Water sorption in silicone foam containing diatomaceous earth.
Room temperature vulcanizing (RTV) silicone foams are commonly used for compression sealing, structural support, packaging, and damping applications. The presence of sorbed water in foams can affect the mechanical and chemical properties of these materials. In order to investigate water sorption behavior, a silicone foam containing diatomaceous earth filler was synthesized and studied for water uptake characteristics at 20, 50, and 80 degrees C. Type II equilibrium and bimodal kinetic behavior that was governed by a rapid initial uptake followed by a prolonged sorption over a larger time scale was observed. In order to explain this bimodal behavior, the major components of this foam-the silicone polymer and the diatomaceous earth-were independently studied for their water equilibrium behavior and uptake kinetic characteristics. Type II equilibrium was observed for both components. The kinetic behavior of the silicone polymer was governed by a very rapid uptake of water. The kinetic behavior of the diatomaceous earth was governed by a rapid initial uptake followed by a prolonged sorption over a larger time scale. A physically based and thermodynamically consistent mathematical model describing the water equilibrium and kinetics in diatomaceous earth and silicone polymer components, was employed to characterize the data. This model formed the basis of a predictive model for estimation of water sorption in filled silicone foam. The predictive model was tested against sorption and desorption data yielding favorable results for a range of temperatures.
Rutherford
S W
SW
WT-6, Los Alamos National Laboratory, Los Alamos, NM 87545, USA. stevenr@lanl.gov
Coons
J E
JE