title: Multicomponent semiconducting polymer systems with low crystallization-induced percolation threshold.
abstract: Blends and other multicomponent systems are used in various polymer applications to meet multiple requirements that cannot be fulfilled by a single material. In polymer optoelectronic devices it is often desirable to combine the semiconducting properties of the conjugated species with the excellent mechanical properties of certain commodity polymers. Here we investigate bicomponent blends comprising semicrystalline regioregular poly(3-hexylthiophene) and selected semicrystalline commodity polymers, and show that, owing to a highly favourable, crystallization-induced phase segregation of the two components, during which the semiconductor is predominantly expelled to the surfaces of cast films, we can obtain vertically stratified structures in a one-step process. Incorporating these as active layers in polymer field-effect transistors, we find that the concentration of the semiconductor can be reduced to values as low as 3 wt% without any degradation in device performance. This is in stark contrast to blends containing an amorphous insulating polymer, for which significant reduction in electrical performance was reported. Crystalline-crystalline/semiconducting-insulating multicomponent systems offer expanded flexibility for realizing high-performance semiconducting architectures at drastically reduced materials cost with improved mechanical properties and environmental stability, without the need to design all performance requirements into the active semiconducting polymer itself.
authors.affiliation: Cavendish Laboratory, University of Cambridge, JJ Thomson Ave., Cambridge CB3 0HE, UK.
authors.forename: Shalom
authors.initials: S
authors.lastname: Goffri
authors.forename: Christian
authors.initials: C
authors.lastname: Müller
authors.forename: Natalie
authors.initials: N
authors.lastname: Stingelin-Stutzmann
authors.forename: Dag W
authors.initials: DW
authors.lastname: Breiby
authors.forename: Christopher P
authors.initials: CP
authors.lastname: Radano
authors.forename: Jens W
authors.initials: JW
authors.lastname: Andreasen
authors.forename: Richard
authors.initials: R
authors.lastname: Thompson
authors.forename: René A J
authors.initials: RA
authors.lastname: Janssen
authors.forename: Martin M
authors.initials: MM
authors.lastname: Nielsen
authors.forename: Paul
authors.initials: P
authors.lastname: Smith
authors.forename: Henning
authors.initials: H
authors.lastname: Sirringhaus