Effect of oxidation treatment on the adsorption and the stability of mercury on activated carbon.
Oxidation treatment on the adsorption and the stability of Hg on activated carbon (AC) was inrestigated. Both MnO2-AC and FeCl3-AC were produced during oxidation treatment. The measurement of modified AC's mercury adsorption capacity was conducted in a simulated coal-fired flue gas by adsorbing test apparatus. TCLP and column leaching methods were used to test the stability of mercury adsorbed on ACs. The results indicate that the oxidation treatment changed the pore structure of the AC and modified the carbon surface by creating chemical components such as MnO4-, Mn4+, O, NO3-, Fe3+, Cl-, etc. The Hg sorption capacity on MnO2-AC or FeCl3-AC was about three times higher than that of untreated carbon. In addition, the mercury control cost of each of the formers was about the half cost of the untreated carbon. The stability of Hg absorption was studied, it found that mercury adsorbed on the oxidation treated AC was not better than that of untreated carbon. It could concluded that the insoluble form of Hg is very important to the stability of mercury adsorbed on AC. This study suggests that the FeCl3-AC is the best absorbent for Hg with high adsorption capacity, better Hg adsorption stability in leaching environment, and lower cost among the three ACs tested.
Hu
Chang-xing
CX
State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China. huchx@zju.edu.cn
Zhou
Jin-song
JS
Luo
Zhong-yang
ZY
He
Sheng
S
Wang
Guang-kai
GK
Cen
Ke-fa
KF
D000327:Adsorption; D002606:Charcoal / Q000737:chemistry*; D002681:China; D004787:Environmental Pollution / Q000517:prevention & control*; D008628:Mercury / Q000737:chemistry*; D008854:Microscopy, Electron; D010084:Oxidation-Reduction; D011210:Power Plants / Q000379:methods*; D013050:Spectrometry, Fluorescence
D002606:Charcoal; D008628:Mercury