Hydrogen storage using polymer-supported organometallic dihydrogen complexes: a mechanistic study.
The dihydrogen complex W(CO)(5)(H(2)) can be both generated and dissociated in polymer matrices by UV photolysis at 220 K and 90 K, respectively, suggesting a potential "UV-activated" mechanism for hydrogen storage and release.
Cooper
Andrew I
AI
Department of Chemistry, University of Liverpool, Crown Street, Liverpool, UK. aicooper@liv.ac.uk
Poliakoff
Martyn
M