Cyclic C-amino phosphorus ylides as a source of bidentate heteroditopic ligands (phosphine/aminocarbene) for transition metals.
In contrast with most of their congeners, acyclic and cyclic C-amino phosphorus ylides behave as genuine carbene and phosphine transfer agents for transition metal centers. They allow the facile synthesis of a variety of metal complexes that feature heteroditopic ligands, such as 1,6-(phosphine)(aminocarbene) systems with a biphenyl backbone.
Vignolle
Joan
J
UCR-CNRS Joint Research Chemistry Laboratory (UMI 2957), Department of Chemistry, University of California-Riverside, Riverside, CA 92521-0403, USA.
Donnadieu
Bruno
B
Bourissou
Didier
D
Soleilhavoup
Michèle
M
Bertrand
Guy
G
D000480:Alkynes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004148:Dioxolanes / Q000737:chemistry*; D008024:Ligands; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D010720:Phosphines / Q000737:chemistry*; D010758:Phosphorus / Q000737:chemistry*
D000480:Alkynes; D004148:Dioxolanes; D008024:Ligands; D008670:Metals; D010720:Phosphines; C504703:aminocarbene; D010758:Phosphorus; C044646:phosphine