title: A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes.
abstract: The new zinc compound N-cyclohexyl-2-(cyclohexylamino)troponiminate zinc methyl, [(Cy)2ATI]ZnMe, was synthesized and showed a superior reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to previously reported homogeneous zinc complexes.
authors.affiliation: Technische Universität Berlin, Institut für Chemie, Strasse des 17. Juni 135, 10623 Berlin, Germany.
authors.forename: Maximilian
authors.initials: M
authors.lastname: Dochnahl
authors.forename: Jens-Wolfgang
authors.initials: JW
authors.lastname: Pissarek
authors.forename: Siegfried
authors.initials: S
authors.lastname: Blechert
authors.forename: Karolin
authors.initials: K
authors.lastname: Löhnwitz
authors.forename: Peter W
authors.initials: PW
authors.lastname: Roesky
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D000586:Amination; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012680:Sensitivity and Specificity; D015032:Zinc / Q000737:chemistry*
chemical_list: D000475:Alkenes; D009942:Organometallic Compounds; D015032:Zinc