title: Tracking pore to pore exchange using relaxation exchange spectroscopy.
abstract: We observe the movement of water over time between pores of differing sizes in Castlegate sandstone. To achieve this, we perform an NMR transverse relaxation exchange experiment for several mixing times. The resulting data are converted to 2D T2 distributions using a 2D inverse Laplace transform (ILT). We show for the first time that quantitative analysis of ILT distributions enables one to extract characteristic times for different pores sizes. This information is potentially useful for permeability determination as well as better understanding of exchange between specific pore subpopulations.
authors.affiliation: MacDiarmid Institute for Advanced Materials and Nanotechnology, School of Chemical and Physical Sciences, Victoria University of Wellington, New Zealand.
authors.forename: K E
authors.initials: KE
authors.lastname: Washburn
authors.forename: P T
authors.initials: PT
authors.lastname: Callaghan
mesh_terms: D009682:Magnetic Resonance Spectroscopy / Q000379:methods*