Supported ionic liquid phase catalysis with supercritical flow.
Rapid hydroformylation of 1-octene (rates up to 800 h(-1)) with the catalyst remaining stable for at least 40 h and with very low rhodium leaching levels (0.5 ppm) is demonstrated when using a system involving flowing the substrate, reacting gases and products dissolved in supercritical CO(2) (scCO(2)) over a fixed bed supported ionic liquid phase catalyst.
Hintermair
Ulrich
U
EaStCHEM, School of Chemistry, University of St. Andrews, St. Andrews, Fife, Scotland, UK.
Zhao
Guoying
G
Santini
Catherine C
CC
Muldoon
Mark J
MJ
Cole-Hamilton
David J
DJ