title: Photocatalytic degradation of L-acid by TiO2 supported on the activated carbon.
abstract: TiO2 sol was prepared by sol-gel technique with tetrabutyl titanate as precursor. Supported TiO2 catalysts on activated carbon were prepared by soak and sintering method. The aggregation of nano-TiO2 particles can be effectively suppressed by added polyethylene glycol (PEG) as a surface modifier. The average particle diameter of TiO2, specific surface area and absorbability of catalyst can be modified. Based on characteristics of the TiO2 photocatalyst with XRD, specific surface area, adsorption valves of methylene blue and the amount of TiO2 supported on the activated carbon, the photocatalytic degradation of L-acid was studied. The effect of the factors, such as pH of the solution, the initial concentration of L-acid on the photocatalytic degradation of L-acid, were studied also. It was found that when the pH of the solution is 1.95, the amount of photocatalyst is 0.5 g, the concentration of the L-acid solution is 1.34 x 10(-3) mol/L and the illumination time is 7 h, the photocatalytic degradation efficiency of L-acid can reach 89.88%. The catalyst was reused 6 times and its degradation efficiency hardly changed.
authors.affiliation: School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
authors.forename: Yu-Ping
authors.initials: YP
authors.lastname: Wang
authors.forename: Lian-Jun
authors.initials: LJ
authors.lastname: Wang
authors.forename: Pan-Ying
authors.initials: PY
authors.lastname: Peng
mesh_terms: D000327:Adsorption; D002384:Catalysis; D002606:Charcoal / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D009282:Naphthalenesulfonates / Q000032:analysis / Q000737:chemistry*; D010100:Oxygen / Q000032:analysis; D010316:Particle Size; D044367:Phase Transition; D010777:Photochemistry / Q000379:methods*; D011092:Polyethylene Glycols; D014025:Titanium / Q000737:chemistry*; D014865:Waste Disposal, Fluid / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000032:analysis*; D018508:Water Purification / Q000379:methods*; D014961:X-Ray Diffraction
chemical_list: D009282:Naphthalenesulfonates; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; D002606:Charcoal; D011092:Polyethylene Glycols; D014025:Titanium; D010100:Oxygen