Dissymmetry effects on the laser spectroscopy of supersonically expanded rare gas/chiral arene heteroclusters.
The R2PI-TOF spectra of supersonically expanded rare gas/chiral arene heteroclusters have been rationalized in terms of the distortion of the pi-electron density reflecting the different dipole and quadrupole momenta induced in the rare gas atoms by interaction with the opposite pi-faces of the chiral arene itself.
Filippi
Antonello
A
Dipartimento di Studi di Chimica e Tecnologia delle Sostanze Biologicamente Attive, Università "La Sapienza", Roma, 00185, Italy.
Giardini
Anna
A
Marcantoni
Enrico
E
Paladini
Alessandra
A
Piccirillo
Susanna
S
Renzi
Gabriele
G
Rondino
Flaminia
F
Roselli
Graziella
G
Satta
Mauro
M
Speranza
Maurizio
M
D001555:Benzene Derivatives / Q000737:chemistry*; D004583:Electrons; D007834:Lasers; D013058:Mass Spectrometry / Q000295:instrumentation / Q000379:methods*; D008956:Models, Chemical; D005741:Noble Gases / Q000737:chemistry*; D013057:Spectrum Analysis / Q000295:instrumentation / Q000379:methods*; D013237:Stereoisomerism
D001555:Benzene Derivatives; D005741:Noble Gases