Bimodal Floquet description of heteronuclear dipolar decoupling in solid-state nuclear magnetic resonance.
A theoretical treatment of heteronuclear dipolar decoupling in solid-state nuclear magnetic resonance is presented here based on bimodal Floquet theory. The conditions necessary for good heteronuclear decoupling are derived. An analysis of a few of the decoupling schemes implemented until date is presented with regard to satisfying such decoupling conditions and efficiency of decoupling. Resonance conditions for efficient heteronuclear dipolar decoupling are derived with and without the homonuclear (1)H-(1)H dipolar couplings and their influence on heteronuclear dipolar decoupling is pointed out. The analysis points to the superior efficiency of the newly introduced swept two-pulse phase-modulation (SW(f)-TPPM) sequence. It is shown that the experimental robustness of SW(f)-TPPM as compared to the original TPPM sequence results from an adiabatic sweeping of the modulation frequencies. Based on this finding alternative strategies are compared here. The theoretical findings are corroborated by both numerical simulations and representative experiments.
Leskes
Michal
M
Department of Chemical Physics, Weizmann Institute of Science, Rehovot 76100, Israel.
Thakur
Rajendra Singh
RS
Madhu
P K
PK
Kurur
Narayanan D
ND
Vega
Shimon
S