title: Relativistic correlating basis sets for actinide atoms from 90Th to 103Lr.
abstract: For 14 actinide atoms from (90)Th to (103)Lr, contracted Gaussian-type function sets are developed for the description of correlations of the 5f, 6d, and 7s electrons. Basis sets for the 6d orbitals are also prepared, since the orbitals are important in molecular environments despite their vacancy in the ground state of some actinides. A segmented contraction scheme is employed for the compactness and efficiency. Contraction coefficients and exponents are so determined as to minimize the deviation from accurate natural orbitals of the lowest term arising from the 5f(n-1)6d(1)7s(2) configuration. The spin-free relativistic effects are considered through the third-order Douglas-Kroll approximation. To test the present correlating sets, all-electron calculations are performed on the ground state of (90)ThO molecule. The calculated spectroscopic constants are in excellent agreement with experimental values.
authors.affiliation: Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, Hokkaido, Japan. tashi@sci.hokduai.ac.jp
authors.forename: Takeshi
authors.initials: T
authors.lastname: Noro
authors.forename: Masahiro
authors.initials: M
authors.lastname: Sekiya
authors.forename: You
authors.initials: Y
authors.lastname: Osanai
authors.forename: Toshikatsu
authors.initials: T
authors.lastname: Koga
authors.forename: Hisashi
authors.initials: H
authors.lastname: Matsuyama
mesh_terms: D008671:Actinoid Series Elements / Q000737:chemistry*; D003198:Computer Simulation; D004583:Electrons; D007852:Lawrencium / Q000737:chemistry*; D011789:Quantum Theory; D013910:Thorium / Q000737:chemistry*
chemical_list: D008671:Actinoid Series Elements; D013910:Thorium; D007852:Lawrencium