Emission efficiency of diamine derivatives of tris[4,4,4-trifluoro-1-(2-thienyl)-1,3-butanediono]europium.
Diamine derivatives of tris[4,4,4-trifluoro-1-(2-thienyl)-1,3-butanediono]europium were synthesized and characterized by NMR, IR and UV-vis spectroscopy. The emission efficiency and decay times of the produced Eu(III) coordination complexes in acetone solutions were measured upon ligand excitation. The effect of the amine ligands was studied and the relation between the emission and the structure of the synthesized compounds was discussed.
Stanimirov
S S
SS
Laboratory of Organic Photochemistry, Faculty of Chemistry, University of Sofia, 1 James Baurchier blvd., 1164 Sofia, Bulgaria. sstanimirov@chem.uni-sofia.bg
Hadjichristov
G B
GB
Petkov
I K
IK
D003959:Diamines / Q000737:chemistry*; D004735:Energy Transfer; D005063:Europium / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D012996:Solutions; D013057:Spectrum Analysis; D013997:Time Factors
D003959:Diamines; D009942:Organometallic Compounds; D012996:Solutions; C522985:tris(4,4,4-trifluoro-1-(2-thienyl)-1,3-butanediono)europium; D005063:Europium