Asymmetric self-assembly with atmospheric CO2 fixation of a pentanuclear carbonate NiI) complex based on dissimilar building blocks.
Formation in basic solution of an asymmetric pentanuclear carbonate Ni(II) complex with a compartmental ligand involves atmospheric CO(2) uptake, either by reaction of two slightly different dinuclear precursors that yield its di- and trinuclear "building blocks", or directly, by spontaneous self-organization of metal and ligand starting reactants.
Fondo
Matilde
M
Dpto. de Química Inorgánica, Fac. de Ciencias. Univ. de Santiago de Compostela, Campus Univeristario, 27002, Lugo, Spain. qimatf69@usc.es
García-Deibe
Ana M
AM
Ocampo
Noelia
N
Sanmartín
Jesús
J
Bermejo
Manuel R
MR