title: Surface and chemical properties of surface-modified UHMWPE powder and mechanical and thermal properties of its impregnated PMMA bone cement, IV: effect of MMA/accelerator on the surface modification of UHMWPE powder.
abstract: In our previous study, we manufactured a reinforced poly(methylmethacrylate) (PMMA) bone cement with 3 wt% of the surface-modified ultra high molecular weight polyethylene (UHMWPE) powder to improve its poor mechanical and thermal properties resulting from unreacted methylmethacrylate (MMA), the generation of bubble and shrinkage, and high curing temperature. In the present study, the effect of ratios of MMA and N,N'-dimethyl-p-toluidine (DMPT) solutions in redox polymerization system was investigated for the surface modification of UHMWPE powder. We characterized physical and chemical properties of surface-modified UHMWPE powder and reinforced bone cements by a scanning electron microscope, ultimate tensile strength (UTS) and curing temperature (Tmax). It was found that UTSs (41.3-51.3 MPa) of the reinforced PMMA bone cements were similar to those (44.5 MPa) of conventional PMMA bone cement (control), as well as significantly higher (P < 0.05) than those (33.8 MPa) of 3 wt% unmodified UHMWPE powder-impregnated bone cement. In particular, the UTS of redox polymerization system using MMA/DMPT solution was better than that of radical system using MMA/xylene solution. Also, Tmax of the reinforced PMMA bone cements decreased from 103 to 72-84 degrees C. From these results, we confirmed that the surface-modified UHMWPE powder can be used as reinforcing agent to improve the mechanical and thermal properties of conventional PMMA bone cement.
authors.affiliation: Department of Advanced Organic Materials Engineering, Chonbuk National University, 664-14, Dukjin-gu, Jeonju 561-756, South Korea.
authors.forename: Dae Hyeok
authors.initials: DH
authors.lastname: Yang
authors.forename: Jong Tae
authors.initials: JT
authors.lastname: Ko
authors.forename: Yong Sik
authors.initials: YS
authors.lastname: Kim
authors.forename: Moon Suk
authors.initials: MS
authors.lastname: Kim
authors.forename: Hyung Sik
authors.initials: HS
authors.lastname: Shin
authors.forename: John M
authors.initials: JM
authors.lastname: Rhee
authors.forename: Gilson
authors.initials: G
authors.lastname: Khang
authors.forename: Hai Bang
authors.initials: HB
authors.lastname: Lee
mesh_terms: D001696:Biomechanical Phenomena; D001698:Biomedical Engineering; D001843:Bone Cements / Q000138:chemical synthesis*; D020366:Methylmethacrylate / Q000737:chemistry*; D008954:Models, Biological; D008970:Molecular Weight; D020959:Polyethylene / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D011208:Powders / Q000737:chemistry; D013499:Surface Properties / Q000187:drug effects; D013501:Surface-Active Agents / Q000737:chemistry*; D013696:Temperature; D013718:Tensile Strength / Q000187:drug effects
chemical_list: D001843:Bone Cements; D011108:Polymers; D011208:Powders; D013501:Surface-Active Agents; D020366:Methylmethacrylate; D020959:Polyethylene