An unusually high thermal stability within a novel lanthanide 1,3,5-cyclohexanetricarboxylate framework: synthesis, structure, and thermal data.
A novel three-dimensional lanthanide-organic framework has been synthesized; this material has an exceptionally high thermal stability (600 degrees C) and an unusually low coordination number for a lanthanide ion (CN = 6).
de Lill
Daniel T
DT
Department of Chemistry, The George Washington University, Washington, DC, 20052, USA.
Cahill
Christopher L
CL
D002264:Carboxylic Acids / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003510:Cyclohexanes / Q000737:chemistry*; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D013696:Temperature
C517114:1,3,5-cyclohexanetricarboxylate; D002264:Carboxylic Acids; D003510:Cyclohexanes; D028581:Lanthanoid Series Elements; D009942:Organometallic Compounds