title: Synthesis of carbon encapsulated magnetic nanoparticles with giant coercivity by a spray pyrolysis approach.
abstract: Carbon encapsulated magnetic (metal) nanoparticles (CEMNPs) have wide applications in biomedicine and the magnetic recording industry. However, synthesis of such particles with a high coercive force and good ferromagnetism is still a great challenge. The present study reports a new method for the continuous production of CEMNPs of high purity. This involves the spray pyrolysis of a mixture of iron pentacarbonyl and ethanol at 500-900 degrees C. Results show that the Fe (or Fe3C) particles synthesized at 700 and 900 degrees C were well encapsulated by graphitic layers with rare byproducts such as carbon nanotubes, nanofibers, or bulk amorphous carbon. Those synthesized at 700 degrees C had a particle size of 30-50 nm, a giant coercive force of 867 Oe, and a good magnetic remanence of 33% at room temperature. The present approach based on spray pyrolysis is advantageous over previous ones in suitability for large-scale production, and the synthesized material has wide applications in many fields.
authors.affiliation: School of Materials Science and Engineering, Shanghai Jiao Tong University, Shanghai 200030, People's Republic of China. jnwang@mail.sjtu.edu.cn
authors.forename: Jian Nong
authors.initials: JN
authors.lastname: Wang
authors.forename: Li
authors.initials: L
authors.lastname: Zhang
authors.forename: Fan
authors.initials: F
authors.lastname: Yu
authors.forename: Zhao Ming
authors.initials: ZM
authors.lastname: Sheng
mesh_terms: D000431:Ethanol / Q000737:chemistry; D006108:Graphite / Q000737:chemistry*; D058085:Iron Compounds / Q000737:chemistry*; D008280:Magnetics; D053768:Metal Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure
chemical_list: D058085:Iron Compounds; D000431:Ethanol; C515100:iron pentacarbonyl; D006108:Graphite