A novel asymmetric hydroarsination reaction promoted by a chiral organopalladium complex.
The dissymmetrical chiral bidentate (R)-(+)-1-(diphenylphosphino)-2-(diphenylarsino)propane was prepared stereoselectively via the novel asymmetric hydroarsination reaction between diphenylarsine and diphenyl-1-propenyl-(E)-phosphine using di-mu-chlorobis{(S)-1-[1-(dimethylamino)ethyl]-2-naphthalenyl-C,N}dipalladium(II) as the chiral reaction promoter.
Bungabong
Maricar L
ML
Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637616, Singapore.
Tan
Kien Wee
KW
Li
Yongxin
Y
Selvaratnam
Selvasothi V
SV
Dongol
Krishna G
KG
Leung
Pak-Hing
PH