title: Detection and spectral analysis of trifluoromethyl groups at a surface by sum frequency generation vibrational spectroscopy.
abstract: Sum frequency generation (SFG) vibrational spectroscopy was used to detect the presence of trifluoromethyl groups on the surface of 4-(trifluoromethyl)benzyl alcohol (TFMBA) in air. Supplementary data from infrared and Raman spectra were correlated to ab initio calculations by use of density functional theory (DFT) for TFMBA and three related compounds to reliably assign vibrational modes to the spectra. It was shown that strongly ordered CF3 groups dominate the surface of the TFMBA, and the vibrational modes of this functional group are strongly coupled to the benzene ring of the benzyl alcohol. This coupling, along with the SFG activity of the CF3 group, is removed with the insertion of an oxygen atom between the CF3 group and the benzene ring.
authors.affiliation: Department of Chemistry, 930 North University Avenue, University of Michigan, Ann Arbor, Michigan 48109, USA.
authors.forename: Mark A
authors.initials: MA
authors.lastname: Even
authors.forename: Sang-Ho
authors.initials: SH
authors.lastname: Lee
authors.forename: Jie
authors.initials: J
authors.lastname: Wang
authors.forename: Zhan
authors.initials: Z
authors.lastname: Chen