Encapsulation of a (H3O2)- unit in the aromatic core of a calix[6]arene closed by two Zn(II) ions at the small and large rims.
The coordination of a first Zn(II) ion to a calix[6]arene presenting three imidazolyl arms at the small rim and three aniline moieties at the large rim allows the binding of a second Zn(II) ion while hosting a (H3O2)- unit in the aromatic cavity.
Coquière
David
D
Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques, UMR CNRS 8601, Université René Descartes, 45 rue des Saints-Pères, 75270 Paris Cedex 06, France.
Marrot
Jérôme
J
Reinaud
Olivia
O
D000814:Aniline Compounds / Q000737:chemistry; D047250:Calixarenes / Q000138:chemical synthesis*; D002413:Cations, Divalent; D006878:Hydroxides / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D010636:Phenols / Q000138:chemical synthesis*; D015032:Zinc / Q000737:chemistry*
D000814:Aniline Compounds; D002413:Cations, Divalent; D006878:Hydroxides; D007093:Imidazoles; D009942:Organometallic Compounds; D010636:Phenols; C476540:calix(6)arene; D047250:Calixarenes; C029899:imidazole; D015032:Zinc; C023650:aniline