title: Reductive hydrogenation of polycyclic aromatic hydrocarbons catalyzed by metalloporphyrins.
abstract: The hydrogenation of polycyclic aromatic hydrocarbons (PAHs) (naphthalene, anthracene, and phenanthrene) catalyzed by metalloporphyrins based on cobalt, nickel or iron was studied in aqueous solutions at room temperature and ambient pressure. Nickel porphyrin (P1) activated by nanosized zero-valent iron (nano-ZVI) and cobalt porphyrins (P2) and (P4) activated by titanium(III) citrate as the electron donor were demonstrated to be promising catalysts for the reductive hydrogenation of PAHs. In particular, partially saturated di-, tetra-, and octahydrogenated products were obtained for anthracene or phenanthrene using a nickel porphyrin activated by nano-ZVI, while naphthalene was transformed to tetralin. Systems containing cobalt porphyrins activated by titanium(III) citrate exhibited a high selectivity and activity toward hydrogenation of anthracene, producing 9,10-dihydroanthracene. However, no formation of hydrogenated hydrocarbons was observed from naphthalene or phenanthrene using cobalt porphyrins.
authors.affiliation: Department of Environmental Science and Energy Research, Weizmann Institute of Science, 76804 Rehovot, Israel.
authors.forename: Elza
authors.initials: E
authors.lastname: Nelkenbaum
authors.forename: Ishai
authors.initials: I
authors.lastname: Dror
authors.forename: Brian
authors.initials: B
authors.lastname: Berkowitz
mesh_terms: D000873:Anthracenes / Q000737:chemistry; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry; D006865:Hydrogenation; D007501:Iron / Q000737:chemistry; D008665:Metalloporphyrins / Q000737:chemistry*; D036103:Nanotechnology; D009281:Naphthalenes / Q000737:chemistry; D009532:Nickel / Q000737:chemistry; D010084:Oxidation-Reduction; D010616:Phenanthrenes / Q000737:chemistry; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry*
chemical_list: D000873:Anthracenes; D008665:Metalloporphyrins; D009281:Naphthalenes; D010616:Phenanthrenes; D011084:Polycyclic Aromatic Hydrocarbons; C031721:naphthalene; D003035:Cobalt; C031181:phenanthrene; D009532:Nickel; D007501:Iron; C034020:anthracene