Mediated coadsorption at the liquid-solid interface: Stabilization through hydrogen bonds.
Stable adsorption of 1,3,5-tris(4-pyridyl)-2,4,6-triazine (TPT) molecules from the liquid phase was only observed in binary solutions, that is, in the presence of a second (adsorptive) species. The process of mediated coadsorption of a molecular species at the liquid-solid interface was accomplished through complexation of TPT with a second type of molecule acting as a "molecular glue" via hydrogen bonds. Scanning tunneling microscopy (STM) was utilized to investigate the structure of the coadsorbed monolayers at the liquid-solid interface. Trimesic acid (TMA) and terephthalic acid (TPA)--both benzene rings with disposed carboxylic acid groups-were appropriate to precipitate the stable adsorption of TPT. According to the different symmetry and number of carboxylic acid groups, various networks were observed.
Kampschulte
Lorenz
L
Ludwig-Maximilians-University Munich, Department for Earth- and Environmental Sciences, and Center for Nanoscience (CeNS), Theresienstr. 41, 80333 München, Germany.
Griessl
Stefan
S
Heckl
Wolfgang M
WM
Lackinger
Markus
M