title: A process-based model for the partitioning of soluble, suspended particulate and bed sediment fractions of plutonium and caesium in the eastern Irish Sea.
abstract: A dynamic model of plutonium behaviour in the marine environment has been developed, representing the oxidation state distribution and partitioning of plutonium between the soluble, colloidal, suspended particulate and seabed sediment fractions. With simple re-parameterisation, this model can also be applied to (137)Cs. The model, which is calibrated and validated against field data, has been used to predict concentrations of Pu(alpha) and (137)Cs in both water and seabed sediments from the vicinity of the Sellafield Ltd. reprocessing plant in Cumbria, UK. The model predicts that sediment reworking and transport are the key environmental processes as the Sellafield Pu(alpha) and (137)Cs discharge continues to decline. Inventory calculations generated by the model are consistent with previous estimations. For a hypothetical post-discharge scenario, the concentrations of these radionuclides in both seawater and surface sediments are predicted to decrease sharply, concurrent with a downward vertical migration of the activity retained in sediments.
authors: Westlakes Scientific Consulting Ltd, The Princess Royal Building, Westlakes Science & Technology Park, Moor Row, Cumbria CA24 3LN, UK. Jordi.Vives@westlakes.ac.uk
authors: J
authors: J
authors: Vives I Batlle
authors: S
authors: S
authors: Bryan
authors: P
authors: P
authors: McDonald
mesh_terms: D002588:Cesium Radioisotopes / Q000032:analysis*; D019015:Geologic Sediments / Q000737:chemistry*; D007494:Ireland; D008962:Models, Theoretical; D011005:Plutonium / Q000032:analysis*; D012623:Seawater; D012995:Solubility
chemical_list: D002588:Cesium Radioisotopes; D011005:Plutonium