Progress toward the total synthesis of bacchopetiolone: application of a tandem aromatic oxidation/Diels-Alder reaction.
A stereoselective synthesis of the bacchopetiolone (1) carbocyclic core using a tandem phenolic oxidation/Diels-Alder reaction is described. [reaction: see text].
Bérubé
Amélie
A
Department of Chemistry, Yale University, New Haven, Connecticut 06520-8107, USA.
Drutu
Ioana
I
Wood
John L
JL
D018360:Crystallography, X-Ray; D006868:Hydrolysis; D007202:Indicators and Reagents; D010084:Oxidation-Reduction; D012717:Sesquiterpenes / Q000138:chemical synthesis*; D013237:Stereoisomerism
D007202:Indicators and Reagents; D012717:Sesquiterpenes; C522746:bacchopetiolone