title: Galactose Oxidase models: 19F NMR as a powerful tool to study the solution chemistry of tripodal ligands in the presence of copper(II).
abstract: In copper(ii) complexes of tripodal ligands, the protonation state of the phenol moiety, and its position (axial vs. equatorial), are easily assessed by (19)F NMR.
authors.affiliation: Laboratoire d'Etudes Dynamiques et Structurales de la Sélectivité, Equipe de Chimie Biomimétique, UMR CNRS 5616, ICMG FR CNRS 2607, Université Joseph Fourier, BP 53, 38041, Grenoble cedex 9, France.
authors.forename: Fabien
authors.initials: F
authors.lastname: Michel
authors.forename: Sylvain
authors.initials: S
authors.lastname: Hamman
authors.forename: Fabrice
authors.initials: F
authors.lastname: Thomas
authors.forename: Christian
authors.initials: C
authors.lastname: Philouze
authors.forename: Isabelle
authors.initials: I
authors.lastname: Gautier-Luneau
authors.forename: Jean-Louis
authors.initials: JL
authors.lastname: Pierre
mesh_terms: D002413:Cations, Divalent; D003300:Copper / Q000737:chemistry*; D005461:Fluorine; D005692:Galactose Oxidase / Q000737:chemistry*; D008024:Ligands; D008956:Models, Chemical; D008958:Models, Molecular; D019906:Nuclear Magnetic Resonance, Biomolecular / Q000379:methods*; D011487:Protein Conformation; D012996:Solutions
chemical_list: D002413:Cations, Divalent; D008024:Ligands; D012996:Solutions; D005461:Fluorine; D003300:Copper; D005692:Galactose Oxidase