Phosphine-olefin ligands: a facile dehydrogenative route to catalytically active rhodium complexes.
Facile, metal-mediated, (acceptorless) dehydrogenation of tricyclopentyl phosphine directly affords rhodium chelating phosphine-olefin complexes, some of which are catalytically active for 1,4-additions.
Douglas
Thomas M
TM
Department of Chemistry, University of Bath, Bath, UK.
Le Nôtre
Jérôme
J
Brayshaw
Simon K
SK
Frost
Christopher G
CG
Weller
Andrew S
AS
D000475:Alkenes / Q000737:chemistry*; D002384:Catalysis; D006865:Hydrogenation; D007659:Ketones / Q000138:chemical synthesis / Q000737:chemistry; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D012680:Sensitivity and Specificity
D000475:Alkenes; D007659:Ketones; D008024:Ligands; D009942:Organometallic Compounds; D010720:Phosphines; D012238:Rhodium; C044646:phosphine