Synthesis, structure and spectroscopic properties of rare earth complexes with a new aryl amide 2,2'-bipyridine derivative.
Solid complexes of rare earth nitrates and picrates with a new aryl amide ligand 3.3'-bis(benzylamido)-2,2'-bipyridine (L) were synthesized and characterized by elemental analysis, IR and molar conductivity measurements. The molecular structures of the complex [TbL(2)(NO(3))(3)H(2)O].2H(2)O have been determined by single-crystal X-ray diffraction. The fluorescent properties of the Eu(III) and Tb(III) nitrates and picrates complexes in solid state were also investigated in detail. Under the excitation, these complexes exhibited characteristic emissions of europium and terbium ions. It is worth noting that the nature of the anion has a great effect upon the composition of the complexes as well as emission properties of them.
Song
Xue-Qin
XQ
State Key Laboratory of Applied Organic Chemistry, Lanzhou university, Lanzhou 730000, China.
Zheng
Jiang-Rong
JR
Liu
Wei-Sheng
WS
Ju
Zheng-Hua
ZH
D015082:2,2'-Dipyridyl / Q000031:analogs & derivatives / Q000138:chemical synthesis* / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004553:Electric Conductivity; D004583:Electrons; D008024:Ligands; D008674:Metals, Rare Earth / Q000138:chemical synthesis* / Q000737:chemistry*; D008958:Models, Molecular; D010851:Picrates / Q000737:chemistry; D011725:Pyridines / Q000138:chemical synthesis* / Q000737:chemistry*; D013050:Spectrometry, Fluorescence; D013055:Spectrophotometry, Infrared; D013057:Spectrum Analysis
D008024:Ligands; D008674:Metals, Rare Earth; D010851:Picrates; D011725:Pyridines; D015082:2,2'-Dipyridyl; C005858:picric acid