A tightly coupled bis(zinc(II) phthalocyanine)-perylenediimide ensemble to yield long-lived radical ion pair states.
A conjugated donor-acceptor array composed of two phthalocyanines connected to the bay region of a perylenediimide is assembled by using palladium chemistry. Excitation of the phthalocyanine produces a nanosecond lived charge-separated state.
Jiménez
Angel J
AJ
Departamento de Química OrgAnica, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049-Madrid, Spain.
Spänig
Fabian
F
Rodríguez-Morgade
M Salomé
MS
Ohkubo
Kei
K
Fukuzumi
Shunichi
S
Guldi
Dirk M
DM
Torres
Tomás
T