Interpretation of the odd-even behavior for the emergence of ferroelectricity and antiferroelectricity in bent-core mesogens.
Simple theoretical interpretation has been made on the previously reported odd-even behavior of the emergence of ferroelectricity and antiferroelectricity in homologous series of bent-core mesogens with the same chiral end chains (S,S) ; compounds with even and odd carbon numbers (including oxygen) exhibit ferroelectric and antiferroelectric B2 phases, respectively. The odd-even behavior was confirmed in newly synthesized racemic compounds with chiral end chains of R and S forms (R,S) together with (R,R) and (S,S) forms. According to our theoretical interpretation, ferroelectricity should be more stable in (R,S) compounds than in (S,S) compounds. Actually, the transition temperature from the isotropic phase to the Sm-CP phase was higher and the temperature range of the B2 phase was broader in the (R,S) compound than in the (S,S) compound.
Nishida
Koushi
K
Department of Organic and Polymeric Materials, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8552, Japan.
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