title: Aryl trihydroxyborates: easily isolated discrete species convenient for direct application in coupling reactions.
abstract: A conceptually and practically simple alternative approach to the use of arylboron species as the organometallic component in cross-coupling processes is described whereby trihydroxyborate salts are isolated and directly employed. The protocol derives practical benefit from the ease and convenience of the isolation and subsequent use of the discrete borate salts, eliminates the need for additional base, and aids the use of correct reaction stoichiometry.
authors.affiliation: School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich NR4 7TJ, U.K. a.cammidge@uea.ac.uk
authors.forename: Andrew N
authors.initials: AN
authors.lastname: Cammidge
authors.forename: Victoria H M
authors.initials: VH
authors.lastname: Goddard
authors.forename: Hemant
authors.initials: H
authors.lastname: Gopee
authors.forename: Nicola L
authors.initials: NL
authors.lastname: Harrison
authors.forename: David L
authors.initials: DL
authors.lastname: Hughes
authors.forename: Christopher J
authors.initials: CJ
authors.lastname: Schubert
authors.forename: Benjamin M
authors.initials: BM
authors.lastname: Sutton
authors.forename: Gary L
authors.initials: GL
authors.lastname: Watts
authors.forename: Andrew J
authors.initials: AJ
authors.lastname: Whitehead