title: Boronated enynes as versatile sources of stereodefined and skeletally diverse molecules.
abstract: [reaction: see text] The application of a one-pot palladium-catalyzed cycloisomerization of enynes 1/Diels-Alder cycloaddition/allylboration sequence efficiently generates tricyclic structures with complete control of the four stereogenic centers. Ruthenium and platinum catalysts perform distinct transformations providing other isomeric boron-substituted cyclic compounds.
authors.affiliation: Ingéniérie Chimique et Molécules pour le Vivant, Sciences Chimiques de Rennes, UMR 6226, Rennes CEDEX, France.
authors.forename: Alain
authors.initials: A
authors.lastname: Hercouet
authors.forename: Fabienne
authors.initials: F
authors.lastname: Berrée
authors.forename: Chia Hui
authors.initials: CH
authors.lastname: Lin
authors.forename: Loïc
authors.initials: L
authors.lastname: Toupet
authors.forename: Bertrand
authors.initials: B
authors.lastname: Carboni
mesh_terms: D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D007536:Isomerism; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D001896:Boron Compounds; D010165:Palladium