High-resolution NMR with resistive and hybrid magnets: deconvolution using a field-fluctuation signal.
A method for compensating effect of field fluctuation is examined to attain high-resolution NMR spectra with resistive and hybrid magnets. In this method, time dependence of electromotive force induced for a pickup coil attached near a sample is measured synchronously with acquisition of NMR. Observed voltage across the pickup coil is converted to field fluctuation data, which is used to deconvolute NMR signals. The feasibility of the method is studied by (79)Br MAS NMR of KBr under a 30T magnetic field of a hybrid magnet. Twenty single-scan NMR signals were accumulated after the manipulation, resulting in a high-resolution NMR spectrum.
Iijima
Takahiro
T
Department of Chemistry, Kyoto University, Kyoto 606-8502, Japan. iijima@kuchem.kyoto-u.ac.jp
Takegoshi
K
K
Hashi
Kenjiro
K
Fujito
Teruaki
T
Shimizu
Tadashi
T
D000465:Algorithms; D017097:Electric Impedance; D004574:Electromagnetic Fields; D004867:Equipment Design; D019544:Equipment Failure Analysis; D009682:Magnetic Resonance Spectroscopy / Q000295:instrumentation* / Q000379:methods*; D008280:Magnetics / Q000295:instrumentation*; D012044:Regression Analysis; D012680:Sensitivity and Specificity; D012815:Signal Processing, Computer-Assisted; D014159:Transducers