title: Channel flow and trichloroethylene treatment in a partly iron-filled fracture: experimental and model results.
abstract: Technical developments have now made it possible to emplace granular zero-valent iron (Fe(0)) in fractured media to create a Fe(0) fracture reactive barrier (Fe(0) FRB) for the treatment of contaminated groundwater. To evaluate this concept, we conducted a laboratory experiment in which trichloroethylene (TCE) contaminated water was flushed through a single uniform fracture created between two sandstone blocks. This fracture was partly filled with what was intended to be a uniform thickness of iron. Partial treatment of TCE by iron demonstrated that the concept of a Fe(0) FRB is practical, but was less than anticipated for an iron layer of uniform thickness. When the experiment was disassembled, evidence of discrete channelised flow was noted and attributed to imperfect placement of the iron. To evaluate the effect of the channel flow, an explicit Channel Model was developed that simplifies this complex flow regime into a conceptualised set of uniform and parallel channels. The mathematical representation of this conceptualisation directly accounts for (i) flow channels and immobile fluid arising from the non-uniform iron placement, (ii) mass transfer from the open fracture to iron and immobile fluid regions, and (iii) degradation in the iron regions. A favourable comparison between laboratory data and the results from the developed mathematical model suggests that the model is capable of representing TCE degradation in fractures with non-uniform iron placement. In order to apply this Channel Model concept to a Fe(0) FRB system, a simplified, or implicit, Lumped Channel Model was developed where the physical and chemical processes in the iron layer and immobile fluid regions are captured by a first-order lumped rate parameter. The performance of this Lumped Channel Model was compared to laboratory data, and benchmarked against the Channel Model. The advantages of the Lumped Channel Model are that the degradation of TCE in the system is represented by a first-order parameter that can be used directly in readily available numerical simulators.
authors.affiliation: Groundwater Protection and Restoration Group, Kroto Research Institute, University of Sheffield, Sheffield S3 7HQ, UK. zu.cai@sheffield.ac.uk
authors.forename: Zuansi
authors.initials: Z
authors.lastname: Cai
authors.forename: Corrine
authors.initials: C
authors.lastname: Merly
authors.forename: Neil R
authors.initials: NR
authors.lastname: Thomson
authors.forename: Ryan D
authors.initials: RD
authors.lastname: Wilson
authors.forename: David N
authors.initials: DN
authors.lastname: Lerner
mesh_terms: D002713:Chlorine / Q000737:chemistry; D003198:Computer Simulation; D004867:Equipment Design; D007501:Iron / Q000737:chemistry*; D015233:Models, Statistical; D008962:Models, Theoretical; D016062:Porosity; D012997:Solvents; D013997:Time Factors; D014241:Trichloroethylene / Q000494:pharmacology*; D014874:Water Pollutants, Chemical / Q000032:analysis; D018508:Water Purification / Q000379:methods*
chemical_list: D012997:Solvents; D014874:Water Pollutants, Chemical; D014241:Trichloroethylene; D002713:Chlorine; D007501:Iron