TCNQ dianion-based coordination polymer whose open framework shows charge-transfer type guest inclusion.
A three-dimensional coordination framework constructed with 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) diainon has been synthesized and structurally characterized. This open framework possessing a highly electron-rich surface has an optical sensing cavity for several aromatics with crystal-to-crystal transformation and strong accommodation, which are based on a charge-transfer interaction with them.
Shimomura
Satoru
S
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Matsuda
Ryotaro
R
Tsujino
Takashi
T
Kawamura
Takashi
T
Kitagawa
Susumu
S
D000838:Anions / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
D000838:Anions; D009570:Nitriles; D009942:Organometallic Compounds; D011108:Polymers; D011725:Pyridines; C013703:tetracyanoquinodimethane; D015032:Zinc