Organoruthenium derivative of the cyclic [H7P8W48O184]33- anion: [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27-.
Reaction of [Ru(p-cymene)Cl2]2 with [H7P8W48O184]33- (P8W48) in aqueous acidic medium results in the organometallic derivative [{K(H2O)}3{Ru(p-cymene)(H2O)}4P8W49O186(H2O)2]27- (1); in addition to the four {Ru(p-cymene)(H2O)} units, an unusual WO6 group with four equatorial, terminal ligands is also grafted to the crown-shaped P8W48 precursor.
Mal
Sib Sankar
SS
Jacobs University Bremen, School of Engineering and Science, 28725 Bremen, Germany.
Nsouli
Nadeen H
NH
Dickman
Michael H
MH
Kortz
Ulrich
U
D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D014414:Tungsten / Q000737:chemistry*
D009942:Organometallic Compounds; D012428:Ruthenium; D014414:Tungsten