Bis(acesulfamato-kappa2O4,N)bis(3-methylpyridine)copper(II).
In the crystal structure of the title compound {systematic name: bis[6-methyl-1,2,3-oxathiazin-4(3H)-one 2,2-dioxide(1-)-kappa2N3,O4]bis(3-methylpyridine)copper(II)}, [Cu(C4H4NO4S)2(C6H7N)2], the CuII centre resides on a centre of symmetry and has an octahedral geometry that is distorted both by the presence of four-membered chelate rings and because of the Jahn-Teller effect. The equatorial plane is formed by the N atoms of two methylpyridine ligands and by the more basic O atoms of the acesulfamate ligands, while the weakly basic N atoms of these ligands are in elongated axial positions with a misdirected valence. The crystal is stabilized by two intermolecular C-H...O interactions involving the methyl and CH groups, and the sulfonyl O atoms of the acesulfamate group.
Dege
Necmi
N
Department of Physics, Arts and Sciences Faculty, Ondokuz Mayis University, 55139 Samsun, Turkey. dege@omu.edu.tr
Içbudak
Hasan
H
Adiyaman
Elif
E
D002413:Cations, Divalent / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D015394:Molecular Structure; D010847:Picolines / Q000737:chemistry*; D013457:Sulfur Compounds / Q000737:chemistry*
D002413:Cations, Divalent; D010847:Picolines; D013457:Sulfur Compounds; D003300:Copper; C053603:3-methylpyridine