Asymmetric organocatalysis with glycosyl-beta-amino acids: direct asymmetric aldol reaction of acetone with aldehydes.
Direct asymmetric aldol reaction of acetone with aromatic aldehydes was achieved in good yields and high enantioselectivity using 5-amino-5-deoxy-beta-L-ido-(alpha-D-gluco)-heptofuranuronic acids as a new class of organocatalysts.
Dwivedi
Namrata
N
Medicinal and Process Chemistry Division, Central Drug Research Institute, Lucknow 226 001, India.
Bisht
Surendra S
SS
Tripathi
Rama P
RP
D000096:Acetone / Q000737:chemistry*; D000447:Aldehydes / Q000737:chemistry*; D000606:Amino Sugars / Q000737:chemistry*; D002384:Catalysis; D013237:Stereoisomerism; D014574:Uronic Acids / Q000737:chemistry*
D000447:Aldehydes; D000606:Amino Sugars; D014574:Uronic Acids; D000096:Acetone