Excitation of magnetization using a modulated radiation damping field.
In this work, pulsed-field gradients are used to modulate the radiation damping field generated by the detection coil in an NMR experiment in order that spins with significantly different chemical shifts can affect one another via the radiation damping field. Experiments performed on solutions of acetone/water and acetone/DMSO/water demonstrate that spins with chemical shift differences much greater than the effective radiation damping field strength can still be coupled by modulating the radiation damping field. Implications for applications in high-field NMR and for developing sensitive magnetization detectors are discussed.
Walls
Jamie D
JD
Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, California 90095, USA.
Huang
Susie Y
SY
Lin
Yung-Ya
YY