Multicomponent adhesive hard sphere models and short-ranged attractive interactions in colloidal or micellar solutions.
We investigate the dependence of the stickiness parameters tij=1/(12tauij)--where the tauij are the conventional Baxter parameters--on the solute diameters sigmai and sigmaj in multicomponent sticky hard sphere (SHS) models for fluid mixtures of mesoscopic neutral particles. A variety of simple but realistic interaction potentials, utilized in the literature to model short-ranged attractions present in real solutions of colloids or reverse micelles, is reviewed. We consider: (i) van der Waals attractions, (ii) hard-sphere-depletion forces, (iii) polymer-coated colloids, and (iv) solvation effects (in particular hydrophobic bonding and attractions between reverse micelles of water-in-oil microemulsions). We map each of these potentials onto an equivalent SHS model by requiring the equality of the second virial coefficients. The main finding is that, for most of the potentials considered, the size-dependence of tij(T,sigmai,sigmaj) can be approximated by essentially the same expression, i.e., a simple polynomial in the variable sigmaisigmaj/sigmaij2, with coefficients depending on the temperature T, or--for depletion interactions--on the packing fraction eta0 of the depletant particles.
Gazzillo
Domenico
D
Istituto Nazionale per la Fisica della Materia and Dipartimento di Chimica Fisica, Università di Venezia, S. Marta DD 2137, I-30123 Venezia, Italy. gazzillo@unive.it
Giacometti
Achille
A
Fantoni
Riccardo
R
Sollich
Peter
P
D000268:Adhesiveness; D003102:Colloids / Q000737:chemistry*; D003198:Computer Simulation; D004548:Elasticity; D006244:Hardness; D008823:Micelles; D008956:Models, Chemical; D008958:Models, Molecular; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D012996:Solutions; D055672:Static Electricity; D013314:Stress, Mechanical
D003102:Colloids; D008823:Micelles; D012996:Solutions