Fe(III) homogeneous photocatalysis for the removal of 1,2-dichlorobenzene in aqueous solution by means UV lamp and solar light.
Chlorinated hydrocarbons are widely used in chemical industries as solvents and intermediates for pesticides and dyes manufacture. Their presence was documented in rivers, groundwaters and seawaters. In this work, the oxidation of 1,2-dichlorobenzene in aqueous solutions by means of Fe(III) homogeneous photocatalysis under UV lamp and sunlight irradiations is studied. The results show that the best working conditions are found for pH=3.0 and initial [Fe(III)] concentration equal to 1.0x10(-4) molL(-1) although the investigated system can be utilized even at pH close to 4.0 but with slower abatement kinetics. Some dicholoroderivatives, such as 2,3-dichlorophenol, 3,4-dichlorophenol and 2-chlorophenol, are identified as oxidation intermediates. The values of the kinetic constant for the photochemical reoxidation of Fe(II) to Fe(III) are evaluated by a mathematical model in the range 1.58-3.78 Lmol(-1)s(-1) and 0.69-0.78 Lmol(-1)s(-1) for the systems irradiated by UV lamp and sunlight, respectively.
Andreozzi
Roberto
R
Università degli Studi di Napoli Federico II, Facoltà di Ingegneria, Dipartimento di Ingegneria Chimica, p.le V. Tecchio, 80-80125 Napoli, Italy.
Canterino
Marisa
M
Marotta
Raffaele
R
D002384:Catalysis; D002722:Chlorobenzenes / Q000737:chemistry / Q000302:isolation & purification* / Q000528:radiation effects; D007501:Iron / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry / Q000302:isolation & purification / Q000528:radiation effects; D013472:Sunlight; D014466:Ultraviolet Rays; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000302:isolation & purification* / Q000528:radiation effects; D018508:Water Purification / Q000379:methods
D002722:Chlorobenzenes; D012997:Solvents; D014874:Water Pollutants, Chemical; C004726:2-dichlorobenzene; D007501:Iron