Kinetics and branching ratio studies of the reaction of C2H5O2 + HO2 using chemical ionisation mass spectrometry.
The overall rate coefficient for the reaction of C(2)H(5)O(2) with HO(2) was determined using a turbulent flow chemical ionization mass spectrometer (TF-CIMS) system over the pressure range of 75 to 200 Torr and temperatures between 195 and 298 K. The temperature dependence of the overall rate coefficient for the reaction between C(2)H(5)O(2) and HO(2) was fitted using the following Arrhenius expression: k(T) = (2.08) x 10(-13) exp [(864 +/- 79)/T] cm(-3) molecule(-1) s(-1). The upper limits for the branching ratios for reactive channels leading to O(3) and OH production were quantified for the first time. A tropospheric model has been used to assess the impact of the experimental error of the rate coefficients determined in this study on predicted concentrations of a number of key species, including O(3), OH, HO(2), NO and NO(2). In all cases it is found that the propagated error is very small and will not in itself be a major cause of uncertainty in modelled concentrations. However, at low temperatures, where there is a wide discrepancy between existing kinetic studies, modelling using the range of kinetic data in the literature shows a small but significant variation for [C(2)H(5)O(2)], [C(2)H(5)OOH], [NO(x)] and the HO(2) : OH ratio. Furthermore, a structure-activity relationship (SAR) was developed to rationalise the reactivity of the reaction between RO(2) and HO(2).
The School of Earth, Atmospheric and Environmental Science, The University of Manchester, Sackville Street, Manchester, UK.
M
M
Teresa Raventós-Duran
Carl J
CJ
Percival
Max R
MR
McGillen
Paul D
PD
Hamer
Dudley E
DE
Shallcross
D004867:Equipment Design; D005998:Glycine / Q000737:chemistry*; D006838:Hydrocarbons / Q000737:chemistry; D017665:Hydroxyl Radical; D007700:Kinetics; D013058:Mass Spectrometry / Q000379:methods*; D008956:Models, Chemical; D008962:Models, Theoretical; D010100:Oxygen / Q000737:chemistry; D010126:Ozone / Q000737:chemistry; D010545:Peroxides / Q000737:chemistry*; D011312:Pressure; D013329:Structure-Activity Relationship; D013696:Temperature; D013997:Time Factors
D006838:Hydrocarbons; D010545:Peroxides; C049375:perhydroxyl radical; D017665:Hydroxyl Radical; D010126:Ozone; D010100:Oxygen; D005998:Glycine