title: The first calibration of an aminiumyl radical ion clock: why N-cyclopropylanilines may be poor mechanistic probes for single electron transfer.
abstract: Using direct and indirect electrochemical methods, the rate constant for ring opening of the radical cation generated from N-cyclopropyl-N-methylaniline was found to be 4.1 x 10(4) s(-1).
authors.affiliation: Department of Chemistry, Virginia Polytechnic Institute and State University, Blacksburg, VA 24061, USA.
authors.forename: Xiangzhong
authors.initials: X
authors.lastname: Li
authors.forename: Michelle L
authors.initials: ML
authors.lastname: Grimm
authors.forename: Kazuo
authors.initials: K
authors.lastname: Igarashi
authors.forename: Neal
authors.initials: N
authors.lastname: Castagnoli
authors.forename: J M
authors.initials: JM
authors.lastname: Tanko
mesh_terms: D000814:Aniline Compounds / Q000737:chemistry*; D002138:Calibration; D004563:Electrochemistry; D005609:Free Radicals / Q000737:chemistry*; D007477:Ions / Q000737:chemistry*; D010084:Oxidation-Reduction; D021241:Spectrometry, Mass, Electrospray Ionization
chemical_list: D000814:Aniline Compounds; D005609:Free Radicals; D007477:Ions