title: Comparison of four fluoride etchants in bonding between titanium and a self-curing luting agent.
abstract: The purpose of the present study was to investigate the efficacy of four different fluoride etchants in titanium bonding. The etchants were aqueous solutions of 5 wt% sodium fluoride (NaF), ammonium fluoride (NH4F), sodium hydrogen fluoride (NaFHF), and ammonium hydrogen fluoride (NH4FHF). Cast specimens of commercially pure titanium were air-abraded with alumina, etched for 30 seconds, and then primed with a phosphate primer. An acrylic rod was bonded to the specimen with a tri-n-butylborane-initiated self-curing luting agent. Shear bond strengths were determined before and after 10,000 thermocycles. Regarding pre-thermocycling bond strength, there were no significant differences among the etchants. After thermocycling, there was a decrease in bond strength for all groups. Nonetheless, the bond strengths of NaFHF and NH4FHF were significantly higher than those of NaF, NH4F, and non-etched control. In terms of bonding durability between resin and titanium, it was significantly improved when the titanium surface was microscopically roughened with alumina blasting and etching using NaFHF or NH4FHF.
authors.affiliation: Division of Fixed Prosthodontics and Oral Rehabilitation, Nagasaki University Graduate School of Biomedical Sciences, 1-7-1 Sakamoto, Nagasaki 852-8588, Japan. yohsuke@net.nagasaki-u.ac.jp
authors.forename: Yohsuke
authors.initials: Y
authors.lastname: Taira
authors.forename: Lei
authors.initials: L
authors.lastname: Yang
authors.forename: Mitsuru
authors.initials: M
authors.lastname: Atsuta
mesh_terms: D064751:Ammonium Compounds; D001840:Dental Bonding; D045662:Dental Etching / Q000379:methods*; D003799:Dental Stress Analysis; D005459:Fluorides / Q000737:chemistry*; D006858:Hydrofluoric Acid; D000644:Quaternary Ammonium Compounds; D019279:Resin Cements; D033081:Shear Strength; D012969:Sodium Fluoride; D013499:Surface Properties; D014025:Titanium
chemical_list: D064751:Ammonium Compounds; D000644:Quaternary Ammonium Compounds; D019279:Resin Cements; C024822:ammonium fluoride; D012969:Sodium Fluoride; D014025:Titanium; D005459:Fluorides; D006858:Hydrofluoric Acid