An unexpected synthesis of ketene monothioacetals.
Some dithiocarbonates (xanthates) can be converted into ketene monothioacetals through extrusion of sulfur upon treatment with base and an alkylating agent.
Fabre
Stéphanie
S
Laboratoire de Synthèse Organique associé au C. N. R. S., Département de Chimie, Ecole Polytechnique, F-91128 Palaiseau, France.
Vila
Xavier
X
Zard
Samir Z
SZ
D000080:Acetals / Q000138:chemical synthesis* / Q000737:chemistry; D005030:Ethylenes / Q000138:chemical synthesis* / Q000737:chemistry; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D013237:Stereoisomerism; D013844:Thiazoles / Q000138:chemical synthesis* / Q000737:chemistry
D000080:Acetals; D005030:Ethylenes; D007659:Ketones; D013844:Thiazoles; C008223:ketene