title: Encapsulation of a trinuclear silver(I) cluster by two imido-nitrido metalloligands [{Ti(eta5-C5Me5)(micro-NH)}3(micro3-N)].
abstract: Treatment of the metalloligand [{Ti(eta(5)-C(5)Me(5))(micro-NH)}(3)(micro(3)-N)] with silver(i) trifluoromethanesulfonate in different molar ratios gives the ionic compounds [Ag{(micro(3)-NH)(3)Ti(3)(eta(5)-C(5)Me(5))(3)(micro(3)-N)}(2)][O(3)SCF(3)] and [Ag{(micro(3)-NH)(3)Ti(3)(eta(5)-C(5)Me(5))(3)(micro(3)-N)}][O(3)SCF(3)] or the triangular silver cluster [(CF(3)SO(2)O)(3)Ag(3){(micro(3)-NH)(3)Ti(3)(eta(5)-C(5)Me(5))(3)(micro(3)-N)}(2)] in which each face is capped by a metalloligand.
authors.affiliation: Departamento de Química Inorgánica, Universidad de Alcalá, 28871, Alcalá de Henares-Madrid, Spain.
authors.forename: Avelino
authors.initials: A
authors.lastname: Martín
authors.forename: Noelia
authors.initials: N
authors.lastname: Martínez-Espada
authors.forename: Miguel
authors.initials: M
authors.lastname: Mena
authors.forename: Carlos
authors.initials: C
authors.lastname: Yélamos