title: Structural phase contrast in polycrystalline organic semiconductor films observed by broadband near-field optical spectroscopy.
abstract: We demonstrate a novel near-field absorption spectrometer with 100 nm spatial resolution based on an ultrabroadband Ti:sapphire oscillator coupled to an aperture NSOM, enabling the measurement of nanoscale absorption spectra. The instrument is particularly suited for structural phase-selective imaging of organic materials at the nanoscale. We demonstrate that variations in the local absorption spectrum allow us to distinguish between the crystalline and the amorphous phases in polycrystalline phtalocyanine films, thus providing previously unavailable information on their mesoscopic texture.
authors: Max-Born-Institut für Nichtlineare Optik und Kurzzeitspektroskopie, 12489 Berlin, Germany.
authors: Robert
authors: R
authors: Pomraenke
authors: Claus
authors: C
authors: Ropers
authors: Julien
authors: J
authors: Renard
authors: Christoph
authors: C
authors: Lienau
authors: Larry
authors: L
authors: Lüer
authors: Dario
authors: D
authors: Polli
authors: Giulio
authors: G
authors: Cerullo
mesh_terms: D003460:Crystallization / Q000379:methods*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008567:Membranes, Artificial; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D009930:Organic Chemicals / Q000737:chemistry*; D010316:Particle Size; D012031:Refractometry / Q000379:methods*; D012666:Semiconductors; D013057:Spectrum Analysis / Q000379:methods*; D013499:Surface Properties
chemical_list: D046911:Macromolecular Substances; D008567:Membranes, Artificial; D009930:Organic Chemicals