title: Meso-13C-labeled porphyrins for studies of ground-state hole transfer in multiporphyrin arrays.
abstract: Understanding electronic communication among interacting chromophores provides the foundation for a variety of applications. The ground-state electronic communication in diphenylethyne-linked zinc-porphyrin dyads has been investigated by a novel molecular design strategy that entails introduction of a 13C-atom (*) at specific sites of the porphyrins where there is substantial electron density in the relevant frontier (highest occupied) molecular orbital. The site of 13C substitution is at a meso-position, either the site of attachment of the linker (proximal, "P") or the site trans to the linker (distal, "D"). The substituents (R) at the non-linking meso-positions are mesityl, tridec-7-yl ("swallowtail"), or p-tolyl groups. Altogether five isotopically labeled porphyrin dyads have been prepared. The hole/electron-transfer properties of one-electron oxidized dyads have been examined by electron paramagnetic resonance (EPR) spectroscopy. The introduction of the meso-13C label provides a "clock" (via the hyperfine interactions) that allows investigation of a time scale for hole transfer that is 3-4 times shorter than that provided by the natural abundance 14N nuclei of the pyrrole nitrogen atoms. The EPR studies indicate that the hole transfer, which has been previously shown to be fast on the time scale of the 14N hyperfine clock ( approximately 220 ns), remains fast on the time scale of the 13C hyperfine clock ( approximately 50 ns).
authors.affiliation: Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695-8204, USA.
authors.forename: Patchanita
authors.initials: P
authors.lastname: Thamyongkit
authors.forename: Ana Z
authors.initials: AZ
authors.lastname: Muresan
authors.forename: James R
authors.initials: JR
authors.lastname: Diers
authors.forename: Dewey
authors.initials: D
authors.lastname: Holten
authors.forename: David F
authors.initials: DF
authors.lastname: Bocian
authors.forename: Jonathan S
authors.initials: JS
authors.lastname: Lindsey