title: Synthesis, characterization, and immobilization of Prussian blue-modified Au nanoparticles: application to electrocatalytic reduction of H2O2.
abstract: Au nanoparticles modified with electroactive Prussian blue (PB) were for the first time synthesized by a simple chemical method. Transmission electronic microscopy showed that the average size of the Prussian blue shell/Au core hybrid composite (PB@Au) was about 50 nm, and Fourier transform IR, UV-vis spectra, and cyclic voltammetry confirmed the existence of PB on the surface of Au nanoparticles. Using the LbL technique, multilayer thin films of PB@Au nanoparticles were prepared by the alternate adsorption of oppositely charged linear polyelectrolyte poly(allylamine hydrochloride) (PAH) onto ITO glass for the construction of a hydrogen peroxide sensor. The novel multilayer films were characterized by SEM, cyclic voltammetry, and UV-visible absorption spectroscopy. The {PAH/PB@Au}n multilayer-modified electrode showed a well-defined pair of redox peaks and dramatic catalytic activity toward the reduction of hydrogen peroxide.
authors.affiliation: Key Laboratory of Analytical Chemistry for Life Science, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
authors.forename: Jian-Ding
authors.initials: JD
authors.lastname: Qiu
authors.forename: Hong-Zhen
authors.initials: HZ
authors.lastname: Peng
authors.forename: Ru-Ping
authors.initials: RP
authors.lastname: Liang
authors.forename: Jian
authors.initials: J
authors.lastname: Li
authors.forename: Xing-Hua
authors.initials: XH
authors.lastname: Xia
mesh_terms: D002384:Catalysis; D004563:Electrochemistry; D005295:Ferrocyanides / Q000138:chemical synthesis / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure*; D010084:Oxidation-Reduction; D013057:Spectrum Analysis
chemical_list: D005295:Ferrocyanides; D006046:Gold; D006861:Hydrogen Peroxide; C000170:ferric ferrocyanide