title: Sunflower seed shells: a novel and effective low-cost adsorbent for the removal of the diazo dye Reactive Black 5 from aqueous solutions.
abstract: In this paper, the potential of two low-cost adsorbents such as sunflower seed shells (SS) and mandarin peelings (MP) in the removal of the synthetic anionic dye Reactive Black 5 (RB5) from aqueous solutions was investigated. SS led to a percentage of dye removal higher than MP (85% and 71% after 210min, respectively, for an initial RB5 concentration of 50mgL(-1) and an initial pH of 2.0). The rate of adsorption followed a pseudo-second-order kinetic model and the intra-particle diffusion was found to be the rate-controlling stage. In addition, the equilibrium data fitted well both the Freundlich and multilayer adsorption isotherm equations indicating the heterogeneity of the adsorbent surface. This was also corroborated by the SEM photographs. On the whole, the results in this study indicated that SS were very attractive materials for removing anionic dyes from dyed effluents.
authors.affiliation: Department of Chemical Engineering, Rovira i Virgili University, Av. Països Catalans 26, 43007 Tarragona, Spain.
authors.forename: Johann F
authors.initials: JF
authors.lastname: Osma
authors.forename: Verónica
authors.initials: V
authors.lastname: Saravia
authors.forename: José L
authors.initials: JL
authors.lastname: Toca-Herrera
authors.forename: Susana Rodríguez
authors.initials: SR
authors.lastname: Couto
mesh_terms: D000327:Adsorption; D003365:Costs and Cost Analysis; D006368:Helianthus / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008855:Microscopy, Electron, Scanning; D009282:Naphthalenesulfonates / Q000302:isolation & purification*; D010316:Particle Size; D012639:Seeds / Q000737:chemistry*; D012996:Solutions; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
chemical_list: D009282:Naphthalenesulfonates; D012996:Solutions; D014874:Water Pollutants, Chemical; C063421:Remazol black B