New preparation of 1,2,4,5,7,8-hexaoxonanes.
A new versatile procedure was developed for the synthesis of 1,2,4,5,7,8-hexaoxonanes based on the Lewis acid catalyzed reaction of acetals with 1,1'-dihydroperoxydicycloalkyl peroxides. The procedure substantially extends the structural diversity of these compounds and, in most cases, allows the synthesis of these compounds in higher yields (to 96%) and with higher selectivity. Complexation of hexaoxonane with chloroform was documented for the first time. The structures of several triperoxides were established by X-ray diffraction.
Terent'ev
Alexander O
AO
N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation. terentev@ioc.ac.ru
Platonov
Maxim M
MM
Sonneveld
Eduard J
EJ
Peschar
Rene
R
Chernyshev
Vladimir V
VV
Starikova
Zoya A
ZA
Nikishin
Gennady I
GI