title: Zerovalent titanium-sulfur complexes. Novel dithiocarbamato derivatives of Ti(CO)6: [Ti(CO)4(S2CNR2)]-.
abstract: Oxidation of [Ti(CO)(6)](2-) by thiuram disulfides, (R(2)NCS(2))(2), affords the first isolable mononuclear six-coordinate titanium(0) carbonyls, [Ti(CO)(4)(S(2)CNR(2))](-), which have unusual trigonal prismatic geometries and chemical and spectral properties that are remarkably similar to those of the 18-electron and seven-coordinate anion [Ti(CO)(4)(eta(5)-C(5)H(5))](-).
authors.affiliation: Department of Chemistry, University of Minnesota, 207 Pleasant Street SE, Minneapolis, MN 55455, USA.
authors.forename: Robert E
authors.initials: RE
authors.lastname: Jilek
authors.forename: Giovanna
authors.initials: G
authors.lastname: Tripepi
authors.forename: Eugenijus
authors.initials: E
authors.lastname: Urnezius
authors.forename: William W
authors.initials: WW
authors.lastname: Brennessel
authors.forename: Victor G
authors.initials: VG
authors.lastname: Young
authors.forename: John E
authors.initials: JE
authors.lastname: Ellis