title: A diastereoselective and concise synthesis of functionalised vinyl epoxides with a Morita-Baylis-Hillman backbone.
abstract: A highly diastereoselective organocatalytic synthesis of unique functionalised vinyl epoxides, displaying a Morita-Baylis-Hillman backbone, has been developed by means of an user friendly sulfonium ylide epoxidation of aldehydes from a readily available alpha-(bromomethyl)acrylamide derivative. The first result in the asymmetric version is discussed.
authors.affiliation: Laboratoire de Chimie Moléculaire et Thio-organique (UMR CNRS 6507), ENSICaen-Université, 6 Boulevard du Maréchal Juin, F-14050, Caen, France.
authors.forename: Marion
authors.initials: M
authors.lastname: Davoust
authors.forename: Jean-François
authors.initials: JF
authors.lastname: Brière
authors.forename: Patrick
authors.initials: P
authors.lastname: Metzner