title: Ferrimagnetic FeIII-MnIII zigzag chain formed by a new mer-positioned ironIII cyanide precursor.
abstract: A new cyanide-bearing molecular precursor, mer-[Fe(pzcq)(CN)(3)]- (1), and a zigzag chain, [Fe(pzcq)(CN)(3)][Mn(salen)].4H(2)O (2), were prepared and characterized in terms of structure and magnetism. Magnetic data reveal that intrachain antiferromagnetic couplings via cyanide ligands in 2 are clearly operating, resulting in a ferrimagnetic nature.
authors.affiliation: Department of Chemistry, Korea University, Seoul 136-713, Korea.
authors.forename: Jae Il
authors.initials: JI
authors.lastname: Kim
authors.forename: Houng Sik
authors.initials: HS
authors.lastname: Yoo
authors.forename: Eui Kwan
authors.initials: EK
authors.lastname: Koh
authors.forename: Hyoung Chan
authors.initials: HC
authors.lastname: Kim
authors.forename: Chang Seop
authors.initials: CS
authors.lastname: Hong
mesh_terms: D015392:Chemistry, Inorganic / Q000379:methods*; D018360:Crystallography, X-Ray / Q000379:methods; D003486:Cyanides / Q000032:analysis; D005290:Ferric Compounds / Q000737:chemistry; D005292:Ferricyanides / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008968:Molecular Conformation; D015394:Molecular Structure; D009991:Oscillometry; D013696:Temperature
chemical_list: D003486:Cyanides; D005290:Ferric Compounds; D005292:Ferricyanides; D008024:Ligands; D007501:Iron; C053439:ferric ferricyanide