Hydrolysis rates of 1-glucosyl-2-benzoylhydrazines in aqueous solution.
A series of substituted 1-glucosyl-2-benzoylhydrazines were synthesized and their pseudo-first-order rate constants for hydrolysis were determined at pH 4, 5, 6 at 50 degrees C. All the compounds hydrolyzed quickly (t(1/2)<3h) at pH 4.0, but were increasingly stable as the pH approached neutrality.
Gudmundsdottir
Anna V
AV
Department of Chemistry, 80 St. George Street, Toronto, Ont., Canada.
Nitz
Mark
M
D006001:Glycoconjugates / Q000138:chemical synthesis* / Q000737:chemistry; D006834:Hydrazines / Q000138:chemical synthesis* / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D006868:Hydrolysis; D007700:Kinetics; D013696:Temperature
D006001:Glycoconjugates; D006834:Hydrazines