix of the product pair from F + CD(4)--> DF(nu') + CD(3)(0 v(2) 0 0).
The title reaction was investigated under crossed-beam conditions at three different collision energies, E(c) = 8.4, 2.76 and 1.46 kcal mol(-1). The combination of using a (2 + 1) resonance-enhanced multiphoton ionization for tagging state-specific CD(3) products and exploiting a time-sliced velocity imaging for ion detection allows us to reveal the coincident information of the two product pairs in a state-correlated manner. The pair-correlated results are reported for the two product vibrators -- (v(2) = 0, v'), (v(2) = 1, v'), (v(2) = 2, v') and (v(2) = 3, v')-and the dynamics attributes we examined include product state distributions, energy disposals and angular distributions. Together with our earlier communications, a rather complete picture of the correlated dynamics of the title reaction emerges. One of the major findings, the anti-correlated excitations of the two product vibrators at all four energies of this study, can qualitatively be understood by kinematics arguments.
Zhou
Jingang
J
The Institute of Atomic and Molecular Sciences (IAMS), Academia Sinica, P.O. Box 23-166, Taipei 10617, Taiwan.
Lin
Jim J
JJ
Shiu
Weicheng
W
Liu
Kopin
K
D000465:Algorithms; D003198:Computer Simulation; D008956:Models, Chemical; D008958:Models, Molecular; D017785:Photons; D013057:Spectrum Analysis / Q000379:methods*; D013223:Statistics as Topic