title: Platinum(II), palladium(II), rhodium(III) and lead(II) voltammetric determination in sites differently influenced by vehicle traffic.
abstract: The present work reports analytical results relevant to voltammetric determination of Pt(II), Pd(II), Rh(III) [Platinum Group Metals (PGMs)] and Pb(II) in superficial water sampled in sites differently influenced by vehicle traffic, especially considering their temporal behaviour. For all the elements, in addition to detection limits, precision, expressed as relative standard deviation (s(r) %) and accuracy, expressed as percentage recovery (R %) are also reported. In all cases they show to be good, being the former lower than 6% and the latter in the range 94-105%. A critical comparison with spectroscopic measurements is also discussed.
authors: Department of Chemistry "G. Ciamician", University of Bologna, Via F. Selmi 2, I-40126 Bologna, Italy.
authors: Dora
authors: D
authors: Melucci
authors: Clinio
authors: C
authors: Locatelli
mesh_terms: D002412:Cations / Q000032:analysis; D004563:Electrochemistry; D004784:Environmental Monitoring; D005843:Geography; D007854:Lead / Q000032:analysis*; D018986:Motor Vehicles; D010165:Palladium / Q000032:analysis*; D010984:Platinum / Q000032:analysis*; D015203:Reproducibility of Results; D012238:Rhodium / Q000032:analysis*; D012680:Sensitivity and Specificity; D013053:Spectrophotometry; D014874:Water Pollutants, Chemical / Q000032:analysis*
chemical_list: D002412:Cations; D014874:Water Pollutants, Chemical; D007854:Lead; D010984:Platinum; D010165:Palladium; D012238:Rhodium