Crossed beam studies of radical-radical reactions: O(3P) + C3H5 (allyl).
The dynamics of the radical-radical reaction O((3)P) + C(3)H(5) has been investigated by means of the crossed molecular beam technique with mass spectrometric detection at a collision energy of 73.0 kJ mol(-1); the reaction mechanism of the H-displacement channel has been elucidated, while experimental evidence of the occurrence of one or more C-C bond-breaking channels at this collision energy has been obtained.
Leonori
F
F
Dipartimento di Chimica, Università di Perugia, Perugia, Italy.
Balucani
N
N
Capozza
G
G
Segoloni
E
E
Stranges
D
D
Casavecchia
P
P
D003198:Computer Simulation; D005609:Free Radicals / Q000737:chemistry*; D005990:Glycerol / Q000031:analogs & derivatives*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D008956:Models, Chemical; D008958:Models, Molecular; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*
D005609:Free Radicals; D005990:Glycerol; D010100:Oxygen