Synthesis and spectral properties of some bis-substituted formazans.
Novel, 1,4-bis-[3,3'-phenyl-5,5'-(o-carboxyphenyl)-formaz-1-yl]-benzene-o-sulphonic acid and its derivatives contained OH group at the o-, m-, p-positions of the 3-phenyl ring were synthesized. The structures of the formazans were confirmed by elemental analyses, GC-mass, IR, (1)H NMR, UV-vis spectra. Their absorption properties were investigated. It was seen that lambda(max) values shifted towards shorter wave lengths by 130nm in CSPF relative to 1,3,5-triphenylformazan (TPF) due to the fact that the structure of CSPF contained electron withdrawing COOH and SO(3)H groups (hypsochromic effect). With binding of OH group to 3-phenyl ring of CSPF, it was observed a small bathochromic effect in accordance to the electron donating effect of OH group.
Tezcan
Habibe
H
Department of Chemistry, Gazi University, Faculty of Gazi Education, Teknikokullar, 06500 Ankara, Turkey. habibe@gazi.edu.tr
D004583:Electrons; D004602:Elements; D005562:Formazans / Q000138:chemical synthesis* / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D012997:Solvents; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet
D004602:Elements; D005562:Formazans; D012997:Solvents