A one-pot synthesis of a paramagnetic high-nuclearity nickel(II) cluster: an octadecanuclear Ni(II)16Na(I)2 metal aggregate.
An unusual Ni(II)(16)Na(I)(2) cluster which features formate as a bridging clamp between two octanuclear nickel cages is reported; preliminary magnetic studies exhibit paramagnetic low-lying states resulting from dominating antiferromagnetic interactions between the nickel(II) centers.
Biswas
Biplab
B
Max-Planck-Institut für Bioanorganische Chemie, Stiftstrasse 34-36, D-45470, Mülheim an der Ruhr, Germany.
Khanra
Sumit
S
Weyhermüller
Thomas
T
Chaudhuri
Phalguni
P