Optical behaviors of conjugated-chain compounds containing benzene and furan units.
Thirteen conjugated-chain compounds which contain benzene and furan units were prepared, their optical behaviors, including UV-vis absorption coefficient (epsilon), absorption wavelengths (lambdaa), fluorescence emission wavelengths (lambdae), and quantum yields (Phi) were measured. Meanwhile, their LUMO and HOMO energy were determined by cyclic voltammetry and their second-order polarizations (betaxxx) values were determined by solvatochromic method, respectively. The results showed that this kind of compounds possess a shorter lambdaa (320-365 nm) and performance a higher Phi values, especially for 2aa, 2ab, 2ac and 2bb, their Phi values are all more than 90%. These compounds, except 2db, showed a higher betaxxx values in DMSO, especially for 2dc (75.77x10(-30) m5 C-1) and 2dd (83.32x10(-30) m5 C-1), than that 10-methyl-acridone (6.578x10(-30) m5 C-1) or 10-benzylacridone (6.845x10(-30) m5 C-1) in DMSO did, and second harmonic generation value of 10-methylacridone and 10-benzylacridone in powder are, respectively, 1.381 and 1.861 times of that value of urea. The betaxxx values and Phi values determined for these compounds in this work were lower than these values which were desired in the original work, this phenomena was explained from their molecular structures. This work confirmed that as these compounds performance shorter lambdaa and higher Phi values, they could be good blue-color optical materials for some fields, such as OLED materials, two-photo absorption materials, fluorescent dyes.
Pan
Wen-Long
WL
School of Chemistry and Chemical Engineering, Sun yat-Sen University, Guangzhou 510275, PR China.
Song
Ji-Guo
JG
Chen
Yong
Y
Wan
Yi-Qian
YQ
Song
Hua-Can
HC
D001554:Benzene / Q000138:chemical synthesis / Q000737:chemistry*; D005663:Furans / Q000138:chemical synthesis / Q000737:chemistry*; D008956:Models, Chemical; D055095:Optics and Photonics; D011789:Quantum Theory; D012997:Solvents; D013056:Spectrophotometry, Ultraviolet; D055672:Static Electricity
D005663:Furans; D012997:Solvents; D001554:Benzene; C039281:furan