Grignard reagents in ionic solvents: electron transfer reactions and evidence for facile Br-Mg exchange.
Grignard reagents form persistent solutions in phosphonium ionic liquids possessing O-donor anions and these solutions are excellent reaction media for electron transfer processes and transmetallation reactions.
Ramnial
Taramatee
T
Department of Chemistry, Simon Fraser University, 8888 University Drive, Burnaby, British Columbia, Canada.
Taylor
Stephanie A
SA
Clyburne
Jason A C
JA
Walsby
Charles J
CJ