Planar array infrared emission spectroscopy.
Planar array infrared spectroscopy (PA-IR) is shown to be a powerful new approach to infrared emission spectroscopy (IRES). A proof-of-concept study of selected polymers indicates that PA-IRES allows acquisition of emission spectra with a high signal-to-noise ratio at temperatures as low as 80 degrees C. It is shown that a time resolution below 20 ms is readily achievable for time-resolved characterization of single non-repeatable events. The possibility of recording spatially resolved emission spectra is also demonstrated, and potential applications of this novel technique are finally described.
Pellerin
Christian
C
Département de Chimie, Université de Montréal, Montréal, Québec, H3C 3J7, Canada. c.pellerin@umontreal.ca
Pelletier
Isabelle
I
Rabolt
John F
JF
Chase
D Bruce
DB
D011137:Polystyrenes / Q000737:chemistry*; D013055:Spectrophotometry, Infrared / Q000379:methods*
D011137:Polystyrenes