title: Emissions and distribution of methyl bromide in field beds applied at two rates and covered with two types of plastic mulches.
abstract: A field experiment was conducted to compare two plastic mulches and two application rates on surface emissions and subsurface distribution of methyl bromide (MBr) in field beds in Florida. Within 30 minutes after injection of MBr to 30 cm depth, MBr had diffused upward to soil surface in all beds covered with polyethylene film (PE) or virtually impermeable film (VIF) and applied at a high rate (392 kg/ha) and a low rate (196 kg/ha). Due to the highly permeable nature of PE, within 30 minutes after injection, MBr volatilized from the bed surfaces of the two PE-covered beds into the atmosphere. The amount of volatilization was greater for the high rate-treatment bed. On the other hand, volatilization of MBr from the bed surfaces of the two VIF-covered beds were negligible. Volatilization losses occurred from the edges of all the beds covered with PE or VIF and were greater from the high rate-treatment beds. Initial vertical diffusion of MBr in the subsurface of the beds covered with PE or VIF was mainly upward, as large concentrations of MBr were detected from near bed surfaces to 20 cm depth in these beds 30 minutes after injection and little or no MBr was found at 40 cm depth. The two VIF-covered beds exhibited greater MBr concentrations and longer resident times in the root zone (0.5-40 cm depth) than corresponding PE-covered beds. Concentrations of MBr in the root zone of the high rate-treatment beds were 3.6-6.1 times larger than the low rate-treatment beds during the first days after application. In conclusion, VIF promoted retention of MBr in the root zone and, if volatilization loss from bed edges can be blocked, volatilization loss from VIF-covered beds should be negligible.
authors.affiliation: Soil and Water Science Department, University of Florida, Gainesville, FL 32611-0290, USA. LTO@ufl.edu
authors.forename: Li-Tse
authors.initials: LT
authors.lastname: Ou
authors.forename: John E
authors.initials: JE
authors.lastname: Thomas
authors.forename: L Hartwell
authors.initials: LH
authors.lastname: Allen
authors.forename: Joseph C
authors.initials: JC
authors.lastname: Vu
authors.forename: Donald W
authors.initials: DW
authors.lastname: Dickson
mesh_terms: D000383:Agriculture / Q000379:methods; D000393:Air Pollutants / Q000032:analysis*; D004305:Dose-Response Relationship, Drug; D004784:Environmental Monitoring; D006842:Hydrocarbons, Brominated / Q000032:analysis / Q000737:chemistry / Q000494:pharmacology*; D007700:Kinetics; D009676:Noxae / Q000032:analysis / Q000737:chemistry / Q000494:pharmacology*; D010969:Plastics; D012987:Soil / Q000032:analysis*; D014835:Volatilization
chemical_list: D000393:Air Pollutants; D006842:Hydrocarbons, Brominated; D009676:Noxae; D010969:Plastics; D012987:Soil; C005218:methyl bromide