A simple method to determine kinetic deuterium isotope effects provides evidence that proton transfer to carbon proceeds over and not through the reaction barrier.
Department of Chemistry, University at Buffalo, Buffalo, New York 14260, USA.
Wing-Yin
WY
Tsang
John P
JP
Richard
D002244:Carbon / Q000737:chemistry*; D003903:Deuterium; D007700:Kinetics; D015394:Molecular Structure; D011522:Protons
D011522:Protons; D002244:Carbon; D003903:Deuterium