Photolysis and photocatalysis of bisphenol A: identification of degradation products by liquid chromatography with electrospray ionization/time-of-flight/mass spectrometry (LC/ESI/ToF/MS).
Bisphenol A is a commonly known endocrine-disrupting compound detected in environmental water samples. The persistence of this compound has been studied by photolysis and photocatalysis studies. In this work, several experiments were performed in order to identify the degradation products under various conditions and in different types of matrices (deionized and waste water). These studies included the influence of sodium hypochlorite (NaClO), commonly present in drinking water, on the generation of chlorine by-products of bisphenol A. The effect of catalyses in solar degradation studies was evaluated as well. The identification of the degradation products was accomplished by liquid chromatography/time-of-flight/mass spectrometry (LC-ToF-MS), which provided highly selective information about elemental compositions. Accurate mass measurements for three main degradation products permitted the postulation of proposed empirical formula in this study. Some of the degradation products were formed in waste water matrices, thus suggesting their potential presence in environmental conditions and in drinking water.
Mezcua
M
M
Department of Analytical Chemistry, University of Almería, Carretera Sacramenta s/n, La Cañada de San Urbano, 04120 Almería, Spain. mmezcua@ual.es
Ferrer
I
I
Hernando
M D
MD
Fernández-Alba
A R
AR
D001559:Benzhydryl Compounds; D002853:Chromatography, Liquid / Q000379:methods*; D013058:Mass Spectrometry / Q000379:methods*; D008970:Molecular Weight; D010636:Phenols / Q000737:chemistry / Q000528:radiation effects*; D010777:Photochemistry; D015203:Reproducibility of Results; D014466:Ultraviolet Rays; D014865:Waste Disposal, Fluid; D000098826:Bisphenol A Compounds
D001559:Benzhydryl Compounds; D010636:Phenols; C006780:bisphenol A; D000098826:Bisphenol A Compounds