Linear-dichroic infrared spectral (IR-LD) analysis of codeine and its derivatives.
By means of IR-LD spectroscopy of oriented as suspension in nematic liquid crystal solids, a detailed IR-bands assignment and a stereo-structural prediction of codeine, codeinone and N-norcodeine have been carried out. The data are compared with known crystallographic ones of codeine and codeinone obtained by single crystal X-ray diffraction.
Koleva
Bojidarka
B
Sofia University, St. Kl. Ohridki, Department of Analytical Chemistry, 1 J. Bourchier blvd., 1164 Sofia, Bulgaria. BKoleva@chem.uni-sofia.bg
Kolev
Tsonko
T
Bakalska
Rumyana
R
D001965:Bromides; D003061:Codeine / Q000031:analogs & derivatives* / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D017680:Potassium Compounds; D013055:Spectrophotometry, Infrared; D013057:Spectrum Analysis / Q000379:methods
D001965:Bromides; D017680:Potassium Compounds; C039004:potassium bromide; D003061:Codeine