Chiral boron enolate aldol additions to chiral aldehydes.
We have examined the double-diastereodifferentiating aldol addition reactions of chiral enolborinate 1a with chiral aldehydes leading to the corresponding aldol adducts with excellent levels of 1,5-anti diastereoselection.
Dias
Luiz C
LC
Instituto de Química, Universidade Estadual de Campinas, UNICAMP, C.P. 6154, CEP 13084-971, Campinas SP, Brazil. ldias@iqm.unicamp.br
Aguilar
Andrea M
AM