[Characterization and photocatalytic activity of Ni-doped tiO2 nano photocatalysts prepared by low temperature combustion synthesis].
Ni-doped TiO2 photocatalysts were prepared by low temperature combustion synthesis and some properties, such as optical absorption, crystal type, grain size distribution and chemistry transformation during temperature rising were characterized by UV-Vis DRS, X-ray diffraction (XRD), laser light dispersion grain size measurement machine and TG-DSC respectively. The photocatalytic activities of the prepared photocatalysts under visible light irradiation were evaluated by monitoring the degradation of methylene blue dye, a probe pollutant. The results indicate that the Ni-doped TiO2 photocatalysts prepared by low temperature combustion synthesis shift the optical absorption threshold to visible light, the band gap of 0.4 Ni-TiO2 (atomic ratio) is 2.3 eV, which corresponds to a 564 nm threshold in the visible light range. The crystal type of photocatalyst is anatase TiO2 and the content of NiTiO3 rise with the increase of Ni dopant. The grain size of photocatalyst distributes from 50 to 150nm, which account for 96.9% of entire quantity. During temperature rising, the TiO2 phase in photocatalyst transforms from amorphous structure to anatase and NiTiO3 crystallites appear at 445.2 degrees C. After 150 min visible light irradiation, 93.9% of methylene blue dye are degraded over 0.4 Ni-TiO2 photocatalyst. The photocatalytic activity of Ni doped TiO2 is higher than that of P25 under identical conditions.
Liu
Chao
C
Department of Environmental Engineering, Jinan University, Guangzhou 510632, China.
Tang
Xin-Hu
XH
Mo
Ce-Hui
CH
Wang
Jun
J
D001557:Benzenesulfonates / Q000737:chemistry*; D002384:Catalysis / Q000528:radiation effects; D003080:Cold Temperature; D004785:Environmental Pollutants / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry*; D010777:Photochemistry; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction
D001557:Benzenesulfonates; D004785:Environmental Pollutants; C009495:titanium dioxide; D009532:Nickel; C414357:Methyl Blue; D014025:Titanium