Synthesis, structural characterization, and properties of aluminum (III) meso-tetraphenylporphyrin complexes axially bonded to phosphinate anions.
Aluminum (III) meso-tetraphenylporphyrins axially bonded to phosphinate anions have been synthesized and characterized by NMR and UV-visible spectroscopy, single-crystal X-ray diffraction, and FAB+ mass spectrometry. According to the solvent and the size of the anion, these compounds are able to self-assemble in two different manners.
Richeter
Sébastien
S
Laboratoire de Chimie Moléculaire et Organisation du Solide, UMR 5637, Université Montpellier II, CC 007, Place Eugène Bataillon, 34095 Montpellier Cedex 05, France. sricheter@univ-montp2.fr
Thion
Julien
J
van der Lee
Arie
A
Leclercq
Dominique
D