title: A novel, facile route to beta-fluoroamines by hydrofluorination using superacid HF-SbF(5).
abstract: A range of unsaturated amines and sulfonamides were converted to beta-fluoro nitrogen analogues after hydrofluorination in superacid HF-SbF(5), based on the formation of highly reactive electrophilic intermediates.
authors.affiliation: Université de Poitiers, CNRS UMR 6514, Laboratoire "Synthèse et Réactivité des Substances Naturelles", F-86022 Poitiers Cedex, France. sebastien.thibaudeau@univ-poitiers.fr
authors.forename: Sébastien
authors.initials: S
authors.lastname: Thibaudeau
authors.forename: Agnès
authors.initials: A
authors.lastname: Martin-Mingot
authors.forename: Marie-Paule
authors.initials: MP
authors.lastname: Jouannetaud
authors.forename: Omar
authors.initials: O
authors.lastname: Karam
authors.forename: Fabien
authors.initials: F
authors.lastname: Zunino
mesh_terms: D000498:Allyl Compounds / Q000737:chemistry; D000588:Amines / Q000138:chemical synthesis*; D000965:Antimony / Q000737:chemistry; D005459:Fluorides / Q000737:chemistry; D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis*; D006858:Hydrofluoric Acid / Q000737:chemistry
chemical_list: D000498:Allyl Compounds; D000588:Amines; D006845:Hydrocarbons, Fluorinated; D000965:Antimony; D005459:Fluorides; D006858:Hydrofluoric Acid