[Synthesis of heteroaromatic N-beta-glycosides of N-acetylglucosamine under the conditions of phase transfer catalysis: I. Glucosaminides of 2-oxobenzazoles].
Glycosylation of methylbenzoxazolone-2 and benzothiazolone-2 with the full acetate of alpha-D-glucosaminyl chloride in the phase transfer systems investigated (solid-organic solvent and aqueous alkali-organic solvent) regioselectively leads to the corresponding N-beta-D-glucosaminides, which is proved by 1H NMR spectroscopy and X-ray analysis.
Kur'ianov
V O
VO
Chupakhina
T A
TA
Zemliakov
A E
AE
Chirva
V Ia
VIa
Shishkin
O V
OV
Shishkina
S V
SV
Kotliar
S A
SA
Kamalov
G L
GL
D000117:Acetylglucosamine / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D006027:Glycosides / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
D006027:Glycosides; D000117:Acetylglucosamine