Unprecedented formation of an acetamidate-bridged dinuclear platinum(II) terpyridyl complex-correlation of luminescence properties with the crystal forms and dimerization studies in solution.
An [corrected] acetamidate-bridged dinuclear platinum(ii) terpyridyl complex has been isolated in two crystal forms, a red form and a dark form, with different luminescence properties; electronic absorption, emission and (1)H NMR studies revealed the presence of a dimerization process in the solution state.
Wong
Keith Man-Chung
KM
Department of Chemistry and HKU-CAS Joint Laboratory on New Materials, University of Hong Kong, Pokfulam Road, Hong Kong, P. R. China. wongmc@hku.hk
Zhu
Nianyong
N
Yam
Vivian Wing-Wah
VW
D000577:Amides / Q000737:chemistry*; D003460:Crystallization; D018360:Crystallography, X-Ray; D019281:Dimerization; D049449:Luminescence; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009944:Organoplatinum Compounds / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D012680:Sensitivity and Specificity; D012996:Solutions / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet
D000577:Amides; D009944:Organoplatinum Compounds; D011725:Pyridines; D012996:Solutions