Highly stable electrochemical oxidation of phenolic compounds at carbon ionic liquid electrode.
A carbon ionic liquid electrode (CILE) was used for the investigation of the electrochemical oxidation of phenolic compounds in acidic media using cyclic voltammetry, chronoamperometry and square wave voltammetry techniques. The results indicate that, contrary to many other electrodes, the oxidation of phenolic compounds on CILE is highly stable and does not result in electrode fouling. Cyclic voltammetry showed that phenolic compounds such as phenol, 2,4-dichlorophenol and catechol were oxidized at CILE and remained electroactive after multiple cycles and at high concentrations of phenol. The cyclic voltammetric response of the CILE is very stable with more than 99% of the initial activity remaining after 20 s of stirring of a 0.5 mM solution of phenol.
Safavi
Afsaneh
A
Department of Chemistry, College of Sciences, Shiraz University, Shiraz, 71454 Iran. safavi@ chem.susc.ac.ir
Maleki
Norouz
N
Tajabadi
Fariba
F
D002244:Carbon; D004563:Electrochemistry / Q000295:instrumentation / Q000379:methods; D004566:Electrodes; D004785:Environmental Pollutants / Q000032:analysis*; D007477:Ions; D010636:Phenols / Q000032:analysis*
D004785:Environmental Pollutants; D007477:Ions; D010636:Phenols; D002244:Carbon