Synthesis, spectral, optical and thermal studies of 1-methyl-2,6-dimethyl-4-hydroxypyridinium chloride monohydrate and bromide monohydrate.
Semiorganic 1-methyl-2,6-dimethyl-4-hydroxypyridinium chloride monohydrate (MDMPCl.H(2)O) and bromide monohydrate (MDMPBr.H(2)O) salts have been synthesized. Single crystals of MDMPCl.H(2)O and MDMPBr.H(2)O were grown by the slow evaporation method from aqueous solution at constant temperatures 30 and 32 degrees C respectively. The grown crystals were characterized by elemental analysis, FT-IR and FT-NMR techniques and their molecular structures were elucidated. Thermogravimetric, differential thermal analyses and differential scanning calorimetry reveal the presence of water molecules in the crystal lattices and thermal stabilities. Optical transmittance windows in aqueous solution were found as 300-1100 nm using UV-vis-NIR spectrophotometer.
Dhanuskodi
S
S
School of Physics, Bharathidasan University, Tiruchirappalli 620024, India. dhanus2k3@yahoo.com
Manivannan
S
S
Philip
J
J
D002151:Calorimetry; D018360:Crystallography, X-Ray; D004055:Differential Thermal Analysis; D009682:Magnetic Resonance Spectroscopy; D055095:Optics and Photonics; D011725:Pyridines / Q000138:chemical synthesis* / Q000737:chemistry*; D011726:Pyridinium Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D013053:Spectrophotometry; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D013818:Thermogravimetry; D014732:Vibration
C529666:1-methyl-2,6-dimethyl-4-hydroxypyridinium; D011725:Pyridines; D011726:Pyridinium Compounds