title: Phosphonopeptide K-26 biosynthetic intermediates in Astrosporangium hypotensionis.
abstract: Precursors and advanced intermediates for phosphonopeptide K-26 biosynthesis were synthesized and incorporation studies in Astrosporangium hypotensionis suggest a new mechanism of C-P bond formation in aromatic phosphonates.
authors.affiliation: Vanderbilt University Chemistry Department, Nashville, TN, USA.
authors.forename: Ioanna
authors.initials: I
authors.lastname: Ntai
authors.forename: Vanessa V
authors.initials: VV
authors.lastname: Phelan
authors.forename: Brian O
authors.initials: BO
authors.lastname: Bachmann
mesh_terms: D001419:Bacteria / Q000378:metabolism*; D009842:Oligopeptides / Q000096:biosynthesis*; D063065:Organophosphonates; D010750:Phosphoproteins / Q000096:biosynthesis
chemical_list: D009842:Oligopeptides; D063065:Organophosphonates; D010750:Phosphoproteins; C005149:phosphonoproteins; C508953:tripeptide K-26