title: Manipulation of the wettability of surfaces on the 0.1- to 1 -micrometer scale through micromachining and molecular self-assembly.
abstract: Micromachining allows the formation of micrometer-sized regions of bare gold on the surface of a gold film supporting a self-assembled monolayer (SAM) of alkanethiolate. A second SAM forms on the micromachined surfaces when the entire system-the remaining undisturbed gold-supported SAM and the micromachined features of bare gold-is exposed to a solution of dialkyl disulfide. By preparing an initial hydrophilic SAM from HS(CH(2))(15)COOH, micromachining features into this SAM, and covering these features with a hydrophobic SAM formed from [CH(3)(CH(2))(11)S](2), it is possible to construct micrometer-scale hydrophobic lines in a hydrophilic surface. These lines provide new structures with which to manipulate the shapes of liquid drops.
authors.forename: N L
authors.initials: NL
authors.lastname: Abbott
authors.forename: J P
authors.initials: JP
authors.lastname: Folkers
authors.forename: G M
authors.initials: GM
authors.lastname: Whitesides