title: Highly-oxidised, sulfur-rich, mixed-valence vanadium(IV/V) complexes.
abstract: The reactions of [V(2)(micro-S(2))(2)(S(2)CNR(2))(4)] (R = alkyl) with NOBF(4) produce highly-oxidised, sulfur-rich, V(iv/v) complexes, [V(2)(micro-S(2))(2)(S(2)CNR(2))(4)]BF(4), that exhibit 15-line EPR spectra and structures consistent with Class III mixed-valence behaviour.
authors.affiliation: School of Chemistry, University of Melbourne, Victoria 3010, Australia.
authors.forename: Michelle K
authors.initials: MK
authors.lastname: Taylor
authors.forename: David J
authors.initials: DJ
authors.lastname: Evans
authors.forename: Charles G
authors.initials: CG
authors.lastname: Young