title: TCNQ dianion-based coordination polymer whose open framework shows charge-transfer type guest inclusion.
abstract: A three-dimensional coordination framework constructed with 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) diainon has been synthesized and structurally characterized. This open framework possessing a highly electron-rich surface has an optical sensing cavity for several aromatics with crystal-to-crystal transformation and strong accommodation, which are based on a charge-transfer interaction with them.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
authors.forename: Satoru
authors.initials: S
authors.lastname: Shimomura
authors.forename: Ryotaro
authors.initials: R
authors.lastname: Matsuda
authors.forename: Takashi
authors.initials: T
authors.lastname: Tsujino
authors.forename: Takashi
authors.initials: T
authors.lastname: Kawamura
authors.forename: Susumu
authors.initials: S
authors.lastname: Kitagawa
mesh_terms: D000838:Anions / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry; D015032:Zinc / Q000737:chemistry
chemical_list: D000838:Anions; D009570:Nitriles; D009942:Organometallic Compounds; D011108:Polymers; D011725:Pyridines; C013703:tetracyanoquinodimethane; D015032:Zinc