Synthesis of N-confused phlorins via an addition/cyclization pathway.
The syntheses of N-confused phlorins are provided by reactions of N-confused porphyrins with nitrilimines and with dialkyl acetylenedicarboxylate. Both reactions involve zwitterionic intermediates and proceed through an addition/cyclization pathway.
Li
Xiaofang
X
CAS Key Laboratory of Organic Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, PR China.
Chmielewski
Piotr J
PJ
Xiang
Junfeng
J
Xu
Jialiang
J
Jiang
Li
L
Li
Yuliang
Y
Liu
Huibiao
H
Zhu
Daoben
D
D003500:Cyclization; D003998:Dicarboxylic Acids / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy / Q000379:methods / Q000592:standards; D015394:Molecular Structure; D011166:Porphyrins / Q000138:chemical synthesis* / Q000737:chemistry; D012015:Reference Standards; D013237:Stereoisomerism
D003998:Dicarboxylic Acids; D007097:Imines; D047028:Macrocyclic Compounds; D011166:Porphyrins