Exploiting the multifunctionality of organocations in the assembly of hybrid polyoxometalate clusters and networks.
Assembly of an unprecedented [(P(V)Mn(II)W(VI)(11)O(39))2{P(V)O(4)}](13-) and a [P(2)Mn(4)W(18)O(68)](10-) cluster have been observed and structurally characterised and cryospray mass spectroscopic ionization (CSI) has been used to observe one of the very reactive building blocks linking solid state with solution studies.
Ritchie
Chris
C
WestCHEM, Department of Chemistry, University of Glasgow, Joseph Black Building, University Avenue, Glasgow, UKG12 8QQ.
Burkholder
Eric M
EM
Long
De-Liang
DL
Adam
David
D
Kögerler
Paul
P
Cronin
Leroy
L
D002412:Cations / Q000737:chemistry; D017895:Manganese Compounds / Q000737:chemistry*; D015394:Molecular Structure; D028561:Transition Elements / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*; D017968:Vanadium Compounds / Q000737:chemistry*
D002412:Cations; D017895:Manganese Compounds; D028561:Transition Elements; D017973:Tungsten Compounds; D017968:Vanadium Compounds