Why excess cyanide can be detrimental to Pd-catalyzed cyanation of haloarenes. Facile formation and characterization of [Pd(CN)(3)(H)](2-) and [Pd(CN)(3)(Ph)](2-).
Dobbs
Kerwin D
KD
Central Research and Development, E. I. DuPont de Nemours and Company, Inc., Experimental Station, Wilmington, Delaware 19880-0328, USA.
Marshall
William J
WJ
Grushin
Vladimir V
VV