title: Organoruthenium derivative of the cyclic [H7P8W48O184]33- anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27-.
abstract: Reaction of [Ru(p-cymene)Cl2]2 with [H7P8W48O184]33- (P8W48) in aqueous acidic medium results in the organometallic derivative [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27- (1); in addition to the four {Ru(p-cymene)(H2O)} units, an unusual WO6 group with four equatorial, terminal ligands is also grafted to the crown-shaped P8W48 precursor.
authors.affiliation: Jacobs University Bremen, School of Engineering and Science, 28725 Bremen, Germany.
authors.forename: Sib Sankar
authors.initials: SS
authors.lastname: Mal
authors.forename: Nadeen H
authors.initials: NH
authors.lastname: Nsouli
authors.forename: Michael H
authors.initials: MH
authors.lastname: Dickman
authors.forename: Ulrich
authors.initials: U
authors.lastname: Kortz
mesh_terms: D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D014414:Tungsten / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D012428:Ruthenium; D014414:Tungsten