Anchored oxygen-donor coordination to iron for photodegradation of organic pollutants.
A photocatalyst of oxygen-donor coordination to iron, complex of 5-sulfosalicylic acid (SSA) with ferric ion, supported on resin to cycle Fe3+/Fe2+ center under visible irradiation can effectively generate *OH radicals from H2O2, leading to degradation of organic pollutants in water. The higher turnover number was achieved by this catalyst for the degradation of model compound than those reported for the general N-donor ligands catalysts. The reversible "on/ off" switching of Fe3+/Fe2+ complexation with SSA, coupled with the phenol/phenoxyl radical conversion of the o-phenoxyl moiety of SSA, produces an ideal catalytic system that separates the Fenton reaction and the followed oxidations by *OH radicals (in water phase) from the regeneration of the catalytic species, Fe (SSA)2-, which occurs on the surface of resin. This system not only inhibits the undesired destruction of the ligands by *OH radicals, improving the stability of the catalyst, but also avoids the unnecessary decomposition of H2O2 into HO2* that occurs in the homogeneous Fenton system. Therefore, the system suggests an efficient utilization of H2O2 for degradation of organic pollutants.
Ji
Hongwei
H
Laboratory of Photochemistry, Beijing National Laboratory for Molecular Sciences, Institute of Chemistry, The Chinese Academy of Science, Beijing 100080, China.
Song
Wenjing
W
Chen
Chuncheng
C
Yuan
Hong
H
Ma
Wanhong
W
Zhao
Jincai
J
D002384:Catalysis; D002733:Chlorophenols / Q000737:chemistry; D004785:Environmental Pollutants / Q000737:chemistry*; D009930:Organic Chemicals / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D010777:Photochemistry
D002733:Chlorophenols; D004785:Environmental Pollutants; D009930:Organic Chemicals; C004762:2,4-dichlorophenol; D010100:Oxygen