title: Highly enantioselective recognition of dicarboxylic acid substrates by the control of nonlinear responses.
abstract: An allosteric host, in which the molecular information of the chiral guest was precisely introduced, exhibits unconventional enantioselectivity toward the target enantiomer even under the conditions of a -20% enantiomeric excess (ee) mixture within a certain concentration window. This is effected by incorporation of the structural information of the enantiomer into the host and the utilization of multiple equilibrium.
authors.affiliation: Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395, Japan.
authors.forename: Tomohiro
authors.initials: T
authors.lastname: Ikeda
authors.forename: Osamu
authors.initials: O
authors.lastname: Hirata
authors.forename: Masayuki
authors.initials: M
authors.lastname: Takeuchi
authors.forename: Seiji
authors.initials: S
authors.lastname: Shinkai