Phase separation and percolation of reversibly aggregating spheres with a square-well attraction potential.
Reversible aggregation of spheres is simulated using a novel method in which clusters of bound spheres diffuse collectively with a diffusion coefficient proportional to their radius. It is shown that the equilibrium state is the same as with other simulation techniques, but with the present method more realistic kinetics are obtained. The behavior as a function of volume fraction and interaction strength was tested for two different attraction ranges. The binodal and the percolation threshold were determined. The cluster structure and size distribution close to the percolation threshold were found to be consistent with the percolation model. Close to the binodal phase separation occurred through the growth of spherical dense domains, while for deep quenches a system spanning network is formed that coarsens with a rate that decreases with increasing attraction. We found no indication for arrest of the coarsening.
Babu
Sujin
S
Polymères Colloïdes Interfaces, CNRS UMR 6120, Université du Maine, F-72085 Le Mans Cedex 9, France.
Gimel
Jean Christophe
JC
Nicolai
Taco
T
D003198:Computer Simulation; D008956:Models, Chemical