Manganese(III,IV) and manganese(III) oxide clusters trapped by copper(II) complexes.
Reactions of quinquedentate Schiff base ligands with Mn and Cu ions afforded icosa- and hexadecanuclear mixed-metal clusters in which dinuclear CuII complexes trapped oxo-bridged [MnIII8MnIV4O12] and [MnIII6O6] cores, respectively. Maximum entropy method analysis for synchrotron X-ray diffraction data was used to determine the oxidation states of the Mn ions.
Yamashita
Satoshi
S
Graduate School of Pure and Applied Sciences, Department of Chemistry, University of Tsukuba, Tennodai 1-1-1, Tsukuba 305-8571, Japan.
Shiga
Takuya
T
Kurashina
Masashi
M
Nihei
Masayuki
M
Nojiri
Hiroyuki
H
Sawa
Hiroshi
H
Kakiuchi
Toru
T
Oshio
Hiroki
H