title: In situ surface x-ray diffraction studies of homoepitaxial electrochemical growth on Au(100).
abstract: Direct in situ x-ray surface scattering studies of growth at a solid-liquid interface are demonstrated using the homoepitaxial electrodeposition on Au(100) as an example. With decreasing potential transitions from step-flow to layer-by-layer growth, manifested by layering oscillations in the x-ray intensity, then to multilayer growth, and finally back to layer-by-layer growth were observed. This complex growth behavior can be explained by the effect of anion coadsorbates and the potential-dependent Au surface reconstruction on the Au surface mobility.
authors.affiliation: Institut für Experimentelle und Angewandte Physik, Universität Kiel, Olshausenstrasse 40, 24098 Kiel, Germany.
authors.forename: K
authors.initials: K
authors.lastname: Krug
authors.forename: J
authors.initials: J
authors.lastname: Stettner
authors.forename: O M
authors.initials: OM
authors.lastname: Magnussen