Induced hyper-valence of carbon in metal:fluorocarbon complexes.
Charge-transfer in combination with geometric features induces a pentavalent state of the carbon atom in metastable super-fluorinated alkali-metal compounds, M:C2F7 (M = K to Cs).
Naumkin
Fedor Y
FY
Faculty of Science, UOIT, Oshawa, Ontario, Canada L1H 7K4. fedor.naumkin@uoit.ca
D002244:Carbon / Q000737:chemistry*; D005466:Fluorocarbons / Q000737:chemistry*; D008672:Metals, Alkali / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013055:Spectrophotometry, Infrared / Q000379:methods
D005466:Fluorocarbons; D008672:Metals, Alkali; D002244:Carbon