Substrate-controlled asymmetric total synthesis of (+)-microcladallene B with a bromination strategy based on a nucleophile-assisting leaving group.
Park
Janghyun
J
The Research Institute of Pharmaceutical Sciences, College of Pharmacy, Seoul National University, San 56-1, Shinrim-Dong, Kwanak-Ku, Seoul 151-742, Korea.
Kim
Byungsook
B
Kim
Hyoungsu
H
Kim
Sanghee
S
Kim
Deukjoon
D
D001966:Bromine / Q000737:chemistry*; D002384:Catalysis; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D012717:Sesquiterpenes / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism; D013379:Substrate Specificity
D012717:Sesquiterpenes; C523111:microcladallene B; D001966:Bromine