The telomerisation of 1,3-butadiene and carbon dioxide: process development and optimisation in a continuous miniplant.
The telomerisation of 1,3-butadiene and carbon dioxide is one of the first homogeneously catalyzed reactions using carbon dioxide as a C1-building block. In this article we describe the process development for a miniplant applying this telomerisation in a continuous scale. Through repeated optimisation of the plant setup combined with parallel laboratory batch experiments the overall space-time-yield of the plant was enhanced significantly.
Behr
Arno
A
Lehrstuhl für Technische Chemie A, Universität Dortmund, Emil-Figge-Str. 66, D-44227, Dortmund, Germany. behr@bci.uni-dortmund.de
Becker
Marc
M