title: Effects of temperature on the alignment and electrooptical responses of a nematic nanoscale liquid crystalline film.
abstract: The surface-induced alignment and electrooptical (EO) dynamics of a 50-nm-thick liquid crystalline (4-n-pentyl-4'-cyanobiphenyl; 5CB) film were studied at three temperatures: 25 and 33 degrees C (near the crystalline-nematic and nematic-isotropic transition temperatures, respectively) and 29 degrees C (a median temperature in the stability region of the nematic phase). The ZnSe surfaces that entrap the liquid crystal (LC) film have been polished unidirectionally to produce a grooved surface presenting nanometer-scale corrugations, a structure that induces a planar and homogeneous orientation in the nematic phase. The present work attempts to understand the influences of temperature on the surface-induced alignment and corresponding EO dynamics of the material. Step-scan time-resolved spectroscopy measurements were made to determine the rate constants for the electric-field-induced orientation and thermal relaxation of the 5CB film. The field-driven orientation rates vary sensitively with temperature across a range that spans the stability limits of the nematic phase; the relaxation rates, however, vary very little across this same temperature range. We propose that these differences in LC behavior arise as consequence of the interplay of the temperature dependence of the elastic constants, viscosity, and degree of orientational order of the LC medium. A simple theoretical model provides some understanding of these behaviors.
authors.affiliation: Department of Chemistry, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801, USA.
authors.forename: Lay Min
authors.initials: LM
authors.lastname: Lee
authors.forename: Hye J
authors.initials: HJ
authors.lastname: Kwon
authors.forename: Ralph G
authors.initials: RG
authors.lastname: Nuzzo
authors.forename: Ken S
authors.initials: KS
authors.lastname: Schweizer
mesh_terms: D001713:Biphenyl Compounds / Q000737:chemistry*; D004563:Electrochemistry; D007700:Kinetics; D050866:Liquid Crystals / Q000737:chemistry*; D008567:Membranes, Artificial; D008956:Models, Chemical; D036103:Nanotechnology / Q000379:methods; D009570:Nitriles / Q000737:chemistry*; D055095:Optics and Photonics; D018036:Selenium Compounds / Q000737:chemistry; D013499:Surface Properties; D013696:Temperature; D017967:Zinc Compounds / Q000737:chemistry
chemical_list: D001713:Biphenyl Compounds; D008567:Membranes, Artificial; D009570:Nitriles; D018036:Selenium Compounds; D017967:Zinc Compounds; C433919:4-cyano-4'-pentylbiphenyl; C044696:zinc selenide