New organically templated copper(I) sulfites: the role of sulfite anion as both soft and hard ligand.
Two new organically templated layered copper(I) sulfites, namely, {H2pip}{Cu3(CN)3(SO3)} (1) and {H2pip}{NaCu2(SO3)2Br(H2O)}.2H2O (2) (pip = piperazine), have been synthesized by hydrothermal reactions of copper(I) cyanide or copper(I) bromide with NaHSO3 and piperazine. Both compounds exhibit a layered structure. The 2D layer of {Cu3(CN)3(SO3)}2- in 1 is composed of 1D chains of copper(I) cyanide interconnected by sulfite anions via both Cu-S and Cu-O bonds, whereas the 2D layer of {NaCu2(SO3)2Br}2- in 2 is formed by 1D chains of copper(I) bromide and 1D sodium(I) aqua chains that are interconnected by sulfite anions via Na-O, Cu-S, and Cu-O bonds. Chemical bonding in 1 and 2 has been also investigated by theoretical calculations based on DFT methods.
Li
Pei-Xin
PX
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, PR China.
Jiang
Hai-Long
HL
Feng
Mei-Ling
ML
Mao
Jiang-Gao
JG