Mononuclear copper(II)-hydroperoxo complex derived from reaction of copper(I) complex with dioxygen as a model of DbetaM and PHM.
A mononuclear copper(II)-hydroperoxo species has been generated by the reaction of Cu(I)-H2BPPA complex with dioxygen, which illustrates the enzymatic reaction process of the CuB site in the DbetaM and PHM.
Fujii
Tatsuya
T
Department of Applied Chemistry, Nagoya Institute of Technology, Showa-ku, Nagoya, 466-8555, Japan.
Yamaguchi
Syuhei
S
Funahashi
Yasuhiro
Y
Ozawa
Tomohiro
T
Tosha
Takehiko
T
Kitagawa
Teizo
T
Masuda
Hideki
H