Resolution of enantiomers in solution and determination of the chirality of extended metal atom chains.
The resolution of enantiomers of extended metal atom chains of the type Ni3[(C5H5N)2N]4Cl2 has been accomplished by chromatographic methods in solution, and the chirality was determined using vibrational circular dichroism, electronic circular dichroism, optical rotatory dispersion, and density functional theory calculations.
Armstrong
Daniel W
DW
Department of Chemistry and Biochemistry, University of Texas at Arlington, Arlington, Texas 76019, USA.
Cotton
F Albert
FA
Petrovic
Ana G
AG
Polavarapu
Prasad L
PL
Warnke
Molly M
MM
D002942:Circular Dichroism; D008956:Models, Chemical; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009905:Optical Rotatory Dispersion; D009942:Organometallic Compounds / Q000737:chemistry*; D012680:Sensitivity and Specificity; D012996:Solutions / Q000737:chemistry; D013237:Stereoisomerism
D009942:Organometallic Compounds; D012996:Solutions; D009532:Nickel