title: Characterization of equatorial and axial six-membered-ring peroxyl radicals.
abstract: Spectroscopic data are consistent with computations that show that, in their most stable conformations, the peroxyl moiety is equatorial in cyclohexylperoxyl radicals and axial in oxa- and most polyoxacyclohexyl-2-peroxyl radicals.
authors.affiliation: National Institute for Nanotechnology, National Research Council of Canada, 11421 Saskatchewan Drive, Edmonton, AB, Canada T6G 2M9.
authors.forename: Gino A
authors.initials: GA
authors.lastname: DiLabio
authors.forename: Keith U
authors.initials: KU
authors.lastname: Ingold
authors.forename: John C
authors.initials: JC
authors.lastname: Walton