Accounting for the unique, doubly dual nature of ionic liquids from a molecular thermodynamic and modeling standpoint.
The fascinating, complex behavior of ionic liquids is analyzed using a molecular perspective that emphasizes the doubly dual nature of ionic liquids underlying the existence of cations and anions forming high- and low-charge-density regions. Our work bridges the liquid, gas, and solid phases spanning 5 years of research on themes as diverse as the vaporization, liquid-liquid demixing, solidification, and thermophysical behavior of ionic liquids and their mixtures and solutions.
Rebelo
Luís Paulo N
LP
Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa, Av. República, Apartado 127, 2780-901 Oeiras, Portugal. luis.rebelo@itqb.unl.pt
Lopes
José N Canongia
JN
Esperança
José M S S
JM
Guedes
Henrique J R
HJ
Łachwa
Joanna
J
Najdanovic-Visak
Vesna
V
Visak
Zoran P
ZP
D052578:Ionic Liquids / Q000737:chemistry*; D008956:Models, Chemical; D044367:Phase Transition; D013816:Thermodynamics
D052578:Ionic Liquids