Light-fluorous safety-catch arylgermanes - exceptionally robust, photochemically activated precursors for biaryl synthesis by Pd(0) catalysed cross-coupling.
A new class of arylgermane derivative that participate efficiently in Pd(0)-catalysed cross-coupling reactions with aryl bromides following photochemical activation is described.
Spivey
Alan C
AC
Department of Chemistry, South Kensington Campus, Imperial College, London, UK SW7 2AZ. a.c.spivey@imperial.ac.uk
Tseng
Chih-Chung
CC
Hannah
Joseph P
JP
Gripton
Christopher J G
CJ
de Fraine
Paul
P
Parr
Nigel J
NJ
Scicinski
Jan J
JJ
D001713:Biphenyl Compounds / Q000138:chemical synthesis; D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry*; D005857:Germanium / Q000737:chemistry*; D009930:Organic Chemicals / Q000138:chemical synthesis; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010777:Photochemistry
D001713:Biphenyl Compounds; D003432:Cross-Linking Reagents; D009930:Organic Chemicals; D009942:Organometallic Compounds; D005857:Germanium; D010165:Palladium