Phosphazene base-promoted halogen-zinc exchange reaction of aryl iodides using diethylzinc.
The use of catalytic t-Bu-P4 base dramatically improved the performance of halogen-zinc exchange of aryl iodides, and the arylzinc derivatives were functionalized under copper-free reaction conditions.
Ueno
Masahiro
M
Graduate School of Pharmaceutical Sciences, Tohoku University, Aoba-ku, Sendai 980-8578, Japan.
Wheatley
Andrew E H
AE
Kondo
Yoshinori
Y
D001388:Aziridines / Q000737:chemistry*; D002384:Catalysis; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D007455:Iodine / Q000737:chemistry*; D008956:Models, Chemical; D009942:Organometallic Compounds / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
D001388:Aziridines; D006847:Hydrocarbons, Iodinated; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; C008880:phosphazine; D007455:Iodine; D015032:Zinc; C454811:diethylzinc