Self-assembly of a bis-porphyrinic supramolecular rectangle using two orthogonal binding strategies.
A bis-porphyrinic rectangle is created via a double self-assembly algorithm using two orthogonal coordination themes, i.e. first a 90 degrees building block composed of a dynamic heteroleptic Cu(I) or Ag(I) bisphenanthroline followed by a coordinative dimerization using the pyridine-zinc porphyrin motif; the spectroscopic and electrochemical properties as well as the dynamic nature of the supramolecule were tested.
Kishore
Ravuri S K
RS
Center of Micro and Nanochemistry and Engineering, Organische Chemie I, Universität Siegen, Adolf-Reichwein-Str., D-57068 Siegen, Germany.
Kalsani
Venkateshwarlu
V
Schmittel
Michael
M
D000465:Algorithms; D003300:Copper / Q000737:chemistry; D019281:Dimerization; D004563:Electrochemistry; D046911:Macromolecular Substances / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D012680:Sensitivity and Specificity; D012834:Silver / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
D046911:Macromolecular Substances; D009942:Organometallic Compounds; D011166:Porphyrins; D012834:Silver; D003300:Copper; D015032:Zinc