Highly selective R,S-coordination of non racemic (1R,2R)-(1,2-dialkyl)-1,2-diamine cyclohexane derivatives to palladium dichloride.
In non-racemic (1R,2R)-(1,2-dialkyl)-1,2-diaminocyclohexane palladium dichloride complexes the C2 symmetry of the diamine ligand is broken, resulting in selective R,S-coordination.
Rafii
Esfandiar
E
Université Paul Cézanne, UMR CNRS 6180 Chirotechnologies: Catalyse et Biocatalyse, Faculté Saint-Jérôme, Case A 62, 13397 Marseille Cedex 20, France.
Dassonneville
Benjamin
B
Heumann
Andreas
A