Ionic contribution to the electric current in an electrolytic cell submitted to an external voltage.
The ionic contribution to the electrical current in an electrolytic cell submitted to an external voltage linearly increasing with the time is evaluated. The investigation is performed in the limit of small and large electric field, in which the density of ions depends on the actual electric field in the sample. In the analysis, it is assumed that the ionic separation induced by an external field can be described by a surface density of charge. We show that the ions are responsible for a peak in the current, followed by a delay in the application of the external voltage. From the analysis of the peak and its delay, it is possible to obtain information on the density of ions in thermodynamical equilibrium, and on the mobility of the ions in the considered liquid.
Barbero
G
G
Instituto de Física, Universidade de São Paulo, PO Box 66318, São Paulo, 05389-970 SP, Brazil.
Evangelista
L R
LR
Lelidis
I
I