Twelve-connected porous metal-organic frameworks with high H(2) adsorption.
The twelve-connected metal-organic frameworks {[Ni(3)(OH)(L)(3)].n(solv)}(infinity) and {[Fe(3)(O)(L)(3)].n(solv)}(infinity) [LH(2) = pyridine-3,5-bis(phenyl-4-carboxylic acid)] have been prepared and characterised: these materials can be desolvated to form porous materials that show adsorption of H(2) up to 4.15 wt% at 77 K.
Jia
Junhua
J
School of Chemistry, University of Nottingham, University Park, Nottingham, UK.
Lin
Xiang
X
Wilson
Claire
C
Blake
Alexander J
AJ
Champness
Neil R
NR
Hubberstey
Peter
P
Walker
Gavin
G
Cussen
Edmund J
EJ
Schröder
Martin
M