Selective oxidation of benzene to phenol over FeAlPO catalysts using nitrous oxide as oxidant.
A tetrahedrally coordinated iron in framework substituted microporous AlPO-5 catalysts are shown to be active and selective for the hydroxylation of benzene to phenol, using nitrous oxide as the oxidant.
Shiju
N Raveendran
NR
Davy Faraday Research Laboratory, The Royal Institution of Great Britain, London, W1S 4BS, United Kingdom.
Fiddy
Steven
S
Sonntag
Olivier
O
Stockenhuber
Michael
M
Sankar
Gopinathan
G
D017607:Aluminum Compounds / Q000737:chemistry*; D001554:Benzene / Q000737:chemistry*; D002384:Catalysis; D007501:Iron / Q000737:chemistry*; D009609:Nitrous Oxide / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry*; D010084:Oxidation-Reduction; D010636:Phenols / Q000138:chemical synthesis* / Q000737:chemistry; D010710:Phosphates / Q000737:chemistry*; D013696:Temperature
D017607:Aluminum Compounds; D016877:Oxidants; D010636:Phenols; D010710:Phosphates; D007501:Iron; C012714:aluminum phosphate; D001554:Benzene; D009609:Nitrous Oxide