Removal of an anionic dye by adsorption/precipitation processes using alkaline white mud.
Alkaline white mud (AWM) has been investigated as a low-cost material for removal of an anionic dye, acid blue 80. The effects of contact time, initial pH of dye solution, AWM dosage, and the presence of inorganic anion sulphate or phosphate ion on removal of the dye were evaluated. The results show that AWM could be used as an effective material for removal of acid blue 80 in a pre or main process, particularly at high dye concentration (>300 mgL(-1)), reaching maximum removal efficiency of 95%. At low dye concentration, surface adsorption is mainly responsible for the dye removal, while chemical precipitation of the dye anions with soluble Ca(2+) and Mg(2+) may play a dominant role for the dye removal at high concentration, producing much less sludge than conventional adsorption method. Solution pH has only a limited effect on the dye removal due to high alkalinity and large pH buffer capacity of AWM suspension and thereby pH is not a limiting factor in pursuing high dye removal. The presence of SO(4)(2-) could reduce the dye removal by AWM only when SO(4)(2-) concentration is beyond 0.7 mmolL(-1). The dye removal may be significantly suppressed by the presence of phosphate with increasing concentration, and the reduction in the dye removal is much larger at high dye concentrations than at low ones.
Zhu
Mao-Xu
MX
Department of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, PR China. zhumaoxu@ouc.edu.cn
Lee
Li
L
Wang
Hai-Hua
HH
Wang
Zheng
Z
D000327:Adsorption; D000838:Anions / Q000737:chemistry*; D000880:Anthraquinones / Q000032:analysis* / Q000737:chemistry; D002118:Calcium / Q000032:analysis*; D004396:Coloring Agents / Q000032:analysis / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D007477:Ions; D008274:Magnesium / Q000032:analysis*; D008956:Models, Chemical; D010087:Oxides / Q000737:chemistry*; D010710:Phosphates / Q000737:chemistry*; D012722:Sewage; D013431:Sulfates / Q000737:chemistry*; D013457:Sulfur Compounds / Q000737:chemistry*; D013696:Temperature; D018508:Water Purification / Q000379:methods*
D000838:Anions; D000880:Anthraquinones; D004396:Coloring Agents; D007477:Ions; D010087:Oxides; D010710:Phosphates; D012722:Sewage; D013431:Sulfates; D013457:Sulfur Compounds; C405951:sulfur monoxide; C433873:acid blue 80; D008274:Magnesium; D002118:Calcium