title: Facets of early transition metal-sulfur chemistry: metal-sulfur ligand redox, induced internal electron transfer, and the reactions of metal-sulfur complexes with alkynes.
abstract: Metal-sulfur ligand redox interplay, induced internal electron transfer reactions, and the generation of dithiolene and organosulfur ligands in the reactions of metal-sulfur compounds with alkynes are important and useful facets of early transition metal-sulfur chemistry. This review focuses on developments in these areas over the past 30 years.
authors.affiliation: School of Chemistry, University of Melbourne, Victoria 3010, Australia. cgyoung@unimelb.edu.au
authors.forename: Charles G
authors.initials: CG
authors.lastname: Young
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D004579:Electron Transport; D008024:Ligands; D008670:Metals / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013455:Sulfur / Q000737:chemistry*; D028561:Transition Elements / Q000737:chemistry*
chemical_list: D000480:Alkynes; D008024:Ligands; D008670:Metals; D028561:Transition Elements; D013455:Sulfur