Investigations of the EPR g factors and hyperfine structure constants for two trigonal Co2+ centers in Al2O3 crystals.
The EPR g factors gparallel, gperpendicular and the hyperfine structure constants Aparallel, Aperpendicular for two trigonal Co2+ centers (i.e. Co2+(I) center at the substitutional site and Co2+(II) center at the interstitial site) in Al2O3 crystals are calculated from the second-order perturbation formulas based on the cluster approach. In these formulas, the contributions to EPR parameters from both the spin-orbit coupling parameter of central 3dn ion and that of ligand are included. The calculated results are in reasonable agreement with the observed values. Based on the calculations, the defect structures of both Co2+ centers in Al2O3 crystals are obtained and the negative sign of Aparallel for Co2+(I) center is suggested. The results are discussed.
Zheng
Wen-Chen
WC
Department of Material Science, Sichuan University, Chengdu 610064, PR China. zhengwc1@163.com
Wu
Xiao-Xuan
XX
Fang
Wang
W
Mei
Yang
Y
D000537:Aluminum Oxide / Q000737:chemistry*; D003035:Cobalt / Q000737:chemistry*; D003460:Crystallization; D004578:Electron Spin Resonance Spectroscopy; D008956:Models, Chemical
D003035:Cobalt; D000537:Aluminum Oxide