title: Mass spectrometry of lipids. I. Cyclopropane fatty acid esters.
abstract: A method was developed for the almost quantitative conversion of unsaturated esters (from monoenes to tetraenes) to cyclopropanes using diiodomethane and a highly active zinc-copper couple. These derivatives are sufficiently volatile for GLC analysis andcis andtrans isomers can be distinguished by this technique. Equivalent chain lengths of the cyclopropane derivatives were measured on polar and nonpolar phases. The mass spectra of the monocyclopropane compounds are very similar to those of the parent unsaturated esters. Those of dicyclopropanes, however, are quite distinctive so that the original structure of the ester can be deduced. Polycyclopropanes give complex spectra which are difficult to interpret in terms of the position of the original double bonds.
authors.affiliation: The Hormel Institute, University of Minnesota, Austin, Minnesota.
authors.forename: W W
authors.initials: WW
authors.lastname: Christie
authors.forename: R T
authors.initials: RT
authors.lastname: Holman