title: Trimesitylmethylphosphonium cation. Supramolecular stereocontrol and simple enantiomerization mechanism determination.
abstract: Stereocontrol over the propeller isomerism of trimesitylmethylphosphonium cation was achieved through an ion pairing with chiral hexacoordinated phosphate anions; the asymmetric ion pairing allowed also a most simple experimental proof of the nature of the enantiomerization pathway in solution (two-ring flip).
authors.affiliation: Département de Chimie Organique, Université de Genève, quai Ernest-Ansermet 30, 1211 Genève 4, Switzerland.
authors.forename: Benoît
authors.initials: B
authors.lastname: Laleu
authors.forename: Gérald
authors.initials: G
authors.lastname: Bernardinelli
authors.forename: Remi
authors.initials: R
authors.lastname: Chauvin
authors.forename: Jérôme
authors.initials: J
authors.lastname: Lacour