title: Crossed beam studies of radical-radical reactions: O(3P) + C3H5 (allyl).
abstract: The dynamics of the radical-radical reaction O((3)P) + C(3)H(5) has been investigated by means of the crossed molecular beam technique with mass spectrometric detection at a collision energy of 73.0 kJ mol(-1); the reaction mechanism of the H-displacement channel has been elucidated, while experimental evidence of the occurrence of one or more C-C bond-breaking channels at this collision energy has been obtained.
authors.affiliation: Dipartimento di Chimica, Università di Perugia, Perugia, Italy.
authors.forename: F
authors.initials: F
authors.lastname: Leonori
authors.forename: N
authors.initials: N
authors.lastname: Balucani
authors.forename: G
authors.initials: G
authors.lastname: Capozza
authors.forename: E
authors.initials: E
authors.lastname: Segoloni
authors.forename: D
authors.initials: D
authors.lastname: Stranges
authors.forename: P
authors.initials: P
authors.lastname: Casavecchia
mesh_terms: D003198:Computer Simulation; D005609:Free Radicals / Q000737:chemistry*; D005990:Glycerol / Q000031:analogs & derivatives*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008956:Models, Chemical; D008958:Models, Molecular; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*
chemical_list: D005609:Free Radicals; D005990:Glycerol; D010100:Oxygen