title: Spatial and temporal variability of water repellency in a sandy soil contaminated with tar oil and heavy metals.
abstract: Water repellency can induce preferential flow and thus affect water flow and contaminant transport at hazardous waste sites. Since the spatial patterns of water repellency are mostly unknown, it is problematic to use numerical transport models to predict leachate composition. In this study, the spatial variability of soil water repellency was studied at an industrial site contaminated with tar oil, chromium, copper and arsenic. The persistence of water repellency was assessed by the water drop penetration time (WDPT), and the degree of water repellency was quantified by the ethanol percentage (EP) test. Measurements were made at the soil surface along 3.5-12.1 m long transects at different times between March and October 2002. The spatial variability of WDPT, EP, water content, and organic matter content was quantified by variogram analyses. Both the persistence and the degree of water repellency varied seasonally, with the highest water repellency during the summer months. The correlation lengths of WDPT values ranged between 16 and 406 cm, whereas EP values showed no spatial correlation. For field-moist samples, a critical soil water threshold, below which water repellency prevails, was estimated to be 2.5-4%. For oven dry samples, the WDPT values were dependent on the water content prior to drying. The wide range of correlation lengths and the temporal dynamics of spatial repellency patterns suggest that simulations of solute leaching must consider the spatial and temporal variability of soil hydrophobic properties.
authors.affiliation: University of Rostock, Institute for Land Use, Justus-von-Liebig-Weg 6, D-18059 Rostock, Germany. uwe.buczko@uni-rostock.de
authors.forename: Uwe
authors.initials: U
authors.lastname: Buczko
authors.forename: Oliver
authors.initials: O
authors.lastname: Bens
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Durner
mesh_terms: D001151:Arsenic / Q000737:chemistry; D002857:Chromium / Q000737:chemistry; D003300:Copper / Q000737:chemistry; D006812:Humic Substances; D057927:Hydrophobic and Hydrophilic Interactions; D019216:Metals, Heavy / Q000737:chemistry*; D009821:Oils / Q000737:chemistry*; D012987:Soil; D012989:Soil Pollutants / Q000737:chemistry*; D013499:Surface Properties; D014867:Water / Q000737:chemistry*
chemical_list: D006812:Humic Substances; D019216:Metals, Heavy; D009821:Oils; D012987:Soil; D012989:Soil Pollutants; D014867:Water; D002857:Chromium; D003300:Copper; D001151:Arsenic