Poly[aqua-mu3-2,2-dimethylmalonato-zinc(II)].
The title complex, [Zn(C5H6O4)(H2O)]n, has a two-dimensional layer structure. The Zn atoms, in a geometry that is closer to trigonal bipyramidal than square pyramidal, are coordinated by two O atoms of a bidentate dimethylmalonate ligand, two O atoms of monodentate dimethylmalonate ligands and one O atom from the aqua ligand. The crystal structure is characterized by the intralayer motif of a hydrogen-bonded network. Neighboring layers are linked together to build up a three-dimensional network via van der Waals forces.
Guo
Ming Lin
ML
School of Materials and Chemical Engineering, and Key Laboratory of Hollow Fiber Membrane Materials and Membrane Processes, Tianjin Polytechnic University, Tianjin 300160, People's Republic of China. guomlin@yahoo.com
Zhao
Yong Nan
YN