A coordination polymer strategy for anion encapsulation: anion-pi interactions in (4,4) nets formed from Ag(I) salts and a flexible pyrimidine ligand.
Anions encapsulated by a uniform mode of anion-pi binding in isomorphous (4,4) nets formed from Ag(I) salts and bis(4-pyrimidylmethyl)sulfide appear to be structurally directing.
Black
Cory A
CA
Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.
Hanton
Lyall R
LR
Spicer
Mark D
MD