title: Memory effect of activated Mg-Al hydrotalcite: in situ XRD studies during decomposition and gas-phase reconstruction.
abstract: The thermal decomposition of Mg-Al hydrotalcite and the subsequent reconstruction of the decomposed products in the presence of water vapor (2 vol. % H(2)O in N(2)) have been investigated by in situ XRD. Thermographic analysis and temperature-programmed desorption MS results complemented the diffraction data. Valuable mechanistic and kinetic insights into these processes, which are of prime importance for optimal activation of this type of material for catalytic applications, were obtained. Hydrotalcite decomposition to the mixed oxide proceeds via formation at 423-473 K of an intermediate phase, consisting of a highly disordered, dehydrated, layered structure. The latter evolves by removal of interlayer water on heating, causing a shrinking of the interlayer space (it is up to 45 % smaller than in the as-synthesized hydrotalcite). Above 623 K, Mg(Al)O(x) oxide with the periclase structure is formed. Reversion of the intermediate dehydrated structure to hydrotalcite upon contact with water vapor is complete and very fast at room temperature. Recovery of hydrotalcite from the oxide calcined at 723 K is two orders of magnitude slower than rehydration of the intermediate layered structure and one order of magnitude slower than the typically practiced liquid-phase reconstruction. In contrast to the decomposition, the reconstruction mechanism does not involve an intermediate phase. The gas-phase rehydration and reconstruction was interrupted above 303 K. This is attributed to the poor wetting of the surface of the decomposed materials induced by hampered H(2)O adsorption above room temperature at the water vapor pressure applied. The Avrami-Erofe'ev model describes the reconstruction kinetics well.
authors.affiliation: Laboratory for Heterogeneous Catalysis, Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain. jperez@iciq.es
authors.forename: Javier
authors.initials: J
authors.lastname: Pérez-Ramírez
authors.forename: Sònia
authors.initials: S
authors.lastname: Abelló
authors.forename: Niek M
authors.initials: NM
authors.lastname: van der Pers
mesh_terms: D000536:Aluminum Hydroxide / Q000737:chemistry*; D005740:Gases / Q000737:chemistry; D008276:Magnesium Hydroxide / Q000737:chemistry*; D008958:Models, Molecular; D010316:Particle Size; D013696:Temperature; D013997:Time Factors; D014961:X-Ray Diffraction / Q000295:instrumentation / Q000379:methods
chemical_list: D005740:Gases; C010467:hydrotalcite; D000536:Aluminum Hydroxide; D008276:Magnesium Hydroxide