Water-dissolvable sodium sulfate nanowires as a versatile template for the fabrication of polyelectrolyte- and metal-based nanotubes.
This study presents the synthesis of water-dissolvable sodium sulfate nanowires, where Na(2)SO(4) nanowires were produced by an easy reflux process in an organic solvent, N,N-dimethylformamide (DMF) and formed from the coexistence of AgNO(3), SnCl(2), dodecylsodium sulfate (SDS), and cetyltrimethylammonium bromide (CTAB). Na(2)SO(4) nanowires were derived from SDS, and the morphology control of the Na(2)SO(4) nanowires was established by the cooperative effects of Sn and NO(3)(-), while CTAB served as the template and led to homogeneous nanowires with a smooth surface. Since the as-synthesized sodium sulfate nanowires are readily dissolved in water, these nanowires can be treated as soft templates for the fabrication of nanotubes by removing the Na(2)SO(4) core. This process is therefore significantly better than other reported methodologies to remove the templates under harsh condition. We have demonstrated the preparation of biocompatible polyelectrolyte (PE) nanotubes using a layer-by-layer (LbL) method on the Na(2)SO(4) nanowires and the formation of Au nanotubes by the self-assembly of Au nanoparticles. In both nanotube synthesis processes, PEI (polyethylenimine), PAA (poly(acrylic acid)), and Au nanoparticles served as the building blocks on the Na(2)SO(4) templates, which were then rinsed with water to remove the core templates. This unique water-dissolvable template is anticipated to bring about versatile and flexible downstream applications.
Pu
Ying-Chih
YC
Department of Chemistry and Center for Micro/Nano Technology Research, National Cheng Kung University, Tainan 701, Taiwan.
Hwu
Jih Ru
JR
Su
Wu-Chou
WC
Shieh
Dar-Bin
DB
Tzeng
Yonhua
Y
Yeh
Chen-Sheng
CS
D020099:Coated Materials, Biocompatible / Q000138:chemical synthesis* / Q000737:chemistry; D004247:DNA / Q000737:chemistry; D004573:Electrolytes / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D043942:Nanotubes / Q000737:chemistry*; D053770:Nanowires / Q000737:chemistry*; D012835:Silver Nitrate / Q000737:chemistry; D012995:Solubility; D012997:Solvents / Q000737:chemistry; D013431:Sulfates / Q000737:chemistry*; D013499:Surface Properties; D017971:Tin Compounds / Q000737:chemistry; D014867:Water / Q000737:chemistry
D020099:Coated Materials, Biocompatible; D004573:Electrolytes; D008670:Metals; D012997:Solvents; D013431:Sulfates; D017971:Tin Compounds; D014867:Water; C012036:sodium sulfate; C023599:stannous chloride; D004247:DNA; D012835:Silver Nitrate