Early-late heterobimetallic complexes as initiator for ethylene polymerization. Cooperative effect of two metal centers to afford highly branched polyethylene.
Ethylene polymerization initiated by early-late transition-metal complexes afforded a polymer with different branched structures and properties depending on the type of late transition-metal.
Kuwabara
Junpei
J
Chemical Resources Laboratory (R1-03), Tokyo Institute of Technology, 4259 Nagatsuta, Yokohama, 226-8503, Japan.
Takeuchi
Daisuke
D
Osakada
Kohtaro
K