Ozonation of dyes and textile wastewater in a rotating packed bed.
This study investigates the ozonation of Reactive Red 120 and Acid Red 299 dyes in the synthesized solution and textile wastewater by using a rotating packed bed. The decomposition rate of Reactive Red 120 and Acid Red 299 dyes via ozonation can be described by the pseudo-first-order kinetics. Ozonation of Reactive Red 120 exhibited the higher mineralization rate compared with that of Acid Red 299. The biodegradability of the two dyes could be significantly promoted during the ozonation. The BOD5/TOC (5-day biological oxygen demand/total organic carbons) ratios of the ozonated Reactive Red 120 and Acid Red 299 solutions would increase and have the maximum values. Moreover, the oxidized textile wastewater revealed the fast decolorization and moderate COD (chemical oxidation demand) removal rates. The optimal ADMI (American Dye Manufactures Institute) and COD removal of the textile wastewater were 93% and 37% in 30 minutes ozonation time, respectively. The performance evaluation of ozonation in the rotating packed bed indicated that the higher water flow rate, gas ozone concentration and rotational rotating speed would increase the efficiency of mineralization.
Shang
Neng-Chou
NC
Graduate Institute of Environmental Engineering, National Taiwan University, Taipei, Taiwan. shangnc@ntu.edu.tw
Chen
Yi-Hung
YH
Yang
Yi-Ping
YP
Chang
Cheng-Hsin
CH
Yu
Yue-Hwa
YH
D001391:Azo Compounds / Q000737:chemistry; D004396:Coloring Agents / Q000737:chemistry*; D005069:Evaluation Studies as Topic; D007220:Industrial Waste; D007700:Kinetics; D008956:Models, Chemical; D010084:Oxidation-Reduction; D010126:Ozone / Q000737:chemistry*; D013624:Taiwan; D013783:Textile Industry; D014227:Triazines / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000295:instrumentation*
D001391:Azo Compounds; D004396:Coloring Agents; D007220:Industrial Waste; D014227:Triazines; D014874:Water Pollutants, Chemical; C042516:reactive red 120 dye; D010126:Ozone