Ice chromatography modification of solute retention on water-ice stationary phase.
Ice chromatography, in which water-ice particles are used as the stationary phase, has high potential as a separation tool, and is an efficient approach to probe the molecular interaction occurring on the water-ice surface. In the present paper, to modify solute retention, several methods are proposed, that is, changing the mobile phase composition, the surface modification of water-ice, and the implantation of functional molecules into water-ice. The retention mechanism of ice chromatography is discussed through these retention modifications.
Tasaki
Yuiko
Y
Department of Chemistry, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8551, Japan.
Okada
Tetsuo
T
D002851:Chromatography, High Pressure Liquid / Q000295:instrumentation / Q000379:methods*; D006860:Hydrogen Bonding; D007053:Ice; D008958:Models, Molecular; D014867:Water / Q000737:chemistry
D007053:Ice; D014867:Water