Electropolymeric materials incorporating subsite structures related to iron-only hydrogenase: active ester functionalised poly(pyrroles) for covalent binding of {2Fe3S}-carbonyl/cyanide assemblies.
We report the assembly of the first electropolymeric materials incorporating catalytic diiron subsites related to those of the iron-only hydrogenases.
Ibrahim
Saad K
SK
School of Chemical Sciences and Pharmacy, University of East Anglia, Norwich, UK.
Liu
Xiaoming
X
Tard
Cédric
C
Pickett
Christopher J
CJ
D003486:Cyanides / Q000737:chemistry; D004563:Electrochemistry / Q000379:methods*; D004952:Esters / Q000737:chemistry; D006864:Hydrogenase / Q000138:chemical synthesis / Q000737:chemistry*; D058085:Iron Compounds / Q000737:chemistry; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D011108:Polymers / Q000138:chemical synthesis / Q000737:chemistry*; D011758:Pyrroles / Q000138:chemical synthesis / Q000737:chemistry*; D013455:Sulfur / Q000737:chemistry
D003486:Cyanides; D004952:Esters; D058085:Iron Compounds; D009942:Organometallic Compounds; D011108:Polymers; D011758:Pyrroles; D013455:Sulfur; D006864:Hydrogenase