title: Pb(2.63)Cd(2)V(3)O(12), a cation-deficient garnet-type vanadate.
abstract: In the crystal structure of the cation-deficient garnet Pb(2.63)Cd(2)V(3)O(12) (lead cadmium vanadium oxide), the Cd and V atoms fully occupy octahedral and tetrahedral sites, respectively, whereas the Pb atoms partially occupy a dodecahedral site. The total Pb and Cd content indicates that vanadium is slightly reduced from the +5 oxidation state.
authors.affiliation: Department of Chemistry, Moscow State University, 119992 Moscow, Russian Federation.
authors.forename: Alexander A
authors.initials: AA
authors.lastname: Tsirlin
authors.forename: Evgeny V
authors.initials: EV
authors.lastname: Dikarev
authors.forename: Yuri A
authors.initials: YA
authors.lastname: Velikodny
authors.forename: Roman V
authors.initials: RV
authors.lastname: Shpanchenko
authors.forename: Evgeny V
authors.initials: EV
authors.lastname: Antipov