Size effect of encaged clusters on the exohedral chemistry of endohedral fullerenes: a case study on the pyrrolidino reaction of ScxGd3-xN@C80 (x = 0-3).
We report a combined experimental and theoretical investigation on the regiochemistry of a series of TNT endohedral fullerenes ScxGd3-xN@C80 (x = 0-3) in 1,3-dipolar cycloadditions, which demonstrates that the regioselectivity of the TNT-based endohedral fullerenes ScxGd3-xN@C80 (x = 0-3) in the exohedral cycloadditions depends remarkably on the size of the encaged cluster.
Chen
Ning
N
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing, China.
Zhang
Er-Yun
EY
Tan
Kai
K
Wang
Chun-Ru
CR
Lu
Xin
X