A Duffing oscillator algorithm to detect the weak chromatographic signal.
Based on the Duffing equation, a Duffing oscillator algorithm (DOA) to improve the signal-to-noise ratio (SNR) was presented. By simulated and experimental data sets, it was proven that the signal-to-noise ratio (SNR) of the weak signal could be greatly enhanced by this method. Using signal enhancement by DOA, this method extends the SNR of low concentrations of methylbenzene from 2.662 to 29.90 and the method can be used for quantitative analysis of methylbenzene, which are lower than detection limit of an analytical system. The Duffing oscillator algorithm (DOA) might be a promising tool to extend instrumental linear range and to improve the accuracy of trace analysis. The research enlarged the application scope of Duffing equation to chromatographic signal processing.
Zhang
Wei
W
Center for Instrumental Analysis of China Pharmaceutical University, Nanjing 210009, China.
Xiang
Bing-Ren
BR
D000465:Algorithms; D016477:Artifacts; D001555:Benzene Derivatives / Q000737:chemistry; D002845:Chromatography / Q000379:methods*; D002851:Chromatography, High Pressure Liquid; D005583:Fourier Analysis; D007091:Image Processing, Computer-Assisted; D009991:Oscillometry; D015203:Reproducibility of Results; D012815:Signal Processing, Computer-Assisted; D012984:Software; D013269:Stochastic Processes; D014466:Ultraviolet Rays
D001555:Benzene Derivatives