Cis-bis[(3-aminopropyl)dimethylphosphine-kappa2N,P]palladium(II) dichloride methanol solvate.
In the title compound, cis-[Pd(C5H14NP)2]Cl2.CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 A, indicating no obvious interaction.
Suzuki
Takayoshi
T
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka 560-0043, Japan. suzuki@chem.sci.osaka-u.ac.jp
Hasegawa
Atsushi
A
Yamaguchi
Hiroshi
H
Kashiwabara
Kazuo
K
Takagi
Hideo D
HD