Total synthesis of (+/-)-trans-dihydronarciclasine through a highly endo-selective Diels-Alder cycloaddition of 3,5-dibromo-2-pyrone.
Shin
In-Ji
IJ
Department of Chemistry, Hanyang University, 17 Haengdang-Dong, Sungdong-Ku, Seoul, Korea.
Choi
Eun-Sil
ES
Cho
Cheon-Gyu
CG
D000470:Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry; D004365:Drugs, Chinese Herbal / Q000138:chemical synthesis* / Q000737:chemistry; D006801:Humans; D008968:Molecular Conformation; D015394:Molecular Structure; D010936:Plant Extracts / Q000737:chemistry; D011753:Pyrones / Q000737:chemistry*
C450850:3,5-dibromo-2-pyrone; D000470:Alkaloids; D004365:Drugs, Chinese Herbal; D010936:Plant Extracts; D011753:Pyrones; C064338:dihydronarciclasine