title: Stepwise charge transfer complexation of some pyrimidines with sigma-acceptor iodine involving a new unconventional acceptor.
abstract: Interactions of some pyrimidine derivatives, 4-amino-2,6-dimethylpyrimidine, kyanmethin, (4AP), 2-amino-4,6-dimethylpyrimidine (2AP), 2-aminopyrimidine (AP), 2-amino-4-methylpyrimidine (AMP), 2-amino-4-methoxy-6-methylpyrimidine (AMMP), and 4-amino-5-chloro-2,6-dimethylpyrimidine (ACDP) as electron donors, with iodine (I(2)), as a typical sigma-electron acceptor, have been studied. Electronic absorption spectra of these interactions in several organic solvents of different polarities have performed instant appearance of clear charge transfer (CT) bands. Formation constants (KCT), molar absorption coefficients (epsilonCT) and thermodynamic properties, DeltaH, DeltaS, and DeltaG, of these interactions have been determined and discussed. Electronic absorption spectra of the solutions of the synthesized pyrimidines-iodine, P-I2, CT complexes have shown the characteristic bands of the triiodide ion, I3*. UV/vis spectral tracking of these interactions have shown that by lapse of time the first formed CT complex, P-I2, is transformed to the corresponding triiodide complex, P(+)I.I3*, then, the later interacts as a new unconventional acceptor and it forms a CT complex of the form (P).(P+I.I3*). Elemental analyses of these solid complexes have indicated the stoichiometric ratio 2:2, or formally 1:1, P:I2.
authors.affiliation: Chemistry Department, Faculty of Science at Qena, South Valley University, Qena, Egypt. umrabie@yahoo.com
authors.forename: Usama M
authors.initials: UM
authors.lastname: Rabie
authors.forename: Ramadan A
authors.initials: RA
authors.lastname: Mohamed
authors.forename: Moustafa H
authors.initials: MH
authors.lastname: Abou-El-Wafa
mesh_terms: D007455:Iodine / Q000737:chemistry*; D007700:Kinetics; D011743:Pyrimidines / Q000737:chemistry*; D012997:Solvents; D013057:Spectrum Analysis; D013696:Temperature; D013816:Thermodynamics
chemical_list: D011743:Pyrimidines; D012997:Solvents; D007455:Iodine; C030986:pyrimidine