Score-moment combined linear discrimination analysis (SMC-LDA) as an improved discrimination method.
A new discrimination method called the score-moment combined linear discrimination analysis (SMC-LDA) has been developed and its performance has been evaluated using three practical spectroscopic datasets. The key concept of SMC-LDA was to use not only the score from principal component analysis (PCA), but also the moment of the spectrum, as inputs for LDA to improve discrimination. Along with conventional score, moment is used in spectroscopic fields as an effective alternative for spectral feature representation. Three different approaches were considered. Initially, the score generated from PCA was projected onto a two-dimensional feature space by maximizing Fisher's criterion function (conventional PCA-LDA). Next, the same procedure was performed using only moment. Finally, both score and moment were utilized simultaneously for LDA. To evaluate discrimination performances, three different spectroscopic datasets were employed: (1) infrared (IR) spectra of normal and malignant stomach tissue, (2) near-infrared (NIR) spectra of diesel and light gas oil (LGO) and (3) Raman spectra of Chinese and Korean ginseng. For each case, the best discrimination results were achieved when both score and moment were used for LDA (SMC-LDA). Since the spectral representation character of moment was different from that of score, inclusion of both score and moment for LDA provided more diversified and descriptive information.
Han
Jintae
J
Department of Chemistry, College of Natural Sciences, Hanyang University, Haengdang-Dong, Seongdong-Gu, Seoul, Korea 133-791.
Chung
Hoeil
H
Han
Sung-Hwan
SH
Yoon
Moon-Young
MY
D003627:Data Interpretation, Statistical; D004785:Environmental Pollutants / Q000737:chemistry; D009821:Oils / Q000737:chemistry; D005894:Panax / Q000737:chemistry; D025341:Principal Component Analysis; D012680:Sensitivity and Specificity; D012815:Signal Processing, Computer-Assisted; D013057:Spectrum Analysis / Q000379:methods*; D013270:Stomach / Q000737:chemistry; D013274:Stomach Neoplasms / Q000737:chemistry
D004785:Environmental Pollutants; D009821:Oils