Hydrocarboxylation of terminal alkenes in supercritical carbon dioxide using perfluorinated surfactants.
High selectivity in acids is obtained in the first example of hydrocarboxylation of 1-octene in supercritical carbon dioxide using a Pd/P(4-C6H4-CF3)3 catalyst system and a perfluorinated surfactant.
Tortosa-Estorach
Clara
C
Departament de Química Física i Inorgànica, Universitat Rovira i Virgili, Campus Sescelades, c/Marcel lí Domingo, s/n, E-43007 Tarragona, Spain.
Ruiz
Núria
N
Masdeu-Bultó
Anna M
AM