Synthesis and properties of a fluorene-capped isotruxene: a new unsymmetrical star-shaped pi-system.
An unsymmetrical star-shaped pi-system (1) with an isotruxene core and three fluorene arms has been synthesized, and its photophysical, electrochemical, and thermochemical properties have been investigated and compared with the corresponding symmetrical truxene derivatives 2a-d (Kanibolotsky, A. L.; Berridge, R.; Skabara, P. J.; Perepichka, I. F.; Bradley, D. D. C.; Koeberg, M. J. Am. Chem. Soc. 2004, 126, 13695-13702). Stronger electronic couplings between the arms in 1 vs 2a-d lead to lower optical band gap, larger splitting in oxidation potentials, and superior thermostability. [structure: see text]
Yang
Jye-Shane
JS
Department of Chemistry, National Taiwan University, Taipei, Taiwan 10617. jsyang@ntu.edu.tw
Lee
Yar-Ru
YR
Yan
Jyu-Lun
JL
Lu
Ming-Chun
MC