title: Versatile and efficient synthesis of omega-functionalized asymmetric disulfides via sulfenyl bromide adducts.
abstract: Various types of asymmetric disulfides can be synthesized under mild conditions and in excellent yields by a method involving dialkoxylthiophosphoranesulfenyl halide precursors. This straightforward, rapid procedure is used to prepare a series of disulfides bearing neutral, acidic, and basic terminal groups as well as groups commonly used in biospecific self-assembled monolayers.
authors.affiliation: ProChimia Surfaces, ul. Zacisze 2, 81-823 Sopot, Poland.
authors.forename: Janusz
authors.initials: J
authors.lastname: Kowalczyk
authors.forename: Piotr
authors.initials: P
authors.lastname: Barski
authors.forename: Dariusz
authors.initials: D
authors.lastname: Witt
authors.forename: Bartosz A
authors.initials: BA
authors.lastname: Grzybowski
mesh_terms: D001965:Bromides / Q000737:chemistry*; D002384:Catalysis; D002627:Chemistry, Physical / Q000379:methods*; D004220:Disulfides / Q000737:chemistry*; D004563:Electrochemistry / Q000379:methods; D008956:Models, Chemical; D015394:Molecular Structure
chemical_list: D001965:Bromides; D004220:Disulfides