Study on synthesis and electrochemical properties of a novel ferrocene-based compound and its application in anion recognition.
The novel ferrocene-based compound 2-Fc is synthesized through the reaction of ferrocene carbonate acid and epoxy rosin E-51, and characterized by 1H NMR. The CV behaviors of 2-Fc in different organic solvents are recorded, and the major influential factors, namely, potential scan rate, concentration of electrolyte, and concentration of 2-Fc, and the mechanism of the electrode process are investigated. The CV behaviors of 2-Fc film on electrode in LiClO4 aqueous and organic solutions and the application of 2-Fc in H2PO4- recognition are also studied.
Tan
Qiaohua
Q
State Key Laboratory of Polymer Reaction Engineering, College of Materials Science and Chemical Engineering, Zhejiang University, Hangzhou, China.
Wang
Li
L
Yu
Haojie
H
Deng
Libo
L
D000838:Anions / Q000737:chemistry; D004563:Electrochemistry; D004566:Electrodes; D005296:Ferrous Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D000075163:Metallocenes; D015394:Molecular Structure; D012680:Sensitivity and Specificity; D012996:Solutions / Q000737:chemistry; D014867:Water / Q000737:chemistry
D000838:Anions; D005296:Ferrous Compounds; D000075163:Metallocenes; D012996:Solutions; D014867:Water; C004998:ferrocene