Supramolecular rotor: adamantylammonium([18]crown-6) in [Ni(dmit)2]- salt.
Adamantylammonium (ADNH3+) was complexed with [18]crown-6, forming a supramolecular cation of (ADNH3+)([18]crown6), which was introduced into a [Ni(dmit)2]- salt as a supramolecular rotor. The cation layers were alternately arranged with [Ni(dmit)2]- layers in the crystal, in which the molecular rotation of (ADNH3+)([18]crown-6) was confirmed from the temperature-dependent solid-state 1H NMR.
Sato
Daisuke
D
Research Institute for Electronic Science, Hokkaido University, N12W6, Sapporo 060-0812, Japan.
Akutagawa
Tomoyuki
T
Takeda
Sadamu
S
Noro
Shin-ichiro
S
Nakamura
Takayoshi
T