Plastic and moldable metals by self-assembly of sticky nanoparticle aggregates.
Deformable, spherical aggregates of metal nanoparticles connected by long-chain dithiol ligands self-assemble into nanostructured materials of macroscopic dimensions. These materials are plastic and moldable against arbitrarily shaped masters and can be thermally hardened into polycrystalline metal structures of controllable porosity. In addition, in both plastic and hardened states, the assemblies are electrically conductive and exhibit Ohmic characteristics down to approximately 20 volts per meter. The self-assembly method leading to such materials is applicable both to pure metals and to bimetallic structures of various elemental compositions.
Klajn
Rafal
R
Department of Chemical and Biological Engineering, Northwestern University, Evanston, IL 60208, USA.
Bishop
Kyle J M
KJ
Fialkowski
Marcin
M
Paszewski
Maciej
M
Campbell
Christopher J
CJ
Gray
Timothy P
TP
Grzybowski
Bartosz A
BA