title: Rhodium diphosphite pincer complexes. Rare preferred in-plane olefin conformation in square-planar compounds.
abstract: Square-planar ethylene rhodium derivatives bearing pincer diphosphite ligands have been prepared and characterized, they display a rare in-plane coordination which, based on DFT calculations, has been mainly attributed to steric effects.
authors.affiliation: Instituto de Investigaciones Químicas, Consejo Superior de Investigaciones Científicas and Universidad de Sevilla, Avda Américo Vespucio no. 49, Isla de la Cartuja, 41092, Sevilla, Spain.
authors.forename: Miguel
authors.initials: M
authors.lastname: Rubio
authors.forename: Andrés
authors.initials: A
authors.lastname: Suárez
authors.forename: Diego
authors.initials: D
authors.lastname: del Río
authors.forename: Agustín
authors.initials: A
authors.lastname: Galindo
authors.forename: Eleuterio
authors.initials: E
authors.lastname: Alvarez
authors.forename: Antonio
authors.initials: A
authors.lastname: Pizzano