title: On-line determination of the molar ratio between methanol and isobutylene in feedstock of a methyl tertiary butyl ether production plant using near-infrared spectroscopy.
abstract: The molar ratio between methanol and isobutylene (MRMI) is very important to the operation of methyl tertiary butyl ether (MTBE) production units. A new on-line near-infrared (NIR) analytical system was integrated for monitoring the MRMI in real time and was successfully applied in a rubber plant. Calibration models for methanol and isobutylene were established using partial least squares (PLS). The sample temperature effect on the performance of the models is discussed. The MRMI is calculated by methanol content and isobutylene content predicted by NIR. A large benefit has been obtained by the user through controlling the operation of the unit according to the monitoring of the MRMI of the feedstock in real time.
authors.affiliation: Beijing University of Chemical Technology, Beijing 100029 China. yhf204@263.net
authors.forename: Hongfu
authors.initials: H
authors.lastname: Yuan
authors.forename: Xianhui
authors.initials: X
authors.lastname: Luo
authors.forename: Guojun
authors.initials: G
authors.lastname: Zheng
authors.forename: Wei
authors.initials: W
authors.lastname: Hua
authors.forename: Xiaoli
authors.initials: X
authors.lastname: Chu
authors.forename: Wanzhen
authors.initials: W
authors.lastname: Lu
mesh_terms: D000475:Alkenes / Q000032:analysis*; D002617:Chemical Industry / Q000379:methods*; D004867:Equipment Design; D019544:Equipment Failure Analysis; D005336:Fiber Optic Technology / Q000295:instrumentation* / Q000379:methods; D017022:Flow Injection Analysis / Q000295:instrumentation* / Q000379:methods; D000432:Methanol / Q000032:analysis*; D008738:Methyl Ethers / Q000032:analysis / Q000737:chemistry*; D009862:Online Systems; D013055:Spectrophotometry, Infrared / Q000295:instrumentation* / Q000379:methods
chemical_list: D000475:Alkenes; D008738:Methyl Ethers; C043243:methyl tert-butyl ether; C008176:isobutylene; D000432:Methanol