title: Development of high-pressure, high-field and multifrequency electron spin resonance system.
abstract: The electron spin resonance (ESR) system which covers the magnetic field region up to 16 T, the quasicontinuous frequency region from 60 to 700 GHz, the temperature region from 1.8 to 4.2 K, and the hydrostatic pressure region up to 1.1 GPa has been developed. This is the first pulsed high-field and multifrequency ESR system with the pressure region over 1 GPa as far as we know. Transmission ESR spectra under hydrostatic pressure can be obtained by combining a piston-cylinder-type pressure cell and the pulsed magnetic field ESR apparatus. The pressure cell consists of a NiCrAl cylinder and sapphire or zirconia inner parts. The use of sapphire or zirconia as inner parts enables us to observe ESR under pressure because these inner parts have high transmittance for the electromagnetic wave with millimeter and submillimeter wavelengths. We have successfully applied this system for the pressure dependence measurements of an isolated spin system NiSnCl(6)6H(2)O up to 1.1 GPa. It was found that the single ion anisotropy parameter D of this compound strongly depends on pressure. The parameter D is approximately proportional to the pressure up to 0.75 GPa, and the relation between D and the pressure can be used for the pressure calibration of this high-field and high-pressure ESR system.
authors.affiliation: Center for Supports to Research and Education Activities, Kobe University, Nada, Kobe 657-8501, Japan. tsakurai@kobe-u.ac.jp
authors.forename: T
authors.initials: T
authors.lastname: Sakurai
authors.forename: A
authors.initials: A
authors.lastname: Taketani
authors.forename: T
authors.initials: T
authors.lastname: Tomita
authors.forename: S
authors.initials: S
authors.lastname: Okubo
authors.forename: H
authors.initials: H
authors.lastname: Ohta
authors.forename: Y
authors.initials: Y
authors.lastname: Uwatoko
mesh_terms: D004574:Electromagnetic Fields; D004578:Electron Spin Resonance Spectroscopy / Q000295:instrumentation* / Q000379:methods; D004867:Equipment Design; D019544:Equipment Failure Analysis; D011312:Pressure; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D013048:Specimen Handling / Q000295:instrumentation*; D013113:Spin Labels
chemical_list: D013113:Spin Labels