Phosphonopeptide K-26 biosynthetic intermediates in Astrosporangium hypotensionis.
Precursors and advanced intermediates for phosphonopeptide K-26 biosynthesis were synthesized and incorporation studies in Astrosporangium hypotensionis suggest a new mechanism of C-P bond formation in aromatic phosphonates.
Ntai
Ioanna
I
Vanderbilt University Chemistry Department, Nashville, TN, USA.
Phelan
Vanessa V
VV
Bachmann
Brian O
BO
D001419:Bacteria / Q000378:metabolism*; D009842:Oligopeptides / Q000096:biosynthesis*; D063065:Organophosphonates; D010750:Phosphoproteins / Q000096:biosynthesis
D009842:Oligopeptides; D063065:Organophosphonates; D010750:Phosphoproteins; C005149:phosphonoproteins; C508953:tripeptide K-26