title: High-sensitivity transmission IR spectroscopy for the chemical identification and structural analysis of conjugated molecules on gallium arsenide surfaces.
abstract: We demonstrate the use of high-sensitivity, off-normal transmission IR spectroscopy with s-polarized light to probe the chemical identity and orientation of quaterphenyldithiol (QPDT) molecular assemblies on GaAs as a function of ammonium hydroxide (NH4OH) concentration. NH4OH is added to the assembly solution to convert the thioacetyl groups on the QPDT precursor to thiolates. When assembled at high NH4OH concentrations, the acetyl groups are completely removed, and QPDT is disordered on GaAs. Assembly at low NH4OH concentrations, however, results in QPDT assemblies that are preferentially upright. The molecular orientation is further quantified with near-edge X-ray absorption fine structure spectroscopy.
authors.affiliation: Chemical Engineering Department and Center for Nano- and Molecular Science and Technology, University of Texas at Austin, Austin, Texas 78712, USA.
authors.forename: Dmitry A
authors.initials: DA
authors.lastname: Krapchetov
authors.forename: Hong
authors.initials: H
authors.lastname: Ma
authors.forename: Alex K Y
authors.initials: AK
authors.lastname: Jen
authors.forename: Daniel A
authors.initials: DA
authors.lastname: Fischer
authors.forename: Yueh-Lin
authors.initials: YL
authors.lastname: Loo