Homoleptic 12-coordinate lanthanoids with eta(2)-nitroso ligands.
The complexes [Et(4)N](3)[Ln(eta(2)-dcnm)(6)] (Ln = La, Ce, Nd, Gd, dcnm = dicyanonitrosomethanide) have discrete N, O 12-coordination owing to symmetrical chelation of the nitroso donor groups.
Chesman
Anthony S R
AS
School of Chemistry, Monash University, Clayton, VIC 3800, Australia.
Turner
David R
DR
Izgorodina
Ekaterina I
EI
Batten
Stuart R
SR
Deacon
Glen B
GB