Equilibrium studies of sorption of lead(II) ions by different pectin compounds.
The adsorption of Pb(II) ions from aqueous solution by different pectin compounds was studied in a batch sorption system. Water-soluble low- and high-esterified pectins and insoluble calcium pectate beads were investigated. The lead-binding capacity of all pectin compounds was highest within the pH range from 7 to 8. The binding capacities and rates of Pb(II) ions by pectin compounds were evaluated. The Langmuir, Freundlich and BET sorption models were applied to describe the isotherms and isotherm constants. Sorption isothermal data could be well interpreted by the Langmuir model. These results obtained through the study suggest that pectin compounds are favorable sorbers. The largest amount of Pb(II) ions were bound by pectin with the low degree of esterfication. Therefore, pectin substances may be considered as perspective for sorption and removal of Pb(II) ions from wastewaters.
Khotimchenko
Maxim
M
Department of Pharmacy, Vladivostok State Medical University, 2 Ostryakova Ave., Vladivostok 690990, Russia. maxkhot@stl.ru
Kovalev
Valeri
V
Khotimchenko
Yuri
Y
D000327:Adsorption; D002627:Chemistry, Physical / Q000379:methods; D006863:Hydrogen-Ion Concentration; D007477:Ions; D007854:Lead / Q000032:analysis* / Q000737:chemistry; D019216:Metals, Heavy / Q000737:chemistry*; D008956:Models, Chemical; D010368:Pectins / Q000737:chemistry*; D013696:Temperature; D013816:Thermodynamics; D014865:Waste Disposal, Fluid / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000032:analysis*; D018508:Water Purification / Q000379:methods*
D007477:Ions; D019216:Metals, Heavy; D014874:Water Pollutants, Chemical; D007854:Lead; D010368:Pectins