X-ray photoreduction of a di(mu-oxo)Mn(III)Mn(IV) complex occurs at temperatures as low as 20 K.
Full reduction of the Mn(III)(mu-O)2Mn(IV) core to Mn(II)(mu-OH2)2Mn(II) is observed upon irradiation by an X-ray beam at ca. 20 K.
Dubois
Lionel
L
Laboratoire DRDCIPMB, UMR 5155 CEA-CNRS- UJF, CEA-Grenoble, 38054 Grenoble Cedex 9, France.
Jacquamet
Lilian
L
Pécaut
Jacques
J
Latour
Jean-Marc
JM
D003080:Cold Temperature; D008345:Manganese; D009942:Organometallic Compounds / Q000737:chemistry*; D010777:Photochemistry; D013696:Temperature; D014965:X-Rays
D009942:Organometallic Compounds; D008345:Manganese