title: Efficient oxidative radical spirolactamization.
abstract: An efficient xanthate-based method for the preparation of azaspirocyclic cyclohexadienones via an ipso oxidative radical cyclization of p-oxygenated N-benzylacetamides and N-phenetylacetamide is described.
authors: Facultad de Química, Universidad de Guanajuato, Noria Alta S/N, Guanajuato, México CP 36050.
authors: Tannya R
authors: TR
authors: Ibarra-Rivera
authors: Rocio
authors: R
authors: Gámez-Montaño
authors: Luis D
authors: LD
authors: Miranda
mesh_terms: D001372:Aza Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D044482:Benzeneacetamides / Q000737:chemistry; D003500:Cyclization; D003510:Cyclohexanes / Q000138:chemical synthesis* / Q000737:chemistry; D053138:Cyclohexenes; D005609:Free Radicals / Q000737:chemistry*; D007769:Lactams / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010084:Oxidation-Reduction; D010627:Phenethylamines / Q000737:chemistry; D013141:Spiro Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D001372:Aza Compounds; D044482:Benzeneacetamides; D003510:Cyclohexanes; D053138:Cyclohexenes; D005609:Free Radicals; D007769:Lactams; D010627:Phenethylamines; D013141:Spiro Compounds; C507608:cyclohexadienone; C054480:N-acetyl-2-phenylethylamine