Boron removal from aqueous solutions by activated carbon impregnated with salicylic acid.
In this study, the removal of boric acid from aqueous solution by activated carbon impregnated with salicylic acid was studied in batch system. pH, adsorbent amount, initial boron concentration, temperature, shaking rate and salicylic acid film thickness were chosen as parameters. Boron removal efficiencies increased with increasing adsorbent amount, temperature and pH, decreasing initial boron concentration. As thickness of salicylic acid film on activated carbon becomes thin up to 0.088nm, the efficiency increased, and then, the efficiency decreased with becoming thinner than 0.088nm of salicylic acid film. Shaking rate was no effect on removal efficiency. In result, it was determined that the use of salicylic acid as an impregnant for activated carbon led to the increase of the amount of boron adsorbed. A lactone ring, being the most appropriate conformation, forms between boric acid and -COOH and -OH groups of salicylic acid.
Celik
Z Ceylan
ZC
Department of Environmental Engineering, Atatürk University, Faculty of Engineering, Erzurum, Turkey. zcelik@atauni.edu.tr
Can
B Z
BZ
Kocakerim
M Muhtar
MM
D001895:Boron / Q000302:isolation & purification*; D002244:Carbon / Q000737:chemistry*; D006863:Hydrogen-Ion Concentration; D020156:Salicylic Acid / Q000737:chemistry*; D012996:Solutions; D014867:Water
D012996:Solutions; D014867:Water; D002244:Carbon; D001895:Boron; D020156:Salicylic Acid