{[Cu(mtz)]3(CuI)}n: an unprecedented non-interpenetrated (12(3))(12(2).14)(3) network with triple-stranded helices.
A complex with triple-stranded helices, {[Cu(mtz)]3(CuI)}n, was obtained under hydrothermal conditions. The complex possesses an unprecedented non-interpenetrated (12(3))(12(2).14)3 network, which represents the first example of the largest gon value of the smallest ring for the Archimedean net reported so far.
Huang
Xi-He
XH
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China.
Sheng
Tian-Lu
TL
Xiang
Sheng-Chang
SC
Fu
Rui-Biao
RB
Hu
Sheng-Min
SM
Li
Ya-Min
YM
Wu
Xin-Tao
XT
D003300:Copper / Q000737:chemistry*; D008958:Models, Molecular; D013055:Spectrophotometry, Infrared; D014961:X-Ray Diffraction
D003300:Copper