Selective ligand conversion of ethylenediamine tetraacetate to its triacetate on peroxotitanate(IV).
Ethylenediaminetetraacetate is converted into its triacetate by peroxotitanate(IV), and strong chelation of the triacetate ligand to the metal center facilitates elimination of the pendant acetoxylate group. Various species of peroxotitanium(IV) complexes in the reaction sequence are fully characterized.
Zhou
Zhao-Hui
ZH
Department of Chemistry, College of Chemistry and Chemical Engineering and State Key Laboratory for Physical Chemistry of Solid Surfaces, Xiamen University, Xiamen 361005, China. zhzhou@xmu.edu.cn
Deng
Yuan-Fu
YF
Liu
Qiong-Xin
QX
Zhang
Hua-Lin
HL
Mak
Thomas C W
TC
Chow
Yuan L
YL