title: Effects of operating parameters on advanced oxidation of diuron by the Fenton's reagent: a statistical design approach.
abstract: Advanced oxidation of diuron in aqueous solution by Fenton's reagent using FeSO(4) as source of Fe(II) was investigated in the absence of light. Effects of operating parameters namely the concentrations of pesticide (diuron), H(2)O(2) and Fe(II) on oxidation of diuron was investigated by using Box-Behnken statistical experiment design and the surface response analysis. Diuron oxidation by the Fenton reagent was evaluated by determining the total organic carbon (TOC), diuron, and adsorbable organic halogen (AOX) removals. Concentration ranges of the reagents resulting in the highest level of diuron oxidation were determined. Diuron removal increased with increasing H(2)O(2) and Fe(II) concentrations up to a certain level. Diuron concentration had a more profound effect than H(2)O(2) and Fe(II) in removal of diuron, TOC and AOX from the aqueous solution. Nearly complete (98.5%) disappearance of diuron was achieved after 15min reaction period. However, only 58% of diuron was mineralized after 240min under optimal operating conditions indicating formation of some intermediate products. Optimal H(2)O(2)/Fe(II)/diuron ratio resulting in the maximum diuron removal (98.5%) was found to be 302/38/20 (mgl(-1)).
authors.affiliation: Department of Environmental Engineering, Dokuz Eylul University, Buca, Izmir, Turkey.
authors.forename: Ebru Cokay
authors.initials: EC
authors.lastname: Catalkaya
authors.forename: Fikret
authors.initials: F
authors.lastname: Kargi
mesh_terms: D002851:Chromatography, High Pressure Liquid; D004237:Diuron / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D010084:Oxidation-Reduction; D013056:Spectrophotometry, Ultraviolet
chemical_list: C045076:Fenton's reagent; D004237:Diuron; D006861:Hydrogen Peroxide; D007501:Iron