title: Photophysical properties and energy transfer pathway of Er(III) complexes with Pt-porphyrin and terpyridine ligands.
abstract: The photophysical properties of Er(III) complexes coordinated with platinum[5,10,15-triphenyl-20-(4-carboxyphenyl)-porphyrin] (PtP) and terpyridine (tpy) ligands in organic solution were investigated. The Er(III) complex emitted sensitized near-IR (NIR) luminescence when the PtP ligands were excited under deoxygenated conditions. The quantum yield (PhiLn) of the sensitized luminescence was 0.015%, as evaluated from luminescence lifetime. The photophysical studies and theoretical calculations suggest that the Förster resonance mechanism is very suitable for the energy transfer from PtP to the Er(III) ion and occurred through the first triplet excited state of PtP. The 12.3% energy transfer from the triplet state to the 4F9/2 and 4I9/2 states of Er(III) occurred with a rate distribution of 3.36x10(5) and 6.67x10(4) s(-1), respectively. In addition, the observed triplet quantum yield of the PtP ligand in [Ln(PtP)3(tpy)] proved that the energy transfer from the singlet excited state of the PtP ligand to the Er(III) ion did not take place.
authors.affiliation: Center for Smart Light-Harvesting Materials and Department of Advanced Materials, Hannam University, Deajeon 306-791, Korea.
authors.forename: Min-Kook
authors.initials: MK
authors.lastname: Nah
authors.forename: Jae Buem
authors.initials: JB
authors.lastname: Oh
authors.forename: Hwan Kyu
authors.initials: HK
authors.lastname: Kim
authors.forename: Kyong-Hoon
authors.initials: KH
authors.lastname: Choi
authors.forename: Yong-Rok
authors.initials: YR
authors.lastname: Kim
authors.forename: Jun-Gill
authors.initials: JG
authors.lastname: Kang