Nickel catalyzed Grob fragmentation: Omega-dienyl aldehydes synthesis.
With a proper choice of phosphane ligands, a Ni(cod)2-phosphane catalyst promotes decarboxylative ring-opening reaction of a wide structural variety of cyclic carbonates to give omega-dienyl aldehydes in good yields.
Mori
Masahiko
M
Graduate School of Science and Technology, Nagasaki University, 1-14 Bunkyo, Nagasaki, 852-8521, Japan.
Kimura
Masanari
M
Takahashi
Yushi
Y
Tamaru
Yoshinao
Y