[Determination of trace impurities in high purity titanium dioxide by high resolution inductively coupled plasma mass spectrometry].
An analytical method using high resolution inductively coupled plasma mass spectrometry (HR-ICP-MS) for the rapid simultaneous determination of twenty six elements (Be, Na, Mg, Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, Ga, Ge, As, Mo, Cd, Sn, Sb, Ba, Ce, Nd, Sm, Pt, Pb and Bi) in high purity titanium dioxide was described. Samples were decomposed by (NH4)2SO4 and H2SO4. Most of the spectral interferences could be avoided by measuring in the high-resolution mode. The matrix effects due to the presence of excess sulfuric acid and Ti were evaluated. The optimum conditions for the determination were tested and discussed. The standard addition method was employed for quantitative analysis. The detection limits are 0.004-0.63 microg x g(-1), the recovery ratio is 87.6%-106.4%, and the RSD is less than 3.5%. The method is accurate, quick and convenient. It has been applied to the determination of trace impurities in high purity titanium dioxide with satisfactory results.
He
Xiao-Mei
XM
Department of Chemistry, Hunan Institute of Technology, Hengyang 421008, China.
Xie
Hua-Lin
HL
Nie
Xi-Du
XD
Tang
You-Gen
YG
D013058:Mass Spectrometry / Q000379:methods*; D012015:Reference Standards; D015203:Reproducibility of Results; D014025:Titanium / Q000737:chemistry*; D014131:Trace Elements / Q000032:analysis* / Q000592:standards
D014131:Trace Elements; C009495:titanium dioxide; D014025:Titanium