13-tungstoborate stabilized by an organostannoxane hexamer.
The novel dimethyltin-containing polyanion [{(CH3)2Sn}6(OH)2O2(H2BW13O46)2]12- (1) is composed of two [H2BW13O46]9- clusters linked by an unprecedented planar, hexameric [{(CH3)2Sn}6(OH)2O2]8+ organostannoxane moiety, representing the first X-ray structural characterization of a molecular hybrid organic-inorganic tungstoborate and of the elusive [HnBW13O46](11-n)- species.
Reinoso
Santiago
S
School of Engineering and Science, Jacobs University Bremen, P.O. Box 750 561, 28725 Bremen, Germany.
Dickman
Michael H
MH
Matei
Marius F
MF
Kortz
Ulrich
U