Synthesis of functionalized thia analogues of phlorins and covalently linked phlorin-porphyrin dyads.
The 21,23-dithia and 21-thia analogues of phlorins and mono-functionalized thiaphlorins were synthesized using easily available precursors and the mono-functionalized thiaphlorins were used further to synthesize the first examples of three covalently linked thiaphlorin-porphyrin dyads.
Gupta
Iti
I
Department of Chemistry, Indian Institute of Technology, Mumbai, India.
Fröhlich
Roland
R
Ravikanth
M
M
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D011166:Porphyrins / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis* / Q000737:chemistry*
D011166:Porphyrins; D013438:Sulfhydryl Compounds; C008870:phlorin porphyrin