INDOLPhos: novel hybrid phosphine-phosphoramidite ligands for asymmetric hydrogenation and hydroformylation.
Hybrid bidentate phosphine-phosphoramidite ligands are prepared in a modular 2-step sequence and their rhodium complexes display high selectivity in rhodium catalysed hydrogenation and hydroformylation reactions.
Wassenaar
Jeroen
J
Van't Hoff Institute for Molecular Sciences, University of Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands.
Reek
Joost N H
JN
D002384:Catalysis; D006865:Hydrogenation; D007202:Indicators and Reagents; D007211:Indoles / Q000737:chemistry*; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D012238:Rhodium
D007202:Indicators and Reagents; D007211:Indoles; D008024:Ligands; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D010720:Phosphines; C434331:phosphoramidite; D012238:Rhodium; C044646:phosphine