Kinetic and adsorption study of acid dye removal using activated carbon.
The adsorption of three acid dyes, Acid Red 97, Acid Orange 61 and Acid Brown 425 onto activated carbon was studied for the removal of acid dyes from aqueous solutions at room temperature (25 degrees C). The adsorption of each dye with respect to contact time was then measured to provide information about the adsorption characteristics of activated carbon. The rates of adsorption were found to conform to the pseudo-second-order kinetics with a good correlation. The experimental isotherms obtained, except for Acid Orange 61 studied in mixture, were of the S-type in terms of the classification of Giles and co-workers. The best fit of the adsorption isotherm data was obtained using the Freundlich model. When a comparative study was made of the results obtained with single and mixed dyes, it can be seen that some of them affect others and modify their behavior in the adsorption process. The results indicate that activated carbon could be employed for the removal of dyes from wastewater.
Gómez
V
V
Analytical and Organic Chemistry Department, Rovira i Virgili University, Marcel-lí Domingo, s/n. Campus Sescelades, 43007 Tarragona, Spain.
Larrechi
M S
MS
Callao
M P
MP
D000143:Acids / Q000737:chemistry / Q000302:isolation & purification; D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry* / Q000302:isolation & purification*; D007220:Industrial Waste; D007700:Kinetics; D013696:Temperature; D014865:Waste Disposal, Fluid; D014874:Water Pollutants, Chemical / Q000737:chemistry* / Q000302:isolation & purification*
D000143:Acids; D004396:Coloring Agents; D007220:Industrial Waste; D014874:Water Pollutants, Chemical; D002244:Carbon