Total synthesis of (+)-aquaticol by biomimetic phenol dearomatization: double diastereofacial differentiation in the Diels-Alder dimerization of orthoquinols with a C2-symmetric transition state.
Gagnepain
Julien
J
Institut Européen de Chimie et Biologie, 2 rue Robert Escarpit, 33607 Pessac Cedex, France.
Castet
Frédéric
F
Quideau
Stéphane
S
D029661:Alnus; D040761:Biomimetic Materials / Q000737:chemistry*; D032701:Biomimetics; D003500:Cyclization; D019281:Dimerization; D006873:Hydroquinones / Q000737:chemistry*; D015394:Molecular Structure; D010636:Phenols / Q000737:chemistry*; D013237:Stereoisomerism; D014315:Triterpenes / Q000138:chemical synthesis* / Q000737:chemistry
D006873:Hydroquinones; D010636:Phenols; D014315:Triterpenes; C409886:aquaticol