Organocatalysis "on water". Regioselective [3 + 2]-cycloaddition of nitrones and allenolates.
The first example of a regioselective and organocatalyzed 1,3-dipolar cycloaddition reaction between conjugated alkynoates and nitrones "on water" is described.
González-Cruz
David
D
Instituto de Productos Naturales y Agrobiologia, CSIC, Astrofísico Francisco Sánchez 3, 38206 La Laguna, Tenerife, Islas Canarias, Spain.
Tejedor
David
D
de Armas
Pedro
P
Morales
Ezequiel Q
EQ
García-Tellado
Fernando
F
D000588:Amines / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D009281:Naphthalenes / Q000737:chemistry*; D009589:Nitrogen Oxides / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry; D013237:Stereoisomerism; D014867:Water / Q000737:chemistry*
D000588:Amines; D009281:Naphthalenes; D009589:Nitrogen Oxides; D010720:Phosphines; C015388:nitrones; D014867:Water; C044646:phosphine; C110055:allenolic acid