Photolysis of heptanal.
Photolysis of heptanal is investigated from an experimental and theoretical point of view. Photoexcited heptanal is believed to undergo rapid intersystem crossing to the triplet manifold and from there undergoes internal H-abstraction to form biradical intermediates. The favored gamma-H abstraction pathway can cyclize or cleave to 1-pentene and hydroxyethene, which tautomerizes to acetaldehyde. Yields of 1-pentene and acetaldehyde were measured at 62 +/- 7% and 63 +/- 7%, respectively, relative to photolyzed heptanal. Additionally, small quantities of hexanal and hexanol were observed. On the basis of combined experimental and theoretical evidence, the remaining heptanal photolysis proceeds to form an estimated 10% HCO + hexyl radical and 30% cyclic alcohols, particularly 2-propyl cyclobutanol and 2-ethyl cyclopentanol.
Paulson
Suzanne E
SE
Department of Atmospheric and Oceanic Sciences, University of California, Los Angeles, California 90095-1565, USA. paulson@atmos.ucla.edu
Liu
De-Ling
DL
Orzechowska
Grazyna E
GE
Campos
Luis M
LM
Houk
K N
KN