title: Energy transfer in oligofluorene-C60 and C60-oligofluorene-C60 donor-acceptor conjugates.
abstract: Two complementary series of C(60)-(Fl)(n) and C(60)-(Fl)(n)-C60 (Fl = 9,9-dihexylfluorene-2,7-diyl; n = 1-5) derivatives with terminal N-methylfulleropyrrolidine units have been synthesized from CHO-(Fl)(n) and CHO-(Fl)(n)-CHO precursors via 1,3-dipolar cycloaddition reaction of in situ generated azomethine ylides with an excess of C60. In solution electrochemical experiments, these conjugates give rise to amphoteric redox behavior. Three consecutive quasireversible reduction waves have been observed at the expected potentials for the N-methylfulleropyrrolidine cores. For the C(60)-(Fl)(n)-C(60) series, each reduction wave is a two-electron process with no observable interaction between the C(60) units. Two or, in some cases, three oxidation waves--most of them irreversible--are ascribed to the oligofluorene system. These waves are cathodically shifted with an increasing number of fluorene units and anodically shifted by the conjugated terminal aldehyde units, compared to the N-methylfulleropyrrolidine termini. Steady-state and time-resolved photolytic techniques show that an efficient transduction of singlet excited-state energy transfer prevails from the photoexcited oligofluorene to the energy accepting fullerene.
authors: Department of Chemistry, Durham University, Durham DH1 3LE, UK.
authors: Cornelia
authors: C
authors: van der Pol
authors: Martin R
authors: MR
authors: Bryce
authors: Mateusz
authors: M
authors: Wielopolski
authors: Carmen
authors: C
authors: Atienza-Castellanos
authors: Dirk M
authors: DM
authors: Guldi
authors: Salvatore
authors: S
authors: Filippone
authors: Nazario
authors: N
authors: Martín