title: alpha-Oxygenated crotyltitanium and dyotropic rearrangement in the total synthesis of discodermolide.
authors.affiliation: Université de Cergy-Pontoise, CNRS UMR 8123, 5 Mail Gay Lussac, 95031 Cergy Pontoise Cedex, France.
authors.forename: Elsa
authors.initials: E
authors.lastname: de Lemos
authors.forename: François-Hugues
authors.initials: FH
authors.lastname: Porée
authors.forename: Alain
authors.initials: A
authors.lastname: Commerçon
authors.forename: Jean-François
authors.initials: JF
authors.lastname: Betzer
authors.forename: Ange
authors.initials: A
authors.lastname: Pancrazi
authors.forename: Janick
authors.initials: J
authors.lastname: Ardisson
mesh_terms: D000473:Alkanes / Q000138:chemical synthesis*; D000498:Allyl Compounds / Q000138:chemical synthesis; D000818:Animals; D000970:Antineoplastic Agents / Q000138:chemical synthesis*; D002219:Carbamates / Q000138:chemical synthesis*; D007202:Indicators and Reagents; D007783:Lactones / Q000138:chemical synthesis*; D009682:Magnetic Resonance Spectroscopy; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D011161:Porifera / Q000737:chemistry; D011753:Pyrones / Q000138:chemical synthesis*; D013237:Stereoisomerism; D014025:Titanium / Q000737:chemistry*
chemical_list: D000473:Alkanes; D000498:Allyl Compounds; D000970:Antineoplastic Agents; D002219:Carbamates; D007202:Indicators and Reagents; D007783:Lactones; D009942:Organometallic Compounds; D011753:Pyrones; D014025:Titanium; C071229:discodermolide