Enantiopure pseudo-C3-symmetric titanium alkoxide with propeller-like chirality.
An enantiopure amine tris(phenolate) ligand containing a single stereogenic center has been used to control the propeller-like chirality of a derived pseudo-C3-symmetric titanium isopropoxide complex with excellent levels of diastereocontrol. [structure: see text].
Axe
Philip
P
Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK.
Bull
Steven D
SD
Davidson
Matthew G
MG
Gilfillan
Carly J
CJ
Jones
Matthew D
MD
Robinson
Diane E J E
DE
Turner
Luke E
LE
Mitchell
William L
WL
D018360:Crystallography, X-Ray; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013237:Stereoisomerism; D014025:Titanium / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D014025:Titanium