The active role of NHC ligands in platinum-mediated tandem hydroboration-cross coupling reactions.
Stable N-heterocyclic platinum-carbene complexes are the first example of platinum-mediated regioselective H-B addition to vinylarenes and alkynes, allowing consecutive cross coupling reactions with the same catalytic system.
Lillo
Vanesa
V
Departament de Química Física i Inorgànica. Universitat Rovira i Virgili, Pça, Imperial Tàrraco 1, 43005, Tarragona, Spain.
Mata
Jose A
JA
Segarra
Anna M
AM
Peris
Eduardo
E
Fernandez
Elena
E