Phosphorus-nitrogen compounds: synthesis and spectral investigations on new spiro-cyclic phosphazene derivatives.
The condensation reaction of {N-[(2-hydroxyphenylmethyl)amino]-4,6-dimethylpyridine} (2), which is a reduction product of 1, with trimer N(3)P(3)Cl(6) affords partially a substituted spiro-cyclic phosphazene derivative (3). The fully substituted phosphazenes (4 and 5) have also been obtained from the reactions of 3 with the excess of pyrrolidine and morpholine. The characterizations and spectral investigations of these compounds have been made by elemental analyses, FTIR, 1H-, 13C-, 31P NMR, correlation spectroscopy (COSY), heteronuclear chemical shift correlation (HETCOR), heteronuclear multiple-bond correlation (HMBC) and mass spectroscopy (MS). The salient features of spectral data of these compounds have been discussed.
Dal
Hakan
H
Department of Chemistry, Faculty of Science, Anadolu University, 26470 Yenibağlar, Eskişehir, Turkey. hakandal@anadolu.edu.tr
Süzen
Yasemin
Y
D002247:Carbon Isotopes; D006859:Hydrogen; D009682:Magnetic Resonance Spectroscopy; D017672:Nitrogen Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010758:Phosphorus / Q000737:chemistry*; D013141:Spiro Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D002247:Carbon Isotopes; D017672:Nitrogen Compounds; D009943:Organophosphorus Compounds; D013141:Spiro Compounds; D010758:Phosphorus; D006859:Hydrogen