Metal-catalyzed silylene transfer to imines: synthesis and reactivity of silaaziridines.
Metal-catalyzed silylene transfer to imines provides an efficient synthesis of silaaziridines. These strained cyclic silanes undergo selective bond-forming reactions, permitting the synthesis of nitrogen-containing compounds after protodesilylation of the resulting vinyl silane.
Nevárez
Zulimar
Z
Department of Chemistry, University of California, Irvine, Irvine, California 92697-2025, USA.
Woerpel
K A
KA
D000480:Alkynes / Q000737:chemistry; D000498:Allyl Compounds / Q000737:chemistry; D001388:Aziridines / Q000138:chemical synthesis / Q000737:chemistry*; D002384:Catalysis; D007097:Imines / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*
D000480:Alkynes; D000498:Allyl Compounds; D001388:Aziridines; D007097:Imines; D012821:Silanes; D012834:Silver; D010165:Palladium