One-pot synthesis of 7H-dibenzo[b,d]azepin-7-one by heterogeneous flash vacuum pyrolysis with MCM-41 catalysts.
Homogeneous and heterogeneous flash vacuum pyrolysis (fvp) reactions of 2-(1H-1,2,3-benzotriazol-1-yl)phenylethanone (1) are reported. Heterogeneous reactions were carried out with Al-MCM-41 catalysts, mesoporous molecular sieves of the type M41S. In both cases, 7H-dibenzo[b,d]azepin-7-one (4) was the major product; however, in the catalytic reactions, yields and selectivity were very high. A mechanism for this reaction is also discussed.
Moyano
Elizabeth L
EL
INFIQC, Departamento de Química OrgAnica, Facultad de Ciencias Químicas, Universidad Nacional de Córdoba, Ciudad Universitaria, Córdoba 5016, Argentina. lauramoy@mail.fcq.unc.edu.ar
Lucero
Paola L
PL
Eimer
Griselda A
GA
Herrero
Eduardo R
ER
Yranzo
Gloria I
GI