title: Alkali-metalated forms of thiacalix[4]arenes.
abstract: The alkali metal salts [TCALi4] (1), [TCANa4] (2), and [TCALK4] (3) of fully deprotonated p-tert-butyltetrathiacalix[4]arene (H(4)TCA) are readily available from the reactions of thiacalix[4]arene and n-BuLi, NaH, or KH as deprotonating reagents. Crystals of the sodium salts 2 and the potassium salt 3 suitable for X-ray diffraction were obtained in the form of the pyridine solvates [(TCA)2Na8.8py] (2.8py) and [(TCA)2K(8).8py] (3.8py). These molecules are dimers in the solid state but are structurally not related. In addition, the reaction of H(4)TCA and lithium hydroxide afforded the structurally characterized complex [(TCA)Li5(OH).4THF] (4). The molecular structure of 4 as well as the structures of 2.8py and 3.8py reveal a close relationship to the corresponding alkali metal salts of the calix[4]arenes.
authors.affiliation: Institut für Anorganische Chemie, Universität Karlsruhe, Engesserstrasse, Geb. 30.45, D-76131 Karlsruhe, Germany.
authors.forename: Jürgen
authors.initials: J
authors.lastname: Zeller
authors.forename: Udo
authors.initials: U
authors.lastname: Radius