title: Carbon-free fullerenes: condensed and stuffed anionic examples in indium systems.
abstract: Condensed, well-ordered analogs of the fullerenes occur in the hexagonal phases Na(96)In(97)Z(2) (Z = nickel, palladium, or platinum). Large cages of In(74) (D3h) and M(60) (= In(48)Na(12), D3d) share pentagonal faces to generate a double-hexagonal close-packed analog of NiAs. All these polyhedra are centered by partially disordered In(10)Z clusters within deltahedra of sodium atoms that cap all inner faces of the cages, namely, Z@In(10)@Na(39)@In(74) and Z@In(10)@Na(32)@Na(12)In(48) "onions" The highest filled bands in these compounds apparently involve localized electron pairs on surface features on In(74)-based layers. Structural and electronic relations between diamond and Naln (stuffed diamond structure) parallel those between certain fullerenes and Na(96)In(97)Z(2) and, presumably, other valence-driven intermetallic phases.
authors.forename: S C
authors.initials: SC
authors.lastname: Sevov
authors.forename: J D
authors.initials: JD
authors.lastname: Corbett