Very large acceleration of the photoinduced electron transfer in a Ru(bpy)3-naphthalene bisimide dyad bridged on the naphthyl core.
By linking a naphthalenebisimide (NBI) unit to [Ru(bpy)3]2+ on the naphthyl core the rate of photoinduced Ru-to-NBI electron transfer was 1000-fold increased compared to the case with a conventional linking on the nitrogen.
Chaignon
Frédérique
F
Laboratoire de Synthèse Organique, UMR 6513 CNRS & FR CNRS 2465, Université de Nantes, Faculté des Sciences et des Techniques de Nantes, BP 92208, Nantes Cedex 03, France.
Falkenström
Magnus
M
Karlsson
Susanne
S
Blart
Errol
E
Odobel
Fabrice
F
Hammarström
Leif
L