Multiexponential decay autocorrelation function in dynamic light scattering in near-critical ternary liquid mixture.
The dynamic structure factor of a ternary liquid mixture is calculated from the theory of thermodynamic fluctuations with the help of linearized hydrodynamic equations. The theoretical model allows evaluating and classifying the transport properties near a critical solution point of a ternary mixture. In the vicinity of the critical solution point, experimental dynamic light scattering measurements reveal two hydrodynamic relaxation modes with well-separated characteristic relaxation times. From the autocorrelation functions, we can determine two effective diffusivities D(1) and D(2). As theoretically predicted by a model developed in this work, one of these two modes can be associated with thermal diffusion and the other with mass diffusion. In the special case of an incompressible liquid mixture limit, D(1) and D(2) are decoupled, becoming thermodiffusion coefficient D(T) and mutual mass diffusion coefficient D(ij). A possible physical meaning of D(1) and D(2) for a ternary mixture is discussed.
Ivanov
D A
DA
Institut für Physikalische Chemie, Universität Halle-Wittenberg, Mühlpforte 1, D-06108 Halle (Saale), Germany.
Winkelmann
J
J