A theory of the interaction between electrical double layers.
A generalization of the Poisson-Boltzmann approach to the repulsive electrostatic force between similar electrical double layers is presented. It is based on the integral equation formalism of the statistical mechanical theories of fluids and it is shown that the Poisson-Boltzmann result follows from a well-defined and improvable set of approximations.
Olivares
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Department of Chemistry, University of California, Davis, CA 95616, USA.
McQuarrie
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