title: Hydrothermal petroleum from lacustrine sedimentary organic matter in the East African Rift.
abstract: Cape Kalamba oil seeps occur at the south end of the Ubwari Peninsula, at the intersection of faults controlling the morphology of the northern basin of the Tanganyika Rift, East Africa. Oil samples collected at the surface of the lake 3-4 km offshore from Cape Kalamba have been studied. The aliphatic hydrocarbon and biomarker compositions, with the absence of the typical suite of polynuclear aromatic hydrocarbons, indicate an origin from hydrothermal alteration of immature microbial biomass in the sediments. These data show a similarity between a tar sample from the beach and the petroleum from the oil seeps, and confirm that the source of these oils is from organic matter consisting mainly of bacterial and degraded algal biomass, altered by hydrothermal activity. The compositions also demonstrate a < 200 degrees C temperature for formation/generation of this hydrothermal petroleum, similar to the fluid temperature identified for the Pemba hydrothermal site located 150 km north of Cape Kalamba. The 14C age of 25.6 ka B.P. obtained for the tar ball suggests that Pleistocene lake sediments could be the source rock. Hydrothermal generation may have occurred slightly before 25 ka B.P., during a dry climatic environment, when the lake level was lower than today. These results also suggest that the Cape Kalamba hydrothermal activity did not occur in connection with an increased flux of meteoric water, higher water tables and lake levels as demonstrated in the Kenya Rift and for the Pemba site. Hydrothermal petroleum formation is a facile process also in continental rift systems and should be considered in exploration for energy resources in such locales.
authors.affiliation: Petroleum and Environmental Geochemistry Group, Oregon State University, Corvallis 97331, USA.
authors.forename: B R
authors.initials: BR
authors.lastname: Simoneit
authors.forename: T A
authors.initials: TA
authors.lastname: Aboul-Kassim
authors.forename: J J
authors.initials: JJ
authors.lastname: Tiercelin
mesh_terms: D000351:Africa, Eastern; D015415:Biomarkers / Q000032:analysis; D018533:Biomass; D004783:Environmental Microbiology; D056890:Eukaryota; D005618:Fresh Water; D019015:Geologic Sediments / Q000032:analysis / Q000737:chemistry* / Q000382:microbiology; D055593:Geological Phenomena; D005844:Geology; D006358:Hot Temperature; D006838:Hydrocarbons / Q000032:analysis*; D006841:Hydrocarbons, Aromatic / Q000032:analysis; D010578:Petroleum / Q000032:analysis* / Q000382:microbiology; D013638:Tars / Q000032:analysis
chemical_list: D015415:Biomarkers; D006838:Hydrocarbons; D006841:Hydrocarbons, Aromatic; D010578:Petroleum; D013638:Tars