title: Heterogeneous photocatalytic degradation of p-toluenesulfonic acid using concentrated solar radiation in slurry photoreactor.
abstract: In this work, the photocatalytic degradation (PCD) of p-toluenesulfonic acid (p-TSA) in batch reactor using concentrated solar radiation was investigated. The effect of the various operating parameters such as initial concentration of substrate, catalyst loading, solution pH and types of ions on photocatalytic degradation has been studied in a batch reactor to derive the optimum conditions. The rate of photocatalytic degradation was found to be maximum at the self pH (pH 3.34) of p-TSA. It was also observed that in the presence of anions and cations, the rate of PCD decreases drastically. The kinetics of photocatalytic degradation of p-TSA was studied. The PCD of p-TSA was also carried at these optimized conditions in a bench scale slurry bubble column reactor using concentrated solar radiation.
authors.affiliation: Environmental Materials Unit, National Environmental Engineering Research Institute, Nehru Marg, Nagpur 400020, India.
authors.forename: Sanjay P
authors.initials: SP
authors.lastname: Kamble
authors.forename: Sudhir B
authors.initials: SB
authors.lastname: Sawant
authors.forename: Vishwas G
authors.initials: VG
authors.lastname: Pangarkar
mesh_terms: D001557:Benzenesulfonates / Q000737:chemistry* / Q000528:radiation effects*; D002384:Catalysis; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D010777:Photochemistry; D011827:Radiation; D012993:Solar Energy
chemical_list: D001557:Benzenesulfonates; C029501:4-toluenesulfonic acid