Synthesis and structural characterization of cross-linked histidine-phenol Cu(ii) complexes as cytochrome c oxidase active site models.
Tridentate cross-linked histidine-phenol Cu(ii) ether and ester complexes, chemical analogs of the active site of several heme-copper oxidases, have been synthesized and crystallized.
Department of Chemistry and Biochemistry, University of California, Santa Cruz, CA 95064, USA.
Kimberly N
KN
White
Indranil
I
Sen
Istvan
I
Szundi
Yakira R
YR
Landaverry
Lauren E
LE
Bria
Joseph P
JP
Konopelski
Marilyn M
MM
Olmstead
Olöf
O
Einarsdóttir
D003300:Copper / Q000737:chemistry*; D003432:Cross-Linking Reagents; D003576:Electron Transport Complex IV / Q000737:chemistry* / Q000378:metabolism; D006639:Histidine / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D019800:Phenol / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet
D003432:Cross-Linking Reagents; D008024:Ligands; D019800:Phenol; D006639:Histidine; D003300:Copper; D003576:Electron Transport Complex IV