title: Inhibition of nonlinear acoustic cavitation dynamics in liquid CO2.
abstract: The authors present a model to study ultrasound-induced cavitation dynamics in liquid carbon dioxide (CO(2)), which includes descriptions for momentum, mass, and energy transport. To assist in the interpretation of these results, numerical simulations are presented for an argon cavity in water. For aqueous systems, inertia effects and force accumulation lead to a nonlinear radial motion, resulting in an almost adiabatic compression of the cavity interior. The simulations for liquid CO(2) suggest that transport limitations impede nonlinear cavitation dynamics and the corresponding temperature rise. Consequently, in liquid CO(2) the ultrasound-induced formation of radicals appears improbable.
authors.affiliation: Process Development Group, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
authors.forename: Maikel M
authors.initials: MM
authors.lastname: van Iersel
authors.forename: Jeroen
authors.initials: J
authors.lastname: Cornel
authors.forename: Nieck E
authors.initials: NE
authors.lastname: Benes
authors.forename: Jos T F
authors.initials: JT
authors.lastname: Keurentjes