title: High pressure co-ordination chemistry of a palladium thioether complex: pressure versus electrons.
abstract: The mononuclear Pd(ii) complex cis-[PdCl(2)([9]aneS(3))]([9]aneS(3)= 1,4,7-trithiacyclononane) converts at 44 kbar pressure into an intensely coloured chain polymer, which exhibits distorted octahedral co-ordination at the metal centre and an unprecedented [1233] conformation for the thioether crown.
authors.affiliation: School of Chemistry, The University of Edinburgh, The King's Buildings, UK.
authors.forename: David R
authors.initials: DR
authors.lastname: Allan
authors.forename: Alexander J
authors.initials: AJ
authors.lastname: Blake
authors.forename: Deguang
authors.initials: D
authors.lastname: Huang
authors.forename: Timothy J
authors.initials: TJ
authors.lastname: Prior
authors.forename: Martin
authors.initials: M
authors.lastname: Schröder