title: Antiferromagnetic interaction achieved by a 3-D supramolecular CuII complex with pyrazino-fused TTF as the ligand, [CuCl2(BP-TTF)].
abstract: The diffusion reaction of TBA2Cu(II)Cl4 (TBA = tetrabutylammonium) and a N-containing organic donor, BP-TTF [=bis(pyrazino)tetrathiafulvalene], yielded a 3-D supramolecular Cu complex, [CuCl2(BP-TTF)] (1). The magnetic measurement of 1 exhibits an antiferromagnetic interaction by fitting a Bonner-Fisher model from 2 to 300 K with S = 1/2 and J = -3.5 K between Cu(IotaIota) mediated by self-assembling donor columns.
authors.affiliation: The Institute for Solid State Physics, The University of Tokyo, Kashiwa, Chiba 277-8581, Japan. ichikawa@issp.u-tokyo.ac.jp
authors.forename: Shun
authors.initials: S
authors.lastname: Ichikawa
authors.forename: Shinya
authors.initials: S
authors.lastname: Kimura
authors.forename: Hatsumi
authors.initials: H
authors.lastname: Mori
authors.forename: Gosuke
authors.initials: G
authors.lastname: Yoshida
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Tajima