title: New fluorescent chemosensors for heavy metal ions based on functionalized pendant arm derivatives of 7-anthracenylmethyl-1,4,10-trioxa-7,13-diazacyclopentadecane.
abstract: Two new ligands 7-anthracenylmethyl-13-methylpyridyl-1,4,10-trioxa-7,13-diazacyclopentadecane (L4) and 7-anthracenylmethyl-13-(2,2-dimethyl-2-hydroxyethyl)-1,4,10-trioxa-7,13-diazacyclopentadecane (L(5)) have been synthesized and characterized. Both derive from 7-anthracenylmethyl-1,4,10-trioxa-7,13-diazacyclopentadecane (L(3)) and differ for having a differently functionalized pendant arm covalently attached to the remaining secondary nitrogen donor of the macrocyclic framework. The protonation and coordination behavior of L(4), L(5), and the unbranched L(3) with metal ions have been studied in MeCN/H2O (1:1 v/v, 298.1 K, I = 0.1 M) using potentiometric methods. The crystal structures of L(3), [(H2L(3))(HL(3))](ClO4)3, and the complex [CdL(3)(NO3)2] have been determined by single-crystal X-ray methods. The fluorescent behavior of L(3)-L(5) in the presence of Cu(II), Zn(II), Cd(II), Hg(II), and Pb(II) has been studied as a function of pH in MeCN/H2O (1:1 v/v). The presence of Cu(II), Hg(II), or Pb(II) does not affect the fluorescent behavior observed for the three free ligands upon changing the pH. Interestingly, the fluorescent emission of L(3) and L(5) is selectively enhanced only in the presence of Cd(II) at basic pH. The same effect is observed for L4 in the presence of Cd(II) or Zn(II) at about pH 7.
authors: Dipartimento di Chimica Inorganica ed Analitica, Università degli Studi di Cagliari, S.S. 554 Bivio per Sestu, 09042 Monserrato (CA), Italy.
authors: M Carla
authors: MC
authors: Aragoni
authors: Massimiliano
authors: M
authors: Arca
authors: Andrea
authors: A
authors: Bencini
authors: Alexander J
authors: AJ
authors: Blake
authors: Claudia
authors: C
authors: Caltagirone
authors: Andrea
authors: A
authors: Danesi
authors: Francesco A
authors: FA
authors: Devillanova
authors: Alessandra
authors: A
authors: Garau
authors: Thomas
authors: T
authors: Gelbrich
authors: Francesco
authors: F
authors: Isaia
authors: Vito
authors: V
authors: Lippolis
authors: Michael B
authors: MB
authors: Hursthouse
authors: Barbara
authors: B
authors: Valtancoli
authors: Claire
authors: C
authors: Wilson