title: Neutron and X-ray scattering on the monolayer structure of a lecithin fullerene-derivative.
abstract: Using neutron reflectivity with contrast variation, X-ray reflectivity, and grazing incident small-angle X-ray scattering (GISAXS), we have characterized the in-depth and in-plane structural characteristics of the Langmuir and Langmuir-Blodgett (LB) films formed by a novel lecithin C60-derivative, FPTL, of three phospholipids jointly bonded on one single olefinic moiety of a C60 cage. Based on the neutron reflectivity measured, we have proposed a monolayer structure, with the C60 cages of FPTL lifted into the air and hydrophilic phospholipid heads immersed in water, for the FPTL Langmuir layer formed on water. On the other hand, the LB film of FPTL prepared on mica exhibits clear Kiessig fringes in the X-ray reflectivity profile, indicating a 27 angstroms monolayer film with less molecular orientation. With GISAXS, we have extracted an in-plane correlation length of about 210 A for a possible in-plane aggregation of C60 of FPTL in the LB monolayer. We have also demonstrated the highly ordered monolayer structures of a lecithin lipid, in elucidating the positive effect of the attached functional group-phospholipids on the monolayer formation of the lecithin C60-derivative.
authors: National Synchrotron Radiation Research Center, Hsinchu Science Park, Hsinchu 300, Taiwan.
authors: U-Ser
authors: US
authors: Jeng
authors: Tsang-Lang
authors: TL
authors: Lin
authors: Kwanwoo
authors: K
authors: Shin
authors: Hsin-Yi
authors: HY
authors: Lee
authors: Chia-Hung
authors: CH
authors: Hsu
authors: Zau-Ann
authors: ZA
authors: Chi
authors: Ming Chih
authors: MC
authors: Shih
authors: Naoya
authors: N
authors: Torikai
mesh_terms: D037741:Fullerenes / Q000737:chemistry*; D008956:Models, Chemical; D008968:Molecular Conformation; D015394:Molecular Structure; D036103:Nanotechnology / Q000379:methods*; D009502:Neutrons; D010713:Phosphatidylcholines / Q000737:chemistry*; D010743:Phospholipids / Q000737:chemistry; D011312:Pressure; D012542:Scattering, Radiation; D014867:Water / Q000737:chemistry; D014965:X-Rays
chemical_list: D037741:Fullerenes; D010713:Phosphatidylcholines; D010743:Phospholipids; D014867:Water; C069837:fullerene C60