title: First enantioselective organocatalytic allylation of simple aldimines with allyltrichlorosilane.
abstract: A new organocatalytic system, novel chiral bisformamide and in situ generated L-proline-derived allylsilane reagent , which converts different aldimines to homoallylic amines in good to high yields (up to 95%) and good enantioselectivities (up to 85% ee) has been described.
authors.affiliation: Institut für Organische und Biomolekulare Chemie der Georg-August-Universität Göttingen, Tammannstrasse 2, 37077, Göttingen, Germany.
authors.forename: Sunil B
authors.initials: SB
authors.lastname: Jagtap
authors.forename: Svetlana B
authors.initials: SB
authors.lastname: Tsogoeva
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000627:Aminophenols / Q000737:chemistry; D002384:Catalysis; D005559:Formamides / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D015394:Molecular Structure; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D000627:Aminophenols; D005559:Formamides; D012821:Silanes; C516132:allyltrichlorosilane