Linkage isomerism in a face-centered cubic Cu6Cr8(CN)24 cluster with an S=15 ground state.
Access to the new complex [TpCr(CN)3]- enables isolation of two metastable linkage isomers of a face-centered cubic cluster, [Tp8(H2O)6Cu6Cr8(CN)24]4+, both exhibiting an S=15 ground state.
Harris
T David
TD
Department of Chemistry, University of California, Berkeley, California 94720-1460, USA.
Long
Jeffrey R
JR