title: Healing substrates with mobile, particle-filled microcapsules: designing a 'repair and go' system.
abstract: We model the rolling motion of a fluid-driven, particle-filled microcapsule along a heterogeneous, adhesive substrate to determine how the release of the encapsulated nanoparticles can be harnessed to repair damage on the underlying surface. We integrate the lattice Boltzmann model for hydrodynamics and the lattice spring model for the micromechanics of elastic solids to capture the interactions between the elastic shell of the microcapsule and the surrounding fluids. A Brownian dynamics model is used to simulate the release of nanoparticles from the capsule and their diffusion into the surrounding solution. We focus on a substrate that contains a damaged region (e.g. a crack or eroded surface coating), which prevents the otherwise mobile capsule from rolling along the surface. We isolate conditions where nanoparticles released from the arrested capsule can repair the damage and thereby enable the capsules to again move along the substrate. Through these studies, we establish guidelines for designing particle-filled microcapsules that perform a 'repair and go' function and thus, can be utilized to repair damage in microchannels and microfluidic devices.
authors.affiliation: Department of Chemical Engineering, University of Pittsburgh, Pittsburgh, PA 15261, USA.
authors.forename: Rolf
authors.initials: R
authors.lastname: Verberg
authors.forename: Alex T
authors.initials: AT
authors.lastname: Dale
authors.forename: Prashant
authors.initials: P
authors.lastname: Kumar
authors.forename: Alexander
authors.initials: A
authors.lastname: Alexeev
authors.forename: Anna C
authors.initials: AC
authors.lastname: Balazs
mesh_terms: D000269:Adhesives / Q000737:chemistry*; D044085:Microfluidics; D008962:Models, Theoretical; D053758:Nanoparticles / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*
chemical_list: D000269:Adhesives; D011108:Polymers