Identification of organic acids in bayer liquors by GC-MS: a comparison using butylation and methylation.
Two well known derivatization methods, butylation and methylation, are compared by gas chromatography (GC)-mass spectrometry (MS) to identify organic acids in Bayer liquors. These two derivatization methods should be combined together for the determination of the carboxylic acids. Twenty-four organic acids are identified by GC-MS and 13 organic acids are firstly found in Bayer liquors. The retention times and the carbon number of these seven n-dicarboxylic acids (C(4)-C(10)) are fit into the linear relationship in Microsoft Excel.
Xiao
Jian Bo
JB
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, PR China.
Jiang
Xin Yu
XY
Chen
Xiao Qing
XQ