Bis(5-tert-butyl-2-hydroxy-3-methylbenzyl)(6-hydroxyhexyl)ammonium chloride monohydrate, an anion receptor complex.
In the title compound, C(30)H(48)NO(3)(+) x Cl(-) x H(2)O, the cation acts with a water molecule as a chloride ion receptor. The chloride ion forms three strong intramolecular hydrogen bonds. The water molecule forms both an intramolecular bridge between one phenol H atom and the chloride ion, and an intermolecular link to the aliphatic alcohol O atom. Weak intermolecular C-H...Cl and C-H ...O hydrogen bonds provide additional packing interactions.
Sopo
Harri
H
Department of Chemistry at University of Jyväskylä, PO Box 35, FIN-40014 University of Jyväskylä, Finland.
Sillanpää
Reijo
R
D000643:Ammonium Chloride / Q000737:chemistry*; D000838:Anions / Q000737:chemistry; D001596:Benzylamines / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular
D000838:Anions; D001596:Benzylamines; C523139:bis(5-tert-butyl-2-hydroxy-3-methylbenzyl)(6-hydroxyhexyl)amine; D000643:Ammonium Chloride