Palladium-Catalyzed Buchwald-Hartwig Type Amination of Fluorous Arylsulfonates.
Palladium-catalyzed cross-coupling reactions of aryl perfluorooctanesulfonates with amines are introduced. Application of the fluorous tag in multistep synthesis of triaryl-substituted pyrimidine is also described.
Zhang
Wei
W
Fluorous Technologies, Inc., University of Pittsburgh Applied Research Center 970 William Pitt Way, Pittsburgh, Pennsylvania 15238, USA.
Nagashima
Tadamichi
T