Ascospiroketals A and B, unprecedented cycloethers from the marine-derived fungus Ascochyta salicorniae.
Chemical investigation of the marine-derived fungus Ascochyta salicorniae led to the isolation of two novel natural products, ascospiroketals A (1) and B (2). From a biosynthetic standpoint, the compounds possess new ring systems. [structure: see text].
Seibert
Simon F
SF
Institute for Pharmaceutical Biology, University of Bonn, Nussallee 6, D-53115 Bonn, Germany.
Krick
Anja
A
Eguereva
Ekaterina
E
Kehraus
Stefan
S
König
Gabriele M
GM
D001203:Ascomycota / Q000737:chemistry*; D004988:Ethers, Cyclic / Q000737:chemistry* / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy / Q000379:methods / Q000592:standards; D008958:Models, Molecular; D008968:Molecular Conformation; D012015:Reference Standards; D013141:Spiro Compounds / Q000737:chemistry* / Q000302:isolation & purification; D013237:Stereoisomerism
D004988:Ethers, Cyclic; D013141:Spiro Compounds; C518010:ascospiroketal A; C518009:ascospiroketal B