Characterization and alkane oxidation activity of a diastereopure seven-coordinate iron(III) alkylperoxo complex.
Spectroscopic characterization and alkane oxidation studies of a diastereopure seven-coordinate high-spin iron(iii) alkylperoxo complex based on the chiral N,N',N-bis(l-prolinate)pyridine ligand Py(ProMe)(2) () are reported.
Organic Chemistry and Catalysis, Utrecht University, Padualaan 8, 3584, CH Utrecht, The Netherlands.
Silvia
S
Gosiewska
Ernst E
EE
van Faassen
Hjalmar P
HP
Permentier
Andries P
AP
Bruins
Gerard
G
van Koten
Robertus J M Klein
RJ
Gebbink
D000218:Adamantane / Q000737:chemistry; D000473:Alkanes / Q000737:chemistry*; D005290:Ferric Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D010084:Oxidation-Reduction; D011392:Proline / Q000031:analogs & derivatives / Q000737:chemistry; D013237:Stereoisomerism
D000473:Alkanes; D005290:Ferric Compounds; D011392:Proline; D000218:Adamantane