title: 1,2-sulfanyl group migration as a driving force: new approach to pyrroles by reaction of allenic aldehydes with amines.
abstract: [reaction: see text] Acid-promoted reaction of sulfanyl group substituted allenic aldehyde with amine affords pyrrole derivatives in high yields. The neighboring group participation of the sulfanyl group is the driving force in this transformation.
authors: Beijing National Laboratory of Molecular Sciences (BNLMS), Green Chemistry Center (GCC) and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
authors: Lingling
authors: L
authors: Peng
authors: Xiu
authors: X
authors: Zhang
authors: Jie
authors: J
authors: Ma
authors: Zhenzhen
authors: Z
authors: Zhong
authors: Jianbo
authors: J
authors: Wang
mesh_terms: D000447:Aldehydes / Q000737:chemistry*; D000466:Alkadienes / Q000737:chemistry*; D000588:Amines / Q000737:chemistry*; D000814:Aniline Compounds / Q000737:chemistry; D002384:Catalysis; D015394:Molecular Structure; D011758:Pyrroles / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry*
chemical_list: D000447:Aldehydes; D000466:Alkadienes; D000588:Amines; D000814:Aniline Compounds; D011758:Pyrroles; C025947:propadiene; D013455:Sulfur; C023650:aniline