Macrocyclic ferrocenyl-bisimidazoline palladacycle dimers as highly active and enantioselective catalysts for the aza-claisen rearrangement of Z-configured N-para-methoxyphenyl trifluoroacetimidates.
Jautze
Sascha
S
Laboratory of Organic Chemistry, ETH Zürich, Wolfgang-Pauli-Strasse 10, Hönggerberg HCI E 111, 8093 Zürich, Switzerland.
Seiler
Paul
P
Peters
René
R
D001372:Aza Compounds / Q000737:chemistry*; D002384:Catalysis; D019281:Dimerization; D005296:Ferrous Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D005461:Fluorine / Q000737:chemistry*; D048288:Imidazolines / Q000138:chemical synthesis / Q000737:chemistry*; D007096:Imidoesters / Q000737:chemistry*; D008024:Ligands; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D013237:Stereoisomerism
D001372:Aza Compounds; D005296:Ferrous Compounds; D048288:Imidazolines; D007096:Imidoesters; D008024:Ligands; D047028:Macrocyclic Compounds; C518848:ferrocenyl-bisimidazoline; D005461:Fluorine