Self-assembly of square-planar halide complexes of phosphine-stabilised stibenium salts.
Chloride and bromide ions direct the self-assembly of supramolecular square-planar halide complexes in which four trimethylphosphine-stabilised diphenylstibenium ions surround the central halide ion in discrete centrosymmetrical structures of C(4h) symmetry.
Wielandt
J Wolfram
JW
Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory 0200, Australia.
Kilah
Nathan L
NL
Willis
Anthony C
AC
Wild
S Bruce
SB
D000965:Antimony / Q000737:chemistry*; D001965:Bromides / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010720:Phosphines / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013237:Stereoisomerism
D001965:Bromides; D002712:Chlorides; D009942:Organometallic Compounds; D010720:Phosphines; D000965:Antimony; C044646:phosphine