A potential intermediate for the aza-Corey-Chaykovsky reaction: synthesis, structure, and thermolysis of a pentacoordinate 1,2-thiazetidine 1-oxide.
Thermolysis of a pentacoordinate 1lambda(6),2-thiazetidine, which was synthesized for the first time and characterized by X-ray crystallographic analysis, gave the corresponding aziridine and a cyclic sulfinate almost quantitatively. The potential intermediacy of a 1lambda(6),2-thiazetidine was suggested in the aza-Corey-Chaykovsky reaction.
Kano
Naokazu
N
Department of Chemistry, Graduate School of Science, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Daicho
Yuya
Y
Kawashima
Takayuki
T