title: Light-fluorous safety-catch arylgermanes - exceptionally robust, photochemically activated precursors for biaryl synthesis by Pd(0) catalysed cross-coupling.
abstract: A new class of arylgermane derivative that participate efficiently in Pd(0)-catalysed cross-coupling reactions with aryl bromides following photochemical activation is described.
authors.affiliation: Department of Chemistry, South Kensington Campus, Imperial College, London, UK SW7 2AZ. a.c.spivey@imperial.ac.uk
authors.forename: Alan C
authors.initials: AC
authors.lastname: Spivey
authors.forename: Chih-Chung
authors.initials: CC
authors.lastname: Tseng
authors.forename: Joseph P
authors.initials: JP
authors.lastname: Hannah
authors.forename: Christopher J G
authors.initials: CJ
authors.lastname: Gripton
authors.forename: Paul
authors.initials: P
authors.lastname: de Fraine
authors.forename: Nigel J
authors.initials: NJ
authors.lastname: Parr
authors.forename: Jan J
authors.initials: JJ
authors.lastname: Scicinski
mesh_terms: D001713:Biphenyl Compounds / Q000138:chemical synthesis; D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry*; D005857:Germanium / Q000737:chemistry*; D009930:Organic Chemicals / Q000138:chemical synthesis; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010777:Photochemistry
chemical_list: D001713:Biphenyl Compounds; D003432:Cross-Linking Reagents; D009930:Organic Chemicals; D009942:Organometallic Compounds; D005857:Germanium; D010165:Palladium