title: Ultrafast to slow orientational dynamics of a homeotropically aligned nematic liquid crystal.
abstract: The orientational dynamics of a homeotropically aligned nematic liquid crystal, 4'-pentyl-4-biphenylcarbonitrile (5-CB), is studied over more than six decades of time (500 fs to 2 mus) using optical heterodyne detected optical Kerr effect experiments. In contrast to the dynamics of nematogens in the isotropic phase, the data do not decay as a highly temperature-dependent exponential on the longest time scale, but rather, a temperature-independent power law spanning more than two decades of time, the final power law, is observed. On short time scales (approximately 3 ps to approximately 1 ns) another power law, the intermediate power law, is observed that is temperature dependent. The power law exponent of the correlation function associated with the intermediate power law displays a linear dependence on the change in the nematic order parameter with temperature. Between the intermediate power law and the final power law, there is a crossover region that displays an inflection point. The temperature-dependent orientational dynamics in the nematic phase are shown to be very different than those observed in the isotropic phase.
authors.affiliation: Department of Chemistry, Stanford University, Stanford, California 94305, USA.
authors.forename: Jie
authors.initials: J
authors.lastname: Li
authors.forename: Irene
authors.initials: I
authors.lastname: Wang
authors.forename: M D
authors.initials: MD
authors.lastname: Fayer