Effect of dendrimer generation on electron self-exchange kinetics between metal tris(bipyridine) core dendrimers.
Here we report the first measurement of homogeneous electron transfer between oxidized and reduced metal tris(bipyridine) core dendrimers by NMR line-broadening; the results indicated that, as the generation of the dendrimer increased, the rate of self-exchange decreased.
Hong
Young-Rae
YR
Department of Chemistry, North Carolina State University, Box 8204, Raleigh, NC 27695-8204, USA.
Gorman
Christopher B
CB