Ruthenium-catalyzed cross-metathesis between diallylsilanes and electron-deficient olefins.
Diallysilanes can be selectively coupled with electron-deficient olefins under cross-metathesis (CM) conditions using the Hoveyda-Grubbs catalyst to produce mono- and/or bis-CM compounds in good yield. The formation of the mono- and the bis-CM compounds depends on the nature of the electron-deficient olefin.
BouzBouz
Samir
S
Laboratoire de Chimie Organique, ESPCI, CNRS, 10 rue Vauquelin, 75231 Paris Cedex 05, France.
Boulard
Lucie
L
Cossy
Janine
J