Synthesis and olefination of carbonyl compounds using solid-supported reagents.
The development and application of three new solid-supported reagents for use in the synthesis or olefination of carbonyl compounds are described. The reagents include the Weinreb amide, Mukaiyama's S-2-pyridyl thioate and a Peterson methylenation reagent. As solid-supports p-benzyl alcohol resin, Wang resin and Merrifield resin (1-2% crosslinked polystyrene) have been used.
Hansen
Anne-Lene L
AL
Department of Chemistry, Kemitorvet, Building 201, Technical University of Denmark, 2800, Kgs. Lyngby, Denmark.
Murray
Anthony
A
Tanner
David
D
D000475:Alkenes / Q000737:chemistry*; D000577:Amides / Q000737:chemistry; D007202:Indicators and Reagents / Q000737:chemistry; D015394:Molecular Structure; D012117:Resins, Synthetic
D000475:Alkenes; D000577:Amides; D007202:Indicators and Reagents; D012117:Resins, Synthetic