Selective oxo functionalization of the uranyl ion with 3d metal cations.
The linear uranyl dication [UO2]2+ can be bound in one of two coordination sites in the ditopic Pacman-shaped pyrrolic macrocyle H4L. Incorporation of Mn2+, Fe2+, or Co2+ cations in the second donor compartment affords the first uranyl complexes with a transition-metal-functionalized oxo group.
Arnold
Polly L
PL
School of Chemistry, University Park, University of Nottingham, Nottingham NG7 2RD, United Kingdom. polly.arnold@nott.ac.uk
Patel
Dipti
D
Blake
Alexander J
AJ
Wilson
Claire
C
Love
Jason B
JB