Electrochemical synthesis of cobalt hydroxide films with tunable interlayer spacings.
An electrochemical synthetic condition is developed to produce cobalt hydroxide films with significantly increased basal spacings (d(001)>or= 25.0 A) by incorporating anionic surfactants (i.e. sodium dodecyl sulfate and 1-hexadecanesulfonate) into the interlayer regions via electrodeposition.
Yarger
Matthew S
MS
Department of Chemistry, Purdue University, West Lafayette, IN 47907, USA.
Steinmiller
Ellen M P
EM
Choi
Kyoung-Shin
KS
D017738:Alkanesulfonic Acids / Q000737:chemistry; D003035:Cobalt / Q000737:chemistry*; D004563:Electrochemistry; D004566:Electrodes; D006878:Hydroxides / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D053838:Scattering, Small Angle; D012967:Sodium Dodecyl Sulfate / Q000737:chemistry; D014961:X-Ray Diffraction
D017738:Alkanesulfonic Acids; D006878:Hydroxides; C518276:cobalt hydroxide; D012967:Sodium Dodecyl Sulfate; D003035:Cobalt; C025737:cetylsulfonic acid; C025913:cobaltous nitrate