Pallado-catalysed hydrophosphination of alkynes: access to enantio-enriched P-stereogenic vinyl phosphine-boranes.
Preliminary results dealing with the synthesis of non-racemic P-stereogenic vinylphosphine-boranes by hydrophosphination of alkynes in the presence of a chiral catalyst are reported.
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Benoît
B
Laboratoire de Chimie Moléculaire et Thio-organique, UMR CNRS 6507, ENSI-CAEN, and Université de Caen, 6 bd du Maréchal Juin, 14050 Caen, France.
Mimeau
David
D
Delacroix
Olivier
O
Gaumont
Annie-Claude
AC