Electronic effects on the selectivity of pd-catalyzed C-N bond-forming reactions using biarylphosphine ligands: the competitive roles of amine binding and acidity.
Department of Chemistry, Room 18-490, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.
Mark R
MR
Biscoe
Timothy E
TE
Barder
Stephen L
SL
Buchwald
D000588:Amines / Q000737:chemistry; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D003510:Cyclohexanes / Q000737:chemistry*; D008024:Ligands; D009584:Nitrogen / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*
D000588:Amines; D003510:Cyclohexanes; D008024:Ligands; D009942:Organometallic Compounds; D010720:Phosphines; D010165:Palladium; D002244:Carbon; D009584:Nitrogen