catena-Poly[[[tetrakis(mu-acetato-kappa2O:O')dirhodium(II)]-mu-[1,3-bis(dimethylamino)propan-2-ol-kappa2N:N']] tetrahydrofuran hemisolvate].
In the structure of the title compound, {[Rh2(C2H3O2)4(C7H18N2O)].0.5C4H8O}n or {[Rh2(O2CMe)4(Hbdmap)].0.5C4H8O}n, where Hbdmap is 1,3-bis(dimethylamino)propan-2-ol, each Hbdmap ligand is coordinated to two [Rh2(O2CMe)4] units by two N atoms, resulting in a polymeric chain structure. The observed coordination mode of the Hbdmap molecule is unprecedented.
Pevec
Andrej
A
Faculty of Chemistry and Chemical Technology, University of Ljubljana, Askerceva 5, 1000 Ljubljana, Slovenia.
Demsar
Alojz
A
Aoki
Katsuyuki
K
Turel
Iztok
I