title: Mechanistic studies of the photocatalytic degradation of methyl green: an investigation of products of the decomposition processes.
abstract: The methyl green (MG) dye dissolves into an alkaline solution when the pH value is too high (pH 9). The cationic MG dye molecules are converted into the colorless carbinol base (CB) and produce crystal violet (CV) dye and ethanol by hydroxide anion. Thirty-three intermediates of the process were separated, identified, and characterized by HPLC-ESI-MS technique in this study and their evolution during the photocatalytic reaction is presented. Moreover, the other intermediates formed in the photocatalytic degradation MG processes were separated and identified by HPLC-PDA technique. The results indicated that the N-de-methylated degradation of CV dye took place in a stepwise manner to yield N-de-methylated CV species, and the N-de-alkylated degradation of CB also took place in a stepwise manner to yield N-de-alkylated CB species generated during the processes. Moreover, the oxidative degradation of the CV dye (or CB) occurs to yield 4-(N,N-dimethylamino)phenol (DAP), 4-(N,N-dimethylamino)-4'-(N',N'-dimethylamino)benzophenone (DDBP) and their N-de-methylated products [or to yield 4-(N-ethyl-N,N-dimethyl)aminophenol (EDAP), DDBP, 4-(N-ethyl-N,N-dimethylamino)-4'-(N',N'-dimethylamino)benzophenone (EDDBP), DAP, and their N-de-alkylated products], which were found for the first time. A proposed degradation pathway of CV and CB is presented, involving mainly the N-de-alkylation and oxidation reaction.
authors.affiliation: Department of General Education, National Taichung Nursing College, Taichung 403, Taiwan, ROC. ccchen@ntcnc.edu.tw
authors.forename: Chiing-Chang
authors.initials: CC
authors.lastname: Chen
authors.forename: Chung-Shin
authors.initials: CS
authors.lastname: Lu
mesh_terms: D002851:Chromatography, High Pressure Liquid; D052918:Environmental Restoration and Remediation; D005840:Gentian Violet / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D008027:Light; D000432:Methanol / Q000737:chemistry; D008739:Methyl Green / Q000737:chemistry*; D010777:Photochemistry; D021241:Spectrometry, Mass, Electrospray Ionization
chemical_list: D008739:Methyl Green; D005840:Gentian Violet; D000432:Methanol