Cyanation: providing a three-in-one advantage for the design of n-type organic field-effect transistors.
The theoretical work presented here demonstrates that, when substitution takes place at appropriate positions, cyanation could be a useful tool for reducing the internal reorganization energy of molecules. A molecular-orbital-based explanation is given for this fundamentally important phenomenon. Some of the cyanated pentacene derivatives (nCN-PENT-n) not only have internal reorganization energies for electron transfer (lambda(-)) smaller than that of pentacene, but the lambda(-) values are even of the same magnitude as the internal reorganization energy for hole transfer (lambda(+)) of pentacene, a small value that few organic compounds have surpassed. In addition, cyanation raises the electron affinity of the parent compound and may afford good electronic couplings between neighboring molecules, because of its ability in promoting pi-stacking. For the design of high performance n-Type Organic field-effect transistors, high electron affinities, large intermolecular electronic couplings, and small reorganization energies are necessary. Cyanation may help in all three aspects. Two cyanated trialkylsilylethynyl pentacene derivatives with known pi-stacking structures are predicted to provide reasonably small internal reorganization energies, large electronic couplings, and high electron affinities. They have the potential to outperform N-fluoroalkylated dicyanoperylene-3,4:9,10-bis(dicarboximides) (PDI-FCN(2)) in terms of electron mobility.
Kuo
Ming-Yu
MY
Institute of Chemistry, Academia Sinica, Taipei, 11529, Taiwan.
Chen
Hsing-Yin
HY
Chao
Ito
I
D003485:Cyanates / Q000737:chemistry*; D008956:Models, Chemical; D011084:Polycyclic Aromatic Hydrocarbons / Q000737:chemistry*; D012666:Semiconductors; D014173:Transistors, Electronic
D003485:Cyanates; D011084:Polycyclic Aromatic Hydrocarbons