Molecular dynamics investigation with the time resolved optical Kerr effect on the CS2-C6H6 mixtures.
An investigation of the molecular dynamics in pure liquids and in mixtures through the technique of time resolved optical Kerr effect is performed. The samples studied were the mixtures of carbon disulfide (CS(2)) with benzene (C(6)H(6)). The molecular dynamics of the pure liquids is briefly discussed while the main results are obtained for the mixtures. A slow dynamics component is observed for the optical heterodyne detected optical Kerr effect transient decaying exponentially with time constants on picosecond time scale. The fast subpicosend time relaxations are analyzed in terms of the nondiffusive component of the spectral response that is associated with the molecular dynamics. The modifications of the spectrum are quantified, and the explanation of the observed changes is given in terms of the structural interaction configurations that produced changes in the intermolecular potential within which the molecules execute librational motions.
Heisler
Ismael A
IA
Instituto de Física, Universidade Federal do Rio Grande do Sul-UFRGS, Avenida Bento Gonçalves, 9500, Caixa Postal 15051, CEP 91501-970, Porto Alegre, RS, Brazil. iheisler@yahoo.com.br
Correia
Ricardo R B
RR
Cunha
Silvio L S
SL