Spectroscopic evaluation of Co(II), Ni(II) and Cu(II) complexes derived from thiosemicarbazone and semicarbazone.
Co(II), Ni(II) and Cu(II) complexes were synthesized with thiosemicarbazone (L(1)) and semicarbazone (L(2)) derived from 2-acetyl furan. These complexes were characterized by elemental analysis, molar conductance, magnetic moment, mass, IR, electronic and EPR spectral studies. The molar conductance measurement of the complexes in DMSO corresponds to non-electrolytic nature. All the complexes are of high-spin type. On the basis of different spectral studies six coordinated geometry may be assigned for all the complexes except Co(L)(2)(SO(4)) and Cu(L)(2)(SO(4)) [where L=L(1) and L(2)] which are of five coordinated square pyramidal geometry.
Chandra
Sulekh
S
Department of Chemistry, Zakir Husain College, JLN Marg, New Delhi, India. schandra_00@yahoo.com
Kumar
Anil
A
D003035:Cobalt / Q000737:chemistry; D003300:Copper / Q000737:chemistry; D004553:Electric Conductivity; D004578:Electron Spin Resonance Spectroscopy; D008024:Ligands; D008280:Magnetics; D013058:Mass Spectrometry; D019216:Metals, Heavy / Q000737:chemistry*; D009532:Nickel / Q000737:chemistry; D012664:Semicarbazones / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013431:Sulfates / Q000737:chemistry; D013882:Thiosemicarbazones / Q000737:chemistry*
D008024:Ligands; D019216:Metals, Heavy; D012664:Semicarbazones; D013431:Sulfates; D013882:Thiosemicarbazones; D003035:Cobalt; D003300:Copper; D009532:Nickel