Coordination complexes of the dimethyl-thio-phosphonium cation and ligand exchange.
The quantitative exchange of a 4-(dimethylamino)pyridine ligand on the dimethyl-thio-phosphonium cation by Me3P demonstrates the coordinative nature of the N-P and P-P bond and diversifies a fundamentally important new direction in the coordination chemistry of phosphorus as an acceptor.
Weigand
Jan J
JJ
Department of Chemistry, Dalhousie University, Halifax, Nova Scotia B3H 4J3, Canada.
Burford
Neil
N
Mahnke
Devin
D
Decken
Andreas
A