Ruthenium(0) nanoparticle-catalyzed isotope exchange between 10B and 11B nuclei in decaborane(14).
Well dispersed ruthenium(0) nanoparticles, stabilized in the ionic liquid agent, trihexyltetradecylphosphonium dodecylbenzenesulfonate, have been successfully prepared via a reduction reaction of the precursor [CpRuCp*RuCp*]PF6 (Cp* = C5Me5). The ruthenium(0) nanoparticles were shown to catalyze the isotope exchange reaction between 10B enriched diborane and natural abundant B10H14 to produce highly 10B enriched (approximately 90%) decaborane(14) products. The ruthenium(0) nanoparticles were characterized by TEM, XRD, and XPS. The 10B enriched decaborane(14) has been analyzed by Raman spectroscopy, NMR, and high-resolution MS.
Yinghuai
Zhu
Z
Institute of Chemical and Engineering Sciences, No. 1 Pesek Road, Jurong Island, Singapore 627833.
Widjaja
Effendi
E
Sia
Shirley Lo Pei
SL
Zhan
Wang
W
Carpenter
Keith
K
Maguire
John A
JA
Hosmane
Narayan S
NS
Hawthorne
M Frederick
MF
D001896:Boron Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D002384:Catalysis; D007554:Isotopes / Q000737:chemistry; D046529:Microscopy, Electron, Transmission; D008958:Models, Molecular; D015394:Molecular Structure; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure; D012428:Ruthenium / Q000737:chemistry*; D013057:Spectrum Analysis; D014965:X-Rays
D001896:Boron Compounds; D007554:Isotopes; C100070:decaborane; D012428:Ruthenium