Layered heterometallic iodoplumbate containing a novel Pb3Cu6I16 net: structure and optical properties.
A new heterometallic iodoplumbate was synthesized solvothermally. The complex, [Co(phen)3][Pb3Cu6I16].C2H5OH, contains a novel Pb3Cu6I16 net made up of linked Pb3I11 and Cu6I11 clusters. The clusters form a BN-type layer, where the Pb3I11 and Cu6I11 clusters take the place of B and N. The layers, which are separated by [Co(phen)3]2+ cations, contain cavities in which ethanol molecules are located.
Burns
Michael C
MC
Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208, USA.
Tershansy
Meredith A
MA
Ellsworth
Joseph M
JM
Khaliq
Zeeshan
Z
Peterson
LeRoy
L
Smith
Mark D
MD
zur Loye
Hans-Conrad
HC