title: Coordination symmetry-dependent structure restoration function of one-dimensional MOFs by molecular respiration.
abstract: One-dimensional metal-organic compounds with cis, trans symmetry-controlled counter anions were synthesized (cis compound {[Cu(azpy)(H2O)2(OTs)2]*2H2O*(acetone)} (1) and trans compound {[Cu(H2O)4Cu(azpy)2(OTs)2(H2O)2]*2(OTs)*2H2O*2EtOH} (2)). Only 2, having trans conformation, exhibited a complete structure-restoration effect with a mechanism involving layering of molecular "bricks" of water and solvent molecules.
authors.affiliation: Graduate School of Science and Technology, Chiba University, Yayoi, Inage, Chiba 263-8522, Japan.
authors.forename: Atsushi
authors.initials: A
authors.lastname: Kondo
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Noguchi
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Kajiro
authors.forename: Lucia
authors.initials: L
authors.lastname: Carlucci
authors.forename: Pierluigi
authors.initials: P
authors.lastname: Mercandelli
authors.forename: Davide M
authors.initials: DM
authors.lastname: Proserpio
authors.forename: Hideki
authors.initials: H
authors.lastname: Tanaka
authors.forename: Katsumi
authors.initials: K
authors.lastname: Kaneko
authors.forename: Hirofumi
authors.initials: H
authors.lastname: Kanoh