The racemate cage. Influence of p(1),n(1) salt occurrence on enantiomer separation processes. The case of trans-chrysanthemic acid.
The occurrence of p(1),n(1) salt when accompanied by substrate self-association can have profound effects on enantiomer separation processes of non-racemic mixtures, impeding the complete recovery of the major enantiomer through formation of an inescapable racemate cage.
Rosini
Goffredo
G
Dipartimento di Chimica Organica "A. Mangini", Alma Mater Studiorum--Università di Bologna, V.le del Risorgimento 4, 40136 Bologna, Italy. goffredo.rosini@unibo.it
Borzatta
Valerio
V
Boschi
Francesca
F
Candido
Gabriele
G
Marotta
Emanuela
E
Righi
Paolo
P