Heterogeneity analysis of single-walled carbon nanotubes from the adsorption equilibria of nitrogen and benzene.
Nitrogen adsorption/desorption isotherms and gravimetric methods were employed to examine the structural and adsorption properties of selected adsorbent. The equilibrium data of benzene were also obtained at three different temperatures (303.15, 313.15, and 323.15 K) with pressures up to 7 kPa. The results of nitrogen and benzene sorption isotherm revealed that SWCNTs exhibit type II with the features of type I. The Toth and UNILAN models were found to provide a reasonable correlation between the adsorption isotherm data. In addition, the adsorption second virial coefficient and the isosteric heat of adsorption were determined by using these isotherm models. The isosteric heat of adsorption and adsorption energy distribution indicated that SWCNTs have energetically and structurally heterogeneous surfaces.
Shim
Wang-Geun
WG
Faculty of Applied Chemical Engineering, Chonnam National University 300 Yongbong Dong, Buk-Ku, Gwangju 500-757, Korea.
Kang
Hyun-Chul
HC
Kim
Chan
C
Lee
Jae-Wook
JW
Kim
Sang-Chai
SC
Lee
Chul-Jin
CJ
Moon
Hee
H
D000327:Adsorption; D001554:Benzene / Q000737:chemistry*; D008956:Models, Chemical; D053758:Nanoparticles / Q000737:chemistry; D036103:Nanotechnology / Q000379:methods*; D037742:Nanotubes, Carbon / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D013499:Surface Properties; D013696:Temperature; D013816:Thermodynamics
D037742:Nanotubes, Carbon; D001554:Benzene; D009584:Nitrogen