title: Cryogenic synthesis of molecules of astrobiological interest: catalytic role of cosmic dust analogues.
abstract: We have studied the effects of the substrate, namely amorphous olivine (MgFeSiO(4)) cosmic dust analogues (CDAs), in synthesis of molecules obtained after 200 keV proton irradiation of formamide (NH(2)COH). Formamide has been deposited on the olivine substrate at 20 K. The abundances of new molecular species formed after an irradiation dose of 12 eV/16 amu in formamide pure (i.e. deposited on an inert silicon substrate) and deposited on CDAs have been compared. Specifically, MgFeSiO(4) amorphous olivine is a selective catalyst preventing formation of NH(3) and CN(-) molecules and changing the relative abundances of NH4(+)OCN(-), CO(2), HNCO, CO. We have shown that the role of CDAs has to be taken into account in experiments simulating processes occurring in astronomical environments.
authors.affiliation: INAF-Astronomical Observatory of Capodimonte, via Moiariello 16, 80131 Naples, Italy. brucato@na.astro.it
authors.forename: J R
authors.initials: JR
authors.lastname: Brucato
authors.forename: G
authors.initials: G
authors.lastname: Strazzulla
authors.forename: G A
authors.initials: GA
authors.lastname: Baratta
authors.forename: A
authors.initials: A
authors.lastname: Rotundi
authors.forename: L
authors.initials: L
authors.lastname: Colangeli
mesh_terms: D000641:Ammonia / Q000737:chemistry; D055580:Astronomical Phenomena; D001256:Astronomy; D002384:Catalysis; D019443:Cosmic Dust / Q000032:analysis*; D003486:Cyanides / Q000737:chemistry; D019418:Evolution, Chemical; D005118:Extraterrestrial Environment / Q000737:chemistry*; D005559:Formamides / Q000737:chemistry; D007287:Inorganic Chemicals / Q000737:chemistry*; D058085:Iron Compounds / Q000737:chemistry; D017616:Magnesium Compounds / Q000737:chemistry; D017640:Silicates / Q000737:chemistry; D013055:Spectrophotometry, Infrared
chemical_list: D019443:Cosmic Dust; D003486:Cyanides; D005559:Formamides; D007287:Inorganic Chemicals; D058085:Iron Compounds; D017616:Magnesium Compounds; D017640:Silicates; C031066:formamide; D000641:Ammonia; C034475:olivine