title: The reaction of [Bu4N]2[Pd2Br6(Se2N2)] with [14]aneS4; an effective source of the diselenium dinitride unit.
abstract: Reaction of [Bu(4)N](2)[Pd(2)Br(6)(Se(2)N(2))] with [14]aneS(4) results in eventual formation of Se(4)N(4); intermediates in this reaction include an air-sensitive insoluble material which reacts with [PtCl(2)(PMe(2)Ph)](2) to give the first example of a platinum adduct of Se(2)N(2) and with [Pd(2)Br(6)](2-) to regenerate the starting material.
authors.affiliation: Department of Chemistry, Loughborough University, Leics, UK LE11 3TU.
authors.forename: Stephen M
authors.initials: SM
authors.lastname: Aucott
authors.forename: Dennis
authors.initials: D
authors.lastname: Drennan
authors.forename: Sarah L M
authors.initials: SL
authors.lastname: James
authors.forename: Paul F
authors.initials: PF
authors.lastname: Kelly
authors.forename: Alexandra M Z
authors.initials: AM
authors.lastname: Slawin