Tricarbonylmanganese(I)-lysozyme complex: a structurally characterized organometallic protein.
The reaction of the new and structurally characterized covalent {Mn(CO)(3)(H(2)O)(2)}(+)-lysozyme adduct with NiS(4) and NiN(2)S(2) complexes generates binuclear Ni-Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)(2)} intermediate during maturation of [NiFe] hydrogenases is discussed.
Razavet
Mathieu
M
Laboratoire de Chimie et Biologie des Métaux, Université Joseph Fourier, Grenoble, France.
Artero
Vincent
V
Cavazza
Christine
C
Oudart
Yohan
Y
Lebrun
Colette
C
Fontecilla-Camps
Juan Carlos
JC
Fontecave
Marc
M
D018360:Crystallography, X-Ray; D008345:Manganese / Q000737:chemistry*; D009113:Muramidase / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared
D009942:Organometallic Compounds; D008345:Manganese; D009113:Muramidase