title: Overlapping resonances in the control of intramolecular vibrational redistribution.
abstract: Coherent control of bound state processes via the interfering overlapping resonance scenario [Christopher et al., J. Chem. Phys. 123, 064313 (2006)] is developed to control intramolecular vibrational redistribution (IVR). The approach is applied to the flow of population between bonds in a model of chaotic OCS vibrational dynamics, showing the ability to significantly alter the extent and rate of IVR by varying quantum interference contributions.
authors.affiliation: Chemical Physics Theory Group, Department of Chemistry, University of Toronto, Toronto M5S 3H6, Canada.
authors.forename: D
authors.initials: D
authors.lastname: Gerbasi
authors.forename: A S
authors.initials: AS
authors.lastname: Sanz
authors.forename: P S
authors.initials: PS
authors.lastname: Christopher
authors.forename: M
authors.initials: M
authors.lastname: Shapiro
authors.forename: P
authors.initials: P
authors.lastname: Brumer