title: Reversible structural isomerisation in rare thioether complexes of cobalt(II)--effects of ligand architecture.
abstract: Rare examples of (high spin) Co(II) complexes with geometrically constrained tetrathioether ligands exhibit a very unusual structural isomerism, switching reversibly between tetrahedral monomers in solution and octahedral chain polymers in the solid; the crystal structures of one polymeric species and a tetrahedral monomer model compound are described.
authors.affiliation: School of Chemistry, University of Southampton, Highfield, Southampton, UKSO17 1BJ.
authors.forename: John
authors.initials: J
authors.lastname: Evans
authors.forename: William
authors.initials: W
authors.lastname: Levason
authors.forename: Joanna M
authors.initials: JM
authors.lastname: Manning
authors.forename: Gillian
authors.initials: G
authors.lastname: Reid
authors.forename: Nikolaos
authors.initials: N
authors.lastname: Tsoureas
authors.forename: Michael
authors.initials: M
authors.lastname: Webster