title: Inorganic selenium speciation in groundwaters by solid phase extraction on Dowex 1X2.
abstract: A Dowex 1X2 resin separation technique followed by analysis with atomic absorption spectroscopy was evaluated for the study of inorganic selenium speciation in groundwaters. After Se(IV) and Se(VI) were retained on the resin column, Se(IV) and Se(VI) were eluted out by 0.1 and 1M nitric acid solutions. The method detection limit was 5.6 ng/L for both Se(IV) and Se(VI). Analysis of synthetic solutions consistently yielded more than 90% recovery of these two selenium forms with negligible cross-contamination. The results of spiked well waters show that this method can be applied at ultra-trace level of Se in groundwater and the interference of chloride ion can be neglected. Water samples collected from the monitoring wells in the Science-based Industrial Park, Hsin-Chu, Taiwan, were analyzed. Average dissolved selenium concentrations were 32.1+/-17.6 ng/L. The proportion of Se(VI) to the total dissolved selenium ranged from 47.6 to 61.2% and an average of 53.8% in water samples analyzed.
authors: Department of Environmental Engineering and Health, Yuanpei University, 306 Yuanpei Street, Hsinchu City 300, Taiwan. larvin@ms21.hinet.net
authors: Tser-Sheng
authors: TS
authors: Lin
mesh_terms: D000837:Anion Exchange Resins; D004784:Environmental Monitoring; D017942:Nitric Acid / Q000737:chemistry; D012117:Resins, Synthetic; D012643:Selenium / Q000032:analysis*; D052616:Solid Phase Extraction; D014874:Water Pollutants, Chemical / Q000032:analysis*; D014881:Water Supply / Q000032:analysis*
chemical_list: D000837:Anion Exchange Resins; D012117:Resins, Synthetic; D014874:Water Pollutants, Chemical; D017942:Nitric Acid; C036240:Dowex 1X2; D012643:Selenium