Kinetics of bond formation in cross-linked gelatin gels.
In chemical cross-linking of gelatin solutions, two different time scales affect the kinetics of the gel formation in the experiments. We complement the experimental study with Monte Carlo numerical simulations of a lattice model. This approach shows that the two characteristic time scales are related to the formation of single bond cross-linker-chain and of bridges between chains. In particular, their ratio turns out to control the kinetics of the gel formation. We discuss the effect of the concentration of chains. Finally our results suggest that by varying the probability of forming bridges as an independent parameter, one can finely tune the kinetics of the gelation via the ratio of the two characteristic times.
Abete
T
T
Department of Physical Sciences, University of Naples Federico II, 80125 Naples, Italy. abete@na.infn.it
Del Gado
E
E
Serughetti
D Hellio
DH
de Arcangelis
L
L
Djabourov
M
M
Coniglio
A
A
D002151:Calorimetry; D003432:Cross-Linking Reagents / Q000737:chemistry*; D005780:Gelatin / Q000737:chemistry*; D005782:Gels / Q000737:chemistry*; D007700:Kinetics; D008956:Models, Chemical; D009010:Monte Carlo Method; D044367:Phase Transition; D011336:Probability
D003432:Cross-Linking Reagents; D005782:Gels; D005780:Gelatin