title: A simple solution route to single-crystalline Sb2O3 nanowires with rectangular cross sections.
abstract: We report a simple solution route to large-scale synthesis of uniform, single-crystalline, and well-faceted orthorhombic antimony trioxide (Sb(2)O(3)) nanowires with rectangular cross sections by direct air oxidation of bulk metal antimony (Sb) in a mixed solution made of ethylenediamine (EDA) and deionized water (DIW). The as-synthesized products were analyzed by range of methods, such as XRD, SEM, EDX, TEM, SAED, HRTEM, FTIR, Raman, UV-vis absorption, and photoluminescence (PL) spectra. The as-synthesized Sb(2)O(3) nanowires with rectangular cross sections are usually hundreds of micrometers in length, typically 80-100 nm in width, and 60-80 nm in thickness. The novel room temperature photoluminescence properties of Sb(2)O(3) nanowires with rectangular cross sections displayed a significant UV luminescence with a strong emission band at 374 nm, which was reported for the first time, indicating the as-synthesized products with an optical band gap E(g) = 3.3 eV. It is expected that as-synthesized Sb(2)O(3) nanowires would be a new member of functional materials and used in the manufacture of advanced nanodevices.
authors.affiliation: Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
authors.forename: Zhengtao
authors.initials: Z
authors.lastname: Deng
authors.forename: Fangqiong
authors.initials: F
authors.lastname: Tang
authors.forename: Dong
authors.initials: D
authors.lastname: Chen
authors.forename: Xianwei
authors.initials: X
authors.lastname: Meng
authors.forename: Li
authors.initials: L
authors.lastname: Cao
authors.forename: Bingsuo
authors.initials: B
authors.lastname: Zou
mesh_terms: D000965:Antimony / Q000737:chemistry*; D002627:Chemistry, Physical / Q000379:methods*; D003460:Crystallization; D008027:Light; D053768:Metal Nanoparticles / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D008956:Models, Chemical; D053770:Nanowires / Q000737:chemistry*; D010087:Oxides / Q000737:chemistry*; D010777:Photochemistry / Q000379:methods; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013059:Spectrum Analysis, Raman; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D010087:Oxides; C091696:antimony oxide; D000965:Antimony