title: Magnetic canting or not? Two isomorphous 3D CoII and NiII coordination polymers with the rare non-interpenetrated (10,3)-d topological network, showing spin-canted antiferromagnetism only in the CoII system.
abstract: The in situ solvothermal reaction of 3,4-dicyano-1,2,5-thiadiazole with MCl(2) (M = Co, Ni) and NaOH afforded two isomorphous complexes, [M2(L)2(H(2)O)2]n (L = 2,1,3-thiadiazole-4,5-dicarboxylate), which exhibit a rare non-interpenetrated (10,3)-d (utp) network topology and interesting magnetic behaviors: spin-canted antiferromagnetism for the Co(II) complex, but simple antiferromagnetic coupling for the Ni(II).
authors.affiliation: Department of Chemistry, Nankai University, Tianjin 300071, China.
authors.forename: Jian-Rong
authors.initials: JR
authors.lastname: Li
authors.forename: Qun
authors.initials: Q
authors.lastname: Yu
authors.forename: Ying
authors.initials: Y
authors.lastname: Tao
authors.forename: Xian-He
authors.initials: XH
authors.lastname: Bu
authors.forename: Joan
authors.initials: J
authors.lastname: Ribas
authors.forename: Stuart R
authors.initials: SR
authors.lastname: Batten