Tetraalkylphosphonium polyoxometalates: electroactive, "task-specific" ionic liquids.
The pairing of selected polyoxometalate (POM) anions with appropriate tetraalkylphosphonium cations is shown to yield an original family of ionic liquids, among them an ambient-temperature "liquid POM".
Rickert
Paul G
PG
Chemistry Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, USA.
Antonio
Mark R
MR
Firestone
Millicent A
MA
Kubatko
Karrie-Ann
KA
Szreder
Tomasz
T
Wishart
James F
JF
Dietz
Mark L
ML
D000838:Anions; D002384:Catalysis; D002412:Cations; D004563:Electrochemistry; D052578:Ionic Liquids / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry; D010084:Oxidation-Reduction; D012997:Solvents; D013696:Temperature; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
D000838:Anions; D002412:Cations; D052578:Ionic Liquids; D009943:Organophosphorus Compounds; D012997:Solvents; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates