A new homogeneous zinc complex with increased reactivity for the intramolecular hydroamination of alkenes.
The new zinc compound N-cyclohexyl-2-(cyclohexylamino)troponiminate zinc methyl, [(Cy)2ATI]ZnMe, was synthesized and showed a superior reactivity in the intramolecular hydroamination reaction of non-activated alkenes compared to previously reported homogeneous zinc complexes.
Dochnahl
Maximilian
M
Technische Universität Berlin, Institut für Chemie, Strasse des 17. Juni 135, 10623 Berlin, Germany.
Pissarek
Jens-Wolfgang
JW
Blechert
Siegfried
S
Löhnwitz
Karolin
K
Roesky
Peter W
PW
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D000586:Amination; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012680:Sensitivity and Specificity; D015032:Zinc / Q000737:chemistry*
D000475:Alkenes; D009942:Organometallic Compounds; D015032:Zinc