title: Site-selective modification of peptides using rhodium and palladium catalysis: complementary electrophilic and nucleophilic arylation.
abstract: The site-selective modification of peptides containing dehydroalanine, tyrosine and tryptophan residues has been achieved using rhodium catalysed conjugate additions or palladium catalysed aryl-amination and -etherification reactions.
authors: Department of Chemistry, University of Bath, Claverton Down, Bath, UKBA2 7AY.
authors: Christopher J
authors: CJ
authors: Chapman
authors: Ai
authors: A
authors: Matsuno
authors: Christopher G
authors: CG
authors: Frost
authors: Michael C
authors: MC
authors: Willis
mesh_terms: D000215:Acylation; D002384:Catalysis; D010165:Palladium / Q000737:chemistry*; D010455:Peptides / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
chemical_list: D010455:Peptides; D010165:Palladium; D012238:Rhodium