Polarizability of helium and gas metrology.
Using a quasispherical, microwave cavity resonator, we measured the refractive index of helium to deduce its molar polarizability A(epsilon) in the limit of zero density. We obtained (A(epsilon,meas) - A(epsilon,theory))/A(epsilon) = (-1.8 +/- 9.1) x 10(-6), where the standard uncertainty (9.1 ppm) is a factor of 3.3 smaller than that of the best previous measurement. If the theoretical value of A(epsilon) is accepted, these data determine a value for the Boltzmann constant that is only 1.8 +/- 9.1 ppm larger than the accepted value. Our techniques will enable a helium-based pressure standard and measurements of thermodynamic temperatures.
Process Measurements Division, National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8360, USA.
J W
JW
Schmidt
R M
RM
Gavioso
E F
EF
May
M R
MR
Moldover