Large area, molecularly smooth (0.2 nm rms) gold films for surface forces and other studies.
Using large-area (cm2) single-crystal mica sheets as the templating substrate, we have created correspondingly large template-stripped (TS) gold films (thickness 82 +/- 2 nm) that appear smooth to within 0.2 nm rms roughness over their entire area. These gold films, created without the use of any releasing solvent, are characterized using AFM, X-ray diffraction, multiple beam interferometric fringes of equal chromatic order (FECO), and contact angle measurements. Being molecularly smooth over large areas and (adjustably) semitransparent, these films are especially suitable for use in the surface force balance (SFB), as shown by measurements of the normal force (F) versus distance (D) profiles between such a flat gold surface and a bare mica surface in water. The F(D) profiles are in good agreement with DLVO theory down to molecular contact and indicate that the gold surface is negatively charged under water.
Chai
Liraz
L
Department of Materials and Interfaces, Weizmann Institute of Science, Rehovot 76100, Israel.
Klein
Jacob
J