Aryl C-glycosylation of phenols with glycosyl trifluoroacetimidates.
Aryl C-glycosylation of a variety of phenols with glycosyl trifluoroacetimidates in the presence of TMSOTf was examined, leading to the corresponding ortho-hydroxyaryl C-glycosides in variable yields.
Li
Yuwen
Y
State Key Laboratory of Bio-organic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, China.
Wei
Guo
G
Yu
Biao
B
D000081:Acetamides; D005463:Fluoroacetates; D006031:Glycosylation; D008698:Mesylates / Q000737:chemistry; D010636:Phenols / Q000737:chemistry*; D014269:Trifluoroacetic Acid / Q000737:chemistry; D014297:Trimethylsilyl Compounds
D000081:Acetamides; D005463:Fluoroacetates; D008698:Mesylates; D010636:Phenols; D014297:Trimethylsilyl Compounds; C053353:trimethylsilyl trifluoromethanesulfonate; C030688:trifluoroacetamide; D014269:Trifluoroacetic Acid