Enantioselective palladium-catalysed conjugate addition of arylsiloxanes.
The complex formed from Pd(CH(3)CN)(4)(BF(4))(2) and (R,R)-MeDUPHOS is a highly enantioselective catalyst for the asymmetric conjugate addition of aryltriethylsiloxanes to a variety of unsaturated ketones, lactones and lactams.
Gini
Francesca
F
Stratingh Institute, University of Groningen, Nijenborgh 4, 9747 AG, Groningen, The Netherlands.
Hessen
Bart
B
Feringa
Ben L
BL
Minnaard
Adriaan J
AJ