Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides.
SET oxidation of bis-sulfinyl anions has enabled the uses of bis-sulfinyl radical as a synthetic equivalent of chiral acyl and methylene radicals involved in tandem reactions leading to the enantioselective construction of various carbo- and heterocyclic derivatives.
Goddard
Jean-Philippe
JP
Laboratoire de Chimie Organique (UMR CNRS 7611), Institut de chimie moléculaire FR 2769, Université Pierre et Marie Curie-Paris 6, case 229, 4 place Jussieu, 75252 Paris cedex 05, France.
Gomez
Catherine
C
Brebion
Franck
F
Beauvière
Sophie
S
Fensterbank
Louis
L
Malacria
Max
M