Thorpe-Ingold effect on the conformation and photophysical properties of dialkylsilylene-spaced divinylarene copolymers.
Geminal disubstitution on silicon in dialkylsilylene-spaced divinylarene copolymers may dictate the conformation and photophysical properties of the copolymers, bulky (i)Pr substituted copolymers being more folded than Me substituent analogues.
Yeh
Mei-Yu
MY
Department of Chemistry, National Taiwan University, Taipei, Taiwan 106.
Lin
Hsin-Chieh
HC
Lee
Shern-Long
SL
Chen
Chun-Hsien
CH
Lim
Tsong-Shin
TS
Fann
Wunshain
W
Luh
Tien-Yau
TY