Development of bacteriorhodopsin analogues and studies of charge separated excited states in the photoprocesses of linear polyenes.
Development of bacteriorhodopsin (bR) analogues employing chromophore substitution technique for the purpose of characterizing the binding site of bR and generating bR analogues with novel opto-electronic properties for applications as photoactive element in nanotechnical devices are described. Additionally, the photophysical and photochemical properties of variously substituted diarylpolyenes as models of photobiologically relevant linear polyenes are discussed. The role of charge separated dipolar excited states in the photoprocesses of linear polyenes is highlighted.
Singh
Anil K
AK
Department of Chemistry, Indian Institute of Technology Bombay, Powai, Mumbai, India. retinal@chem.iitb.ac.in
Hota
Prasanta K
PK
D001436:Bacteriorhodopsins / Q000737:chemistry* / Q000502:physiology / Q000528:radiation effects*; D001665:Binding Sites; D006217:Halobacterium / Q000737:chemistry*; D008954:Models, Biological; D008956:Models, Chemical; D036103:Nanotechnology; D010777:Photochemistry; D011090:Polyenes / Q000737:chemistry* / Q000378:metabolism; D013237:Stereoisomerism
D011090:Polyenes; D001436:Bacteriorhodopsins