Turning up the spin, turning on single-molecule magnetism: from S = 1 to S = 7 in a [Mn(8)] cluster via ligand induced structural distortion.
The spin ground state of a [Mn(III)(6)Mn(II)(2)] cluster has been deliberately switched from S = 1 to S = 7 upon designed ligand substitution.
Milios
Constantinos J
CJ
School of Chemistry, The University of Edinburgh, West Mains Road, Edinburgh, UK EH9 3JJ.
Inglis
Ross
R
Vinslava
Alina
A
Prescimone
Alessandro
A
Wernsdorfer
Wolfgang
W
Parsons
Simon
S
Perlepes
Spyros P
SP
Christou
George
G
Brechin
Euan K
EK