title: First mixed hydrazide/hydroxylamide metal aggregates.
abstract: The first organometallic clusters of mixed hydrazide/hydroxylamide clusters of zinc, [Zn(MeZn)(4)(HNNMe(2))(2)(ONEt(2))(4)] and {Zn(EtZn)(4)[HNN(CH(2))(5)](2)(ONEt(2))(4)} were synthesized in one-pot synthesis protocols from dialkylzinc solutions, substituted hydrazines and N,N-diethylhydroxylamine; competing for the Zn atoms, the different binding properties of hydrazide and hydroxylamide ligands in these heteroleptic clusters are discussed.
authors.affiliation: Institut für Anorganische und Analytische Chemie and NRW Graduate School of Chemistry, Westfälische Wilhelms-Universität Münster, Corrensstrasse 30, D-48149, Münster, Germany.
authors.forename: Surajit
authors.initials: S
authors.lastname: Jana
authors.forename: Raphael J F
authors.initials: RJ
authors.lastname: Berger
authors.forename: Roland
authors.initials: R
authors.lastname: Fröhlich
authors.forename: Norbert W
authors.initials: NW
authors.lastname: Mitzel