title: Deuterated H3+ as a probe of isotope fractionation in star-forming regions.
abstract: Observations of molecular D/H ratios in the interstellar medium are used to probe the physical conditions, such as temperature, ionization fraction and the importance of gas-grain reactions. In cold, dense regions, such as cores which are collapsing to form stars, the level of deuterium fractionation depends on the conversion of H3+ into its deuterated isotopologues (H2D+, D2H+ and D3+). The relative abundances of these molecules uniquely probe the centres of these cores where other, heavier, species have frozen onto dust grains. We present models of the deuterium chemistry close to the centre of a pre-stellar core, in the last stage before the star forms, showing the dependence of the observable molecular D/H ratios on the physical parameters and rate coefficients that are assumed. We compare model predictions with the latest observations of these regions.
authors.affiliation: School of Physics and Astronomy, University of Manchester, PO Box 88, Manchester M60 1QD, UK. helen.h.roberts@manchester.ac.uk
authors.forename: Helen
authors.initials: H
authors.lastname: Roberts
authors.forename: T J
authors.initials: TJ
authors.lastname: Millar