Front propagation in patterned precipitation. 3. Composition variations in two-precipitate stratum dynamics.
This paper is a study of the composition dynamics of Liesegang band strata of Co(OH)2 and Ni(OH)2 from NH4OH, with redissolution by complex formation with ammonia. At a fixed time, the cobalt hydroxide composition was found to exhibit a random variation with band number, yet within a general overall decrease. The decrease with band number becomes more pronounced as the initial concentrations of Co2+ and Ni2+ get closer to each other. At equal concentrations, periodic oscillations in Co(OH)2 composition appear over consecutive bands. The time evolution of the total Co(OH)2 mass percent (over the entire pattern of strata) passes through a maximum. The dynamics of this complex system has been simulated by theoretical calculations using the model of Müller and Polezhaev, modified by Al-Ghoul and Sultan in a series of two papers in J. Phys. Chem. A; the present paper is the third in the series. The simulations capture the essential features of the experimentally observed dynamics.
Msharrafieh
Maysam
M
Department of Chemistry, American University of Beirut, 1107 2020 Riad El Solh, Beirut, Lebanon.
Al-Ghoul
Mazen
M
Batlouni
Hazar
H
Sultan
Rabih
R