Coexistence of spin canting and metamagnetism in a one-dimensional Mn(III) complex bridged by a single end-to-end azide.
Two manganese(III) azide complexes capped with tetradentate Schiff bases were characterized structurally and magnetically. The replacement of halogens on the Schiff bases leads to a drastic structural alteration from a dimer (1) bridged by phenoxide to a one-dimensional chain (2) linked by azide in a single end-to-end mode. Notably, magnetic studies of 2 show the concomitant existence of spin canting and metamagnetism.
Ko
Hyun Hee
HH
Department of Chemistry and Center for Electro- and Photo-Responsive Molecules, Korea University, Seoul 136-701, Korea.
Lim
Jeong Hak
JH
Kim
Hyoung Chan
HC
Hong
Chang Seop
CS