One-Step Synthesis and Magnetic Phase Transformation of Ln-TM-B Alloy by Chemical Reduction.
Binary and ternary intermetallic alloy systems are of interest for a variety of academic and technological applications. Despite recent advances in synthesizing binary alloy, there are very few reports of ternary alloy related to lanthanide series. The purpose of this work is to contribute to ternary alloy systems such as lanthanide-transition metal-boron with a simple chemical method and analysis of its magnetic behavior. Ternary Nd-Fe-B amorphous alloy was successfully synthesized with borohydride. The magnetic behavior in the process of formation of ternary Nd-Fe-B alloy and Nd2Fe14B from amorphous phase alloy is reported. Compared with the synthesis of a transition metal, the existence of a lanthanide ion makes aggregates-like particles with a diameter of 2 nm possible in the formation of a nanosphere, which is a significantly important result in terms of acceleration of the reduction-diffusion reaction for the formation of ternary alloy. In the process of reduction and diffusion, the Nd phase is diffused into the Fe-based phase, and then the ternary Nd2Fe14B intermetallic compound is fabricated.
Kim
Chang Woo
CW
Department of Chemistry, Pukyong National University, Busan 608-737, Korea, and Department of Chemistry and Chemical Biology, Harvard University, Cambridge, Massachusetts 02138.
Kim
Young Hwan
YH
Cha
Hyun Gil
HG
Lee
Don Keun
DK
Kang
Young Soo
YS