Helicity induction through hydrogen bonding and spontaneous resolution of a bimetallic nickel complex coordinated to an octahedral metalloligand.
A new bimetallic complex of nickel(II) coordinated to a molybdenum-containing metalloligand has been synthesized that forms a helical chain through hydrogen bonding and shows spontaneous resolution upon crystallization.
Khatua
Snehadrinarayan
S
Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India.
Stoeckli-Evans
Helen
H
Harada
Takunori
T
Kuroda
Reiko
R
Bhattacharjee
Manish
M
D002942:Circular Dichroism; D003460:Crystallization; D006860:Hydrogen Bonding; D008024:Ligands; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry; D009532:Nickel / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D013818:Thermogravimetry / Q000379:methods
D008024:Ligands; D008670:Metals; D009532:Nickel; D008982:Molybdenum