title: Application of palladium-catalyzed allylic arylation to the synthesis of a (+/-)-7-deoxypancratistatin analogue.
abstract: Palladium-catalyzed coupling of an aryl siloxane and an allylic carbonate proceeded in good yield to give an adduct that was converted to an analogue of (+/-)-7-deoxypancratistatin.
authors.affiliation: Department of Chemistry and Biochemistry, University of Maryland, College Park, Maryland 20742, USA.
authors.forename: Krupa H
authors.initials: KH
authors.lastname: Shukla
authors.forename: Debra J
authors.initials: DJ
authors.lastname: Boehmler
authors.forename: Suzanne
authors.initials: S
authors.lastname: Bogacyzk
authors.forename: Bridget R
authors.initials: BR
authors.lastname: Duvall
authors.forename: William A
authors.initials: WA
authors.lastname: Peterson
authors.forename: William T
authors.initials: WT
authors.lastname: McElroy
authors.forename: Philip
authors.initials: P
authors.lastname: Deshong
mesh_terms: D047151:Amaryllidaceae Alkaloids / Q000138:chemical synthesis*; D002384:Catalysis; D003500:Cyclization; D007546:Isoquinolines / Q000138:chemical synthesis*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: C418326:7-deoxypancratistatin; D047151:Amaryllidaceae Alkaloids; D007546:Isoquinolines; D010165:Palladium