Discrete copper(I) clusters with Cu6P6Se6 and Cu6P4Se6 cores.
The reactions of chalcogenophosphinites with copper(I) metal salts are shown to yield highly stable, multi-metallic copper-chalcogen based clusters with novel topologies.
Davies
Robert P
RP
Department of Chemistry, Imperial College London, South Kensington, London, UK SW7 2AZ. r.davies@imperial.ac.uk
Martinelli
M Giovanna
MG
White
Andrew J P
AJ