Polymeric organometallic architectures of novel P-Se anions.
The characterisation of a series of compounds obtained from Woollins' reagent (W.R.) offers a novel approach to organometallic coordination polymers. The syntheses were achieved by nucleophilic ring-opening reactions of W.R. with metal salts and crystallisation using solvent-diffusion techniques. One-dimensional coordination polymers are formed as a result, and we demonstrate that the dimensionality of the polymers can be influenced by using hydrated metal salts or by the construction of heterometallic arrangements.
Shi
Weifeng
W
Institut für Anorganische Chemie, Universität Karlsruhe, Karlsruhe, Germany.
Shafaei-Fallah
Maryam
M
Zhang
Le
L
Anson
Christopher E
CE
Matern
Eberhard
E
Rothenberger
Alexander
A
D000838:Anions / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008672:Metals, Alkali / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000138:chemical synthesis / Q000737:chemistry; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D012643:Selenium / Q000737:chemistry; D018036:Selenium Compounds / Q000737:chemistry
D000838:Anions; D008672:Metals, Alkali; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D011108:Polymers; D018036:Selenium Compounds; D012643:Selenium