A method for preparing ferric activated carbon composites adsorbents to remove arsenic from drinking water.
Iron oxide/activated carbon (FeO/AC) composite adsorbent material, which was used to modify the coal-based activated carbon (AC) 12 x 40, was prepared by the special ferric oxide microcrystal in this study. This composite can be used as the adsorbent to remove arsenic from drinking water, and Langmuir isotherm adsorption equation well describes the experimental adsorption isotherms. Then, the arsenic desorption can subsequently be separated from the medium by using a 1% aqueous NaOH solution. The apparent characters and physical chemistry performances of FeO/AC composite were investigated by X-ray diffraction (XRD), nitrogen adsorption, scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Batch and column adsorption experiments were carried out to investigate and compare the arsenic removal capability of the prepared FeO/AC composite material and virgin activated carbon. It can be concluded that: (1) the main phase present in this composite are magnetite (Fe(3)O(4)), maghemite (gamma-Fe(2)O(3)), hematite (alpha-Fe(2)O(3)) and goethite (alpha-FeO(OH)); (2) the presence of iron oxides did not significantly affect the surface area or the pore structure of the activated carbon; (3) the comparisons between the adsorption isotherms of arsenic from aqueous solution onto the composite and virgin activated carbon showed that the FeO/AC composite behave an excellent capacity of adsorption arsenic than the virgin activated carbon; (4) column adsorption experiments with FeO/AC composite adsorbent showed that the arsenic could be removed to below 0.01 mg/L within 1250 mL empty bed volume when influent concentration was 0.5mg/L.
Zhang
Qiao Li
QL
State Key Laboratory of Pollution Control and Resources Reuse, Tongji University, Shanghai 200092, PR China. qiaolizh@yahoo.com.cn
Lin
Y C
YC
Chen
X
X
Gao
Nai Yun
NY
D000327:Adsorption; D001151:Arsenic / Q000737:chemistry*; D002606:Charcoal / Q000737:chemistry; D005290:Ferric Compounds / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods*
D005290:Ferric Compounds; D014874:Water Pollutants, Chemical; D002606:Charcoal; C000499:ferric oxide; D001151:Arsenic