Cross-coupling of alkyl halides with Grignard reagents using nickel and palladium complexes bearing eta(3)-allyl ligand as catalysts.
The cross-coupling of Grignard reagents with alkyl bromides and tosylates has been achieved by the use of eta(3)-allylnickel and eta(3)-allylpalladium complexes as catalysts.
Terao
Jun
J
Science and Technology Centre for Atoms, Molecules and Ions Control, Graduate School of Engineering, Osaka University, Yamadaoka 2-1, Suita, Osaka, 565-0871, Japan. terao@chem.eng.osaka-u.ac.jp.
Naitoh
Yoshitaka
Y
Kuniyasu
Hitoshi
H
Kambe
Nobuaki
N