title: Highly diastereoselective ionic/radical domino reactions: single electron transfer induced cyclization of bis-sulfoxides.
abstract: SET oxidation of bis-sulfinyl anions has enabled the uses of bis-sulfinyl radical as a synthetic equivalent of chiral acyl and methylene radicals involved in tandem reactions leading to the enantioselective construction of various carbo- and heterocyclic derivatives.
authors.affiliation: Laboratoire de Chimie Organique (UMR CNRS 7611), Institut de chimie moléculaire FR 2769, Université Pierre et Marie Curie-Paris 6, case 229, 4 place Jussieu, 75252 Paris cedex 05, France.
authors.forename: Jean-Philippe
authors.initials: JP
authors.lastname: Goddard
authors.forename: Catherine
authors.initials: C
authors.lastname: Gomez
authors.forename: Franck
authors.initials: F
authors.lastname: Brebion
authors.forename: Sophie
authors.initials: S
authors.lastname: Beauvière
authors.forename: Louis
authors.initials: L
authors.lastname: Fensterbank
authors.forename: Max
authors.initials: M
authors.lastname: Malacria