Cyanide-bridged W(V)-Co(II) double-zigzag chain based on an octacoordinated W precursor: metamagnetism and spin canting.
A cyanide-bridged W-Co bimetallic complex (1) with a double-zigzag chain structure was characterized in terms of structure and magnetism. Compound 1 exhibits metamagnetism and spin canting induced by the presence of anisotropic CoII ions and noncovalent interactions.
Yoon
Jung Hee
JH
Department of Chemistry and Center for Electro- and Photo-Responsive Molecules, Korea University, Seoul 136-701, Korea.
Lim
Jeong Hak
JH
Choi
Seok Woo
SW
Kim
Hyoung Chan
HC
Hong
Chang Seop
CS