Two-dimensional hopping motion of encapsulated La atoms in silylated La(2)@C(80).
The (139)La NMR study of the exohedrally functionalized derivatives of La(2)@C(80) metallofullerene, La(2)@C(80)(Ar(2)Si)(2)CH(2) (: Ar = Mes, Mes = mesityl, : Ar = Dep, Dep = 2,6-diethylphenyl), reveal that the two La atoms hop between two sites along the equator of the C(80) cage.
Wakahara
Takatsugu
T
Center for Tsukuba Advanced Research Alliance, University of Tsukuba, Tsukuba, Ibaraki 305-8577, Japan.
Yamada
Michio
M
Takahashi
Satomi
S
Nakahodo
Tsukasa
T
Tsuchiya
Takahiro
T
Maeda
Yutaka
Y
Akasaka
Takeshi
T
Kako
Masahiro
M
Yoza
Kenji
K
Horn
Ernst
E
Mizorogi
Naomi
N
Nagase
Shigeru
S