Detection of chemical warfare simulants by phosphorylation of a coumarin oximate.
The detection of chemical warfare simulants is attained by the PET mechanism that gives an "off-on" fluorescent response with a half-life of approximately 50 ms upon phosphorylation of a reactive oximate functionality; the X-ray crystal structure of the oximate was also obtained and is discussed.
Wallace
Karl J
KJ
Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, TX, USA.
Fagbemi
Ruth I
RI
Folmer-Andersen
Frantz J
FJ
Morey
Jeroni
J
Lynth
Vincent M
VM
Anslyn
Eric V
EV