Slice imaging of the quantum state-to-state cross section for photodissociation of state-selected rovibrational bending states of OCS (v2=0,1,2/JlM)+hnu-->CO(J)+S(1D2).
Using hexapole quantum state-selection of OCS (v(2)=0,1,2/JlM) and high-resolution slice imaging of quantum state-selected CO(J), the state-to-state cross section OCS (v(2)=0,1,2/JlM)+hnu-->CO(J)+S((1)D(2)) was measured for bending states up to v(2)=2. The population density of the state-selected OCS (v(2)=0,1,2 /JlM) in the molecular beam was obtained by resonantly enhanced multiphoton ionization of OCS and comparison with room temperature bulk gas. A strong increase of the cross section with increasing bending state is observed for CO(J) in the high J region, J=60-67. Integrating over all J states the authors find sigma(v(2)=0):sigma(v(2)=1):sigma(v(2)=2)=1.0:7.0:15.0. A quantitative comparison is made with the dependence of the transition dipole moment function on the bending angle.
Lipciuc
M Laura
ML
Department of Chemistry, Laser Centre, Vrije Universiteit, de Boelelaan 1083, 1081 HV Amsterdam, The Netherlands.
Janssen
Maurice H M
MH