A study on electron impact mass spectrometry of epoxy methylated fullerenols.
Mass spectra of the epoxy methylated[60]fullerenols were obtained by EI mass spectrometry using "desorption" or "in-beam" technique. The mass spectra have an intense molecular monocation peak M(+) and a weak dication peak M(++), revealing the stability of these products under the MS (EI) conditions. The remaining peaks correspond to the successive loss of methyl groups and oxygen atoms for which the pure fullerene represents a more stable product. The distinction between the multiply charged fullerene C(60)(z+) and their fragments with equal m/z was also studied.
Al-Matar
Hamad M
HM
Chemistry Department, Faculty of Science, Kuwait University, Safat, Kuwait. almatar@kuc01.kuniv.edu.kw
Badawy
Sayed M
SM
D004583:Electrons; D004852:Epoxy Compounds / Q000737:chemistry*; D037741:Fullerenes / Q000737:chemistry*; D013058:Mass Spectrometry; D008745:Methylation
D004852:Epoxy Compounds; D037741:Fullerenes; C108127:fullerenol