The synthesis of 1-thia-6-oxa-6alambda(4)-seleno-3-azapentalene and a 3H-1,2,4-dithiazole.
The reaction of thiocarbamoyl isoselenocyanate with a carbanion gave 1-thia-6-oxa-6alambda(4)-seleno-3-azapentalene, which has a hypervalent selenium, as the major product. The by-products 3-diacylmethylidene-5-dimethylamino-3H-1,2,4-dithiazole and thiocarbamate thioanhydride were also formed.
Koketsu
Mamoru
M
Division of Instrumental Analysis, Life Science Research Center, Gifu University, Gifu 501-1193, Japan. koketsu@gifu-u.ac.jp
Otsuka
Toshihiro
T
Swenson
Dale
D
Ishihara
Hideharu
H
D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D016566:Organoselenium Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012680:Sensitivity and Specificity; D013237:Stereoisomerism; D013844:Thiazoles / Q000138:chemical synthesis* / Q000737:chemistry; D013859:Thiocarbamates / Q000138:chemical synthesis / Q000737:chemistry
C519291:1-thia-6-oxa-6agamma(4)-seleno-3-azapentalene; D019086:Bridged Bicyclo Compounds, Heterocyclic; D016566:Organoselenium Compounds; D013844:Thiazoles; D013859:Thiocarbamates