A rare and highly oxidized Mo(2)5.5+ unit stabilized by oxo anions and supported by formamidinate bridges.
A series of tetranuclear compounds consisting of two {Mo2[(m-CF3C6H4)NC(H)N(m-CF3C6H4)]3}n+ moieties linked by two OH- or two O2- ions has been characterized. Abbreviating the dimolybdenum plus three spectator bridging ligands as [Mo2], the following three compounds have been made-[Mo2](mu-OH)2[Mo2] (1), [Mo2](mu-O)2[Mo2] (2), and {[Mo2](mu-O)2[Mo2]}SbF6 (3). Compound 1, which is diamagnetic and contains quadruply bonded Mo2(4+) units, is converted to diamagnetic 2 by oxidation with O2. Compound 2, which has Mo2(5+) units, is oxidized by NOSbF6 to 3 which has a rare Mo2(5.5+) core and an odd electron delocalized over the two dimolybdenum units.
Cotton
F Albert
FA
Department of Chemistry and Laboratory for Molecular Structure and Bonding, P.O. Box 3012, Texas A&M University, College Station, Texas 77842-3012, USA. cotton@tamu.edu
Murillo
Carlos A
CA
Yu
Rongmin
R
Zhao
Qinliang
Q
D004578:Electron Spin Resonance Spectroscopy; D005559:Formamides / Q000138:chemical synthesis / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011199:Potentiometry; D011789:Quantum Theory; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet
D005559:Formamides; D009942:Organometallic Compounds; D008982:Molybdenum