The highest D value for a Mn(II) ion: investigation of a manganese(II) polyoxometalate complex by high-field electron paramagnetic resonance.
Using magnetization measurements and multifrequency high-field electron paramagnetic resonance, the largest zero-field splitting for any individual isolated Mn(II) ion has been found in a polyoxometalate complex, suggesting that the inorganic ligand induces large Ising-type magnetic anisotropy.
Pichon
Céline
C
Institut Lavoisier, UMR 8180, Université de Versailles Saint-Quentin, 45 Avenue des Etats-Unis, 78035 Versailles Cedex, France.
Mialane
Pierre
P
Rivière
Eric
E
Blain
Guillaume
G
Dolbecq
Anne
A
Marrot
Jérôme
J
Sécheresse
Francis
F
Duboc
Carole
C