Arrangement of tris(phthalocyaninato) gadolinium triple-decker complexes with multi-octyloxy groups on water surface.
A series of five carefully designed tris(phthalocyaninato) gadolinium triple-decker complexes [Pc(R)8]Gd[Pc(R')8]Gd[Pc(R'')8] (R=R'=R''=H; R=R'=H, R''=OC8H17; R=R''=H, R'=OC8H17; R=H, R'=R''=OC8H17; R=R'=R''=OC8H17) (1-5) were prepared and the film forming properties on water surface were systematically investigated. The limited mean molecular area obtained by pi-A isotherms revealed an "edge-on" conformation for all these compounds. UV-vis absorption spectra showed red-shifted Q bands, indicating the formation of J aggregates and effective intermolecular interaction in solid film. Phthalocyanine rings were found to take tilted orientation with respect to the normal of substrate according to the polarized absorption spectroscopic measurements. Low angle X-ray diffraction results provide direct evidence and therefore clearly clarify the point, for the first time, that unsymmetrical triple-decker molecules pack on the water surface with the unsubstituted phthalocyanine ring set close to the water surface and the substituted phthalocyanine ligand with octyloxy groups lies on the top.
Chen
Yanli
Y
Key Lab for Colloid and Interface Chemistry of Education Ministry, Department of Chemistry, Shandong University, Jinan 250100, China.
Zhang
Ying
Y
Zhu
Peihua
P
Fan
Yingju
Y
Bian
Yongzhong
Y
Li
Xiyou
X
Jiang
Jianzhuang
J