title: X-ray photoreduction of a di(mu-oxo)Mn(III)Mn(IV) complex occurs at temperatures as low as 20 K.
abstract: Full reduction of the Mn(III)(mu-O)2Mn(IV) core to Mn(II)(mu-OH2)2Mn(II) is observed upon irradiation by an X-ray beam at ca. 20 K.
authors.affiliation: Laboratoire DRDCIPMB, UMR 5155 CEA-CNRS- UJF, CEA-Grenoble, 38054 Grenoble Cedex 9, France.
authors.forename: Lionel
authors.initials: L
authors.lastname: Dubois
authors.forename: Lilian
authors.initials: L
authors.lastname: Jacquamet
authors.forename: Jacques
authors.initials: J
authors.lastname: Pécaut
authors.forename: Jean-Marc
authors.initials: JM
authors.lastname: Latour
mesh_terms: D003080:Cold Temperature; D008345:Manganese; D009942:Organometallic Compounds / Q000737:chemistry*; D010777:Photochemistry; D013696:Temperature; D014965:X-Rays
chemical_list: D009942:Organometallic Compounds; D008345:Manganese