Spontaneous resolution of silver double helicates consisting of achiral ligands with several aromatic rings.
Symmetric breaking of silver double helicates through spontaneous crystallization was achieved via incorporation of C-H...pi and pi-pi stacking interactions of achiral ligands consisting of several aromatic rings.
Sun
Qiaozhen
Q
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, 210093, PR China.
Bai
Yan
Y
He
Guangjie
G
Duan
Chunying
C
Lin
Zhihua
Z
Meng
Qingjin
Q
D002942:Circular Dichroism; D006859:Hydrogen / Q000737:chemistry; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D012834:Silver / Q000737:chemistry*; D013237:Stereoisomerism
D008024:Ligands; D012834:Silver; D006859:Hydrogen