Radical reactions of [60]fullerene mediated by manganese(III) acetate dihydrate.
Mn(OAc)3 x 2H2O is an excellent reagent to promote free radical reactions of C60. C60 reacted with various methylene active compounds, methyl ketones, beta-enamino carbonyl compounds, carboxylic acid derivatives, and diallylamines in the presence of Mn(OAc)3 x 2H2O to afford singly-bonded fullerene dimers, 1,4-bisadducts and 1,16-bisadducts of C60, C60-fused dihydrofuran derivatives, methanofullerenes, C60-fused pyrroline derivatives, C60-fused lactone derivatives, and C60-fused pyrrolidine derivatives. Mn(OAc)3 x 2H2O was successfully employed to transform ArC60-H into ArC60-OAc.
Wang
Guan-Wu
GW
National Laboratory for Physical Sciences at Microscale and Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China.
Li
Fa-Bao
FB
D000085:Acetates / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D002264:Carboxylic Acids / Q000737:chemistry; D019281:Dimerization; D004952:Esters; D005609:Free Radicals; D037741:Fullerenes / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry; D007783:Lactones / Q000737:chemistry; D008314:Malonates / Q000737:chemistry; D008345:Manganese / Q000737:chemistry*; D008956:Models, Chemical; D008968:Molecular Conformation; D009570:Nitriles / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D013696:Temperature
D000085:Acetates; D002264:Carboxylic Acids; D004952:Esters; D005609:Free Radicals; D037741:Fullerenes; D007659:Ketones; D007783:Lactones; D008314:Malonates; D009570:Nitriles; D009942:Organometallic Compounds; C521134:manganese(III) acetate dihydrate; D008345:Manganese; D002244:Carbon; C030290:malonic acid; C000945:dicyanmethane; C069837:fullerene C60