Coding a coordination-driven self-assembly via a hydrogen bond-directed solid-state synthesis: an unexpected chiral tetrahedral capsule.
An achiral ligand, synthesized in the solid state via a coded hydrogen bond-directed organic synthesis, self-assembles with Cu(II) ions to form a chiral tetrahedral capsule that hosts an anion as a guest.
Hamilton
Tamara D
TD
University of Iowa, Department of Chemistry, Iowa City, IA 52242-1294, USA.
Bucar
Dejan-Kresimir
DK
MacGillivray
Leonard R
LR
D000838:Anions / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009930:Organic Chemicals / Q000138:chemical synthesis* / Q000737:chemistry*; D013237:Stereoisomerism
D000838:Anions; D008024:Ligands; D009930:Organic Chemicals; D003300:Copper