Tetranuclear Cu(II) complex supported by a central mu4-1,1,3,3 azide bridge.
The new cluster [Cu4L2(N3)]Cl.16H2O has been synthesized and characterized; it features a unique mu4-1,1,3,3 bridging mode for azide, whose capacity to mediate magnetic coupling has been examined through bulk magnetic measurements and numeric fitting procedures.
Nanda
Prasant Kumar
PK
Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India.
Aromí
Guillem
G
Ray
Debashis
D