title: Generation of allylic indium by hydroindation of 1,3-dienes and one-pot reaction with carbonyl compounds.
abstract: A hydroindation of 1,3-dienes by dichloroindium hydride (HInCl2) generates allylic indiums that react with carbonyl or imine moieties in a one-pot treatment. The former reaction proceeds in a radical manner, and the latter is ionic allylation. Moreover, both reactions require no additives such as radical initiators, Lewis acids, or transition metal catalysts.
authors.affiliation: Research Center for Environmental Preservation, Osaka University, 2-4 Yamadaoka, Suita, Osaka 565-0871, Japan.
authors.forename: Naoki
authors.initials: N
authors.lastname: Hayashi
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Honda
authors.forename: Makoto
authors.initials: M
authors.lastname: Yasuda
authors.forename: Ikuya
authors.initials: I
authors.lastname: Shibata
authors.forename: Akio
authors.initials: A
authors.lastname: Baba