title: A rheo-optical apparatus for real time kinetic studies on shear-induced alignment of self-assembled soft matter with small sample volumes.
abstract: In soft materials, self-assembled nanoscale structures can allow new functionalities but a general problem is to align such local structures aiming at monodomain overall order. In order to achieve shear alignment in a controlled manner, a novel type of rheo-optical apparatus has here been developed that allows small sample volumes and in situ monitoring of the alignment process during the shear. Both the amplitude and orientation angles of low level linear birefringence and dichroism are measured while the sample is subjected to large amplitude oscillatory shear flow. The apparatus is based on a commercial rheometer where we have constructed a flow cell that consists of two quartz teeth. The lower tooth can be set in oscillatory motion whereas the upper one is connected to the force transducers of the rheometer. A custom made cylindrical oven allows the operation of the flow cell at elevated temperatures up to 200 degrees C. Only a small sample volume is needed (from 9 to 25 mm(3)), which makes the apparatus suitable especially for studying new materials which are usually obtainable only in small quantities. Using this apparatus the flow alignment kinetics of a lamellar polystyrene-b-polyisoprene diblock copolymer is studied during shear under two different conditions which lead to parallel and perpendicular alignment of the lamellae. The open device geometry allows even combined optical/x-ray in situ characterization of the alignment process by combining small-angle x-ray scattering using concepts shown by Polushkin et al. [Macromolecules 36, 1421 (2003)].
authors.affiliation: Department of Engineering Physics and Mathematics and Center for New Materials, Helsinki University of Technology, FI-02015 HUT, Espoo, Finland. ari.laiho@hut.fi
authors.forename: Ari
authors.initials: A
authors.lastname: Laiho
authors.forename: Olli
authors.initials: O
authors.lastname: Ikkala
mesh_terms: D004548:Elasticity; D007700:Kinetics; D046210:Microfluidic Analytical Techniques / Q000295:instrumentation; D055095:Optics and Photonics; D015203:Reproducibility of Results; D033081:Shear Strength