title: Synthesis and structures of cross-conjugated bis-dehydroannulenes with a Y-enediyne motif and different pi topologies.
abstract: A synthesis of cross-conjugated bis-dehydroannulenes with different topologies of the pi electrons by Cu(II)-mediated oxidative coupling of the corresponding terminal acetylenic precursors is reported. In general, of the two possible modes of cyclization, which would yield either a [13]annulene or an [18]annulene, the precursors yielded exclusively the bis-dehydro[13]annulenes. However, one example of the formation of a bis-dehydro[18]annulene is also reported. The mode of cyclization to form either the [13]annulene or the [18]annulene is explained on the basis of the conformational preference of the core unit bearing the Y-enediyne moieties. The structures of the two types of bis-annulenes have been unequivocally established by means of single-crystal X-ray crystallographic analysis.
authors.affiliation: Department of Chemistry, Indian Institute of Technology Madras, Chennai 600036, India.
authors.forename: Arkasish
authors.initials: A
authors.lastname: Bandyopadhyay
authors.forename: Babu
authors.initials: B
authors.lastname: Varghese
authors.forename: Henning
authors.initials: H
authors.lastname: Hopf
authors.forename: Sethuraman
authors.initials: S
authors.lastname: Sankararaman