Enhanced luminescence of Eu(3+) by Y(3+) in ternary complexes Eu(X)Y(1-X)(TTA)3Dipy.
Rare-earth ternary complexes Eu(X)Y(1-X)(TTA)3Dipy {X=0, 0.1, 0.25, 0.5, 0.75, 0.9, 1.0, using thenoyltrifluoroacetone (TTA) as ligand and 2,2'-dipyridyl (Dipy) as synergic agent} were synthesized. Characterization with X-ray diffraction (XRD), IR and elemental analysis had also been carried out. The photophysical properties of these complexes were studied in detail with ultraviolet absorption spectra and fluorescent spectra. It is found that the enhanced luminescence of Eu(3+) ions by Y(3+) ions occurs in ternary complexes. And we monitored the spectra of Eu(X)Y(1-X)(TTA)3Dipy (PVK:Eu/BCP/AlQ/Al) at the different rate (rpm). The results showed that the Y(3+) ion acts as an energy transfer bridge that helps energy transfer from PVK to Eu(3+).
Lv
Yuguang
Y
Institute of Modern Catalysis, Beijing University of Chemical Technology, State Key Laboratory of Chemical Resource Engineering, Beijing 100029, China.
Zhang
Jingchang
J
Cao
Weiliang
W
Juan
Joon Ching
JC
Zhang
Fujun
F
Xu
Zheng
Z
D015082:2,2'-Dipyridyl / Q000737:chemistry*; D004563:Electrochemistry; D005063:Europium / Q000737:chemistry*; D008024:Ligands; D049449:Luminescence; D009942:Organometallic Compounds / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D013804:Thenoyltrifluoroacetone / Q000737:chemistry*; D014961:X-Ray Diffraction; D015019:Yttrium / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D013804:Thenoyltrifluoroacetone; D005063:Europium; D015082:2,2'-Dipyridyl; D015019:Yttrium