On a novel coordination mode of phosphinine C5H5P.
In an unprecedented coordination mode two phosphinines simultaneously bridge a Mn-Mn bond and the latter with two Mn(CO)3 fragments; the distortion of the resulting central heterobicyclo[1.1.0]butane unit follows from the Mn(18VE) requirement.
Elschenbroich
Christoph
C
Fachbereich Chemie, Philipps-Universität Marburg, 35032 Marburg, Germany. eb@chemie.uni-marburg.de
Six
Jörg
J
Harms
Klaus
K