Tuning of fluorescence properties of aminoterpyridine fluorophores by N-substitution.
Several N-alkyl and N-phenyl derivatives of 6-amino- () and 6,6'-diamino-2,2':6',2''-terpyridine () were synthesized, and their fluorescence properties were studied. A successive red-shift was observed as the number of the N-substituted groups increased. It was also shown that the susceptivity of the fluorophores to a solvent varied considerably according to the mode of the N-substitution. While the monoamino-tpys (tpy: 2,2':6',2''-terpyridine) suffered almost complete quenching of their fluorescence in ethanol, the fully N-alkylated diamino-tpys and retained their fluorescence. The results show that N-substitution is a useful way to tune both the radiation energy and solvent susceptivity of the fluorescence of the amino-tpys.
Cheon
Jin-Dong
JD
Institute of Industrial Science, University of Tokyo, 4-6-1, Komaba, Meguro-ku, Tokyo, 153-8505, Japan.
Mutai
Toshiki
T
Araki
Koji
K
D000586:Amination; D004583:Electrons; D005456:Fluorescent Dyes / Q000737:chemistry*; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry; D011725:Pyridines / Q000737:chemistry*; D012996:Solutions
D005456:Fluorescent Dyes; D009930:Organic Chemicals; D011725:Pyridines; D012996:Solutions; D009584:Nitrogen