title: Photochemistry of 1,2-dihydronaphthalene oxide: concurrent triplet and singlet processes via singlet excitation.
abstract: The photochemistry of 1,2-dihydronaphthalene oxide (254 nm) was reexamined and indan was found to be a primary photoproduct, as well as the traditionally assumed secondary photoproduct. Quenching studies demonstrated that indan, as a primary photoproduct, is derived from a triplet pathway, competing with a singlet route, back to the ground state surface. CASSCF calculations strongly suggest that the triplet pathway consists of a dissociation of the oxirane moiety to give a triplet carbene and aldehyde, which via hydrogen abstraction-decarbonylation-ISC recloses to give indan. Conical intersections corresponding to the presumed 1,2-hydrogen shift and 1,2-alkyl shift to give 2-tetralone and 1-indancarbaldehyde, respectively, were located computationally.
authors.affiliation: Department of Chemistry, Sam Houston State University, Huntsville, Texas 77341, USA. chm_bea@shsu.edu
authors.forename: Rick C
authors.initials: RC
authors.lastname: White
authors.forename: Benny E
authors.initials: BE
authors.lastname: Arney
authors.forename: Katherine M
authors.initials: KM
authors.lastname: White