Molecular diffusion in liquid crystals and chiral discrimination. II. Model calculations.
We perform model calculations of the macroscopic diffusion coefficient for a solute moving in a chiral nematic (cholesteric) liquid crystal (LC) phase applying the methodology developed by Frezzato et al. [J. Chem. Phys. 122, 164904 (2005)]. Three types of solutes with different features are studied: ellipsoid [roto-translational coupling (RTC) absent], bent rod (RTC present), and two-blade propeller (with RTC and chiral shape). For each prototype molecule we estimate the effect of cholesteric helix pitch and local order on the diffusion along the helix axis. For the ellipsoidal particle we find that translational diffusion is slowed down by rotation around the short axis. For the chiral solute we show that the enantiomer with shape chirality opposite to that of the LC phase is slowed down more than the other. This provides a proof of principle of the possibility of separating the two enantiomers via transport in a suitable chiral medium.
Frezzato
Diego
D
Dipartimento di Scienze Chimiche, Università di Padova and INSTM, Università di Padova, via Marzolo 1, I-35131 Padua, Italy.
Zannoni
Claudio
C
Moro
Giorgio J
GJ