title: Selective attachment of 1,4-benzenedimethanethiol on the copper mediated Si(111)-(7 x 7) surface through S-Cu linkage.
abstract: The well-defined and patterned copper clusters formed on the Si(111)-(7 x 7) surface have been employed as a template for selective binding of 1,4-benzenedimethanethiol (HS-CH2-C6H4-CH2-SH, 1,4-BDMT), to form ordered molecular nanostructures. Scanning tunneling microscopic (STM) studies showed that each 1,4-BDMT molecule preferentially binds to two neighboring copper atoms within one copper cluster through the S-Cu interaction with its molecular plane parallel to the surface, whereas some 1,4-BDMT bond to individually adsorbed copper atoms, resulting in an upright configuration. Large-scale two-dimensional molecular nanostructures can be obtained using this patterned assembly technique. Our experiments demonstrate the feasibility for controllable growth of ordered molecular nanostructures on the Si(111)-(7 x 7) surface.
authors.forename: Yong Ping
authors.initials: YP
authors.lastname: Zhang
authors.forename: Kian Soon
authors.initials: KS
authors.lastname: Yong
authors.forename: Yee Hing
authors.initials: YH
authors.lastname: Lai
authors.forename: Guo Qin
authors.initials: GQ
authors.lastname: Xu
authors.forename: Xue Sen
authors.initials: XS
authors.lastname: Wang