Bis[bis(methoxycarbimido)amine-kappa2N,N']bis(perchlorato-kappaO)copper(II) bis[bis(methoxycarbimido)amine-kappa2N,N']bis(methanol-kappaO)copper(II) bis(perchlorate) methanol disolvate.
The title compound, [Cu(ClO4)2(C4H9N3O2)2][Cu(C4H9N3O2)2(CH4O)2](ClO4)2.2CH3OH, comprises two independent Cu(II) species lying on different inversion sites. In the Cu complexes, a distorted octahedral geometry arises (from basic square-planar N4 coordination) from the weak coordination of two perchlorate ions (as Cu-O) in one species and two methanol molecules in the other (also as Cu-O). Interactions between the O atoms of the perchlorate anions or methanol groups and the imide or amine NH groups afford an extensive intermolecular hydrogen-bonding network.
Liu
Guang Fei
GF
Key Laboratory of Organic Synthesis of Jiangsu Province, School of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215123, Jiangsu, People's Republic of China.
Li
Lin Lin
LL
Zhang
Yong
Y
Lang
Jian Ping
JP
Ng
Seik Weng
SW