Determination of the acid/base properties of MgY and NH4Y molecular sieves by inverse gas chromatography.
The surface characterization of MgY and NH(4)Y zeolites was performed using inverse gas chromatography (IGC). The adsorption thermodynamic parameters (the standard enthalpy (DeltaH degrees ), standard entropy change (DeltaS degrees ), and free energy change of adsorption (DeltaG degrees ), the dispersive component of the surface free energies (gamma(S)(d)), and the acid-base character of the surface of MgY and NH(4)Y zeolites were estimated using the retention time of different non-polar and polar probes at infinite dilution region. The specific free energy of adsorption (DeltaG(sp)), the specific enthalpy of adsorption (DeltaH(sp)), and the specific entropy of adsorption (DeltaS(sp)) of polar probes on MgY and NH(4)Y zeolites were determined. The values of the DeltaH(sp) were correlated with both the donor and acceptor numbers of the probes to quantify the acidic K(A) and the basic K(D) parameters of the zeolite surfaces. The values obtained for the K(A) and K(D) parameters indicated a basic character for the surface of MgY and NH(4)Y zeolites.
Bilgiç
Ceyda
C
Department of Chemical Engineering, Faculty of Engineering and Architecture, Eskişehir Osmangazi University, 26480 Eskişehir, Turkey. cbilgic@ogu.edu.tr
Tümsek
Fatma
F
D000143:Acids; D000327:Adsorption; D000465:Algorithms; D002849:Chromatography, Gas / Q000379:methods*; D002850:Chromatography, Gel; D006863:Hydrogen-Ion Concentration; D008274:Magnesium / Q000737:chemistry*; D008956:Models, Chemical; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D013499:Surface Properties; D013816:Thermodynamics; D014835:Volatilization; D017641:Zeolites / Q000737:chemistry*
D000143:Acids; D000644:Quaternary Ammonium Compounds; D017641:Zeolites; D008274:Magnesium