A metal-organic framework with entatic metal centers exhibiting high gas adsorption affinity.
A metal-organic framework, PCN-9, containing entatic metal centers, has been synthesized and crystallographically characterized. The H2 and CH4 adsorption enthalpies of PCN-9 are among the highest reported thus far.
Ma
Shengqian
S
Department of Chemistry & Biochemistry, Miami University, Oxford, Ohio 45056, USA. zhouh@muohie.edu
Zhou
Hong-Cai
HC