title: Two new copper azido polymorphs: structures, magnetic properties, and effects of "noninnocent" reagents in hydrothermal methods.
abstract: Two new 3D copper(II) azido isomers, [Cu(N3)(nic)]infinity (1 and 2) (nic = nicotinate), have been synthesized and characterized. To the best of our knowledge, 1 is the first metal azido complex showing rutile-type topology, while 2 is a chiral compound obtained by spontaneous resolution upon crystallization.
authors: Department of Chemistry, Nankai University, Tianjin 300071, China.
authors: Fu-Chen
authors: FC
authors: Liu
authors: Yong-Fei
authors: YF
authors: Zeng
authors: Jiong-Peng
authors: JP
authors: Zhao
authors: Bo-Wen
authors: BW
authors: Hu
authors: E Carolina
authors: EC
authors: Sañudo
authors: Joan
authors: J
authors: Ribas
authors: Xian-He
authors: XH
authors: Bu