title: Porous nonlinear-optical material based on a twin-nest-shaped heterothiometallic cluster: {[NH(4)][W(2)O(2)S(6)Cu(6)I(3)(4,4'-bipy)(4)].5H(2)O}n.
abstract: A novel 3D porous coordination complex based on a twin-nest-shaped heterothiometallic cluster has been synthesized and characterized. The complex shows an unprecedented structure type and interesting nonlinear-optical properties. Its gas sorption property was studied and shown to be comparable to that of previously reported metal-organic frameworks.
authors.affiliation: State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, PR China.
authors.forename: Kexuan
authors.initials: K
authors.lastname: Huang
authors.forename: Yinglin
authors.initials: Y
authors.lastname: Song
authors.forename: Zhaorui
authors.initials: Z
authors.lastname: Pan
authors.forename: Yizhi
authors.initials: Y
authors.lastname: Li
authors.forename: Xin
authors.initials: X
authors.lastname: Zhuo
authors.forename: Hegen
authors.initials: H
authors.lastname: Zheng