title: Structural and optical characterization of strained free-standing InP nanowires.
abstract: The structural and optical properties of high-quality crystalline strained InP nanowires are reported in this article. The nanowires were produced by the vapor-liquid-solid growth method in a chemical-beam epitaxy reactor, using 20 nm gold nanoparticles as catalysts. Polarization-resolved photoluminescence experiments were carried out to study the optical properties of the InP nanowires. These experiments revealed a large blue shift of 74 meV of the first electron-to-heavy hole optical transition in the nanowires, which cannot be solely explained by quantum size effects. The blue shift is mainly attributed to the presence of biaxial compressive strain in the inward radial direction of the InP nanowires. High-resolution transmission electron microscopy Electron and selected area electron diffraction experiments show that the nanowires have high crystal quality and grow along a [001] axes. These experiments also confirmed the presence of 1.8% compressive radial strain and 2% tensile longitudinal strain in the nanowires. A simple theoretical model including both quantum confinement and strain effects consistently describes the actual energy position of the InP nanowires optical emission.
authors.affiliation: Departamento de Física, Universidade Federal de Minas Gerais, Belo Horizonte, Brazil.
authors.forename: J C
authors.initials: JC
authors.lastname: González
authors.forename: M I N
authors.initials: MI
authors.lastname: da Silva
authors.forename: X S
authors.initials: XS
authors.lastname: Lozano
authors.forename: D
authors.initials: D
authors.lastname: Zanchet
authors.forename: D
authors.initials: D
authors.lastname: Ugarte
authors.forename: E
authors.initials: E
authors.lastname: Ribeiro
authors.forename: H R
authors.initials: HR
authors.lastname: Gutiérrez
authors.forename: M A
authors.initials: MA
authors.lastname: Cotta
mesh_terms: D003198:Computer Simulation; D003460:Crystallization / Q000379:methods*; D004548:Elasticity; D007204:Indium / Q000737:chemistry* / Q000528:radiation effects; D049449:Luminescence; D008422:Materials Testing; D008956:Models, Chemical; D008958:Models, Molecular; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000528:radiation effects / Q000648:ultrastructure*; D036103:Nanotechnology / Q000295:instrumentation / Q000379:methods; D055095:Optics and Photonics; D010316:Particle Size; D010720:Phosphines / Q000737:chemistry* / Q000528:radiation effects; D010777:Photochemistry / Q000295:instrumentation / Q000379:methods*; D013314:Stress, Mechanical; D013499:Surface Properties
chemical_list: D010720:Phosphines; D007204:Indium; C090882:indium phosphide