BiCl3-catalyzed propargylic substitution reaction of propargylic alcohols with C-, O-, S- and N-centered nucleophiles.
A general and efficient BiCl3-catalyzed substitution reaction of propargylic alcohols with carbon and heteroatom-centered nucleophiles such as allyl trimethylsilane, alcohols, aromatic compounds, thiols and amides, leading to the construction of C-C, C-O, C-S and C-N bonds, has been developed.
Zhan
Zhuang-ping
ZP
Department of Chemistry and Key Laboratory for Chemical Biology of Fujian Province, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen, 361005 Fujian, P. R. China. zpzhan@xmu.edu.cn
Yang
Wen-zhen
WZ
Yang
Rui-feng
RF
Yu
Jing-liang
JL
Li
Jun-ping
JP
Liu
Hui-juan
HJ