Highly-oxidised, sulfur-rich, mixed-valence vanadium(IV/V) complexes.
The reactions of [V(2)(micro-S(2))(2)(S(2)CNR(2))(4)] (R = alkyl) with NOBF(4) produce highly-oxidised, sulfur-rich, V(iv/v) complexes, [V(2)(micro-S(2))(2)(S(2)CNR(2))(4)]BF(4), that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour.
Taylor
Michelle K
MK
School of Chemistry, University of Melbourne, Victoria 3010, Australia.
Evans
David J
DJ
Young
Charles G
CG