Desolvation tips the balance: solvent effects on aromatic interactions.
The folding behaviour of the molecular torsion balance framework is rationalised by considering the effects of solvation using the alpha/beta H-bond parameter scheme for estimating the free energies of pairwise functional group interactions in solution.
Cockroft
Scott L
SL
Centre for Chemical Biology, Krebs Institute for Biomolecular Science, Department of Chemistry, University of Sheffield, Sheffield, UKS3 7HF.
Hunter
Christopher A
CA
D006860:Hydrogen Bonding; D008956:Models, Chemical; D012995:Solubility; D012996:Solutions / Q000737:chemistry; D012997:Solvents / Q000737:chemistry*; D013816:Thermodynamics; D014867:Water / Q000737:chemistry
D012996:Solutions; D012997:Solvents; D014867:Water