Gas-phase regiocontrolled generation of charged amino acid and peptide radicals.
The combined use of advanced mass spectrometry experiments, condensed-phase synthesis of serine and homoserine nitrate ester radical precursors, and high-level ab initio calculations provides a powerful way of examining the fundamental reactivity of radicals derived from peptides.
Wee
Sheena
S
School of Chemistry, University of Melbourne, Victoria 3010, Australia.
Mortimer
Adam
A
Moran
Damian
D
Wright
Adam
A
Barlow
Christopher K
CK
O'Hair
Richard A J
RA
Radom
Leo
L
Easton
Christopher J
CJ
D000596:Amino Acids / Q000737:chemistry*; D004579:Electron Transport; D004952:Esters; D005609:Free Radicals / Q000737:chemistry*; D005740:Gases / Q000737:chemistry*; D006714:Homoserine / Q000737:chemistry; D010455:Peptides / Q000737:chemistry*; D012694:Serine / Q000737:chemistry; D021241:Spectrometry, Mass, Electrospray Ionization
D000596:Amino Acids; D004952:Esters; D005609:Free Radicals; D005740:Gases; D010455:Peptides; D012694:Serine; D006714:Homoserine