title: Chemical modification of wheat protein-based natural polymers: cross-linking effect on mechanical properties and phase structures.
abstract: Chemical modification of wheat protein-based natural polymer materials was conducted using glyoxal as cross-linker, and the cross-linking effect was studied on mechanical properties under different humidity conditions, the molecular motions of each component, and the phase structures/components of the whole materials. The cross-linking significantly enhanced the mechanical strength of wheat gluten (WG) materials under RH = 50%. The elongation of materials was also increased, which was in contrast to many cross-linked protein systems. The reaction mainly occurred in proteins and starch components, resulting in the formation of a stable cross-linked network with restricted molecular motions and modified motional dynamics. Although the plasticizer glycerol could also take part in the reaction with glyoxal or other components in WG especially when the glyoxal content was higher, the amount of glycerol involved in such reactions was very little. Glycerol was predominantly hydrogen-bonded with the network. The lipid component did not seem to take part in the cross-linking reaction; its mobility was promoted while its interaction with the protein-starch network was weakened after cross-linking. The formation of the cross-linked network did not enhance the hydrophobicity of the materials; the materials still adsorbed a high level of moisture under high humidity conditions (ca. RH = 85%) with no improvement in mechanical strength. In addition, further increasing the amount of glyoxal did not generate an additional strength improvement even at RH = 50%, possibly because the enhanced mobility of lipid promoted the component to be phase-separated from the WG system. To improve the water-resistant properties, the hydrophobicity of the protein macromolecules requires enhancement by other chemical modifications.
authors.affiliation: CSIRO Manufacturing & Materials Technology, Private Bag 33, Clayton South MDC, Clayton South, VIC 3169, Australia. Xiaoqing.Zhang@csiro.au
authors.forename: Xiaoqing
authors.initials: X
authors.lastname: Zhang
authors.forename: Pam
authors.initials: P
authors.lastname: Hoobin
authors.forename: Iko
authors.initials: I
authors.lastname: Burgar
authors.forename: My Dieu
authors.initials: MD
authors.lastname: Do
mesh_terms: D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003432:Cross-Linking Reagents; D009682:Magnetic Resonance Spectroscopy; D010940:Plant Proteins / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013010:Sonication; D013718:Tensile Strength; D014908:Triticum / Q000737:chemistry*
chemical_list: D003432:Cross-Linking Reagents; D010940:Plant Proteins; D011108:Polymers