title: Synthesis, structure, redox properties, and catalytic activity of new ruthenium complexes containing neutral or anionic and facial or meridional ligands: an evaluation of electronic and geometrical effects.
abstract: The synthesis of a family of new Ru complexes containing meridional or facial tridentate ligands with the general formula [Ru(II)(T)(D)(X)](n+) [T = 2,2':6',2' '-terpyridine or tripyrazolylmethane; D = 4,4'-dibenzyl-4,4',5,5'-tetrahydro-2,2'-bioxazole (S,S-box-C) or 2-[((1'S)-1'-(hydroxymethyl)-2'-phenyl)ethylcarboxamide]-(4S)-4-benzyl-4,5-dihydrooxazole (S,S-box-O); X = Cl, H(2)O, MeCN or pyridine] has been described. All complexes have been spectroscopically characterized in solution through (1)H NMR and UV-vis techniques. Furthermore, all of the chloro complexes presented here have also been characterized in the solid state through monocrystal X-ray diffraction analysis. The oxazolinic S,S-box-C ligands undergo a Ru-assisted hydrolysis reaction generating the corresponding amidate anionic oxazolinic ligands S,S-box-O, which are also strongly attached to the metal center and produce a strong sigma-donation effect over the Ru metal center. The redox properties of all complexes have also been studied by means of cyclic voltammetry, strongly reflecting the nature of the ligands; both effects, geometrical (facial vs meridional) and electronic (neutral vs anionic), can be unveiled and rationalized. Finally, the reactivity of the Ru-OH(2) complexes has been tested with regard to the epoxidation of trans-stilbene, and it has been shown that, in this particular case, the reactivity is practically not dependent on the redox potentials of the catalyst but, in sharp contrast, it is strongly dependent on the geometry of the tridentate ligands.
authors.affiliation: Departament de Química, Universitat de Girona, Campus de Montilivi, E-17071 Girona, Spain.
authors.forename: Isabel
authors.initials: I
authors.lastname: Serrano
authors.forename: Xavier
authors.initials: X
authors.lastname: Sala
authors.forename: Elena
authors.initials: E
authors.lastname: Plantalech
authors.forename: Montserrat
authors.initials: M
authors.lastname: Rodríguez
authors.forename: Isabel
authors.initials: I
authors.lastname: Romero
authors.forename: Susanna
authors.initials: S
authors.lastname: Jansat
authors.forename: Montserrat
authors.initials: M
authors.lastname: Gómez
authors.forename: Teodor
authors.initials: T
authors.lastname: Parella
authors.forename: Helen
authors.initials: H
authors.lastname: Stoeckli-Evans
authors.forename: Xavier
authors.initials: X
authors.lastname: Solans
authors.forename: Mercè
authors.initials: M
authors.lastname: Font-Bardia
authors.forename: Balamurugan
authors.initials: B
authors.lastname: Vidjayacoumar
authors.forename: Antoni
authors.initials: A
authors.lastname: Llobet