Microstructures by solvent drop evaporation on polymer surfaces: dependence on molar mass.
When a solvent drop evaporates from a polymer surface, it leaves behind a characteristic structure, typically a crater. We deposited toluene drops with a microsyringe onto planar polystyrene (PS) surfaces and analyzed the surface topography after drying. For low molar mass PS (Mw = 20.9-24.3 kDa) dotlike protrusions with a ridge at the periphery formed on the polymer surface. With increasing molar mass the central region decreased in height. At Mw = 29.6-643 kDa a craterlike structure with a depression in the center and a ridge was observed. At even higher molar mass, irregular structures without rotational symmetry occurred. We explain the observed dependence on the molar mass with a different degree of entanglement, leading to different dissolution rates and different diffusion constants.
Li
Guangfen
G
Max Planck Institute for Polymer Research, Ackermannweg 10, 55128 Mainz, Germany.
Butt
Hans-Jürgen
HJ
Graf
Karlheinz
K