Conversion of a Bi nanowire array to an array of Bi-Bi2O3 core-shell nanowires and Bi2O3 nanotubes.
A template-based heat-treatment method has been developed to convert metal nanowire arrays into arrays of metal-metal oxide core-shell nanowires and single-crystalline metal oxide nanotubes. This process is demonstrated by kinetically controlling the conversion of single-crystalline Bi nanowires to Bi-Bi(2)O(3) core-shell nanowires via a multistep, slow oxidation method, and then controlling their further conversion to a single-crystalline Bi(2)O(3) nanotube array via fast oxidation. This process can conveniently be extended to fabricate a free-standing, easily oxidized metal-metal oxide nanowire and metal oxide nanotube array, which may have future applications in nanoscale optics, electronics, and magnetics.
Li
Liang
L
Key Laboratory of Materials Physics, Anhui Key Laboratory of Nanomaterials and Nanotechnology, Institute of Solid State Physics, Chinese Academy of Sciences, Hefei 230031, China. liliang@issp.ac.cn
Yang
You-Wen
YW
Li
Guang-Hai
GH
Zhang
Li-De
LD
D001729:Bismuth / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D006358:Hot Temperature; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D043942:Nanotubes / Q000737:chemistry*; D010084:Oxidation-Reduction; D010316:Particle Size; D013499:Surface Properties
D046911:Macromolecular Substances; C033301:bismuth oxide; D001729:Bismuth