Cellulose tris(3,5-dichlorophenylcarbamate) immobilised on silica: a novel chiral stationary phase for resolution of enantiomers.
CHIRALPAK IC is a new chiral stationary phase (CSP) made by immobilising cellulose tris(3,5-dichlorophenylcarbamate) on silica gel. The chiral selector is distinct from any other commercially available polysaccharide-based CSPs. Apart from its compatibility with the whole series of solvents; this CSP is able to operate under various chromatographic conditions and bring about new characteristics in enantiomeric recognition. It can afford many large and specific enantiomeric separations. It exhibits complementary properties with regard to the existing immobilised chiral packing materials of the same category.
Chiral Technologies Europe, Parc d'Innovation, Bd. Gonthier d'Andernach, 67404 Illkirch Cedex, France. tzhang@chiral.fr <tzhang@chiral.fr>
Tong
T
Zhang
Dung
D
Nguyen
Pilar
P
Franco
Yutaka
Y
Isobe
Takashi
T
Michishita
Tatsushi
T
Murakami
D002482:Cellulose / Q000031:analogs & derivatives* / Q000737:chemistry; D002851:Chromatography, High Pressure Liquid; D015394:Molecular Structure; D048448:Phenylcarbamates / Q000737:chemistry*; D012822:Silicon Dioxide / Q000737:chemistry; D012997:Solvents / Q000737:chemistry; D013237:Stereoisomerism
D048448:Phenylcarbamates; D012997:Solvents; C420325:cellulose tris(3,5-dichlorophenylcarbamate); D012822:Silicon Dioxide; D002482:Cellulose