Trigonal-prismatic CuII6-pyrazolato cages: structural and electrochemical study, evidence of charge delocalisation.
Hexanuclear CuII-complexes of formula PPN[Cu6(micro3-O)2(micro-4-Rpz)6(micro-4-R'-3,5-Ph2pz)3] have been structurally characterized and the effect of pyrazole substituents on their two consecutive one-electron oxidation processes, leading to (possibly delocalised) mixed-valent products, has been probed by cyclic voltammetry.
Mezei
Gellert
G
Department of Chemistry, University of Puerto Rico, San Juan, PR 00931-3346.
Rivera-Carrillo
Marlyn
M
Raptis
Raphael G
RG
D003300:Copper / Q000737:chemistry*; D004563:Electrochemistry; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D011720:Pyrazoles / Q000737:chemistry*; D012680:Sensitivity and Specificity
D009942:Organometallic Compounds; D011720:Pyrazoles; D003300:Copper