Prepared chiral nanorods of a cobalt(II) porphyrin dimer and studied changes of UV-Vis and CD spectra with aggregate morphologies under different temperatures.
Novel porphyrin dimer ligand and cobalt complexes by directly bridging with l-glutamic acid have been prepared and characterized. The intensities of circular dichroism and UV-vis spectra that change the aggregate morphologies of the porphyrin dimer under different temperatures have been investigated.
Guo
Xi ming
Xm
The Academy of Science and Technology, Harbin Institute of Technology, Heilongjiang 150001, People's Republic of China. ximing.guo@yahoo.com.cn
Jiang
Chang
C
Shi
Tong Shun
TS
D002942:Circular Dichroism; D003035:Cobalt; D019281:Dimerization; D018698:Glutamic Acid / Q000737:chemistry; D011166:Porphyrins / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet; D013696:Temperature
D011166:Porphyrins; D003035:Cobalt; D018698:Glutamic Acid