A novel mixed-valence copper complex, poly[[mu2-4,4'-bipyridine-mu3-pyridine-2,4,6-tricarboxylato-dicopper(I,II)] monohydrate].
In the title novel mixed-valence copper complex, {[Cu2(C8H2NO6)(C10H8N2)].H2O}n, the Cu(I) and Cu(II) ions are linked by 4,4'-bipyridine (bpy) and pyridine-2,4,6-tricarboxylate (ptc) ligands into corrugated layers, which are assembled via interlayer C-H...O hydrogen bonds to give a three-dimensional supramolecular architecture.
Dong
You Ren
YR
State Key Laboratory Base of Novel Functional Materials and Preparation Science, Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, Zhejiang 315211, People's Republic of China.
Wang
Xian Wen
XW
Zheng
Yue Qing
YQ