title: Measuring the force of interaction between a metallic probe and a single molecule.
abstract: Precision current measurements are recorded at 5 K during the approach and contact between a Pt-inked probe and the carbon-carbon double-bond region of an isolated 1,3-cyclohexadiene molecule chemisorbed on a Si(100) surface. Scanning tunneling spectroscopic data reveal systematic features in the current at specific probe-molecule separations. Aided by density functional theory calculations, we show that these features arise from interaction forces between the probe and molecule, which can be interpreted as the relaxation of the probe-molecule system prior to and during contact.
authors.affiliation: School of Chemistry and the Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN), Trinity College, Dublin 2, Ireland.
authors.forename: B
authors.initials: B
authors.lastname: Naydenov
authors.forename: P
authors.initials: P
authors.lastname: Ryan
authors.forename: L C
authors.initials: LC
authors.lastname: Teague
authors.forename: John J
authors.initials: JJ
authors.lastname: Boland
mesh_terms: D000465:Algorithms; D002244:Carbon / Q000737:chemistry; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D053138:Cyclohexenes / Q000737:chemistry; D004563:Electrochemistry; D004566:Electrodes; D008670:Metals / Q000737:chemistry*; D036103:Nanotechnology; D017711:Nonlinear Dynamics; D010984:Platinum / Q000737:chemistry; D012828:Silicones / Q000737:chemistry
chemical_list: D053138:Cyclohexenes; D008670:Metals; D012828:Silicones; D010984:Platinum; D002244:Carbon; C034005:1,3-cyclohexadiene