Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in water and suspended particulate matter from the Xijiang River, China.
Concentrations of polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) in water and suspended particulate matter (SPM) collected from the Xijiang River, China, were measured by the quarter from September 2005 to June 2006. Total PCDD/F concentration ranged from 2.659 to 4.596pg/L for water and from 562.4 to 3259.5pg/g for SPM. Concentrations were high in summer and low in winter. I-TEQ values in water and SPM were low, ranging from 0.012 to 0.075pg/L, with a mean value of 0.039pg/L. Calculated annual loadings of total PCDD/Fs and I-TEQ were 8.55kg and 0.026kg, respectively. Composition and homologue distribution of PCDD/Fs were varied because of large seasonal differences in discharge from the Xijiang River into the South China Sea. Comparison of the PCDD/Fs homologue and congener profiles of atmospheric deposition, soil, and water revealed that soil was the dominant source of PCDD/Fs in the Xijiang River. Industrial effluents were also possible sources of PCDD/Fs. A good correlation between logK(oc) and logK(ow) was observed for 2,3,7,8-substituted PCDDs and PCDFs and correlation coefficients were 0.71 and 0.84, indicating organic matter in SPM played a dominant role in PCDD/Fs partition between SPM and water.
Liu
Yanlin
Y
State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, People's Republic of China.
Peng
Ping'an
P
Li
Xiaoming
X
Zhang
Sukun
S
Ren
Man
M
D001572:Benzofurans / Q000032:analysis*; D002681:China; D000072338:Dibenzofurans, Polychlorinated; D000072317:Polychlorinated Dibenzodioxins / Q000031:analogs & derivatives* / Q000032:analysis; D011786:Quality Control; D012621:Seasons; D014874:Water Pollutants, Chemical / Q000032:analysis*
D001572:Benzofurans; D000072338:Dibenzofurans, Polychlorinated; D000072317:Polychlorinated Dibenzodioxins; D014874:Water Pollutants, Chemical