title: Conformational product control in the low-temperature photochemistry of cyclopropylcarbenes.
abstract: [reaction: see text] Different conformers of two fused-ring cyclopropylchlorocarbenes are shown to undergo distinct, wavelength-selectable, photochemistry in low-temperature matrixes. Conformers with H and Cl syn give ring expansion predominantly, whereas those with H and Cl anti mainly fragment.
authors.affiliation: Department of Chemistry, University of Nevada, Reno, Nevada 89557, USA.
authors.forename: Peter S
authors.initials: PS
authors.lastname: Zuev
authors.forename: Robert S
authors.initials: RS
authors.lastname: Sheridan
authors.forename: Ronald R
authors.initials: RR
authors.lastname: Sauers
authors.forename: Robert A
authors.initials: RA
authors.lastname: Moss
authors.forename: Gaosheng
authors.initials: G
authors.lastname: Chu