title: Effect of operating conditions on the removal of Pb2+ by microporous titanosilicate ETS-10 in a fixed-bed column.
abstract: The breakthrough behavior of Pb2+ in an ETS-10 fixed bed was experimentally examined at various operating conditions. Results showed that the adsorption amount of Pb2+ ions per unit mass of ETS-10 particles in a column is about 1.68 mmol/g under the experimental conditions. This amount was not markedly affected by the operating conditions because of the rapid adsorption rate of Pb2+ ions on ETS-10. In the presence of competitive metal ions, the amount of Pb2+ adsorbed on ETS-10 was slightly reduced. An overshoot of the effluent concentrations of competitive metal ions Cu2+ and Cd2+ was observed in the adsorption systems of binary and ternary solutions. This is ascribed to the replacement of pre-adsorbed Cu2+ and Cd2+ ions by Pb2+ ions. The ETS-10 column broken up by Pb2+ ions can be regenerated by using an EDTA-Na2 solution and the regenerated column can be reused.
authors.affiliation: Department of Chemical & Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117576 Singapore.
authors.forename: Lu
authors.initials: L
authors.lastname: Lv
authors.forename: Kean
authors.initials: K
authors.lastname: Wang
authors.forename: X S
authors.initials: XS
authors.lastname: Zhao