The first route to large pore metal phosphonates.
The first large pore (free diameter > 7 A) metal phosphonates have been prepared as divalent metal N,N'-piperazinebis(methylenephosphonate)s that possess pores greater than ca. 10 A in free diameter, are stable up to 400 degrees C and offer a route to chiral adsorbents and catalysts.
Groves
John A
JA
School of Chemistry, University of St. Andrews, Purdie Building, North Haugh, St. Andrews, Fife KY16 9ST, UK.
Miller
Stuart R
SR
Warrender
Stewart J
SJ
Mellot-Draznieks
Caroline
C
Lightfoot
Philip
P
Wright
Paul A
PA