Matrix isolation infrared spectroscopic and theoretical study of NgMO (Ng = Ar, Kr, Xe; M = Cr, Mn, Fe, Co, Ni) complexes.
The matrix isolation infrared spectroscopic and quantum chemical calculation results indicate that late transition metal monoxides CrO through NiO coordinate one noble gas atom in forming the NgMO complexes (Ng = Ar, Kr, Xe; M = Cr, Mn, Fe, Co, Ni) in solid noble gas matrixes. Hence, the late transition metal monoxides previously characterized in solid noble gas matrixes should be regarded as the NgMO complexes, which were predicted to be linear. The M-Ng bond distances decrease, while the M-Ng binding energies increase from NgCrO to NgNiO. In contrast, the early transition metal monoxides, ScO, TiO, and VO, are not able to form similar noble gas atom complexes.
Zhao
Yanying
Y
Department of Chemistry & Laser Chemistry Institute, Shanghai Key Laboratory of Molecular Catalysts and Innovative Materials, Fudan University, Shanghai 200433, People's Republic of China.
Gong
Yu
Y
Zhou
Mingfei
M