title: 4-O-Acetyl-3-O-tert-butyldimethylsilyl-L-rhamnal: a building block in the stereoselective synthesis of 2-deoxy-alpha-L-rhamnopyranosides.
abstract: The stereoselective synthesis of 2-deoxy-alpha-L-glycosides by addition of various acceptors to 4-O-acetyl-3-O-tert-butyldimethylsilyl-L-rhamnal promoted by triphenylphosphine-hydrogen bromide is developed.
authors.affiliation: Silesian University of Technology, Faculty of Chemistry, Department of Organic Chemistry, Bioorganic Chemistry and Biotechnology, 44-100 Gliwice, Krzywoustego 4, Poland.
authors.forename: Ilona
authors.initials: I
authors.lastname: Wandzik
authors.forename: Tadeusz
authors.initials: T
authors.lastname: Bieg
mesh_terms: D006031:Glycosylation; D018054:Hydrobromic Acid / Q000737:chemistry; D019906:Nuclear Magnetic Resonance, Biomolecular; D009943:Organophosphorus Compounds / Q000737:chemistry; D017646:Organosilicon Compounds / Q000737:chemistry*; D012210:Rhamnose / Q000031:analogs & derivatives* / Q000138:chemical synthesis*; D013237:Stereoisomerism
chemical_list: D009943:Organophosphorus Compounds; D017646:Organosilicon Compounds; C061896:triphenylphosphine; D018054:Hydrobromic Acid; D012210:Rhamnose