title: Brilliant Sm, Eu, Tb, and Dy chiral lanthanide complexes with strong circularly polarized luminescence.
abstract: The synthesis, characterization, and luminescent behavior of trivalent Sm, Eu, Dy, and Tb complexes of two enantiomeric, octadentate, chiral, 2-hydroxyisophthalamide ligands are reported. These complexes are highly luminescent in solution. Functionalization of the achiral parent ligand with a chiral 1-phenylethylamine substituent on the open face of the complex in close proximity to the metal center yields complexes with strong circularly polarized luminescence (CPL) activity. This appears to be the first example of a system utilizing the same ligand architecture to sensitize four different lanthanide cations and display CPL activity. The luminescence dissymmetry factor, g(lum), recorded for the Eu(III) complex is one of the highest values reported, and this is the first time the CPL effect has been demonstrated for a Sm(III) complex with a chiral ligand. The combination of high luminescence intensity with CPL activity should enable new bioanalytical applications of macromolecules in chiral environments.
authors.affiliation: Department of Chemistry, University of California, Berkeley, California 94720, USA.
authors.forename: Stéphane
authors.initials: S
authors.lastname: Petoud
authors.forename: Gilles
authors.initials: G
authors.lastname: Muller
authors.forename: Evan G
authors.initials: EG
authors.lastname: Moore
authors.forename: Jide
authors.initials: J
authors.lastname: Xu
authors.forename: Jurek
authors.initials: J
authors.lastname: Sokolnicki
authors.forename: James P
authors.initials: JP
authors.lastname: Riehl
authors.forename: Uyen N
authors.initials: UN
authors.lastname: Le
authors.forename: Seth M
authors.initials: SM
authors.lastname: Cohen
authors.forename: Kenneth N
authors.initials: KN
authors.lastname: Raymond
mesh_terms: D002942:Circular Dichroism; D004419:Dysprosium / Q000737:chemistry; D005063:Europium / Q000737:chemistry; D028581:Lanthanoid Series Elements / Q000138:chemical synthesis / Q000737:chemistry*; D008024:Ligands; D049449:Luminescence; D008163:Luminescent Measurements / Q000379:methods*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012493:Samarium / Q000737:chemistry; D012996:Solutions / Q000737:chemistry; D013725:Terbium / Q000737:chemistry; D014466:Ultraviolet Rays
chemical_list: D028581:Lanthanoid Series Elements; D008024:Ligands; D009942:Organometallic Compounds; D012996:Solutions; D013725:Terbium; D004419:Dysprosium; D012493:Samarium; D005063:Europium