Significant change of alignment effect by dimer formation in the dissociative energy transfer reaction of Ar(3P2)+(N2O)n and (H2O)n.
An alignment effect in the dissociative energy transfer reaction of Ar((3)P(2))+(X(2)O)(n)(X=N,H) was directly measured using an oriented Ar((3)P(2),M(J)=2) beam. The chemiluminescence intensity of N(2)(B,(3)Pi(g)) for (N(2)O)(n) and OH(A,(2)Sigma(+)) for (H(2)O)(n) was measured as a function of the magnetic orientation field direction in the collision frame. The relative reaction cross section for each magnetic substate in the collision frame, sigma(M(J) (') ), was determined. In both the reaction systems, it is observed that the dimer formation significantly enhances the alignment effect and decreases the reactivity, especially for sigma|1| and sigma|2|. A significant contribution of rank 4 moment is recognized in the dimer reaction.
Watanabe
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D
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, Japan.
Ohoyama
H
H
Matsumura
T
T
Kasai
T
T