Characterization of equatorial and axial six-membered-ring peroxyl radicals.
Spectroscopic data are consistent with computations that show that, in their most stable conformations, the peroxyl moiety is equatorial in cyclohexylperoxyl radicals and axial in oxa- and most polyoxacyclohexyl-2-peroxyl radicals.
DiLabio
Gino A
GA
National Institute for Nanotechnology, National Research Council of Canada, 11421 Saskatchewan Drive, Edmonton, AB, Canada T6G 2M9.
Ingold
Keith U
KU
Walton
John C
JC