Structure of strontium barium niobate SrxBa1-xNb2O6 (SBN) in the composition range 0.32<or=x<or=0.82.
The structure of strontium barium niobate crystals SrxBa1-xNb2O6 is comprehensively studied in the whole range of the tetragonal tungsten bronze phase (x=0.32-0.82) using both powder and single-crystal X-ray diffraction measurements. Unit-cell parameters, density, site-occupancy factors and interionic distances show an explicit composition dependence which can be consistently explained using simple model calculations. The temperature dependence of the unit-cell parameters exhibits a remarkable anisotropy in a broad temperature region below the phase transition temperature. This proves that the electrostrictive contribution to the thermal expansion plays an important role in strontium barium niobate.
Podlozhenov
Sergey
S
Fachbereich Physik, Universität Osnabrück, D-49069 Osnabrück, Germany.
Graetsch
Heribert A
HA
Schneider
Julius
J
Ulex
Michael
M
Wöhlecke
Manfred
M
Betzler
Klaus
K