Adsorption of water on three-dimensional pillared-layer metal organic frameworks.
We showed water adsorption isotherms at 303 K on water-resistant three-dimensional (3-D) pillared-layer metal organic frameworks (MOFs) with 1-D semi-rectangular pores, of which size depends on the length of ligand. The shapes of all three adsorption isotherms are type I by IUPAC classification showing strong water-MOFs interaction. The adsorbed amount of water molecules on the hydrophilic site of carboxylic group in 2-D sheets coincided with the crystal water amount. The adsorption on the hydrophilic sites occurs at similar relative pressure even if the used ligand is different.
Kondo
Atsushi
A
Graduate School of Science and Technology, Chiba University, Yayoi, Inage, Chiba 263-8522, Japan.
Daimaru
Takamichi
T
Noguchi
Hiroshi
H
Ohba
Tomonori
T
Kaneko
Katsumi
K
Kanoh
Hirofumi
H