title: t-Bu-QuinoxP* ligand: applications in asymmetric Pd-catalyzed allylic substitution and Ru-catalyzed hydrogenation.
abstract: The potential of the t-Bu-QuinoxP* ligand (1) as a chiral ligand in asymmetric synthesis was examined. The ligand exhibited good to excellent asymmetric induction in Pd-catalyzed asymmetric allylic substitution of 1,3-diphenyl-2-propenyl acetate (up to 98.7% ee) and in Ru-catalyzed asymmetric hydrogenation of ketones (up to 99.9% ee).
authors: Department of Chemistry, Graduate School of Science, Chiba University, Yayoi-cho, Inage-ku, Chiba 263-8522, Japan. imamoto@faculty.chiba-u.jp
authors: Tsuneo
authors: T
authors: Imamoto
authors: Miwako
authors: M
authors: Nishimura
authors: Aya
authors: A
authors: Koide
authors: Kazuhiro
authors: K
authors: Yoshida