Synthesis of bulky phosphines by rhodium-catalyzed formal [2+2+2] cycloaddition reactions of tethered diynes with 1-alkynylphosphine sulfides.
Kondoh
Azusa
A
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoto-daigaku Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
Yorimitsu
Hideki
H
Oshima
Koichiro
K
D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D009281:Naphthalenes / Q000737:chemistry; D010720:Phosphines / Q000138:chemical synthesis* / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry; D013440:Sulfides / Q000737:chemistry
D000480:Alkynes; C406943:BINAP, 2-naphthol; D009281:Naphthalenes; D010720:Phosphines; D013440:Sulfides; D012238:Rhodium