title: Simultaneous conversion of CHClF(2) and CH(3)Br to CH(2)CF(2).
abstract: Gas phase reaction of CHClF(2) with CH(3)Br in an alumina tube reactor at 773-1123 K as a function of various input ratios of CH(3)Br to CHClF(2) is presented. The major products detected include C(2)F(4), CH(2)CF(2), and CH(4). Minor products include CH(3)Cl, CHF(3), C(2)H(4), C(2)H(2), CH(2)CF-CF(3), and C(2)H(3)F. The reaction produces a high yield of CH(2)CF(2) (53% based on CHClF(2) feed) at 1123 K and an input molar ratio of CH(3)Br to CHClF(2) of 1.8, suggesting that the reaction potentially can be developed as a process to convert two ozone depleting substances (CHClF(2) and CH(3)Br) to a highly valuable chemical, CH(2)CF(2). The reaction of CHClF(2) with CH(3)Cl and CH(3)I was also investigated under similar reaction conditions, to assist in understanding the reaction chemistry involved in the reaction of CHClF(2) with CH(3)Br.
authors.affiliation: Process Safety and Environment Protection Research Group, School of Engineering, The University of Newcastle, Callaghan, NSW 2308, Australia.
authors.forename: Hai
authors.initials: H
authors.lastname: Yu
authors.forename: Eric M
authors.initials: EM
authors.lastname: Kennedy
authors.forename: John C
authors.initials: JC
authors.lastname: Mackie
authors.forename: Bogdan Z
authors.initials: BZ
authors.lastname: Dlugogorski
mesh_terms: D005617:Chlorofluorocarbons, Methane / Q000737:chemistry*; D005466:Fluorocarbons / Q000737:chemistry*; D006842:Hydrocarbons, Brominated / Q000737:chemistry*
chemical_list: D005617:Chlorofluorocarbons, Methane; D005466:Fluorocarbons; D006842:Hydrocarbons, Brominated; C009755:fluorocarbon 22; C005218:methyl bromide