Stabilization of heavy metals in ceramsite made with sewage sludge.
In order to investigate stabilization of heavy metals in ceramsite made with sewage sludge as an additive, the configuration of heavy metals in ceramsite was analysed by XRD and while leaching tests were conducted to find out the effect of sintering temperature (850 degrees C, 900 degrees C, 950 degrees C, 1000 degrees C, 1100 degrees C, and 1200 degrees C), pH (1, 3, 5, 7, 9, and 12), and H2O2 concentration (0.5molL(-1), 1molL(-1), 1.5molL(-1), 3molL(-1), and 5molL(-1)) on stabilization of heavy metals (Cd, Cr, Cu, and Pb) in ceramsite. The results indicate that leaching contents of heavy metals do not change above 1000 degrees C and sintering temperature has a significant effect on stabilization of heavy metals in ceramsite; leaching contents of heavy metals decrease as pH increases and increase as H2O2 concentration increases. XRD analysis reveals that the heavy metals exist in steady forms, mainly Pb2O(CrO(4)), CdSiO3, and CuO at 1100 degrees C. It is therefore concluded that heavy metals are properly stabilized in ceramsite and cannot be easily released into the environment again to cause secondary pollution.
Xu
G R
GR
School of Municipal and Environmental Engineering, Harbin Institute of Technology, P.O. Box 2602, Harbin, Heilongjiang Province, China. xgr@hit.edu.cn
Zou
J L
JL
Li
G B
GB
D002516:Ceramics / Q000737:chemistry*; D006358:Hot Temperature; D006861:Hydrogen Peroxide / Q000737:chemistry; D019216:Metals, Heavy / Q000737:chemistry*; D012722:Sewage; D014961:X-Ray Diffraction
D019216:Metals, Heavy; D012722:Sewage; D006861:Hydrogen Peroxide