title: Supramolecular rotor: adamantylammonium([18]crown-6) in [Ni(dmit)2]- salt.
abstract: Adamantylammonium (ADNH3+) was complexed with [18]crown-6, forming a supramolecular cation of (ADNH3+)([18]crown6), which was introduced into a [Ni(dmit)2]- salt as a supramolecular rotor. The cation layers were alternately arranged with [Ni(dmit)2]- layers in the crystal, in which the molecular rotation of (ADNH3+)([18]crown-6) was confirmed from the temperature-dependent solid-state 1H NMR.
authors.affiliation: Research Institute for Electronic Science, Hokkaido University, N12W6, Sapporo 060-0812, Japan.
authors.forename: Daisuke
authors.initials: D
authors.lastname: Sato
authors.forename: Tomoyuki
authors.initials: T
authors.lastname: Akutagawa
authors.forename: Sadamu
authors.initials: S
authors.lastname: Takeda
authors.forename: Shin-ichiro
authors.initials: S
authors.lastname: Noro
authors.forename: Takayoshi
authors.initials: T
authors.lastname: Nakamura