Simple glycosylation reaction of allyl glycosides.
A simple glycosylation strategy employing only allyl glycosides is described. In a one-pot fashion, an allyl glycoside is first isomerized to the reactive 1-prop-en-yl glycoside intermediate, which subsequently undergoes glycosylation with a glycosyl acceptor, promoted by NIS at room temperature.
Wang
Pengfei
P
Department of Chemistry, University of Alabama at Birmingham, Birmingham, AL 35294, USA. wangp@uab.edu
Haldar
Pranab
P
Wang
Yun
Y
Hu
Huayou
H
D006027:Glycosides / Q000737:chemistry*; D006031:Glycosylation; D009682:Magnetic Resonance Spectroscopy; D021241:Spectrometry, Mass, Electrospray Ionization; D017550:Spectroscopy, Fourier Transform Infrared
D006027:Glycosides