title: Fullerene acting as an electron donor in a donor-acceptor dyad to attain the long-lived charge-separated state by complexation with scandium ion.
abstract: A long-lived charge-separated (CS) state of fullerene-trinitrofluorenone linked dyad in which fullerene acts as an electron donor is formed by photoinduced electron transfer from C60 to TNF in the presence of Sc(OTf)3; the CS lifetime is determined as 23 ms in PhCN at 298 K.
authors.affiliation: Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST, Japan Science and Technology Agency (JST), Suita, Osaka, 565-0871, Japan.
authors.forename: Kei
authors.initials: K
authors.lastname: Ohkubo
authors.forename: Javier
authors.initials: J
authors.lastname: Ortiz
authors.forename: Luis
authors.initials: L
authors.lastname: Martín-Gomis
authors.forename: Fernando
authors.initials: F
authors.lastname: Fernández-Lázaro
authors.forename: Angela
authors.initials: A
authors.lastname: Sastre-Santos
authors.forename: Shunichi
authors.initials: S
authors.lastname: Fukuzumi