Self-exchange electron transfer in high oxidation state non-oxo metal complexes: amavadin.
The electron transfer self-exchange rate constant between the oxidized and reduced forms of amavadin equals approximately 1 x 10(5) dm3 mol(-1) s(-1) at 25 degrees C and represents the first unambiguous example for a vanadium(IV/V) couple.
Lenhardt
Jeremy
J
Department of Chemistry and Biochemistry, New Mexico State University, Las Cruces, New Mexico, USA.
Baruah
Bharat
B
Crans
Debbie C
DC
Johnson
Michael D
MD
D000409:Alanine / Q000031:analogs & derivatives* / Q000737:chemistry; D004583:Electrons; D006863:Hydrogen-Ion Concentration; D006877:Hydroxamic Acids / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods / Q000592:standards; D010084:Oxidation-Reduction; D012015:Reference Standards
D006877:Hydroxamic Acids; C502921:N-hydroxyimino-2,2'-dipropionic acid; D000409:Alanine