Rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks.
Novel rhodium(I) complexes with N-heterocyclic carbenes bearing a 2,3,4,5-tetraphenylphenyl and its higher dendritic frameworks were synthesized and the complexes were used as catalysts in rhodium-catalyzed hydrosilylation of alpha,beta-unsaturated ketones to show high 1,4-adduct selectivity.
Sato
Hiromichi
H
Department of Energy and Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, and CREST, Japan Science and Technology Agency (JST), Kyoto 615-8510, Japan.
Fujihara
Tetsuaki
T
Obora
Yasushi
Y
Tokunaga
Makoto
M
Kiyosu
Junya
J
Tsuji
Yasushi
Y