2-amino-4-nitroaniline, a known compound with unexpected properties.
2-amino-4-nitroaniline crystallizes in a noncentrosymmetric space group, which gives it significant potential for second-order nonlinear optical properties (NLO) in the bulk. Crystallographic and linear-polarized IR-spectrocopic data in the solid state unambiguously confirm a quinoide-like structure in the ground state in contrast to UV and theoretical data, which indicate an aromatic one for the excited state. UV-vis spectral elucidations in solutions with different polarities indicate a significant charge-transfer band with shifts of up to 100 nm, corresponding to a large value for the molecular first hyperpolarizability. Calculations of the UV- and IR-spectroscopic properties confirm the stabilization of the quinoide-like structure in the ground state, as well as the theoretically predicted NLO properties at the molecular level and provide a value of beta(tot), which is some 3.6 times higher than the analogous parameter for p-nitroaniline, a classical compound with experimentally confirmed NLO properties.
Kolev
Tsonko
T
Institute of Organic Chemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Str. build. 9, 1113 Sofia, Bulgaria. kolev@ orgchm.bas.bg
Koleva
Bojidarka B
BB
Spiteller
Michael
M
Mayer-Figge
Heike
H
Sheldrick
William S
WS