A three-dimensional ferromagnet based on linked copper-azido clusters.
Two novel three-dimensional coordination polymers [Cu(6)(N(3))(12)(N-Eten)(2)](n) (1) (N-Eten=N-ethylethylenediamine) and {[Cu(9)(N(3))(18)(1,2-pn)(4)].H(2)O}(n) (2) (1,2-pn=1,2-diaminopropane) have been synthesized by the self-assembly reactions of Cu(NO(3))(2).3H(2)O, NaN(3) and small diamine ligands. Their molecular structures were determined by single-crystal X-ray diffraction. Complex 1 is composed of a neutral 3D coordination framework based on unprecedented hexanuclear copper(ii) clusters which features three types of bridging modes for azide (mu-1,1, mu-1,3 and mu-1,1,3). Complex 2 is a novel 3D coordination polymer featuring octanuclear copper-azido clusters and [Cu(diamine)(2)](2+) units which are linked by azido bridges. Magnetic studies for complex show ferromagnetic ordering at 3.5 K, where the azido bridges mediate ferromagnetic coupling between adjacent Cu(II) ions. The magnetic data for 1 were fitted to a uniform hexanuclear copper model which yielded g=2.21, J=6.26 cm(-1), zJ'=0.39 cm(-1). Complex 2 shows ferromagnetic coupling in the octanuclear unit and antiferromagnetic interaction between neighboring units.
Gu
Zhi-Guo
ZG
Coordination Chemistry Institute and the State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, PR China.
Zuo
Jing-Lin
JL
You
Xiao-Zeng
XZ
D002412:Cations; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray / Q000379:methods; D007477:Ions; D008024:Ligands; D008280:Magnetics; D008670:Metals / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D011108:Polymers / Q000737:chemistry; D013055:Spectrophotometry, Infrared / Q000379:methods; D013696:Temperature; D014961:X-Ray Diffraction