title: Crystal structures of poly(aryl ether) dendrons with palladium scorpionate complexes at their focal point.
abstract: Novel palladium(II) complexes with bis(pyrazol-1-yl)methane ligands at the focal point of G0-G3 poly(aryl ether) Fréchet-type dendrons are reported. The molecular structures of the metallodendrimer series G0, G1, and G2 [(dend)CH(3,5-Me2pz)2(PdCl2)] have been determined by X-ray diffraction methods. The three structures show a similar three-dimensional organization of the metal complex, which is progressively engulfed by the branches with increasing dendrimer generation.
authors.affiliation: Departamento de Química Inorgánica, Universidad de Alcalá, Campus Universitario, Madrid, Spain.
authors.forename: Alberto
authors.initials: A
authors.lastname: Sánchez-Méndez
authors.forename: Ernesto
authors.initials: E
authors.lastname: de Jesús
authors.forename: Juan C
authors.initials: JC
authors.lastname: Flores
authors.forename: Pilar
authors.initials: P
authors.lastname: Gómez-Sal