Factors influencing the selectivity in asymmetric oxidation of sulfides attached to nitrogen containing heterocycles.
Asymmetric oxidation of heterocyclic sulfides, including imidazole, benzimidazole, indole and pyrimidine derivatives, were studied using a tartrate/Ti((i)OPr)4 catalyst system.
Seenivasaperumal
Muthu
M
Stockholm University, Arrhenius Laboratory, Department of Organic Chemistry, Sweden.
Federsel
Hans-Jürgen
HJ
Ertan
Anne
A
Szabó
Kálmán J
KJ
D002384:Catalysis; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D010084:Oxidation-Reduction; D013440:Sulfides / Q000737:chemistry*
D006571:Heterocyclic Compounds; D013440:Sulfides; D009584:Nitrogen