Accelerated carbonation of municipal solid waste incineration fly ashes.
As a result of the EU Landfill Directive, the disposal of municipal solid waste incineration (MSWI) fly ash is restricted to only a few landfill sites in the UK. Alternative options for the management of fly ash, such as sintering, vitrification or stabilization/solidification, are either costly or not fully developed. In this paper an accelerated carbonation step is investigated for use with fly ash. The carbonation reaction involving fly ash was found to be optimum at a water/solid ratio of 0.3 under ambient temperature conditions. The study of ash mineralogy showed the disappearance of lime/portlandite/calcium chloride hydroxide and the formation of calcite as carbonation proceeded. The leaching properties of carbonated ash were examined. Release of soluble salts, such as SO4, Cl, was reduced after carbonation, but is still higher than the landfill acceptance limits for hazardous waste. It was also found that carbonation had a significant influence on lead leachability. The lead release from carbonated ash, with the exception of one of the fly ashes studied, was reduced by 2-3 orders of magnitude.
Li
Xiaomin
X
Centre for Contaminated Land Remediation, University of Greenwich at Medway, Chatham Maritime, Kent, ME4 4TB, UK.
Bertos
Marta Fernández
MF
Hills
Colin D
CD
Carey
Paula J
PJ
Simon
Stef
S
D002244:Carbon / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry*; D002712:Chlorides / Q000032:analysis; D060729:Coal Ash; D006863:Hydrogen-Ion Concentration; D017745:Incineration; D007220:Industrial Waste / Q000032:analysis; D008670:Metals / Q000032:analysis; D052638:Particulate Matter / Q000737:chemistry*; D013431:Sulfates / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000032:analysis
D002712:Chlorides; D060729:Coal Ash; D007220:Industrial Waste; D008670:Metals; D052638:Particulate Matter; D013431:Sulfates; D014874:Water Pollutants, Chemical; D002245:Carbon Dioxide; D002244:Carbon