Sensitivity enhanced recoupling experiments in solid-state NMR by gamma preparation.
In this paper, we introduce a class of dipolar recoupling experiments under magic angle spinning (MAS), which use gamma dependent antiphase polarization during the t1 evolution period. We show that this helps us to design dipolar recoupling experiments that transfer both components of the transverse magnetization of spin S to a coupled spin I in the mixing step of a 2D NMR experiment. We show that it is possible to design such transfer schemes and make them insensitive to the orientation dependency of the couplings in powders. This helps us to develop sensitivity enhanced 2D NMR experiments of powder samples under MAS.
Khaneja
Navin
N
Division of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA.
D000465:Algorithms; D001704:Biopolymers / Q000032:analysis*; D003198:Computer Simulation; D005720:Gamma Rays; D008956:Models, Chemical; D008958:Models, Molecular; D019906:Nuclear Magnetic Resonance, Biomolecular / Q000379:methods*; D011208:Powders / Q000032:analysis*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity
D001704:Biopolymers; D011208:Powders