A self-assembled hexadecanuclear 4 x[2 x 2] Mn(II)16 square grid from a pyridazine bis(hydrazone) ligand: synthesis, structure and magnetism.
A compartmentalized {4 x[2 x 2]} Mn(II)16 antiferromagnetically coupled square grid results from the self-assembly reaction of a tetratopic pyridazine bis(hydrazone) ligand and Mn(II).
Dey
Subrata K
SK
Dept of Chemistry, Memorial University, St. John's, Newfoundland, CanadaA1B 3X7.
Thompson
Laurence K
LK
Dawe
Louise N
LN
D018360:Crystallography, X-Ray; D006835:Hydrazones / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D011724:Pyridazines / Q000737:chemistry*; D013696:Temperature
D006835:Hydrazones; D008024:Ligands; D009942:Organometallic Compounds; D011724:Pyridazines; D008345:Manganese; C062482:pyridazine