title: Chiral molecule-based ferrimagnets with helical structures.
abstract: Two enantiopure one-dimensional complexes with helical structures, [Mn(3)((R,R)-Salcy)(3)(H2O)(2)Fe(CN)(6).2H2O]n (1) and [Mn(3)((S,S)-Salcy)(3)(H2O)(2)Fe(CN)(6).2H2O]n (2) [Salcy = N,N'-(1,2-cyclohexanediylethylene)bis(salicylideneiminato) dianion], have been synthesized and characterized. Magnetic studies show that both complexes are ferrimagnets with the magnetic transition temperature at 3 K.
authors.affiliation: Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, People's Republic of China.
authors.forename: He-Rui
authors.initials: HR
authors.lastname: Wen
authors.forename: Cai-Feng
authors.initials: CF
authors.lastname: Wang
authors.forename: Yi-Zhi
authors.initials: YZ
authors.lastname: Li
authors.forename: Jing-Lin
authors.initials: JL
authors.lastname: Zuo
authors.forename: You
authors.initials: Y
authors.lastname: Song
authors.forename: Xiao-Zeng
authors.initials: XZ
authors.lastname: You
mesh_terms: D018360:Crystallography, X-Ray; D008280:Magnetics; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature
chemical_list: D009942:Organometallic Compounds