RuCl3-catalyzed oxidation of iodoarenes with peracetic acid: new facile preparation of iodylarenes.
New facile methodology for the preparation of pentavalent iodine compounds using peracetic acid as an oxidant in the presence of catalytic amounts of ruthenium trichloride is described. The new procedure allows the preparation of several previously unknown iodylarenes bearing strongly electron-withdrawing CF3 groups in the aromatic ring.
Koposov
Alexey Y
AY
Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota 55812, USA.
Karimov
Rashad R
RR
Pronin
Andrey A
AA
Skrupskaya
Tatyana
T
Yusubov
Mekhman S
MS
Zhdankin
Viktor V
VV
D002384:Catalysis; D006847:Hydrocarbons, Iodinated / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010463:Peracetic Acid / Q000737:chemistry*; D017975:Ruthenium Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D006847:Hydrocarbons, Iodinated; D017975:Ruthenium Compounds; D010463:Peracetic Acid; C038365:ruthenium chloride