title: Air sampling of nickel in a refinery.
abstract: Air monitoring was conducted in a nickel base metal refinery to determine compliance with occupational exposure limits. The hypothesis stated that levels of airborne dust may pose a risk to worker health if compared to the relevant exposure limits. Exposure limits for nickel species are set for the inhalable nickel dust fraction. Personal air samples, representative of three selected areas were collected in the workers' breathing zones, using the Institute of Occupational Medicine (IOM) samplers. Real-time personal samples were collected randomly over a two-month period in three nickel production areas. Filter papers were treated gravimetrically and were analysed for soluble and insoluble nickel through inductive coupled plasma-mass spectrometry (ICP-MS). Measured concentrations were expressed as time weighted average exposure concentrations. Results were compared to South African occupational exposure limits (OELs) and to the threshold limit values (TLVs) set by the American Conference of Governmental Industrial Hygienists (ACGIH) to determine compliance. Statistical compliance was also determined using the National Institute for Occupational Safety and Health procedure as prescribed by South Africa's Hazardous Chemical Substances Regulations in 1995. In two of the areas it was found that exposure concentrations complied with the OELs. Some exposures exceeded the OEL values and most exposures exceeded the TLV values in the other area concerned. A comprehensive health risk assessment needs to be conducted to determine the cause of non-compliance.
authors.affiliation: Faculty of Science, Department of Environmental Health, Tshwane University of Technology, Pretoria, South Africa. harmsejl@tut.ac.za
authors.forename: Johannes L
authors.initials: JL
authors.lastname: Harmse
authors.forename: Jacobus C
authors.initials: JC
authors.lastname: Engelbrecht
mesh_terms: D000395:Air Pollutants, Occupational / Q000032:analysis*; D004391:Dust / Q000032:analysis; D004784:Environmental Monitoring; D009532:Nickel / Q000032:analysis*; D016273:Occupational Exposure / Q000032:analysis*; D010316:Particle Size; D013019:South Africa
chemical_list: D000395:Air Pollutants, Occupational; D004391:Dust; D009532:Nickel