Complexes of 1,2-bis(aryl-imino)acenaphthene (Ar-BIAN) ligands with some heavy p-block elements.
The new Ar-BIAN complexes [(mes-BIAN)InCl(3)(THF)] (1), [(mes-BIAN)(2)Tl][PF(6)] (2), [(dipp-BIAN)SnCl(4)] (3), [(dipp-BIAN)SbCl(3)] (4), [(dipp-BIAN)BiCl(3)] (5) and [(mes-BIAN)BiCl(3)] (6) have been prepared by treatment of the neutral mes- and dipp-substituted BIAN ligands with the p-block reagents InCl(3), TlPF(6), SnCl(4), SbCl(3), and BiCl(3). The molecular structures of complexes 1-6 have been determined by single-crystal X-ray diffraction methods. However, only the atom connectivity was established for 5.
Hill
Nicholas J
NJ
Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712, USA.
Reeske
Gregor
G
Moore
Jennifer A
JA
Cowley
Alan H
AH
D000073:Acenaphthenes / Q000737:chemistry*; D000965:Antimony / Q000737:chemistry; D001729:Bismuth / Q000737:chemistry; D002712:Chlorides / Q000737:chemistry; D018360:Crystallography, X-Ray; D007204:Indium / Q000737:chemistry; D008024:Ligands; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D017971:Tin Compounds / Q000737:chemistry
D000073:Acenaphthenes; D002712:Chlorides; D008024:Ligands; D009942:Organometallic Compounds; D017971:Tin Compounds; D007204:Indium; C023599:stannous chloride; C020758:indium trichloride; D000965:Antimony; D001729:Bismuth