Manganese(III) acetate promoted regioselective phosphonation of heteroaryl compounds.
[Structure: see text] A new method for direct phosphonation of thiazoles, furans, and pyrroles is introduced. Reactions of the heteroaryl compounds with dimethyl or diethyl phosphites and Mn(OAc)(3).2H2O under mild conditions give phosphonated products in high yield and good regioselectivity.
Mu
Xue-Jun
XJ
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry and Chemical Engineering, Suzhou University, 1 Hengyi Street, Suzhou, Jiangsu, 215123 China.
Zou
Jian-Ping
JP
Qian
Qiu-Feng
QF
Zhang
Wei
W
D006571:Heterocyclic Compounds / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D015394:Molecular Structure
D006571:Heterocyclic Compounds; D008345:Manganese