Photodissociation dynamics of the chromophores of the amino acid tyrosine: p-methylphenol, p-ethylphenol, and p-(2-aminoethyl)phenol.
The photodissociation of p-methylphenol, p-ethylphenol, and p-(2-aminoethyl)phenol, chromophores of the amino acid tyrosine, was studied separately for each compound in a molecular beam at 248 nm using multimass ion imaging techniques. They show interesting side-chain size-dependent dissociation properties. Only one dissociation channel, that is, H atom elimination, was observed for both p-methylphenol and p-ethylphenol. The photofragment translational energy distributions and potential energy surfaces from ab initio calculation suggest that H atom elimination occurs from a repulsive excited state. On the other hand, the H atom elimination channel is quenched completely by internal conversion and/or intersystem crossing in p-(2-aminoethyl)phenol. Only C-C bond cleavage was observed from p-(2-aminoethyl)phenol. The photofragment translational energy distribution shows a slow component and a fast component. The fast component results from dissociation on an electronic excited state, but the slow component occurs only after the internal conversion to the ground electronic state. Comparison with the photodissociation of phenol and ethylbenzene is made.
Tseng
Chien-Ming
CM
Institute of Atomic and Molecular Sciences, Academia Sinica, P.O. Box 23-166, Taipei, 10617 Taiwan.
Lee
Yuan T
YT
Ni
Chi-Kung
CK
Chang
Jia-Lin
JL
D003198:Computer Simulation; D008958:Models, Molecular; D015394:Molecular Structure; D010636:Phenols / Q000737:chemistry*; D010777:Photochemistry; D014439:Tyramine / Q000737:chemistry*; D014443:Tyrosine / Q000737:chemistry*
D010636:Phenols; D014443:Tyrosine; C042291:4-ethylphenol; D014439:Tyramine