Synthesis and characterization of uncapped gamma-Fe2O3 nanoparticles prepared by flame pyrolysis of ferrocene in ethanol.
Nanoparticles of iron(III) oxide were synthesized by spontaneous combustion of ferrocene in ethanol solution using a simple spirit lamp. X-ray powder diffraction and electron diffraction analysis of the powder suggested the formation of gamma-Fe2O3 (Maghemite phase) having lattice constant 8.3539 +/- 0.0209 A. Transmission Electron Micrograph suggested the formation of spherical particles with an average diameter of 24.7 +/- 1.6 nm. A sextet with an isomeric shift of 0.328 mm s(-1) seen in the Mossbauer spectrum recorded at room temperature, further supports the formation of gamma-Fe2O3. The particles were dispersed freely in the polar solvents like ethanol, dimethyl sulfoxide, and water. Infra Red spectrum gave bands at 400, 432, 565, and 638 cm(-1), which confirms the presence of gamma-Fe2O3 phase.
Inamdar
Shaukatali N
SN
Department of Chemistry, University of Pune, Ganeshkhind, India.
Haram
Santosh K
SK
D003460:Crystallization / Q000379:methods*; D000431:Ethanol / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry*; D006358:Hot Temperature; D046911:Macromolecular Substances / Q000737:chemistry; D008280:Magnetics; D008422:Materials Testing; D000075163:Metallocenes; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000295:instrumentation / Q000379:methods*; D010316:Particle Size; D012997:Solvents / Q000737:chemistry; D013499:Surface Properties
D005290:Ferric Compounds; D005296:Ferrous Compounds; D046911:Macromolecular Substances; D000075163:Metallocenes; D012997:Solvents; C000499:ferric oxide; D000431:Ethanol; C004998:ferrocene