Glycoligands and Co(II) glycocomplexes. Investigation of the variation of the sugar-scaffold on the structure and chirality measured by circular dichroism.
Glycoligands using various monosaccharide platforms functionalised by three 2-picolyl groups and coordinated to Co(II) through the bidentate 2-picolyl ether moieties are interesting ligands as they efficiently induce chirality at the cobalt with a fine control of the structure through the central sugar scaffold.
Cisnetti
Federico
F
Institut de Chimie Moléculaire et des Matériaux d'Orsay, Univ Paris-Sud, UMR8182, F-91405, Orsay Cedex.
Guillot
Régis
R
Desmadril
Michel
M
Pelosi
Giorgio
G
Policar
Clotilde
C
D002942:Circular Dichroism; D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D009005:Monosaccharides / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010848:Picolinic Acids / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism
D008024:Ligands; D009005:Monosaccharides; D009942:Organometallic Compounds; D010848:Picolinic Acids; D003035:Cobalt