title: Novel expansion/shrinkage modulation of 2D layered MOF triggered by clathrate formation with CO(2) molecules.
abstract: Crystal-to-crystal transformation from a 3D interpenetrated-type MOF {[Cu(BF(4))(2)(bpy)(H(2)O)(2)] (bpy)} (1) to a 2D square-grid-type [Cu(BF(4))(2)(bpy)(2)] (2) (bpy = 4,4'-bipyridine) was observed. It was derived from dehydration and confirmed by in situ FT-IR, TG, and elemental analysis. Moreover, we elucidate the novel expansion/shrinkage dynamic modulation of 2 triggered by clathrate formation with gas molecules.
authors.affiliation: Graduate School of Science and Technology, Chiba University, Yayoi, Inage, Chiba 263-8522, Japan.
authors.forename: Atsushi
authors.initials: A
authors.lastname: Kondo
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Noguchi
authors.forename: Shunsuke
authors.initials: S
authors.lastname: Ohnishi
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Kajiro
authors.forename: Aya
authors.initials: A
authors.lastname: Tohdoh
authors.forename: Yoshiyuki
authors.initials: Y
authors.lastname: Hattori
authors.forename: Wei-Chun
authors.initials: WC
authors.lastname: Xu
authors.forename: Hideki
authors.initials: H
authors.lastname: Tanaka
authors.forename: Hirofumi
authors.initials: H
authors.lastname: Kanoh
authors.forename: Katsumi
authors.initials: K
authors.lastname: Kaneko
mesh_terms: D000327:Adsorption; D002245:Carbon Dioxide / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D003460:Crystallization; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D033362:Powder Diffraction; D013499:Surface Properties
chemical_list: D009942:Organometallic Compounds; D002245:Carbon Dioxide; D003300:Copper