Synthesis and properties of mononuclear and binuclear molybdenum complexes derived from bis(2-hydroxy-1-naphthaldehyde)oxaloyldihydrazone.
The monomer molybdenum(VI) complex [MoO(2)(napoxlhH(2))].2H(2)O (1) has been synthesized from the reaction of MoO(2)(acac)(2) with bis(2-hydroxy-1-naphthaldehyde)oxaloyldihydrazone (napoxlhH(4)) in 1:1 molar ratio in ethanol under reflux. This complex on reaction with pyridine/3-picoline/4-picoline yielded the dimer molybdenum(VI) complexes [Mo(2)O(4)(napoxlhH(2))(2)(A)(2)].2H(2)O (A=py (2), 3-pic (3), 4-pic (4)), whereas reaction with isonicotinoylhydrazine (inhH(3)) and salicyloylhydrazine (sylshH(3)) lead to the reduction of the metal centre yielding monomeric molybdenum(V) complexes [Mo(napoxlhH(2))(hzid)].2H(2)O (where hzidH(3)=inhH(3) (5) and sylshH(3) (6)). The complexes have been characterized by elemental analyses, molecular weight determinations, molar conductance data, magnetic moment data, electronic, IR, ESR and (1)H NMR spectroscopic studies. The complexes (5) and (6) are paramagnetic to the extent of one unpaired electron. The electronic spectra of the complexes are dominated by strong charge transfer bands. In all of the complexes, the principal dihydrazone ligand has been suggested to coordinate to the metal centres in the anti-cis-configuration. The complexes (1), (5) and (6) are suggested to have six-coordinate octahedral stereochemistry around molybdenum(VI) and molybdenum(V) metal centres, respectively, while the complexes (2)-(4) are suggested to have eight coordinate dodecahedral stereochemistry around molybdenum(VI) metal centre.
Lal
Ram A
RA
Department of Chemistry, North-Eastern Hill University, Shillong 793022, Meghalaya, India. lal_198@rediffmail.com
Basumatary
Debajani
D
Adhikari
Syamal
S
Kumar
Arvind
A
D004578:Electron Spin Resonance Spectroscopy; D004583:Electrons; D006835:Hydrazones / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008280:Magnetics; D008970:Molecular Weight; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013056:Spectrophotometry, Ultraviolet; D013696:Temperature
D006835:Hydrazones; D009942:Organometallic Compounds; D008982:Molybdenum