Energy transfer studies in binary dye solution mixtures: Acriflavine+Rhodamine 6G and Acriflavine+Rhodamine B.
The effect of acceptor concentration on the energy transfer in Acriflavine (donar) plus Rhodamine 6G (Rh 6G) and Acriflavine plus Rhodamine B (Rh B) binary solution mixtures has been studied. The theoretical calculations are done to determine their lifetimes. Effect of these values on the total transfer efficiency at various acceptor concentrations have been studied to identify the appropriate energy transfer mechanism responsible for photon emissions, enhancement in lasing efficiency and dreading of the tenability of such mixed solutions. The energy transfer rate constants and critical transfer radius (R(0)) are calculated using Stern-Volmer plots and concentration dependence of radiative and non-radiative transfer efficiencies have also been determined. The experimental results indicate that dominant mechanism responsible for the efficient energy transfer in the binary mixtures is of non-radiative kind and is due to long-range dipole-dipole interaction.
Sahare
P D
PD
Department of Physics, University of Pune, Pune 411007, India. pdsahare@physics.unipune.ernet.in
Sharma
Vijay K
VK
Mohan
D
D
Rupasov
A A
AA
D000167:Acriflavine / Q000737:chemistry*; D004396:Coloring Agents / Q000737:chemistry*; D004735:Energy Transfer; D000432:Methanol / Q000737:chemistry; D012235:Rhodamines / Q000737:chemistry*; D012996:Solutions; D013050:Spectrometry, Fluorescence
D004396:Coloring Agents; D012235:Rhodamines; D012996:Solutions; C026188:rhodamine 6G; D000167:Acriflavine; C029773:rhodamine B; D000432:Methanol