On the versatile and unusual coordination behavior of ambiphilic ligands o-R2P(Ph)BR'2.
Monophosphine-boranes were shown to behave as bidentate ambiphilic ligands, whose structural versatility has been illustrated by the preparation of PdII and AuI complexes featuring unusual P --> M-Cl --> B and P --> M --> B interactions, respectively.
Bontemps
Sébastien
S
Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, Université Paul Sabatier, 118, route de Narbonne, F-31062 Toulouse Cedex 09, France.
Bouhadir
Ghenwa
G
Miqueu
Karinne
K
Bourissou
Didier
D