title: Carborane radical anions: spectroscopic and electronic properties of a carborane radical anion with a 2n + 3 skeletal electron count.
abstract: One-electron reduction of the well-known carborane 1,2-Ph2-1,2-C2B10H10 (1) gives rise to a stable carborane radical anion ([1]-) with a true 2n + 3 cluster electron count; the geometry of ([1]-) features an elongated C...C cage distance but no significant pi-bonding interactions between the cage and the phenyl substituents.
authors.affiliation: Department of Chemistry, Durham University, South Rd, Durham, UK DH1 3LE. m.a.fox@durham.ac.uk
authors.forename: Mark A
authors.initials: MA
authors.lastname: Fox
authors.forename: Carlo
authors.initials: C
authors.lastname: Nervi
authors.forename: Antonella
authors.initials: A
authors.lastname: Crivello
authors.forename: Paul J
authors.initials: PJ
authors.lastname: Low