title: [Preparation of composite of poly (o-methyl-acrylamide-benzoic acid)/ znO nanoparticles and its property of fluorescence].
abstract: The preparation of P(o-MAABA) via ATRP and the composite of P(o-MAABA)/ZnO nanoparticles were described. 1H NMR, IR, TA and TEM were utilized to confirm the results. 1H NMR indicates that the structure of the P(o-MAABA) was definite, and the molecule weight of P(o-MAABA) was 7900. IR shows that ZnO nanoparticles were introduced to P(o-MAABA) and were interacted with the reactive groups of polymer. TA shows that the heat stability of P(o-MAABA))/ZnO composite increased greatly. TEM photo demonstrates that the composite was spherical and the surface was smooth. The P(o-MAABA)/ZnO composite exhibits particular fluorescence property, and the emission spectrum of the P(o-MAABA)/ZnO composite red shifts 25 nm compared to the polymer. In addition, the composite features good solubility and film formability, and may become a new optical material.
authors.affiliation: Department of Chemistry and Chemical Engineering, Key Laboratory of Organic Synthesis of Jiangsu Province, Suzhou University, Suzhou 215123, China.
authors.forename: Chun-hua
authors.initials: CH
authors.lastname: Ding
authors.forename: Qing-feng
authors.initials: QF
authors.lastname: Xu
authors.forename: Jian-mei
authors.initials: JM
authors.lastname: Lu