Absorption cross sections of formaldehyde at wavelengths from 300 to 340 nm at 294 and 245 K.
Absorption cross sections for the A1A2-X1A1 electronic transition of formaldehyde have been measured by ultraviolet (UV) laser absorption spectroscopy in the tropospherically significant wavelength range 300-340 nm, over which HCHO is photochemically active. Absorption cross sections are reported at two temperatures, 294 and 245 K and at a spectral resolution of 0.0035 nm (0.35 cm-1). At this resolution, greater peak absorption cross sections are obtained for many of the sharp spectral features than were previously reported. To simulate atmospheric conditions in the troposphere, the effects of adding a pressure of nitrogen of up to 500 Torr and of reduced sample temperature were investigated. The overall magnitudes of peak absorption cross sections are largely unaffected by the added pressure of nitrogen, but a modest degree of pressure broadening (0.2-0.3 cm-1 atm-1) is evident in the line shapes. Computer simulations of spectra have been optimized by comparison with wavelength-dependent formaldehyde absorption cross sections for each major vibronic band in the chosen wavelength range. Experimental and computer simulated spectra at 294 and 245 K are compared to test the reliability of the computer simulations for quantification of the effects of temperature on absorption cross sections. All experimental absorption cross section data and tables of input parameters for spectral simulations are available as Supporting Information.
Smith
Carina A
CA
School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK.
Pope
Francis D
FD
Cronin
Bríd
B
Parkes
Clare B
CB
Orr-Ewing
Andrew J
AJ
D001272:Atmosphere; D003198:Computer Simulation; D005557:Formaldehyde / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
D005557:Formaldehyde