Direct synthesis of 1,1-diarylalkenes from alkenyl phosphates via nickel(0)-catalysed Suzuki-Miyaura coupling.
A combination of Ni(COD)(2) and PCy(3) promotes effectively the Suzuki-Miyaura cross coupling of 1-arylalkenyl phosphates with aryl boronic acids with yields attaining 99%.
Hansen
Anders L
AL
Department of Chemistry, University of Aarhus, Langelandsgade 140, 8000, Aarhus C, Denmark.
Ebran
Jean-Philippe
JP
Gøgsig
Thomas M
TM
Skrydstrup
Troels
T