title: Highly stereoselective 6pi electrocyclization of bridged bicyclic 1,3,5-trienes.
abstract: Conjugated 1,3,5-hexatrienes encased in bridged bicyclic skeletons are prepared by cross-coupling followed by half-reduction of the resulting dienynes. The trienes undergo 6pi electrocyclization at an ambient or elevated temperature to furnish complex, polycyclic cyclohexadienes. In all cases, complete selectivity in favor of cyclization from the exo face of the bridged bicyclic system was seen, in contrast to the corresponding 4pi Nazarov cyclizations.
authors.affiliation: Department of Chemistry, University of Alberta, Edmonton, AB, Canada T6G 2G2.
authors.forename: Chantel L
authors.initials: CL
authors.lastname: Benson
authors.forename: F G
authors.initials: FG
authors.lastname: West