title: Palladium-catalyzed anti-hydrothiolation of 1-alkynylphosphines.
abstract: [structure: see text]. Treatment of 1-alkynylphosphine with thiol in the presence of a catalytic amount of palladium acetate results in regio- and stereoselective anti-hydrothiolation, yielding the corresponding (Z)-1-phosphino-2-thio-1-alkene.
authors.affiliation: Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto Daigaku Katsura, Kyoto, Japan.
authors.forename: Azusa
authors.initials: A
authors.lastname: Kondoh
authors.forename: Hideki
authors.initials: H
authors.lastname: Yorimitsu
authors.forename: Koichiro
authors.initials: K
authors.lastname: Oshima