[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2- and pyrazine ligands.
[Cu(HF2)(pyz)2]BF4 consists of rare mu(1,3) bridging HF2- anions and micro-pyrazine ligands leading to a 3D pseudo-cubic framework that antiferromagnetically orders below 1.54(1) K.
Manson
Jamie L
JL
Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA. jmanson@ewu.edu
Conner
Marianne M
MM
Schlueter
John A
JA
Lancaster
Tom
T
Blundell
Stephen J
SJ
Brooks
Michael L
ML
Pratt
Francis L
FL
Papageorgiou
Thomas
T
Bianchi
Andreas D
AD
Wosnitza
Jochen
J
Whangbo
Myung-Hwan
MH
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006858:Hydrofluoric Acid / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D011719:Pyrazines / Q000737:chemistry*; D013237:Stereoisomerism; D013696:Temperature
D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; D011719:Pyrazines; D003300:Copper; D006858:Hydrofluoric Acid