Beyond classical coordination: silver-pi interactions in metal dipyrrin complexes.
Homo- and hetero-leptic Zn and Cu complexes of dipyrrin type ligands bearing mono- and di-cyanophenyl groups when combined with silver cations lead to the formation of Ag(I)-C=C double bond interactions unprecedented in the crystalline phase.
Salazar-Mendoza
Domingo
D
Laboratoire de Chimie de Coordination Organique (UMR 7140), Université Louis Pasteur, Institut Le Bel, 4 rue Blaise Pascal, 67000, Strasbourg, France.
Baudron
Stéphane A
SA
Hosseini
Mir Wais
MW