title: [Formylation of metallocomplexes of tetra-meso-(para- and meta-methoxyphenyl)porphyrines].
abstract: The Vilsmeier formylation of metallocomplexes of isomeric meta- and para-methoxy-substituted tetraphenylporphyrines has was been studied. Formyl derivatives of meta-isomers were shown to form cyclization products not only in solutions, but also in the the solid state. The ability to undergo such transformations decreases in the trend following order: Co > Cu > Ni > Pd > Pt.
authors.forename: V D
authors.initials: VD
authors.lastname: Rumiantseva
authors.forename: S V
authors.initials: SV
authors.lastname: Tsukanov
authors.forename: A F
authors.initials: AF
authors.lastname: Mironov
mesh_terms: D005561:Formates / Q000737:chemistry*; D007536:Isomerism; D008665:Metalloporphyrins / Q000737:chemistry*; D019216:Metals, Heavy / Q000737:chemistry
chemical_list: D005561:Formates; D008665:Metalloporphyrins; D019216:Metals, Heavy; C030544:formic acid