Synthesis, characterization, and photocatalytic activity of TiO(2-x)N(x) nanocatalyst.
Nitrogen-doped titanium dioxide powders were prepared by wet method, that is, the hydrolysis of acidic tetra-butyl titanate using aqueous ammonia solution, followed by calcination at temperatures about 350 degrees C. The catalysts exhibited photocatalytic activity in the visible light region owing to N-doping. The light absorption onset of TiO(2-x)N(x) was shifted to the visible region at 459 nm compared to 330 nm of pure TiO(2). An obvious decrease in the band gap was observed by the optical absorption spectroscopy, which resulted from N2p localized states above the valence band of TiO(2-x)N(x) (compared to TiO(2)). The TiO(2-x)N(x) catalyst was characterized to be anatase with oxygen-deficient stoichiometry by X-ray diffraction (XRD), surface photovoltage spectroscopy (SPS) and X-ray photoelectron spectroscopy (XPS). The binding energy of N1s measured by XPS characterization was 396.6 eV (TiN bonds, beta-N) and 400.9 eV (NN bonds, gamma-N(2)), respectively. The photocatalytic activity of TiO(2-x)N(x) under visible light was induced by the formation of beta-N in the structure. Photocatalytic decomposition of benzoic acid solutions was carried out in the ultraviolet and visible (UV-vis) light region, and the TiO(2-x)N(x) catalyst showed higher activity than pure TiO(2).
Wang
Y Q
YQ
School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin, Heilongjiang 150090, PR China. biguiwang@163.com
Yu
X J
XJ
Sun
D Z
DZ
D019817:Benzoic Acid / Q000737:chemistry* / Q000528:radiation effects*; D002384:Catalysis; D053758:Nanoparticles / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D010084:Oxidation-Reduction; D010777:Photochemistry; D013472:Sunlight; D014025:Titanium / Q000737:chemistry*
C009495:titanium dioxide; D019817:Benzoic Acid; D014025:Titanium; D009584:Nitrogen