Precession technique and electron diffractometry as new tools for crystal structure analysis and chemical bonding determination.
We have developed a new fast electron diffractometer working with high dynamic range and linearity for crystal structure determinations. Electron diffraction (ED) patterns can be scanned serially in front of a Faraday cage detector; the total measurement time for several hundred ED reflections can be tens of seconds having high statistical accuracy for all measured intensities (1-2%). This new tool can be installed to any type of TEM without any column modification and is linked to a specially developed electron beam precession "Spinning Star" system. Precession of the electron beam (Vincent-Midgley technique) reduces dynamical effects allowing also use of accurate intensities for crystal structure analysis. We describe the technical characteristics of this new tool together with the first experimental results. Accurate measurement of electron diffraction intensities by electron diffractometer opens new possibilities not only for revealing unknown structures, but also for electrostatic potential determination and chemical bonding investigation. As an example, we present detailed atomic bonding information of CaF(2) as revealed for the first time by precise electron diffractometry.
Avilov
A
A
Institute of Crystallography of Russian Academy of Sciences, Leninsky prosp. 59, Moscow 119333, Russian Federation. avilov@ns.crys.ras.ru <avilov@ns.crys.ras.ru>
Kuligin
K
K
Nicolopoulos
S
S
Nickolskiy
M
M
Boulahya
K
K
Portillo
J
J
Lepeshov
G
G
Sobolev
B
B
Collette
J P
JP
Martin
N
N
Robins
A C
AC
Fischione
P
P