Model for cage formation in colloidal suspension of laponite.
In this paper we investigate glass transition in aqueous suspension of synthetic hectorite clay, laponite. We believe that upon dispersing laponite clay in water, the system comprises of clusters (agglomerates) of laponite dispersed in the same. Subsequent osmotic swelling of these clusters leads to an increase in their volume fraction. We propose that this phenomenon is responsible for slowing down of the overall dynamics of the system. As clusters fill up the space, the system undergoes glass transition. Along with the mode coupling theory, the proposed mechanism rightly captures various characteristic features of the system in the ergodic regime as it approaches glass transition.
Joshi
Yogesh M
YM
Department of Chemical Engineering, Indian Institute of Technology Kanpur, Kanpur 208016, India. joshi@iitk.ac.in