Solvent-free, heterogeneous photooxygenation of hydrocarbons by hyflon membranes embedding a fluorous-tagged decatungstate.
Hybrid fluoropolymeric membranes with 25% loading of the fluorous-tagged (RfN)4W10O32 effect the solvent-free photooxygenation of benzylic C-H bonds with up to 6100 TONs in 4 hours.
Carraro
Mauro
M
ITM-CNR and Department of Chemical Sciences, University of Padova, Via Marzolo, 1, 35131, Padova, Italy.
Gardan
Martino
M
Scorrano
Gianfranco
G
Drioli
Enrico
E
Fontananova
Enrica
E
Bonchio
Marcella
M