Fine-tuning of a ferrocene[porphyrin]ITO redox cascade for efficient sequential electron transfer commenced by an S2 photoexcited special-pair mimic.
A systematic series of ferrocene/porphyrin redox cascade architectures was assembled through a slipped-cofacial porphyrin dimer on ITO electrode in optimizing the anodic photocurrent generation to perform the highest quantum yield compared to reported values on ITO electrodes.
Morisue
Mitsuhiko
M
Graduate School of Materials Science, Nara Institute of Science and Technology, Ikoma 630-0192, Japan. morisue@kit.ac.jp
Kalita
Dipak
D
Haruta
Noriko
N
Kobuke
Yoshiaki
Y
D004579:Electron Transport; D005296:Ferrous Compounds / Q000737:chemistry*; D000075163:Metallocenes; D010084:Oxidation-Reduction; D010777:Photochemistry; D011166:Porphyrins / Q000737:chemistry*
D005296:Ferrous Compounds; D000075163:Metallocenes; D011166:Porphyrins; C004998:ferrocene