Investigation on the transition crystal of ordinary rutile TiO2 powder by microwave irradiation in hydrogen peroxide solution and its sonocatalytic activity.
The transition crystal TiO(2) catalyst with high sonocatalytic activity was obtained utilizing the microwave irradiation in hydrogen peroxide solution. At the same time a series of affecting factors (microwave irradiation time, heat-treated time and heat-treated temperature) to prepare the TiO(2) catalyst on the sonocatalytic degradation of parathion were considered in this paper. The ultrasound of low power was used as an irradiation source to induce treated TiO(2) particles to perform catalytic activity. The results show that the sonocatalytic activity of the transition crystal TiO(2) powder is obviously higher than those of pure ordinary rutile and anatase TiO(2) powders. At last, the parathion in aqueous solution was degraded completely and became some simple inorganic ions such as NO(3)(-), PO(4)(3-), SO(4)(2-), etc. The degradation ratio of parathion in the presence of the transition crystal TiO(2) catalyst attains nearly 80% within 60 min ultrasonic irradiation, while corresponding ones are only 65.23% and 53.88%, respectively, for pure ordinary rutile and anatase TiO(2) powders.
Wang
Jun
J
Department of Chemistry, Liaoning University, Shenyang 110036, PR China. Electronic address: wangjun890@126.com.
Ma
Teng
T
Department of Chemistry, Liaoning University, Shenyang 110036, PR China.
Zhang
Zhaohong
Z
Department of Environment, Liaoning University, Shenyang 110036, PR China.
Zhang
Xiangdong
X
Department of Chemistry, Liaoning University, Shenyang 110036, PR China.
Jiang
Yuefeng
Y
Department of Chemistry, Liaoning University, Shenyang 110036, PR China.
Sun
Wei
W
Department of Chemistry, Liaoning University, Shenyang 110036, PR China.
Li
Ronghe
R
Department of Chemistry, Liaoning University, Shenyang 110036, PR China.
Zhang
Peng
P
Center of Analysis and Test, Liaoning University, Shenyang 110036, PR China.