title: Stability of pesticides on solid-phase extraction disks after incubation at various temperatures and for various time intervals: interlaboratory study.
abstract: An interlaboratory study was conducted at 8 locations to assess the stability of pesticides on solid-phase extraction (SPE) disks after incubation at various temperatures and for various time intervals. Deionized water fortified with selected pesticides was extracted by using 2 types of SPE filtration disks (Empore C18 and Speedisk C18XF), and after extraction, the disks were incubated at 3 temperatures (25, 40, and 55 degrees C) and for 2 time intervals (4 and 14 days). Deionized water was fortified with atrazine, carbofuran, and chlorpyrifos by all participating laboratories. In addition, some of the laboratories included 2 of the following pesticides: metolachlor, metribuzin, simazine, chlorothalonil, and malathion. Concurrently, fortified water samples were extracted with the incubated samples by using each disk type at 4 and 14 days. Pesticides had equivalent or greater stability on > or = 1 of the C18 disk types, compared with storage in water. The lowest recoveries of carbofuran (6%) and chlorpyrifos (7%) were obtained at 55 degrees C after storage for 14 days in incubated water. At 55 degrees C after 14 days, the lowest recovery for atrazine was 65% obtained by using Empore disks. Pesticide-specific losses occurred on the C18 disks in this study, underlining the importance of temperature and time interval when water is extracted at remote field locations and the SPE disks containing the extracted pesticides are transported or shipped to a laboratory for elution and analysis.
authors.affiliation: Virginia Polytechnic Institute, Department of Biochemistry, Pesticide Residue Laboratory, 352 Litton-Reaves Hall, Blacksburg, VA 24061, USA. jmcc@vt.edu
authors.forename: Jean M
authors.initials: JM
authors.lastname: Cobb
authors.forename: John D
authors.initials: JD
authors.lastname: Mattice
authors.forename: Scott A
authors.initials: SA
authors.lastname: Senseman
authors.forename: Jose A
authors.initials: JA
authors.lastname: Dumas
authors.forename: Wondi
authors.initials: W
authors.lastname: Mersie
authors.forename: Melissa B
authors.initials: MB
authors.lastname: Riley
authors.forename: Thomas L
authors.initials: TL
authors.lastname: Potter
authors.forename: Thomas C
authors.initials: TC
authors.lastname: Mueller
authors.forename: Elizabeth B
authors.initials: EB
authors.lastname: Watson
mesh_terms: D002138:Calibration; D002235:Carbofuran / Q000737:chemistry; D002244:Carbon / Q000737:chemistry; D002623:Chemistry Techniques, Analytical / Q000379:methods* / Q000592:standards; D004390:Chlorpyrifos / Q000737:chemistry; D007700:Kinetics; D010573:Pesticide Residues / Q000737:chemistry; D010575:Pesticides / Q000032:analysis / Q000737:chemistry*; D015203:Reproducibility of Results; D013696:Temperature; D013997:Time Factors; D014867:Water / Q000737:chemistry
chemical_list: D010573:Pesticide Residues; D010575:Pesticides; D014867:Water; D002244:Carbon; D004390:Chlorpyrifos; D002235:Carbofuran