Accidental release of toxic chemicals: influence of the main input parameters on consequence calculation.
In the present paper the accidental release of toxic chemicals has been taken into consideration, and a sensitivity analysis study of the corresponding consequences calculation has been carried out. Four different toxic chemicals have been chosen for the simulations, and the effect of the variability of the main input parameters on the extension of the impact areas has been assessed. The results show that the influence of these parameters depends on the physical properties of the released substance and that not always the widely known rules of thumb, such as the positive influence of the wind velocity on gas dispersion, apply. In particular, the boiling temperature of the chemical has revealed to be the main parameter affecting the type of dependence of the impact distances on the input variables.
Bubbico
Roberto
R
Dipartimento di Ingegneria Chimica, Università di Roma La Sapienza, Via Eudossiana 18, 00184 Roma, Italy. bubbico@ingchim.ing.uniroma1.it
Mazzarotta
Barbara
B
D000059:Accidents; D000393:Air Pollutants; D000641:Ammonia / Q000032:analysis; D001966:Bromine / Q000032:analysis; D002627:Chemistry, Physical / Q000379:methods; D003198:Computer Simulation; D004784:Environmental Monitoring / Q000379:methods*; D004785:Environmental Pollutants; D015386:Hazardous Substances / Q000032:analysis*; D006851:Hydrochloric Acid / Q000032:analysis; D008744:Methylamines / Q000032:analysis; D015203:Reproducibility of Results; D012306:Risk; D013696:Temperature; D014887:Weather; D014919:Wind
D000393:Air Pollutants; D004785:Environmental Pollutants; D015386:Hazardous Substances; D008744:Methylamines; D000641:Ammonia; C023336:trimethylamine; D006851:Hydrochloric Acid; D001966:Bromine