The preparation and properties of monodisperse core-shell silica magnetic microspheres.
The monodisperse core-shell silica magnetic microspheres (MMS) were synthesized by sol-gel method gelling in the emulsion. Optical microscope (OM), field emission scanning electron microscope (FESEM), nitrogen adsorption and desorption Brunauer Emmett Teller Procedure (BET) isotherms and Barrett-Joyner-Halenda (BJH) pore size distribution measurements, X-ray diffraction (XRD), energy dispersive spectrometer (EDS) and vibrating sample magnetometer (VSM) were used to characterize the appearance, size distribution, phase, specific surface area, chemical composition and magnetic property of silica MMS. The results showed that silica MMS prepared through sol-gel method with acid-alkali two-step catalyze and gelling in emulsion exhibited the superior core-shell structure and size distribution of the microspheres concentrated in about 20 mum. The main phase of microspheres was amorphous silica and spinel ferroferric oxide. Meanwhile, the microspheres remained the superparamagnetic behavior and could be used as biomaterials.
Lou
Min-yi
MY
School of Material Science and Engineering, Tongji University, Shanghai, 200092, China.
Jia
Qiu-ling
QL
Wang
De-ping
DP
Liu
Bing
B
Huang
Wen-hai
WH
D000327:Adsorption; D001672:Biocompatible Materials / Q000737:chemistry*; D002384:Catalysis; D003460:Crystallization; D005782:Gels; D008280:Magnetics; D008422:Materials Testing; D008855:Microscopy, Electron, Scanning; D008863:Microspheres; D008956:Models, Chemical; D009584:Nitrogen / Q000737:chemistry; D010087:Oxides / Q000737:chemistry*; D010316:Particle Size; D012822:Silicon Dioxide / Q000737:chemistry*; D014961:X-Ray Diffraction
D001672:Biocompatible Materials; D005782:Gels; D010087:Oxides; D012822:Silicon Dioxide; D009584:Nitrogen