Di-pyrrolyl-pyrazoles: anion receptors in protonated form and efficient building blocks for organized structures.
Synthesis of di-pyrrolyl-substituted pyrazoles (dpp) and anion binding studies in protonated form are reported. Dpp show [2 + 2] binding of trifluoroacetate in the solid state to afford nanometer- and micrometer-scale architectures.
Maeda
Hiromitsu
H
Department of Bioscience and Biotechnology, Faculty of Science and Engineering, Ritsumeikan University, Kusatsu 525-8577, Japan. maedahir@se.ritsumei.ac.jp
Ito
Yoshihiro
Y
Kusunose
Yukio
Y
Nakanishi
Takashi
T
D000838:Anions / Q000737:chemistry; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008855:Microscopy, Electron, Scanning; D008958:Models, Molecular; D011522:Protons; D011720:Pyrazoles / Q000138:chemical synthesis* / Q000737:chemistry; D011758:Pyrroles / Q000138:chemical synthesis* / Q000737:chemistry; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet
D000838:Anions; D011522:Protons; D011720:Pyrazoles; D011758:Pyrroles