Pb(2.63)Cd(2)V(3)O(12), a cation-deficient garnet-type vanadate.
In the crystal structure of the cation-deficient garnet Pb(2.63)Cd(2)V(3)O(12) (lead cadmium vanadium oxide), the Cd and V atoms fully occupy octahedral and tetrahedral sites, respectively, whereas the Pb atoms partially occupy a dodecahedral site. The total Pb and Cd content indicates that vanadium is slightly reduced from the +5 oxidation state.
Tsirlin
Alexander A
AA
Department of Chemistry, Moscow State University, 119992 Moscow, Russian Federation.
Dikarev
Evgeny V
EV
Velikodny
Yuri A
YA
Shpanchenko
Roman V
RV
Antipov
Evgeny V
EV