Dihydrogen complexes as prototypes for the coordination chemistry of saturated molecules.
The binding of a dihydrogen molecule (H(2)) to a transition metal center in an organometallic complex was a major discovery because it changed the way chemists think about the reactivity of molecules with chemically "inert" strong bonds such as H H and C H. Before the seminal finding of side-on bonded H(2) in W(CO)(3)(PR(3))(2)(H(2)), it was generally believed that H(2) could not bind to another atom in stable fashion and would split into two separate H atoms to form a metal dihydride before undergoing chemical reaction. Metal-bound saturated molecules such as H(2), silanes, and alkanes (sigma-complexes) have a chemistry of their own, with surprisingly varied structures, bonding, and dynamics. H(2) complexes are of increased relevance for H(2) production and storage in the hydrogen economy of the future.
Kubas
Gregory J
GJ
Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA. kubas@lanl.gov