title: Tailoring the interfaces between nematic liquid crystal emulsions and aqueous phases via layer-by-layer assembly.
abstract: We report the assembly of polyelectrolyte multilayer (PEM) films at the interfaces of thermotropic liquid crystal (LC) droplets dispersed in an aqueous phase. Exposure of PEM-coated droplets to surfactant slowed the bipolar-to-radial ordering transition of the LCs by 2 orders of magnitude relative to naked droplets. This shows that PEMs can be used to influence the interactions of analytes with the LC cores of the droplets, allowing tuning of the LC emulsion sensing properties.
authors.affiliation: Centre for Nanoscience and Nanotechnology, Department of Chemical and Biomolecular Engineering, The University of Melbourne, Victoria 3010, Australia.
authors.forename: Elvira
authors.initials: E
authors.lastname: Tjipto
authors.forename: Katie D
authors.initials: KD
authors.lastname: Cadwell
authors.forename: John F
authors.initials: JF
authors.lastname: Quinn
authors.forename: Angus P R
authors.initials: AP
authors.lastname: Johnston
authors.forename: Nicholas L
authors.initials: NL
authors.lastname: Abbott
authors.forename: Frank
authors.initials: F
authors.lastname: Caruso
mesh_terms: D003460:Crystallization / Q000379:methods*; D004655:Emulsions; D050866:Liquid Crystals / Q000737:chemistry*; D008422:Materials Testing; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D044367:Phase Transition; D012996:Solutions; D013499:Surface Properties; D014867:Water / Q000737:chemistry*
chemical_list: D004655:Emulsions; D012996:Solutions; D014867:Water