title: Stereochemistry of enacyloxins. Part 4: Complete structural and configurational assignment of the enacyloxin family, a series of antibiotics from Frateuria sp. W-315.
abstract: The absolute configurations of the enacyloxins, a series of polyhydroxylated polyene antibiotics from Frateuria species, were determined. The so far elusive (13'R,14'R,15'S)-configuration was assigned to enacycloxin IVa (1) by means of 'J-resolved HMBC-1' and NOESY NMR methods.
authors.affiliation: Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University, 1-1 Tsutsumidori-Amamiya, Aoba-ku, Sendai 981-8555, Japan.
authors.forename: Hiroyuki
authors.initials: H
authors.lastname: Furukawa
authors.forename: Hiromasa
authors.initials: H
authors.lastname: Kiyota
authors.forename: Teiko
authors.initials: T
authors.lastname: Yamada
authors.forename: Manabu
authors.initials: M
authors.lastname: Yaosaka
authors.forename: Ryo
authors.initials: R
authors.lastname: Takeuchi
authors.forename: Toshihiko
authors.initials: T
authors.lastname: Watanabe
authors.forename: Shigefumi
authors.initials: S
authors.lastname: Kuwahara
mesh_terms: D016947:Acetobacteraceae / Q000737:chemistry*; D000900:Anti-Bacterial Agents / Q000737:chemistry* / Q000302:isolation & purification; D008968:Molecular Conformation; D009492:Neurospora crassa / Q000737:chemistry; D011090:Polyenes / Q000737:chemistry* / Q000302:isolation & purification
chemical_list: D000900:Anti-Bacterial Agents; D011090:Polyenes