Study on ultrasound assisted precipitation of CL-20 and its effect on morphology and sensitivity.
Applying ultrasound to crystallizing systems offers significant advantages for modifying and improving the processes as well as quality of products. This paper reports on ultrasound assisted reprecipitation of CL-20 to obtain fine particles as well as to achieve desired morphology, which will improve insensitivity characteristics. In this study, CL-20 has been reprecipitated by sonication process and has been characterized by DSC, SEM and particle size analysis. The results are compared with control CL-20 sample (unsonicated). SEM photographs revealed that sonication process offer uniform crystalline morphology without any agglomeration. The particle size of sonicated CL-20 sample obtained is around 5+/-1 microm with a narrow particle size distribution. The DSC thermogram of sonicated and unsonicated sample is identical. CL-20 samples were subjected to impact and friction sensitivity experiments, the results indicate the sensitivity characteristics reduced considerably. Ultrasonic assisted crystallization technique reduces the time of reprecipitation considerably with an enhanced recovery of CL-20 with a very narrow particle size distribution.
Sivabalan
R
R
High Energy Materials Research Laboratory, Sutarwadi, Pune 411 021, India. rsivabalan2001@yahoo.co.in
Gore
G M
GM
Nair
U R
UR
Saikia
A
A
Venugopalan
S
S
Gandhe
B R
BR
D001372:Aza Compounds / Q000737:chemistry*; D011232:Chemical Precipitation; D003460:Crystallization; D006571:Heterocyclic Compounds / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D008968:Molecular Conformation; D010316:Particle Size; D014465:Ultrasonics
C482139:2,4,6,8,10,12-hexanitro-2,4,6,8,10,12-hexaaza-isowurtzitane; D001372:Aza Compounds; D006571:Heterocyclic Compounds