Glycol-modified molybdate catalysts for efficient singlet oxygen generation from hydrogen peroxide.
Pretreatment of molybdate-exchanged layered double hydroxides in polyalcohols such as ethylene glycol affords heterogeneous catalysts showing largely improved oxidant efficiency compared to the unmodified materials.
Wahlen
Joos
J
Centre for Surface Chemistry and Catalysis, K.U. Leuven, Kasteelpark Arenberg 23, Box 2461, 3001 Leuven, Belgium.
De Vos
Dirk
D
Jary
Walther
W
Alsters
Paul
P
Jacobs
Pierre
P
D002384:Catalysis; D006018:Glycols / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry*; D008982:Molybdenum / Q000737:chemistry*; D026082:Singlet Oxygen / Q000737:chemistry*
D006018:Glycols; D026082:Singlet Oxygen; D008982:Molybdenum; D006861:Hydrogen Peroxide