Polysilane-supported Pd and Pt nanoparticles as efficient catalysts for organic synthesis.
Polysilane-supported Pd and Pt catalysts have been prepared for the first time, and used successfully in hydrogenation, Suzuki and Sonogashira reactions, and hydrosilylation respectively: the reactions proceeded in high yields, and the catalysts could be recovered almost quantitatively by simple filtration and reused.
Oyamada
Hidekazu
H
Science of Process Laboratories, The HFRE Division, ERATO, Japan Science and Technology Agency (JST), Matoba, Kawagoe, Saitama 350-1101, Japan.
Akiyama
Ryo
R
Hagio
Hiroyuki
H
Naito
Takeshi
T
Kobayashi
Shū
S
D002384:Catalysis; D006865:Hydrogenation; D053758:Nanoparticles; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D010984:Platinum / Q000737:chemistry*; D012828:Silicones / Q000737:chemistry*
D009942:Organometallic Compounds; D012828:Silicones; D010984:Platinum; D010165:Palladium