title: New porphyrinoids: vanadyl(IV) complexes of meso-aryl-substituted corrphycene and 10-oxocorrole ligands.
abstract: Rare vanadyl corrphycene and vanadyl 10-oxocorrole complexes were obtained via an oxidative macrocyclization process by the treatment of 6,6'-di-p-tolyl-2,2'-bidipyrrin with VO(acac)2 in a hot dioxygen atmosphere. The geometric and electronic structures of the new porpyhrinoids were determined and showed the dependency of the spectral pattern from the aromaticity of the macrocyclic ligand.
authors.affiliation: Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerweinstrasse, 35043 Marburg, Germany.
authors.forename: Martin
authors.initials: M
authors.lastname: Bröring
authors.forename: Christian
authors.initials: C
authors.lastname: Hell
authors.forename: Frédérique
authors.initials: F
authors.lastname: Brégier
authors.forename: Olaf
authors.initials: O
authors.lastname: Burghaus
authors.forename: Esther Cónsul
authors.initials: EC
authors.lastname: Tejero