title: Assessment of calcium polysulfide for the remediation of hexavalent chromium in chromite ore processing residue (COPR).
abstract: Bench scale and pilot scale treatability studies were conducted to evaluate the remediation of hexavalent chromium [Cr(VI)] in chromite ore processing residue (COPR) using calcium polysulfide. The results from the bench scale study indicated that a calcium polysulfide dosage twice the molar stoichiometric requirement (2x) proved effective in meeting the New Jersey Department of Environmental Protection (NJDEP) total Cr(VI) and the Environmental Protection Agency (EPA) Toxicity Characteristic Leaching Procedure (TCLP) regulatory standards. The treatment results were more effective at pH 12 than at pH 9.5. X-ray powder diffraction (XRPD) and X-ray absorption near edge structure (XANES) spectroscopy were also used to assess the treatment performance. Based on the bench scale results, an ex-situ pugmill pilot program was implemented to evaluate the applicability of the calcium polysulfide treatment on a larger scale (1000-lb batch test). The pugmill treatment results met Cr(VI) and TCLP regulatory standards over a period of 15 months. XANES analysis indicated that approximately 62% of Cr(VI) was reduced by calcium polysulfide at stoichiometric ratio of 2x after a curing period of 10 months.
authors.affiliation: W.M. Keck Geoenvironmental Laboratory, Center for Environmental Systems, Stevens Institute of Technology, Hoboken, NJ 07030, USA. mwazne@stevens.edu
authors.forename: Mahmoud
authors.initials: M
authors.lastname: Wazne
authors.forename: Santhi Chandra
authors.initials: SC
authors.lastname: Jagupilla
authors.forename: Deok Hyun
authors.initials: DH
authors.lastname: Moon
authors.forename: Sarath Chandra
authors.initials: SC
authors.lastname: Jagupilla
authors.forename: Christos
authors.initials: C
authors.lastname: Christodoulatos
authors.forename: Min Gyu
authors.initials: MG
authors.lastname: Kim
mesh_terms: D017610:Calcium Compounds / Q000008:administration & dosage* / Q000737:chemistry; D002857:Chromium / Q000032:analysis / Q000737:chemistry; D052918:Environmental Restoration and Remediation / Q000379:methods*; D006256:Hazardous Waste; D006801:Humans; D007220:Industrial Waste / Q000032:analysis*; D008669:Metallurgy; D009515:New Jersey; D013440:Sulfides / Q000008:administration & dosage* / Q000737:chemistry; D013885:Thiosulfates / Q000008:administration & dosage* / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000032:analysis; D014961:X-Ray Diffraction
chemical_list: D017610:Calcium Compounds; D006256:Hazardous Waste; D007220:Industrial Waste; D013440:Sulfides; D013885:Thiosulfates; D014874:Water Pollutants, Chemical; D002857:Chromium; C074702:chromium hexavalent ion; C033907:calcium sulfide