Coordination polymers undergoing spin crossover and reversible ligand exchange in the solid.
Here we report the synthesis and characterisation of a polymer made up of a system of parallel 2-D grids of Fe(II) ions linked by [Au(CN)2]- bridges and its transformation into a new system of three interpenetrated 3-D coordination open frameworks with the NbO topology. Reversibility of this crystal-to-crystal transformation is evidenced by X-ray crystallographic data and from their spin crossover properties.
Galet
Ana
A
Departament de Física Aplicada, Universitat Politécnica de València, Camino de Vera s/n, 46022, Valencia, Spain.
Muñoz
M Carmen
MC
Real
José Antonio
JA