Tetrametallic rectangular box complexes assembled from heteroligated macrocycles.
The reaction of a heteroligated Rh(I) bimetallic macrocycle with rigid ditopic ligands (1,4-dicyanobenzene, 4-4'-dicyanobiphenyl, or dipyridyl terminated salen ligand 5) results in the formation of tetrametallic rectangular box complexes.
Brown
Aaron M
AM
Department of Chemistry and the International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208, USA.
Ovchinnikov
Maxim V
MV
Stern
Charlotte L
CL
Mirkin
Chad A
CA
D003300:Copper / Q000737:chemistry; D008024:Ligands; D047028:Macrocyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D008956:Models, Chemical; D008958:Models, Molecular; D015394:Molecular Structure; D010984:Platinum / Q000737:chemistry; D012211:Rhenium / Q000737:chemistry*; D012834:Silver / Q000737:chemistry
D008024:Ligands; D047028:Macrocyclic Compounds; D012834:Silver; D010984:Platinum; D012211:Rhenium; D003300:Copper