title: Aqueous phototransformation of zinc pyrithione Degradation kinetics and byproduct identification by liquid chromatography--atmospheric pressure chemical ionisation mass spectrometry.
abstract: The photochemical behavior of the antifouling agent zinc pyrithione (ZnPT) was studied in aqueous media of different composition under simulated solar irradiation using a xenon light source. The influence of important constituents of natural water (dissolved organic matter and nitrate) was also examined using a multivariate kinetic model. It was found that photodegradation proceeds via a pseudo first-order reaction. Kinetic experiments were monitored by LC-MS and photolytic half-lives ranging between 9.2 and 15.1 min have been observed. The increasing concentration of dissolved organic matter (DOM) accelerates the photolysis reaction, while the effect of nitrate ions was also positive since it increased the degradation rate, but to a lesser extent. Irradiation of the aqueous ZnPT solutions gave rise to several transformation products that were isolated by means of solid-phase extraction using poly(styrene-divinylbenzene) extraction disks. These byproducts were identified using liquid chromatography-atmospheric pressure chemical ionisation mass spectrometry. Besides 2-pyridinesulfonic-acid, other degradation products formed included pyridine-N-oxide, 2-mercaptopyridine, 2,2'-dithiobis(pyridine-N-oxide), 2,2-dipyridyl disulfide and the pyridine/pyrithione mixed disulfide, 2,2'-dithiobispyridine mono-N-oxide (PPMD).
authors.affiliation: Department of Chemistry, University of Ioannina, Ioannina 45110, Greece. vsakkas@cc.uoi.gr
authors.forename: V A
authors.initials: VA
authors.lastname: Sakkas
authors.forename: K
authors.initials: K
authors.lastname: Shibata
authors.forename: Y
authors.initials: Y
authors.lastname: Yamaguchi
authors.forename: S
authors.initials: S
authors.lastname: Sugasawa
authors.forename: T
authors.initials: T
authors.lastname: Albanis
mesh_terms: D001274:Atmospheric Pressure; D006207:Half-Life; D007700:Kinetics; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry* / Q000528:radiation effects*; D010782:Photolysis / Q000528:radiation effects*; D011725:Pyridines / Q000737:chemistry* / Q000528:radiation effects*; D052616:Solid Phase Extraction; D021241:Spectrometry, Mass, Electrospray Ionization / Q000379:methods*; D013056:Spectrophotometry, Ultraviolet; D013472:Sunlight; D014867:Water / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000528:radiation effects
chemical_list: D009942:Organometallic Compounds; D011725:Pyridines; D014874:Water Pollutants, Chemical; D014867:Water; C010423:pyrithione zinc