Phane properties of [2.2]paracyclophane/dehydrobenzoannulene hybrids.
A series of [2.2]paracyclophane/dehydrobenzo[14]annulene (PC/DBA) hybrids (hydrocarbons 5, 6, 9, 10 b, and 10 c), [2.2]paracyclophane/dehydro[14]annulene (PC/DA) hybrids (7 and 8) and suitable model systems (11, 12, and 33) has been synthesized. Comparison of the electronic absorption spectra in each series of compounds provides further insight into the global communication between the decks in the [2.2]paracyclophane unit.
Hinrichs
Heino
H
Institut für Organische Chemie, Technische Universität Braunschweig, Hagenring 30, 38106 Braunschweig, Germany.
Boydston
Andrew J
AJ
Jones
Peter G
PG
Hess
Kirsten
K
Herges
Rainer
R
Haley
Michael M
MM
Hopf
Henning
H