Synthesis and isomerization of imino-fused N-confused porphyrin.
[reaction: see text] A set of mutually interconvertable inner-bridged-type porphyrinoids, imino-fused N-confused porphyrins (IF-NCPs), which possess a [5.7.5] tricyclic ring in the core, were synthesized from a condensation reaction of 21-amino-substituted NCP and an arylaldehyde, and the structures were characterized by X-ray single-crystal analysis.
Kashiwagi
Norimasa
N
Department of Chemistry and Biochemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395, Japan.
Akeda
Takeshi
T
Morimoto
Tatsuki
T
Ishizuka
Tomoya
T
Furuta
Hiroyuki
H
D018360:Crystallography, X-Ray; D007098:Imino Acids / Q000737:chemistry*; D007536:Isomerism; D008958:Models, Molecular; D015394:Molecular Structure; D011166:Porphyrins / Q000138:chemical synthesis / Q000737:chemistry*; D013057:Spectrum Analysis; D013696:Temperature
D007098:Imino Acids; D011166:Porphyrins