Dinitrogen activation at ambient temperatures: new modes of H(2) and PhSiH(3) additions for an "End-On-Bridged" [Ta(IV)](2)(mu-eta(1):eta(1)-N(2)) complex and for the bis(mu-nitrido) [Ta(V)(mu-N)](2) product derived from facile NN bond cleavage.
Hirotsu
Masakazu
M
Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA.
Fontaine
Philip P
PP
Epshteyn
Albert
A
Zavalij
Peter Y
PY
Sita
Lawrence R
LR