Aqua(2,2'-diamino-4,4'-bi-1,3-thiazole-kappa2N,N')(oxydiacetato-kappa3O,O',O'')cobalt(II) trihydrate.
The title compound, [Co(C(4)H(4)O(5))(C(6)H(6)N(4)S(2))(H(2)O)].3H(2)O, displays a distorted octahedral coordination geometry. The tridentate oxydiacetate dianion chelates the Cu(II) atom in the meridional mode. In the crystal packing, hydrophilic and hydrophobic layers are arranged in an alternating manner. In addition, a three-dimensional hydrogen-bonding framework and pi-pi stacking are present.
Wu
Zhi Yong
ZY
Marine Drug and Food Institute, Ocean University of China, 266003 Qingdao, People's Republic of China. zd_wzy@hotmail.com
Sun
Wei
W
Li
Yan Tuan
YT
D003035:Cobalt / Q000737:chemistry*; D018360:Crystallography, X-Ray; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D013844:Thiazoles / Q000737:chemistry*
D009942:Organometallic Compounds; D013844:Thiazoles; C520990:aqua(2,2'-diamino-4,4'-bi-1,3-thiazole-kappa(2)N,N')(oxydiacetato-kappa(3)O,O',O'')cobalt(II); D003035:Cobalt