title: Incorporation of 2,6-di(4,4'-dipyridyl)-9-thiabicyclo[3.3.1]nonane into discrete 2D supramolecules via coordination-driven self-assembly.
abstract: The synthesis and characterization of three new supramolecular complexes 6-8 (a rhomboid and two hexagons) via coordination-driven self-assembly are reported in excellent yields (>90%). These assemblies have 2,6-di(4,4'-dipyridyl)-9-thiabicyclo[3.3.1]nonane 2 as the bridging tecton. All assemblies were characterized by multinuclear NMR (1H and 31P), mass spectrometry (ESI-MS and ESI-FT-ICR), and elemental analysis. The X-ray structure of the 120 degrees tecton 2 is also discussed.
authors.affiliation: Department of Chemistry, University of Utah, 315 South 1400 East, RM, 2020, Salt Lake City, Utah 84112, USA.
authors.forename: Hai-Bo
authors.initials: HB
authors.lastname: Yang
authors.forename: Neeladri
authors.initials: N
authors.lastname: Das
authors.forename: Feihe
authors.initials: F
authors.lastname: Huang
authors.forename: Adam M
authors.initials: AM
authors.lastname: Hawkridge
authors.forename: David D
authors.initials: DD
authors.lastname: Díaz
authors.forename: Atta M
authors.initials: AM
authors.lastname: Arif
authors.forename: M G
authors.initials: MG
authors.lastname: Finn
authors.forename: David C
authors.initials: DC
authors.lastname: Muddiman
authors.forename: Peter J
authors.initials: PJ
authors.lastname: Stang
mesh_terms: D001643:Bridged Bicyclo Compounds / Q000737:chemistry*; D015394:Molecular Structure; D010984:Platinum / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization; D017550:Spectroscopy, Fourier Transform Infrared
chemical_list: C520382:2,6-di(4,4'-dipyridyl)-9-thiabicyclo(3.3.1)nonane; D001643:Bridged Bicyclo Compounds; D011725:Pyridines; D010984:Platinum