Bis(acesulfamato-kappaO4)diaquabis(3-methylpyridine-kappaN)nickel(II).
In the crystal structure of the title compound [systematic name: diaquabis(6-methyl-2,2-dioxo-1,2,3-oxathiazin-4-olato-kappaO4)bis(3-methylpyridine-kappaN)nickel(II)], [Ni(C4H4NO4S)2(C6H7N)2(H2O)2], the Ni(II) centre resides on a centre of symmetry and has a distorted octahedral geometry. The basal plane is formed by two carbonyl O atoms of two monodentate trans-oriented acesulfamate ligands and two trans aqua ligands. The axial positions in the octahedron are occupied by two N atoms of two trans pyridine ligands. Molecules are stacked in columns running along the a axis. There are pi-pi stacking interactions between the molecules in each column, with a distance of 3.623 (2) A between the centroids of the pyridine rings. There are also O-H...O interactions between the columns.
Dege
Necmi
N
Department of Physics, Arts and Sciences Faculty, Ondokuz Mayis University, 55139 Samsun, Turkey. dege@omu.edu.tr
Içbudak
Hasan
H
Adiyaman
Elif
E
D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular; D008968:Molecular Conformation; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*
D009942:Organometallic Compounds; C518418:bis(acesulfamato-kappaO(4))diaquabis(3-methylpyridine-kappaN)nickel(II); D009532:Nickel