A liquid-phase approach to functionalized Janus dendrimers: novel soluble supports for organic synthesis.
A new kind of functionalized Janus dendrimer has been synthesized via a liquid-phase approach, which could easily be purified using a simple precipitation method without the need for chromatographic separation. Their use for liquid-phase organic synthesis has been achieved in the Pd-catalyzed Suzuki coupling reactions, giving biaryl products in excellent yields after cleavage.
Feng
Yu
Y
Beijing National Laboratory for Molecular Sciences, Center for Chemical Biology, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China.
He
Yan-Mei
YM
Zhao
Li-Wen
LW
Huang
Yi-Yong
YY
Fan
Qing-Hua
QH
D002384:Catalysis; D050091:Dendrimers / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009930:Organic Chemicals / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry; D012995:Solubility; D012997:Solvents / Q000737:chemistry
D050091:Dendrimers; D009930:Organic Chemicals; D012997:Solvents; D010165:Palladium