Molecular complexes based on tetrathiafulvalene and dialkylviologens.
Three kinds of molecular complexes based on tetrathiafulvalene (TTF) and dialkylviologens were prepared and their crystal structures elucidated. While TTF-dimethylviologen complex forms a mixed stack arrangement of donors and acceptors in its crystal structure, TTF donors aggregate with long alkyl groups by CH/pi and/or van der Waals interactions in a couple of TTF-heptylviologen complexes.
Rahman
Bilkish
B
Graduate School of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori, Hyogo 678-1297, Japan.
Akutsu
Hiroki
H
Yamada
Jun-ichi
J
Nakatsuji
Shin'ichi
S
D002621:Chemistry / Q000379:methods; D003460:Crystallization; D018360:Crystallography, X-Ray; D006571:Heterocyclic Compounds / Q000737:chemistry*; D006860:Hydrogen Bonding; D007202:Indicators and Reagents; D008956:Models, Chemical; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D014755:Viologens / Q000737:chemistry*
D006571:Heterocyclic Compounds; D007202:Indicators and Reagents; D014755:Viologens; C063887:tetrathiafulvalene