title: Oxidation of aqueous EDTA and associated organics and coprecipitation of inorganics by ambient iron-mediated aeration.
abstract: Cationic metal and radionuclide contaminants can be extracted from soils to groundwater with sequestering agents such as EDTA. However, EDTA must then be removed fromthe groundwater, by advanced oxidation or specialized biological treatment. In this work, aqueous individual metal-EDTA solutions were aerated with steel wool for 25 h, at ambient pH, temperature, and pressure. Removal of approximately 99% of EDTA (0.09-1.78 mM); glyoxylic acid (0.153 mM); chelated Cd2+ (0.94 and 0.0952 mM), Pb2+ (0.0502 mM), and Hg2+ (0.0419 mM); and free chromate and vanadate was shown. EDTA was oxidized to glyoxylic acid and formaldehyde, and metals/metalloids were coprecipitated together with iron oxyhydroxide floc. Free arsenite and arsenate were each removed at 99.97%. Free Sr2+, and chelated Ni2+ were removed at 92% and 63%, respectively. Similar removals were obtained from mixtures, including 99.996+/-0.004% removal of total arsenic (95% confidence). Traces of iminodiacetic acid, nitrilotriacetic acid, and ethylenediaminetriacetic acid were detected after 25 h. Results are consistent with first-order, solution-phase oxidation of EDTA and glyoxylic acid by ferryl ion and H202, respectively, with inhibition due to sludge accumulation, and equilibrium metal coprecipitation. This ambient process, to our knowledge previously unknown, agrees with recently reported findings and shows promise for remediation of metals, metalloids, and radionuclides in wastewater, soil, and sediment.
authors.affiliation: Civil, Architectural, and Environmental Engineering, University of Miami, PO Box 248294, Coral Gables, Florida 33124-0630, USA. jenglehardt@miami.edu
authors.forename: James D
authors.initials: JD
authors.lastname: Englehardt
authors.forename: Daniel E
authors.initials: DE
authors.lastname: Meeroff
authors.forename: Luis
authors.initials: L
authors.lastname: Echegoyen
authors.forename: Yang
authors.initials: Y
authors.lastname: Deng
authors.forename: Françisco M
authors.initials: FM
authors.lastname: Raymo
authors.forename: Tomoyuki
authors.initials: T
authors.lastname: Shibata
mesh_terms: D001149:Arsenates / Q000737:chemistry / Q000302:isolation & purification; D018053:Arsenites / Q000737:chemistry / Q000302:isolation & purification; D011232:Chemical Precipitation; D004492:Edetic Acid / Q000737:chemistry / Q000302:isolation & purification*; D008401:Gas Chromatography-Mass Spectrometry; D006861:Hydrogen Peroxide; D007287:Inorganic Chemicals / Q000737:chemistry / Q000302:isolation & purification*; D007501:Iron / Q000737:chemistry; D008670:Metals / Q000737:chemistry / Q000302:isolation & purification; D010084:Oxidation-Reduction; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014876:Water Pollution / Q000517:prevention & control*
chemical_list: D001149:Arsenates; D018053:Arsenites; D007287:Inorganic Chemicals; D008670:Metals; D014874:Water Pollutants, Chemical; D004492:Edetic Acid; D006861:Hydrogen Peroxide; D007501:Iron; C015001:arsenite; C025657:arsenic acid