Discovery, synthesis, and characterization of an isomeric coordination polymer with pillared kagome net topology.
A topological isomer based on Zn2 paddlewheel, dicarboxylate, and diamine ligands is synthesized by solvothermal methods after careful modulation of the reaction conditions. The new framework is characterized by a pillared Kagome net topology and possesses a sustainable pore structure with high surface area (approximately 2400 m2/g) and large hexagonal channels (approximately 15 A).
Chun
Hyungphil
H
Department of Applied Chemistry, College of Science and Technology, Hanyang University, 1271 Sa-1 dong, Ansan 426-791, Republic of Korea. hchun@hanyang.ac.kr
Moon
Jumi
J