Nucleation and growth characteristics of a binary low-mass organogel.
The system of bis(2-ethylhexyl) sodium sulfosuccinate and 4-chlorophenol, when dissolved in a nonpolar organic solvent, forms an organogel. The fibers of this organogel are formed through a nucleation-growth phenomenon. By reducing evaporation of the pregel solution, the fibers can be directed to grow with extremely long persistence lengths. Alignment of multiple fibers is achieved by inducting growth at the air-solution interface. The interplay of two zones, one above the critical nucleation concentration and the other below, allows orientation to be accomplished as fiber growth proceeds. The observations have implications for the use of the organogel as a template for materials synthesis.
Tan
Grace
G
Department of Chemical and Biomolecular Engineering and Department of Chemistry, Tulane University, New Orleans, Louisiana 70118, USA.
John
Vijay T
VT
McPherson
Gary L
GL