Highly selective thiiranation of 1,2-allenyl sulfones with Br2 and Na2S2O3: mechanism and asymmetric synthesis of alkylidenethiiranes.
Zhou
Chao
C
Laboratory of Molecular Recognition and Synthesis, Department of Chemistry, Zhejiang University, Hangzhou, 310027, Zhejiang, PR China.
Fu
Chunling
C
Ma
Shengming
S
D001966:Bromine / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013450:Sulfones / Q000737:chemistry*; D013885:Thiosulfates / Q000737:chemistry*
D013438:Sulfhydryl Compounds; D013450:Sulfones; D013885:Thiosulfates; C017717:sodium thiosulfate; D001966:Bromine