In situ investigation of the oxidative addition in homogeneous Pd catalysts by synchronised time resolved UV-Vis/EXAFS.
Simultaneous structuro-kinetic information obtained via time resolved stopped-flow/UV-Vis spectroscopy/dispersive EXAFS (EDE) experiments elucidated a two-step process for the addition of iodobenzene to [(Ph3P)2Pd(dba)].
Guilera
Gemma
G
European Synchrotron Radiation Facility (ESRF, ID24), PO Box 220, 38043 Grenoble Cedex, France. guilera@esrf.fr
Newton
Mark A
MA
Polli
Charlene
C
Pascarelli
Sakura
S
Guinó
Meritxell
M
Hii
King Kuok
KK
Hii
King Kuog
KK