title: Tricarbonylmanganese(I)-lysozyme complex: a structurally characterized organometallic protein.
abstract: The reaction of the new and structurally characterized covalent {Mn(CO)(3)(H(2)O)(2)}(+)-lysozyme adduct with NiS(4) and NiN(2)S(2) complexes generates binuclear Ni-Mn complexes; relevance to the reactivity of the protein-bound {Fe(CO)(CN)(2)} intermediate during maturation of [NiFe] hydrogenases is discussed.
authors.affiliation: Laboratoire de Chimie et Biologie des Métaux, Université Joseph Fourier, Grenoble, France.
authors.forename: Mathieu
authors.initials: M
authors.lastname: Razavet
authors.forename: Vincent
authors.initials: V
authors.lastname: Artero
authors.forename: Christine
authors.initials: C
authors.lastname: Cavazza
authors.forename: Yohan
authors.initials: Y
authors.lastname: Oudart
authors.forename: Colette
authors.initials: C
authors.lastname: Lebrun
authors.forename: Juan Carlos
authors.initials: JC
authors.lastname: Fontecilla-Camps
authors.forename: Marc
authors.initials: M
authors.lastname: Fontecave
mesh_terms: D018360:Crystallography, X-Ray; D008345:Manganese / Q000737:chemistry*; D009113:Muramidase / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared
chemical_list: D009942:Organometallic Compounds; D008345:Manganese; D009113:Muramidase