title: Catalytic activity of silica gels bound manganese(III)-porphyrin on oxidative reaction of adrenaline.
abstract: To develop a solid catalysis on oxidative reaction of adrenaline (Ad), supports bound metal-tetrakis(4-carboxyphenyl)porphine (M-TCPP) were investigated. Silica gels bound Mn-TCPP were proved to has a superior activity in the oxidation of Ad and be able to serve as a useful oxidase model for Ad.
authors.affiliation: Department of Pharmaceutical Sciences, Graduate School of Medicine and Dentistry and Pharmaceutical Sciences, Okayama University, Tsushima-Naka, Okayama, Japan.
authors.forename: Youji
authors.initials: Y
authors.lastname: Kitamura
authors.forename: Tsutomu
authors.initials: T
authors.lastname: Takatsuki
authors.forename: Mayu
authors.initials: M
authors.lastname: Kawamoto
authors.forename: Madoka
authors.initials: M
authors.lastname: Saito
authors.forename: Akimasa
authors.initials: A
authors.lastname: Iwado
authors.forename: Ikuko
authors.initials: I
authors.lastname: Tsukamoto
authors.forename: Masaki
authors.initials: M
authors.lastname: Mifune
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Saito
mesh_terms: D002384:Catalysis; D004837:Epinephrine / Q000737:chemistry*; D006415:Hematoporphyrins / Q000737:chemistry*; D008665:Metalloporphyrins / Q000737:chemistry*; D015394:Molecular Structure; D010084:Oxidation-Reduction; D058428:Silica Gel; D012822:Silicon Dioxide / Q000737:chemistry*
chemical_list: D006415:Hematoporphyrins; D008665:Metalloporphyrins; D058428:Silica Gel; C065506:manganese (III) hematoporphyrin; D012822:Silicon Dioxide; D004837:Epinephrine