title: High-pressure studies of cyclohexane to 40 GPa.
abstract: We present data from two room temperature synchrotron X-ray powder diffraction studies of cyclohexane up to approximately 40 and approximately 20 GPa. In the first experiment, pressure cycling was employed wherein pressure was varied up to approximately 16 GPa, reduced to 3.5 GPa, and then raised again to 40 GPa. Initially, the sample was found to be in the monoclinic phase (P12(1)/n1) at approximately 8.4 GPa. Beyond this pressure, the sample adopted triclinic unit cell symmetry (P1) which remained so even when the pressure was reduced to 3.5 GPa, indicating significant hysteresis and metastability. In the second experiment, pressure was more slowly varied, and the monoclinic unit cell structure (P12(1)/n1) was observed at lower pressures up to approximately 7 GPa, above which a phase transformation into the P1 triclinic unit cell symmetry occurred. Thus, the pressure onset of the triclinic phase may be dependent upon the pressurizing conditions. High-pressure Raman data that further emphasize a phase transition (probably into phase VI) around 10 GPa are also presented. We also have further evidence for a phase VII, which is probably triclinic.
authors.affiliation: Department of Physics and High Pressure Science and Engineering Center (HiPSEC), University of Nevada Las Vegas, Las Vegas, Nevada 89154-4002, USA. pravica@physics.unlv.edu
authors.forename: Michael
authors.initials: M
authors.lastname: Pravica
authors.forename: Yongrong
authors.initials: Y
authors.lastname: Shen
authors.forename: Zachary
authors.initials: Z
authors.lastname: Quine
authors.forename: Edward
authors.initials: E
authors.lastname: Romano
authors.forename: David
authors.initials: D
authors.lastname: Hartnett