Creating quaternary centers with high exo stereoselectivity using activated alpha-alkynyl dienophiles.
Min
Sun-Joon
SJ
Department of Chemistry, Columbia University, 3000 Broadway, New York, New York 10027, USA.
Jones
Gavin O
GO
Houk
K N
KN
Danishefsky
Samuel J
SJ
D000447:Aldehydes / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D003500:Cyclization; D053138:Cyclohexenes / Q000138:chemical synthesis*; D007659:Ketones / Q000737:chemistry; D008958:Models, Molecular; D013237:Stereoisomerism
D000447:Aldehydes; D000475:Alkenes; D000480:Alkynes; D053138:Cyclohexenes; D007659:Ketones