Study on the fluorescence behavior of p-sulfonated calix[4,6]arene in cationic surfactant cetyltrimethylammonium bromide solution and its analytical application.
The fluorescence properties of p-sulfonated calix[4,6]arene (SCnA, n=4, 6) in cationic surfactant cetyltrimethylammonium bromide (CTAB) solution were investigated. It was found that the fluorescence intensity of SCnA could be enhanced markedly by an appropriate amount of CTAB. The results indicate the formation of complex between CTAB and SCnA at a 1:1 complex stoichiometry and their association constants were calculated by applying a deduced equation. Based on the obtained results, a new fluorimetric method has been developed for rapid determination of SCnA with a good linearity in the concentration range of 2x10(-7) to 7x10(-6)mol L-1.
Zhou
Yunyou
Y
College of Chemistry and Materials Science, Anhui Key Laboratory of Functional Molecular Solids, Anhui Normal University, Wuhu 241000, China. zy161299@mail.ahnu.edu.cn
Liu
Chun
C
Xu
Hongwei
H
Yu
Huapeng
H
Lu
Qin
Q
Wang
Lun
L
D002021:Buffers; D002138:Calibration; D047250:Calixarenes / Q000737:chemistry*; D000077286:Cetrimonium; D002593:Cetrimonium Compounds / Q000737:chemistry*; D005453:Fluorescence; D006863:Hydrogen-Ion Concentration; D012996:Solutions; D013050:Spectrometry, Fluorescence; D013451:Sulfonic Acids / Q000737:chemistry*; D013501:Surface-Active Agents / Q000737:chemistry*
D002021:Buffers; D002593:Cetrimonium Compounds; D012996:Solutions; D013451:Sulfonic Acids; D013501:Surface-Active Agents; D047250:Calixarenes; D000077286:Cetrimonium