Luminescent 2-D double-layered polymer, [(CuI)4(CH3SCH3)3]infinity, containing helical chains constructed by flower-basket-shaped Cu4I4 clusters.
A new route for the synthesis of coordination compounds with dimethyl sulfide ligand is reported; the prepared compound is a novel 2-D framework with a 1-D right-handed and left-handed helical structure, which is unique in the sense that the fundamental units are unusual Cu4I4 clusters.
Zhou
Jian
J
Department of Chemistry and Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou University, Suzhou 215006, P. R. China.
Bian
Guo-Qing
GQ
Dai
Jie
J
Zhang
Yong
Y
Zhu
Qin-Yu
QY
Lu
Wen
W