title: Direct visualization of a self-organized multilayer film of low T(g) diblock copolymer micelles.
abstract: The first in situ proof of the presence of true nanoscale micelle structure within alternating layers of a self-assembled cationic and anionic diblock copolymer micelle-micelle multilayer film is presented using atomic force microscopy. Apparently similar layer morphologies are distinguished by the interaction force curves normal to each layer. The three-dimensional order in these low Tg diblock copolymer films, together with their mechanical resilience and strongly hydrated nature, suggests many new technological applications.
authors.affiliation: School of Environmental and Life Sciences, University of Newcastle, Callaghan, NSW 2308, Australia.
authors.forename: Emelyn G
authors.initials: EG
authors.lastname: Smith
authors.forename: Grant B
authors.initials: GB
authors.lastname: Webber
authors.forename: Kenichi
authors.initials: K
authors.lastname: Sakai
authors.forename: Simon
authors.initials: S
authors.lastname: Biggs
authors.forename: Steven P
authors.initials: SP
authors.lastname: Armes
authors.forename: Erica J
authors.initials: EJ
authors.lastname: Wanless