title: Dirhodium tetracarboxylates derived from adamantylglycine as chiral catalysts for enantioselective C-h aminations.
abstract: The dirhodium tetracarboxylate, Rh(2)(S-TCPTAD)(4), derived from adamantylglycine, is an effective chiral catalyst for both inter- and intramolecular C-H aminations. [reaction: see text]
authors.affiliation: Department of Chemistry, University at Buffalo, State University of New York, Buffalo, NY 14260-3000, USA.
authors.forename: Ravisekhara P
authors.initials: RP
authors.lastname: Reddy
authors.forename: Huw M L
authors.initials: HM
authors.lastname: Davies
mesh_terms: D000218:Adamantane / Q000031:analogs & derivatives* / Q000737:chemistry; D000586:Amination; D002384:Catalysis; D005998:Glycine / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D009942:Organometallic Compounds; C519986:dirhodium tetracarboxylate; D012238:Rhodium; D000218:Adamantane; D005998:Glycine