New porphyrin-based metal-organic framework with high porosity: 2-D infinite 22.2-A square-grid coordination network.
A new 2-D coordination network with 22.2-A square-grid coordination networks was prepared from a dicopper(II) tetraacetate [Cu2(AcO)4] as a linear linker motif and 5,10,15,20-tetra-4-pyridyl-21H,23H-porphine (H2TPyP) as a four-connected vertex, forming a regular high-porous structure. The characterization by N2 adsorption indicated that this coordination network has uniform micropores and gas adsorption cavities.
Ohmura
Tetsushi
T
Toyota Central R&D Laboratories, Inc., 41-1 Yokomichi, Nagakute, Aichi-gun, Aichi 480-1192, Japan. e1314@mosk.tytlabs.co.jp
Usuki
Arimitsu
A
Fukumori
Kenzo
K
Ohta
Takashi
T
Ito
Mikinao
M
Tatsumi
Kazuyuki
K