A new one-dimensional Mn(II) complex containing two enantiomeric subunits with mixed carboxylate, pyridine and sulfinate bridges.
The first O,O'-bonded metal-stabilized sulfinate has been isolated and structurally characterized to show a novel one-dimensional chain structure containing both the enantiomers of the subunit Mn(2-sinic)(DMSO)2.
Li
Fengyan
F
Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China. linxu@nenu.edu.cn
Xu
Lin
L
Gao
Guanggang
G
Qu
Xiaosu
X
Yang
Yanyan
Y
D002264:Carboxylic Acids / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*; D013237:Stereoisomerism; D013441:Sulfinic Acids / Q000737:chemistry*
D002264:Carboxylic Acids; D011725:Pyridines; D013441:Sulfinic Acids; D008345:Manganese; C023666:pyridine