Phosphorus-carbon bond formation by lewis Acid catalyzed/mediated addition of silylphosphines.
Triethylaluminum-catalyzed/mediated addition of a silylphosphine to aldehydes and epoxides is described. Organophosphines containing a silyloxy group at the alpha- or beta-position on the alkyl substituent are successfully prepared in good yields.
Hayashi
Minoru
M
Department of Materials Science and Biotechnology, Graduate School of Science and Engineering, Ehime University, 3 Bunkyo-cho, Matsuyama 790-8577, Japan. hayashi@eng.ehime-u.ac.jp
Matsuura
Yutaka
Y
Nishimura
Yasunobu
Y
Yamasaki
Toshikazu
T
Imai
Yoshito
Y
Watanabe
Yutaka
Y