Reactions inside a porous nanocapsule/artificial cell: encapsulates' structuring directed by internal surface deprotonations.
In the cavities of unprecedentedly functionalised, spherical, porous capsules of the type {Pentagon}12{Linker}30 identical with [{(Mo)Mo5O21(H2O)6}12{Mo2O4(ligand)}30]n- reactions with the ligands -i.e. at the internal shell surfaces - can be performed, in the present case deliberate aquation/hydration and deprotonation reactions at the linker fragments {(Mo2O4)C2O4H}+ similar to that reported in the literature for [(NH3)5CoC2O4H]2+ in solution.
Müller
Achim
A
Fakultät für Chemie der Universität, Postfach 100131, 33501, Bielefeld, Germany. a.mueller@uni-bielefeld.de
Toma
Liviu
L
Bögge
Hartmut
H
Henry
Marc
M
Haupt
Erhard T K
ET
Mix
Andreas
A
Sousa
Filipa L
FL