Preparation of fused polycyclic vinylcyclopropanes via radical cascade reactions.
Radical cascades employing (dichloromethyl)dimethylsilyl ethers as both a point of radical initiation and termination, allow efficient entry to fused polycyclic cyclopropanes, and are also suitable for the design of other radical processes terminated by beta-elimination of chloride.
Maddess
Matthew L
ML
Laboratorie de Chimie Organique, UMR CNRS 7611, Institut de Chimie Moléculaire FR 2769, Université Pierre et Marie Curie - Paris 6, Case 229, 4 Place Jussieu, 75005, Paris, France.
Mainetti
Emily
E
Harrak
Youssef
Y
Brancour
Célia
C
Devin
Priscille
P
Dhimane
Anne-Lise
AL
Fensterbank
Louis
L
Malacria
Max
M