Residues of organochlorine pesticides in near shore waters of LaiZhou Bay and JiaoZhou Bay, Shandong Peninsula, China.
The extent of organochlorine pesticides (OCPs) contamination in coastal waters around LaiZhou Bay and JiaoZhou Bay in Shandong Peninsula, northern China, was investigated. The areas around the two bays are both densely populated, thrive with intensive agriculture and industrial activities. Multi-techniques including GC-MS, GC-muECD coupled with chemical peak confirmation and strict QC procedures were used for the quantitative determination of 15 OCPs including alpha, beta, gamma and delta isomers of hexachlorocyclohexane (HCH), pentachloronitrobenzene (PCNB), heptachlor, aldrin, endosulfan, p,p'-DDE, dieldrin, endrin, p,p'-DDD, o,p'-DDT, p,p'-DDT and methoxychlor. The survey results show that contaminations by OCP residues remain widespread in the areas, but the averaged concentration levels are all below the regulatory limits, e.g., CMC limits (acute criterion values) specified in US Environmental Protection Agency (USEPA) and China national standards. Average concentration of OCPs in water samples were from undetectable to 3.8 ng l(-1) in LaiZhou Bay and from 0.1 to 3.9 ng l(-1) in JiaoZhou Bay, respectively. A comparison between the current and historical data shows a rapidly decreasing trend of OCPs over the past twenty years in the study areas.
Xu
Xiaoqin
X
Department of Chemistry and the Key Laboratory of Analytical Science of the Ministry of Education, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China.
Yang
Huanghao
H
Li
Qingling
Q
Yang
Baijuan
B
Wang
Xiaoru
X
Lee
Frank S C
FS
D002681:China; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D006843:Hydrocarbons, Chlorinated / Q000032:analysis*; D010573:Pesticide Residues / Q000032:analysis*; D012623:Seawater / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis*
D006843:Hydrocarbons, Chlorinated; D010573:Pesticide Residues; D014874:Water Pollutants, Chemical