title: Generation of pyridyl coordinated organosilicon cation pool by oxidative Si-Si bond dissociation.
abstract: An organosilicon cation stabilized by intramolecular pyridyl coordination was effectively generated and accumulated by oxidative Si-Si bond dissociation of the corresponding disilane using low temperature electrolysis, and was characterized by NMR and CSI-MS.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Kyotodaigakukatsura, Nishikyo-ku, Kyoto, 615-8510, Japan. tnokami@sbchem.kyoto-u.ac.jp
authors.forename: Toshiki
authors.initials: T
authors.lastname: Nokami
authors.forename: Ryoji
authors.initials: R
authors.lastname: Soma
authors.forename: Yoshimasa
authors.initials: Y
authors.lastname: Yamamoto
authors.forename: Toshiyuki
authors.initials: T
authors.lastname: Kamei
authors.forename: Kenichiro
authors.initials: K
authors.lastname: Itami
authors.forename: Jun-Ichi
authors.initials: J
authors.lastname: Yoshida