Highly diastereoselective formation and reactions of a non-mesomerically stabilized, lithiated alpha-thiocarbanion.
A new class of non-mesomerically stabilized, unbranched, configurationally stable lithiated alpha-thiocarbanion has been synthesized and its stereospecific reactions with several electrophiles were investigated.
Sonawane
Ravindra P
RP
Organisch-Chemisches Institut der Universität, Westfälische Wilhelms-Universität Münster, Corrensstrasse 40, 48149, Münster, Germany.
Fröhlich
Roland
R
Hoppe
Dieter
D