title: A natural component as coinitiator for unfilled dental resin composites.
abstract: A natural component, 1,3-benzodioxole (BDO), was used for the purpose of replacing the conventional amine for dental composite. Camphorquinone (CQ)/BDO was used to initiate the photopolymerization of urethane dimethacrylate (UDMA)/triethylene glycol dimethacrylate (TEGDMA) (70/30 wt %). The kinetics was recorded by real-time Fourier transformation infrared spectroscopy (FTIR). The mechanical properties were measured by dynamic mechanical analyzer (DMA), and CQ/ethyl 4-N,N-dimethylaminobenzoate (EDMAB) mixture was used as control in the same photocuring condition. The results indicated that, the addition of BDO as coinitiator greatly improved the rate of polymerization and final double bond conversion (DC), when compared with the system initiated by CQ alone. BDO and EDMAB were found to reach almost the same final DC (75%), though the kinetics of two systems was different. Comparing with EDMAB, BDO brought approximately the same glass transition temperature (Tg), but slightly higher storage modulus around 37 degrees C. The water sorption and solubility for two mixtures were almost the same and within the range of the ISO 4049's standards. These results suggested that BDO was an effective alternative to conventional amine for coinitiator. And the human diet characteristics of BDO made it more promising than amine in the dental resin formulations.
authors.affiliation: Department of Chemistry, Key Laboratory of Biomedical Polymers of Ministry of Education, Wuhan University, Wuhan 430072, People's Republic of China.
authors.forename: Suqing
authors.initials: S
authors.lastname: Shi
authors.forename: Jun
authors.initials: J
authors.lastname: Nie
mesh_terms: D010129:4-Aminobenzoic Acid / Q000737:chemistry / Q000528:radiation effects; D003188:Composite Resins / Q000737:chemistry* / Q000528:radiation effects; D003764:Dental Materials / Q000737:chemistry* / Q000528:radiation effects; D004149:Dioxoles / Q000737:chemistry* / Q000528:radiation effects*; D006801:Humans; D007700:Kinetics; D008027:Light; D008689:Methacrylates / Q000737:chemistry / Q000528:radiation effects; D010777:Photochemistry; D011092:Polyethylene Glycols / Q000737:chemistry; D011109:Polymethacrylic Acids / Q000737:chemistry; D011140:Polyurethanes / Q000737:chemistry / Q000528:radiation effects; D017550:Spectroscopy, Fourier Transform Infrared; D013729:Terpenes / Q000737:chemistry / Q000528:radiation effects; D014867:Water / Q000737:chemistry; D062366:para-Aminobenzoates
chemical_list: D003188:Composite Resins; D003764:Dental Materials; D004149:Dioxoles; D008689:Methacrylates; D011109:Polymethacrylic Acids; D011140:Polyurethanes; D013729:Terpenes; C523330:ethyl 4-N,N-dimethylaminobenzoate; D062366:para-Aminobenzoates; D014867:Water; C029824:urethane dimethacrylate luting resin; C020946:triethylene glycol dimethacrylate; D011092:Polyethylene Glycols; C048339:camphoroquinone; C040539:1,3-benzodioxole; D010129:4-Aminobenzoic Acid