Effect of pre-treatment and supporting media on Ni(II), Cu(II), Al(III) and Fe(III) sorption by plant root material.
In this work Paspalum notatum root material was used to elucidate the influence of acid leaching pre-treatment and of sorption medium on metal adsorption. Ground P. notatum root was leached with 0.14M HNO(3). Leached root material (LRM) and non-leached root material (NLRM) were employed to flow sorption of Ni(II), Cu(II), Al(III) and Fe(III) in 0.5M CH(3)COONH(4) medium at pH 6.5. For LRM the sorption was also studied in 0.5M KNO(3) medium. The acid pre-treatment increased the sorption capacity (SC) for all ions studied. For the KNO(3) medium, Cu(II) and Fe(III) sorption was higher than in CH(3)COONH(4) and the type of the Ni(II) isotherm's model changed. The Freundlich model was the most representative isotherm model to describe metallic ions sorption. The (1)H NMR spectra showed differences between LRM and NLRM and the acid-basic potentiometric titration elucidated that acid-leaching procedure affected the root material sorption sites once only two predominant sorption sites were found for LRM (phenolic and amine, both able cations sorption) and five sorption sites (two carboxylic, amine and two phenolic) were founded for NLRM.
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Grupo de Análise Instrumental Aplicada, Embrapa Pecuária Sudeste, Caixa Postal 339, 13560-970 São Carlos, SP, Brazil. geolabuto@yahoo.com.br
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D000327:Adsorption; D000535:Aluminum / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007501:Iron / Q000737:chemistry*; D007700:Kinetics; D009532:Nickel / Q000737:chemistry*; D009566:Nitrates; D031781:Paspalum; D018517:Plant Roots / Q000737:chemistry* / Q000378:metabolism; D017680:Potassium Compounds; D012989:Soil Pollutants
D009566:Nitrates; D017680:Potassium Compounds; D012989:Soil Pollutants; D003300:Copper; D009532:Nickel; D000535:Aluminum; D007501:Iron; C023844:potassium nitrate