Multiresidue analytical method of pesticides in peanut oil using low-temperature cleanup and dispersive solid phase extraction by GC-MS.
A method for the determination of 33 pesticides in peanut oil by GC-MS was described. Two extraction procedures based on (i) low-temperature extraction and (ii) liquid-liquid extraction were tested for the optimization of the method. The mixture of anhydrous MgSO(4) with primary secondary amine (PSA) or with PSA and C(18) was performed as sorbents in dispersive SPE. Low temperature along with PSA and C(18) cleanup gave the best results. Pesticides were identified and quantified by GC-MS in SIM mode. The correlation coefficients, R(2), in the linear range tests were better than 0.990. The average recoveries for most pesticides (spiked at 0.02, 0.05, 0.2, and 1 mg/kg) ranged from 70 to 110%, the RSD was below 20% in most instances, and LODs varied from 0.5 to 8 mug/kg.
Li
Li
L
Department of Applied Chemistry, College of Science, China Agricultural University, Beijing, PR China.
Zhang
Hongyan
H
Pan
Canping
C
Zhou
Zhiqiang
Z
Jiang
Shuren
S
Liu
Fengmao
F
D000818:Animals; D002138:Calibration; D003080:Cold Temperature; D005504:Food Analysis / Q000379:methods*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D000074241:Peanut Oil; D010575:Pesticides / Q000032:analysis*; D010938:Plant Oils / Q000737:chemistry*; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D052616:Solid Phase Extraction / Q000379:methods*; D012997:Solvents / Q000737:chemistry
D000074241:Peanut Oil; D010575:Pesticides; D010938:Plant Oils; D012997:Solvents