title: Dirhodium(II) tetrakis(perfluorobutyrate)-catalyzed 1,4-hydrosilylation of alpha,beta-unsaturated carbonyl compounds.
abstract: The use of dirhodium(II) catalysts in the 1,4-hydrosilylation of alpha,beta-unsaturated ketones and aldehydes was explored. Dirhodium(II) tetrakis(perfluorobutyrate), Rh2(pfb)4, proved to be the catalyst of choice for this process, providing the corresponding silyl enol ethers in high yields.
authors.affiliation: Faculty of Pharmaceutical Sciences, Hokkaido University, Sapporo, Japan.
authors.forename: Masahiro
authors.initials: M
authors.lastname: Anada
authors.forename: Masahiko
authors.initials: M
authors.lastname: Tanaka
authors.forename: Kanami
authors.initials: K
authors.lastname: Suzuki
authors.forename: Hisanori
authors.initials: H
authors.lastname: Nambu
authors.forename: Shunichi
authors.initials: S
authors.lastname: Hashimoto
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D002384:Catalysis; D005466:Fluorocarbons / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D000447:Aldehydes; D005466:Fluorocarbons; D007659:Ketones; D009942:Organometallic Compounds; D012821:Silanes; D014753:Vinyl Compounds; C100195:vinyl ether; D012238:Rhodium