title: Identification of iron-cyanide complexes in contaminated soils and wastes by Fourier transform infrared spectroscopy.
abstract: Persistent cyanide species in soil are mainly iron-cyanide (Fe-CN) complexes. They originate from anthropogenic inputs of compounds such as Fe4[Fe(II)(CN)6]3 in deposited gas-purifier wastes (GPW) or K2Zn3[Fe(II)(CN)6]2 in deposited blast-furnace sludge (BFSI). Fe-CN species in de-inking sludge (DIS) and sewage farm soils (SF) are still unknown. We investigated 35 soil and waste samples from 15 European sites and five synthesized Fe-CN-containing compounds by Fourier transform infrared spectroscopy. Furthermore, we determined the contents of total and adsorbed CN and pH. In all samples (pH 2.2-9.5), adsorbed Fe-CN complexes were negligible. In GPW and DIS samples, Fe4[Fe(II)(CN)6]3 and KFe[FeII(CN)6] were the only Fe-CN compounds (total CN contents 0.4-449 g kg(-1)). Several BFSI samples were free of CN. The spectra of other BFSI samples partially indicated dissolution of the characteristic compound K2Zn3[Fe(II)(CN)6]2, resulting in a loss of CN (contents < 12.3 g kg(-1)). Distinctive changes in BFSI with respect to CN speciation occurred within relatively short periods, <20 years. Dissolution of K2Zn3[Fe(II)(CN)6]2 was followed by dissociation of free CN from [Fe(CN)6](3-/4-) and adsorption of [Fe(II)(CN)6](4-) on organic surfaces. In DIS and SF samples, Fe4[Fe(11)(CN)6]3 and K2Zn3[Fe(II)(CN)6]2 (SF only) were identified.
authors.affiliation: Arbeitsgruppe Bodengeographie/Bodenkunde, Geographisches Institut, Universität zu Köln, Albertus-Magnus-Platz, 50923 Köln, Germany. Thilo.Rennert@uni-jena.de
authors.forename: Thilo
authors.initials: T
authors.lastname: Rennert
authors.forename: Stephan
authors.initials: S
authors.lastname: Kaufhold
authors.forename: Tim
authors.initials: T
authors.lastname: Mansfeldt
mesh_terms: D003486:Cyanides / Q000032:analysis*; D007501:Iron / Q000032:analysis*; D012722:Sewage / Q000737:chemistry*; D012989:Soil Pollutants / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared; D014732:Vibration