title: Synthesis and isomerization of imino-fused N-confused porphyrin.
abstract: [reaction: see text] A set of mutually interconvertable inner-bridged-type porphyrinoids, imino-fused N-confused porphyrins (IF-NCPs), which possess a [5.7.5] tricyclic ring in the core, were synthesized from a condensation reaction of 21-amino-substituted NCP and an arylaldehyde, and the structures were characterized by X-ray single-crystal analysis.
authors.affiliation: Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395, Japan.
authors.forename: Norimasa
authors.initials: N
authors.lastname: Kashiwagi
authors.forename: Takeshi
authors.initials: T
authors.lastname: Akeda
authors.forename: Tatsuki
authors.initials: T
authors.lastname: Morimoto
authors.forename: Tomoya
authors.initials: T
authors.lastname: Ishizuka
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Furuta
mesh_terms: D018360:Crystallography, X-Ray; D007098:Imino Acids / Q000737:chemistry*; D007536:Isomerism; D008958:Models, Molecular; D015394:Molecular Structure; D011166:Porphyrins / Q000138:chemical synthesis / Q000737:chemistry*; D013057:Spectrum Analysis; D013696:Temperature
chemical_list: D007098:Imino Acids; D011166:Porphyrins