title: RuCl3-catalyzed oxidation of iodoarenes with peracetic acid: new facile preparation of iodylarenes.
abstract: New facile methodology for the preparation of pentavalent iodine compounds using peracetic acid as an oxidant in the presence of catalytic amounts of ruthenium trichloride is described. The new procedure allows the preparation of several previously unknown iodylarenes bearing strongly electron-withdrawing CF3 groups in the aromatic ring.
authors.affiliation: Department of Chemistry and Biochemistry, University of Minnesota Duluth, Duluth, Minnesota 55812, USA.
authors.forename: Alexey Y
authors.initials: AY
authors.lastname: Koposov
authors.forename: Rashad R
authors.initials: RR
authors.lastname: Karimov
authors.forename: Andrey A
authors.initials: AA
authors.lastname: Pronin
authors.forename: Tatyana
authors.initials: T
authors.lastname: Skrupskaya
authors.forename: Mekhman S
authors.initials: MS
authors.lastname: Yusubov
authors.forename: Viktor V
authors.initials: VV
authors.lastname: Zhdankin
mesh_terms: D002384:Catalysis; D006847:Hydrocarbons, Iodinated / Q000138:chemical synthesis* / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010463:Peracetic Acid / Q000737:chemistry*; D017975:Ruthenium Compounds / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D006847:Hydrocarbons, Iodinated; D017975:Ruthenium Compounds; D010463:Peracetic Acid; C038365:ruthenium chloride