title: Diversely substituted sugar-linked alpha,beta-unsaturated gamma-lactones from sugar-derived Baylis-Hillman adducts via a RCM.
abstract: A versatile protocol for the production of sugar-linked alpha,beta-unsaturated gamma-lactones with stereochemical and functional group diversity is described starting from sugar-derived Baylis-Hillman adducts via ring-closing metathesis.
authors.affiliation: D-206/B, Discovery Laboratory, Organic Chemistry Division III, Indian Institute of Chemical Technology, Hyderabad-500 007, India. prkgenius@iict.res.in
authors.forename: Palakodety Radha
authors.initials: PR
authors.lastname: Krishna
authors.forename: M
authors.initials: M
authors.lastname: Narsingam
mesh_terms: D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D002241:Carbohydrates / Q000138:chemical synthesis* / Q000737:chemistry; D020650:Combinatorial Chemistry Techniques / Q000379:methods; D007783:Lactones / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009904:Optical Rotation; D021241:Spectrometry, Mass, Electrospray Ionization; D013055:Spectrophotometry, Infrared; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D002241:Carbohydrates; D007783:Lactones