Copper-mediated cleavage of disulfides by tertiary phosphines: a new route to As-S anions.
The synthesis of [(PhAs)2(micro-S2)(micro-S)] and its reactions to form novel Cu(I) complexes are reported, together with a new cleavage reaction of disulfides by Cu(I) thiolates and tertiary phosphines.
Langer
Robert
R
Institut für Anorganische Chemie der Universität Karlsruhe, Geb. 30.45, Engesserstr. 15a, 76131, Karlsruhe, Germany.
Shi
Weifeng
W
Rothenberger
Alexander
A