Synthesis, characterization, and saccharide binding studies of bile acid-porphyrin conjugates.
Synthesis and characterization of bile acid-porphyrin conjugates (BAPs) are reported. Binding of saccharides with BAPs in aqueous methanol was studied by monitoring changes in the visible absorption spectral of the porphyrin-moieties. Although these studies clearly showed absorbance changes, suggesting quite high if non-selective binding, the mass spectral studies do not unambiguously support these results.
Koivukorpi
Juha
J
Department of Chemistry, University of Jyväskylä, Finland. jkkorpi@jyu.fi
Sievänen
Elina
E
Kolehmainen
Erkki
E
Král
Vladimír
V
D001647:Bile Acids and Salts / Q000737:chemistry*; D002241:Carbohydrates / Q000737:chemistry*; D006571:Heterocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D011166:Porphyrins / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization
D001647:Bile Acids and Salts; D002241:Carbohydrates; D006571:Heterocyclic Compounds; D011166:Porphyrins
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