Metal catalyzed rearrangement of a 2,2'-bipyridine Schiff-base ligand to a quaterpyridine-type complex.
A Co(II) quaterpyridine-type complex has been prepared via a one-pot transformation of a 2,2'-bipyridine Schiff-base ligand in the presence of a Lewis acidic metal salt.
Wang
Jian
J
Department of Chemistry, Brock University, 500 Glenridge Ave, St Catherines, Ontario, Canada L2S 3A1.
Onions
Stuart
S
Pilkington
Melanie
M
Stoeckli-Evans
Helen
H
Halfpenny
Joan C
JC
Wallis
John D
JD
D015082:2,2'-Dipyridyl / Q000737:chemistry*; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D008024:Ligands; D008968:Molecular Conformation; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D003035:Cobalt; D015082:2,2'-Dipyridyl