Chiral sensing for amino acid derivative based on a [2]rotaxane composed of an asymmetric rotor and an asymmetric axle.
A racemic [2]rotaxane, composed of an asymmetric rotor and an asymmetric axle, formed a diastereomer with an amino acid derivative, and showed an optical response for the chiral recognition.
Kameta
Naohiro
N
Nanoarchitectonics Research Center, National Institute of Advanced Industrial Science and Technology, Tsukuba Central 5, 1-1-1 Higashi, Tsukuba, Ibaraki 305-8565, Japan. n-kameta@aist.go.jp
Nagawa
Yoshinobu
Y
Karikomi
Michinori
M
Hiratani
Kazuhisa
K
D000596:Amino Acids / Q000737:chemistry*; D015394:Molecular Structure; D043862:Rotaxanes / Q000737:chemistry*; D013237:Stereoisomerism
D000596:Amino Acids; D043862:Rotaxanes