Oxovanadium(v)-catalyzed oxidative biaryl synthesis from organoborate under O2.
Oxidative ligand coupling of organoborates was catalyzed by VO(OEt)Cl(2) under oxygen atmosphere, which provides a versatile method for the selective synthesis of symmetrical or unsymmetrical biaryls.
Mizuno
Hidenori
H
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Yamada-oka, Suita, Osaka 565-0871, Japan.
Sakurai
Hidehiro
H
Amaya
Toru
T
Hirao
Toshikazu
T