title: Fast removal of copper ions by gum arabic modified magnetic nano-adsorbent.
abstract: A novel magnetic nano-adsorbent was developed by treating Fe(3)O(4) nanoparticles with gum arabic to remove copper ions from aqueous solutions. Gum arabic was attached to Fe(3)O(4) via the interaction between the carboxylic groups of gum arabic and the surface hydroxyl groups of Fe(3)O(4). The surface modification did not result in the phase change of Fe(3)O(4), while led to the formation of secondary particles with diameter in the range of 13-67nm and the shift of isoelectric point from 6.78 to 3.6. The amount of gum arabic in the final product was about 5.1wt%. Both the naked magnetic nanoparticles (MNP) and gum arabic modified magnetic nanoparticles (GA-MNP) could be used for the adsorption of copper ions via the complexation with the surface hydroxyl groups of Fe(3)O(4) and the complexation with the amine groups of gum arabic, respectively. The adsorption rate was so fast that the equilibrium was achieved within 2min due to the absence of internal diffusion resistance and the adsorption capacities for both MNP and GA-MNP increased with increasing the solution pH. However, the latter was significantly higher than the former. Also, both the adsorption data obeyed the Langmuir isotherm equation. The maximum adsorption capacities were 17.6 and 38.5mg/g for MNP and GA-MNP, respectively, and the Langmuir adsorption constants were 0.013 and 0.012L/mg for MNP and GA-MNP, respectively. Furthermore, both the adsorption processes were endothermic due to the dehydration of hydrated metal ions. The enthalpy changes were 11.5 and 9.1kJ/mol for MNP and GA-MNP, respectively. In addition, the copper ions could desorb from GA-MNP by using acid solution and the GA-MNP exhibited good reusability.
authors.affiliation: Department of Chemical Engineering, National Cheng Kung University, Tainan 701, Taiwan.
authors.forename: Shashwat S
authors.initials: SS
authors.lastname: Banerjee
authors.forename: Dong-Hwang
authors.initials: DH
authors.lastname: Chen
mesh_terms: D000327:Adsorption; D003300:Copper / Q000302:isolation & purification*; D004785:Environmental Pollutants / Q000302:isolation & purification*; D052918:Environmental Restoration and Remediation / Q000379:methods*; D052203:Ferrosoferric Oxide / Q000737:chemistry*; D006170:Gum Arabic / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D053758:Nanoparticles / Q000737:chemistry*; D013499:Surface Properties; D013696:Temperature
chemical_list: D004785:Environmental Pollutants; D003300:Copper; D006170:Gum Arabic; D052203:Ferrosoferric Oxide