title: Models of the iron-only hydrogenase: structural studies of chelating diphosphine complexes [Fe2(CO)4(micro-pdt)(kappa2P,P'-diphosphine)].
abstract: Six chelating diphosphine complexes, [Fe2(CO)4(micro-pdt)(kappa2P,P'-diphosphine)], have been crystallographically characterised allowing differences between basal-apical and dibasal conformations to be analysed.
authors.affiliation: Department of Chemistry, University College London, 20 Gordon Street, London, UKWC1H 0AJ.
authors.forename: Fatima I
authors.initials: FI
authors.lastname: Adam
authors.forename: Graeme
authors.initials: G
authors.lastname: Hogarth
authors.forename: Idris
authors.initials: I
authors.lastname: Richards
authors.forename: Benjamin E
authors.initials: BE
authors.lastname: Sanchez
mesh_terms: D018360:Crystallography, X-Ray; D006864:Hydrogenase / Q000737:chemistry*; D007502:Iron Chelating Agents / Q000737:chemistry*; D007506:Iron-Sulfur Proteins / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D010720:Phosphines / Q000737:chemistry*
chemical_list: D007502:Iron Chelating Agents; D007506:Iron-Sulfur Proteins; D010720:Phosphines; C118830:iron hydrogenase; D006864:Hydrogenase