title: Pentachlorophenol association with fulvic acids from recycled wastes.
abstract: The apparent water solubility of pentachlorophenol was measured at pH=6 and at 25 degrees C in pure water, aqueous solutions of three salts (NaCl, KNO(3) and CaCl(2) at 0.010, 0.10 and 1.0M) and in aqueous solutions of three fulvic acids samples extracted from a natural soil (sFA), composted sewage sludge (csFA) and composted livestock's material (lsFA). A solubility enhancement method was developed for the measurement of partition coefficients (K(oc), L/kg organic carbon). Pentachlorophenol associates strongly with the fulvic acid samples and the calculated K(oc) were the following (averages and standard deviations): (sFA) (211+/-22) x 10(2), (csFA) (253+/-26) x 10(2), (lsFA) (235+/-10) x 10(2). For comparison purposes the K(oc) for pyrene were also calculated for the three FA samples and were the following: (sFA) (119+/-10) x 10(2), (csFA) (239+/-21) x 10(2), (lsFA) (92+/-10) x 10(2). The analysis of variance (one-way ANOVA) of the effect of the type of FA sample on the solubilization of pentachlorophenol and pyrene shows that this factor causes significant differences on the aqueous solubilization of these two organic substances.
authors.affiliation: Centro de Investigação em Química, Departamento de Química, Faculdade de Ciências, Universidade do Porto, R. Campo Alegre 687, 4169-007 Porto, Portugal. jcsilva@fc.up.pt <jcsilva@fc.up.pt>
authors.forename: Joaquim C G
authors.initials: JC
authors.lastname: Esteves da Silva
authors.forename: Miguel C P O
authors.initials: MC
authors.lastname: Marques
mesh_terms: D001578:Benzopyrans / Q000737:chemistry*; D004784:Environmental Monitoring / Q000379:methods*; D010416:Pentachlorophenol / Q000737:chemistry*; D010573:Pesticide Residues / Q000737:chemistry*; D011721:Pyrenes / Q000737:chemistry; D012037:Refuse Disposal; D012989:Soil Pollutants / Q000737:chemistry*; D012995:Solubility
chemical_list: D001578:Benzopyrans; D010573:Pesticide Residues; D011721:Pyrenes; D012989:Soil Pollutants; C030984:pyrene; D010416:Pentachlorophenol; C005023:fulvic acid