Ni(0)-promoted hydroxycarboxylation of 1,2-dienes by reaction with CO2 and O2.
[structure: see text]. A novel method for the preparation of hydroxy carboxylic acid derivatives has been developed by O2-oxidation of pi-allylnickel intermediates generated by Ni(0)-mediated coupling of 1,2-dienes with CO2.
Aoki
Masao
M
Department of Chemistry, Tokyo Institute of Technology, O-Okayama, Tokyo, Japan.
Izumi
Sawa
S
Kaneko
Motomu
M
Ukai
Kazutoshi
K
Takaya
Jun
J
Iwasawa
Nobuharu
N