The P(bth)2- anion as a Janus head staple between lithium and manganese (bth = benzothiazol-2-yl, C7H4NS).
Deprotonation of HP(bth)2 (1) affords the lithium phosphanide [(Et2O)2Li(bth)2P], (2) with both nitrogen atoms coordinated to the lithium atom while in the heterobimetallic complex [Li(bth)2P{Mn(CO)2Cp}2](n) (3) additionally the phosphorus atom micro-bridges two Mn(CO)2Cp residues.
Stey
Thomas
T
Institut für Anorganische Chemie der Universität Göttingen, Tammannstrasse 4, 37077, Göttingen, Germany.
Henn
Julian
J
Stalke
Dietmar
D