Models of the iron-only hydrogenase: structural studies of chelating diphosphine complexes [Fe2(CO)4(micro-pdt)(kappa2P,P'-diphosphine)].
Six chelating diphosphine complexes, [Fe2(CO)4(micro-pdt)(kappa2P,P'-diphosphine)], have been crystallographically characterised allowing differences between basal-apical and dibasal conformations to be analysed.
Adam
Fatima I
FI
Department of Chemistry, University College London, 20 Gordon Street, London, UKWC1H 0AJ.
Hogarth
Graeme
G
Richards
Idris
I
Sanchez
Benjamin E
BE
D018360:Crystallography, X-Ray; D006864:Hydrogenase / Q000737:chemistry*; D007502:Iron Chelating Agents / Q000737:chemistry*; D007506:Iron-Sulfur Proteins / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D010720:Phosphines / Q000737:chemistry*
D007502:Iron Chelating Agents; D007506:Iron-Sulfur Proteins; D010720:Phosphines; C118830:iron hydrogenase; D006864:Hydrogenase