title: Design and solvothermal synthesis of luminescent copper(I)-pyrazolate coordination oligomer and polymer frameworks.
abstract: Two luminescent coordination compounds, [Cu(Pz)]3 (1) and [Cu2(Bpz)]n (2), were isolated from solvothermal reactions of Cu(NO3)2 with 3,5-dimethylpyrazole (HPz) and 3,3',5,5'-tetra-methyl-4,4'-bipyrazole (H2Bpz) respectively in the presence of NH3, of which 1 was revealed to be a planar trimer and 2 a three-dimensional framework, presenting a rare 3-connected binodal (6(2).10)(6.10(2)) topology and eight-fold interpenetration.
authors.affiliation: Department of Chemistry, Shantou University, Guangdong 515063, PR China.
authors.forename: Jun
authors.initials: J
authors.lastname: He
authors.forename: Ye-Gao
authors.initials: YG
authors.lastname: Yin
authors.forename: Tao
authors.initials: T
authors.lastname: Wu
authors.forename: Dan
authors.initials: D
authors.lastname: Li
authors.forename: Xiao-Chun
authors.initials: XC
authors.lastname: Huang