K2[Ga(B5O10)].4H2O: the first chiral zeolite-like galloborate with large odd 11-ring channels.
The first chiral zeolite-like galloborate, K2[Ga(B5O10)].4H2O, has been synthesized by a mild solvothermal method and characterized by Fourier transform IR, energy-dispersive spectroscopy, thermogravimetric/differential thermal analysis, and single-crystal X-ray diffraction. This compound crystallizes in the orthorhombic system with space group C2221. The structure possesses a 3D open framework constructed by B5O10 clusters and GaO4 units and contains large odd 11-ring channels.
Liu
Zhi-Hong
ZH
School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an 710062, People's Republic of China. liuzh@ snnu.edu.cn
Yang
Ping
P
Li
Ping
P
D001881:Borates / Q000138:chemical synthesis / Q000737:chemistry*; D001896:Boron Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005682:Gadolinium / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D011188:Potassium / Q000737:chemistry*
D001881:Borates; D001896:Boron Compounds; C519937:K2(Ga(B5O10)); D005682:Gadolinium; D011188:Potassium