title: Selective gas sorption within a dynamic metal-organic framework.
abstract: A microporous metal-organic framework 1 Co(NDC)(4,4'-Bipy)(0.5).G(x) (NDC = 2,6-naphthalenedicarboxylate; 4,4'-Bipy = 4,4'-bipyridine; G = guest molecules) was synthesized and structurally characterized of a doubly interpenetrated primitive cubic net. To make use of the framework flexibility, 1 was activated at temperatures of 150 and 200 degrees C to form 1a and 1b, respectively, exhibiting highly selective sorption behaviors of hydrogen over nitrogen-gas molecules.
authors: Department of Chemistry, University of Texas-Pan American, Edinburg, Texas 78541-2999, USA. banglin@utpa.edu
authors: Banglin
authors: B
authors: Chen
authors: Shengqian
authors: S
authors: Ma
authors: Eric J
authors: EJ
authors: Hurtado
authors: Emil B
authors: EB
authors: Lobkovsky
authors: Chengdu
authors: C
authors: Liang
authors: Haoguo
authors: H
authors: Zhu
authors: Sheng
authors: S
authors: Dai