Coordination symmetry-dependent structure restoration function of one-dimensional MOFs by molecular respiration.
One-dimensional metal-organic compounds with cis, trans symmetry-controlled counter anions were synthesized (cis compound {[Cu(azpy)(H2O)2(OTs)2]*2H2O*(acetone)} (1) and trans compound {[Cu(H2O)4Cu(azpy)2(OTs)2(H2O)2]*2(OTs)*2H2O*2EtOH} (2)). Only 2, having trans conformation, exhibited a complete structure-restoration effect with a mechanism involving layering of molecular "bricks" of water and solvent molecules.
Kondo
Atsushi
A
Graduate School of Science and Technology, Chiba University, Yayoi, Inage, Chiba 263-8522, Japan.
Noguchi
Hiroshi
H
Kajiro
Hiroshi
H
Carlucci
Lucia
L
Mercandelli
Pierluigi
P
Proserpio
Davide M
DM
Tanaka
Hideki
H
Kaneko
Katsumi
K
Kanoh
Hirofumi
H