Solvent water tapes in two hydrates of mu-oxo-bis[bis(2,2'-bipyridine-kappa2N,N')(sulfato-kappaO)iron(III)].
The title compound, [Fe2O(SO4)2(C10H8N2)4], crystallizes as two different hydrates, viz. 11H2O, (I), and 15H2O, (II). The complex is binuclear, in which the two FeIII atoms are coordinated in an octahedral geometry to four N atoms from the two bipyridine ligands, to one O atom from the sulfate ion and to an oxide ion on a twofold axis, which acts as a bridge between the symmetry-related units. The Fe...Fe separation is 3.556 (4) A and the Fe-O-Fe angle is 161.6 (2) degrees in (I); the corresponding values are 3.544 (1) A and 165.8 (2) degrees in (II). In (II), one of the O atoms of the sulfate ion is disordered over two positions. In both compounds, the solvent water molecules form slightly different one-dimensional hydrogen-bonded networks which pass along the c axis of the unit cell. In (I), three solvent water molecules and, in (II), one solvent water molecule, are situated on the twofold axis. In both (I) and (II), the central O atom of the metal complex lies on a twofold axis.
Onawumi
O O E
OO
Department of Pure and Applied Chemistry, Ladoke Akintola University of Technology, Ogbomoso, Nigeria.
Faboya
O O P
OO
Odunola
O A
OA
Prasad
T K
TK
Rajasekharan
M V
MV