Charge transmission through a molecular wire: the role of terminal sites for the current-voltage behavior.
The current-voltage and the conductance-voltage characteristics are analyzed for a particular type of molecular wire embedded between two electrodes. The wire is characterized by internal molecular units where the lowest occupied molecular orbital (LUMO) levels are positioned much above the Fermi energy of the electrodes, as well as above the LUMO levels of the terminal wire units. The latter act as specific intermediate donor and acceptor sites which in turn control the current formation via the superexchange and sequential electron transfer mechanisms. According to the chosen wire structure, intramolecular multiphonon processes may block the superexchange component of the interelectrode current, resulting in a negative differential resistance of the molecular wire. A pronounced current rectification appears if (i) the superexchange component dominates the electron transfer between the terminal sites and if (ii) the multiphonon suppression of distant superexchange charge hopping events between those sites is nonsymmetric.
Petrov
E G
EG
Bogolyubov Institute for Theoretical Physics, National Academy of Sciences of Ukraine, Metrologichna strasse 14-b, UA-03143 Kiev, Ukraine.
Zelinskyy
Ya R
YR
May
V
V
Hänggi
P
P