title: Synthesis, structure, and physical properties of hybrid nanocomposites for solid-state dye lasers.
abstract: We report on the synthesis, structural characterization, physical properties, and lasing action of two organic dyes, Rhodamine 6G (Rh6G) and Pyrromethene 597 (PM597), incorporated into new hybrid organic-inorganic materials, where the organic component was either poly(2-hydroxyethyl-methacrylate) (PHEMA) or copolymers of HEMA with methyl methacrylate (MMA), and the inorganic counterpart consisted of silica derived from hydrolysis-condensation of methyltriethoxysilane (TRIEOS) in weight proportion of up to 30%. Lasing efficiencies of up 23% and high photostabilities, with no sign of degradation in the initial laser output after 100 000 pump pulses at 10 Hz, were demonstrated when pumping the samples transversely at 534 nm with 5.5 mJ/pulse. A direct relationship could be established between the structure of the hybrid materials, analyzed by solid-state NMR, and their laser behavior. An inorganic network dominated by di-/tri- substituted silicates in a proportion approximately 35:65, corresponding to samples of HEMA with 15 and 20 wt % proportion of TRIEOS, optimizes the lasing photostability. The thermal properties of these materials, together with the high homogeneity revealed by atomic force microscopy (AFM) images, even in compounds with high silica content, indicate their microstructure to be a continuous phase, corresponding to the polymer matrix, which "traps" the silica components at molecular level via covalent bonding, with few or no silica islands.
authors.affiliation: Instituto de Química-Física "Rocasolano", C.S.I.C., Serrano 119, 28006 Madrid, Spain.
authors.forename: I
authors.initials: I
authors.lastname: García-Moreno
authors.forename: A
authors.initials: A
authors.lastname: Costela
authors.forename: A
authors.initials: A
authors.lastname: Cuesta
authors.forename: O
authors.initials: O
authors.lastname: García
authors.forename: D
authors.initials: D
authors.lastname: del Agua
authors.forename: R
authors.initials: R
authors.lastname: Sastre
mesh_terms: D055598:Chemical Phenomena; D002627:Chemistry, Physical; D009682:Magnetic Resonance Spectroscopy / Q000379:methods / Q000592:standards; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry*; D055095:Optics and Photonics; D011102:Polyhydroxyethyl Methacrylate / Q000737:chemistry*; D019904:Polymethyl Methacrylate / Q000737:chemistry*; D011162:Porphobilinogen / Q000031:analogs & derivatives* / Q000737:chemistry; D012015:Reference Standards; D012235:Rhodamines / Q000737:chemistry*; D012821:Silanes / Q000138:chemical synthesis / Q000737:chemistry; D012822:Silicon Dioxide / Q000138:chemical synthesis / Q000737:chemistry; D013055:Spectrophotometry, Infrared / Q000379:methods; D013696:Temperature
chemical_list: D012235:Rhodamines; D012821:Silanes; C504197:pyrromethene 597; C026188:rhodamine 6G; D011102:Polyhydroxyethyl Methacrylate; D011162:Porphobilinogen; D012822:Silicon Dioxide; D019904:Polymethyl Methacrylate