Asymmetric reactions on chiral catalysts entrapped within a mesoporous cage.
The encapsulation of homogeneous chiral catalysts, e.g. Co(Salen) and Ru-TsDPEN, in the mesoporous cage of SBA-16 is demonstrated; the encapsulated catalysts show performance as good as that of the homogeneous catalysts, and can be recycled for more than 10 times without significant loss of catalytic performance.
Yang
Hengquan
H
State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China.
Li
Jun
J
Yang
Jie
J
Liu
Zhimin
Z
Yang
Qihua
Q
Li
Can
C