title: On the versatile and unusual coordination behavior of ambiphilic ligands o-R2P(Ph)BR'2.
abstract: Monophosphine-boranes were shown to behave as bidentate ambiphilic ligands, whose structural versatility has been illustrated by the preparation of PdII and AuI complexes featuring unusual P --> M-Cl --> B and P --> M --> B interactions, respectively.
authors.affiliation: Laboratoire Hétérochimie Fondamentale et Appliquée, UMR CNRS 5069, Université Paul Sabatier, 118, route de Narbonne, F-31062 Toulouse Cedex 09, France.
authors.forename: Sébastien
authors.initials: S
authors.lastname: Bontemps
authors.forename: Ghenwa
authors.initials: G
authors.lastname: Bouhadir
authors.forename: Karinne
authors.initials: K
authors.lastname: Miqueu
authors.forename: Didier
authors.initials: D
authors.lastname: Bourissou