Selective formation of polycarbonate over cyclic carbonate: copolymerization of epoxides with carbon dioxide catalyzed by a cobalt(III) complex with a piperidinium end-capping arm.
Nakano
Koji
K
Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Kamada
Toshihiro
T
Nozaki
Kyoko
K
D002245:Carbon Dioxide / Q000737:chemistry*; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D004852:Epoxy Compounds / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010880:Piperidines / Q000737:chemistry*; D011076:Polycarboxylate Cement / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D004852:Epoxy Compounds; D009942:Organometallic Compounds; D010880:Piperidines; D011076:Polycarboxylate Cement; D002245:Carbon Dioxide; C005506:polycarbonate; D003035:Cobalt