[Zn(n)(polyox)(pmtz)n]: the first polyoxalate-containing coordination polymer from an unforeseen chemical rearrangement of 5-pyrimidyl-tetrazole under hydrothermal conditions.
The compound [Zn(2)(polyox)(pmtz)(2)], which has been prepared by the hydrothermal reaction of ZnCl(2) and Napmtz (5-pyrimidyl-tetrazolate), exhibits a unique 2D network with (6,3) topology, in which Zn(II) ions are connected by pmtz- and polyoxalate-bridging ligands (generated in situ from the breaking of the pmzt(-) ligand). This is the first structural report on a polyoxalate species.
Rodríguez-Diéguez
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Departamento de Química Inorgánica, Universidad de Granada, Avenida Fuentenueva s/n, 18071, Granada, Spain.
Colacio
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