Chiral molecule-based ferrimagnets with helical structures.
Two enantiopure one-dimensional complexes with helical structures, [Mn(3)((R,R)-Salcy)(3)(H2O)(2)Fe(CN)(6).2H2O]n (1) and [Mn(3)((S,S)-Salcy)(3)(H2O)(2)Fe(CN)(6).2H2O]n (2) [Salcy = N,N'-(1,2-cyclohexanediylethylene)bis(salicylideneiminato) dianion], have been synthesized and characterized. Magnetic studies show that both complexes are ferrimagnets with the magnetic transition temperature at 3 K.
Wen
He-Rui
HR
Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, People's Republic of China.
Wang
Cai-Feng
CF
Li
Yi-Zhi
YZ
Zuo
Jing-Lin
JL
Song
You
Y
You
Xiao-Zeng
XZ
D018360:Crystallography, X-Ray; D008280:Magnetics; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature
D009942:Organometallic Compounds