N,N'-dimethylformamide-derived products from catalytic oxidation of 3-hydroxyflavone.
The biomimetic conversion of 3-hydroxyflavone in the presence of a copper(II) catalyst, dioxygen, and N,N'-dimethylformamide to oxidation products as well as two previously unreported solvent-derived products is seen. The two solvent-derived products were characterized, and their crystal structures were determined.
Malkhasian
Aramice Y S
AY
Department of Chemistry, Oakland University, Rochester, Michigan 48309-4477, USA.
Finch
Maila E
ME
Nikolovski
Borislava
B
Menon
Adarsh
A
Kucera
Benjamin E
BE
Chavez
Ferman A
FA
D002384:Catalysis; D003300:Copper / Q000737:chemistry; D018360:Crystallography, X-Ray; D004126:Dimethylformamide / Q000737:chemistry*; D005419:Flavonoids / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry; D013237:Stereoisomerism
D005419:Flavonoids; D008024:Ligands; D003300:Copper; D004126:Dimethylformamide; D010100:Oxygen; C041477:3-hydroxyflavone