New water-soluble metal working fluids additives from phosphonic acid derivatives for aluminum alloy materials.
Water-soluble metal working fluids are used for processing of aluminum alloy materials. This short paper describes properties of new additives for water-soluble cutting fluids for aluminum alloy materials. Some alkyldiphosphonic acids were prepared with known method. Amine salts of these phosphonic acids showed anti-corrosion property for aluminum alloy materials. However, they have no hard water tolerance. Monoesters of octylphosphonic acid were prepared by the reaction of octylphosphonic acid dichloride with various alcohols in the presence of triethylamine. Amine salts of monoester of octylphosphonic acid with diethyleneglycol monomethyl ether, ethyleneglycol monomethyl ether and triethyleneglycol monomethyl ether showed both of a good anti-corrosion property for aluminum alloy materials and hard water tolerance.
Kohara
Ichitaro
I
NEOS Research Center, Konan, Shiga, Japan.
Tomoda
Hideyuki
H
Watanabe
Shoji
S
D000497:Alloys / Q000138:chemical synthesis* / Q000737:chemistry; D000535:Aluminum / Q000737:chemistry*; D002627:Chemistry, Physical / Q000379:methods; D003343:Corrosion; D008670:Metals / Q000737:chemistry*; D008954:Models, Biological; D063065:Organophosphonates / Q000737:chemistry*; D012995:Solubility; D012997:Solvents / Q000032:analysis / Q000494:pharmacology*; D014867:Water
D000497:Alloys; D008670:Metals; D063065:Organophosphonates; D012997:Solvents; D014867:Water; D000535:Aluminum