Bifunctional ligand approach for constructing 3d-4f heterometallic clusters.
Using a predesigned Schiff-base tripodal ligand, a heptanuclear CuII-GdIII cluster with a spin ground state of S=17/2 has been synthesized.
Wu
Gang
G
Institut für Anorganische Chemie der Universität Karlsruhe, Engesserstrasse Geb. 30.45, D-76128 Karlsruhe, Germany.
Hewitt
Ian J
IJ
Mameri
Samir
S
Lan
Yanhua
Y
Clérac
Rodolphe
R
Anson
Christopher E
CE
Qiu
Shilun
S
Powell
Annie K
AK