title: Preparation and enhanced daylight-induced photocatalytic activity of C,N,S-tridoped titanium dioxide powders.
abstract: A simple method for preparing highly daylight-induced photoactive nanocrystalline C,N,S-tridoped TiO2 powders was developed by a solid-phase reaction. The as-prepared TiO2 powders were characterized by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), UV-vis diffuse reflectance spectra, N2 adsorption-desorption measurements and transmission electron microscopy (TEM). The photocatalytic activity was evaluated by the photocatalytic oxidation of formaldehyde under daylight irradiation in air. The results show that daylight-induced photocatalytic activities of the as-prepared TiO2 powders were improved by C,N,S-tridoping. The C,N,S-tridoped TiO2 powders exhibited stronger absorption in the near UV and visible-light region with red shift in the band-gap transition. When the molar ratio of CS(NH2)2 to xerogel TiO2 powders (prepared by hydrolysis of Ti(OC4H9)4 in distilled water) (R) was kept in 3, the daylight-induced photocatalytic activities of the as-prepared C,N,S-tridoped TiO2 powders were about more than six times greater than that of Degussa P25 and un-doped TiO2 powders. The high activities of the C,N,S-tridoped TiO2 can be attributed to the results of the synergetic effects of strong absorption in the near UV and visible-light region, red shift in adsorption edge and two phase structures of un-doped TiO2 and C,N,S-tridoped TiO2.
authors.affiliation: Yunyang Medical College, Shiyan 442000, Hubei, PR China.
authors.forename: Minghua
authors.initials: M
authors.lastname: Zhou
authors.forename: Jiaguo
authors.initials: J
authors.lastname: Yu
mesh_terms: D002384:Catalysis; D046529:Microscopy, Electron, Transmission; D010777:Photochemistry; D011208:Powders; D013056:Spectrophotometry, Ultraviolet; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction