title: First isolation and kinetic study of hypervalent 10-As-5 organoarsenic compounds with a C-apical, O-equatorial configuration.
abstract: Hypervalent organoarsenic compounds violating the apicophilicity concept were isolated for the first time, and the energy of isomerization of these arsoranes to the more stable stereoisomers appeared to be lower than that of the phosphorus analogues based on the kinetic studies.
authors.affiliation: Department of Chemistry, Graduate School of Science, Hiroshima University, 1-3-1 Kagamiyama, Higashi-hiroshima 739-8526, Japan.
authors.forename: Xin-Dong
authors.initials: XD
authors.lastname: Jiang
authors.forename: Shiro
authors.initials: S
authors.lastname: Matsukawa
authors.forename: Hideaki
authors.initials: H
authors.lastname: Yamamichi
authors.forename: Yohsuke
authors.initials: Y
authors.lastname: Yamamoto