The performance and application of fly ash modified by PDMDAAC.
Fly ash modification by polydimethydiallylammonium chloride (PDMDAAC) in laboratory scale was explored in this work and the adsorption performance of modified fly ash and its application in dyeing wastewater treatment were also studied. The key factors (concentration and temperature) for PDMDAAC to affect the adsorption properties of fly ash (FA) were revealed using the orthogonal test with four factors. The results indicated that the adsorption magnitude of fly ash to PDMDAAC increased due to its favorable specific surface causing the change of the surface charge nature. Hence, adsorption performance of modified fly ash on organic molecules and its ion exchange capacity are strengthened. The maximum color removal efficiency was obtained as 88.2% by modified fly ash with 2.0 g/100 mL dosage in dyeing wastewater, which is much higher than 12.5% color removal efficiency by raw fly ash with the same dosage. And, the used modified fly ash could be used for cement production as additive agent. The intensity of cement produced with 15% the modified fly ash in weight reached the Chinese Cement Standard (GB/T17671-1999), blazing a promising novel way in fly ash utilization.
Cao
X Y
XY
School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China.
Yue
Q Y
QY
Song
L Y
LY
Li
M
M
Zhao
Y C
YC
D000327:Adsorption; D002244:Carbon; D060729:Coal Ash; D004396:Coloring Agents; D003252:Construction Materials; D007220:Industrial Waste / Q000517:prevention & control*; D052638:Particulate Matter; D011095:Polyethylenes; D000644:Quaternary Ammonium Compounds; D013499:Surface Properties; D014873:Water Pollutants / Q000302:isolation & purification*
D060729:Coal Ash; D004396:Coloring Agents; D007220:Industrial Waste; D052638:Particulate Matter; D011095:Polyethylenes; D000644:Quaternary Ammonium Compounds; D014873:Water Pollutants; C041004:poly-N,N-dimethyl-N,N-diallylammonium chloride; D002244:Carbon