Phosphine dendrimer-stabilized palladium nanoparticles, a highly active and recyclable catalyst for the Suzuki-Miyaura reaction and hydrogenation.
[reaction: see text] Phosphine dendrimer-stabilized palladium nanoparticles were synthesized and found to be highly effective for Suzuki coupling reactions, affording good to excellent product yields, high turnover number (up to 65,000), and excellent reusability (up to 9 catalytic runs). Furthermore, these Pd nanoparticles are efficient and selective catalysts for hydrogenations.
Wu
Lei
L
Beijing National Laboratory for Molecular Sciences, Center for Chemical Biology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
Li
Bao-Lin
BL
Huang
Yi-Yong
YY
Zhou
Hai-Feng
HF
He
Yan-Mei
YM
Fan
Qing-Hua
QH