title: Liquefaction of corn stover and preparation of polyester from the liquefied polyol.
abstract: This research investigated a novel process to prepare polyester from corn stover through liquefaction and crosslinking processes. First, corn stover was liquefied in organic solvents (90 wt% ethylene glycol and 10 wt% ethylene carbonate) with catalysts at moderate temperature under atmospheric pressure. The effect of liquefaction temperature, biomass content, and type of catalyst, such as H2SO4, HCl, H3PO4, and ZnCl2, was evaluated. Higher liquefaction yield was achieved in 2 wt% sulfuric acid, 1/4 (w/w) stover to liquefying reagent ratio; 160 degrees C temperature, in 2 h. The liquefied corn stover was rich in polyols, which can be directly used as feedstock for making polymers without further separation or purification. Second, polyester was made from the liquefied corn stover by crosslinking with multifunctional carboxylic acids and/or cyclic acid anhydrides. The tensile strength of polyester is about 5 MPa and the elongation is around 35%. The polyester is stable in cold water and organic solvents and readily biodegradable as indicated by 82% weight loss when buried in damp soil for 10 mo. The results indicate that this novel polyester could be used for the biodegradable garden mulch film production.
authors.affiliation: Center for Biorefining and Biosystems and Agricultural Engineering, University of Minnesota, 1390 Eckles Avenue, St. Paul, MN 55108, USA.
authors.forename: Fei
authors.initials: F
authors.lastname: Yu
authors.forename: Yuhuan
authors.initials: Y
authors.lastname: Liu
authors.forename: Xuejun
authors.initials: X
authors.lastname: Pan
authors.forename: Xiangyang
authors.initials: X
authors.lastname: Lin
authors.forename: Chengmei
authors.initials: C
authors.lastname: Liu
authors.forename: Paul
authors.initials: P
authors.lastname: Chen
authors.forename: Roger
authors.initials: R
authors.lastname: Ruan
mesh_terms: D045424:Complex Mixtures / Q000737:chemistry; D003246:Conservation of Energy Resources; D004148:Dioxolanes / Q000737:chemistry*; D019855:Ethylene Glycol / Q000737:chemistry*; D007220:Industrial Waste / Q000517:prevention & control; D007700:Kinetics; D035261:Plant Components, Aerial / Q000737:chemistry*; D011091:Polyesters / Q000138:chemical synthesis*; D011108:Polymers / Q000737:chemistry*; D012212:Rheology / Q000379:methods; D012995:Solubility; D012996:Solutions / Q000737:chemistry; D013464:Sulfuric Acids / Q000737:chemistry*; D013696:Temperature; D003313:Zea mays / Q000737:chemistry*
chemical_list: D045424:Complex Mixtures; D004148:Dioxolanes; D007220:Industrial Waste; D011091:Polyesters; D011108:Polymers; D012996:Solutions; D013464:Sulfuric Acids; C024617:polyol; D019855:Ethylene Glycol; C033158:sulfuric acid; C031133:ethylene carbonate