Aquabis(3-methoxy-2-pyridonato)(2,2':6',2''-terpyridine)ruthenium(II)-acetonitrile-water (1/1/1).
The title compound, [Ru(C(6)H(6)NO(2))(2)(C(15)H(11)N(3))(H(2)O)] x CH(3)CNx H(2)O, is a transfer hydrogenation catalyst supported by nitrogen-donor ligands. This octahedral Ru(II) complex features rare monodentate coordination of 3-methoxy-2-pyridonate ligands and interligand S(6)S(6) hydrogen bonding. Comparison of the title complex with a structural analog with unsubstituted 2-pyridonate ligands reveals subtle differences in the orientation of the ligand planes.
Kelson
Eric P
EP
Department of Chemistry and Biochemistry, California State University Northridge, 18111 Nordhoff Street, Northridge, CA 91330-8262, USA. eric.kelson@csun.edu
Dean
Norman S
NS
Algarín
Edgar
E
D002384:Catalysis; D003460:Crystallization; D018360:Crystallography, X-Ray; D006865:Hydrogenation; D008024:Ligands; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D017975:Ruthenium Compounds / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D011725:Pyridines; D017975:Ruthenium Compounds; C519324:aquabis(3-methoxy-2-pyridonato)(2,2':6',2''-terpyridine)ruthenium(II)-acetonitrile