A zigzag chain structure in catena-poly[[[tetra-mu-acetamidato-kappa4N:O;kappa4O:N-dirhodium(II,III)]-mu-chloro] methanol solvate].
In {[Rh2(C2H4NO)4Cl].CH3OH}n, the cationic dirhodium complex and bridging chloro ligands form a one-dimensional zigzag chain, [Rh2(acam)4(mu-Cl)] (Hacam is acetamide). There is a large difference between the two Rh-Cl distances [2.6076 (14) and 2.5027 (14) A]. Neighboring chains are connected by two N-H...O hydrogen bonds per link between the amidate ligands.
Ebihara
Masahiro
M
Department of Chemistry, Faculty of Engineering, Gifu University, Yanagido, Gifu 501-1193, Japan. ebihara@apchem.gifu-u.ac.jp
Fuma
Yasuhiro
Y