Stereoselective synthesis of (E)- and (Z)-enol ethers from beta-amino aldehydes.
Stereocontrolled methods for the direct and divergent synthesis of the silylenol ethers possessing amino group from beta-amino aldehydes have been achieved. These enol ethers with the defined olefin geometry could be key building blocks for the synthesis of the medicinally impor tant compounds.
College of Pharmacy, Chungbuk National University, Cheongju 361-763, Korea.
Jin-Kyung
JK
In
Mi-Sung
MS
Lee
Min-Woo
MW
Lee
Jae-Hwan
JH
Kwak
Heesoon
H
Lee
Jin Tae
JT
Hong
Yongseog
Y
Chung
Yongseok
Y
Choi
Jae-Kyung
JK
Jung
D000447:Aldehydes / Q000737:chemistry*; D000475:Alkenes / Q000737:chemistry; D000478:Alkylation; D001593:Benzyl Compounds / Q000138:chemical synthesis; D004987:Ethers / Q000138:chemical synthesis*; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D008745:Methylation; D012821:Silanes / Q000138:chemical synthesis; D013237:Stereoisomerism
D000447:Aldehydes; D000475:Alkenes; D001593:Benzyl Compounds; D004987:Ethers; D007202:Indicators and Reagents; D012821:Silanes