title: Sequential separation of lanthanides, thorium and uranium using novel solid phase extraction method from high acidic nuclear wastes.
abstract: A novel grafted polymer for selective extraction and sequential separation of lanthanides, thorium and uranium from high acidic wastes has been developed by grafting Merrifield chloromethylated (MCM) resin with octyl(phenyl)-N,N-diisobutylcarbamoyl-methylphosphine oxide (CMPO) (MCM-CMPO). The grafting process is well characterized using FT-IR spectroscopy, (31)P and (13)C CPMAS (cross-polarized magic angle spin) NMR spectroscopy and CHNPS elemental analysis. The influence of various physico-chemical parameters during metal ion extraction by the resin phase are studied and optimized by both static and dynamic methods. The resin shows very high sorption capacity values of 0.960mmolg(-1) for U(VI), 0.984mmolg(-1) for Th(IV), 0.488mmolg(-1) for La(III) and 0.502mmolg(-1) for Nd(III) under optimum HNO(3) medium, respectively. The grafted polymer shows faster rate exchange kinetics (<5min is sufficient for 50% extraction) and greater preconcentration ability, with reusability exceeding 20 cycles. During desorption process, sequential separation of the analytes is possible with varying eluting agents. The developed grafted resin has been successfully applied in extracting Th(IV) from high matrix monazite sand, U(VI) and Th(IV) from simulated nuclear spent fuel mixtures. All the analytical data is based on triplicate analysis and measurements are within 3.5% rsd reflecting the reproducibility and reliability of the developed method.
authors.affiliation: Department of Chemistry, Indian Institute of Technology, Chennai 600036, India.
authors.forename: Ch Siva
authors.initials: ChS
authors.lastname: Kesava Raju
authors.forename: M S
authors.initials: MS
authors.lastname: Subramanian
mesh_terms: D028581:Lanthanoid Series Elements / Q000302:isolation & purification*; D008956:Models, Chemical; D015394:Molecular Structure; D011850:Radioactive Waste / Q000032:analysis*; D012117:Resins, Synthetic / Q000138:chemical synthesis / Q000737:chemistry; D052616:Solid Phase Extraction; D017550:Spectroscopy, Fourier Transform Infrared; D013910:Thorium / Q000302:isolation & purification*; D014501:Uranium / Q000302:isolation & purification*
chemical_list: D028581:Lanthanoid Series Elements; D011850:Radioactive Waste; D012117:Resins, Synthetic; D014501:Uranium; D013910:Thorium