A ketone oximate based cyclic cationic [Ni(II)4] inverse metallacrown from simultaneous chelation and bridging of two ligands.
The Ni(4) inverse metallacrown (NHEt(3)) [Ni(4)(bmo)4(Hael)2(ael)2](ClO(4))3 [(NHEt(3)).1.(ClO(4))3], with the inverse 12-MC-4 motif, has been assembled via simultaneous chelation and bridging of butan-2,3-dionemonoxime (Hbmo) and 2-amino ethanol (Hael).
Mandal
Debashree
D
Department of Chemistry, Indian Institute of Technology, Kharagpur, 721 302, India.
Bertolasi
Valerio
V
Aromí
Guillem
G
Ray
Debashis
D
D000605:Amino Alcohols / Q000737:chemistry; D002413:Cations, Divalent; D002614:Chelating Agents / Q000737:chemistry*; D004852:Epoxy Compounds / Q000737:chemistry; D004988:Ethers, Cyclic / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010091:Oximes / Q000737:chemistry*; D013696:Temperature
D000605:Amino Alcohols; D002413:Cations, Divalent; D002614:Chelating Agents; D004852:Epoxy Compounds; D004988:Ethers, Cyclic; D007659:Ketones; D008024:Ligands; D009942:Organometallic Compounds; D010091:Oximes; C007366:diepoxybutane; D009532:Nickel