Structure-directing effects in the supramolecular intercluster compound [Au9(PPh3)8]2[V10O28H3]2: long-range versus short-range bonding interactions.
Although being composed of trivalent ions, the crystal structure of the supramolecular intercluster compound [Au9(PPh3)8]2[V10O28H3]2 is dominated by short-range intermolecular interactions, i.e., hydrogen bonds, and C-H/pi interactions, avoiding a simple AB-type packing.
Schulz-Dobrick
Martin
M
Max-Planck-Institute for Solid-State Research, Heisenbergstrasse 1, 70563 Stuttgart, Germany.
Jansen
Martin
M