title: Investigation of physicochemical properties of lactam-based Brønsted acidic ionic liquids.
abstract: Novel lactam-cation-based Brønsted acid ionic liquids (ILs) were prepared through a simple and atom-economic neutralization reaction between a lactam, such as caprolactam and butyrolactam, and a Brønsted acid, HX, where X is BF4-, CF3COO-, phCOO-, ClCH2COO-, NO3-, or H2PO4-. The density, viscosity, acidic scale, electrochemical window, temperature dependency of ionic conductivity, and thermal property of these ILs were measured and investigated in detail. The results show that protonated caprolactam tetrafluoroborate (CPBF) has a relatively strong acidity with -0.22 of Hammett acidic scale H0 and caprolactam trifluoroacetate (CPTFA) and pyrrolidonium trifluoroacetate (PYTFA) ILs possess very low viscosities, that is, 28 cP and 11 cP, respectively. An investigation of thermal property showed that a wide liquid range (up to -90 degrees C), moderate thermal stability (up to 249 degrees C for 10% of decomposition), and complex polymorphism were observed in these ILs. In comparison to imidazolium-cation-based ILs, the lactam-cation-based Brønsted acid ILs have a relatively lower cost, lower toxicity, and comparable ion conductivity and heat storage density (more than 200 MJ/m3). They have wide applicable perspectives for fuel cell devices, thermal transfer fluids, and acid-catalyzed reaction media and catalysts as replacements of conventional inorganic acids.
authors.affiliation: Centre for Green Chemistry and Catalysis, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, PRC.
authors.forename: Zhengyin
authors.initials: Z
authors.lastname: Du
authors.forename: Zuopeng
authors.initials: Z
authors.lastname: Li
authors.forename: Shu
authors.initials: S
authors.lastname: Guo
authors.forename: Juan
authors.initials: J
authors.lastname: Zhang
authors.forename: Laiying
authors.initials: L
authors.lastname: Zhu
authors.forename: Youquan
authors.initials: Y
authors.lastname: Deng