MoS2 hierarchical hollow cubic cages assembled by bilayers: one-step synthesis and their electrochemical hydrogen storage properties.
Micrometer scaled MoS2 hierarchical hollow cubic cages assembled by bilayers can be synthesized via a one-step self-assembly coupled with intermediate crystal templating process without any surfactant, in which the intermediate K2NaMoO3F3 crystal formed in-situ and then served as the self-sacrificed template based on the Kirkendall Effect; The MoS2 hierarchical hollow cubic cages were employed for electrochemical hydrogen storage with a high capacity of 375 mAh g(-1) due to the more active edges exposing on the upright-standing nanoplates.
Ye
Lina
L
Department of Nanomaterials and Nanochemistry, Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei 230026, P. R. China.
Wu
Changzheng
C
Guo
Wen
W
Xie
Yi
Y
D004220:Disulfides / Q000737:chemistry*; D004563:Electrochemistry; D004566:Electrodes; D006859:Hydrogen / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D008982:Molybdenum / Q000737:chemistry*; D014961:X-Ray Diffraction
D004220:Disulfides; D006859:Hydrogen; D008982:Molybdenum; C082964:molybdenum disulfide