title: Time-weighted average water sampling with a diffusion-based solid-phase microextraction device.
abstract: A new diffusion-based solid-phase microextraction (SPME) time-weighted average (TWA) field water sampling device was developed and investigated by field trial. The sampler is constructed with copper tube and caps and a commercial SPME fiber assembly. The device possesses all advantages of SPME; it is solvent-free, reusable, combines sampling, isolation and enrichment into one step, and the fiber can be directly injected into a gas chromatograph for analysis with a commercial SPME fiber holder, without further treatment. Field trials in Laurel Creek (Waterloo, Ont., Canada) and Hamilton Harbour (Hamilton, Ont., Canada) illustrated that the device is durable, easy to deploy, and the mass uptake of the device is independent of the face velocity. The device provides good precision [relative standard deviations (RSDs) are less than 20%] and the data obtained with this device are quite comparable to those obtained with the spot sampling method, which demonstrates that the newly developed SPME water sampling device is suitable for long-term monitoring of organic pollutants in water.
authors.affiliation: Department of Chemistry, University of Waterloo, 200 University Avenue West, Waterloo, Ont. N2L 3G1, Canada. cesoygf@sysu.edu.cn
authors.forename: Gangfeng
authors.initials: G
authors.lastname: Ouyang
authors.forename: Wennan
authors.initials: W
authors.lastname: Zhao
authors.forename: Mehran
authors.initials: M
authors.lastname: Alaee
authors.forename: Janusz
authors.initials: J
authors.lastname: Pawliszyn
mesh_terms: D004058:Diffusion; D015203:Reproducibility of Results; D052617:Solid Phase Microextraction / Q000295:instrumentation / Q000379:methods*; D014867:Water / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis
chemical_list: D014874:Water Pollutants, Chemical; D014867:Water