Oxidative photo-decarboxylation in the presence of mesoporous silicas.
FSM-16, a mesoporous silica, was found to catalyze oxidative photo-decarboxylation of alpha-hydroxy carboxylic acid, phenyl acetic acid derivatives and N-acyl-protected alpha-amino acids to afford the corresponding carbonyl compounds. Furthermore, FSM-16 proved to be re-usable by re-calcination at 450 degrees C after the reaction.
Itoh
Akichika
A
Gifu Pharmaceutical University, Mitahora-higashi, Gifu, Japan. itoha@gifu-pu.ac.jp
Kodama
Tomohiro
T
Masaki
Yukio
Y
Inagaki
Shinji
S
D000085:Acetates / Q000737:chemistry*; D000447:Aldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D000596:Amino Acids / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D002384:Catalysis; D003653:Decarboxylation; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010777:Photochemistry; D016062:Porosity; D012822:Silicon Dioxide / Q000737:chemistry*
D000085:Acetates; D000447:Aldehydes; D000596:Amino Acids; D002264:Carboxylic Acids; D007659:Ketones; D012822:Silicon Dioxide