Facile synthesis of silver nano/micro-ribbons or saws assisted by polyoxomolybdate as mediator agent and vanadium(IV) as reducing agent.
Original and effective syntheses of crystalline silver wires and saw bundles, using reduced Keggin polyoxomolybdovanadate (POM) as mediator and reducing agent, were performed in acetonitrile at room temperature; several parameters influencing the final silver 1D-structures, with micrometric length and nanometric thickness, were varied: the nature of the POM, silver salts, vanadium(iv) source and the mild conditions.
Marchal-Roch
Catherine
C
UMR 8180, Centre National de la Recherche Scientifique, ILV, Université de Versailles Saint-Quentin en Yvelines, 45 avenue des Etats-Unis, 78035 Versailles, France. roch@chimie.uvsq.fr
Mayer
Cédric R
CR
Michel
Aude
A
Dumas
Eddy
E
Liu
Feng-Xian
FX
Sécheresse
Francis
F