Infrared spectra and intensities of the H2O and N2 complexes in the range of the nu1- and nu3-bands of water.
The IR spectra of complexes of water with nitrogen molecules in the range of the symmetric (nu(1)) and antisymmetric (nu(3)) bands of H(2)O have been studied in helium droplets. The infrared intensities of the nu(3) and nu(1) modes of H(2)O were found to be larger by factors of 1.3 and 2, respectively, in the N(2)-H(2)O complexes. These factors are smaller than those obtained in recent theoretical calculations. The conformation of the N(2)-H(2)O complex was estimated. Spectra and IR intensities of the (N(2))(2)-H(2)O and N(2)-(H(2)O)(2) complexes were also obtained and their structures are discussed.
Kuma
Susumu
S
Department of Chemistry, University of Southern California, Los Angeles, California 90089, USA.
Slipchenko
Mikhail N
MN
Kuyanov
Kirill E
KE
Momose
Takamasa
T
Vilesov
Andrey F
AF