title: Cis-bis[(3-aminopropyl)dimethylphosphine-kappa2N,P]palladium(II) dichloride methanol solvate.
abstract: In the title compound, cis-[Pd(C5H14NP)2]Cl2.CH4O, the coordination geometry around the PdII center is distorted square planar, with a cis-P2N2 configuration of the two chelating (3-aminopropyl)dimethylphosphine (pdmp) ligands. The six-membered pdmp chelate rings adopt chair conformations, and pairing of the chairs designates the complex cation as a (Cs)-chair2 conformer. The distances between the PdII center and the Cl- anions are greater than 4.5 A, indicating no obvious interaction.
authors.affiliation: Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka 560-0043, Japan. suzuki@chem.sci.osaka-u.ac.jp
authors.forename: Takayoshi
authors.initials: T
authors.lastname: Suzuki
authors.forename: Atsushi
authors.initials: A
authors.lastname: Hasegawa
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Yamaguchi
authors.forename: Kazuo
authors.initials: K
authors.lastname: Kashiwabara
authors.forename: Hideo D
authors.initials: HD
authors.lastname: Takagi