Synthesis of ferrites obtained from heavy metal solutions using wet method.
Wet method was employed to the treatment of heavy metal-contaminated wastewater, and Zn(x)Fe(3-x)O(4), Ni(x)Fe(3-x)O(4) and Cr(x)Fe(3-x)O(4) (0<x<1) were synthesized. Phase identification of the prepared samples was done by X-ray diffraction (XRD), which indicates that the products are spinel-structured; transmission electron microscopy (TEM) images show that crystal size of the ferrite products synthesized is 0.1-0.4 microm. Thermostability of the products was characterized by differential thermal analysis (DTA) and thermal gravimetric analysis (TGA). It was found that when the doped ferrite is qualified, the highest content of doped ion (Zn(2+), Ni(2+) and Cr(3+)) that could enter ferrite lattice is: 0.08, 0.049 and 0.02, respectively. At low concentration the capability of doped ions entering ferrite product is Ni(2+) approximately Zn(2+)>Cr(3+) and the influence of the three ions on sample thermostability is Zn(2+)>Ni(2+)>Cr(3+).
Yang
Ji
J
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, PR China. yangji@sjtu.edu.cn
Peng
Juan
J
Liu
Kaicheng
K
Guo
Rui
R
Xu
Dianliang
D
Jia
Jinping
J
D002857:Chromium / Q000737:chemistry*; D003460:Crystallization; D004055:Differential Thermal Analysis; D005290:Ferric Compounds / Q000138:chemical synthesis*; D009532:Nickel / Q000737:chemistry*; D014865:Waste Disposal, Fluid / Q000379:methods*; D014961:X-Ray Diffraction; D015032:Zinc / Q000737:chemistry*
D005290:Ferric Compounds; D002857:Chromium; C001215:ferrite; D009532:Nickel; D015032:Zinc