Storable, powdered chiral zirconium complex for asymmetric aldol and hetero Diels-Alder reactions.
A storable, powdered chiral zirconium catalyst for asymmetric aldol and hetero Diels-Alder reactions has been developed. The catalyst has the same activity as that prepared in situ even after being stored for 3 months. Moreover, this chiral Zr catalyst worked efficiently not only for asymmetric aldol reactions but also for asymmetric hetero Diels-Alder reactions affording the corresponding addition products with high enantioselectivities.
Seki
Kazutaka
K
Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo, 113-0033, Japan.
Ueno
Masaharu
M
Kobayashi
Shū
S
D000438:Alcohols / Q000737:chemistry*; D002384:Catalysis; D011208:Powders; D013237:Stereoisomerism; D013997:Time Factors; D015040:Zirconium / Q000737:chemistry*
D000438:Alcohols; D011208:Powders; D015040:Zirconium