A CNT-like coordination tube with cyano-bridges.
Reaction of K2[Ru(bipy)(CN)4] with MnCl2 produces a novel bimetallic compound {Mn(H2O)2[Ru(bipy)(CN)4]} (bipy = 2,2'-bipydine), exhibiting a CNT-like structure bridged by cyanide groups and high thermal stability, which has been first observed in coordination polymers.
Xia
Jun
J
Department of Chemistry, Nankai University, Tianjin, 300071, PR China.
Shi
Wei
W
Chen
Xiao-Yan
XY
Wang
Hong-Sheng
HS
Cheng
Peng
P
Liao
Dai-Zheng
DZ
Yan
Shi-Ping
SP