Identification of 1,3-dialkylimidazolium salt supramolecular aggregates in solution.
The nature of the interactions between 1,3-dialkylimidazolium cations and noncoordinating anions such as tetrafluoroborate, hexafluorophosphate, and tetraphenylborate has been studied in the solid state by X-ray diffraction analysis and in solution by (1)H NMR spectroscopy, conductivity, and microcalorimetry. In the solid state, these compounds show an extended network of hydrogen-bonded cations and anions in which one cation is surrounded by at least three anions and one anion is surrounded by at least three imidazolium cations. In the pure form, imidazolium salts are better described as polymeric supramolecules of the type {[(DAI)(3)(X)](2+)[(DAI)(X)(3)](2-)}(n) (where DAI is the dialkylimidazolium cation and X is the anion) formed through hydrogen bonds of the imidazolium cation with the anion. In solution, this supramolecular structural organization is maintained to a great extent, at least in solvents of low dielectric constant, indicating that mixtures of imidazolium ionic liquids with other molecules can be considered as nanostructured materials. This model is very useful for the rationalization of the majority of the unusual behavior of the ionic liquids.
Consorti
Crestina S
CS
Laboratory of Molecular Catalysis, Institute of Chemistry, UFRGS, Av. Bento Gonçalves, 9500 Porto Alegre 91501-970 RS, Brazil.
Suarez
Paulo A Z
PA
de Souza
Roberto F
RF
Burrow
Robert A
RA
Farrar
David H
DH
Lough
Alan J
AJ
Loh
Watson
W
da Silva
Luis H M
LH
Dupont
Jairton
J