title: Computer simulations of block copolymer tethered nanoparticle self-assembly.
abstract: We perform molecular simulations to study the self-assembly of block copolymer tethered cubic nanoparticles. Minimal models of the tethered nanoscale building blocks (NBBs) are utilized to explore the structures arising from self-assembly. We demonstrate that attaching a rigid nanocube to a diblock copolymer affects the typical equilibrium morphologies exhibited by the pure copolymer. Lamellar and cylindrical phases are observed in both systems but not at the corresponding relative copolymer tether block fractions. The effect of nanoparticle geometry on phase behavior is investigated by comparing the self-assembled structures formed by the tethered NBBs with those of their linear ABC triblock copolymer counterparts. The tethered nanocubes exhibit the conventional triblock copolymer lamellar and cylindrical phases when the repulsive interactions between different blocks are symmetric. The rigid and bulky nature of the cube induces interfacial curvature in the tethered NBB phases compared to their linear ABC triblock copolymer counterparts. We compare our results with those structures obtained from ABC diblock copolymer tethered nanospheres to further elucidate the role of cubic nanoparticle geometry on self-assembly.
authors.affiliation: Department of Chemical Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136, USA.
authors.forename: Elaine R
authors.initials: ER
authors.lastname: Chan
authors.forename: Lin C
authors.initials: LC
authors.lastname: Ho
authors.forename: Sharon C
authors.initials: SC
authors.lastname: Glotzer