An efficient electrochemical synthesis of diamino-o-benzoquinone: mechanistic and kinetic evaluation of the reaction of azide ion with o-benzoquinone.
An efficient method for the synthesis of diamino-o-benzoquinone based on the Michael reaction of electrochemically generated o-benzoquinone with azide ion is described, as well as an estimation of the homogeneous rate constant (k(obs)) of the reaction of o-benzoquinone with azide ion by the digital-simulation method.
Nematollahi
Davood
D
Faculty of Chemistry, University of Bu-Ali-Sina, Hamadan, 65174, Iran. nemat@basu.ac.ir
Afkhami
Abbas
A
Tammari
Esmail
E
Shariatmanesh
Tahere
T
Hesari
Mahdi
M
Shojaeifard
Maryam
M