title: An example of lipophiloselectivity: the preferred oxidation, in water, of hydrophobic 2-alkanols catalyzed by a cross-linked polyethyleneimine-polyoxometalate catalyst assembly.
abstract: A cross-linked polyethyleneimine polymer containing the [ZnWZn2(H2O)2(ZnW9O34)2]12- polyoxometalate was prepared from branched polyethyleneimine (Mw = 600), the polyoxometalate, and a n-octylamine-epichlorohydrin cross-linking reagent. This catalytic assembly was active for the selective oxidation of 2-alkanols to 2-alkanones with aqueous H2O2 with reactions presumably occurring at a hydrophobic domain. Most importantly, the catalyst showed distinctive lipophiloselectivity, that is selectivity as a function of the lipophilic nature of a reaction substrate. The lipophiloselectivity was proportional to the relative partition coefficient (1-octanol/water) of the substrates.
authors.affiliation: Department of Organic Chemistry, Weizmann Institute of Science, Rehovot, Israel 76100.
authors.forename: Adina
authors.initials: A
authors.lastname: Haimov
authors.forename: Ronny
authors.initials: R
authors.lastname: Neumann