Organometallic radical-adducts of fullerenes C60, C70, and single-walled carbon nanotubes derived from (cyclopentadienyl)molybdenumtricarbonyl dimer.
Interaction of the metal-centered free radicals [CpMo(CO)3]* generated photochemically from the corresponding dimer [CpMo(CO)3]2 with fullerenes C60, C70, or single-walled carbon nanotubes in toluene results in the radical-adducts investigated by using TGA, ESR, Raman and X-ray Photo-electron spectroscopy. Comparison was made with the chromium analogues previously studied.
Gasanov
Rashid G
RG
Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilov Street, 119991 Moscow, Russia.
Lobach
Anatolii S
AS
Sokolov
Viatcheslav I
VI
Demenjev
Aleksei P
AP
Maslakov
Konstantin I
KI
Obraztsova
Elena D
ED
D018736:DNA Adducts; D019281:Dimerization; D004578:Electron Spin Resonance Spectroscopy; D005609:Free Radicals; D037741:Fullerenes / Q000737:chemistry*; D008956:Models, Chemical; D008982:Molybdenum / Q000737:chemistry*; D053758:Nanoparticles; D036103:Nanotechnology / Q000379:methods*; D037742:Nanotubes, Carbon / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013052:Spectrometry, X-Ray Emission; D013059:Spectrum Analysis, Raman
D018736:DNA Adducts; D005609:Free Radicals; D037741:Fullerenes; D037742:Nanotubes, Carbon; D009942:Organometallic Compounds; C069836:fullerene C70; D008982:Molybdenum; C069837:fullerene C60