[Mechanism and impact for microwave-enhanced integrative sorption of dye to mixture of surfactant and bentonite from water].
Microwave-enhanced integrative sorption (MEIS) of dye to mixture of surfactant and bentonite was put forward. The order of factor for integrative method was obtained by the orthogonal experiment. The optimal conditions, properties, kinetics and mechanisms for microwave-enhanced integrative sorption of Neutral Red S-BR to bentonite from water were investigated. Comparative study on decolorization rates of Neutral Red S-BR by other sorption method and MEIS from water were conducted. It is concluded that the order of factor for integrative method is amount of surfactant, bentonite and microwave time. The optimal condition for MEIS is that the ratio of amount of bentonite and water is equal to 1/1 000, the concentration of cetylpyridinium chloride (CPC) is 120 mg/L (equivalent to 28% cation exchange capacity of bentonite) and microwave time is 60s. Comparative with organobentonite, the decolorization rates of Neutral Red S-BR to bentonite are greatly increased by MEIS at higher concentration of dye, amount of surfactant is greatly decreased, and the saturated sorption capacity and the reactive rate of sorption of dye to bentonite are greatly increased by microwave.
Li
Ji-Wu
JW
Department of Environmental Science, Zhejiang University, Hangzhou 310028, China.
Zhu
Li-Zhong
LZ
Cai
Wei-Jian
WJ
D000327:Adsorption; D001546:Bentonite / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry*; D008872:Microwaves; D013501:Surface-Active Agents / Q000737:chemistry; D014865:Waste Disposal, Fluid / Q000295:instrumentation / Q000379:methods*
D004396:Coloring Agents; D013501:Surface-Active Agents; D001546:Bentonite