Fe L-edge XAS studies of K4[Fe(CN)6] and K3[Fe(CN)6]: a direct probe of back-bonding.
Distinct spectral features at the Fe L-edge of the two compounds K3[Fe(CN)6] and K4[Fe(CN)6] have been identified and characterized as arising from contributions of the ligand pi orbitals due to metal-to-ligand back-bonding. In addition, the L-edge energy shifts and total intensities allow changes in the ligand field and effective nuclear charge to be determined. It is found that the ligand field term dominates the edge energy shift. The results of the experimental analysis were compared to BP86 DFT calculations. The overall agreement between the calculations and experiment is good; however, a larger difference in the amount of pi back-donation between Fe(II) and Fe(III) is found experimentally. The analysis of L-edge spectral shape, energy shift, and total intensity demonstrates that Fe L-edge X-ray absorption spectroscopy provides a direct probe of metal-to-ligand back-bonding.
Hocking
Rosalie K
RK
Department of Chemistry, Stanford University, Stanford, California 94305, USA.
Wasinger
Erik C
EC
de Groot
Frank M F
FM
Hodgson
Keith O
KO
Hedman
Britt
B
Solomon
Edward I
EI
D000465:Algorithms; D005292:Ferricyanides / Q000737:chemistry*; D008024:Ligands; D011188:Potassium / Q000737:chemistry*; D013057:Spectrum Analysis / Q000379:methods; D014965:X-Rays
D005292:Ferricyanides; D008024:Ligands; C007931:hexacyanoferrate III; D011188:Potassium; C028033:potassium ferricyanide