Understanding the selectivity of a moderate oxidation catalyst: hydrogen abstraction by a fully characterized, activated catalyst, the robust dihydroxo manganese(IV) complex of a bridged cyclam.
Yin
Guochuan
G
Department of Chemistry, The University of Kansas, Lawrence, Kansas 66045, USA.
Danby
Andrew M
AM
Kitko
David
D
Carter
John D
JD
Scheper
William M
WM
Busch
Daryle H
DH
D002384:Catalysis; D018360:Crystallography, X-Ray; D006571:Heterocyclic Compounds / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D007700:Kinetics; D008345:Manganese / Q000737:chemistry*; D009942:Organometallic Compounds; D010084:Oxidation-Reduction; D013379:Substrate Specificity
D006571:Heterocyclic Compounds; D009942:Organometallic Compounds; C024560:cyclam; D008345:Manganese; D006859:Hydrogen