Ultrasonic destruction of bisphenol-A: the operating parameters.
Degradation of bisphenol-A (BPA) by ultrasonic irradiation at 300 kHz was investigated at varying substrate concentrations, pH, hydroxyl radical scavengers and sparge gases. It was found that increases in BPA initial concentration slowed down the reaction rate, but enhanced the sonochemical product yield. Both the rate of reaction and the product yield were adversely affected by pH elevation above the neutral level. The degree of BPA decay was fastest in the presence of air due to the formation of acids and excess radicals, and slowed down as the gas was replaced by argon and oxygen. The impact of large concentrations of hydroxyl radical scavengers such as carbonate and t-butanol was to decrease the rate of degradation, particularly when the scavenger concentration was considerably larger than that of BPA, and the deceleration was more remarkable in the presence of t-butanol than in that of carbonate.
Gültekin
Isil
I
Bogazici University, Institute of Environmental Sciences, 34342 Bebek, Istanbul, Turkey.
Ince
Nilsun H
NH
Bogazici University, Institute of Environmental Sciences, 34342 Bebek, Istanbul, Turkey. Electronic address: ince@boun.edu.tr.
D000465:Algorithms; D001559:Benzhydryl Compounds; D002254:Carbonates / Q000737:chemistry; D016166:Free Radical Scavengers; D005740:Gases; D006861:Hydrogen Peroxide / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D017665:Hydroxyl Radical; D016877:Oxidants; D010636:Phenols / Q000528:radiation effects*; D013056:Spectrophotometry, Ultraviolet; D014465:Ultrasonics; D020002:tert-Butyl Alcohol / Q000737:chemistry; D000098826:Bisphenol A Compounds
D001559:Benzhydryl Compounds; D002254:Carbonates; D016166:Free Radical Scavengers; D005740:Gases; D006861:Hydrogen Peroxide; D017665:Hydroxyl Radical; D016877:Oxidants; D010636:Phenols; D020002:tert-Butyl Alcohol; C005686:sodium carbonate; C006780:bisphenol A; D000098826:Bisphenol A Compounds