title: Heterogeneous diffusion in a reversible gel.
abstract: We introduce a microscopically realistic model of a physical gel and use computer simulations to study its static and dynamic properties at thermal equilibrium. The phase diagram comprises a sol phase, a coexistence region ending at a critical point, a gelation line determined by geometric percolation, and an equilibrium gel phase unrelated to phase separation. The global structure of the gel is homogeneous, but the stress is only supported by a fractal network. The gel dynamics is highly heterogeneous and we propose a theoretical model to quantitatively describe dynamic heterogeneity in gels. We elucidate several differences between the dynamics of gels and that of glass formers.
authors.affiliation: Laboratoire des Colloïdes, Verres et Nanomatériaux, UMR 5587, Université Montpellier II and CNRS, Montpellier 34095, France.
authors.forename: Pablo I
authors.initials: PI
authors.lastname: Hurtado
authors.forename: Ludovic
authors.initials: L
authors.lastname: Berthier
authors.forename: Walter
authors.initials: W
authors.lastname: Kob