Hydrolysis of sorghum straw using phosphoric acid: evaluation of furfural production.
Sorghum straw is a waste that has been studied scarcely. The main application is its use as raw material for xylose production. Xylose is a hemicellulosic sugar mainly used for its bioconversion toward xylitol. An alternative use could be its conversion toward furfural. The objective of this work was to study the furfural production by hydrolysis of sorghum straw with phosphoric acid at 134 degrees C. Several concentrations of H(3)PO(4) in the range 2-6% and reaction time (range 0-300 min) were evaluated. Kinetic parameters of mathematical models for predicting the concentration of xylose, glucose, arabinose, acetic acid and furfural in the hydrolysates were found. Optimal conditions for furfural production by acid hydrolysis were 6% H(3)PO(4) at 134 degrees C for 300 min, which yielded a solution with 13.7 g furfural/L, 4.0 g xylose/L, 2.9 g glucose/L, 1.1g arabinose/L and 1.2g acetic acid/L. The furfural yield of the process was 0.1336 g furfural/g initial dry matter was obtained. The results confirmed that sorghum straw can be used for furfural production when it is hydrolyzed using phosphoric acid.
Vázquez
Manuel
M
Department of Food Science and Technology, U. A. M. Reynosa-Aztlán, Universidad Autónoma de Tamaulipas, Reynosa, Tamaulipas, Mexico. vazquezm@lugo.usc.es <vazquezm@lugo.usc.es>
Oliva
Martha
M
Téllez-Luis
Simón J
SJ
Ramírez
José A
JA
D019342:Acetic Acid / Q000737:chemistry; D002241:Carbohydrates / Q000737:chemistry; D005662:Furaldehyde / Q000737:chemistry*; D006868:Hydrolysis; D007700:Kinetics; D008956:Models, Chemical; D010756:Phosphoric Acids / Q000737:chemistry*; D045868:Sorghum / Q000737:chemistry*; D013696:Temperature; D018505:Waste Management / Q000379:methods*
D002241:Carbohydrates; D010756:Phosphoric Acids; D005662:Furaldehyde; C030242:phosphoric acid; D019342:Acetic Acid