Syntheses of N-vanillyl-nonanamide glycosides using amyloglucosidase from Rhizopus and beta-glucosidase from sweet almond.
Enzymatic syntheses of N-vanillyl-nonanamide, 1, glycosides with D-glucose, 2, D-galactose, 3, D-mannose, 4, D-ribose, 5, maltose, 6, and lactose, 7, were carried out using amyloglucosidase from Rhizopus and beta-glucosidase from sweet almond. The latter catalysed the syntheses of N-vanillyl-nonanamide glycosides (8-13) and exclusively yielded beta-glycosides with carbohydrates 2, 3, 4, 6 and 7, while amyloglucosidase yielded C1-alpha- and beta-glycosides and 6-O-aryl derivatives (8, 9, 11 and 12).
Sivakumar
Ramaiah
R
Fermentation Technology & Bioengineering Department, Central Food Technological Research Institute, Mysore, 570020, India.
Divakar
Soundar
S
D005690:Galactose / Q000737:chemistry; D005087:Glucan 1,4-alpha-Glucosidase / Q000378:metabolism*; D005947:Glucose / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry / Q000378:metabolism; D008320:Maltose / Q000737:chemistry; D015394:Molecular Structure; D009005:Monosaccharides / Q000737:chemistry; D027861:Prunus / Q000201:enzymology*; D012233:Rhizopus / Q000201:enzymology*; D001617:beta-Glucosidase / Q000378:metabolism*
D006027:Glycosides; D009005:Monosaccharides; D008320:Maltose; D001617:beta-Glucosidase; D005087:Glucan 1,4-alpha-Glucosidase; D005947:Glucose; D005690:Galactose