title: Rate coefficients for the OH + pinonaldehyde (C10H16O2) reaction between 297 and 374 K.
abstract: The rate coefficientforthe reaction of OH with pinonaldehyde (C10H16O2, 3-acetyl-2,2-dimethyl-cyclobutyl-ethanal), a product of the atmospheric oxidation of alpha-pinene, was measured under pseudo-first-order conditions in OH at temperatures between 297 and 374 K at 55 and 96 Torr (He). Laser induced fluorescence (LIF) was used to monitor OH in the presence of pinonaldehyde following its production by 248 nm pulsed laser photolysis of H2O2. The reaction exhibits a negative temperature dependence with an Arrhenius expression of k1(T) = (4.5 +/- 1.3) x 10(-12) exp((600 +/- 100)/ 7) cm3 molecule(-1) s(-1); k1(297 K) = (3.46 +/- 0.4) x 10(-11) cm3 molecule(-1) s(-1). There was no observed dependence of the rate coefficient on pressure. Our results are compared with previous relative rate determinations of k1 near 297 K and the discrepancies are discussed. The state of knowledge for the atmospheric processing of pinonaldehyde is reviewed, and its role as a marker for alpha-pinene (monoterpene) chemistry in the atmosphere is discussed.
authors.affiliation: Earth System Research Laboratory, National Oceanic and Atmospheric Administration, 325 Broadway, Boulder, Colorado 80305-3328, USA.
authors.forename: Maxine E
authors.initials: ME
authors.lastname: Davis
authors.forename: Ranajit K
authors.initials: RK
authors.lastname: Talukdar
authors.forename: Gregory
authors.initials: G
authors.lastname: Notte
authors.forename: G Barney
authors.initials: GB
authors.lastname: Ellison
authors.forename: James B
authors.initials: JB
authors.lastname: Burkholder
mesh_terms: D000393:Air Pollutants / Q000737:chemistry*; D000447:Aldehydes / Q000737:chemistry*; D001272:Atmosphere / Q000737:chemistry; D003503:Cyclobutanes / Q000737:chemistry*; D006878:Hydroxides / Q000737:chemistry*; D007700:Kinetics; D013696:Temperature
chemical_list: C447863:2,2-dimethyl-3-acetyl-cyclobutyl-ethanal; D000393:Air Pollutants; D000447:Aldehydes; D003503:Cyclobutanes; D006878:Hydroxides