Template synthesis of benzannulated triphosphacyclononanes--a new class of phosphacrowns via template assisted nucleophilic P-C bond formation.
A 9-membered triphosphorus macrocycle with o-phenylene backbone functions has been stereoselectively prepared on a CpFe(+) template by two successive nucleophilic attacks of coordinated phosphide on a coordinated o-fluorophenylbiphosphine.
Albers
Thomas
T
School of Chemistry, Cardiff University, Park Place, Cardiff, UK.
Edwards
Peter G
PG
D018360:Crystallography, X-Ray; D034242:Cyclooctanes / Q000138:chemical synthesis* / Q000737:chemistry; D007202:Indicators and Reagents; D047028:Macrocyclic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D034242:Cyclooctanes; D007202:Indicators and Reagents; D047028:Macrocyclic Compounds; D009943:Organophosphorus Compounds