A general strategy for ligation of organic and biological molecules to Dawson and Keggin polyoxotungstates.
The copper-catalyzed azide/alkyne cycloaddition (click chemistry) is used for the first time in polyoxometalate chemistry to graft any kind of organics (lipophilic, water-soluble, biologically relevant) to polyoxotungstates to generate hybrids. The method is not limited by solvent matching between the polyoxometallic platforms and the organic substrates.
Micoine
Kévin
K
Laboratoire de chimie organique (UMR CNRS 7611), Institut de chimie moléculaire (FR 2769), Université Pierre et Marie Curie-Paris 6, 4 place Jussieu, C. 229, 75005 Paris, France.
Hasenknopf
Bernold
B
Thorimbert
Serge
S
Lacôte
Emmanuel
E
Malacria
Max
M
D002384:Catalysis; D003300:Copper / Q000737:chemistry; D003500:Cyclization; D019281:Dimerization; D008958:Models, Molecular; D015394:Molecular Structure; D009930:Organic Chemicals / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013237:Stereoisomerism; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates