Easily recyclable chiral polymeric Mn(III) salen complexes for oxidative kinetic resolution of racemic secondary alcohols.
Chiral polymeric Mn(III) salen complexes were used efficiently for oxidative kinetic resolution of racemic secondary alcohols at room temperature. High chiral purity (ee; >99%) was achieved for the oxidative kinetic resolution of racemic secondary alcohols with 0.6 mol % catalyst loading in 60 min. The catalyst was easily recycled for five successive catalytic experiments.
Kureshy
Rukhsana I
RI
Silicates and Catalysis Discipline, Central Salt and Marine Chemicals Research Institute, Bhavnagar 364 002, Gujarat, India. rukhsana93@yahoo.co.in
Ahmad
Irshad
I
Pathak
Kavita
K
Khan
Noor-Ul H
NU
Abdi
Sayed H R
SH
Prathap
Jaya K
JK
Jasra
Raksh V
RV