Synthesis and characterisation of a mixed-valence Mn13 complex with S6 symmetry by using 2-phenoxybenzoate.
The synthesis, structure and magnetic properties of [Mn(13)O(8)(OEt)6(O(2)CC(6)H(4)OPh)12] are reported as the first example of a high nuclearity manganese complex with 2-phenoxybenzoate: the complex possesses S6 symmetry and an S = 11/2 ground state.
Ferguson
Alan
A
WestCHEM, Department of Chemistry, University of Glasgow, University Avenue, Glasgow, UKG12 8QQ.
Thomson
Katrina
K
Parkin
Andrew
A
Cooper
Paul
P
Milios
Constantinos J
CJ
Brechin
Euan K
EK
Murrie
Mark
M