title: Photochemical asymmetric synthesis of phenyl-bearing quaternary chiral carbons using chiral-memory effect on beta-hydrogen abstraction by thiocarbonyl group.
abstract: Quaternary chiral carbons were effectively generated from tertiary chiral carbons via photochemical intramolecular beta-hydrogen abstraction reaction of thioimides involving the highly-controlled chiral-memory effect.
authors.affiliation: Department of Applied Chemistry and Biotechnology, Faculty of Engineering, Chiba University, Yayoi-cho, Inage-ku, Chiba, 263-8522, Japan. sakamotom@faculty.chiba-u.jp
authors.forename: Masami
authors.initials: M
authors.lastname: Sakamoto
authors.forename: Hiroya
authors.initials: H
authors.lastname: Kawanishi
authors.forename: Takashi
authors.initials: T
authors.lastname: Mino
authors.forename: Yoshio
authors.initials: Y
authors.lastname: Kasashima
authors.forename: Tsutomu
authors.initials: T
authors.lastname: Fujita