title: Hydrolytic stability of composite repair bond.
abstract: The hydrolytic stability of composite repairs is a desirable property. In the present study, the composite repair microtensile bond strength, failure mode distribution, and nanoleakage occurrence before and after thermocycling were evaluated. Standardized, 1-month-old composite substrates were roughened, cleaned, and randomly assigned to seven groups according to the intermediate agent applied. Resin-based, silane-based, and combined silane/adhesive coupling agents were investigated. The same resin composite as the substrate was used for repair. For each group, repaired samples were wet stored for 24 h (37 degrees C) or thermocycled (5,000 cycles, 5-55 degrees C). Failure mode and silver nitrate penetration were examined by stereomicroscopy. Intermediate agent, experimental condition, and their interaction were significant factors. Hydrophobic flowable composites resulted in statistically higher repair strengths, lower occurrence of adhesive failures, and good quality interfacial coupling without any silver uptake in both conditions. Light-curing, hydrophilic resin monomer-based intermediate agents, although not affected by thermocycling, showed a more pronounced silver penetration. The composite repair strength of a self-curing silane/adhesive agent was significantly affected by thermal stresses, despite the absence of silver uptake. A prehydrolized silane agent recorded the lowest repair strength, with minimal or no evidence of interfacial silver impregnation after thermocycling. In conclusion, flowability and hydrophobic nature can be considered important properties when selecting intermediate agents for composite repair.
authors.affiliation: Department of Dental Materials and Restorative Dentistry, University of Siena, Policlinico Le Scotte, Viale Bracci, Siena, Italy.
authors.forename: Federica
authors.initials: F
authors.lastname: Papacchini
authors.forename: Manuel
authors.initials: M
authors.lastname: Toledano
authors.forename: Francesca
authors.initials: F
authors.lastname: Monticelli
authors.forename: Raquel
authors.initials: R
authors.lastname: Osorio
authors.forename: Ivana
authors.initials: I
authors.lastname: Radovic
authors.forename: Antonella
authors.initials: A
authors.lastname: Polimeni
authors.forename: Franklin
authors.initials: F
authors.lastname: García-Godoy
authors.forename: Marco
authors.initials: M
authors.lastname: Ferrari
mesh_terms: D003188:Composite Resins / Q000737:chemistry*; D001840:Dental Bonding; D003763:Dental Leakage; D017269:Dental Prosthesis Repair; D019232:Dental Restoration Failure; D003799:Dental Stress Analysis; D004356:Drug Storage; D006358:Hot Temperature; D006868:Hydrolysis; D057927:Hydrophobic and Hydrophilic Interactions; D008422:Materials Testing; D011897:Random Allocation; D019279:Resin Cements / Q000737:chemistry*; D012212:Rheology; D012821:Silanes; D016019:Survival Analysis; D013718:Tensile Strength
chemical_list: D003188:Composite Resins; D019279:Resin Cements; D012821:Silanes