Catalytic activity of silica gels bound manganese(III)-porphyrin on oxidative reaction of adrenaline.
To develop a solid catalysis on oxidative reaction of adrenaline (Ad), supports bound metal-tetrakis(4-carboxyphenyl)porphine (M-TCPP) were investigated. Silica gels bound Mn-TCPP were proved to has a superior activity in the oxidation of Ad and be able to serve as a useful oxidase model for Ad.
Kitamura
Youji
Y
Department of Pharmaceutical Sciences, Graduate School of Medicine and Dentistry and Pharmaceutical Sciences, Okayama University, Tsushima-Naka, Okayama, Japan.
Takatsuki
Tsutomu
T
Kawamoto
Mayu
M
Saito
Madoka
M
Iwado
Akimasa
A
Tsukamoto
Ikuko
I
Mifune
Masaki
M
Saito
Yutaka
Y
D002384:Catalysis; D004837:Epinephrine / Q000737:chemistry*; D006415:Hematoporphyrins / Q000737:chemistry*; D008665:Metalloporphyrins / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D058428:Silica Gel; D012822:Silicon Dioxide / Q000737:chemistry*
D006415:Hematoporphyrins; D008665:Metalloporphyrins; D058428:Silica Gel; C065506:manganese (III) hematoporphyrin; D012822:Silicon Dioxide; D004837:Epinephrine