Indium-mediated synthesis of heterobiaryls.
The palladium-mediated coupling reaction between triorganoindium reagents and organic electrophiles is extended to the synthesis of heteroaromatic compounds. Both electron-rich and electron-poor heterocycles can act as the organic electrophile or as the organoindium derivative.
Font-Sanchis
Enrique
E
División de Química Orgánica, Instituto de Bioingeniería, Universidad Miguel Hernández, 03202 Elche, Spain.
Céspedes-Guirao
F Javier
FJ
Sastre-Santos
Angela
A
Fernandez-Lazaro
Fernando
F
D002625:Chemistry, Organic / Q000379:methods*; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis* / Q000737:chemistry; D007204:Indium / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure
D006841:Hydrocarbons, Aromatic; D007204:Indium