Complete (1)H and (13)C NMR spectral assignment of alpha- and beta-adenosine, 2'-deoxyadenosine and their acetate derivatives.
(1)H and (13)C NMR chemical shifts of alpha- and beta-anomers of adenosine, 2'-deoxyadenosine and their acetate derivatives were completely and definitely assigned using the concerted application of one- and two-dimensional experiments (gCOSY, gNOESY, gHSQC and gHMBC). The influence of the stereochemistry of the purine base on the NMR data of the hydrogen and carbon atoms of the furanose moiety was estimated.
Ciuffreda
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Dipartimento di Scienze Precliniche LITA Vialba, Università degli Studi di Milano, Via G.B. Grassi, 74-20157 Milano, Italy.
Casati
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Manzocchi
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D000085:Acetates / Q000737:chemistry; D000241:Adenosine / Q000031:analogs & derivatives* / Q000737:chemistry*; D003839:Deoxyadenosines / Q000737:chemistry*; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D013237:Stereoisomerism
D000085:Acetates; D003839:Deoxyadenosines; D007202:Indicators and Reagents; D000241:Adenosine; C058118:2'-deoxyadenosine