Chloridobis[(2-oxoazocan-1-yl)methyl]germanium(IV) trifluoromethanesulfonate.
In the title compound, [Ge(C(8)H(14)NO)(2)Cl]CF(3)SO(3), which is the first complex containing an eight-membered lactam (enantholactam) as ligand, the coordination polyhedron of the Ge(IV) atom is intermediate between trigonal-bipyramidal and square-pyramidal. Quantum chemical calculations of the crystal structure indicate the absence of additional coordination bonding between the Ge(IV) atom and the trifluoromethanesulfonate anion.
Komissarov
Eugene A
EA
A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Science, 28 Vavilov Street, Moscow 119991, Russian Federation.
Korlyukov
Alexander A
AA
Kramarova
Eugeniya P
EP
Bylikin
Sergey Yu
SY
Negrebetsky
Vadim V
VV
Baukov
Yuri I
YI