Hydrogen-bonded sheets of R2(2)(10) and R4(4)(24) rings in 1-deoxy-1-morpholino-D-fructopyranose.
In the title compound, C(10)H(19)NO(6), both rings adopt almost perfect chair conformations and their mutual orientation is influenced by an intramolecular O-H...N hydrogen bond. The molecules are linked by three independent O-H...O hydrogen bonds into sheets containing equal numbers of R2(2)(10) and R4(4)(24) rings.
Rodríguez
Ricaurte
R
Departamento de Química, Universidad Nacional de Colombia, Bogotá, AA 14490, Colombia.
Cobo
Justo
J
Nogueras
Manuel
M
Low
John N
JN
Glidewell
Christopher
C
D002236:Carbohydrate Conformation; D018360:Crystallography, X-Ray; D005632:Fructose / Q000031:analogs & derivatives* / Q000737:chemistry*; D006860:Hydrogen Bonding; D008958:Models, Molecular; D008968:Molecular Conformation; D009025:Morpholines / Q000737:chemistry*
D009025:Morpholines; D005632:Fructose; C044913:1-deoxy-1-morpholinofructose