Palladium-catalyzed anti-hydrothiolation of 1-alkynylphosphines.
[structure: see text]. Treatment of 1-alkynylphosphine with thiol in the presence of a catalytic amount of palladium acetate results in regio- and stereoselective anti-hydrothiolation, yielding the corresponding (Z)-1-phosphino-2-thio-1-alkene.
Kondoh
Azusa
A
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto Daigaku Katsura, Kyoto, Japan.
Yorimitsu
Hideki
H
Oshima
Koichiro
K