title: Vertical distribution and speciation of trace metals in weathering flotation residues of a zinc/lead sulfide mine.
abstract: Sulfide-bearing mine tailings are a serious environmental problem around the world. In this study, the vertical distribution and speciation of Zn and Pb in the fine-grained flotation residues of a former sulfide ore mine in Germany were investigated to assess the inorganic weathering processes that effect the environmental risk arising from this site. Total metal contents were determined by X-ray fluorescence spectroscopy (XRF). Mobilizable fractions of Zn, Pb, Fe, and Mn were quantified by sequential chemical extractions (SCE). Furthermore, the speciation of Zn was analyzed by Zn K-edge extended X-ray absorption fine structure spectroscopy (EXAFS) to identify the residual Zn species. The variations in pH and inorganic C content show an acidification of the topsoil to pH 5.5. EXAFS results confirm that Zn is mainly bound in sphalerite in the subsoil and weathering reactions lead to a redistribution of Zn in the topsoil. A loss of 35% Zn and S from the topsoil compared with the parent material with 10 g kg-1 Zn and neutral pH has been observed. If acidification proceeds it will lead to a significant release of Zn, S, and Pb to the ground water. In contrast to Zn, Pb is enriched in the mobile fraction of the topsoil by more than a factor of two compared with the subsoil which contains a total of 2 g kg-1 Pb. Thus, the high bioavailability of Pb and the potential for Pb uptake by plants and animals currently represent the most severe threat for environmental health.
authors.affiliation: Institute of Geosciences, Mainz Univ., Becherweg 21, D-55099, Mainz, Germany.
authors.forename: Nele
authors.initials: N
authors.lastname: Schuwirth
authors.forename: Andreas
authors.initials: A
authors.lastname: Voegelin
authors.forename: Ruben
authors.initials: R
authors.lastname: Kretzschmar
authors.forename: Thilo
authors.initials: T
authors.lastname: Hofmann
mesh_terms: D006863:Hydrogen-Ion Concentration; D008670:Metals / Q000032:analysis*; D013050:Spectrometry, Fluorescence / Q000379:methods; D014131:Trace Elements / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D008670:Metals; D014131:Trace Elements; D014874:Water Pollutants, Chemical