First example of a di-cadmium tris-phthalocyanine triple-decker sandwich complex.
An unprecedented M(II)2Pc3 (M = Cd) triple-decker sandwich complex has been synthesized and characterised by single crystal X-ray crystallography; cyclic voltammetry shows an unusually large range of redox states and EPR spectroscopy indicates that the material exists in at least two redox states, one having spin (1/2).
Chambrier
Isabelle
I
Wolfson Materials and Catalysis Centre, School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK.
Hughes
David L
DL
Swarts
Jannie C
JC
Isare
Benjamin
B
Cook
Michael J
MJ