A new detection scheme for ultrafast 2D J-resolved spectroscopy.
Recent ultrafast techniques enable 2D NMR spectra to be obtained in a single scan. A modification of the detection scheme involved in this technique is proposed, permitting the achievement of 2D 1H J-resolved spectra in 500 ms. The detection gradient echoes are substituted by spin echoes to obtain spectra where the coupling constants are encoded along the direct nu2 domain. The use of this new J-resolved detection block after continuous phase-encoding excitation schemes is discussed in terms of resolution and sensitivity. J-resolved spectra obtained on cinnamic acid and 3-ethyl bromopropionate are presented, revealing the expected 2D J-patterns with coupling constants as small as 2 Hz.
Giraudeau
Patrick
P
Université de Nantes, Nantes Atlantique Universités, Laboratoire d'Analyse Isotopique et Electrochimique de Métabolismes, UMR CNRS 6006, Faculté des Sciences, 2 rue de la Houssinière, F-44322 Nantes Cedex 03, France. patrick.giraudeau@univ-nantes.fr
Akoka
Serge
S
D009682:Magnetic Resonance Spectroscopy / Q000379:methods*; D011422:Propionates / Q000737:chemistry; D013696:Temperature
D011422:Propionates; C035776:3-bromopropionic acid