Synthesis of a [2]rotaxane through first- and second-sphere coordination.
In an effort to expand the application of a new template from interpenetrated to interlocked molecular species, we report the synthesis of a new [2]rotaxane by means of both first- and second-sphere coordination of a palladium(II) dichloride subunit.
Blight
Barry A
BA
Department of Chemistry, The University of Western Ontario, Chemistry Building, London, ON, CanadaN6A 5B7.
Wisner
James A
JA
Jennings
Michael C
MC
D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D010165:Palladium / Q000737:chemistry; D043862:Rotaxanes / Q000138:chemical synthesis* / Q000737:chemistry; D012680:Sensitivity and Specificity
D043862:Rotaxanes; D010165:Palladium; C008756:palladium chloride