Rh-catalyzed intermolecular reactions of alkynes with alpha-diazoesters that possess beta-hydrogens: ligand-based control over divergent pathways.
Panne
Patricia
P
Brown Laboratories, Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA.
Fox
Joseph M
JM
D000480:Alkynes / Q000737:chemistry*; D001391:Azo Compounds / Q000737:chemistry*; D002384:Catalysis; D003521:Cyclopropanes / Q000138:chemical synthesis*; D006859:Hydrogen / Q000737:chemistry; D008024:Ligands; D009942:Organometallic Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
D000480:Alkynes; D001391:Azo Compounds; D003521:Cyclopropanes; D008024:Ligands; D009942:Organometallic Compounds; D006859:Hydrogen; D012238:Rhodium