Characteristics of photocatalytic oxidation of toluene, benzene, and their mixture.
The investigation of the photocatalytic oxidation (PCO) of multicomponent volatile organic compounds (VOCs) is very important to the application of PCO technology, because there is seldom a single VOC component in indoor air. In this paper, the characteristics of binary indoor VOCs, toluene and benzene, were experimentally studied using a mass transfer based method that we developed. The concentration ranges for toluene and benzene were 4.48-27.4 mg/m3 and 1.82-4.08 mg/m3, respectively. We found the following: (1) the PCO of each individual contaminant studied obeys the unimolecular form of the Langmuir-Hinshelwood (L-H) rate form; (2) the PCO of the binary contaminants follow the competitive adsorption L-H rate form; (3) the reaction-coefficient for PCO of individual contaminants differs from that in the competitive adsorption L-H rate form; and (4) the component impact factor of A to B, put forward in this paper, is a useful parameter describing the influence of A on the reaction coefficient of B, and it was found that the impact factor of toluene (a chemically active component) on benzene (a chemically stable component) is high, and the impact factor of benzene on toluene is low.
Zhang
Yin-Ping
YP
Department of Building Science, Tsinghua University, Beijing, People's Republic of China. zhangyp@mail.tsinghua.edu.cn
Yang
Rui
R
Xu
Qiu-Jian
QJ
Mo
Jin-Han
JH
D000465:Algorithms; D001554:Benzene / Q000737:chemistry*; D002384:Catalysis; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D007700:Kinetics; D010084:Oxidation-Reduction; D010777:Photochemistry; D014050:Toluene / Q000737:chemistry*
D014050:Toluene; D001554:Benzene