title: Photophysical properties of oligo(2,3-thienyleneethynylene)s.
abstract: Photophysical properties of oligo(2,3-thienyleneethynylene)s (nTE, n denotes the number of thiophene rings, n = 2, 3) in benzene were investigated using steady-state, time-resolved fluorescence, and transient absorption spectroscopies. For 2TE, generation of the radiative S2 and nonradiative S1 states was confirmed. Upon excitation, the S2 state was initially generated and deactivated to the S1 state within 10 ps. The S1 state exhibited the transient absorption band at 470 nm, of which the lifetime was estimated to be 5.3 ns. In the case of 3TE, on the other hand, it was revealed that the radiative S1 state with a transient absorption peak at 650 nm was generated upon excitation. The T1 states of nTE were generated from the S1 states. The quantum yields were estimated to be 0.52 and 0.54 for 2TE and 3TE, respectively. Extremely fast reactions in the higher triplet excited state were indicated for both 2TE and 3TE.
authors.affiliation: The Institute of Scientific and Industrial Research (SANKEN), Osaka University, Mihogaoka 8-1, Ibaraki, Osaka 567-0047, Japan.
authors.forename: Yosuke
authors.initials: Y
authors.lastname: Oseki
authors.forename: Mamoru
authors.initials: M
authors.lastname: Fujitsuka
authors.forename: Michihiro
authors.initials: M
authors.lastname: Hara
authors.forename: Xichen
authors.initials: X
authors.lastname: Cai
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Ie
authors.forename: Yoshio
authors.initials: Y
authors.lastname: Aso
authors.forename: Tetsuro
authors.initials: T
authors.lastname: Majima