title: Electrodeposition of Al in 1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide and 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)amide ionic liquids: in situ STM and EQCM studies.
abstract: In the present paper, the electrodeposition of Al on flame-annealed Au(111) and polycrystalline Au substrates in two air- and water-stable ionic liquids namely, 1-butyl-1-methyl-pyrrolidinium bis(trifluoromethylsulfonyl)amide, [Py(1,4)]Tf(2)N, and 1-ethyl-3-methyl-imidazolium bis(trifluoromethylsulfonyl)amide, [EMIm]Tf(2)N, has been investigated by in situ scanning tunneling microscopy (STM), electrochemical quartz crystal microbalance (EQCM), and cyclic voltammetry. The cyclic voltammogram of aluminum deposition and stripping on Au(111) in the upper phase of the biphasic mixture of AlCl(3)/[EMIm]Tf(2)N at room temperature (25 degrees C) shows that the electrodeposition process is completely reversible as also evidenced by in situ STM and EQCM studies. Additionally, a cathodic peak at an electrode potential of about 0.55 V vs Al/Al(III) is correlated to the aluminum UPD process that was evidenced by in situ STM. A surface alloying of Al with Au at the early stage of deposition occurs. It has been found that the Au(111) surface is subject to a restructuring/reconstruction in the upper phase of the biphasic mixture of AlCl(3)/[Py(1,4)]Tf(2)N at room temperature (25 degrees C) and that the deposition is not fully reversible. Furthermore, the underpotential deposition of Al in [Py(1,4)]Tf(2)N is not as clear as in [EMIm]Tf(2)N. The frequency shift in the EQCM experiments in [Py(1,4)]Tf(2)N shows a surprising result as an increase in frequency and a decrease in damping with bulk aluminum deposition at potentials more negative than -1.8 V was observed at room temperature. However, at 100 degrees C there is a frequency decrease with ongoing Al deposition. At -2.0 V vs Al/Al(III), a bulk aluminum deposition sets in.
authors: Clausthal University of Technology, Robert-Koch-Strasse 42, 38678 Clausthal-Zellerfeld, Germany.
authors: E M
authors: EM
authors: Moustafa
authors: S Zein
authors: SZ
authors: El Abedin
authors: A
authors: A
authors: Shkurankov
authors: E
authors: E
authors: Zschippang
authors: A Y
authors: AY
authors: Saad
authors: A
authors: A
authors: Bund
authors: F
authors: F
authors: Endres
mesh_terms: D000388:Air; D000535:Aluminum / Q000737:chemistry*; D004563:Electrochemistry; D004566:Electrodes; D006046:Gold / Q000737:chemistry; D007093:Imidazoles / Q000737:chemistry*; D007094:Imides / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D016252:Microscopy, Scanning Tunneling / Q000379:methods*; D011758:Pyrroles / Q000737:chemistry*; D011759:Pyrrolidines; D011791:Quartz; D012680:Sensitivity and Specificity; D014867:Water / Q000737:chemistry
chemical_list: C521242:1-butyl-1-methylpyrrolidinium bis(trifluoromethylsulfonyl)amide; C506652:1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide; D007093:Imidazoles; D007094:Imides; D052578:Ionic Liquids; D011758:Pyrroles; D011759:Pyrrolidines; D014867:Water; D011791:Quartz; D006046:Gold; D000535:Aluminum