Unprecedented optically induced long-lived intramolecular electron transfer in cobalt-dioxolene complexes.
The observation of very long lifetimes of the metastable states of two cobalt-dioxolene complexes undergoing photoinduced and high T(c) thermally-induced valence tautomer interconversion opens new research perspectives.
Beni
Alessandra
A
INSTM Research Unit and Dipartimento di Chimica Università di Firenze, Via della Lastruccia 3, 50019, Sesto Fiorentino, Firenze, Italy.
Dei
Andrea
A
Rizzitano
Mario
M
Sorace
Lorenzo
L