title: 1,3 Geminal interactions as the possible trend setting factors for C-H and C-C bond energies in alkanes. Support from a density functional theory based bond energy decomposition study.
abstract: A bond energy decomposition analysis has been carried out to rationalize the well-established experimental fact that C-C and C-H bond energies decrease with increasing substitution on the carbon. It is shown that this trend is set by steric 1,3 repulsive interactions (geminal repulsion) that increase in the order 1,3 hydrogen-hydrogen < 1,3 hydrogen-carbon < 1,3 carbon-carbon. On the other hand, the radical stabilization energy has little influence on the observed trend for the C-H bond energy in H-CR(1)R(2)R(3) or the C-C bond energy in H(3)C-CR(1)R(2)R(3). Thus, it varies in H-CR(1)R(2)R(3) from -7.2 kcal/mol (H-CH3) to -6.5 kcal/mol (H-C(CH3)3) and in H(3)C-CR(1)R(2)R(3) from -19.0 kcal/mol (H(3)C-CH(3)) to -16.9 kcal/mol (H(3)C-C(CH(3))(3)). It was further found that the average intrinsic C-H bond energy in H-CR(1)R(2)R(3) of 129.2 kcal/mol is smaller than the average intrinsic C-C bond energy in H(3)C-CR(1)R(2)R(3) of 143.4 kcal/mol. However, after the inclusion of steric effects, the overall C-H bond becomes stronger than the C-C bond. The role of steric 1,3 repulsive interactions as the trend setting factor has most recently been suggested by Gronert (J. Org. Chem. 2006, 71, 1209) based on an empirical fit of alkane atomization energies.
authors.affiliation: Department of Chemistry, University of Calgary, University Drive 2500, Calgary, Alberta, T2N 1N4 Canada.
authors.forename: Mariusz
authors.initials: M
authors.lastname: Mitoraj
authors.forename: Hungjuan
authors.initials: H
authors.lastname: Zhu
authors.forename: Artur
authors.initials: A
authors.lastname: Michalak
authors.forename: Tom
authors.initials: T
authors.lastname: Ziegler
mesh_terms: D000473:Alkanes / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D006860:Hydrogen Bonding; D013816:Thermodynamics
chemical_list: D000473:Alkanes; D002244:Carbon; D006859:Hydrogen