title: Pyrolysis comprehensive two-dimensional gas chromatography study of petroleum source rock.
abstract: Detailed compositional analyses of sedimentary organic matter can provide information on its biotic input, environment of deposition, and level of thermal maturation. Pyrolysis-gas chromatography (py-GC), often coupled with a mass spectrometer (py-GC/MS), is one technique used to provide this information. New developments in comprehensive two-dimensional gas chromatography (GC x GC or 2D-GC), coupled with pyrolysis (py-GC x GC), offer the prospect of providing more complete and quantitative compositional information of complex organic solids, such as kerogen and coals. This study will describe applications of pyrolysis-GC x GC to the characterization of petroleum source rocks using flame ionization detector (FID) and sulfur chemiluminescence detector (SCD). In the hydrocarbon analysis by FID, paraffins, naphthenes, and aromatics form distinct two-dimensional separated groups. In the analysis with SCD, sulfur-containing compounds can be distinguished as different classes, such as mercaptans, sulfides, thiophenes, benzothiophenes, and dibenzothiophenes. Single components or summed bands of homologous components can be analyzed qualitatively and quantitatively. With these detailed molecular fingerprints, the relations between kerogen composition and its biotic input, environment of deposition, and thermal maturation may be better understood.
authors.affiliation: Corporate Strategic Research, ExxonMobil Research and Engineering Company, 1545 Route 22 East, Annandale, New Jersey 08801, USA.
authors.forename: Frank Cheng-Yu
authors.initials: FC
authors.lastname: Wang
authors.forename: Clifford C
authors.initials: CC
authors.lastname: Walters
mesh_terms: D002849:Chromatography, Gas / Q000379:methods*; D003031:Coal / Q000032:analysis*; D017745:Incineration; D008906:Mining; D010578:Petroleum / Q000032:analysis*; D015203:Reproducibility of Results; D013438:Sulfhydryl Compounds / Q000032:analysis; D013440:Sulfides / Q000032:analysis; D013457:Sulfur Compounds / Q000032:analysis*; D013876:Thiophenes / Q000032:analysis; D013997:Time Factors
chemical_list: D003031:Coal; D010578:Petroleum; D013438:Sulfhydryl Compounds; D013440:Sulfides; D013457:Sulfur Compounds; D013876:Thiophenes