title: Tetraalkylphosphonium polyoxometalates: electroactive, "task-specific" ionic liquids.
abstract: The pairing of selected polyoxometalate (POM) anions with appropriate tetraalkylphosphonium cations is shown to yield an original family of ionic liquids, among them an ambient-temperature "liquid POM".
authors.affiliation: Chemistry Division, Argonne National Laboratory, 9700 South Cass Avenue, Argonne, IL 60439, USA.
authors.forename: Paul G
authors.initials: PG
authors.lastname: Rickert
authors.forename: Mark R
authors.initials: MR
authors.lastname: Antonio
authors.forename: Millicent A
authors.initials: MA
authors.lastname: Firestone
authors.forename: Karrie-Ann
authors.initials: KA
authors.lastname: Kubatko
authors.forename: Tomasz
authors.initials: T
authors.lastname: Szreder
authors.forename: James F
authors.initials: JF
authors.lastname: Wishart
authors.forename: Mark L
authors.initials: ML
authors.lastname: Dietz
mesh_terms: D000838:Anions; D002384:Catalysis; D002412:Cations; D004563:Electrochemistry; D052578:Ionic Liquids / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry; D010084:Oxidation-Reduction; D012997:Solvents; D013696:Temperature; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D000838:Anions; D002412:Cations; D052578:Ionic Liquids; D009943:Organophosphorus Compounds; D012997:Solvents; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates