Yielding in colloidal gels due to nonlinear microstructure bending mechanics.
We report measurements of the nonlinear micromechanics of strongly flocculated model colloidal aggregates. Linear aggregates directly assembled using laser tweezers are subjected to bending loads until a critical bending moment is reached, which is identified by a stictionlike rearrangement of a single colloidal bond. This nanoscale phenomenon provides a quantitative basis for understanding the macroscopic shear yield stresses of strongly flocculated polystyrene latex gels, based on the maximum bending moment exceeding the critical moment of the constituent colloidal bonds of the gel microstructure. These mechanics are consistent with the local bending moment overcoming the static friction force between neighboring adhesive particles. This results in a direct relationship between the rheology of these gels and the boundary friction between Brownian particles.
Colburn Laboratory, Department of Chemical Engineering, University of Delaware, Newark, DE 19716, USA. furst@udel.edu
Eric M
EM
Furst
John P
JP
Pantina