Biosorption of Pb2+ from aqueous solution by waste biomass of aerial roots of Rhizophora mangle (red mangrove).
The processing waste of the aerial roots of Rhizophora mangle was used in both its unmodified or mercaptoacetic acid (MAA) modified form for the sorption of Pb2+ from aqueous solution. The biomass rapidly and strongly sorbed Pb2+ at pH 5.0, which indicated chemisorption. A significant increase in Pb2+ sorption resulted from MAA treatment of the biomass, indicating that sorption occurs through an ion-exchange process. From sorption-capacity experiments, the unmodified and modified materials extracted, at pH 5, 31.3 and 85.5 mg of Pb2+ per gram of biomass, respectively, from aqueous solutions. Our studies may contribute to an innovative method for the economical and ecologically save removal and recovery of heavy-atom metal ions from contaminated waters through biosorption.
Horsfall
Michael
M
Department of Pure & Industrial Chemistry, University of Port Harcourt, P.O. Box 402, Choba, Port Harcourt, Nigeria. horsfalljnr@yahoo.com
Ogban
Fred
F
Akporhonor
Eyitemi Emmanuel
EE
D000327:Adsorption; D018533:Biomass; D006863:Hydrogen-Ion Concentration; D007854:Lead / Q000737:chemistry / Q000302:isolation & purification*; D018517:Plant Roots / Q000737:chemistry / Q000378:metabolism*; D043982:Rhizophoraceae / Q000737:chemistry / Q000378:metabolism*; D012996:Solutions / Q000737:chemistry; D013696:Temperature; D013864:Thioglycolates / Q000737:chemistry; D013995:Time; D014866:Waste Products / Q000032:analysis*
D012996:Solutions; D013864:Thioglycolates; D014866:Waste Products; D007854:Lead; C017487:2-mercaptoacetate