Poly[(mu3-1,1-dioxo-1,2-benzoisothiazole-3-thiolato-kappa3N:S3:S3)silver(I)].
The centrosymmetric title compound, [Ag(C(7)H(4)NO(2)S(2))]n, consists of dinuclear units in which two thiosaccharinate anions each bridge two Ag atoms via an endocyclic N atom and an exocyclic S atom across a crystallographic centre of inversion midway between the Ag atoms. The dimeric units are connected via Ag-S(exo) interactions to create two-dimensional networks. The thiosaccharinate anions bridge in a mu3-S:S:N manner. The Ag...Ag distance can be considered a strong argentophilic interaction.
Dennehy
Mariana
M
Departamento de Química, Universidad Nacional del Sur, Avenida Alem 1253, B8000CPB Bahia Blanca, Argentina.
Quinzani
Oscar V
OV
Burrow
Robert A
RA