Adlayer structures of aza- and/or oxo-bridged calix[2]arene[2]triazines on Au(111) investigated by scanning tunneling microscopy (STM).
The adlayers formed by a series of aza- and/or oxo-bridged calix[2]arene[2]triazines on Au(111) surfaces were investigated by scanning tunneling microscopy (STM) and density functional theory (DFT) calculations. 1,3-Alternate configurations of these molecules are preserved on gold surfaces as in their three-dimensional crystals. STM images show that the cavity sizes of these molecules are finely tuned by substituting the bridging nitrogen atom with oxygen atoms, which change the strengths and densities of the intermolecular hydrogen bonds. Hydrogen bond interaction influences the molecular orientation and conformation in the adlayers, and it plays a key role in the formation of these two-dimensional supramolecular architectures. Coadsorption of calix[2]arene[2]triazine with 1,3,5-tris(5-carboxyamyloxy)benzene (TCAB) intervenes with the intermolecular hydrogen bond formations among the calix[2]arene[2]triazine molecules and consequently causes a conformational transition of the calixarene molecules from rhombic to square. These results demonstrate the role of hydrogen bonds in molecular assembly formations.
Yan
Cun-Ji
CJ
Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences (CAS), Beijing 100080, China.
Yan
Hui-Juan
HJ
Xu
Li-Ping
LP
Song
Wei-Guo
WG
Wan
Li-Jun
LJ
Wang
Qi-Qiang
QQ
Wang
Mei-Xiang
MX