title: Studies of thiol additions of silane coupling agents by vibrational spectroscopy.
abstract: Raman and infrared spectroscopies have been used to determine the addition reaction of mercaptopropyltrimethoxysilane (MPTMS) to allyltrimethoxysilane (ATMS) and 7-octenyltrichlorosilane based on the vibrational intensity variation of thiol and vinyl groups in the reaction mixtures. Due to the distinct and moderate intensity of Raman bands observed in the present experiment, the identification with Raman spectroscopic method is more sensitive than that with FTIR spectroscopy. In the presence of UV radiation, thiol addition reaction has been observed in the direct mixing samples of silanes. Hybrid sol-gels prepared with the use of MPTMS and ATMS as precursors in both acidic and basic conditions have revealed the progression of thiol addition under the UV radiation exposure. UV radiation is similarly effective to induce the thiol addition in the sol-gel coated aluminum tiles. Without UV radiation, the use of free radical initiator in the sol-gel samples might also help to induce the addition reaction.
authors.affiliation: Department of Chemistry, University of Memphis, Memphis, TN 38138-3550, USA. yingli@memphis.edu
authors.forename: Ying-Sing
authors.initials: YS
authors.lastname: Li
authors.forename: N E
authors.initials: NE
authors.lastname: Vecchio
mesh_terms: D000535:Aluminum / Q000737:chemistry; D012821:Silanes / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013059:Spectrum Analysis, Raman; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D014466:Ultraviolet Rays; D014732:Vibration
chemical_list: D012821:Silanes; D013438:Sulfhydryl Compounds; D000535:Aluminum