title: An anthracene-appended beta-cyclodextrin-based dyad: study of self-assembly and photoinduced electron-transfer processes.
abstract: The self-assembly of a beta-cyclodextrin (beta-CD)-based supramolecular dyad is reported, in which the donor anthracene moiety is covalently linked to the smaller rim of the beta-CD and the acceptor pyromellitic diimide (PMDI) is encapsulated within the beta-CD cavity. Encapsulation of the PMDI into the beta-CD cavity was studied by a variety of techniques, which suggested that PMDI is encapsulated so as to position the aromatic part at the centre of the cavity with the 2-propyl end at the narrower rim among the overhanging primary OH groups and the N-ethylpyridinium end situated at the wider rim exposed to water. Photoinduced electron transfer (PET) in the system was studied by fluorescence quenching and laser flash photolysis techniques. At [PMDI]<10(-4) M, the equilibrium is in favour of the free molecules, and under these conditions fluorescence quenching is negligible and diffusion-mediated electron transfer involving the triplet excited state of anthracene predominates. At higher concentrations of PMDI, the equilibrium is largely in favour of the supramolecular dyad and intra-ensemble PET processes predominate. The experimentally determined electron-transfer rate constant agrees very well with that calculated by using the Marcus equation. It was observed that a fraction of the ion pairs survived for more than 200 micros.
authors: Photosciences and Photonics Section, Chemical Sciences and Technology Division, Regional Research Laboratory (CSIR), Trivandrum 695019, India.
authors: Bijitha
authors: B
authors: Balan
authors: Karical R
authors: KR
authors: Gopidas