Solid-state kinetic models: basics and mathematical fundamentals.
Many solid-state kinetic models have been developed in the past century. Some models were based on mechanistic grounds while others lacked theoretical justification and some were theoretically incorrect. Models currently used in solid-state kinetic studies are classified according to their mechanistic basis as nucleation, geometrical contraction, diffusion, and reaction order. This work summarizes commonly employed models and presents their mathematical development.
Khawam
Ammar
A
Division of Pharmaceutics, College of Pharmacy, University of Iowa, Iowa City, Iowa 52242, USA.
Flanagan
Douglas R
DR
D002627:Chemistry, Physical / Q000379:methods*; D004058:Diffusion; D007700:Kinetics; D008956:Models, Chemical; D008962:Models, Theoretical; D013696:Temperature