title: A second polymorph of [H3N(CH2)3NH3][V4O10].
abstract: The title compound, propane-1,3-diammonium tetravanadate, (C3H12N2)[V4O10], represents a second polymorph of composition beta-[H3N(CH2)3NH3][V4O(10)]. It differs from the alpha polymorph [Riou & Ferey (1995). J. Solid State Chem. 120, 137-145] in the conformation of the propane-1,3-diammonium dication which, in the present example, lies on a twofold axis and adopts a syn-syn rather than a syn-anti conformation. The twofold symmetry of this conformation thus co-operates with the vanadium oxide framework to result in a higher symmetry for the resultant crystal, viz. C2/c versus P2(1)/n. The overall unit-cell parameters for the two polymorphs are similar, and the inorganic layer within each is topologically identical, comprising edge-sharing V(IV)O5 square pyramids linked together via corner-sharing with V(V)O4 tetrahedra. A key difference between the two polymorphs is a ;head-to-head' versus ;head-to-tail' stacking of the vanadyl groups in adjacent layers.
authors.affiliation: School of Chemistry, University of St Andrews, St Andrews, Fife KY16 9ST, Scotland.
authors.forename: Nicholas F
authors.initials: NF
authors.lastname: Stephens
authors.forename: Philip
authors.initials: P
authors.lastname: Lightfoot