Synthesis and characterization of difluoromethylene-homo[60]fullerene, C60(CF2).
Refluxing of the o-DCB solution of C60 with CF2ClCOONa and 18-crown-6 leads to formation of C60(CF2)n (n = 1-3); the monoadduct C60(CF2) has been found to consist of the main [6,6]- and minor [5,6]-isomers, both having an open structure.
Pimenova
Anna S
AS
Chemistry Department, Moscow State University, Moscow 119992, Russia.
Kozlov
Andrey A
AA
Goryunkov
Alexey A
AA
Markov
Vitaliy Yu
VY
Khavrel
Pavel A
PA
Avdoshenko
Stanislav M
SM
Ioffe
Ilya N
IN
Sakharov
Sergey G
SG
Troyanov
Sergey I
SI
Sidorov
Lev N
LN