Synthesis of 1,3,5-tricarbonyl derivatives by condensation of 1,3-bis(silyl enol ethers) with acid chlorides.
A variety of 1,3,5-tricarbonyl derivatives were prepared by reaction of 1,3-bis(silyl enol ethers) with acid chlorides under mild conditions. This includes reactions of both aromatic and aliphatic acid chlorides and bis(acid chlorides). The yields vary depending on the type of acid chloride employed.
Rahn
Thomas
T
Institut für Chemie, Universität Rostock, Albert-Einstein-Strasse 3a, 18059 Rostock, Germany.
Nguyen
Van T H
VT
Dang
T H Tam
TH
Ahmed
Zafar
Z
Methling
Karen
K
Lalk
Michael
M
Fischer
Christine
C
Spannenberg
Anke
A
Langer
Peter
P
D000143:Acids / Q000737:chemistry; D004986:Ether / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis; D012821:Silanes / Q000737:chemistry*
D000143:Acids; D009942:Organometallic Compounds; D012821:Silanes; D004986:Ether