Anion and cation leaching or desorption from activated carbons from municipal sludge and poultry manure as affected by pH.
The conversion of municipal sludge and poultry manure to activated carbon results in a significant ash fraction that contains several different anions and cations. The objectives of this study were to determine whether the select ions are released or leached from virgin carbon into the sorption medium at different pH values. Activated carbon was placed in solutions of pH 1, 5, or 7, and the leaching of six cations (cadmium, chromium, copper, nickel, lead, and zinc) and two anions (arsenate and selenate) was recorded. Considerable quantities of zinc and copper were removed at pH 1 from all carbon sources. However, the amounts leached at pH 5 and 7 were small or undetectable. Our results indicate that leaching or desorption from carbons made from municipal sludge or poultry manure is pH-dependent and occurs readily under highly acidic conditions but minimally under pH conditions typically seen in contaminated water or wastewater.
Fitzmorris
Kari B
KB
Commodity Utilization Research, USDA, ARS, Southern Regional Research Center, New Orleans, Louisiana 70179, USA. kfitzmorris@srrc.ars.usda.gov
Lima
Isabel M
IM
Marshall
Wayne E
WE
Reimers
Robert S
RS
D000327:Adsorption; D000818:Animals; D001151:Arsenic / Q000032:analysis / Q000737:chemistry; D002244:Carbon / Q000032:analysis / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D008372:Manure / Q000032:analysis*; D019216:Metals, Heavy / Q000032:analysis / Q000737:chemistry*; D009584:Nitrogen / Q000032:analysis; D010758:Phosphorus / Q000032:analysis; D011200:Poultry; D012722:Sewage / Q000032:analysis*; D013455:Sulfur / Q000032:analysis
D008372:Manure; D019216:Metals, Heavy; D012722:Sewage; D010758:Phosphorus; D013455:Sulfur; D002244:Carbon; D001151:Arsenic; D009584:Nitrogen