title: Structure-property relationships of DEAEM-containing bone cements: effect of the substitution of a methylene group by an aromatic ring.
abstract: New aromatic methacrylates were prepared by substitution of a methylene group from diethylaminoethyl methacrylate (DEAEM) by an aromatic ring at two different positions. Diethylamino benzyl methacrylate (DEABM) and N-methacryloyloxyethyl)-N-ethyl-m-toluidine (MEET) were polymerized and incorporated as co-monomers in bone cement formulations. Cements were evaluated in terms of curing and mechanical properties in addition to changes in their glass transition temperature by DSC and surface properties by contact angle measurements. The immediate effect of the presence of an aromatic ring within the amino methacrylate was that it modified the bone cements' physical appearance, as colored products were obtained. It was also observed that peak temperature increased and setting time decreased by the use of DEABM and MEET instead of DEAEM. Simultaneously, both tensile and compressive strength of bone cements were improved; this effect was related to a higher glass transition temperature. In addition, surface properties of cements were modified by the incorporation of the aromatic ring, being more hydrophilic at low molar fractions and more hydrophobic at high molar fractions. Based on these studies, it is concluded that the position of the aromatic ring within the amino methacrylate modified not only the cement's appearance, but also the setting and mechanical properties.
authors.affiliation: Centro de Investigación Científica de Yucatán, A.C. Calle 43 No. 130, Col. Chuburná de Hidalgo, C.P. 97200 Mérida, Yucatán, México. manceruc@cicy.mx
authors.forename: J M
authors.initials: JM
authors.lastname: Cervantes-Uc
authors.forename: J V
authors.initials: JV
authors.lastname: Cauich-Rodríguez
authors.forename: H
authors.initials: H
authors.lastname: Vázquez-Torres
mesh_terms: D001672:Biocompatible Materials / Q000737:chemistry*; D001843:Bone Cements / Q000737:chemistry*; D008422:Materials Testing; D008689:Methacrylates / Q000737:chemistry*; D011109:Polymethacrylic Acids / Q000737:chemistry*; D013499:Surface Properties; D013696:Temperature; D013718:Tensile Strength; D014052:Toluidines / Q000737:chemistry
chemical_list: D001672:Biocompatible Materials; D001843:Bone Cements; D008689:Methacrylates; C519538:N-methacryloyloxyethyl-N-ethyl-m-toluidine; D011109:Polymethacrylic Acids; D014052:Toluidines; C519537:diethylaminoethyl methacrylate