Slow dynamics and aging in colloidal gels studied by x-ray photon correlation spectroscopy.
Slow, nonequilibrium dynamics during delayed sedimentation in a colloidal depletion gel was studied by x-ray photon correlation spectroscopy. The intermediate scattering functions change during the process from stretched to compressed exponential decays, indicating a jamming transition toward full aging. A complex aging behavior follows this process; it is proposed that large-scale network deformations trigger an unjamming, leading to the final collapse of the gel.
European Synchrotron Radiation Facility, Boîte Postale 220, F-38043 Grenoble, France.
Andrei
A
Fluerasu
Abdellatif
A
Moussaïd
Anders
A
Madsen
Andrew
A
Schofield