title: New insight into reactions of Ni(S2C2(CF3)2)2 with simple alkenes: alkene adduct versus dihydrodithiin product selectivity is controlled by [Ni(S2C2(CF3)2)2]- anion.
abstract: The nickel bis(dithiolene) complex Ni(S2C2(CF3)2)2 employs its sulfur centers in reactions with alkenes, and stable interligand S-bonded alkene adducts can be formed. The present study shows that the selectivity of alkene binding to charge-neutral Ni(S2C2(CF3)2)2 is influenced by the anion [Ni(S2C2(CF3)2)2]-. In the absence of anion, formation of substituted dihydrodithiins (intraligand addition) dominates, whereas the presence of anion allows for the formation of stable interligand adducts. Mechanistic implications are discussed. The X-ray crystal structure of the ethylene adduct of Ni(S2C2(CF3)2)2 is presented, displaying interligand binding of ethylene to sulfur centers in the bis(dithiolene) complex.
authors.affiliation: Department of Chemical and Physical Sciences, UTM, University of Toronto, 3359 Mississauga Road N, Mississauga, Ontario, Canada.
authors.forename: Daniel J
authors.initials: DJ
authors.lastname: Harrison
authors.forename: Neilson
authors.initials: N
authors.lastname: Nguyen
authors.forename: Alan J
authors.initials: AJ
authors.lastname: Lough
authors.forename: Ulrich
authors.initials: U
authors.lastname: Fekl