Assembly between gold-thiolate nanoparticles and the organometallic cluster [Fe(eta5-C5H5)(mu3-CO)]4 toward redox sensing of oxo-anions.
Covalent assembly between gold-thiolate nanoparticles (AuNPs) and the cluster [Fe(eta(5)-C(5)H(5))(mu(3)-CO)](4), 1, can be achieved either by direct Brust-Schriffin-type synthesis using a mixture of undecanethiol and a thiol functionalized with , or by substitution of undecanethiolate ligands in AuNPs by thiolate ligands functionalized with ; cyclic voltammetry of these AuNPs functionalized with allows us to recognize and titrate the oxo-anions H(2)PO(4)(-) and ATP(2-).
Aranzaes
Jaime Ruiz
JR
Institut des Sciences Moléculaires, UMR CNRS N 5255, Université Bordeaux I, 33405, Talence Cedex, France.
Belin
Colette
C
Astruc
Didier
D
D000838:Anions; D006046:Gold / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D053768:Metal Nanoparticles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000138:chemical synthesis / Q000737:chemistry*
D000838:Anions; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D006046:Gold; D007501:Iron; D010100:Oxygen