title: Structural phase transition and hydrogen ordering of TlH2PO4 at low temperature.
abstract: The crystal structure of TlH(2)PO(4) (TDP) has been studied at low temperature. The lattice parameters were derived from high-resolution X-ray powder diffraction in the temperature range between 8 and 300 K. A detailed crystal structure analysis of the antiferroelectric low-temperature phase TDP-III has been performed based on neutron diffraction data measured at 210 K on a twinned crystal consisting of two domain states. The structure model in the triclinic space group P\bar 1 is characterized by a complete ordering of all the H atoms in the asymmetric O-H...O hydrogen bonds. The phase transition from the ferroelastic TDP-II to the antiferroelectric TDP-III phase at 229.5 +/- 0.5 K is only slightly of first order and shows no detectable hysteresis effects. Its mechanism is driven by the hydrogen ordering between the partially ordered TDP-II state and the completely ordered TDP-III state. The polymorphism of TDP and the fully deuterated TlD(2)PO(4) (DTDP) is presented in the form of group-subgroup relations between the different space groups.
authors.affiliation: HANARO Utilization Technology Development Division, HANARO Application Center, Korea Atomic Energy Research Institute, 150 Deokjin-dong, Yusung, Daejon, Korea 305-353.
authors.forename: I H
authors.initials: IH
authors.lastname: Oh
authors.forename: M
authors.initials: M
authors.lastname: Merz
authors.forename: S
authors.initials: S
authors.lastname: Mattauch
authors.forename: G
authors.initials: G
authors.lastname: Heger