Large magnetostriction and negative thermal expansion in the frustrated antiferromagnet ZnCr2Se4.
A detailed investigation of ZnCr2Se4 is presented which is dominated by strong ferromagnetic exchange but orders antiferromagnetically at TN=21 K. Specific heat and thermal expansion exhibit sharp first-order anomalies at the antiferromagnetic transition. TN is shifted to lower temperatures by external magnetic fields and finally is fully suppressed by a field of 65 kOe. The relative length change DeltaL/L(T) is unusually large and exhibits negative thermal expansion alpha below 75 K down to TN indicating strong frustration of the lattice. Magnetostriction DeltaL/L(H) reveals large values comparable to giant magnetostrictive materials. These results point to a spin-driven origin of the structural instability at TN explained in terms of competing ferromagnetic and antiferromagnetic exchange interactions.
Hemberger
J
J
Experimental Physics V, Center for Electronic Correlations and Magnetism, University of Augsburg, D-86159 Augsburg, Germany.
von Nidda
H-A Krug
HA
Tsurkan
V
V
Loidl
A
A