Creation of quaternary stereocenters in carbonyl allylation reactions.
Despite the advances in stereoselective carbonyl allylation reactions, the creation of quaternary stereocenters in the addition of 3,3'-disubstituted allylmetals to aldehydes is still a challenging issue. This feature article describes the most powerful approaches that have been devised to address this problem.
Marek
Ilan
I
The Mallat Family Laboratory of Organic Chemistry, The Lise Meitner-Minerva Center for Computational Quantum Chemistry, Technion-Israel Institute of Technology, Technion City, Haifa, 32 000, Israel. chilanm@tx.technion.ac.il
Sklute
Genia
G