title: Modeling seasonal redox dynamics and the corresponding fate of the pharmaceutical residue phenazone during artificial recharge of groundwater.
abstract: Reactive multicomponent transport modeling was used to investigate and quantify the factors that affect redox zonation and the fate of the pharmaceutical residue phenazone during artificial recharge of groundwater at an infiltration site in Berlin, Germany. The calibrated model and the corresponding sensitivity analysis demonstrated thattemporal and spatial redox zonation at the study site was driven by seasonally changing, temperature-dependent organic matter degradation rates. Breakthrough of phenazone at monitoring wells occurred primarily during the warmer summer months, when anaerobic conditions developed. Assuming a redox-sensitive phenazone degradation behavior the model results provided an excellent agreement between simulated and measured phenazone concentrations. Therefore, the fate of phenazone was shown to be indirectly controlled by the infiltration water temperature through its effect on the aquifer's redox conditions. Other factors such as variable residence times appeared to be of less importance.
authors.affiliation: Leibniz-Institut of Freshwater Ecology and Inland Fisheries, Berlin, Germany.
authors.forename: Janek
authors.initials: J
authors.lastname: Greskowiak
authors.forename: Henning
authors.initials: H
authors.lastname: Prommer
authors.forename: Gudrun
authors.initials: G
authors.lastname: Massmann
authors.forename: Gunnar
authors.initials: G
authors.lastname: Nützmann
mesh_terms: D000983:Antipyrine / Q000032:analysis / Q000633:toxicity*; D002138:Calibration; D004784:Environmental Monitoring / Q000379:methods; D005858:Germany; D006863:Hydrogen-Ion Concentration; D015233:Models, Statistical; D010084:Oxidation-Reduction; D010100:Oxygen / Q000378:metabolism; D012621:Seasons; D013997:Time Factors; D014867:Water / Q000032:analysis*; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000032:analysis*; D018508:Water Purification; D014881:Water Supply
chemical_list: D014874:Water Pollutants, Chemical; D014867:Water; D010100:Oxygen; D000983:Antipyrine