Acetylenedithiolate: alkyne complex formation renders it a dithiolate chelate ligand.
The isostructural complexes [{Tp'W(CO)(2)(eta(2)-C(2)S(2))}(2)M] (M = Ni, Pd, Pt) show that the eta(2)-C,C'-alkyne complexes of acetylenedithiolate at [Tp'W(CO)(2)](+) can generally act as dithiolate chelate ligands, leading to dithiolene type complexes.
Seidel
Wolfram W
WW
Institut für Anorganische und Analytische Chemie, Westfälische Wilhelms-Universität Münster, Germany. seidelww@uni-muenster.de
Schaffrath
Markus
M
Pape
Tania
T