Chemistry of enediynyl azides: activation through a novel pathway.
The spontaneous activation of a nonaromatic enediynyl azide under ambient conditions has been demonstrated. The aromatic enediyne followed the expected cycloaddition with the alkene in the neighbouring arm to form a stable bridged bicyclic enediyne.
Basak
Amit
A
Bioorganic Laboratory, Department of Chemistry, Indian Institute of Technology, Kharagpur, India. absk@chem.iitkgp.ernet.in
Roy
Sandip K
SK
Das
Sanket
S
Hazra
Amrita B
AB
Ghosh
Subhash C
SC
Jha
Shailendra
S