title: Crystal structure of a CsF-uranyl-salen complex. An unusual cesium-chlorine coordination.
abstract: Complexation of CsF with the ditopic uranyl-salen receptor results in a solid-state structure, in which the coordination sphere of cesium is filled by ligation to one of the chlorine atoms of the solvent chloroform. This X-ray structure is the first example of chloroform ligation to an alkali-metal ion.
authors.affiliation: Nanoscience Center, Department of Chemistry, University of Jyväskylä, P.O. Box 35, 40014 JYU, Finland.
authors.forename: Massimo
authors.initials: M
authors.lastname: Cametti
authors.forename: Maija
authors.initials: M
authors.lastname: Nissinen
authors.forename: Antonella
authors.initials: A
authors.lastname: Dalla Cort
authors.forename: Kari
authors.initials: K
authors.lastname: Rissanen
authors.forename: Luigi
authors.initials: L
authors.lastname: Mandolini