trans-Diaqua{5,5'-[(E,E)-pyridine-2,6-diylbis(methylidynenitrilo)]bis[pyrimidine-2,4(1H,3H)-dione]}zinc(II) nitrate hexafluorophosphate trihydrate.
The title compound, [Zn(C(15)H(11)N(7)O(4))(H(2)O)(2)](NO(3))(PF(6)).3H(2)O, contains a mononuclear zinc(II) complex. The Zn(2+) centre is seven-coordinated in a slightly distorted pentagonal-bipyramidal geometry, with the two water O atoms located in the apical positions, and the pyridine N atom, the two imine N atoms and two carbonyl O atoms of the uracil groups located in the equatorial plane. The charge is balanced by PF(6)(-) and NO(3)(-) anions.
Ozdemir
Namik
N
Department of Physics, Arts and Sciences Faculty, Ondokuz Mayis University, 55139 Samsun, Turkey.
Dinçer
Muharrem
M
Doğaner
Gamze
G
Astley
Demet
D
Astley
Stephen T
ST
D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D015394:Molecular Structure; D009566:Nitrates / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D011743:Pyrimidines / Q000737:chemistry*; D014498:Uracil / Q000031:analogs & derivatives* / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
D006845:Hydrocarbons, Fluorinated; D009566:Nitrates; D009942:Organometallic Compounds; D011743:Pyrimidines; C520989:diaqua(5,5'-(pyridine-2,6-diylbis(methylidynenitrilo))bis(pyrimidine-2,4(1H,3H)-dione))zinc(II); D014498:Uracil; D015032:Zinc; C030986:pyrimidine