title: Gas-phase regiocontrolled generation of charged amino acid and peptide radicals.
abstract: The combined use of advanced mass spectrometry experiments, condensed-phase synthesis of serine and homoserine nitrate ester radical precursors, and high-level ab initio calculations provides a powerful way of examining the fundamental reactivity of radicals derived from peptides.
authors.affiliation: School of Chemistry, University of Melbourne, Victoria 3010, Australia.
authors.forename: Sheena
authors.initials: S
authors.lastname: Wee
authors.forename: Adam
authors.initials: A
authors.lastname: Mortimer
authors.forename: Damian
authors.initials: D
authors.lastname: Moran
authors.forename: Adam
authors.initials: A
authors.lastname: Wright
authors.forename: Christopher K
authors.initials: CK
authors.lastname: Barlow
authors.forename: Richard A J
authors.initials: RA
authors.lastname: O'Hair
authors.forename: Leo
authors.initials: L
authors.lastname: Radom
authors.forename: Christopher J
authors.initials: CJ
authors.lastname: Easton
mesh_terms: D000596:Amino Acids / Q000737:chemistry*; D004579:Electron Transport; D004952:Esters; D005609:Free Radicals / Q000737:chemistry*; D005740:Gases / Q000737:chemistry*; D006714:Homoserine / Q000737:chemistry; D010455:Peptides / Q000737:chemistry*; D012694:Serine / Q000737:chemistry; D021241:Spectrometry, Mass, Electrospray Ionization
chemical_list: D000596:Amino Acids; D004952:Esters; D005609:Free Radicals; D005740:Gases; D010455:Peptides; D012694:Serine; D006714:Homoserine