title: Addition of difluoromethyl radicals to glycals: a new route to alpha-CF2-D-glycosides.
abstract: The synthesis of synthetically useful alpha-CF2-glycosides by radical addition of ethyl bromodifluoroacetate onto 2-benzyloxyglycals is described. The methodology provides an access to alpha-O-glycoside mimics and, potentially, to valuable alpha-O-glycoconjugate analogues.
authors.affiliation: Laboratoire d'Hétérochimie Organique, UMR 6014 CNRS, IRCOF, INSA et Université de Rouen, 1 rue Tesnière, 76821 Mont Saint-Aignan Cedex, France.
authors.forename: Benjamin
authors.initials: B
authors.lastname: Moreno
authors.forename: Cindy
authors.initials: C
authors.lastname: Quehen
authors.forename: Maureen
authors.initials: M
authors.lastname: Rose-Hélène
authors.forename: Eric
authors.initials: E
authors.lastname: Leclerc
authors.forename: Jean-Charles
authors.initials: JC
authors.lastname: Quirion