title: Absorption flattening as one cause of distortion of circular dichroism spectra of Delta-RuPhen3 . H2TPPS complex.
abstract: To extend the model that explains why and how much absorption flattening (AF) influences circular dichroism (CD) signals, we have investigated the interesting case of exciton CD in the Soret region of a noncovalent complex formed by (Delta-RuPhen(3))(2+) and the tetraanionic porphyrin H(2)TPPS. Different concentrations have been studied by using an AF emulator and spectra simulation. The CD spectra of this compound occasionally show distortions in the solution sampling mode with the increase of concentration; the inhomogeneous distribution in the cell volume is due to aggregation and is the source of the AF effect. On the basis of these results, we conclude that AF is an important cause of distortions in CD spectra for Delta-RuPhen(3) . H(2)TPPS complexes and might affect the CD bands of other aggregated systems as well.
authors.affiliation: JASCO Corporation, Hachioji-shi, Tokyo, Japan. ettore.castiglioni@jasco-europe.com
authors.forename: Ettore
authors.initials: E
authors.lastname: Castiglioni
authors.forename: Sergio
authors.initials: S
authors.lastname: Abbate
authors.forename: Giovanna
authors.initials: G
authors.lastname: Longhi
authors.forename: Roberto
authors.initials: R
authors.lastname: Gangemi
authors.forename: Rosaria
authors.initials: R
authors.lastname: Lauceri
authors.forename: Roberto
authors.initials: R
authors.lastname: Purrello
mesh_terms: D002942:Circular Dichroism; D009942:Organometallic Compounds / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013053:Spectrophotometry; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism
chemical_list: C429764:5,10,15-tris(4-sulfonatophenyl)-20-phenylporphryin; D009942:Organometallic Compounds; D010618:Phenanthrolines; D011166:Porphyrins; C034282:tris-(1,10-phenanthroline)ruthenium; D012428:Ruthenium