Experimental and theoretical evidence of the first Au(i)...Bi(iii) interaction.
Complex [Au(C6F5)2][Bi(C6H4CH2NMe(2)-2)2] displays the first example of an interaction between Au(I) and Bi(III), the nature of which is shown to be consistent with the presence of a high ionic contribution (79%) and a dispersion type (van der Waals) interaction (21%).
Fernández
Eduardo J
EJ
Departamento de Química, Universidad de La Rioja, Grupo de Síntesis Química de La Rioja, UA-CSIC. Complejo Científico-Tecnológico, 26004, Logroño, Spain. eduardo.fernandez@dq.unirioja.es
Laguna
Antonio
A
López-de-Luzuriaga
José M
JM
Monge
Miguel
M
Nema
Mihai
M
Olmos
M Elena
ME
Pérez
Javier
J
Silvestru
Cristian
C