Porous nonlinear-optical material based on a twin-nest-shaped heterothiometallic cluster: {[NH(4)][W(2)O(2)S(6)Cu(6)I(3)(4,4'-bipy)(4)].5H(2)O}n.
A novel 3D porous coordination complex based on a twin-nest-shaped heterothiometallic cluster has been synthesized and characterized. The complex shows an unprecedented structure type and interesting nonlinear-optical properties. Its gas sorption property was studied and shown to be comparable to that of previously reported metal-organic frameworks.
Huang
Kexuan
K
State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, PR China.
Song
Yinglin
Y
Pan
Zhaorui
Z
Li
Yizhi
Y
Zhuo
Xin
X
Zheng
Hegen
H