Can Sn(OCH2CH2NMe2)2 behave as a stannylene? Equatorial-axial isomerism in the tin(II)-iron(0) complex (Me2NCH2CH2O)2Sn-Fe(CO)4.
Equatorial-axial isomerism of the tin(II)-iron(0) complex (Me2NCH2CH2O)2Sn-Fe(CO)4 (), which indicates that the free Sn(OCH2CH2NMe2)2 () ligand can behave as a stannylene, has been revealed and studied by NMR and IR spectroscopy in solution as well as by Raman spectroscopy and X-ray diffraction analysis in the solid-state.
A. N. Nesmeyanov Institute of Organoelement Compounds RAS, Vavilov St., 28, Moscow, 119991, Russian Federation. vkh@xray.ineos.ac.ru
Victor N
VN
Khrustalev
Ivan A
IA
Portnyagin
Mikhail S
MS
Nechaev
Sergey S
SS
Bukalov
Larissa A
LA
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