title: Simultaneous removal of SO2 and trace SeO2 from flue gas: effect of product layer on mass transfer.
abstract: Sulfur dioxide (SO2) and trace elements are all pollutants derived from coal combustion. This study relates to the simultaneous removal of sulfur and trace selenium dioxide (SeO2) by calcium oxide (CaO) adsorption in the medium temperature range, especially the mass transfer effect of sulfate product layer on trace elements. Through experiments on CaO adsorbing different concentrations of SO2 gases, conclusions can be drawn that although the product layer introduces extra mass transfer resistance into the sorbent-gas reaction process, the extent of CaO adsorption ability loss due to this factor decreases with decreasing SO2 concentration. When the gas concentration is at trace level, the loss of CaO adsorption ability can be neglected. Subsequent experiments on CaO adsorbing trace SeO2 gas suggest that the sulfate product layer, whether it is thick or thin, has no obvious effect on the CaO ability to adsorb trace SeO2 gas.
authors.affiliation: Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084, China. liyuzhong03@mails.tsinghua.edu.cn
authors.forename: Yuzhong
authors.initials: Y
authors.lastname: Li
authors.forename: Huiling
authors.initials: H
authors.lastname: Tong
authors.forename: Yuqun
authors.initials: Y
authors.lastname: Zhuo
authors.forename: Changhe
authors.initials: C
authors.lastname: Chen
authors.forename: Xuchang
authors.initials: X
authors.lastname: Xu
mesh_terms: D000327:Adsorption; D000393:Air Pollutants / Q000737:chemistry*; D000397:Air Pollution / Q000517:prevention & control; D017610:Calcium Compounds / Q000737:chemistry; D003031:Coal; D004058:Diffusion; D005740:Gases / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry; D018036:Selenium Compounds / Q000737:chemistry*; D064588:Selenium Oxides; D013431:Sulfates / Q000737:chemistry; D013458:Sulfur Dioxide / Q000737:chemistry*; D013696:Temperature
chemical_list: D000393:Air Pollutants; D017610:Calcium Compounds; D003031:Coal; D005740:Gases; D010087:Oxides; D018036:Selenium Compounds; D064588:Selenium Oxides; D013431:Sulfates; D013458:Sulfur Dioxide; C016538:lime