title: Highly selective copper-catalyzed ring expansion of vinyl thiiranes: application to synthesis of biotin and the heterocyclic core of plavix.
authors.affiliation: Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.
authors.forename: Erik
authors.initials: E
authors.lastname: Rogers
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Araki
authors.forename: Lindsay A
authors.initials: LA
authors.lastname: Batory
authors.forename: Christine E
authors.initials: CE
authors.lastname: McInnis
authors.forename: Jon T
authors.initials: JT
authors.lastname: Njardarson
mesh_terms: D001710:Biotin / Q000138:chemical synthesis*; D002384:Catalysis; D000077144:Clopidogrel; D003300:Copper / Q000737:chemistry; D006571:Heterocyclic Compounds / Q000138:chemical synthesis*; D013440:Sulfides / Q000737:chemistry*; D013876:Thiophenes / Q000138:chemical synthesis; D013988:Ticlopidine / Q000031:analogs & derivatives* / Q000138:chemical synthesis; D014753:Vinyl Compounds / Q000737:chemistry
chemical_list: D006571:Heterocyclic Compounds; D013440:Sulfides; D013876:Thiophenes; D014753:Vinyl Compounds; D001710:Biotin; D003300:Copper; C013523:ethylene sulfide; D000077144:Clopidogrel; D013988:Ticlopidine