A new type of NADH model compound: synthesis and enantioselective reduction of benzoylformates to the corresponding mandelates.
A new type of NADH model compound with good reactivity and enantioselectivity has been synthesized in good yields by an efficient and convenient synthetic method. The structures of these model compounds were confirmed by 1H and 13C-NMR and MS.
Zhao
Jia
J
Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100080, PR China. jetjoo@hotmail.com
Wang
Nai-Xing
NX
Wang
Wu-Wei
WW
Wang
Gui-Xia
GX
Liu
Yan-Hong
YH
Li
Li
L
Yu
Jin-Lan
JL
Tang
Xin-Liang
XL
D005561:Formates / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008333:Mandelic Acids / Q000737:chemistry*; D013058:Mass Spectrometry; D009243:NAD / Q000737:chemistry*; D013237:Stereoisomerism
D005561:Formates; D008333:Mandelic Acids; D009243:NAD