Selective monoiodination of aromatic compounds with electrochemically generated I+ using micromixing.
Selective monoiodination of aromatic compounds such as dimethoxybenzene has been successfully achieved with I+, which is generated by anodic oxidation of I2 in acetonitrile, using micromixing.
Midorikawa
Koji
K
Technology Laboratory, Nippoh Chemicals Co., Ltd., Chiba, 298-0104, Japan.
Suga
Seiji
S
Yoshida
Jun-ichi
J
D000097:Acetonitriles / Q000737:chemistry; D000840:Anisoles / Q000737:chemistry; D004563:Electrochemistry; D004566:Electrodes; D006841:Hydrocarbons, Aromatic / Q000737:chemistry*; D006847:Hydrocarbons, Iodinated / Q000138:chemical synthesis*; D007455:Iodine / Q000737:chemistry*; D013058:Mass Spectrometry; D044085:Microfluidics; D010084:Oxidation-Reduction
D000097:Acetonitriles; D000840:Anisoles; D006841:Hydrocarbons, Aromatic; D006847:Hydrocarbons, Iodinated; C031200:1,4-dimethoxybenzene; D007455:Iodine; C032159:acetonitrile