A new anode for solid oxide fuel cells with enhanced OCV under methane operation.
A new SOFC anode material based upon oxygen excess perovskite related phases has been synthesised. The material shows better electrochemical performance than other alternative new anodes and comparable performance to the state-of-art of the electrodes, Ni-YSZ cermets, under pure hydrogen. Furthermore, this material shows an enhanced performance under methane operation with high open circuit voltages, i.e. 1.2-1.4 V at 950 degrees C, without using steam excess. The effect of the anode configuration was tested in one and four layer configurations. The optimised electrode polarisation resistances were just 0.12 ohm cm(2) and 0.36 ohm cm(2), at 950 degrees C, in humidified H(2) and humidified CH(4), respectively. Power densities of 0.5 W cm(-2) and 0.35 W cm(-2) were obtained in the same conditions. A very low anodic overpotential of 100 mV at 1 A cm(-2) was obtained under humidified H(2) at 950 degrees C. Samples were tested for two days in reducing and oxidising conditions, alternating heating and cooling processes from 850 degrees C to 950 degrees C, showing stable electrode performance and open circuit voltages. The results show that the substituted strontium titanates are very promising anode materials for SOFC.
Ruiz-Morales
Juan C
JC
School of Chemistry, University of St Andrews, St Andrews, Fife, UK KY16 9ST.
Canales-Vázquez
Jesús
J
Savaniu
Cristian
C
Marrero-López
David
D
Núñez
Pedro
P
Zhou
Wuzong
W
Irvine
John T S
JT
D011211:Electric Power Supplies; D004563:Electrochemistry / Q000295:instrumentation* / Q000379:methods; D004566:Electrodes; D004867:Equipment Design; D019544:Equipment Failure Analysis; D008697:Methane / Q000737:chemistry*; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry*
D010087:Oxides; D008697:Methane