Asymmetric formation of allylic amines with N-substituted quaternary stereocenters by Pd(II)-catalyzed aza-Claisen rearrangements.
Fischer
Daniel F
DF
Laboratory of Organic Chemistry, ETH Zürich, Wolfgang-Pauli-Strasse 10, Hönggerberg HCI E 111, 8093 Zürich, Switzerland.
Xin
Zhuo-Qun
ZQ
Peters
René
R
D000475:Alkenes / Q000737:chemistry; D000577:Amides / Q000737:chemistry; D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry*; D001372:Aza Compounds / Q000737:chemistry*; D002384:Catalysis; D007096:Imidoesters / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D020005:Propanols / Q000737:chemistry*; D013237:Stereoisomerism
D000475:Alkenes; D000577:Amides; D000588:Amines; D001372:Aza Compounds; D007096:Imidoesters; D020005:Propanols; C006463:allyl alcohol; D010165:Palladium