title: Geochemistry of the barkinite liptobiolith (Late Permian) from the Jinshan Mine, Anhui Province, China.
abstract: This paper discusses the geochemistry and mineralogy of the barkinite liptobiolith of the Late Permian age from the Jinshan Mine, Guangde County, Anhui Province, China. Samples were examined using inductively coupled plasma-mass spectroscopy, X-ray fluorescence, cold-vapor atomic absorption spectrometry, ion-selective electrode, sequential chemical extraction, scanning electron microscopy equipped with energy-dispersive X-ray, and optical microscopy. The coal is a medium-ash and high-sulfur resource. Minerals in the coal are composed of kaolinite, pyrite, calcite, and quartz. Pyrite and calcite are derived from seawater during peat accumulation. Quartz in the coal is of authigenic origin. Part of the kaolinite is from a land-source region, and part occurs as cell-fillings and is of authigenic origin. The results also indicate that the barkinite liptobiolith contains some toxic elements in high concentrations. Elements including Li, Be, Si, Sc, Ti, V, Cr, Fe, Ga, Se, Y, Zr, Mo, the rare earth elements (REEs), W, Hg, Tl, Pb, Th, and U in the coals are enriched in the barkinite liptobiolith. Results of sequential chemical extraction showed that Li, Sc, Ti, Cr, Y, Zr, REEs, and Th in the coal mainly occur as silicates, while Be and W are related to organic matter. Pyrite is the dominant source of S, Mo, Hg, Tl, and Pb. Gallium only occurs in silicate, and U and V occur both in organic and silicate associations.
authors.affiliation: Key Laboratory of Resource Exploration Research of Hebei Province, Hebei University of Engineering, Guangmingnan Street 195, Handan, Hebei 056038, China. sun_yz@hotmail.com
authors.forename: Yuzhuang
authors.initials: Y
authors.lastname: Sun
authors.forename: Mingyue
authors.initials: M
authors.lastname: Lin
authors.forename: Peng
authors.initials: P
authors.lastname: Qin
authors.forename: Cunliang
authors.initials: C
authors.lastname: Zhao
authors.forename: Kankun
authors.initials: K
authors.lastname: Jin
mesh_terms: D002681:China; D003031:Coal / Q000032:analysis; D003032:Coal Mining; D008670:Metals / Q000032:analysis*
chemical_list: D003031:Coal; D008670:Metals