title: An enantioselective desymmetrisation approach to C9-substituted trans-hydrindene rings based on a diastereotopic group-selective intramolecular Diels-Alder reaction.
abstract: The synthesis of an achiral skipped bis(1,3-diene) substrate was achieved, which was shown to undergo an enantioselective, diastereotopic group-selective, intramolecular Diels-Alder reaction.
authors.affiliation: University of Southampton, School of Chemistry, Highfield, Southampton, UKSO17 1BJ.
authors.forename: Nadia
authors.initials: N
authors.lastname: Azzi
authors.forename: Ed
authors.initials: E
authors.lastname: Griffen
authors.forename: Mark
authors.initials: M
authors.lastname: Light
authors.forename: Bruno
authors.initials: B
authors.lastname: Linclau
mesh_terms: D002070:Butadienes / Q000138:chemical synthesis* / Q000737:chemistry; D007192:Indenes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D012680:Sensitivity and Specificity; D013237:Stereoisomerism
chemical_list: D002070:Butadienes; D007192:Indenes