Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation.
An organosilicon cation stabilized by intramolecular pyridyl coordination was effectively generated and accumulated by oxidative Si-Si bond dissociation of the corresponding disilane using low temperature electrolysis, and was characterized by NMR and CSI-MS.
Nokami
Toshiki
T
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigakukatsura, Nishikyo-ku, Kyoto, 615-8510, Japan. tnokami@sbchem.kyoto-u.ac.jp
Soma
Ryoji
R
Yamamoto
Yoshimasa
Y
Kamei
Toshiyuki
T
Itami
Kenichiro
K
Yoshida
Jun-Ichi
J