title: Eta1 and eta2 complexes of lambda3-1,2,4,6-thiatriazinyls with CpCr(CO)x.
abstract: The title heterocyclic radicals coordinate to either 17e CpCr(CO)3 or 15e CpCr(CO)2 moieties as one-electron or as three-electron donors, respectively; in the former the bonding is via the perpendicular p orbital of the sulfur atom, while in the latter bonding is via p(pi) orbitals on both sulfur and nitrogen.
authors.affiliation: Department of Chemistry, National University of Singapore, Kent Ridge, Singapore.
authors.forename: Chwee Ying
authors.initials: CY
authors.lastname: Ang
authors.forename: René T
authors.initials: RT
authors.lastname: Boeré
authors.forename: Lai Yoong
authors.initials: LY
authors.lastname: Goh
authors.forename: Lip Lin
authors.initials: LL
authors.lastname: Koh
authors.forename: Seah Ling
authors.initials: SL
authors.lastname: Kuan
authors.forename: Geok Kheng
authors.initials: GK
authors.lastname: Tan
authors.forename: Xin
authors.initials: X
authors.lastname: Yu