3D porous metal-organic framework exhibiting selective adsorption of water over organic solvents.
A 3D porous metal-organic framework (MOF) with 1D open channels has been constructed hydrothermally using Zn(II) and a rigid planar ligand IDC(3)- (imidazole-4,5-dicarboxylate). This MOF can adsorb water selectively over organic solvents and can be regenerated and reused. It also represents a rare example of a MOF with open channels that form/collapse reversibly upon hydration/dehydration.
Gu
Jin-Zhong
JZ
MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China.
Lu
Wen-Guan
WG
Jiang
Long
L
Zhou
Hong-Cai
HC
Lu
Tong-Bu
TB
D000327:Adsorption; D055598:Chemical Phenomena; D002625:Chemistry, Organic / Q000379:methods*; D002627:Chemistry, Physical; D003460:Crystallization; D007477:Ions; D008024:Ligands; D008670:Metals / Q000737:chemistry*; D008956:Models, Chemical; D008968:Molecular Conformation; D012997:Solvents; D014867:Water / Q000737:chemistry*; D014961:X-Ray Diffraction; D015032:Zinc / Q000737:chemistry
D007477:Ions; D008024:Ligands; D008670:Metals; D012997:Solvents; D014867:Water; D015032:Zinc