A chirality-induced alpha phase and a novel molecular magnetic metal in the BEDT-TTF/tris(croconate)ferrate(III) hybrid molecular system.
The novel paramagnetic and chiral anion [Fe(C5O5)3]3- has been combined with the organic donor BEDT-TTF (= ET = bis(ethylenedithio)tetrathiafulvalene) to yield the first chirality-induced alpha phase and a paramagnetic metal.
Gómez-García
Carlos J
CJ
Instituto de Ciencia Molecular (ICMol) Universidad de Valencia, Pol La Coma s/n, Paterna, (Valencia), 46980, Spain. carlos.gomez@uv.es
Coronado
Eugenio
E
Curreli
Simona
S
Giménez-Saiz
Carlos
C
Deplano
Paola
P
Mercuri
Maria Laura
ML
Pilia
Luca
L
Serpe
Angela
A
Faulmann
Christophe
C
Canadell
Enric
E
D018360:Crystallography, X-Ray; D003517:Cyclopentanes / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008280:Magnetics; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D013696:Temperature
C472948:BEDT-TTF; D003517:Cyclopentanes; D005290:Ferric Compounds; D013438:Sulfhydryl Compounds; C017311:ferrate ion; D007501:Iron