title: Phosphine containing oligonucleotides for the development of metallodeoxyribozymes.
abstract: Novel transition metal catalysts based on oligonucleotides can be easily obtained by functionalization of 5-iodouridine with phosphine ligands, resulting in good asymmetric induction in palladium catalyzed allylic nucleophilic substitution.
authors.affiliation: School of Chemistry, University of St. Andrews, St. Andrews, Fife, UK. pcjk@st-andrews.ac.uk
authors.forename: Loïc
authors.initials: L
authors.lastname: Ropartz
authors.forename: Nico J
authors.initials: NJ
authors.lastname: Meeuwenoord
authors.forename: Gijsbert A
authors.initials: GA
authors.lastname: van der Marel
authors.forename: Piet W N M
authors.initials: PW
authors.lastname: van Leeuwen
authors.forename: Alexandra M Z
authors.initials: AM
authors.lastname: Slawin
authors.forename: Paul C J
authors.initials: PC
authors.lastname: Kamer
mesh_terms: D002384:Catalysis; D003461:Crystallography; D021881:DNA, Catalytic / Q000138:chemical synthesis* / Q000737:chemistry; D007065:Idoxuridine / Q000031:analogs & derivatives* / Q000737:chemistry; D008024:Ligands; D009841:Oligonucleotides / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D010720:Phosphines / Q000032:analysis*; D028561:Transition Elements / Q000737:chemistry
chemical_list: D021881:DNA, Catalytic; D008024:Ligands; D009841:Oligonucleotides; D010720:Phosphines; D028561:Transition Elements; C035991:5-iodouridine; D010165:Palladium; C044646:phosphine; D007065:Idoxuridine