Formation of leadhillite and calcium lead silicate hydrate (C-Pb-S-H) in the solidification/stabilization of lead contaminants.
In this study, we have investigated the structure of Pb-doped solidified waste forms (SWF) for assessment of lead fixation. A large quantity of lead precipitates produced during the S/S, based upon the results of cement-water solution analysis, X-ray diffraction and electron probe microanalysis/electron dispersive spectroscopy investigations, have been shown to be principally leadhillite (lead carbonate sulfate hydroxide, Pb(4)SO(4)(CO(3))(2)(OH)(2)), lead carbonate hydroxide hydrate (3PbCO(3).2Pb(OH)(2).H(2)O) and two other unidentified lead salts. In the long curing, the lead species dissolved from the lead precipitates are fixed into the cement matrix, forming a gelling calcium lead silicate hydrate during cement-based solidification. On leaching the lead precipitates such as leadhillite were markedly dissolved/released and some dissolved lead species were adsorbed to silicate-rich surface of leached SWF with the subsequent formation of mainly amorphous gel of calcium lead silicate hydrate.
Lee
Dongjin
D
Department of Environmental Health and Safety, National Institute of Environmental Research, Environmental Research Complex, Kyungseo-dong, Seo-gu, Incheon 404-708, South Korea. dongj7@me.go.kr
D002118:Calcium / Q000737:chemistry; D002254:Carbonates / Q000138:chemical synthesis*; D011232:Chemical Precipitation; D004787:Environmental Pollution / Q000517:prevention & control*; D007854:Lead / Q000737:chemistry*; D012037:Refuse Disposal / Q000379:methods*; D017640:Silicates / Q000138:chemical synthesis*; D013057:Spectrum Analysis; D014961:X-Ray Diffraction
D002254:Carbonates; D017640:Silicates; D007854:Lead; D002118:Calcium