Pulse Radiolysis of Potassium Bromide Solutions.
After application of a 2-microsecond pulse of an electron beam to aqueous, aerated, acid solutions of KBr, transient spectra of Br2- and Br3- were observed. The kinetic analysis of the reactions as well as the measured values of G(H(2)O(2)), G(Br(2)), and G(Br(3)(-)) revealed a reaction mechanism differing from the one which is accepted for radiolysis at low intensity.
Cercek
B
B
Ebert
M
M
Keene
J P
JP
Swallow
A J
AJ