title: Study of the effect of DMSO on VOS odour production in a wastewater plant.
abstract: Odours caused by volatile organic sulphides (VOS) have a history spanning over 20 years for Philadelphia's Northeast Water Pollution Control Plant (NEWPCP). A "canned corn" type of odour has caused residential complaints. Traditional odour control approaches based on hydrogen sulphide failed. This study confirmed that dimethyl sulphoxide (DMSO) from a chemical facility was the dominant cause of the "canned corn" nuisance odour in the form of dimethyl sulphide (DMS). During a discharge, DMSO concentrations up to 12 mg/L were found in the influent of the NEWPCP. Each DMSO concentration peak induced a DMS peak. DMS concentrations increased from less than 50 microg/L to 6 mg/L with a corresponding decrease in DMSO. Approximately 79% of DMSO from the primary sedimentation influent was passed to the effluent, and to downstream processes, such as the aeration tanks where the DMS was volatilised by the aeration. The DMS partial pressure in ambient air of NEWPCP can be between 0.03 and 0.18 x 10(-3) atm during a DMSO discharge. From the above information, the potential of VOS production is estimated and a practical plan for remediation can be designed.
authors.affiliation: Bureau of Laboratory Services, Philadelphia Water Department, 1500 E. Hunting Park Ave. Philadelphia, PA 19124, USA. xianhao.cheng@phila.gov
authors.forename: X
authors.initials: X
authors.lastname: Cheng
authors.forename: E D
authors.initials: ED
authors.lastname: Peterkin
authors.forename: G A
authors.initials: GA
authors.lastname: Burlingame
mesh_terms: D004121:Dimethyl Sulfoxide / Q000032:analysis*; D004784:Environmental Monitoring; D009812:Odorants / Q000032:analysis*; D009930:Organic Chemicals / Q000032:analysis; D015143:Philadelphia; D012722:Sewage; D013440:Sulfides / Q000032:analysis; D014865:Waste Disposal, Fluid / Q000379:methods*; D014876:Water Pollution; D018508:Water Purification / Q000379:methods*
chemical_list: D009930:Organic Chemicals; D012722:Sewage; D013440:Sulfides; D004121:Dimethyl Sulfoxide