Synthesis of oligo(phenylene ethynylene)s with dendrimer "shells" for molecular electronics.
Two series of oligo(phenylene ethynylene)s (OPEs) with different dendrimer side groups have been designed and synthesized. The molecules contain thiol groups at both ends to enable interconnection between nanoscale gapped metallic electrodes. The different dendrimer groups act as "shells", allowing tailoring to the nanoscopic environment surrounding the OPE "core". Meanwhile, the dendrimer shells also act as spacers for the precise control of the packing density and intermolecular interaction between the OPE cores. [structure: see text].
Shi
Zi-Fa
ZF
State Key Laboratory of Applied Organic Chemistry and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou, Gansu 730000, China.
Wang
Le-Jia
LJ
Wang
Hong
H
Cao
Xiao-Ping
XP
Zhang
Hao-Li
HL