Asymmetric transfer hydrogenation over Ru-TsDPEN catalysts supported on siliceous mesocellular foam.
A siliceous mesocellular foam-immobilized Ru-TsDPEN complex exhibited excellent catalytic reactivity, enantioselectivity and reusability in the asymmetric transfer hydrogenation of an imine and ketones.
Huang
Xiaohua
X
Department of Chemical Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139-4307, USA.
Ying
Jackie Y
JY
D002384:Catalysis; D005029:Ethylenediamines / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry; D007097:Imines / Q000737:chemistry; D007659:Ketones / Q000737:chemistry; D008024:Ligands; D009942:Organometallic Compounds / Q000737:chemistry*; D017975:Ruthenium Compounds / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry; D021241:Spectrometry, Mass, Electrospray Ionization; D013237:Stereoisomerism
D005029:Ethylenediamines; D007097:Imines; D007659:Ketones; D008024:Ligands; D009942:Organometallic Compounds; D017975:Ruthenium Compounds; C520782:ruthenium-(1S,2S)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine; D012822:Silicon Dioxide; D006859:Hydrogen