title: Abiotic reduction of antimony(V) by green rust (Fe(4)(II)Fe(2)(III)(OH)(12)SO(4).3H(2)O).
abstract: Green rust (Fe(4)(II)Fe(2)(III)(OH)(12)SO(4).3H(2)O) is an intermediate phase in the formation of iron (oxyhydr)oxides such as goethite, lepidocrocite, and magnetite. It is widely considered that green rust occurs in many soil and sediment systems. Green rust has been shown to reduce sorbed Se(VI), Cr(VI), and U(VI). In addition, it is also reported that green rust does not reduce As(V) to As(III). In this study, we have investigated for the first time the interaction between Sb(V) and green rust using XAFS and HPLC-ICP-MS. Most of the added Sb(V) was adsorbed on green rust, and Sb(III), a reduced form, was observed in both solid and liquid phases. Thus, it was shown that green rust has high affinity for Sb(V), and that Sb(V) was reduced to more toxic Sb(III) by green rust despite the high stability of the Sb(V) species even under reducing condition as reported in previous studies. Therefore, green rust can be one of the most important reducing agents for Sb(V), which can influence the Sb mobility in suboxic environments where green rust is formed.
authors.affiliation: Department of Earth and Planetary Systems Science, Graduate School of Science, Hiroshima University, Higashi-Hiroshima, Hiroshima 739-8526, Japan. mitsunobu@hiroshima-u.ac.jp
authors.forename: Satoshi
authors.initials: S
authors.lastname: Mitsunobu
authors.forename: Yoshio
authors.initials: Y
authors.lastname: Takahashi
authors.forename: Yoichi
authors.initials: Y
authors.lastname: Sakai
mesh_terms: D000965:Antimony / Q000737:chemistry*; D002851:Chromatography, High Pressure Liquid; D002980:Climate; D005290:Ferric Compounds / Q000737:chemistry*; D052203:Ferrosoferric Oxide / Q000737:chemistry; D005296:Ferrous Compounds / Q000737:chemistry*; D058085:Iron Compounds / Q000737:chemistry; D007700:Kinetics; D008903:Minerals; D008962:Models, Theoretical; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D012989:Soil Pollutants / Q000032:analysis* / Q000737:chemistry; D013057:Spectrum Analysis; D013472:Sunlight; D014874:Water Pollutants, Chemical / Q000032:analysis* / Q000737:chemistry
chemical_list: D005290:Ferric Compounds; D005296:Ferrous Compounds; D058085:Iron Compounds; D008903:Minerals; D012989:Soil Pollutants; D014874:Water Pollutants, Chemical; C094886:goethite; C000499:ferric oxide; D000965:Antimony; D010100:Oxygen; D052203:Ferrosoferric Oxide