Diamidonaphthalene-supported pnictogenium cations: synthesis of an N-heterocyclic stibenium cation by a novel protonation route.
A 1,8-bis(alkylamido)naphthalene framework has been applied to the construction of N-heterocyclic arsenium and stibenium cations; a novel synthetic route, involving protonation of an ancillary amido ligand, was used to generate the base-stabilized stibenium cation.
Spinney
Heather A
HA
Department of Chemistry and Center for Catalysis Research and Innovation, University of Ottawa, Ottawa, Ontario, CanadaK1N 6N5.
Korobkov
Ilia
I
Richeson
Darrin S
DS