title: Phosphorus transport pathways to streams in tile-drained agricultural watersheds.
abstract: Agriculture is a major nonpoint source of phosphorus (P) in the Midwest, but how surface runoff and tile drainage interact to affect temporal concentrations and fluxes of both dissolved and particulate P remains unclear. Our objective was to determine the dominant form of P in streams (dissolved or particulate) and identify the mode of transport of this P from fields to streams in tile-drained agricultural watersheds. We measured dissolved reactive P (DRP) and total P (TP) concentrations and loads in stream and tile water in the upper reaches of three watersheds in east-central Illinois (Embarras River, Lake Fork of the Kaskaskia River, and Big Ditch of the Sangamon River). For all 16 water year by watershed combinations examined, annual flow-weighted mean TP concentrations were >0.1 mg L(-1), and seven water year by watershed combinations exceeded 0.2 mg L(-1). Concentrations of DRP and particulate P (PP) increased with stream discharge; however, particulate P was the dominant form during overland runoff events, which greatly affected annual TP loads. Concentrations of DRP and PP in tiles increased with discharge, indicating tiles were a source of P to streams. Across watersheds, the greatest DRP concentrations (as high as 1.25 mg L(-1)) were associated with a precipitation event that followed widespread application of P fertilizer on frozen soils. Although eliminating this practice would reduce the potential for overland runoff of P, soil erosion and tile drainage would continue to be important transport pathways of P to streams in east-central Illinois.
authors.affiliation: Department of Natural Resources and Environmental Sciences, University of Illinois at Urbana-Champaign, 1102 S. Goodwin Ave., Urbana, IL 61801, USA. gentryl@msu.edu
authors.forename: L E
authors.initials: LE
authors.lastname: Gentry
authors.forename: M B
authors.initials: MB
authors.lastname: David
authors.forename: T V
authors.initials: TV
authors.lastname: Royer
authors.forename: C A
authors.initials: CA
authors.lastname: Mitchell
authors.forename: K M
authors.initials: KM
authors.lastname: Starks
mesh_terms: D000383:Agriculture / Q000379:methods*; D010758:Phosphorus / Q000032:analysis*; D011891:Rain; D045483:Rivers / Q000737:chemistry; D012914:Snow; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014881:Water Supply
chemical_list: D014874:Water Pollutants, Chemical; D010758:Phosphorus