A sulfitylation-oxidation protocol for the preparation of sulfates.
A novel, high-yielding method for sulfation of alcohols has been developed, proceeding via sulfite- and sulfate diester intermediates. Sulfite diesters serve as versatile sulfate monoester precursors, allowing for transformations that are difficult or impossible with the latter compounds.
Huibers
M
M
Institute for Molecules and Materials, Organic Chemistry, Radboud University Nijmegen, Toernooiveld 1, 6525 ED Nijmegen, The Netherlands.
Manuzi
Alvaro
A
Rutjes
Floris P J T
FP
van Delft
Floris L
FL
D000438:Alcohols / Q000737:chemistry*; D004952:Esters / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013447:Sulfites / Q000737:chemistry; D013463:Sulfuric Acid Esters / Q000138:chemical synthesis* / Q000737:chemistry
D000438:Alcohols; D004952:Esters; D013447:Sulfites; D013463:Sulfuric Acid Esters