title: Efficient green-blue-light-emitting cationic iridium complex for light-emitting electrochemical cells.
abstract: A highly luminescent novel cationic iridium complex [iridium bis(2-phenylpyridine)(4,4'-(dimethylamino)-2,2'-bipyridine)]PF6 was synthesized and characterized using NMR, UV-visible absorption, and emission spectroscopy and electrochemical methods. This complex displays intense photoluminescence maxima in the green-blue region of the visible spectrum and exhibits unprecedented phosphorescence quantum yields, 80 +/- 10% with an excited-state lifetime of 2.2 mus in a dichloromethane solution at 298 K. Single-layer light-emitting electrochemical cells with the charged complex as conducting and electroluminescent material sandwiched between indium-tin oxide and Ag electrodes were fabricated, which emit green-blue light with an onset voltage as low as 2.5 V. Density functional theory calculations were performed to provide insight into the electronic structure of the [iridium bis(2-phenylpyridine)(4,4'-(dimethylamino)-2,2'-bipyridine)]PF6 complex, comparing these results with those obtained for [iridium bis(2-phenylpyridine)(4,4'-tert-butyl-2,2'-bipyridine)]PF6.
authors.affiliation: Laboratory for Photonics and Interfaces, Institute of Chemical Sciences and Engineering, School of basic Sciences, Swiss Federal Institute of Technology, CH-1015 Lausanne, Switzerland. MdKhaja.Nazeeruddin@epfl.ch
authors.forename: Md K
authors.initials: MK
authors.lastname: Nazeeruddin
authors.forename: R T
authors.initials: RT
authors.lastname: Wegh
authors.forename: Z
authors.initials: Z
authors.lastname: Zhou
authors.forename: C
authors.initials: C
authors.lastname: Klein
authors.forename: Q
authors.initials: Q
authors.lastname: Wang
authors.forename: F
authors.initials: F
authors.lastname: De Angelis
authors.forename: S
authors.initials: S
authors.lastname: Fantacci
authors.forename: M
authors.initials: M
authors.lastname: Grätzel