Catalytic promiscuity in biomimetic systems: catecholase-like activity, phosphatase-like activity, and hydrolytic DNA cleavage promoted by a new dicopper(II) hydroxo-bridged complex.
Presented in this Communication are the structure, physicochemical properties, and catalytic promiscuity of a new dinuclear CuII(mu-OH)CuII complex containing a novel N,O-donor symmetric dinucleating ligand.
Rey
Nicolás A
NA
Laboratório de Bioinorgânica e Cristalografia (LABINC), Departamento de Química, Universidade Federal de Santa Catarina, 88040-900 Florianópolis, Santa Catarina, Brazil.
Neves
Ademir
A
Bortoluzzi
Adailton J
AJ
Pich
Claus T
CT
Terenzi
Hernán
H
D002384:Catalysis; D002396:Catechols / Q000378:metabolism*; D003300:Copper / Q000378:metabolism*; D004247:DNA / Q000378:metabolism*; D006868:Hydrolysis; D008958:Models, Molecular; D018716:Molecular Mimicry; D010744:Phosphoric Monoester Hydrolases / Q000378:metabolism*; D013056:Spectrophotometry, Ultraviolet
D002396:Catechols; D003300:Copper; D004247:DNA; D010744:Phosphoric Monoester Hydrolases