title: Elucidation of the naproxen sodium adsorption onto activated carbon prepared from waste apricot: kinetic, equilibrium and thermodynamic characterization.
abstract: In this study, activated carbon (WA11Zn5) was prepared from waste apricot, which is waste in apricot plants in Malatya, by chemical activation with ZnCl(2). BET surface area of activated carbon is determined as 1060 m(2)/g. The ability of WA11Zn5, to remove naproxen sodium from effluent solutions by adsorption has been studied. Equilibrium isotherms for the adsorption of naproxen sodium on activated carbon were measured experimentally. Results were analyzed by the Langmiur, Freundlich equation using linearized correlation coefficient at 298 K. The characteristic parameters for each isotherm have been determined. Langmiur equation is found to best represent the equilibrium data for naproxen sodium-WA11Zn5 systems. The monolayer adsorption capacity of WA11Zn5 for naproxen sodium was found to be 106.38 mg/g at 298 K. The process was favorable and spontaneous. The kinetics of adsorption of naproxen sodium have been discussed using three kinetic models, i.e., the pseudo first-order model, the pseudo second-order model, the intraparticle diffusion model. Kinetic parameters and correlation coefficients were determined. It was shown that the pseudo second-order kinetic equation could describe the adsorption kinetics for naproxen sodium onto WA11Zn5. The thermodynamic parameters, such as DeltaG degrees , DeltaS degrees and DeltaH degrees, were calculated. The thermodynamics of naproxen sodium-WA11Zn5 system indicates endothermic process.
authors.affiliation: Inonu University, Faculty of Engineering, Department of Chemical Engineering, 44280 Malatya, Turkey. yonal@inonu.edu.tr
authors.forename: Y
authors.initials: Y
authors.lastname: Onal
authors.forename: C
authors.initials: C
authors.lastname: Akmil-Başar
authors.forename: C
authors.initials: C
authors.lastname: Sarici-Ozdemir
mesh_terms: D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D007700:Kinetics; D009288:Naproxen / Q000737:chemistry*; D027861:Prunus / Q000737:chemistry*; D013696:Temperature; D013816:Thermodynamics; D013997:Time Factors
chemical_list: D009288:Naproxen; D002244:Carbon