title: Clathrate formation mechanism of supercritical hydrogen adsorption on copper(II) benzoate pyrazine.
abstract: The adsorption isotherms of supercritical hydrogen on [Cu2(bz)4(pyz)]n were measured at 77 K up to 10 MPa. The amount of supercritical hydrogen adsorbed on [Cu2(bz)4(pyz)]n at 77 K was 1.4 wt % at 10 MPa. The adsorption isotherms of supercritical hydrogen on [Cu2(bz)4(pyz)]n showed a stepwise adsorption that suggests clathrate formation between [Cu2(bz)4(pyz)]n and hydrogen molecules.
authors.affiliation: Materials Research Laboratory, NGK Insulators, Ltd., 2-56 Suda-cho, Mizuho, Nagoya 467-8530, Japan. mgoto@ngk.co.jp
authors.forename: Masashi
authors.initials: M
authors.lastname: Goto
authors.forename: Masahiro
authors.initials: M
authors.lastname: Furukawa
authors.forename: Junichi
authors.initials: J
authors.lastname: Miyamoto
authors.forename: Hirofumi
authors.initials: H
authors.lastname: Kanoh
authors.forename: Katsumi
authors.initials: K
authors.lastname: Kaneko