Preparation and evaluation of candidate certified reference materials (CRMs) for nutrients in seawater.
Certified reference materials (CRMs) are an essential part of the quality assurance (QA) necessary for the reliable analytical measurement of nutrients in seawater. The CRMs currently available for these analyses are not matrix matched to marine samples. QUASIMEME routinely produces test materials for the nutrients in seawater and nutrients in estuarine water and low-salinity open water Laboratory Performance Studies (LPS) that are both homogeneous and stable. QUASIMEME, in conjunction with Eurofins Scientific, Denmark have produced two reference materials (RMs). The homogeneity testing and preliminary stability studies were carried out by QUASIMEME, and the results are presented in this article. Participants of the QUASIMEME LPS who demonstrated satisfactory long-term performance for the analysis of nutrients in seawater and nutrients in estuarine water and low-salinity open water were invited to take part in the certification exercise. Twenty laboratories returned data, a summary of which is also presented. The certification and long-term stability testing and additional data analysis were carried out by Eurofins Scientific, Denmark, and are outwith the scope of this article and not reported here. Eurofins Scientific, Denmark have marketed these RMs as part of their range of VKI Reference Materials (further information is available from eurofins@eurofins.dk).
Smith
Kerry M
KM
Fisheries Research Services Marine Laboratory, 375 Victoria Road, Aberdeen, UK. smithk@marlab.ac.uk
Wells
David E
DE
D000641:Ammonia / Q000032:analysis / Q000592:standards; D004784:Environmental Monitoring / Q000592:standards*; D009566:Nitrates / Q000032:analysis / Q000592:standards; D009573:Nitrites / Q000032:analysis / Q000592:standards; D010710:Phosphates / Q000032:analysis / Q000592:standards; D012015:Reference Standards; D015203:Reproducibility of Results; D012623:Seawater / Q000032:analysis*; D017640:Silicates / Q000032:analysis / Q000592:standards; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000592:standards*
D009566:Nitrates; D009573:Nitrites; D010710:Phosphates; D017640:Silicates; D014874:Water Pollutants, Chemical; D000641:Ammonia