title: First trinuclear paramagnetic transition metal complexes with redox active ligands derived from TTF: Co2M(PhCOO)6(TTF-CH=CH-py)2.2CH3CN, M = CoII, MnII.
abstract: The first paramagnetic homo- and hetero-metallic trinuclear complexes with redox active ligands derived from TTF are synthesized, the central metal ion has an octahedral coordination sphere while the outer Co(II) ions are in a distorted bipyramidal surrounding, bearing TTF-ligands, the magnetic properties show antiferromagnetic coupling leading to a magnetic ground state.
authors.affiliation: Organométalliques et Matériaux Moléculaires, UMR 6226 CNRS-UR1 Sciences Chimiques de Rennes, Université de Rennes 1, 35042, Rennes Cedex, France.
authors.forename: Konstantin S
authors.initials: KS
authors.lastname: Gavrilenko
authors.forename: Yann Le
authors.initials: YL
authors.lastname: Gal
authors.forename: Olivier
authors.initials: O
authors.lastname: Cador
authors.forename: Stéphane
authors.initials: S
authors.lastname: Golhen
authors.forename: Lahcène
authors.initials: L
authors.lastname: Ouahab