title: A proposal for a convenient notation for P-chiral nucleotide analogues. Part 2. Dinucleoside monophosphate analogues.
abstract: A configuration of ligands around a phosphorus atom in P-chiral dinucleoside monophosphate analogues can be described using DP/LP stereochemical notation, which allows immediate correlation between the notation of configuration and the actual spatial arrangement of the phosphorus ligands. The area of applications of this new stereochemical nomenclature covers dinucleoside units bridged by virtually any type of tri-and tetra-coordinated phosphorus moieties, that is, phosphorothioates, phosphoramidates, phosphoramidites, boranephosphates, methanephosphonates, H-phosphonates, and many others.
authors.affiliation: Institute of Bioorganic Chemistry, Polish Academy of Sciences, Poznan, Poland. msob@ibch.poznan.pl
authors.forename: Michal
authors.initials: M
authors.lastname: Sobkowski
authors.forename: Jacek
authors.initials: J
authors.lastname: Stawinski
authors.forename: Adam
authors.initials: A
authors.lastname: Kraszewski
mesh_terms: D002621:Chemistry / Q000379:methods*; D015226:Dinucleoside Phosphates / Q000737:chemistry*; D008024:Ligands; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure; D009705:Nucleosides / Q000737:chemistry*; D009711:Nucleotides / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry; D011993:Recombinant Fusion Proteins / Q000737:chemistry; D013237:Stereoisomerism; D009626:Terminology as Topic
chemical_list: D015226:Dinucleoside Phosphates; D008024:Ligands; D009705:Nucleosides; D009711:Nucleotides; D011993:Recombinant Fusion Proteins; D010100:Oxygen