Iridium-catalyzed C-C bond forming hydrogenation: direct regioselective reductive coupling of alkyl-substituted alkynes to activated ketones.
Ngai
Ming-Yu
MY
Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712, USA.
Barchuk
Andriy
A
Krische
Michael J
MJ
D000480:Alkynes / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000138:chemical synthesis* / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry; D006860:Hydrogen Bonding; D006865:Hydrogenation; D007495:Iridium / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D000480:Alkynes; D004952:Esters; D007659:Ketones; D009942:Organometallic Compounds; D007495:Iridium; D002244:Carbon; D006859:Hydrogen