Transmission electron microscopy investigation of Sb-doped ZnO nanoribbons and Zn7Sb2O12 branched ZnO nanoribbon structure.
Sb-doped ZnO nanoribbons have been synthesized by simple thermal evaporation of powder mixtures of Zn and Sb2O3. The Sb-doped ZnO nanoribbons with hexagonal wurtzite structure have a growth direction of [0110], widths of 100-300 nm, and lengths up to several hundreds of micrometers. The atomic ratio of Sb and Zn is about 1:40 by energy dispersive X-ray spectroscopy measurement. A stripe contrast is found in the center of the Sb-doped ZnO nanoribbon, which is speculated to be due to the enrichment of Sb in the center of the Sb-doped ZnO nanoribbon by energy dispersive X-ray spectroscopy line scanning element mapping. Furthermore, a novel Zn7Sb2O12 branched ZnO nanoribbon structure is investigated. The growth direction of the branch and the backbone are [211] and [0110], respectively. The mechanisms of formation of such nanomaterials are also discussed.
Zou
Kai
K
Nano-Organic Photoelectronic Laboratory, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing, P R China.
Zhou
Shaomin
S
Zhang
Xiaohong
X
Qi
Xiaoying
X
Duan
Xiaofeng
X
D000965:Antimony / Q000737:chemistry*; D005591:Chemical Fractionation / Q000379:methods; D003460:Crystallization / Q000379:methods*; D006358:Hot Temperature; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D046529:Microscopy, Electron, Transmission; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods; D010087:Oxides / Q000737:chemistry*; D010316:Particle Size; D013499:Surface Properties; D015032:Zinc / Q000737:chemistry*; D015034:Zinc Oxide / Q000737:chemistry*
D046911:Macromolecular Substances; D010087:Oxides; C091696:antimony oxide; D000965:Antimony; D015032:Zinc; D015034:Zinc Oxide