title: Seasonal variation of monomethylmercury concentrations in surface sediments of the Tagus Estuary (Portugal).
abstract: Surface sediments (0-2cm) were collected at 40 sites along the Tagus Estuary in July and December 2004. The sediments were analysed for total mercury, monomethylmercury (MMHg) and interpretative parameters (e.g. redox potential, pH, C(org)). No significant differences in total Hg, pH, Al, Fe, Mn and C(org) were found between sediments collected in the two periods, but MMHg concentrations were higher in July. On average sediments were warmer and more reducing in summer. On the basis of these results, an increase of 7kg of MMHg (+37%) in surface sediments of the Tagus Estuary was estimated. Presumably higher temperatures in summer promote the increase of microbial activity and higher methylation rates. The alterations observed in this study point to the potential importance of seasonal changes in MMHg production at surface sediments with eventual changes in the MMHg uptake by benthic invertebrates and other organisms in the food web.
authors.affiliation: IPIMAR, National Institute for Agronomy and Fisheries Research, Av Brasília, Lisbon, Portugal. jcanario@ipimar.pt
authors.forename: João
authors.initials: J
authors.lastname: Canário
authors.forename: Vasco
authors.initials: V
authors.lastname: Branco
authors.forename: Carlos
authors.initials: C
authors.lastname: Vale
mesh_terms: D004784:Environmental Monitoring / Q000379:methods; D019015:Geologic Sediments / Q000032:analysis*; D006256:Hazardous Waste; D006863:Hydrogen-Ion Concentration; D008628:Mercury / Q000032:analysis; D008767:Methylmercury Compounds / Q000032:analysis*; D009498:Neurotoxins / Q000032:analysis*; D011174:Portugal; D045483:Rivers; D012621:Seasons; D012989:Soil Pollutants / Q000032:analysis*
chemical_list: D006256:Hazardous Waste; D008767:Methylmercury Compounds; D009498:Neurotoxins; D012989:Soil Pollutants; D008628:Mercury