Flavonol galactoside caffeiate ester and homoisoflavones from Caesalpinia millettii HOOK. et ARN.
Chemical examination of the stems of Caesalpinia millettii HOOK. et ARN. led to the isolation of new flavonol glycoside caffeiate ester (1) and homoisoflavone (2), along with four known homoisoflavones: eucomin (3), bonducellin (4), 8-methoxybonducellin (5) and intricatinol (6). The structures of 1 and 2 were established to be tamarixetin 3-O-(6''-O-E-caffeoyl)-beta-D-galactopyranoside (1) and (Z)-7-hydroxy-8-methoxy-3-(4-methoxybenzyl) chroman-4-one (2) on the basis of detailed analyses of physical, chemical, and spectral data. Compounds 3-6 were isolated from this plant for the first time.
Chen
Ping
P
Institute of Medicinal Plant Development, Chinese Academy of Medical Sciences and Peking Union Medical College, Beijing, China.
Yang
Jun-Shan
JS
D029911:Caesalpinia / Q000737:chemistry*; D044948:Flavonols / Q000737:chemistry / Q000302:isolation & purification*; D007529:Isoflavones / Q000737:chemistry / Q000302:isolation & purification*; D016339:Spectrometry, Mass, Fast Atom Bombardment; D013055:Spectrophotometry, Infrared
D044948:Flavonols; D007529:Isoflavones