Design and solvothermal synthesis of luminescent copper(I)-pyrazolate coordination oligomer and polymer frameworks.
Two luminescent coordination compounds, [Cu(Pz)]3 (1) and [Cu2(Bpz)]n (2), were isolated from solvothermal reactions of Cu(NO3)2 with 3,5-dimethylpyrazole (HPz) and 3,3',5,5'-tetra-methyl-4,4'-bipyrazole (H2Bpz) respectively in the presence of NH3, of which 1 was revealed to be a planar trimer and 2 a three-dimensional framework, presenting a rare 3-connected binodal (6(2).10)(6.10(2)) topology and eight-fold interpenetration.
He
Jun
J
Department of Chemistry, Shantou University, Guangdong 515063, PR China.
Yin
Ye-Gao
YG
Wu
Tao
T
Li
Dan
D
Huang
Xiao-Chun
XC