title: Ru(0001) model catalyst under oxidizing and reducing reaction conditions: in-situ high-pressure surface X-ray diffraction study.
abstract: With surface X-ray diffraction (SXRD) using a high-pressure reaction chamber we investigated in-situ the oxidation of the Ru(0001) model catalyst under various reaction conditions, starting from a strongly oxidizing environment to reaction conditions typical for CO oxidation. With a mixture of O(2) and CO (stoichiometry, 2:1) the partial pressure of oxygen has to be increased to 20 mbar to form the catalytically active RuO(2)(110) oxide film, while in pure oxygen environment a pressure of 10(-5) mbar is already sufficient to oxidize the Ru(0001) surface. For preparation temperatures in the range of 550-630 K a self-limiting RuO(2)(110) film is produced with a thickness of 1.6 nm. The RuO(2)(110) film grows self-acceleratedly after an induction period. The RuO(2) films on Ru(0001) can readily be reduced by H(2) and CO exposures at 415 K, without an induction period.
authors.affiliation: Department of Physical Chemistry, Justus-Liebig University, Heinrich-Buff-Ring, D-35392 Giessen, Germany.
authors.forename: Y B
authors.initials: YB
authors.lastname: He
authors.forename: M
authors.initials: M
authors.lastname: Knapp
authors.forename: E
authors.initials: E
authors.lastname: Lundgren
authors.forename: H
authors.initials: H
authors.lastname: Over