title: A novel 3D cyano-bridged mixed-valence CoII/CoIII canted antiferromagnet constructed from defective cubanes. Synthesis, X-ray structure and magnetic properties.
abstract: The hydrothermal reaction of 2-pyrimidine-carboxamide, CoCl2.6H(2)O and K3[Co(CN)6] affords a novel mixed-valence Co(II)/Co(III) 3D complex K[Co3(CN)6(ox)(H(2)O)2].H2O, which contains cyano-bridged Co(7) defective cubanes connected by oxalate and cyanide bridging groups and behaves as a canted antiferromagnet with Tc = 17.5 K.
authors.affiliation: Departamento de Química Inorgánica, Universidad de Granada, Avenida Fuente nueva s/n, 18071, Granada, Spain.
authors.forename: Antonio
authors.initials: A
authors.lastname: Rodríguez-Diéguez
authors.forename: Raikko
authors.initials: R
authors.lastname: Kivekäs
authors.forename: Hiroshi
authors.initials: H
authors.lastname: Sakiyama
authors.forename: Ahderrahmane
authors.initials: A
authors.lastname: Debdoubi
authors.forename: Enrique
authors.initials: E
authors.lastname: Colacio