Iodine catalyzed one-pot diamination of glycals with chloramine-T: a new approach to 2-amino-beta-glycosylamines for applications in N-glycopeptide synthesis.
Iodine catalyzes a facile one-pot direct diamination of glycals with chloramine-T to afford stereoselectively 2-amino-beta-glycosylamine derivatives that serve as convenient precursors for the synthesis of N-linked glycopeptides.
Kumar
Vipin
V
Department of Chemistry, Indian Institute of Technology - Delhi, Hauz Khas, New Delhi - 110016, India.
Ramesh
Namakkal G
NG
D000586:Amination; D000606:Amino Sugars / Q000138:chemical synthesis* / Q000737:chemistry; D002236:Carbohydrate Conformation; D002241:Carbohydrates / Q000737:chemistry*; D002384:Catalysis; D002700:Chloramines / Q000737:chemistry*; D006020:Glycopeptides / Q000138:chemical synthesis* / Q000737:chemistry; D007455:Iodine / Q000737:chemistry*; D013237:Stereoisomerism; D014105:Tosyl Compounds / Q000737:chemistry*
D000606:Amino Sugars; D002241:Carbohydrates; D002700:Chloramines; D006020:Glycopeptides; D014105:Tosyl Compounds; C016300:chloramine-T; D007455:Iodine