title: New preparation of 1,2,4,5,7,8-hexaoxonanes.
abstract: A new versatile procedure was developed for the synthesis of 1,2,4,5,7,8-hexaoxonanes based on the Lewis acid catalyzed reaction of acetals with 1,1'-dihydroperoxydicycloalkyl peroxides. The procedure substantially extends the structural diversity of these compounds and, in most cases, allows the synthesis of these compounds in higher yields (to 96%) and with higher selectivity. Complexation of hexaoxonane with chloroform was documented for the first time. The structures of several triperoxides were established by X-ray diffraction.
authors: N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation. terentev@ioc.ac.ru
authors: Alexander O
authors: AO
authors: Terent'ev
authors: Maxim M
authors: MM
authors: Platonov
authors: Eduard J
authors: EJ
authors: Sonneveld
authors: Rene
authors: R
authors: Peschar
authors: Vladimir V
authors: VV
authors: Chernyshev
authors: Zoya A
authors: ZA
authors: Starikova
authors: Gennady I
authors: GI
authors: Nikishin