Determination of the hyperpolarizability components of hemicyanine dyes by measuring the anisotropic fluorescence and second harmonic of the dyes uniformly aligned within zeolite channels.
A unidirectional ensemble of hemicyanine molecules was prepared by inserting the molecules into the vertical channels of a uniformly oriented zeolite (silicalite-1) film grown on a glass substrate. Fluorescence from this sample excited with light polarized along the vertical channel was 50 times larger than that excited with light polarized orthogonal to the vertical channel direction. These vertically aligned hemicyanine dyes were used to determine the ratio of the molecular hyperpolarizability components beta(zxx)/beta(zzz) of hemicyanine.
Shim
Tae Kyu
TK
Department of Physics, Sogang University, Seoul 121-742, Korea.
Kim
Doseok
D
Lee
Myoung Hee
MH
Rhee
Bum Ku
BK
Cheong
Hyeonsik M
HM
Kim
Hyun Sung
HS
Yoon
Kyung Byung
KB
D002232:Carbocyanines / Q000737:chemistry*; D005454:Fluorescence Polarization; D005456:Fluorescent Dyes / Q000737:chemistry*; D005898:Glass / Q000737:chemistry; D008956:Models, Chemical; D013050:Spectrometry, Fluorescence / Q000379:methods; D017641:Zeolites / Q000737:chemistry*
D002232:Carbocyanines; D005456:Fluorescent Dyes; D017641:Zeolites