title: Development of a solid-phase microextraction method with micellar desorption for the determination of chlorophenols in water samples. Comparison with conventional solid-phase microextraction method.
abstract: A novel analytical method is presented for the determination of chlorophenols in water. This method involves pre-concentration by solid-phase microextraction (SPME) and an external desorption using a micellar medium as desorbing agent. Final analysis of the selected chlorophenols compounds was carried out by high-performance liquid chromatography (HPLC) with diode array detection (DAD). Optimum conditions for desorption, using the non-ionic surfactant polyoxyethylene 10 lauryl ether (POLE), such as surfactant concentration and time were studied. A satisfactory reproducibility for the extraction of target compounds, between 6 and 15%, was obtained, and detection limits were in the range of 1.1-5.9ngmL(-1). The developed method is evaluated and compared with the conventional one using organic solvent as a desorbing agent. The method was successfully applied to the determination of chlorophenols in water samples from different origin. This study has demonstrated that solid-phase microextraction with micellar desorption (SPME-MD) can be used as an alternative to conventional SPME method for the extraction of chlorophenols in water samples.
authors.affiliation: Department of Chemistry, Faculty of Marine Sciences, University of Las Palmas de Gran Canaria, 35017 Las Palmas de Gran Canaria, Spain.
authors.forename: C Mahugo
authors.initials: CM
authors.lastname: Santana
authors.forename: M E Torres
authors.initials: ME
authors.lastname: Padrón
authors.forename: Z Sosa
authors.initials: ZS
authors.lastname: Ferrera
authors.forename: J J Santana
authors.initials: JJ
authors.lastname: Rodríguez
mesh_terms: D002733:Chlorophenols / Q000032:analysis*; D002851:Chromatography, High Pressure Liquid / Q000379:methods*; D008823:Micelles; D052616:Solid Phase Extraction / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D002733:Chlorophenols; D008823:Micelles; D014874:Water Pollutants, Chemical