Entropy Estimates for Some Silicates at 298{degrees}K from Molar Volumes.
Third law entropies for silicates of Be, Mg, Ca, Zn, Na, and K containing the same anion group, for example, SiO(4) or SiO(3) or AlSi(3)O(8), are found to be linearly related to their molar volumes. The relationship between the molar volume and the entropy of silicates of Fe and Mn, atoms with unfilled d electron subshells, is different from that of other silicates. The linear correlations yield a useful method of estimating the entropies of ortho-, meta-, and framework silicates (feldspars and feld-spathoids). The estimated entropies of pyrope and almandine at 298 degrees K are 47.47 and 68.13 gibbs per mole, respectively.
Saxena
S K
SK