Structurally characterized intermediates in the stepwise insertion of CO-ethylene or CO-methyl acrylate into the metal-carbon bond of Pd(II) complexes stabilized by (phosphinomethyl)oxazoline ligands.
The initial CO-ethylene or CO-methyl acrylate insertion steps into the Pd-Me bond of methylpalladium(II) complexes with (phosphinomethyl)oxazoline ligands, leading to metallacycles, have been fully characterized, including by X-ray diffraction.
Agostinho
Magno
M
Laboratoire de Chimie de Coordination (UMR 7177 CNRS), Institut de Chimie, Université Louis Pasteur, 4 rue Blaise Pascal, F-67070 Strasbourg Cédex, France.
Braunstein
Pierre
P