Preparation of allyl sulfoxides by palladium-catalyzed allylic alkylation of sulfenate anions.
Palladium-catalyzed allylic alkylation of sulfenate anions, generated from beta-sulfinylesters by retro-Michael reaction, can take place under biphasic conditions. This new reaction provides a simple, mild, and efficient route to allyl sulfoxides in good yields.
Maitro
Guillaume
G
Laboratoire de Chimie organique (UMR CNRS 7611), Institut de Chimie Moléculaire (FR 2769), Université Pierre et Marie Curie-Paris 6, Case 183, 4 Place Jussieu, F-75252, Paris Cedex 05, France.
Prestat
Guillaume
G
Madec
David
D
Poli
Giovanni
G