Diruthenium, diiron and mixed ruthenium-iron tetraiminediphenolate macrocyclic complexes: synthetic route, spectroscopy, molecular mechanics and redox properties.
A series of diruthenium(II), [Ru(2)(tidf)Cl(2)(H(2)O)(2)] x H(2)O, diiron(II) [Fe(2)(tidf)(MeOH)(4)](ClO(4))(2) and mixed ruthenium(II)-iron(II) [Ru(MeOH)(2)FeCl(H(2)O)(tidf)](ClO(4)) (tidf=a two compartment tetraiminediphenolate macrocycle) complexes were prepared and characterized by elemental analysis, FTIR, UV-vis, cyclic voltammetry and semi-empirical molecular mechanics calculations.
Raimondi
Angela C
AC
Departamento de Química, Universidade Federal do Paraná, Centro Politécnico, C.P. 19081, 81531-990 Curitiba, PR, Brazil.
Evans
David J
DJ
Hasegawa
Tai
T
Drechsel
Sueli M
SM
Nunes
Fábio S
FS
D006575:Heterocyclic Compounds, 3-Ring / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008274:Magnesium / Q000737:chemistry; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D012428:Ruthenium / Q000737:chemistry*; D013053:Spectrophotometry; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D015204:Spectroscopy, Mossbauer
D006575:Heterocyclic Compounds, 3-Ring; D009942:Organometallic Compounds; D012428:Ruthenium; D007501:Iron; D008274:Magnesium