[Establishment and melting of charge ordering in La0.3Ca0.7Mn(1-x)W(x)O3 system].
Polycrystalline samples of La0.3Ca0.7Mn(1-x)W(x)O3 (0.00 < or = x < or = 0.15) were prepared by conventional solid-state reaction method. The influence of W doping at Mn site on the magnetic transition of La0.3Ca0.7Mn(1-x)W(x)O3 system was studied by the measurements of magnetization-temperature (MT) curves, magnetization-magnetic intensity (MH) curves, and ESR spectra. The results show that, with the increase in W doping amount, the magnetic transition of the system exhibits a complicated charge process, when the doping amount is 0.00 < or = x < or = 0.08, the charge-ordering (CO) phase exists in the system, AFM/CO states coexist below the transition temperature, and the charge-ordering temperature (Tco) goes up with the increase in W doping content; when x > or = 0.12, the charge ordering (CO) state of the system weakens and melts, and paramagnetism-ferromagnetism (PM-FM) transition exists at extremely low temperature.
Cai
Zhi-rang
ZR
Materials Research Laboratory, Suzhou College, Suzhou 234000, China. caizr3680760@163.com
Guo
Huan-yin
HY
Liu
Ning
N
Zhang
Yu-heng
YH