An unusual 1D manganese azido complex with novel EO/EO/EO/EE coordination mode: synthesis, structure, and magnetic properties.
A novel one-dimensional manganese(II) azido complex, [Mn2(N3)4(phen)2]n (1), in which the azido bridging ligands take on an unusual new type of combination with the metal center as the sign of [-EO-EO-EO-EE-]n, has been hydrothermally synthesized, and its magnetic properties have been studied.
Liu
Fu-Chen
FC
Department of Chemistry, Nankai University, Tianjin 300071, China.
Zeng
Yong-Fei
YF
Zhao
Jiong-Peng
JP
Hu
Bo-Wen
BW
Bu
Xian-He
XH
Ribas
Joan
J
Cano
Joan
J
D001386:Azides / Q000737:chemistry*; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D013696:Temperature
D001386:Azides; D009942:Organometallic Compounds; D008345:Manganese