A novel efficient way to estimate the chemical rank of high-way data arrays.
A novel method, a subspace projection of pseudo high-way data array (SPPH), was developed for estimating the chemical rank of high-way data arrays. The proposed method determines the chemical rank through performing singular value decomposition (SVD) on the slice matrices of original high-way data array to produce a pseudo high-way data array and employing the idea of the difference of the original truncated data set and the pseudo one. Compared with traditional methods, it uses the information from eigenvectors combined with the projection residual to estimate the rank of the three-way data arrays instead of using the eigenvalue. In order to demonstrate the excellent performance of the new method, simulated and real three-way data arrays were carried out by the proposed method. The results showed that the proposed method could accurately and quickly determine the chemical rank to fit the trilinear model. Moreover, the newly proposed method was compared with the other four factor-determining methods, i.e. factor indicator function (IND), ADD-ONE-UP, core consistency diagnostic (CORCONDIA) and two-mode subspace comparison (TMSC) approaches. It was found that the proposed method can deal with more complex situations with existence of severe collinearity and trace concentration than many other methods can and performs well in practical applications.
Xia
A-Lin
AL
State Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China.
Wu
Hai-Long
HL
Zhang
Yan
Y
Zhu
Shao-Hua
SH
Han
Qing-Juan
QJ
Yu
Ru-Qin
RQ