title: Studies of an Fe9 tridiminished icosahedron.
abstract: The synthesis and structural characterization of a nonanuclear FeIII cage complex is reported. The nine iron centers in [Fe9(mu3-O)4(O3PPh)3(O2CCMe3)13] lie on the vertices of an incomplete icosahedron, with the P atoms of triphenylphosphonate at the other three vertices. The paramagnetic core therefore describes a tridiminished icosahedron. Magnetic studies suggest an S=1/2 ground state for the molecule. Analysis of exchange paths and the susceptibility data point to the interpretation that the cluster can be divided into two nearly decoupled sections: an {Fe6O3} section, with an S=0 ground state, in which three oxo-centered triangles bound a central triangle that is not oxo-centered; and an {Fe3O} triangle with S=1/2. The analysis of the susceptibility data leads to a Heisenberg model based on three significant antiferromagnetic exchange interactions, with values of 173.7 cm-1 in the {Fe3O} triangle, and 30.9 and 19.1 cm-1 within the {Fe6O3} section, while the exchange between them is <1 cm-1. With these assignments, the theoretical low-temperature differential susceptibility is also in very good agreement with measurements up to 50 T. Magnetic measurements in the milli-kelvin range reveal striking hysteresis loops and magnetization reversals associated with a Landau-Zener-Stückelberg (LZS) transition as enhanced by the occurrence of a phonon bottleneck.
authors.affiliation: School of Chemistry, The University of Manchester, Oxford Road, Manchester, M13 9PL, UK.
authors.forename: Evangelos I
authors.initials: EI
authors.lastname: Tolis
authors.forename: Larry P
authors.initials: LP
authors.lastname: Engelhardt
authors.forename: Pamela V
authors.initials: PV
authors.lastname: Mason
authors.forename: Gopalan
authors.initials: G
authors.lastname: Rajaraman
authors.forename: Koichi
authors.initials: K
authors.lastname: Kindo
authors.forename: Marshall
authors.initials: M
authors.lastname: Luban
authors.forename: Akira
authors.initials: A
authors.lastname: Matsuo
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Nojiri
authors.forename: James
authors.initials: J
authors.lastname: Raftery
authors.forename: Christian
authors.initials: C
authors.lastname: Schröder
authors.forename: Grigore A
authors.initials: GA
authors.lastname: Timco
authors.forename: Floriana
authors.initials: F
authors.lastname: Tuna
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Wernsdorfer
authors.forename: Richard E P
authors.initials: RE
authors.lastname: Winpenny