title: Photoelectrochemical oxidation of water at transparent ferric oxide film electrodes.
abstract: The fabrication of thin-film Fe(2)O(3) photoanodes from the spray pyrolysis of Fe(III)-containing solutions is reported along with their structural characterization and application to the photoelectrolysis of water. These films combine good performance, measured in terms of photocurrent density, with excellent mechanical stability. A full investigation into the effects that modifications of the spray-pyrolysis method, such as the addition of dopants or structure-directing agents and changes in precursor species or carrier solvent, have on the performance of the photoanodes has been realized. The largest photocurrents were obtained from photoanodes prepared from ferric chloride precursor solutions, simultaneously doped with Ti(4+) (5%) and Al(3+) (1%). Doping with Zn(2+) also shows promise, cathodically shifting the onset potential by approximately 0.22 V.
authors.affiliation: Département de Chimie Minérale, Analytique et Appliquée, Université de Genève, 1211 Genève, Switzerland.
authors.forename: Chantal
authors.initials: C
authors.lastname: Jorand Sartoretti
authors.forename: Bruce D
authors.initials: BD
authors.lastname: Alexander
authors.forename: Renata
authors.initials: R
authors.lastname: Solarska
authors.forename: Iwona A
authors.initials: IA
authors.lastname: Rutkowska
authors.forename: Jan
authors.initials: J
authors.lastname: Augustynski
authors.forename: Radovan
authors.initials: R
authors.lastname: Cerny