Poly[[[mu-5,10,15,20-tetrakis(4-methoxycarbonylphenyl)porphyrinato(2-)]zinc(II)] N,N'-dimethylacetamide disolvate].
The crystal structure of the title compound, {[Zn(C52H36N4O8)].2C4H9NO}n, consists of two-dimensional coordination polymers of the six-coordinate zinc-porphyrin unit [Zn-N = 2.039 (2) and 2.061 (2) A, and Zn-O = 2.540 (2) A], which intercalate between the molecules of N,N-dimethylacetamide solvent. The Zn atom lies on an inversion centre.
Muniappan
Sankar
S
School of Chemistry, Sackler Faculty of Exact Sciences, Tel-Aviv University, Ramat-Aviv, 69978 Tel-Aviv, Israel.
Lipstman
Sophia
S
Goldberg
Israel
I
D018360:Crystallography, X-Ray; D008665:Metalloporphyrins / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
C519930:(mu-5,10,15,20-tetrakis-(4-methoxycarbonylphenyl)porphyrinato(2-))zinc(II); D008665:Metalloporphyrins