title: Silver(I) triflate-catalyzed direct synthesis of N-PMP protected alpha-aminopropargylphosphonates from terminal alkynes.
abstract: [reaction: see text] N-PMP protected alpha-aminopropargylphosphonates have been synthesized by using a silver(I) triflate-catalyzed one-pot three-component reaction of terminal alkynes, p-anisidine, and diethyl formylphosphonate hydrate. Good to excellent yields of the desired products may be obtained with a very simple procedure.
authors.affiliation: Department of Chemistry, University of Texas at San Antonio, One UTSA Circle, San Antonio, Texas 78249-0698, USA.
authors.forename: Rajasekhar
authors.initials: R
authors.lastname: Dodda
authors.forename: Cong-Gui
authors.initials: CG
authors.lastname: Zhao
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D000586:Amination; D001554:Benzene / Q000737:chemistry*; D002384:Catalysis; D008698:Mesylates / Q000737:chemistry*; D015394:Molecular Structure; D063065:Organophosphonates / Q000737:chemistry*
chemical_list: D000480:Alkynes; D008698:Mesylates; D063065:Organophosphonates; D001554:Benzene; C012077:trifluoromethanesulfonic acid