Absorption flattening as one cause of distortion of circular dichroism spectra of Delta-RuPhen3 . H2TPPS complex.
To extend the model that explains why and how much absorption flattening (AF) influences circular dichroism (CD) signals, we have investigated the interesting case of exciton CD in the Soret region of a noncovalent complex formed by (Delta-RuPhen(3))(2+) and the tetraanionic porphyrin H(2)TPPS. Different concentrations have been studied by using an AF emulator and spectra simulation. The CD spectra of this compound occasionally show distortions in the solution sampling mode with the increase of concentration; the inhomogeneous distribution in the cell volume is due to aggregation and is the source of the AF effect. On the basis of these results, we conclude that AF is an important cause of distortions in CD spectra for Delta-RuPhen(3) . H(2)TPPS complexes and might affect the CD bands of other aggregated systems as well.
Castiglioni
Ettore
E
JASCO Corporation, Hachioji-shi, Tokyo, Japan. ettore.castiglioni@jasco-europe.com
Abbate
Sergio
S
Longhi
Giovanna
G
Gangemi
Roberto
R
Lauceri
Rosaria
R
Purrello
Roberto
R
D002942:Circular Dichroism; D009942:Organometallic Compounds / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013053:Spectrophotometry; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism
C429764:5,10,15-tris(4-sulfonatophenyl)-20-phenylporphryin; D009942:Organometallic Compounds; D010618:Phenanthrolines; D011166:Porphyrins; C034282:tris-(1,10-phenanthroline)ruthenium; D012428:Ruthenium