title: The effect of changes in surface wettability on two-phase saturated flow in horizontal replicas of single natural fractures.
abstract: By using translucent epoxy replicas of natural single fractures, it is possible to optically measure aperture distribution and directly observe NAPL flow. However, detailed characterization of epoxy reveals that it is not a sufficiently good analogue to natural rock for many two-phase flow studies. The surface properties of epoxy, which is hydrophobic, are quite unlike those of natural rock, which is generally assumed to be hydrophilic. Different surface wettabilities result in dramatically different two-phase flow behavior and residual distributions. In hydrophobic replicas, the NAPL flows in well-developed channels, displacing water and filling all of the pore space. In hydrophilic replicas, the invading NAPL is confined to the largest aperture pathways and flow frequently occurs in pulses, with no limited or no stable channel development, resulting in isolated blobs with limited accessible surface area. The pulsing and channel abandonment behaviors described are significantly different from the piston-flow frequently assumed in current modeling practice. In addition, NAPL never achieved total saturation in hydrophilic models, indicating that significantly more than a monolayer of water was bound to the model surface. Despite typically only 60-80% NAPL saturation, there was generally good agreement between theoretically calculated Young-Laplace aperture invasion boundaries and the observed minimum apertures invaded. The key to determining whether surface wettability is negligible, or not, lies in accurate characterization of the contaminant-geologic media system under study. As long as the triple-point contact angle of the system is low (<20 degrees), the assumption of perfect water wettability is not a bad one.
authors.affiliation: Earth Sciences and Science Education Department, 271 Science Building, Buffalo State College, 1300 Elmwood Ave., Buffalo, NY 14222, USA. bergslet@buffalostate.edu
authors.forename: Elisa
authors.initials: E
authors.lastname: Bergslien
authors.forename: John
authors.initials: J
authors.lastname: Fountain
mesh_terms: D004853:Epoxy Resins / Q000737:chemistry; D055593:Geological Phenomena; D005844:Geology; D008962:Models, Theoretical; D011137:Polystyrenes / Q000737:chemistry; D013499:Surface Properties; D013501:Surface-Active Agents / Q000737:chemistry; D013816:Thermodynamics; D014867:Water / Q000737:chemistry*; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D017155:Wettability
chemical_list: D004853:Epoxy Resins; D011137:Polystyrenes; D013501:Surface-Active Agents; D014874:Water Pollutants, Chemical; D014867:Water