title: Stereoselective oxy-functionalization of gamma-silyl allylic alcohols with ozone: a facile synthesis of silyl peroxide and its reactions.
abstract: A reaction of gamma-silyl allylic alcohol and its ether with ozone provides synthetically versatile alpha-formyl silyl peroxide in good yield without normal fission of carbon-carbon double bond. Thus, the provided silyl peroxide serves as a good precursor for the stereochemically defined triol derivative via alkylation and reduction of peroxide moiety.
authors.affiliation: Department of Applied Chemistry, Graduate School of Science and Engineering, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8552, Japan.
authors.forename: Masanori
authors.initials: M
authors.lastname: Murakami
authors.forename: Kyohei
authors.initials: K
authors.lastname: Sakita
authors.forename: Kazunobu
authors.initials: K
authors.lastname: Igawa
authors.forename: Katsuhiko
authors.initials: K
authors.lastname: Tomooka