A facile synthesis of aliphatic thiol surfactant with tunable length as a stabilizer of gold nanoparticles in organic solvents.
Three new aliphatic thiol surfactants were synthesized by reacting alkyl bromide with hexamethyldisilathiane under a mild condition. This approach provides an easy access for the direct synthesis of various different length thiol surfactants which play a crucial role in tuning the properties of gold nanoparticles. Gold nanoparticles encapsulated with one of our synthetic thiols were prepared and well characterized by H NMR, UV-vis, FT-IR, and TEM. The hybrid nanoparticles are very stable in both organic solvents and the solid state.
Zhou
Xiaoli
X
Liquid Crystal Institute, Kent State University, Kent, OH 44242, USA.
El Khoury
Jouliana M
JM
Qu
Liangti
L
Dai
Liming
L
Li
Quan
Q
D006046:Gold / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D053768:Metal Nanoparticles; D046529:Microscopy, Electron, Transmission; D009930:Organic Chemicals / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis*; D013501:Surface-Active Agents / Q000138:chemical synthesis*
D009930:Organic Chemicals; D013438:Sulfhydryl Compounds; D013501:Surface-Active Agents; D006046:Gold