Synthesis and characterization of nickel nanoparticles dispersed in imidazolium ionic liquids.
The diameter and size-distribution of Ni nanoparticles prepared by the decomposition of [bis(1,5-cyclooctadiene)nickel(0)] organometallic precursor dissolved in 1-alkyl-3-methylimidazolium N-bis(trifluoromethanesulfonyl) amide ionic liquids depend on the length of the alkyl side-chain of the imidazolium ring. The increase of the organization range order of the ionic liquid that increases with that of the alkyl side-chain (from n-butyl to n-hexadecyl) induces the formation of nanoparticles with a smaller diameter and size-distribution. The cubic fcc Ni nanoparticles with 4.9 +/- 0.9 to 5.9 +/- 1.4 nm in mean diameter and monomodal size-distribution thus prepared are probably composed of a small cap layer of NiO around a core of Ni metal. The contribution of the oxide layer also depends on the medium i.e. the metal oxide ratio increases in salts containing four to eight carbons on their side-chains and then decreases as the number of carbons increases. The Ni nanoparticles dispersed in the ionic liquids are active catalysts for the hydrogenation of olefins under relatively mild reaction conditions.
Migowski
Pedro
P
Laboratory of Molecular Catalysis, Instituto de Química-UFRGS, P.O. Box 15003, Porto Alegre, 91501-970, RS Brazil.
Machado
Giovanna
G
Texeira
Sergio R
SR
Alves
Maria C M
MC
Morais
Jonder
J
Traverse
Agnès
A
Dupont
Jairton
J
D003102:Colloids / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D048288:Imidazolines / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D053758:Nanoparticles / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D009532:Nickel / Q000737:chemistry*; D010316:Particle Size
D003102:Colloids; D048288:Imidazolines; D052578:Ionic Liquids; D009532:Nickel