Photocatalytic degradation of pesticides in pure water and a commercial agricultural solution on TiO2 coated media.
Heterogeneous photocatalysis of pesticides is an effective process for removing pesticides from pure water. With a view to treating real agricultural effluents, this paper deals with the degradation of the chlortoluron and cyproconazole pesticides in pure water and the treatment of commercial solutions by photocatalysis on TiO2 coated media. The process was effective in degrading and mineralizing the pesticides. The changes of the fate of heteroatoms showed that during irradiation of the chlortoluron and cyproconazole, NH4+ and NO3(-) ions were produced. A release of chloride ions was observed from the beginning of the irradiation and stoichiometry was achieved. The photodegradation of chlortoluton and cyproconazole in commercial solutions was studied. For the degradation of chlortoluton in a commercial solution, the mineralization was completely achieved whereas in the case of the commercial cyproconazole solution, the degradation kinetic was lower. These results highlight the fact that the chemical nature of the additives in the commercial pesticide solutions does significantly affect the degradation yield of the target compound by photocatalysis.
Lhomme
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Laboratoire Sciences Chimiques de Rennes UMR CNRS 6226/ENSCR/UR1, Equipe CIP, Ecole Nationale Supérieure de Chimie de Rennes, avenue du Général Leclerc, 35700 Rennes, France.
Brosillon
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S
Wolbert
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D000383:Agriculture; D002384:Catalysis; D002712:Chlorides / Q000737:chemistry; D009566:Nitrates / Q000737:chemistry; D010575:Pesticides / Q000737:chemistry* / Q000528:radiation effects*; D010671:Phenylurea Compounds / Q000737:chemistry* / Q000528:radiation effects*; D010777:Photochemistry; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D012996:Solutions; D014025:Titanium / Q000737:chemistry; D014230:Triazoles / Q000737:chemistry* / Q000528:radiation effects*; D014466:Ultraviolet Rays; D014867:Water; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000528:radiation effects; D018508:Water Purification / Q000379:methods
D002712:Chlorides; D009566:Nitrates; D010575:Pesticides; D010671:Phenylurea Compounds; D000644:Quaternary Ammonium Compounds; D012996:Solutions; D014230:Triazoles; D014874:Water Pollutants, Chemical; D014867:Water; C009495:titanium dioxide; C093628:cyproconazole; D014025:Titanium; C007033:chlortoluron