title: Diastereoselective synthesis of arylglycine derivatives by cationic palladium(II)-catalyzed addition of arylboronic acids to N-tert-butanesulfinyl imino esters.
abstract: A cationic palladium-complex-catalyzed addition of arylboronic acids to N-tert-butanesulfinyl iminoacetates to yield the optically active arylglycine derivatives with moderate to good yield and high diastereoselectivity was developed. This reaction provides a convenient and efficient method for the synthesis of arylglycine derivatives.
authors.affiliation: State Key Laboratory of Organometallic Chemistry, Shanghai, Institute of Organic Chemistry, Chinese Academy of Sciences, 354 Fenglin Lu, Shanghai 200032, China.
authors.forename: Huixiong
authors.initials: H
authors.lastname: Dai
authors.forename: Xiyan
authors.initials: X
authors.lastname: Lu
mesh_terms: D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000737:chemistry*; D005998:Glycine / Q000031:analogs & derivatives* / Q000138:chemical synthesis*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D013452:Sulfonium Compounds / Q000737:chemistry*
chemical_list: D001897:Boronic Acids; D004952:Esters; C481933:N-tert-butanesulfinylimino ester; D013452:Sulfonium Compounds; D010165:Palladium; D005998:Glycine