Going to extremes: "super" armed glycosyl donors in glycosylation chemistry.
This concept article gives an overview of stereoelectronic effects in monosaccharide systems and how these can be used to dramatically enhance the reactivity of glycosyl donors in oligosaccharide synthesis.
Jensen
Henrik H
HH
Department of Chemistry, University of Aarhus, Langelandsgade 140, 8000 Aarhus C, Denmark. hhj@chem.au.dk
Pedersen
Christian Marcus
CM
Bols
Mikael
M
D006027:Glycosides / Q000138:chemical synthesis; D006031:Glycosylation; D009844:Oligosaccharides / Q000138:chemical synthesis*; D013237:Stereoisomerism
D006027:Glycosides; D009844:Oligosaccharides