Unusual nickel-mediated C-S cleavage of alkyl and aryl sulfoxides.
The first examples of transition metal mediated C-S cleavage of sulfoxides containing sp2- and sp3-hybridized carbon bonds attached to the sulfur atom and the first example of a structurally characterized complex featuring an oxygen-bound sulfinyl ligand are presented.
Schaub
Thomas
T
Universität Karlsruhe (TH), Institut für Anorganische Chemie, Engesserstr., Geb. 30.4, D-76131 Karlsruhe, Germany.
Backes
Marc
M
Radius
Udo
U