Long-lived and efficient emission from mononuclear amidophosphine complexes of copper.
A number of structurally unusual, monomeric amidophosphine complexes of copper exhibit luminescence properties that are unprecedented for monocopper systems in solution at room temperature. The complexes exhibit lifetimes as long as 150 micros in benzene and quantum efficiencies in the range of 0.16<phi<0.70.
Division of Chemistry and Chemical Engineering, Arnold and Mabel Beckman Laboratories of Chemical Synthesis, California Institute of Technology, Pasadena, California 91125, USA.
Alexander J M
AJ
Miller
Jillian L
JL
Dempsey
Jonas C
JC
Peters
D003300:Copper / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D010777:Photochemistry; D013997:Time Factors
D009942:Organometallic Compounds; D010720:Phosphines; D003300:Copper