Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: I. from isolated cluster to 1-D chain.
The hydrothermal reactions of [A-alpha-SiW(9)O(34)](10-)/[A-alpha-PW(9)O(34)](9-) with NiCl(2) x 6H(2)O and amines yielded four unprecedented hybrid high-nuclear Ni-subsituted polyoxotungstates.
Zheng
Shou-Tian
ST
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian, 350002, China.
Yuan
Da-Qiang
DQ
Jia
Hong-Peng
HP
Zhang
Jie
J
Yang
Guo-Yu
GY
D000588:Amines / Q000737:chemistry; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003460:Crystallization; D018360:Crystallography, X-Ray; D008024:Ligands; D021241:Spectrometry, Mass, Electrospray Ionization; D028561:Transition Elements / Q000737:chemistry; D017973:Tungsten Compounds / Q000138:chemical synthesis*
D000588:Amines; D008024:Ligands; D028561:Transition Elements; D017973:Tungsten Compounds