title: Balancing framework densification with charged, halogen-bonded-pi-conjugated linkages: [PPh4]2{[E-TTF-I2][Re6Se8(CN)6]} versus [PPh4]2[EDT-TTF-I]2{[EDT-TTF-I][Re6Se8(CN)6]}.
abstract: The ionic character of a set of two redox linkages and strong, directional halogen bonding at the organic-inorganic interface compromise to produce two materials sharing a common two-dimensional net, eventually extended in a third dimension, although two of the six symmetrical halogen bond acceptors ultimately remain uninvolved as a result of charge densification.
authors.affiliation: Laboratoire de Chimie, Ingénierie Moléculaire et Matériaux d'Angers, UMR 6200 CNRS-Université d'Angers, 2 Boulevard Lavoisier, 49045 Angers, France.
authors.forename: Anupama
authors.initials: A
authors.lastname: Ranganathan
authors.forename: Abdelkrim
authors.initials: A
authors.lastname: El-Ghayoury
authors.forename: Cécile
authors.initials: C
authors.lastname: Mézière
authors.forename: Etienne
authors.initials: E
authors.lastname: Hartê
authors.forename: Rodolphe
authors.initials: R
authors.lastname: Clérac
authors.forename: Patrick
authors.initials: P
authors.lastname: Batail