Simultaneous two-photon excited fluorescence and one-photon excited phosphorescence from single molecules of an organometallic complex Ir(ppy)3.
We report a study of excited-state lifetimes of the phosphorescent organometallic complex Ir(ppy)3 on ensemble and a single-molecule level. With decreasing concentration, an increasingly intense fast component of 3 ns lifetime appears next to the 1.1 mus phosphorescence. Experimental evidence suggests that strong two-photon absorption followed by fluorescence is responsible for the fast lifetime component.
Koide
Yohei
Y
Department of Organic and Polymeric Materials, Tokyo Institute of Technology, Ookayama 2-12-1-S8, Meguro-ku, Tokyo 152-8552, Japan.
Takahashi
Susumu
S
Vacha
Martin
M