Synthesis and structural characterization of a molecular plutonium(IV) compound constructed from dimeric building blocks.
Single crystals of Na(8)Pu(2)(O(2))(2)(CO(3))(6) x 12H(2)O, exhibiting bridging mu(2),eta(2)-O(2) ligands in unprecedented Pu(IV) dimeric units, were obtained at ambient temperature from an aqueous Pu(IV) peroxide carbonate solution.
Runde
Wolfgang
W
Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA. runde@lanl.gov
Brodnax
Lia F
LF
Goff
George S
GS
Peper
Shane M
SM
Taw
Felicia L
FL
Scott
Brian L
BL