title: Measuring and modelling experimental densities and ultrasonic velocities of aromatic and halogenated environmental pollutants.
abstract: The potential environmental impact of aromatic and halogenated chemicals from the petrochemical and steel industry is of growning concern. The present paper deals with the modelling and experimental determination of density and speed of sound at the range 278.15-323.15 of six aromatic and halogenated compounds (Benzene, Toluene, Ethylbenzene, Fluorobenzene, 2-Fluorotoluene and Chlorobenzene). Fitting equations were applied to the data in order to correlate for later computer based design. The estimation of the studied properties was made by the application of different theoretical procedures. The Mchaweh-Nasrifar-Moshfeghian model (MNM), an equation of state based on the generalized van der Waals theory which combines the Staverman-Guggenheim combinatorial term of lattice statistics with an attractive lattice gas expression and the Free Length Theory showed a good response at the studied conditions.
authors.affiliation: Departament d'Enginyeria Química, Escola Tècnica Superior d'Enginyeria Química, Universitat Rovira i Virgili, Avinguda Països Catalans 26, Campus Sescelades, 43007 Tarragona, Spain. miguelangel.iglesias@urv.net
authors.forename: M
authors.initials: M
authors.lastname: Iglesias
authors.forename: S
authors.initials: S
authors.lastname: Mattedi
authors.forename: R
authors.initials: R
authors.lastname: Gonzalez-Olmos
authors.forename: J M
authors.initials: JM
authors.lastname: Goenaga
authors.forename: J M
authors.initials: JM
authors.lastname: Resa
mesh_terms: D001555:Benzene Derivatives / Q000737:chemistry*; D003720:Densitometry; D004785:Environmental Pollutants / Q000737:chemistry*; D006846:Hydrocarbons, Halogenated / Q000737:chemistry*; D008962:Models, Theoretical; D013696:Temperature; D013816:Thermodynamics; D014465:Ultrasonics
chemical_list: D001555:Benzene Derivatives; D004785:Environmental Pollutants; D006846:Hydrocarbons, Halogenated