title: Chemical modification of jute fibers for the production of green-composites.
abstract: Natural fiber reinforced composites is an emerging area in polymer science. Fibers derived from annual plants are considered a potential substitute for non-renewable synthetic fibers like glass and carbon fibers. The hydrophilic nature of natural fibers affects negatively its adhesion to hydrophobic polymeric matrices. To improve the compatibility between both components a surface modification has been proposed. The aim of the study is the chemical modification of jute fibers using a fatty acid derivate (oleoyl chloride) to confer hydrophobicity and resistance to biofibers. This reaction was applied in swelling and non-swelling solvents, pyridine and dichloromethane, respectively. The formation of ester groups, resulting from the reaction of oleoyl chloride with hydroxyl group of cellulose were studied by elemental analysis (EA) and Fourier Transform infrared spectroscopy (FTIR). The characterization methods applied has proved the chemical interaction between the cellulosic material and the coupling agent. The extent of the reactions evaluated by elemental analysis was calculated using two ratios. Finally electron microscopy was applied to evaluate the surface changes of cellulose fibers after modification process.
authors.affiliation: Group Lepamap, Department of Chemical Engineering, University of Girona, Girona 17071, Spain. farners.corrales@udg.es
authors.forename: F
authors.initials: F
authors.lastname: Corrales
authors.forename: F
authors.initials: F
authors.lastname: Vilaseca
authors.forename: M
authors.initials: M
authors.lastname: Llop
authors.forename: J
authors.initials: J
authors.lastname: Gironès
authors.forename: J A
authors.initials: JA
authors.lastname: Méndez
authors.forename: P
authors.initials: P
authors.lastname: Mutjè
mesh_terms: D002384:Catalysis; D002482:Cellulose / Q000737:chemistry*; D003247:Conservation of Natural Resources; D008752:Methylene Chloride / Q000737:chemistry; D009829:Oleic Acids / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry; D012997:Solvents / Q000737:chemistry
chemical_list: C417980:4-(dimethylamine)pyridine; D009829:Oleic Acids; D011725:Pyridines; D012997:Solvents; D008752:Methylene Chloride; D002482:Cellulose; C023666:pyridine