Diaquabis[5-(pyrazin-2-yl-kappaN(1))-1H-tetrazolato-kappaN(1)]manganese(II) and diaquabis[5-(pyrazin-2-yl-kappaN(1))-1H-tetrazolato-kappaN(1)]zinc(II).
The two new title complexes, [Mn(C5H3N6)2(H2O)2] and [Zn(C5H3N6)2(H2O)2], are isomorphous. In both compounds, the metal atom is located on an inversion center and is coordinated by four N atoms from two 5-(pyrazin-2-yl)-1H-tetrazolate anions in the basal plane and by two O atoms of water ligands in the apical positions to form a distorted octahedral geometry. Intermolecular hydrogen-bond interactions between the uncoordinated N atoms of the tetrazolate anions and the H atoms of the water molecules lead to the formation of a three-dimensional network.
Luo
Jun
J
School of Pharmacy, Second Military Medical University, Shanghai 200433, People's Republic of China. junluo30@263.net
Zhang
Xin Rong
XR
Cui
Li Li
LL
Dai
Wei Quan
WQ
Liu
Bao Shu
BS
D018360:Crystallography, X-Ray; D008345:Manganese / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
D009942:Organometallic Compounds; C517991:diaquabis(5-(pyrazin-2-yl-kappaN(1))-1H-tetrazolato-kappaN(1))manganese(II); C517992:diaquabis(5-(pyrazin-2-yl-kappaN(1))-1H-tetrazolato-kappaN(1))zinc(II); D008345:Manganese; D015032:Zinc