title: Exploring the interaction of mercury(II) by N(2)S(2) and NS(3) anthracene-containing macrocyclic ligands: photophysical, analytical, and structural studies.
abstract: The complexation properties toward Hg(II) of six macrocyclic ligands, 3,11-dithia-7,17-diazabicyclo[11.3.1]heptadeca-1(17),13,15-triene (L1), 7-(9-anthracenylmethyl)-3,11-dithia-7,17-diazabicyclo[11.3.1]heptadeca-1(17),13,15-triene (L2), 7-(10-methyl-9-anthracenylmethyl)-3,11-dithia-7,17-diazabicyclo[11.3.1]heptadeca-1(17),13,15-triene (L3), 7,7'-[9,10-anthracenediylbis(methylene)]bis-3,11-dithia-7,17-diazabicyclo[11.3.1]heptadeca-1(17),13,15-triene (L4), 1,4,7-trithia-11-azacyclotetradecane (L5), and 11,-(anthracen-9-ylmethyl)-1,4,7-trithia-11-azacyclotetradecane (L6), were studied. The stoichiometries of the formed species were determined from absorption and fluorescence titrations. In these anthracene-containing macrocycles, a fluorescent quenching of the emission was found upon Hg(II) addition. The X-ray crystal structure of [HgCl2(L2)] x 1/2CH2Cl2 was determined. The asymmetric unit contains two independent [HgCl2(L2)] molecules and one dichloromethane molecule. Each Hg(II) ion is coordinated by the pyridine nitrogen, the two sulfur atoms of one L2 molecule, and two chloride ions. Analytical studies using solvent extraction separation of Hg(II) from aqueous solutions were performed to determine the Hg(II) extraction capability of ligands L1, L2, and L5.
authors: Departament de Química, Universitat Autònoma de Barcelona, 08193 Bellaterra, Spain.
authors: Abel
authors: A
authors: Tamayo
authors: Bruno
authors: B
authors: Pedras
authors: Carlos
authors: C
authors: Lodeiro
authors: Lluis
authors: L
authors: Escriche
authors: Jaume
authors: J
authors: Casabó
authors: José Luis
authors: JL
authors: Capelo
authors: Berta
authors: B
authors: Covelo
authors: Raikko
authors: R
authors: Kivekäs
authors: Reijo
authors: R
authors: Sillanpää
mesh_terms: D000873:Anthracenes / Q000737:chemistry*; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D018360:Crystallography, X-Ray; D008024:Ligands; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008628:Mercury / Q000737:chemistry*; D017672:Nitrogen Compounds / Q000737:chemistry*; D010777:Photochemistry; D013440:Sulfides / Q000737:chemistry*
chemical_list: D000873:Anthracenes; D008024:Ligands; D047028:Macrocyclic Compounds; D017672:Nitrogen Compounds; D013440:Sulfides; C034020:anthracene; D008628:Mercury