title: Self-assembly of a high-nuclearity chloride-centered copper(II) cluster. Structure and magnetic properties of [Au(PPh3)2][trans-Cu6(micro-OH)6[micro-(3,5-CF3)2pz]6Cl].
abstract: A chloride-centered hexanuclear copper(II) pyrazolate [Au(PPh3)2][trans-Cu6(micro-OH)6[micro-(3,5-CF3)2pz]6Cl] is isolated from the reaction of the trinuclear copper(I) pyrazolate [Cu3[micro-(CF3)2pz]3] with PPh3AuCl and Ph3P in moist air. The six copper atoms are bridged by pyrazolate and hydroxyl ligands, above and below the copper plane. The chloride anion exists at the center of the planar cavity formed by the copper atoms with Cu-Cl distances of 3.02-3.13 A. The magnetic susceptibility measurements show a strong antiferromagnetic coupling between the copper centers with an estimated exchange constant of J approximately 650 cm-1.
authors.affiliation: Laboratory for Molecular Structure and Bonding, Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, USA.
authors.forename: Ahmed A
authors.initials: AA
authors.lastname: Mohamed
authors.forename: Alfredo
authors.initials: A
authors.lastname: Burini
authors.forename: Rossana
authors.initials: R
authors.lastname: Galassi
authors.forename: Daniele
authors.initials: D
authors.lastname: Paglialunga
authors.forename: José-Ramón
authors.initials: JR
authors.lastname: Galan-Mascarós
authors.forename: Kim R
authors.initials: KR
authors.lastname: Dunbar
authors.forename: John P
authors.initials: JP
authors.lastname: Fackler
mesh_terms: D002712:Chlorides / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013696:Temperature
chemical_list: D002712:Chlorides; D009942:Organometallic Compounds; C519831:bis(triphenylphosphine)gold(0) chlorohexakis(mu-hydroxo)hexakis(3,5-bis(trifluoromethyl)pyrazolate)hexacopper(II); D003300:Copper