title: Use of 1,10-phenanthroline in diiron dithiolate derivatives related to the [Fe-Fe] hydrogenase active site.
abstract: Treatment of [Fe(2)(micro-pdt)(CO)(6)] (pdt = S(CH(2))(3)S) with 1,10-phenanthroline (phen) in refluxing toluene affords the asymmetric complex [Fe(2)(micro-pdt)(CO)(4)(phen)] (1); the protonation of with HBF(4).OEt(2) in CD(2)Cl(2) at 203 K has been monitored by (1)H NMR.
authors: UMR CNRS 6521, Chimie, Electrochimie Moléculaires et Chimique Analytique, UFR Sciences et Techniques Université de Bretagne Occidentale, CS 93837, 29238 Brest-cedex 3, France. schollha@univ-brest.fr
authors: Pierre-Yves
authors: PY
authors: Orain
authors: Jean-François
authors: JF
authors: Capon
authors: Nelly
authors: N
authors: Kervarec
authors: Frédéric
authors: F
authors: Gloaguen
authors: François
authors: F
authors: Pétillon
authors: Roger
authors: R
authors: Pichon
authors: Philippe
authors: P
authors: Schollhammer
authors: Jean
authors: J
authors: Talarmin
mesh_terms: D001665:Binding Sites; D002384:Catalysis; D018360:Crystallography, X-Ray; D005290:Ferric Compounds / Q000737:chemistry*; D006864:Hydrogenase / Q000737:chemistry*; D007202:Indicators and Reagents; D007501:Iron / Q000737:chemistry*; D007506:Iron-Sulfur Proteins / Q000737:chemistry*; D010618:Phenanthrolines / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*
chemical_list: D005290:Ferric Compounds; D007202:Indicators and Reagents; D007506:Iron-Sulfur Proteins; D010618:Phenanthrolines; D013438:Sulfhydryl Compounds; C002007:dithiol-iron(III)-sulfide complex; D007501:Iron; C118830:iron hydrogenase; D006864:Hydrogenase; C025205:1,10-phenanthroline