title: A facile Er(OTf)3-catalyzed synthesis of 2,3-unsaturated O- and S-glycosides.
abstract: Er(OTf)(3) is a useful catalyst for the Ferrier rearrangement furnishing high yields of O- and S-glycosides. The transformation has wide applicability, cleaner reaction profiles, mild reaction conditions, and high stereoselectivity and the catalyst, which is also commercially available, can be recovered and reused.
authors.affiliation: Dipartimento Farmacobioiologiche, Università degli Studi della Magna Graecia Complesso Ninì Barbieri, 88021, Roccelletta di Borgia (CZ), Italy. procopio@unicz.it
authors.forename: Antonio
authors.initials: A
authors.lastname: Procopio
authors.forename: Renato
authors.initials: R
authors.lastname: Dalpozzo
authors.forename: Antonio
authors.initials: A
authors.lastname: De Nino
authors.forename: Loredana
authors.initials: L
authors.lastname: Maiuolo
authors.forename: Monica
authors.initials: M
authors.lastname: Nardi
authors.forename: Manuela
authors.initials: M
authors.lastname: Oliverio
authors.forename: Beatrice
authors.initials: B
authors.lastname: Russo
mesh_terms: D002384:Catalysis; D006027:Glycosides / Q000138:chemical synthesis*; D013865:Thioglycosides / Q000138:chemical synthesis
chemical_list: D006027:Glycosides; D013865:Thioglycosides