A cyclic triphenylamine dimer for organic field-effect transistors with high performance.
A cyclic ethylene linked triphenylamine dimer formed highly crystalline thin film via vapor deposition. Meanwhile, the corresponding linear molecule only resulted in amorphous films under the same condition. The performance as FET semiconductor also improved significantly when the molecular structure derived from linear to cyclic type. The cyclic molecule displayed mobilities in excess of 10-2 cm2 V-1 s-1 and high on/off ratios up to 107.
Song
Yabin
Y
Key Laboratory of Organic Solids, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Science, Beijing 100080, PR China.
Di
Chong'an
C
Yang
Xiaodi
X
Li
Shouping
S
Xu
Wei
W
Liu
Yunqi
Y
Yang
Lianming
L
Shuai
Zhigang
Z
Zhang
Deqing
D
Zhu
Daoben
D
D002625:Chemistry, Organic; D003500:Cyclization; D019281:Dimerization; D015394:Molecular Structure; D055601:Organic Chemistry Phenomena; D010649:Phenylalanine / Q000737:chemistry*; D013696:Temperature; D014173:Transistors, Electronic
D010649:Phenylalanine