Ruthenium-catalysed linear-selective allylic alkylation of allyl acetates.
The regioselectivity in the ruthenium-catalysed allylic alkylation of mono substituted allyl acetates with the malonate anion was highly controlled by Ru3(CO)12 with 2-(diphenylphosphino)benzoic acid, and the linear-type alkylated product was obtained.
Kawatsura
Motoi
M
Department of Materials Science, Faculty of Engineering, Tottori University, Koyama, Tottori, 680-8552, Japan. kawatsur@chem.tottori-u.ac.jp
Ata
Fumio
F
Wada
Shohei
S
Hayase
Shuichi
S
Uno
Hidemitsu
H
Itoh
Toshiyuki
T