Poly[[mu-aqua-bis(mu-2,4-dichlorophenoxyacetato)barium(II)] monohydrate].
In the title coordination polymer, {[Ba(C8H5Cl2O3)2(H2O)].H2O}n, each Ba(II) atom is nine-coordinated by six carboxylate O atoms and one ether O atom from five symmetry-related 2,4-dichlorophenoxyacetate ligands, and by two O atoms from water molecules, thus defining a distorted tricapped trigonal prism. The Ba(II) ions are bridged by bidentate water molecules and by tridentate and tetradentate 2,4-dichlorophenoxyacetate groups, leading to a two-dimensional layer structure. The crystal structure is further stabilized by hydrogen-bonding interactions within each layer.
Gu
Chang Sheng
CS
Department of Applied Chemistry, Guangdong University of Ocean, Zhanjiang 524006, People's Republic of China.
Hao
Xiao Min
XM
Guan
Shu Xia
SX
Liu
Ji Wei
JW