Effect of surfactants at low concentrations on the sorption of atrazine by natural sediment.
A series of experiments were carried out to determine the effect of surfactants at low concentrations on the sorption of atrazine by natural sediments. With surfactant concentrations ranging from 0 to 20 mg/ L, anionic and cationic surfactants appreciably reduce the adsorption of atrazine, while nonionic surfactant decreases the adsorption of atrazine at concentrations equal to or less than 1 mg/L and increases adsorption at higher concentrations. Desorption of atrazine in the presence of different sodium dodecylbenzene sulfonate (SDBS) concentrations shows that a portion of the bound pesticide resists desorption in the SDBS free system. However, the addition of SDBS accelerates the desorption of atrazine. Furthermore, the nature of sediment and the contacting sequence of SDBS, at 10 mg/L, with the sediment, also influence the adsorption of atrazine. The conclusions in this study could be explained partially by the effect of the type and concentration of surfactants and the characteristics of sediments.
Tao
Qing H
QH
State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Science, Chinese Academy of Sciences, Beijing. taoqh2008@yahoo.com.cn
Wang
Dong S
DS
Tang
Hong X
HX
D000327:Adsorption; D001280:Atrazine / Q000378:metabolism*; D001557:Benzenesulfonates / Q000378:metabolism*; D002851:Chromatography, High Pressure Liquid; D019015:Geologic Sediments / Q000032:analysis; D013501:Surface-Active Agents / Q000494:pharmacology*; D014961:X-Ray Diffraction
D001557:Benzenesulfonates; D013501:Surface-Active Agents; C001114:dodecylbenzenesulfonic acid; D001280:Atrazine