Generation of allylic indium by hydroindation of 1,3-dienes and one-pot reaction with carbonyl compounds.
A hydroindation of 1,3-dienes by dichloroindium hydride (HInCl2) generates allylic indiums that react with carbonyl or imine moieties in a one-pot treatment. The former reaction proceeds in a radical manner, and the latter is ionic allylation. Moreover, both reactions require no additives such as radical initiators, Lewis acids, or transition metal catalysts.
Hayashi
Naoki
N
Research Center for Environmental Preservation, Osaka University, 2-4 Yamadaoka, Suita, Osaka 565-0871, Japan.
Honda
Hiroyuki
H
Yasuda
Makoto
M
Shibata
Ikuya
I
Baba
Akio
A