A new copper(II) complex as an efficient catalyst of luminol chemiluminescence.
A new copper complex (2) has exhibited highly efficient catalytic activity of luminol chemiluminescence in water in the presence of ascorbic acid and dissolved O2 under conditions that conventional catalysts such as Cu(OAc)2, hemin or cyclen-Cu(II) did not show significant activity.
Uzu
Takahiro
T
Graduate School of Pharmaceutical Sciences, Kyushu University, 3-1-1, Maidashi, Fukuoka 812-8582, Japan.
Sasaki
Shigeki
S
D001205:Ascorbic Acid / Q000737:chemistry; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D008163:Luminescent Measurements; D008165:Luminol / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry; D014867:Water / Q000737:chemistry
D009942:Organometallic Compounds; D014867:Water; D008165:Luminol; D003300:Copper; D001205:Ascorbic Acid; D010100:Oxygen