title: Measurement and modeling of oxidation rate of hydrogen isotopic gases by soil.
abstract: Measurements of oxidation rate of hydrogen isotopic gases by soil were made to model HT oxidation rate by soil. Soil was sampled at a cultivated farmland and laboratory measurements of the oxidation rate of H(2) and D(2) gases simulating HT gas were carried out under controlled conditions of soil. The oxidation rate increased with increase of H(2) or D(2) concentration in air and nearly saturated at high concentration. The oxidation rate was low under extremely dry and wet soil conditions and was the highest at soil water content of 8-14 w/w%. The oxidation rate increased exponentially with increasing soil temperature and was the highest at 46 degrees C. Michaelis constant K(m) increased exponentially with increasing soil temperature. Oxidation rate of H(2) was generally higher than that of D(2), while K(m) of H(2) was generally lower than that of D(2). From these results, oxidation rate of HT was modeled as a product of the functions that represent dependency on each soil factor.
authors.affiliation: Department of Energy Engineering and Science, Graduate School of Engineering, Nagoya University, Nagoya 464-8603, Japan. m-ota@ees.nagoya-u.ac.jp
authors.forename: Masakazu
authors.initials: M
authors.lastname: Ota
authors.forename: Hiromi
authors.initials: H
authors.lastname: Yamazawa
authors.forename: Jun
authors.initials: J
authors.lastname: Moriizumi
authors.forename: Takao
authors.initials: T
authors.lastname: Iida
mesh_terms: D003903:Deuterium / Q000378:metabolism*; D006859:Hydrogen / Q000378:metabolism*; D010084:Oxidation-Reduction; D012988:Soil Microbiology; D012990:Soil Pollutants, Radioactive / Q000378:metabolism*; D013696:Temperature; D014316:Tritium / Q000378:metabolism*; D014867:Water / Q000032:analysis
chemical_list: D012990:Soil Pollutants, Radioactive; D014867:Water; D014316:Tritium; D006859:Hydrogen; D003903:Deuterium