Solvatochromic study of 1,2-dihydroxyanthraquinone in neat and binary solvent mixtures.
Preferential solvation of a solvatochromic probe has been studied in binary mixtures comprising of a non-protic and a protic solvent. The non-protic solvents employed are carbon tetrachloride (CCl(4)), acetonitrile (AcN) and N,N-dimethyl formamide (DMF) and the protic solvents are methanol (MeOH) and ethanol (EtOH). The probe molecule exhibits different spectroscopic characteristics depending upon the properties of the solubilizing media. The observed spectral features provide an indication of the microenvironment immediately surrounding the probe. Solvatochromic shifts of the ground and excited states of the probe were analysed by monitoring the charge transfer absorption band and the fluorescence emission spectra in terms of the solute-solvent and solvent-solvent interactions. Fluorescence emission spectra show the dual emission due to excited state proton transfer nature of the probe molecule. The effect of solvent and the excitation energy on dual emission are also studied. The observed magnitude of the Stokes shift in the above solvents has been used to deduce experimentally the dipole moment ratio of the probe molecule for the excited state to the ground state. The dipole moment of excited state is higher than the ground state.
Sasirekha
V
V
Department of Laser Studies, Madurai Kamaraj University, Madurai 625021, India.
Umadevi
M
M
Ramakrishnan
V
V
D000097:Acetonitriles / Q000737:chemistry; D000880:Anthraquinones / Q000737:chemistry*; D002251:Carbon Tetrachloride / Q000737:chemistry; D004126:Dimethylformamide / Q000737:chemistry; D004553:Electric Conductivity; D000431:Ethanol / Q000737:chemistry; D000432:Methanol / Q000737:chemistry; D012997:Solvents / Q000737:chemistry*; D013053:Spectrophotometry
D000097:Acetonitriles; D000880:Anthraquinones; D012997:Solvents; D000431:Ethanol; C010078:alizarin; D004126:Dimethylformamide; D002251:Carbon Tetrachloride; D000432:Methanol; C032159:acetonitrile