Long-range ordering effect in electrodeposition of zinc and zinc oxide.
In this paper, we report the long-range ordering effect observed in the electro-crystallization of Zn and ZnO from an ultrathin aqueous electrolyte layer of ZnSO4 . The deposition branches are regularly angled, covered with random-looking, scalelike crystalline platelets of ZnO. Although the orientation of each crystalline platelet of ZnO appears random, transmission electron microscopy shows that they essentially possess the same crystallographic orientation as the single-crystalline zinc electrodeposit underneath. Based on the experimental observations, we suggest that this unique long-range ordering effect results from an epitaxial nucleation effect in electrocrystallization.
Liu
Tao
T
National Laboratory of Solid State Microstructures & Department of Physics, Nanjing University, Nanjing, China.
Wang
Sheng
S
Shi
Zi-Liang
ZL
Ma
Guo-Bin
GB
Wang
Mu
M
Peng
Ru-Wen
RW
Hao
Xi-Ping
XP
Ming
Nai-Ben
NB