title: Self-healing kinetics and the stereoisomers of dicyclopentadiene.
abstract: While original epoxy resin-based self-healing systems used the commercially available endo-isomer of dicyclopentadiene (DCPD), the exo-stereoisomer is known to have much faster olefin metathesis reaction rates with first-generation Grubbs' catalyst. Here, we measure the energy to failure of healed specimens as a function of healing time and compare the kinetics of damage repair for endo- and exo-DCPD, and mixtures of the two isomers. Using catalyst loading levels previously reported to be effective for endo-DCPD, exo-DCPD was found to heal approximately 20 times faster than the endo-isomer, but with a lower healing efficiency. The fracture toughness of the repaired specimens decreased when the exo content of the blends was greater than 40% and, for the pure exo-DCPD, when the catalyst loadings were below 1%. Possible causes of the reduced healing efficiencies of the exo-DCPD healing agent are discussed.
authors.affiliation: Department of Chemistry, University of Illinois, Urbana, IL 61801, USA. mauldin@lastate.edu
authors.forename: Timothy C
authors.initials: TC
authors.lastname: Mauldin
authors.forename: Joseph D
authors.initials: JD
authors.lastname: Rule
authors.forename: Nancy R
authors.initials: NR
authors.lastname: Sottos
authors.forename: Scott R
authors.initials: SR
authors.lastname: White
authors.forename: Jeffrey S
authors.initials: JS
authors.lastname: Moore
mesh_terms: D002384:Catalysis; D007192:Indenes / Q000737:chemistry*; D007700:Kinetics; D013237:Stereoisomerism
chemical_list: D007192:Indenes; C004689:dicyclopentadiene