Total synthesis of gymnoconjugatins A and B.
Convergent and efficient syntheses of the microbial natural products gymnoconjugatin A and B are reported and were based on a linchpin coupling strategy using a boron/tin hetero-bis-metallated butadiene system.
Coleman
Robert S
RS
Department of Chemistry, The Ohio State University, Columbus, Ohio 43210, USA. coleman@chemistry.ohio-state.edu
Walczak
Matthew C
MC
D001896:Boron Compounds / Q000737:chemistry; D005663:Furans / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009947:Organotin Compounds / Q000737:chemistry; D011753:Pyrones / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D001896:Boron Compounds; D005663:Furans; D009947:Organotin Compounds; D011753:Pyrones; C514632:gymnoconjugatin A; C514633:gymnoconjugatin B