Carborane functionalized pyrroles and porphyrins via the Suzuki cross-coupling reaction.
A new route to carboranylated pyrroles and porphyrins is reported which involves the Suzuki coupling of readily available bromo- and boronic acid-pyrroles and bromoporphyrins with functionalized carboranes; the X-ray structures of two targeted products are presented and discussed.
Hao
Erhong
E
Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA.
Fronczek
Frank R
FR
Vicente
M Graça H
MG
D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D011758:Pyrroles / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D001896:Boron Compounds; D011166:Porphyrins; D011758:Pyrroles