High-yielding one-pot synthesis of diaryliodonium triflates from arenes and iodine or aryl iodides.
Unsymmetric and symmetric diaryliodonium triflates are synthesized from both electron-deficient and electron-rich substrates in a fast, high yielding, and operationally simple protocol employing arenes and aryl iodides or iodine.
Bielawski
Marcin
M
Department of Organic Chemistry, Arrhenius Laboratory, Stockholm University, SE-106 91 Stockholm, Sweden.
Olofsson
Berit
B
D001713:Biphenyl Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006847:Hydrocarbons, Iodinated / Q000138:chemical synthesis* / Q000737:chemistry; D007455:Iodine / Q000737:chemistry*; D008698:Mesylates / Q000737:chemistry*; D015394:Molecular Structure; D009861:Onium Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D001713:Biphenyl Compounds; D006847:Hydrocarbons, Iodinated; D008698:Mesylates; D009861:Onium Compounds; C031291:diphenyliodonium; D007455:Iodine; C012077:trifluoromethanesulfonic acid