Eta1 and eta2 complexes of lambda3-1,2,4,6-thiatriazinyls with CpCr(CO)x.
The title heterocyclic radicals coordinate to either 17e CpCr(CO)3 or 15e CpCr(CO)2 moieties as one-electron or as three-electron donors, respectively; in the former the bonding is via the perpendicular p orbital of the sulfur atom, while in the latter bonding is via p(pi) orbitals on both sulfur and nitrogen.
Ang
Chwee Ying
CY
Department of Chemistry, National University of Singapore, Kent Ridge, Singapore.
Boeré
René T
RT
Goh
Lai Yoong
LY
Koh
Lip Lin
LL
Kuan
Seah Ling
SL
Tan
Geok Kheng
GK
Yu
Xin
X