Self-assembly of a high-nuclearity chloride-centered copper(II) cluster. Structure and magnetic properties of [Au(PPh3)2][trans-Cu6(micro-OH)6[micro-(3,5-CF3)2pz]6Cl].
A chloride-centered hexanuclear copper(II) pyrazolate [Au(PPh3)2][trans-Cu6(micro-OH)6[micro-(3,5-CF3)2pz]6Cl] is isolated from the reaction of the trinuclear copper(I) pyrazolate [Cu3[micro-(CF3)2pz]3] with PPh3AuCl and Ph3P in moist air. The six copper atoms are bridged by pyrazolate and hydroxyl ligands, above and below the copper plane. The chloride anion exists at the center of the planar cavity formed by the copper atoms with Cu-Cl distances of 3.02-3.13 A. The magnetic susceptibility measurements show a strong antiferromagnetic coupling between the copper centers with an estimated exchange constant of J approximately 650 cm-1.
Mohamed
Ahmed A
AA
Laboratory for Molecular Structure and Bonding, Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, USA.
Burini
Alfredo
A
Galassi
Rossana
R
Paglialunga
Daniele
D
Galan-Mascarós
José-Ramón
JR
Dunbar
Kim R
KR
Fackler
John P
JP
D002712:Chlorides / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013696:Temperature
D002712:Chlorides; D009942:Organometallic Compounds; C519831:bis(triphenylphosphine)gold(0) chlorohexakis(mu-hydroxo)hexakis(3,5-bis(trifluoromethyl)pyrazolate)hexacopper(II); D003300:Copper