Synthesis of new enantiomerically enriched beta-Hydroxy-gamma-amino phosphines by selective transformation of naturally occurring amino acids.
Ring opening of amino epoxides derived from naturally occurring amino acids with lithium diphenylphosphido borane is reported as an efficient approach to a new family of enantiomerically enriched multifunctional phosphines.
Ciardi
Chiara
C
Area de Química InorgAnica, Facultad de Ciencias Experimentales, Universidad de Almería, 04071 Almería, Spain.
Romerosa
Antonio
A
Serrano-Ruiz
Manuel
M
Gonsalvi
Luca
L
Peruzzini
Maurizio
M
Reginato
Gianna
G
D000588:Amines / Q000737:chemistry*; D000596:Amino Acids / Q000737:chemistry*; D004852:Epoxy Compounds / Q000737:chemistry; D010720:Phosphines / Q000138:chemical synthesis*; D013237:Stereoisomerism