Preparation and characterization of sodium iron titanate ion exchanger and its application in heavy metal removal from waste waters.
The ion exchange properties of sodium iron titanates, namely, NaFeTiO(4), Na(2)Fe(2)Ti(6)O(16) and iron-doped sodium nonatitanate were investigated. Conventional solid state and sol-gel methods were used in the synthesis of the sodium iron titanates. Structural characterization of the materials was performed with powder X-ray diffraction (XRD), thermogravimetry (TG), scanning electron microscopy (SEM) equipped with energy dispersive spectrometer (EDS) and with inductively coupled plasma optical emission spectrometry (ICP-OES). Based on TG analyses, the novel iron-doped sodium nonatitanate was proven to be a member of the layered titanate family. The different sodium iron titanates were compared based on the efficiency in separating Ni from aqueous streams by conducting batch experiments with a batch factor of 1000 ml/g. Iron-doped sodium nonatitanate exhibited the best ion exchange performance compared to the other sodium iron titanates studied. It was found to be selective for nickel over potassium and showed 99% removal efficiency for Ni.
Akieh
Marceline N
MN
Laboratory of Applied Environmental Chemistry, Department of Environmental Sciences, University of Kuopio, Patteristonkatu 1, FIN-50100 Mikkeli, Finland.
Lahtinen
Manu
M
Väisänen
Ari
A
Sillanpää
Mika
M
D007220:Industrial Waste; D007474:Ion Exchange; D007501:Iron; D019216:Metals, Heavy / Q000302:isolation & purification*; D010087:Oxides; D014025:Titanium; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
D007220:Industrial Waste; D019216:Metals, Heavy; D010087:Oxides; D014874:Water Pollutants, Chemical; C471701:sodium titanate; C066317:ferryl iron; D014025:Titanium; D007501:Iron