A new versatile strategy for C-aryl glycosides.
A versatile strategy involving a sequential intermolecular enyne metathesis of C-alkynyl glycosides with ethylene, Diels-Alder, and aromatization reactions is successfully developed to provide a range of C-aryl glycosides. [reaction: see text]
Kaliappan
Krishna P
KP
Department of Chemistry, Indian Institute of Technology-Bombay, Powai, Mumbai 400 076, India. kpk@chem.iitb.ac.in
Subrahmanyam
Ayyagari V
AV