Formation of stable enols from 1,4-dilithio-1,3-dienes and acid chlorides by a de-aromatization/Michael addition/re-aromatization domino process.
Stable enols were synthesized from the reaction of (1Z,3Z)-1,4-dilithio-1,3-dienes with acid chlorides and structurally characterized by single-crystal X-ray analysis. These stable enols were formed by a novel de-aromatization/Michael addition/re-aromatization domino process.
Hu
Qiaoshu
Q
Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry, Peking University, Beijing, 100871, China.
Wang
Chao
C
Li
Dongzhen
D
Xi
Zhenfeng
Z
D000143:Acids / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D013438:Sulfhydryl Compounds / Q000737:chemistry*
D000143:Acids; D002712:Chlorides; D013438:Sulfhydryl Compounds