Synthesis of an aluminum spirocyclic hybrid with an inorganic B2O3 and an organic C3N2 core.
The reaction of LAl (L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3) or LAlH2 with PhB(OH)2 yields the unprecedented spirocyclic LAl[(OBPh)2O] compound. The former reaction proceeds under hydrogen formation and simultaneous oxidation of the aluminum(I).
Yang
Zhi
Z
Institut für Anorganische Chemie der Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.
Ma
Xiaoli
X
Oswald
Rainer B
RB
Roesky
Herbert W
HW
Noltemeyer
Mathias
M