[Biosorptive-flotation and desorption operation of heavy metals from wastewater effluents by Gordona amarae].
The process of adsorptive-flotation and desorption to remove and recovery heavy metals from aqueous solution was studied using Gordona amarae as sorbent, and the mechanisms of biosorption and flotation were analyzed. Experimental results showed that the selectivity of Gordona amarae for various heavy metal cations was Pb > Hg > Cu, and the restrain oneself of Cu2+ was the highest. the present of NH4+ ion on loaded Pb2+ cells was remarkably improved, however, K+, Na+, Ca2+, Mg2+ of co-existing ions slightly restrained influence. The flotation recoveries respectively of Pb2+ and biomass more than 93% and 96% for with DA dosage of 17.5 mmol/L in the pH of 9.5, and that was almost quantitative remaining around 94% and 97% being desorbed when desorption frequence of Na2CO3 was up to three times. The measure of Zeta potential and infrared spectroscopy analysis showed that the ioselectric point of Gordona amarae in water was 3.50, up to 4.02 when loaded Pb2+, down to 3.02 when DA doseage added in the loaded biomass. Experiments indicated the lead bosorpting process was likely to involving in the group of -NHCOCH3 and COO- on the cell wall, while the biosorptive flotation was concerned cooperatively to be basing on electrostatic attraction, hydrogen bond, ion exchange and chemical complexation. SEM observation showed that Gordona amarae biomass loaded Hg2+ changed into flocculent matter.
Zhou
Dong-qin
DQ
School of Resources & Civil Engineering, Northeastern University, Shengyang 110004, China. zhoudongqin1973@163.com
Wei
De-zhou
DZ
D000042:Absorption; D001673:Biodegradation, Environmental; D003300:Copper / Q000378:metabolism; D033601:Gordonia Bacterium / Q000378:metabolism*; D007220:Industrial Waste / Q000032:analysis; D007854:Lead / Q000378:metabolism; D008628:Mercury / Q000378:metabolism; D019216:Metals, Heavy / Q000378:metabolism*; D014865:Waste Disposal, Fluid / Q000379:methods*
D007220:Industrial Waste; D019216:Metals, Heavy; D007854:Lead; D003300:Copper; D008628:Mercury