Determination of dieldrin in wool products by gas chromatography with microwave-assisted extraction.
Dieldrin is a moth-proofing agent that was banned by the Stockholm Convention in 2001. The amount of dieldrin in wool products was measured by a microwave-assisted extraction (MAE) method. The optimal conditions were as follows: extraction solvent, acetone/n-hexane (1:1 v/v); extraction temperature, 110 degrees C; extraction time, 10 min; solvent volume, 25 mL. When six samples were used, dieldrin contents determined by GC with the proposed MAE agreed closely with those by the Japanese official method using GC with solvent extraction and cleanup by column chromatography. The proposed MAE has two merits. First, the pretreatment of the MAE needs only 4 h for 11 samples, while that using the Japanese official method needs 2 days for six samples. Second, the volume of organic solvents used for the proposed method was only about one-tenth of that used in the Japanese official method. Our proposed method seems to be easy and useful for daily (routine) tests. Dieldrin contents of 28 used wool products, which were obtained from local clothing shops and ordinary homes, were determined by GC with the proposed MAE, and six products contained dieldrin (0.310-175 ppm). The dry cleaning of the woolen yarn containing 175 ppm dieldrin did not remove a significant amount of dieldrin. Therefore, it seems likely that dieldrin is still distributed slightly but widely throughout the world.
Ohto
Mikiya
M
Toyama Institute of Health, Imizu-City, Toyama, Japan. mikiya.oto@pref.toyama.lg.jp
Kodama
Shuji
S
Saito
Yukio
Y
Yamamoto
Atushi
A
D000818:Animals; D002849:Chromatography, Gas / Q000379:methods*; D004026:Dieldrin / Q000032:analysis*; D007306:Insecticides / Q000032:analysis*; D013058:Mass Spectrometry; D008872:Microwaves; D014935:Wool / Q000737:chemistry*
D007306:Insecticides; D004026:Dieldrin