Photocatalytic degradation of phenol in aqueous solutions by Pr-doped TiO2 nanoparticles.
Photocatalytic degradation of phenol in water was examined using Pr-doped TiO(2) nanoparticles. These photocatalysts were synthesized by an acid-peptized sol-gel method from titanium tetra-isopropoxide with different concentrations of Pr(III) dopant and calcination temperatures. Several tools such as XRD, BET surface area, SEM, and EDX, were used to evaluate particle structure, size distribution, and composition. The optical absorption properties of the prepared particles were also measured. Photocatalytic activity of the particles was studied in a batch reactor containing phenol solution with 400W UV irradiation. Parameters affecting photocatalytic process such as the catalyst crystallinity, light absorption efficiency, the dosage of catalyst, dopant and phenol concentrations were investigated. The Pr-doped TiO(2) showed high activity for photocatalytic degradation of phenol. The presence of Pr ions in the TiO(2) particles would cause a significant absorption shift towards the visible region. The degradation process was optimized using 1g/L Pr-doped TiO(2) with a Pr(III) concentration of 0.072 mol% after 2h irradiation. It was shown that photodegradation followed a pseudo-first-order kinetics and the rate constant changed with phenol concentration.
Chiou
Chwei-Huann
CH
Department of Chemical Engineering and Materials Science, Yuan Ze University, Chung-Li 32003, Taiwan.
Juang
Ruey-Shin
RS
D002384:Catalysis; D053758:Nanoparticles / Q000737:chemistry; D019800:Phenol / Q000737:chemistry / Q000528:radiation effects; D011221:Praseodymium / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*; D014466:Ultraviolet Rays; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000528:radiation effects; D018508:Water Purification / Q000379:methods
D014874:Water Pollutants, Chemical; C009495:titanium dioxide; D019800:Phenol; D014025:Titanium; D011221:Praseodymium