Regio- and stereoselective copper-catalyzed carbozincation reactions of alkynyl sulfoximines and sulfones.
[structure: see text]. Stereochemically pure polysubstituted vinyl sulfoximines and sulfones are easily prepared by a copper-catalyzed syn carbozincation reaction of the corresponding alkynyl derivatives.
Sklute
Genia
G
The Mallat Family Laboratory of Organic Chemistry, Schulich Faculty of Chemistry and The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Haifa, Israel.
Bolm
Carsten
C
Marek
Ilan
I