Synthesis and structural characterisation of the first N-heterocyclic carbene ligand fused to a porphyrin.
The functionalisation of two neighboring beta-pyrrolic positions of a porphyrin by a fused N-heterocyclic carbene ligand, the subsequent metallation of this external coordination site by palladium(II) and the structural characterisation of the resulting compounds are presented.
Richeter
Sébastien
S
Institut Charles Gerhardt, UM2, CNRS, équipe CMOS, CC 007, Université Montpellier 2, Place Eugène Bataillon, 34095, Montpellier Cedex 05, France. Sebastien.Richeter@univ-montp2.fr
Hadj-Aïssa
Aurélie
A
Taffin
Céline
C
van der Lee
Arie
A
Leclercq
Dominique
D
D018360:Crystallography, X-Ray; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006838:Hydrocarbons / Q000138:chemical synthesis / Q000737:chemistry; D008024:Ligands; D008697:Methane / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*
D006571:Heterocyclic Compounds; D006838:Hydrocarbons; D008024:Ligands; D011166:Porphyrins; C030011:carbene; D009584:Nitrogen; D008697:Methane