title: Synthesis of a [2]rotaxane through first- and second-sphere coordination.
abstract: In an effort to expand the application of a new template from interpenetrated to interlocked molecular species, we report the synthesis of a new [2]rotaxane by means of both first- and second-sphere coordination of a palladium(II) dichloride subunit.
authors.affiliation: Department of Chemistry, The University of Western Ontario, Chemistry Building, London, ON, CanadaN6A 5B7.
authors.forename: Barry A
authors.initials: BA
authors.lastname: Blight
authors.forename: James A
authors.initials: JA
authors.lastname: Wisner
authors.forename: Michael C
authors.initials: MC
authors.lastname: Jennings
mesh_terms: D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D010165:Palladium / Q000737:chemistry; D043862:Rotaxanes / Q000138:chemical synthesis* / Q000737:chemistry; D012680:Sensitivity and Specificity
chemical_list: D043862:Rotaxanes; D010165:Palladium; C008756:palladium chloride