Amineborane dehydrogenation promoted by isolable zirconium sandwich, titanium sandwich and N(2) complexes.
Catalytic dehydrogenation of R(2)NHBH(3) (R = Me, H) promoted by a family of bis(cyclopentadienyl)titanium and bis(indenyl)zirconium compounds is reported; structure-reactivity relationships as a function of cyclopentadienyl and indenyl substituents have been examined.
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, NY 14853, USA.
Doris
D
Pun
Emil
E
Lobkovsky
Paul J
PJ
Chirik