Monetite formed in mixed solvents of water and ethylene glycol and its transformation to hydroxyapatite.
Agglomerated nanorods of hydroxyapatite have been synthesized using monetite as a precursor in a NaOH solution. Monetite consisting of nanosheets has been successfully synthesized by a one-step microwave-assisted method using CaCl(2).2.5H(2)O, NaH(2)PO(4), and sodium dodecyl sulfate (SDS) in water/ethylene glycol (EG) mixed solvents. The effects of the molar ratio of water to EG and the reaction time on the products were investigated. The products were characterized by X-ray powder diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and Fourier transform infrared spectrometry (FTIR).
Ma
Ming-Guo
MG
State Key Laboratory of High Performance Ceramics and Superfine Microstructure, Biomaterials and Tissue Engineering Research Center, Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, People's Republic of China.
Zhu
Ying-Jie
YJ
Chang
Jiang
J
D002130:Calcium Phosphates / Q000138:chemical synthesis* / Q000737:chemistry; D017886:Durapatite / Q000138:chemical synthesis* / Q000737:chemistry / Q000528:radiation effects; D019855:Ethylene Glycol / Q000737:chemistry* / Q000528:radiation effects; D008855:Microscopy, Electron, Scanning; D008872:Microwaves; D043942:Nanotubes / Q000737:chemistry*; D010316:Particle Size; D033362:Powder Diffraction; D012997:Solvents / Q000737:chemistry / Q000528:radiation effects; D017550:Spectroscopy, Fourier Transform Infrared; D014867:Water / Q000737:chemistry
D002130:Calcium Phosphates; D012997:Solvents; D014867:Water; C485838:calcium phosphate, monobasic, anhydrous; D017886:Durapatite; D019855:Ethylene Glycol