title: Competition between phenanthrene, chrysene, and 2,5-dichlorobiphenyl for high-energy adsorption sites in a sediment.
abstract: We determined the maximum amounts of added phenanthrene, chrysene, and 2,5-dichlorobiphenyl sorbed onto high-energy adsorption sites in a sediment on bi-solute experiments. The bi-solute pairs were phenanthrene/chrysene and phenanthrene/2,5-dichlorobiphenyl. On the bi-solute sorption experiments, one solute was introduced and equilibrated with sediment prior to addition of the second solute. The values for the maximum amounts adsorbed onto high-energy sites revealed that, after equilibration of the first solute, still some high-energy sites could be occupied by the second solute. Phenanthrene, chrysene, and 2,5-dichlorobiphenyl seem to share about 30% of the accessible high-energy adsorption sites in the sediment employed.
authors.affiliation: Institute for Inland Water Management and Wastewater Treatment (RIZA), P.O. Box 17, 8200 AA Lelystad, The Netherlands.
authors.forename: Simone
authors.initials: S
authors.lastname: Morelis
authors.forename: Henny
authors.initials: H
authors.lastname: van den Heuvel
authors.forename: Paul C M
authors.initials: PC
authors.lastname: van Noort
mesh_terms: D000327:Adsorption; D002911:Chrysenes / Q000737:chemistry*; D005618:Fresh Water; D019015:Geologic Sediments; D010616:Phenanthrenes / Q000737:chemistry*; D011078:Polychlorinated Biphenyls / Q000737:chemistry*; D014874:Water Pollutants, Chemical
chemical_list: D002911:Chrysenes; D010616:Phenanthrenes; D014874:Water Pollutants, Chemical; C031180:chrysene; C029905:2,5-dichlorobiphenyl; C031181:phenanthrene; D011078:Polychlorinated Biphenyls