The reductive amination of aldehydes and ketones by catalytic use of dibutylchlorotin hydride complex.
The reductive amination of aldehydes or ketones using Ph(2)SiH(2) or PhSiH(3) has been effectively promoted by the direct use of Bu(2)SnClH-pyridine N-oxide as a catalyst; this method has advantages in terms of its mild conditions and wide application to various carbonyls and amines, including aliphatic examples.
Kato
Hirofumi
H
Department of Applied Chemistry, Center for Atomic and Molecular Technologies, CAMT, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
Shibata
Ikuya
I
Yasaka
Yuta
Y
Tsunoi
Shinji
S
Yasuda
Makoto
M
Baba
Akio
A