title: Experimental observations of water-framework interactions in a hydrated microporous aluminum phosphate.
abstract: Differential scanning calorimetry of the hydrated, microporous aluminum phosphate AlPO-14 shows two distinct water losses between room temperature and 120 degrees C, indicating the presence of two types of water in the solid. Multiple-quantum magic angle spinning (MQMAS) (27)Al NMR shows that, while in dehydrated AlPO-14 all aluminum is found in tetrahedral sites, on hydration a significant proportion of the aluminum increases its coordination number to 6. This accounts for the presence of tightly bound water. The first detailed incoherent inelastic neutron scattering (IINS) studies of such a system give a spectrum with distinct and sharp librational bands for bound water, significantly different than seen in ice Ih. Using these data, and by consideration of the crystal structure of dehydrated AlPO-14, we propose a model for the hydrated material in which the tightly bound water bridges pairs of Lewis acidic framework aluminums in a dense region of the structure, while loosely bound water resides in the pores of the solid. Further IINS measurements using a high-incident neutron energy provide data that are in agreement with our model. We can detect two O-H stretching modes for bound water in hydrated AlPO-14, consistent with the model of two types of water present in the material, with the loosely bound water connected to neighboring water molecules by intermolecular hydrogen bonds.
authors.affiliation: Department of Chemistry, University of Exeter, Stocker Road, Exeter EX4 4QD, UK.
authors.forename: Huaixin
authors.initials: H
authors.lastname: Yang
authors.forename: Richard I
authors.initials: RI
authors.lastname: Walton
authors.forename: Silke
authors.initials: S
authors.lastname: Biedasek
authors.forename: Sasa
authors.initials: S
authors.lastname: Antonijevic
authors.forename: Stephen
authors.initials: S
authors.lastname: Wimperis
authors.forename: Anibal J
authors.initials: AJ
authors.lastname: Ramirez-Cuesta
authors.forename: Jichen
authors.initials: J
authors.lastname: Li
authors.forename: Alexander I
authors.initials: AI
authors.lastname: Kolesnikov