title: PAHs in the bulk atmospheric deposition of the Seine river basin: source identification and apportionment by ratios, multivariate statistical techniques and scanning electron microscopy.
abstract: The origin of polycyclic aromatic hydrocarbons (PAH) contamination in bulk atmospheric deposition at two sites of the Seine estuary, one urban and one industrial, has been investigated. The PAH profiles indicate that PAHs mainly have a pyrolytic origin, both in urban and industrial areas. PAH sources vary during the year with an increase of high molecular weight PAH proportions (especially for carcinogenic PAHs) in winter, that means an increase of combustion processes such as domestic heating. Ratios of indicator PAHs (FTH/FTH+PYR and IcdP/IcdP+BghiP) confirm the pyrolytic origin of PAHs. In summer, ratios show the presence of industrial sources. In addition to these two methods, a factor analysis/multiple linear regression model was applied and gave an approximation of PAH source apportionment. PAH were found to be associated predominantly with emissions from road traffic (gasoline and diesel), that accounts for 17-34%. Domestic heating is a very important PAH source in urban areas and accounts for up to 85% of PAHs in winter. Industrial emissions (refineries...) account for 25% in the industrial area in summer. Each is an identified source category for the region and these results are consistent with fly-ashes identified by scanning electron microscopy. This study demonstrates that a combination of source identification methods is a far more efficient than one method alone.
authors.affiliation: Département de Géologie, Université de Rouen, UMR CNRS 6143 M2C, 10 Boulevard de Broglie, 76821 Mont-Saint-Aignan cedex, France. anne.motelay-massei@univ-rouen.fr
authors.forename: Anne
authors.initials: A
authors.lastname: Motelay-Massei
authors.forename: Donatienne
authors.initials: D
authors.lastname: Ollivon
authors.forename: Brigitte
authors.initials: B
authors.lastname: Garban
authors.forename: Karen
authors.initials: K
authors.lastname: Tiphagne-Larcher
authors.forename: Irène
authors.initials: I
authors.lastname: Zimmerlin
authors.forename: Marc
authors.initials: M
authors.lastname: Chevreuil
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D004785:Environmental Pollutants / Q000032:analysis*; D005602:France; D006361:Heating; D007221:Industry; D008855:Microscopy, Electron, Scanning; D052638:Particulate Matter / Q000032:analysis*; D011084:Polycyclic Aromatic Hydrocarbons / Q000032:analysis*; D045483:Rivers; D012621:Seasons; D001335:Vehicle Emissions / Q000032:analysis
chemical_list: D000393:Air Pollutants; D004785:Environmental Pollutants; D052638:Particulate Matter; D011084:Polycyclic Aromatic Hydrocarbons; D001335:Vehicle Emissions