title: Determination of the anomeric configuration in carbohydrates by longitudinal cross-correlated relaxation studies: application to mono- and disaccharides.
abstract: The role of cross-correlated relaxation between the anomeric proton chemical shift anisotropy (CSA) and its dipolar relaxation with nearby proton on the longitudinal relaxation in mono- and disaccharides at two magnetic field strengths has been investigated and shown to directly report the identity of their anomeric configuration.
authors.affiliation: Department of Chemistry and Biochemistry, Ohio University, Athens, Ohio 45701, USA. pichuman@ohiou.edu
authors.forename: Kumar
authors.initials: K
authors.lastname: Pichumani
authors.forename: Xiang
authors.initials: X
authors.lastname: Zou
authors.forename: Tilak
authors.initials: T
authors.lastname: Chandra
authors.forename: Kenneth L
authors.initials: KL
authors.lastname: Brown
mesh_terms: D000465:Algorithms; D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D004187:Disaccharides / Q000737:chemistry*; D005947:Glucose / Q000737:chemistry; D007536:Isomerism; D007785:Lactose / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008320:Maltose / Q000737:chemistry; D008969:Molecular Sequence Data; D011522:Protons
chemical_list: D004187:Disaccharides; D011522:Protons; D008320:Maltose; D005947:Glucose; D007785:Lactose