Controlled synthesis of Y-junction polyaniline nanorods and nanotubes using in situ self-assembly of magnetic nanoparticles.
Novel Y-junction polyaniline (PANI) nanorods and nanotubes (40-100 nm in diameter and a few micrometers in length) were selectively prepared, for the first time, using in situ self-assembly of water-soluble Fe3O4 nanoparticles coated with polyethylene glycol(5) nonylphenyl ether (NP5) and cyclodextrin (CD) as templates and pH control in an aqueous medium. The morphology of Fe3O4 nanoparticles and the PANI nanostructures (rods and tubes) was determined by TEM and the effects of reaction conditions on the morphology of PANI nanostructures were also studied. Characterization experiments including FTIR and X-ray diffraction were carried out to study the chemical and electronic structures of the PANI nanostructures.
Xia
Haibing
H
Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543 Singapore.
Cheng
Daming
D
Xiao
Changyong
C
Chan
Hardy Sze On
HS
D000814:Aniline Compounds / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D005290:Ferric Compounds / Q000737:chemistry*; D046911:Macromolecular Substances / Q000737:chemistry; D008280:Magnetics; D008422:Materials Testing; D008968:Molecular Conformation; D036103:Nanotechnology / Q000379:methods*; D043942:Nanotubes / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D013499:Surface Properties
D000814:Aniline Compounds; D005290:Ferric Compounds; D046911:Macromolecular Substances; C416807:polyaniline; C000499:ferric oxide