title: Surface structure and properties of mixed fumed oxides.
abstract: A variety of fumed oxides such as silica, alumina, titania, silica/alumina (SA), silica/titania (ST), and alumina/silica/titania (AST) were characterized. These oxides have different specific surface areas and different primary particle composition in the bulk and at the surface. These materials were studied by FTIR, NMR, Auger electron spectroscopy, one-pass temperature-programmed desorption with mass spectrometry control (OP TPDMS), microcalorimetry, and nitrogen adsorption. Nonlinear changes in the surface content of alumina in SA and AST and titania in ST and AST samples with increasing oxide content along with simultaneous changes in their specific surface area cause complex dependencies of the heat of immersion in water and desorption of water on heating on the structural parameters. Simultaneous analysis of changes in the surface phase composition, in the concentration of hydroxyls, and in the structural characteristics reveals that at a low content of the second phase the structural characteristics (e.g., S(BET)) are predominant; however, at a large content of these oxides the phase composition plays a more important role.
authors.affiliation: Institute of Surface Chemistry, 17 General Naumov Street, Kiev 03164, Ukraine. gun@voliacable.com
authors.forename: V M
authors.initials: VM
authors.lastname: Gun'ko
authors.forename: J P
authors.initials: JP
authors.lastname: Blitz
authors.forename: K
authors.initials: K
authors.lastname: Gude
authors.forename: V I
authors.initials: VI
authors.lastname: Zarko
authors.forename: E V
authors.initials: EV
authors.lastname: Goncharuk
authors.forename: Y M
authors.initials: YM
authors.lastname: Nychiporuk
authors.forename: R
authors.initials: R
authors.lastname: Leboda
authors.forename: J
authors.initials: J
authors.lastname: Skubiszewska-Zieba
authors.forename: V D
authors.initials: VD
authors.lastname: Osovskii
authors.forename: Y G
authors.initials: YG
authors.lastname: Ptushinskii
authors.forename: O A
authors.initials: OA
authors.lastname: Mishchuk
authors.forename: S V
authors.initials: SV
authors.lastname: Pakhovchishin
authors.forename: P P
authors.initials: PP
authors.lastname: Gorbik
mesh_terms: D000537:Aluminum Oxide / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008422:Materials Testing; D010087:Oxides / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D013499:Surface Properties; D013816:Thermodynamics; D014025:Titanium / Q000737:chemistry*
chemical_list: D010087:Oxides; C009495:titanium dioxide; D012822:Silicon Dioxide; D014025:Titanium; D000537:Aluminum Oxide