Theoretical model based on the memory effect for the strange photoisomerization kinetics of diarylethene derivatives dispersed on polymer films.
In the present paper the authors present a theoretical model to explain the kinetics involving the induction period observed by Irie et al. [Nature (London) 420, 759 (2002)] for photoisomerization of diarylethene derivatives dispersed on polymer films at a single molecular level. In the model we assume that both ground state and excited state free energy landscapes which result from the interaction between the photochromic molecule and the surrounding polymer are rugged and have several local minima along the pathway to the critical point at which isomerization actually occurs. We assume that after one photoexcitation a fraction of the photochromic molecule moves to a new local minimum and stays there, although the other fraction returns to the original local minimum. The former effect is referred to as the memory effect. After repeated photoexcitations the photochromic molecule moves gradually from one local minimum to another in the pathway to the isomerization point. It finally reaches the isomerization point, where isomerization occurs. Their model successfully reproduces the kinetics of photoisomerization of diarylethene derivatives dispersed on polymer films observed experimentally.
Seki
Kazuhiko
K
National Institute of Advanced Industrial Science and Technology, AIST Tsukuba Central 5, Higashi 1-1-1, Tsukuba, Ibaraki 305-8565, Japan. k-seki@aist.go.jp
Tachiya
M
M