title: Electron transfer promoted regioselective ring-opening reaction of cyclopropyl silyl ethers.
abstract: Oxidative ring-opening reactions of cyclopropyl silyl ethers incorporated into bicyclo[m.1.0]alkane framework were investigated. The results show that the regioselectivities for ring-opening of intermediate radical cations, formed by single electron transfer, are governed by the nature of the nucleophile as well as oxidizing species.
authors.affiliation: Department of Chemistry, Faculty of Science, Niigata University, Ikarashi-2 8050, Niigata 950-2181, Japan. ehase@chem.sc.niigata-u.ac.jp
authors.forename: Eietsu
authors.initials: E
authors.lastname: Hasegawa
authors.forename: Naoto
authors.initials: N
authors.lastname: Yamaguchi
authors.forename: Hiroyasu
authors.initials: H
authors.lastname: Muraoka
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Tsuchida
mesh_terms: D003521:Cyclopropanes / Q000737:chemistry*; D004583:Electrons; D004987:Ethers; D019158:N-Acetylneuraminic Acid / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D003521:Cyclopropanes; D004987:Ethers; D019158:N-Acetylneuraminic Acid