Efficient chirality transfer in the SmI2-mediated cyclization of aldehydo beta-alkoxyvinyl sulfoxides: asymmetric synthesis of 3-hydroxyoxanes.
Stereoselective syntheses of 3-hydroxyoxanes were achieved via efficient chirality transfer in the SmI2-mediated cyclization reactions of aldehydo beta-alkoxyvinyl sulfoxides.
Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.
Jae Hoon
JH
Jung
Yong Wook
YW
Kim
Min Ah
MA
Kim
Soo Young
SY
Choi
Young Keun
YK
Chung
Tae-Rae
TR
Kim
Seokmin
S
Shin
Eun
E
Lee
D003500:Cyclization; D007454:Iodides; D010545:Peroxides / Q000138:chemical synthesis*; D012493:Samarium; D013237:Stereoisomerism; D013454:Sulfoxides / Q000737:chemistry*
D007454:Iodides; D010545:Peroxides; D013454:Sulfoxides; D012493:Samarium; C409809:samarium diiodide