title: 57Fe Mössbauer spectroscopy predicts superstructure for K0.08[Cu(II)(N,N'app)Cl]2[Fe(III)(CN)6].0.92H3O.3H2O.
abstract: The compound [Cu(N,N'app)Cl](2)[Fe(CN)(6)].xH(2)O, with N,N'app being bis(N,N'-3-aminopropylpiperazine), was prepared and its structure determined by single crystal X-ray analysis, confirming a ratio of two copper complexes to one iron complex; (57)Fe Mössbauer spectra showed three quadrupole doublets typical of iron(iii) low spin species which call for the presence of a superstructure.
authors: University of Houston, Chemistry Department, Houston, TX 77204-5003, USA.
authors: Uday
authors: U
authors: Mukhopadhyay
authors: C Matthias
authors: CM
authors: Grunert
authors: Joachim
authors: J
authors: Kusz
authors: Sergey
authors: S
authors: Reiman
authors: P
authors: P
authors: Gütlich
authors: Ivan
authors: I
authors: Bernal