title: Synthesis and stereochemical confirmation of the secoiridoid glucosides nudiflosides D and A.
abstract: We describe herein an efficient access to the highly substituted cyclopentane unit present in the Nudifloside secoiridoid family via crotyl phosphonamide anion mediated conjugate addition to cyclopentenone.
authors.affiliation: Department of Chemistry, Université de Montréal, C.P. 6128, Succursale Centre-ville, Montréal, Québec H3C 3J7 Canada. stephen.hanessian@umontreal.ca
authors.forename: Stephen
authors.initials: S
authors.lastname: Hanessian
authors.forename: Emily
authors.initials: E
authors.lastname: Mainetti
authors.forename: Fabien
authors.initials: F
authors.lastname: Lecomte
mesh_terms: D039823:Iridoids / Q000138:chemical synthesis*; D015394:Molecular Structure
chemical_list: D039823:Iridoids; C520909:nudifloside A; C520908:nudifloside D