Trace analysis of impurities in bulk gases by gas chromatography-pulsed discharge helium ionization detection with "heart-cutting" technique.
A method has been developed for the detection of low-nL/L-level impurities in bulk gases such as H(2), O(2), Ar, N(2), He, methane, ethylene and propylene, respectively. The solution presented here is based upon gas chromatography-pulsed discharge helium ionization detection (GC-PDHID) coupled with three two-position valves, one two-way solenoid valve and four packed columns. During the operation, the moisture and heavy compounds are first back-flushed via a pre-column. Then the trace impurities (except CO(2) which is diverted to a separate analytical column for separation and detection) together with the matrix enter onto a main column, followed by the heart-cut of the impurities onto a longer analytical column for complete separation. Finally the detection is performed by PDHID. This method has been applied to different bulk gases and the applicability of detecting impurities in H(2), Ar, and N(2) are herewith demonstrated. As an example, the resulting detection limit of 100 nL/L and a dynamic range of 100-1000 nL/L have been obtained using an Ar sample containing methane.
Weijun
Yao
Y
Agilent Technologies (Shanghai) Co. Ltd., 412 Yinglun Road, Waigaoqiao Free Trade Zone, Shanghai 200131, China. wei-jun_yao@agilent.com
D002849:Chromatography, Gas / Q000295:instrumentation / Q000379:methods*; D005740:Gases / Q000032:analysis*; D006371:Helium / Q000737:chemistry*; D015203:Reproducibility of Results
D005740:Gases; D006371:Helium