SOA formation by biogenic and carbonyl compounds: data evaluation and application.
The organic fraction of atmospheric aerosols affects the physical and chemical properties of the particles and their role in the climate system. Current models greatly underpredict secondary organic aerosol (SOA) mass. Based on a compilation of literature studies that address SOA formation, we discuss different parameters that affect the SOA formation efficiency of biogenic compounds (alpha-pinene, isoprene) and aliphatic aldehydes (glyoxal, hexanal, octanal, hexadienal). Applying a simple model, we find that the estimated SOA mass after one week of aerosol processing under typical atmospheric conditions is increased by a few microg m(-3) (low NO(x) conditions). Acid-catalyzed reactions can create > 50% more SOA mass than processes under neutral conditions; however, other parameters such as the concentration ratio of organics/NO(x), relative humidity, and absorbing mass are more significant. The assumption of irreversible SOA formation not limited by equilibrium in the particle phase or by depletion of the precursor leads to unrealistically high SOA masses for some of the assumptions we made (surface vs volume controlled processes).
Ervens
Barbara
B
Atmospheric Science Department, Colorado State University, Fort Collins, Colorado 80523, USA. barbara.ervens@noaa.gov
Kreidenweis
Sonia M
SM
D000336:Aerosols / Q000737:chemistry*; D000447:Aldehydes / Q000737:chemistry*; D000081008:Bicyclic Monoterpenes; D002070:Butadienes / Q000737:chemistry*; D045782:Hemiterpenes / Q000737:chemistry*; D007700:Kinetics; D008956:Models, Chemical; D039821:Monoterpenes / Q000737:chemistry*; D010420:Pentanes / Q000737:chemistry*; D013816:Thermodynamics
D000336:Aerosols; D000447:Aldehydes; D000081008:Bicyclic Monoterpenes; D002070:Butadienes; D045782:Hemiterpenes; D039821:Monoterpenes; D010420:Pentanes; C005059:isoprene; C005451:alpha-pinene