Novel 3D LnIII-CuI supramolecular architecture based on 2D MOFs with (6,3) topology.
Three novel coordination polymers, [LnCu(PZDC)3].[Ln(H2O)9]0.5.[(H2O)7H+]0.5 [Ln = La (1), Eu (2), Gd (3)], were synthesized. They are the first 3d-4f heterometallic framework with supramolecular 1D channels, in which lanthanide hydrate cations and lattice water molecules are located.
Wang
Feng-Qin
FQ
Department of Chemistry, Beijing Normal University, Beijing 100875, People's Republic of China.
Zheng
Xiang-Jun
XJ
Wan
Yong-Hong
YH
Sun
Chang-Yan
CY
Wang
Zhe-Ming
ZM
Wang
Ke-Zhi
KZ
Jin
Lin-Pei
LP
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D028581:Lanthanoid Series Elements; D009942:Organometallic Compounds; D003300:Copper