A green method for the electroorganic synthesis of new 1,3-Indandione derivatives.
This is an environmentally friendly method in the field of electroorganic reactions under controlled potential electrolysis, without toxic reagents at a carbon electrode in an undivided cell which involves the (EC) mechanism reaction and comprises two steps alternatively; (i) electrochemical oxidation and (ii) chemical reaction. In particular, the electrochemical oxidation of 4-tert-butylcatechol, 4-methylcatechol and 2,3-dihydroxybenzoic acid in the presence of 2-phenyl-1,3-indandione has been studied in a water-acetonitrile (90 : 10) mixture. The research includes the use of a variety of experimental techniques, such as cyclic voltammetry, controlled-potential electrolysis, and spectroscopic identification of products (FT-IR, (1)H-NMR, and MS spectrometry).
Moghaddam
Abdolmajid Bayandori
AB
Center of Excellence in Electrochemistry, Faculty of Chemistry, University of Tehran, Teheran, Iran.
Ganjali
Mohammad Reza
MR
Norouzi
Parviz
P
Latifi
Maryam
M
D002244:Carbon; D002396:Catechols / Q000138:chemical synthesis / Q000737:chemistry; D004563:Electrochemistry; D004566:Electrodes; D004572:Electrolysis; D062385:Hydroxybenzoates / Q000138:chemical synthesis / Q000737:chemistry; D007189:Indans / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D002396:Catechols; D062385:Hydroxybenzoates; D007189:Indans; C018599:4-methylcatechol; C038096:tert-butylcatechol; C001445:1,3-indandione; C009135:2,3-dihydroxybenzoic acid; D002244:Carbon