Dynamical slowdown of polymers in laminar and random flows.
The influence of an external flow on the relaxation dynamics of a single polymer is investigated theoretically and numerically. We show that a pronounced dynamical slowdown occurs in the vicinity of the coil-stretch transition, especially when the dependence on polymer conformation of the drag is accounted for. For the elongational flow, relaxation times are exceedingly larger than the Zimm relaxation time, resulting in the observation of conformation hysteresis. For random smooth flows, hysteresis is not present. Yet, relaxation dynamics is significantly slowed down because of the large variety of accessible polymer configurations. The implications of these results for the modeling of dilute polymer solutions in turbulent flows are addressed.
Celani
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CNRS-INLN, 1361 Route des Lucioles, 06560 Valbonne, France.
Puliafito
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A
Vincenzi
D
D
D000180:Acrylic Resins / Q000737:chemistry; D000465:Algorithms; D001703:Biophysics / Q000379:methods; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D015233:Models, Statistical; D008968:Molecular Conformation; D016011:Normal Distribution; D011108:Polymers / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013816:Thermodynamics; D013997:Time Factors; D000099166:Polyacrylamides
D000180:Acrylic Resins; D011108:Polymers; D012997:Solvents; D000099166:Polyacrylamides