title: Enantiopure pseudo-C3-symmetric titanium alkoxide with propeller-like chirality.
abstract: An enantiopure amine tris(phenolate) ligand containing a single stereogenic center has been used to control the propeller-like chirality of a derived pseudo-C3-symmetric titanium isopropoxide complex with excellent levels of diastereocontrol. [structure: see text].
authors.affiliation: Department of Chemistry, University of Bath, Claverton Down, Bath, BA2 7AY, UK.
authors.forename: Philip
authors.initials: P
authors.lastname: Axe
authors.forename: Steven D
authors.initials: SD
authors.lastname: Bull
authors.forename: Matthew G
authors.initials: MG
authors.lastname: Davidson
authors.forename: Carly J
authors.initials: CJ
authors.lastname: Gilfillan
authors.forename: Matthew D
authors.initials: MD
authors.lastname: Jones
authors.forename: Diane E J E
authors.initials: DE
authors.lastname: Robinson
authors.forename: Luke E
authors.initials: LE
authors.lastname: Turner
authors.forename: William L
authors.initials: WL
authors.lastname: Mitchell
mesh_terms: D018360:Crystallography, X-Ray; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013237:Stereoisomerism; D014025:Titanium / Q000737:chemistry*
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D014025:Titanium