title: Total synthesis of (+)-sundiversifolide.
abstract: The first, enantiocontrolled total synthesis of (+)-sundiversifolide has been accomplished using the sequential ring-closing metathesis, [3,3]-sigmatropic rearrangement, and iodolactonization for the key assembly of the cis-fused oxabicyclo[5.3.0]decene framework of the natural product. [structure: see text]
authors.affiliation: Graduate School of Pharmaceutical Sciences, The University of Tokushima, 1-78-1 Sho-machi, Tokushima 770-8505, Japan.
authors.forename: Hiromasa
authors.initials: H
authors.lastname: Yokoe
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Sasaki
authors.forename: Tomoyuki
authors.initials: T
authors.lastname: Yoshimura
authors.forename: Mitsuru
authors.initials: M
authors.lastname: Shindo
authors.forename: Masahiro
authors.initials: M
authors.lastname: Yoshida
authors.forename: Kozo
authors.initials: K
authors.lastname: Shishido
mesh_terms: D001688:Biological Products / Q000138:chemical synthesis*; D001643:Bridged Bicyclo Compounds / Q000737:chemistry; D001952:Bridged-Ring Compounds / Q000737:chemistry; D003500:Cyclization; D007783:Lactones / Q000737:chemistry; D008956:Models, Chemical; D013237:Stereoisomerism; D014966:Xanthenes / Q000138:chemical synthesis*
chemical_list: D001688:Biological Products; D001643:Bridged Bicyclo Compounds; D001952:Bridged-Ring Compounds; D007783:Lactones; D014966:Xanthenes; C516925:bicyclo(5.3.0)decane; C433844:sundiversifolide