title: Slow dynamics and re-entrant melting in a polydisperse hard-sphere fluid.
abstract: Extensive molecular dynamics simulations are performed at 6% polydispersity to investigate the phase diagram of a polydisperse hard-sphere fluid and the dynamical behavior in each phase. As the volume fraction phi is increased, the existence of a supercooled liquid is suggested above phi = 0.5524 by the mean-field analysis proposed recently. The first-order phase transition from supercooled liquid to crystal is then shown to occur around phi = 0.5630. The occurrence of re-entrant melting, a first-order phase transition from crystal to supercooled liquid, is also found around phi = 0.5715. The existence of the glass transition is thus suggested, even in the hard-sphere fluid with small polydispersity.
authors.affiliation: Institute of Fluid Science, Tohoku University, Sendai, 980-8577, Japan. tokuyama@fmail.ifs.tohoku.ac.jp
authors.forename: Michio
authors.initials: M
authors.lastname: Tokuyama
authors.forename: Yayoi
authors.initials: Y
authors.lastname: Terada