title: Near ultraviolet photolysis of deuterated pyrrole.
abstract: High resolution time-of-flight (TOF) measurements of the D atom fragments arising in the near ultraviolet (UV) photodissociation of deuterated pyrrole are reported. Structures evident in the measured TOF spectra are all interpretable in terms of N-D bond fission, and population of selected vibrational states of the pyrrolyl-d(4) co-fragment -- thereby clarifying previous uncertainties regarding the branching into different vibronic states of the pyrrolyl radical following UV excitation of pyrrole.
authors.affiliation: School of Chemistry, University of Bristol, Bristol, UK BS8 1TS.
authors.forename: Bríd
authors.initials: B
authors.lastname: Cronin
authors.forename: Adam L
authors.initials: AL
authors.lastname: Devine
authors.forename: Michael G D
authors.initials: MG
authors.lastname: Nix
authors.forename: Michael N R
authors.initials: MN
authors.lastname: Ashfold
mesh_terms: D003198:Computer Simulation; D003903:Deuterium / Q000032:analysis / Q000737:chemistry* / Q000528:radiation effects*; D008956:Models, Chemical; D010782:Photolysis / Q000528:radiation effects; D011758:Pyrroles / Q000737:chemistry* / Q000528:radiation effects*; D014466:Ultraviolet Rays
chemical_list: D011758:Pyrroles; D003903:Deuterium