title: Reactions inside a porous nanocapsule/artificial cell: encapsulates' structuring directed by internal surface deprotonations.
abstract: In the cavities of unprecedentedly functionalised, spherical, porous capsules of the type {Pentagon}12{Linker}30 identical with [{(Mo)Mo5O21(H2O)6}12{Mo2O4(ligand)}30]n- reactions with the ligands -i.e. at the internal shell surfaces - can be performed, in the present case deliberate aquation/hydration and deprotonation reactions at the linker fragments {(Mo2O4)C2O4H}+ similar to that reported in the literature for [(NH3)5CoC2O4H]2+ in solution.
authors.affiliation: Fakultät für Chemie der Universität, Postfach 100131, 33501, Bielefeld, Germany. a.mueller@uni-bielefeld.de
authors.forename: Achim
authors.initials: A
authors.lastname: Müller
authors.forename: Liviu
authors.initials: L
authors.lastname: Toma
authors.forename: Hartmut
authors.initials: H
authors.lastname: Bögge
authors.forename: Marc
authors.initials: M
authors.lastname: Henry
authors.forename: Erhard T K
authors.initials: ET
authors.lastname: Haupt
authors.forename: Andreas
authors.initials: A
authors.lastname: Mix
authors.forename: Filipa L
authors.initials: FL
authors.lastname: Sousa