Inverse characterization of NAPL source zones.
This work presents a possible tool for inverse characterization of NAPL (nonaqueous phase liquid) source zones in terms of contaminant mass flux. A hybrid solution technique was applied that considers contaminant transport through a vertical flux plane. The hybrid solution technique takes advantage of the robust solution capabilities of simulated annealing (SA) and the uncertainty estimation capabilities of minimum relative entropy (MRE). The coupled technique (SA-MRE) provides probability density functions and confidence intervals that would not be available from an independent SA algorithm, and they are obtained more efficiently than if provided by an independent MRE algorithm. The SA-MRE method was used to characterize a NAPL source zone that was emplaced in a three-dimensional aquifer model. When dissolution experiments were complete, the aquifer model was excavated, and the distribution of NAPL zones was recorded using digital images of excavation grids. The excavation images were compiled into a three-dimensional representation of the source zone for comparison with and validation of modeling results.
Newman
Mark A
MA
Department of Civil and Coastal Engineering, University of Florida, Gainesville 32611-6450, USA. markn@ce.ufl.edu
Hatfield
Kirk
K
Hayworth
Joel
J
Rao
P Suresh C
PS
Stauffer
Tom
T
D000473:Alkanes / Q000032:analysis*; D008962:Models, Theoretical; D013750:Tetrachloroethylene / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014881:Water Supply
D000473:Alkanes; D014874:Water Pollutants, Chemical; C007932:n-hexadecane; D013750:Tetrachloroethylene