1,4,8,11-Tetraazacyclotetradecane antimony(III) sulfide.
Poly[1,4,8,11-tetraazacyclotetradecane(2+) [hepta-mu-sulfido-trisulfidohexaantimony(III)]], {(C10H26N4)[Sb6S10]}n, consists of novel [Sb6S10]2- layers containing Sb2S2, Sb4S4 and Sb7S7 hetero-rings, which are separated by macrocyclic amine molecules. The macrocyclic amine molecules are disordered over two crystallographically distinct positions and are diprotonated in order to balance the charge of the anionic layers.
Lees
Rachel J E
RJ
Department of Chemistry, Heriot-Watt University, Edinburgh EH14 4AS, Scotland.
Powell
Anthony V
AV
Watkin
David J
DJ
Chippindale
Ann M
AM