Biomimetic fat cell (BFC) modification and for lindane removal from aqueous solution.
To improve the regeneration ability of biomimetic fat cell (BFC), an innovative agent for hydrophobic organic contaminants (HOCs) removal, BFC was modified through introducing 1, 3, 5-benzenetricarboxyl trichloride with trifunctional group and heterocyclic piperazine in this research. Modified biomimetic fat cell (MBFC) has a good lindane removal capacity close to that of BFC and powder activated carbon (PAC), and the lindane removal is 97.68, 96.65 and 98.36% with 7 mg/L lindane initial concentration, respectively. At the same time, 20 mg/L MBFC or PAC is sufficient for 10 microg/L lindane removal, and in 20-60 mg/L doses range the lindane removal by both MBFC and PAC can reach 99.0%; When the doses is below 10 mg/L, MBFC showed better lindane removal than PAC and MBFC even could reach 96.8% lindane removal in 5 mg/L dose. Lindane removal by MBFC could be held on 95% above in first 6-time reuse. Though the lindane removal by MBFC decreased with the reuse time increasing, MBFC still could remove 80 % lindane after 9 times regeneration. In contract with BFC, MBFC showed obvious advantage on the regeneration. The lindane removal mechanism by MBFC, similar with BFC, includes bioaccumulation by MBFC nucleolus-triolein and adsorption by MBFC membrane, and the bioaccumulation is the main way.
Liyan
Song
S
State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China. songly@msu.edu
Youcai
Zhao
Z
Guojian
Wang
W
Bing
Li
L
Dongjie
Niu
N
Xiaoli
Chai
C
D000327:Adsorption; D032701:Biomimetics; D002625:Chemistry, Organic / Q000379:methods; D002712:Chlorides / Q000737:chemistry; D001556:Hexachlorocyclohexane / Q000032:analysis / Q000737:chemistry*; D008855:Microscopy, Electron, Scanning; D008956:Models, Chemical; D009930:Organic Chemicals / Q000737:chemistry; D013696:Temperature; D013818:Thermogravimetry; D013997:Time Factors; D014865:Waste Disposal, Fluid / Q000379:methods; D014867:Water / Q000737:chemistry*; D014874:Water Pollutants, Chemical; D018508:Water Purification / Q000379:methods*
D002712:Chlorides; D009930:Organic Chemicals; D014874:Water Pollutants, Chemical; D014867:Water; D001556:Hexachlorocyclohexane