title: Aryl sulfoxides via palladium-catalyzed arylation of sulfenate anions.
abstract: [Structure: see text] Palladium-catalyzed arylation of sulfenate anions generated from beta-sulfinyl esters can take place under biphasic conditions. This hitherto unknown reaction provides a simple, mild, and efficient route to aryl sulfoxides in good yields. The development of a new pseudo-domino type I procedure involving a sulfinylation followed by a Mirozoki-Heck coupling is also described.
authors.affiliation: Université Pierre et Marie Curie-Paris 6, Laboratoire de Chimie Organique (UMR CNRS 7611), Institut de Chimie Moléculaire (FR 2769), Case 183, 4 Place Jussieu, F-75252, Paris Cedex 05, France.
authors.forename: Guillaume
authors.initials: G
authors.lastname: Maitro
authors.forename: Sophie
authors.initials: S
authors.lastname: Vogel
authors.forename: Guillaume
authors.initials: G
authors.lastname: Prestat
authors.forename: David
authors.initials: D
authors.lastname: Madec
authors.forename: Giovanni
authors.initials: G
authors.lastname: Poli