Asymmetric synthesis of isomerically pure allenyl boranes from alkynyl boranes through a 1,2-insertion-1,3-borotropic rearrangement.
Canales
Eda
E
Department of Chemistry, University of Puerto Rico, San Juan, Puerto Rico 00931-3346, USA.
Gonzalez
Ana Z
AZ
Soderquist
John A
JA
D000438:Alcohols / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D001880:Boranes / Q000138:chemical synthesis* / Q000737:chemistry*; D008745:Methylation; D015394:Molecular Structure; D010126:Ozone / Q000737:chemistry; D013237:Stereoisomerism
D000438:Alcohols; D000480:Alkynes; D001880:Boranes; D010126:Ozone