Steric and electronic factors influencing recognition by a simple, charge neutral norbornene based anion receptor.
Based on (1)H NMR studies, subtle electronic factors rather than pre-organisation dictate the binding stoichiometry of the new, norbornene based, anion hosts 1 and 2 with acetate, however, the binding of dihydrogenphosphate appears to be based solely on steric constraints.
Lowe
Adam J
AJ
School of Life and Environmental Sciences, Deakin University, Geelong, VIC, Australia.
Dyson
Gail A
GA
Pfeffer
Frederick M
FM
D000838:Anions / Q000737:chemistry; D003517:Cyclopentanes / Q000737:chemistry; D004583:Electrons; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy; D008298:Maleates / Q000737:chemistry; D008968:Molecular Conformation; D009636:Norbornanes / Q000737:chemistry*; D055672:Static Electricity; D013329:Structure-Activity Relationship
D000838:Anions; D003517:Cyclopentanes; D008298:Maleates; D009636:Norbornanes; C004780:dimethyl maleate