Design and interfacial assembly of a new series of gemini amphiphiles with hydrophilic poly(ethyleneamine) spacers.
A new series of gemini amphiphiles containing two Schiff base moieties linked by the poly(ethyleneamine) with different lengths were designed, and their interfacial assemblies were investigated. Condensed monolayers were obtained on nearly neutral subphase where the hydrophilic spacers were found to immerse into the subphase. On strong alkaline and acidic subphase, the headgroup and the spacer of the gemini amphiphiles underwent dissociation and protonation, respectively, resulting in the enlargement of the molecular areas. Flat and uniform domains were obtained for the monolayers from nearly neutral subphase; flower-like or dendritic domains were observed for the films transferred from strong acidic subphase. On the other hand, when an anionic tetrakis(4-sulfonatonphenyl)porphine (TPPS) was added into an acidic subphase, an in situ complex formation between the gemini amphiphiles and TPPS occurred. The complex monolayers were transferred onto solid substrate and TPPS existed predominantly as J-aggregate in the complex films. Due to the multisited positive charges in the spacer on acidic subphase, the complex films of gemini amphiphiles with TPPS appeared as short fiber or nanorod structures and formed two-dimensional (2D) conglomerate chiral domains.
Jiao
Tifeng
T
Beijing National Laboratory for Molecular Science, CAS Key Laboratory of Colloid and Interface Science, Institute of Chemistry, CAS, Beijing 100080, People's Republic of China.
Zhang
Guocheng
G
Liu
Minghua
M