Supramolecular hydrogen-bonded networks in adeninium phenylacetate phenylacetic acid monohydrate and adeninium 3-carboxypropionate monohydrate.
In the title compounds, C(5)H(6)N(5)(+) x C(8)H(7)O(2)(-) x C(8)H(8)O(2) x H(2)O, (I), and C(5)H(6)N(5)(+) x C(4)H(3)O(4)(-) x H(2)O, (II), the adeninium cations form N-H...O hydrogen bonds with their anion counterparts and adeninium-adeninium self-association base pairs with the R(2)(2)(10) motif (Bernstein et al., 1995). A complete hydrogen-bonding motif analysis is presented. Conventional hydrogen bonds lead to layer structures in (I) and to two-dimensional infinite polymeric ribbons in (II). C-H...O interactions are found in both structures, while weak pi-pi stacking interactions are only observed in (I).
Sridhar
Balasubramanian
B
Laboratory of X-ray Crystallography, Indian Institute of Chemical Technology, Hyderabad 500 007, India. sshiya@yahoo.com
Ravikumar
Krishnan
K
D000225:Adenine / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D010648:Phenylacetates / Q000737:chemistry*; D011422:Propionates / Q000737:chemistry; D013386:Succinates / Q000737:chemistry*
D010648:Phenylacetates; D011422:Propionates; D013386:Succinates; C025136:phenylacetic acid; D000225:Adenine