Nonaqueous suspensions of surface-modified kaolin.
A range of different stabilizers have been used to render natural kaolin clay particles hydrophobic and dispersible in nonpolar solvents such as heptane. Both silanol and aluminol groups are known to be present at the kaolin surface. Use of a Hammett indicator showed that silanes would not neutralize the acidic aluminol sites, whereas amines would neutralize these sites. Both types of stabilizer adsorbed chemically onto the clay. In addition, a combined silane + amine treatment and a polyisobutylene-based stabilizer with a succinimide/amine head group (SAP230) were also considered. Both would neutralize the acid sites. The final sediment density after settling under gravity was used to gauge suspension stability, which varied with the kaolin surface treatment as silanes < amines < silane + amine < SAP230. This behavior was very similar for suspensions in heptane and in a higher molecular weight branched alkane, polydecene. This trend of increasing stability correlated very well with an increase in surface coverage of the stabilizing moieties, a decrease in particle size found using small-angle light scattering, and a decrease in Bingham yield stress obtained by fitting rheological data.
Zhang
Yan
Y
School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, U.K.
Gittins
David I
DI
Skuse
David
D
Cosgrove
Terence
T
van Duijneveldt
Jeroen S
JS