title: Bioaccumulation and enantiomeric profiling of organochlorine pesticides and persistent organic pollutants in the killer whale (Orcinus orca) from British and Irish waters.
abstract: Concentrations and enantiomeric profiles for a range of organochlorine compounds are reported in blubber samples from a number of individual killer whales (Orcinus orca) from British and Irish waters. Elevated contaminant levels and enriched isotopic ratios were determined in one individual whale sampled in the Scottish Western Isles compared to the others suggesting marine mammal based dietary influences. The potential application of isotopic ratios to model contaminant uptake, enantioselective enrichment and accumulation is demonstrated. Data are presented which provide information on enantioselective enrichment factors (EFs) for o,p'-DDT, alpha-HCH and toxaphene congeners CHB26 and CHB 50. This dataset further improves the current database on reported levels of a number of contaminants and provides additional background information on potential metabolic processes in killer whales from British and Irish waters.
authors.affiliation: Marine Institute, Rinville, Oranmore, Galway, Ireland. brendan.mchugh@marine.ie
authors.forename: Brendan
authors.initials: B
authors.lastname: McHugh
authors.forename: Robin J
authors.initials: RJ
authors.lastname: Law
authors.forename: Colin R
authors.initials: CR
authors.lastname: Allchin
authors.forename: Emer
authors.initials: E
authors.lastname: Rogan
authors.forename: Sinead
authors.initials: S
authors.lastname: Murphy
authors.forename: M Barry
authors.initials: MB
authors.lastname: Foley
authors.forename: Denise
authors.initials: D
authors.lastname: Glynn
authors.forename: Evin
authors.initials: E
authors.lastname: McGovern
mesh_terms: D000818:Animals; D001711:Biotransformation; D004784:Environmental Monitoring; D005618:Fresh Water; D005843:Geography; D006843:Hydrocarbons, Chlorinated / Q000032:analysis / Q000737:chemistry / Q000493:pharmacokinetics; D007494:Ireland; D010575:Pesticides / Q000032:analysis / Q000737:chemistry / Q000493:pharmacokinetics; D013237:Stereoisomerism; D006113:United Kingdom; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry / Q000493:pharmacokinetics; D050685:Whale, Killer / Q000378:metabolism*
chemical_list: D006843:Hydrocarbons, Chlorinated; D010575:Pesticides; D014874:Water Pollutants, Chemical