Cycloaddition reaction of zirconacyclopentadienes to quinones: synthesis of higher para-quinones.
Efficient synthetic approaches to higher para-dihydroquinones and -quinones have been developed through zirconium/CuCl-mediated cycloaddition reactions of two alkynes and quinone in a one-pot procedure.
Chen
Chao
C
Key Lab of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China.
Xi
Chanjuan
C
Ai
Zhezhe
Z
Hong
Xiaoyin
X
D000466:Alkadienes / Q000737:chemistry*; D015394:Molecular Structure; D011809:Quinones / Q000737:chemistry*
D000466:Alkadienes; D011809:Quinones