Metal cages using a bulky phosphonate as a ligand.
The synthesis, structure, magnetic and electronic properties of soluble transition metal phosphonate cages utilizing tritylphosphonic acid (TPA) as ligand are reported.
Baskar
Viswanathan
V
Department of Chemistry, The University of Manchester, Oxford Road, Manchester, UK M13 9PL.
Shanmugam
Muralidharan
M
Sañudo
E Carolina
EC
Shanmugam
Maheswaran
M
Collison
David
D
McInnes
Eric J L
EJ
Wei
Qiang
Q
Winpenny
Richard E P
RE
D003035:Cobalt / Q000737:chemistry; D003300:Copper / Q000737:chemistry; D018360:Crystallography, X-Ray; D004578:Electron Spin Resonance Spectroscopy; D008280:Magnetics; D008345:Manganese / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D063065:Organophosphonates / Q000737:chemistry*; D028561:Transition Elements / Q000737:chemistry; D014320:Triphenylmethyl Compounds / Q000737:chemistry*
D009942:Organometallic Compounds; D063065:Organophosphonates; D028561:Transition Elements; D014320:Triphenylmethyl Compounds; D003035:Cobalt; D008345:Manganese; D003300:Copper