title: Tribological investigation of novel HDPE-HAp-Al2O3 hybrid biocomposites against steel under dry and simulated body fluid condition.
abstract: Among various biocompatible polymers, polyethylene based materials have received wider attention because of its excellent stability in body fluid, inertness, and easy formability. Attempts have been made to improve their physical properties (modulus/strength) to enable them to be used as load bearing hard tissue replacement applications. Among such attempts, high density polyethylene (HDPE)-hydroxyapatite (HAp) composite (HAPEX), has already been developed for total hip replacement (THR) acetabular cup and low load bearing bone tissue replacement. In the present work, alumina has been added as a partial replacement of HAp phase to improve the mechanical and tribological properties of the HAPEX composite. In an attempt to assess the suitability of the developed composite in THR application, the tribological properties against steel counterbody under both in air and simulated body fluid (SBF), have been investigated and efforts have been made to understand the wear mechanisms. The fretting wear study indicates the possibility of achieving extremely low COF (Coefficient of Friction approximately 0.09) as well as higher wear resistance (order of 10(-6) mm(3)/N m) with the newly developed composites in SBF. A low wear depth of approximately 4.6-5.3 microm is recorded, irrespective of fretting environment. The implication of the work is that optimal and combined addition of bioactive and bioinert ceramic filler to HDPE can provide a good opportunity to obtain hybrid biocomposites with better combination of physical properties (modulus, hardness) as well as low friction and high wear resistance.
authors.affiliation: Department of Materials and Metallurgical Engineering, Indian Institute of Technology, IIT-Kanpur, Kanpur 208016, India.
authors.forename: Shekhar
authors.initials: S
authors.lastname: Nath
authors.forename: Subhadip
authors.initials: S
authors.lastname: Bodhak
authors.forename: Bikramjit
authors.initials: B
authors.lastname: Basu
mesh_terms: D000537:Aluminum Oxide / Q000737:chemistry*; D001672:Biocompatible Materials / Q000737:chemistry*; D001826:Body Fluids; D003890:Desiccation; D017886:Durapatite / Q000737:chemistry*; D017276:Friction; D008855:Microscopy, Electron, Scanning; D020959:Polyethylene / Q000737:chemistry*; D011312:Pressure; D013232:Steel; D013499:Surface Properties
chemical_list: D001672:Biocompatible Materials; D013232:Steel; D020959:Polyethylene; D017886:Durapatite; D000537:Aluminum Oxide