Silver clusters on silver sulfide nanocrystals: synthesis and behavior after electron beam irradiation.
Nanocomposite crystals, (Ag)(x)(Ag(2)S)(y) with x < y, are synthesized in micellar media. The generation of Ag clusters on Ag(2)S nanocrystals is attributed to the reduction of mobile Ag(+) ions in the Ag(2)S nanocrystals by sulfur derivatives. The proportions in the composite material can be modulated by electron beam irradiation. Using dodecanethiol as surface passivating agent, 2D self-organizations of these nanocomposite crystals are produced.
Motte
L
L
Laboratoire LM2N, URA CNRS 1662, Université P. et M. Curie, 4 Place Jussieu, Paris, France.
Urban
J
J
D004583:Electrons; D008823:Micelles; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry* / Q000528:radiation effects; D010316:Particle Size; D012834:Silver / Q000737:chemistry*; D018030:Silver Compounds / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry; D013499:Surface Properties
D008823:Micelles; D018030:Silver Compounds; D013438:Sulfhydryl Compounds; C013976:dodecylmercaptan; D012834:Silver; C013251:silver sulfide