title: Effect of temperature, gas phase composition, pH and microbial activity on As, Zn, Pb and Cd mobility in selected soils in the Ebro and Meuse Basins in the context of global change.
abstract: This study estimates the effect of environmental parameters on the mobility of four inorganic contaminants (As, Zn, Pb and Cd) in soils from three areas in the Ebro and Meuse River basins, within the context of global change. An experimental method, applicable to various soil systems, is used to measure the effect of four global-change-sensitive parameters (temperature, gas phase composition, pH and microbial activity). The aqueous phase of batch incubations was sampled regularly to monitor toxic element concentrations in water. Statistical processing enabled discrimination of the most relevant variations in dissolved concentrations measured at different incubation times and under different experimental conditions. Gas phase composition was identified as the most sensitive parameter for toxic element solubilization. This study confirms that total soil concentrations of inorganic pollutants are irrelevant when assessing the hazard for ecosystems or water resource quality.
authors.affiliation: Laboratoire des Interactions Micro-organismes, Minéraux et Matières organiques dans les Sols (LIMOS) UMR 7137, Nancy University, CNRS, BP 239, 54506 Vandoeuvre-les-Nancy cedex, France. antoine.joubert@limos.uhp-nancy.fr
authors.forename: A V P
authors.initials: AV
authors.lastname: Joubert
authors.forename: L
authors.initials: L
authors.lastname: Lucas
authors.forename: F
authors.initials: F
authors.lastname: Garrido
authors.forename: C
authors.initials: C
authors.lastname: Joulian
authors.forename: M
authors.initials: M
authors.lastname: Jauzein
mesh_terms: D001151:Arsenic / Q000032:analysis* / Q000737:chemistry; D004784:Environmental Monitoring; D005740:Gases; D006863:Hydrogen-Ion Concentration; D019216:Metals, Heavy / Q000032:analysis* / Q000737:chemistry; D045483:Rivers; D012988:Soil Microbiology; D012989:Soil Pollutants / Q000032:analysis* / Q000737:chemistry; D012995:Solubility; D013696:Temperature
chemical_list: D005740:Gases; D019216:Metals, Heavy; D012989:Soil Pollutants; D001151:Arsenic