Facile S(N)2' coupling reactions of wittig reagents with dimethyl bromomethylfumarate: synthesis of enes, dienes, and related natural products.
A new simple and efficient synthetic protocol with an ample scope has been demonstrated, by employing S(N)2' coupling reactions of a variety of Wittig reagents with dimethyl bromomethylfumarate to obtain the corresponding enes, dienes, and related natural and unnatural products.
Patel
Ramesh M
RM
Division of Organic Chemistry (Synthesis), National Chemical Laboratory, Pune 411 008, India.
Argade
Narshinha P
NP
D001688:Biological Products / Q000737:chemistry*; D005650:Fumarates / Q000138:chemical synthesis / Q000737:chemistry*; D005663:Furans / Q000737:chemistry*; D006842:Hydrocarbons, Brominated / Q000138:chemical synthesis / Q000737:chemistry*; D008745:Methylation; D015394:Molecular Structure; D013237:Stereoisomerism
D001688:Biological Products; D005650:Fumarates; D005663:Furans; D006842:Hydrocarbons, Brominated; C522528:dimethyl bromomethylfumarate