Infrared-emitting colloidal nanocrystals: synthesis, assembly, spectroscopy, and applications.
Semiconductor nanocrystals produced by means of colloidal chemistry in a solvent medium are an attractive class of nanometer-sized building blocks from which to create complex materials with unique properties for a variety of applications. Their optical and electronic properties can be tailored easily, both by their chemical composition and particle size. While colloidal nanocrystals emitting in the infrared region have seen a burst of attention during the last decade there is clearly a paucity of review articles covering their synthesis, assembly, spectroscopic characterization, and applications. This Review comprehensively addresses these topics for II-VI, III-V, and IV-VI nanocrystals, examples being HgTe and Cd(x)Hg(1-) (x)Te, InP and InAs, and PbS, PbSe, and PbTe, respectively. Among the applications discussed here are optical amplifier media for telecommunications systems, electroluminescence devices, and noninvasive optical imaging in biology.
Rogach
Andrey L
AL
Photonics and Optoelectronics Group, Physics Department and Centre for NanoScience (CeNS), Ludwig-Maximilians-Universität München, Munich, Germany. andrey.rogach@physik.uni-muenchen.de
Eychmüller
Alexander
A
Hickey
Stephen G
SG
Kershaw
Stephen V
SV
D003102:Colloids / Q000737:chemistry*; D004553:Electric Conductivity; D004563:Electrochemistry / Q000379:methods; D007259:Infrared Rays; D053768:Metal Nanoparticles; D018625:Microscopy, Atomic Force; D046529:Microscopy, Electron, Transmission; D053758:Nanoparticles / Q000737:chemistry*; D036103:Nanotechnology / Q000379:methods; D011108:Polymers; D012666:Semiconductors; D012680:Sensitivity and Specificity; D012997:Solvents; D013055:Spectrophotometry, Infrared / Q000379:methods; D014961:X-Ray Diffraction
D003102:Colloids; D011108:Polymers; D012997:Solvents