Increased crystal porosity and enhanced gas adsorption by intracolumnar gliding for broadband gas detection.
A new three-level structural approach based on anion-induced intracolumnar gliding of stacked coordinatively unsaturated units is described for design of metal-organic crystals which exhibit concentration- and gas-specific adsorption of a variety of small molecules and could be employed for multiple and rapid qualitative and quantitative broadband detection of gases or gaseous mixtures.
Naumov
Pance
P
ICYS, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan. naumov.pance@nims.go.jp
Sakurai
Kenji
K
Nukui
Akihiko
A
Tanaka
Masahiko
M