title: Stereoselective synthesis of 1,2-aminoalcohols by [2,3]-wittig rearrangements.
abstract: [2,3]-Wittig rearrangements of (E)-3-aza-allylic alcohol derivatives can provide access to functionalized 1,2-aminoalcohols with high syn or anti diastereoselectivity depending on the anionic stabilizing group (amide or alkyne).
authors.affiliation: Laboratoire de Chimie Organique, ESPCI, CNRS, 10 rue Vauquelin 75231 Paris Cedex 05, France.
authors.forename: Marion
authors.initials: M
authors.lastname: Barbazanges
authors.forename: Christophe
authors.initials: C
authors.lastname: Meyer
authors.forename: Janine
authors.initials: J
authors.lastname: Cossy
mesh_terms: D000438:Alcohols; D000480:Alkynes; D000577:Amides; D000605:Amino Alcohols / Q000138:chemical synthesis*; D013237:Stereoisomerism
chemical_list: D000438:Alcohols; D000480:Alkynes; D000577:Amides; D000605:Amino Alcohols