Incorporation of 2,6-di(4,4'-dipyridyl)-9-thiabicyclo[3.3.1]nonane into discrete 2D supramolecules via coordination-driven self-assembly.
The synthesis and characterization of three new supramolecular complexes 6-8 (a rhomboid and two hexagons) via coordination-driven self-assembly are reported in excellent yields (>90%). These assemblies have 2,6-di(4,4'-dipyridyl)-9-thiabicyclo[3.3.1]nonane 2 as the bridging tecton. All assemblies were characterized by multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR), and elemental analysis. The X-ray structure of the 120 degrees tecton 2 is also discussed.
Yang
Hai-Bo
HB
Department of Chemistry, University of Utah, 315 South 1400 East, RM, 2020, Salt Lake City, Utah 84112, USA.
Das
Neeladri
N
Huang
Feihe
F
Hawkridge
Adam M
AM
Díaz
David D
DD
Arif
Atta M
AM
Finn
M G
MG
Muddiman
David C
DC
Stang
Peter J
PJ
D001643:Bridged Bicyclo Compounds / Q000737:chemistry*; D015394:Molecular Structure; D010984:Platinum / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization; D017550:Spectroscopy, Fourier Transform Infrared
C520382:2,6-di(4,4'-dipyridyl)-9-thiabicyclo(3.3.1)nonane; D001643:Bridged Bicyclo Compounds; D011725:Pyridines; D010984:Platinum