Electronic structure and solvatochromism of merocyanines NMR spectroscopic point of view.
(1)H and (13)C NMR spectra of two series of malononitrile-based merocyanines, which possess positive and negative solvatochromism have been in detail investigated in low polar chloroform and polar dimethyl sulfoxide (DMSO). Careful attribution of signals in spectra has been made with the help of two-dimensional NMR experiments (COSY, NOESY, HMBC, and HMQC). Hence, the dependence of merocyanines electronic structure on their chemical structure and solvent nature has been studied by this powerful method. It has been shown that there exists a good correlation between the calculated charges on carbon atoms of a polymethine chain and their chemical shifts in (13)C NMR spectra. The influence of solvent polarity on bond orders for dyes with positive and negative solvatochromism is also observed. The comparison of (13)C NMR spectra of merocyanines and corresponding parent ionic dyes allows to determine their sign of solvatochromism irrespectively of electronic spectra, and also to find the key atoms of chromophore whose signals in (13)C NMR spectra are most informative.
Kulinich
Andrii V
AV
Taras Shevchenko Kyiv National University, Volodymyrska Street 64, Kyiv-01033, Ukraine. kulinich@univ.kiev.ua
Ishchenko
Alexander A
AA
Groth
Ulrich M
UM
D000042:Absorption; D002244:Carbon / Q000737:chemistry; D002621:Chemistry / Q000379:methods; D004563:Electrochemistry / Q000379:methods; D004581:Electronics; D004583:Electrons; D005456:Fluorescent Dyes / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000295:instrumentation* / Q000379:methods; D008956:Models, Chemical; D011744:Pyrimidinones / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013053:Spectrophotometry / Q000379:methods; D013056:Spectrophotometry, Ultraviolet / Q000379:methods
D005456:Fluorescent Dyes; D011744:Pyrimidinones; D012997:Solvents; C003954:merocyanine dye; D002244:Carbon