title: Self-assembly of a bis-porphyrinic supramolecular rectangle using two orthogonal binding strategies.
abstract: A bis-porphyrinic rectangle is created via a double self-assembly algorithm using two orthogonal coordination themes, i.e. first a 90 degrees building block composed of a dynamic heteroleptic Cu(I) or Ag(I) bisphenanthroline followed by a coordinative dimerization using the pyridine-zinc porphyrin motif; the spectroscopic and electrochemical properties as well as the dynamic nature of the supramolecule were tested.
authors.affiliation: Center of Micro and Nanochemistry and Engineering, Organische Chemie I, Universität Siegen, Adolf-Reichwein-Str., D-57068 Siegen, Germany.
authors.forename: Ravuri S K
authors.initials: RS
authors.lastname: Kishore
authors.forename: Venkateshwarlu
authors.initials: V
authors.lastname: Kalsani
authors.forename: Michael
authors.initials: M
authors.lastname: Schmittel
mesh_terms: D000465:Algorithms; D003300:Copper / Q000737:chemistry; D019281:Dimerization; D004563:Electrochemistry; D046911:Macromolecular Substances / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D012680:Sensitivity and Specificity; D012834:Silver / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
chemical_list: D046911:Macromolecular Substances; D009942:Organometallic Compounds; D011166:Porphyrins; D012834:Silver; D003300:Copper; D015032:Zinc