A pillared layer MOF with anion-tunable magnetic properties and photochemical [2 + 2] cycloaddition.
A magnetic MOF with two distinct functions was prepared and characterized: [2 + 2] photodimerization and anti-ferro-magnetism with a well-pronounced anion-tunable spin-flop transition below 2.5 K were both observed.
Wang
Xin-Yi
XY
Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China.
Wang
Zhe-Ming
ZM
Gao
Song
S