A NADPH substitute for selective photo-initiation of reductive bioprocesses via two-photon induced electron transfer.
A NADPH substitute where the nicotinamide moiety is replaced by a chromophoric unit having much larger two-photon absorption cross-section and able to transfer electrons to flavins only upon excitation is described as an effective two-photon nanotrigger for selective photo-activation of electron transfer in bioreductive processes.
Robin
Anne-Claire
AC
Synthèse et Electrosynthèse Organiques (CNRS, UMR 6510), Université de Rennes 1, Campus Scientifique de Beaulieu, Bât. 10A, F-35042, Rennes Cedex, France.
Gmouh
Said
S
Mongin
Olivier
O
Jouikov
Viatcheslav
V
Werts
Martinus H V
MH
Gautier
Clément
C
Slama-Schwok
Anny
A
Blanchard-Desce
Mireille
M
D004583:Electrons; D015394:Molecular Structure; D009249:NADP / Q000737:chemistry*; D010084:Oxidation-Reduction; D010777:Photochemistry; D017785:Photons
D009249:NADP