Preconcentration and solid phase extraction method for the determination of Co, Cu, Ni, Zn and Cd in environmental and biological samples using activated carbon by FAAS.
2-{[1-(2-Hydroxynaphthyl) methylidene] amino} benzoic acid (HNMABA) was synthesized for solid phase extraction (SPE) to the determination of Co, Cu, Ni, Zn and Cd in environmental and biological samples by flame atomic absorption spectrophotometry (FAAS). These metals were sorbed as HNMABA complexes on activated carbon (AC) at the pH range of 5.0+/-0.2 and eluted with 6 ml of 1M HNO3 in acetone. The effects of sample volume, eluent volume and recovery have been investigated to enhance the sensitivity and selectivity of proposed method. The effect of interferences on the sorption of metal ions was studied. The concentration of the metal ions detected after preconcentration was in agreement with the added amount. The detection limits for the metals studied were in the range of 0.75-3.82 microg ml(-1). The proposed system produced satisfactory results for the determination of Co, Cu, Ni, Zn and Cd metals in environmental and biological samples.
Kiran
K
K
Department of Environmental Sciences, S. V. University, Tirupati 517502, AP, India.
Suresh Kumar
K
K
Suvardhan
K
K
Janardhanam
K
K
Chiranjeevi
P
P
D002104:Cadmium / Q000032:analysis; D002606:Charcoal; D003035:Cobalt / Q000032:analysis; D003300:Copper / Q000032:analysis; D004784:Environmental Monitoring / Q000379:methods*; D019216:Metals, Heavy / Q000032:analysis*; D009532:Nickel / Q000032:analysis; D052616:Solid Phase Extraction / Q000379:methods*; D013054:Spectrophotometry, Atomic; D015032:Zinc / Q000032:analysis
D019216:Metals, Heavy; D002104:Cadmium; D002606:Charcoal; D003035:Cobalt; D003300:Copper; D009532:Nickel; D015032:Zinc