RbBa2(N3)5: a new ternary azide.
Rubidium dibarium pentaazide, RbBa2(N3)5, was prepared from an aqueous solution of the binary azides at room temperature. It crystallizes in the monoclinic system (space group P2/n). Two central atoms of azide groups occupy the 2c (1) and 2b (1) positions, another azide group lies completely on a twofold axis (2f), while Rb atoms are situated in 2e (2) positions. The crystal structure of RbBa2(N3)5 can be regarded as a distorted AlB2-type arrangement of the metal atoms, with the azide groups occupying the voids between the cations. This results in coordination numbers of 8 (Rb) and 10 (Ba). The N-N distances are in the range 1.169 (8)-1.190 (5) A, typical for the azide group.
Vajenine
Grigori V
GV
Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, 70569 Stuttgart, Germany, and Institut für Anorganische Chemie, Universität Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany. g.vajenine@fkf.mpg.de