Silyl-modified Bellus-Claisen rearrangement.
A silyl-modified variant of the Bellus-Claisen rearrangement is described; the generality of this rearrangement has been demonstrated with a range of allylic amines and ketenes.
Craig
Donald
D
Department of Chemistry, Imperial College London, South Kensington Campus, London, UKSW7 2AZ. d.craig@imperial.ac.uk
King
N Paul
NP
Mountford
David M
DM
D000475:Alkenes / Q000737:chemistry*; D000498:Allyl Compounds / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D003500:Cyclization; D004952:Esters; D005030:Ethylenes / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D008698:Mesylates / Q000737:chemistry*; D008956:Models, Chemical; D015394:Molecular Structure; D013237:Stereoisomerism; D014297:Trimethylsilyl Compounds
D000475:Alkenes; D000498:Allyl Compounds; D000588:Amines; D004952:Esters; D005030:Ethylenes; D007659:Ketones; D008698:Mesylates; D014297:Trimethylsilyl Compounds; C053353:trimethylsilyl trifluoromethanesulfonate; C008223:ketene