Can Sn(OCH2CH2NMe2)2 behave as a stannylene? Equatorial-axial isomerism in the tin(II)-iron(0) complex (Me2NCH2CH2O)2Sn-Fe(CO)4.
Equatorial-axial isomerism of the tin(II)-iron(0) complex (Me2NCH2CH2O)2Sn-Fe(CO)4 (), which indicates that the free Sn(OCH2CH2NMe2)2 () ligand can behave as a stannylene, has been revealed and studied by NMR and IR spectroscopy in solution as well as by Raman spectroscopy and X-ray diffraction analysis in the solid-state.
Khrustalev
Victor N
VN
A. N. Nesmeyanov Institute of Organoelement Compounds RAS, Vavilov St., 28, Moscow, 119991, Russian Federation. vkh@xray.ineos.ac.ru
Portnyagin
Ivan A
IA
Nechaev
Mikhail S
MS
Bukalov
Sergey S
SS
Leites
Larissa A
LA