Bis[bis(2-pyridylcarbonyl)aminato]iron(III) perchlorate acetonitrile disolvate.
The title compound, [Fe(C12H8N3O2)2]ClO4.2C2H3N, contains Fe(III) in a distorted octahedral coordination environment, with the Fe-N(pyridine) bonds significantly longer than the Fe-N(amine) bonds. The crystal packing involves a bifurcated C-H...(O,O) contact that is also found in all other [M(C12H8N3O2)2] complexes reported previously.
Kooijman
Huub
H
Crystal and Structural Chemistry, Bijvoet Center for Biomolecular Research, Faculty of Science, Utrecht University, Padualaan 8, 3584 CH Utrecht, The Netherlands. h.kooijman@chem.uu.nl
Tanase
Stefania
S
Bouwman
Elisabeth
E
Reedijk
Jan
J
Spek
Anthony L
AL
D000097:Acetonitriles / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005290:Ferric Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D007477:Ions; D007501:Iron / Q000737:chemistry; D008024:Ligands; D008968:Molecular Conformation; D010472:Perchlorates / Q000737:chemistry
D000097:Acetonitriles; D005290:Ferric Compounds; D007477:Ions; D008024:Ligands; D010472:Perchlorates; C517845:bis(bis(2-pyridylcarbonyl)aminato)iron(III) perchlorate acetonitrile; D007501:Iron; C494474:perchlorate; C032159:acetonitrile