Study on use of MSWI fly ash in ceramic tile.
In this work, MSWI (municipal solid waste incineration) fly ash is used as a blending in production of ceramic tile by taking advantage of its high contents of SiO(2), Al(2)O(3) and CaO. Besides, macro-performance and microstructure of the product as well as its leaching toxicity in practical application were studied by means of XRD, IR and SEM analysis, and leaching toxicity and sequential chemical extraction analysis of the product. It is found that when 20% fly ash is added, the product registers a high compressive strength of 18.6MPa/cm(2) and a low water absorption of 7.4% after being sintered at 960 degrees C. It is found that the glazed tile shows excellent resistance against leaching, in accordance with HVEP stand, of heavy metals with Cd<0.0002ppm, Pb<0.0113ppm and Zn<0.0749ppm, and Hg below the low detection limit. These results show that heavy metals are cemented among the solid lattice in the product and can hardly be extracted. Leaching toxicity of heavy metals in the product, especially Hg, Pb, Zn and Cd, is substantially reduced to less than one-tenth of that in fly ash. In addition, specifications of Hg, Pb, Zn and Cd are largely changed and only a small portion of these heavy metals exists in soluble phases. These results as a whole suggest that the use of MSWI fly ash in ceramic tile constitutes a potential means of adding value.
Haiying
Zhang
Z
Department of Environmental and Energy Engineering, Shanghai Institute of Technology, Shanghai, China. haiying86@sohu.com
Youcai
Zhao
Z
Jingyu
Qi
Q
D002244:Carbon / Q000737:chemistry*; D002516:Ceramics / Q000138:chemical synthesis / Q000737:chemistry*; D060729:Coal Ash; D019245:Compressive Strength; D004147:Dioxins / Q000737:chemistry; D006358:Hot Temperature; D017745:Incineration; D008422:Materials Testing / Q000706:statistics & numerical data*; D019216:Metals, Heavy / Q000737:chemistry; D052638:Particulate Matter / Q000737:chemistry*; D014867:Water / Q000032:analysis
D060729:Coal Ash; D004147:Dioxins; D019216:Metals, Heavy; D052638:Particulate Matter; D014867:Water; D002244:Carbon