Coil-globule transition of a single short polymer chain: an exact enumeration study.
The authors present an exact enumeration study of short self-avoiding walks in two as well as in three dimensions that addresses the question, "what is the shortest walk for which the existence of all the three scaling regimes--coil, globule, and the theta--could be demonstrated." Even though they could easily demonstrate the coil and the globule phase from free energy considerations, they could demonstrate the existence of a theta temperature only by using a scaling form for the distribution of gyration radius. That even such short walks have a scaling behavior is an unexpected result of this work.
Ponmurugan
M
M
Materials Science Division, Indira Gandhi Center of Atomic Research, Kalpakkam 603102, Tamil Nadu, India.
Narasimhan
S L
SL
Krishna
P S R
PS
Murthy
K P N
KP
D000465:Algorithms; D003198:Computer Simulation; D008956:Models, Chemical; D008958:Models, Molecular; D015233:Models, Statistical; D008970:Molecular Weight; D044367:Phase Transition; D011108:Polymers / Q000737:chemistry*; D011487:Protein Conformation; D011506:Proteins / Q000737:chemistry* / Q000648:ultrastructure*
D011108:Polymers; D011506:Proteins