Synthesis of resorcinol derived spironitronates.
Syntheses of several unique spironitronates are reported. The key transformation involves the first known example of an ipso oxidative cyclization of nitro functionality. Oxidation proceeds from both o- and p-phenols. Reductions of these compounds provide novel spiroisoxazoline derivatives.
Marsini
Maurice A
MA
Department of Chemistry and Biochemistry, University of California at Santa Barbara, Santa Barbara, California 93106-9510, USA.
Huang
Yaodong
Y
Van De Water
Ryan W
RW
Pettus
Thomas R R
TR
D007555:Isoxazoles / Q000138:chemical synthesis*; D009574:Nitro Compounds / Q000737:chemistry; D010636:Phenols; D012118:Resorcinols / Q000737:chemistry*; D013141:Spiro Compounds / Q000737:chemistry
D007555:Isoxazoles; D009574:Nitro Compounds; D010636:Phenols; D012118:Resorcinols; D013141:Spiro Compounds