[Determination of trace heavy metal elements in cortex Phellodendron chinense by ICP-MS after microwave-assisted digestion].
An inductively coupled plasma mass spectrometry (ICP-MS) for determination of the contents of 8 trace heavy metal elements in cortex Phellodendron chinense after microwave-assisted digestion of the sample has been developed. The accuracy of the method was evaluated by the analysis of corresponding trace heavy metal elements in standard reference materials (GBW 07604 and GBW 07605). By applying the proposed method, the contents of 8 trace heavy metal elements in cortex Phellodendron chinense cultivated in different areas (in Bazhong, Yibin and Yingjing, respectively) of Sichuan and different growth period (6, 8 and 10 years of samples from Yingjing) were determined. The relative standard deviation (RSD) is in the range of 3.2%-17.8% and the recoveries of standard addition are in the range of 70%-120%. The results of the study indicate that the proposed method has the advantages of simplicity, speediness and sensitivity. It is suitable for the determination of the contents of 8 trace heavy metal elements in cortex Phellodendron chinense. The results also show that the concentrations of 4 harmful trace heavy metal elements As, Cd, Hg and Pb in cortex Phellodendron chinense are all lower than the limits of Chinese Pharmacopoeia and Green Trade Standard for Importing and Exporting Medicinal Plant and Preparation. Therefore, the cortex Phellodendron chinense is fit for use as medicine and export.
Kou
Xing-Ming
XM
Faculty of Chemistry, Sichuan University, Chengdu 610064, China. kouxm@scu.edu.cn
Xu
Min
M
Gu
Yong-Zuo
YZ
D001151:Arsenic / Q000032:analysis; D002104:Cadmium / Q000032:analysis; D002681:China; D003035:Cobalt / Q000032:analysis; D003300:Copper / Q000032:analysis; D005843:Geography; D007854:Lead / Q000032:analysis; D013058:Mass Spectrometry / Q000379:methods*; D008628:Mercury / Q000032:analysis; D019216:Metals, Heavy / Q000032:analysis*; D008872:Microwaves; D009532:Nickel / Q000032:analysis; D032102:Phellodendron / Q000737:chemistry*; D015203:Reproducibility of Results; D015032:Zinc / Q000032:analysis
D019216:Metals, Heavy; D002104:Cadmium; D007854:Lead; D003035:Cobalt; D003300:Copper; D009532:Nickel; D008628:Mercury; D015032:Zinc; D001151:Arsenic