Removal of a dye from simulated wastewater by adsorption using treated parthenium biomass.
In the present study adsorption of rhodamine-B from aqueous solution on formaldehyde treated parthenium biomass (WC) and phosphoric acid treated parthenium carbon (PWC) was studied. Aqueous solutions of various concentrations (50-500 mg/l) were shaken with certain amount of adsorbent to determine the adsorption capacity of rhodamine-B on WC and PWC. The effectiveness of formaldehyde treated parthenium biomass (WC) and phosphoric acid treated parthenium carbon (PWC) in adsorbing rhodamine-B from aqueous solution has been studied as a function of agitation time, adsorbent dose, initial dye concentration and pH. The adsorption capacities of the studied adsorbents were in the order PWC>WC. Initial pH had negligible effect on the adsorption capacity. Maximum dye was sequestered from the solution within 60min after the start of every experiment. After that, the concentration of rhodamine-B in the liquid-phase remained constant. The adsorption of rhodamine-B onto PWC and WC followed second-order kinetic model. Adsorption data were modeled using both Langmuir and Freundlich classical adsorption isotherms. The adsorption capacity Q(0) was 59.17 mg/g at initial pH 7.0 for the particle size 0.3-1.0mm for phosphoric acid treated parthenium carbon (PWC). The FT-IR spectra of the adsorbents were recorded to explore number and position of functional groups available for the binding of dye cation onto studied adsorbents. SEMs of the adsorbents were recorded to explore the morphology of the studied adsorbents.
Lata
Hem
H
Department of Chemistry, Guru Jambheshwar University of Science and Technology, Hisar, Haryana, India.
Mor
Suman
S
Garg
V K
VK
Gupta
R K
RK
D000327:Adsorption; D019659:Asteraceae / Q000737:chemistry*; D018533:Biomass; D004396:Coloring Agents / Q000737:chemistry*; D005557:Formaldehyde / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D010756:Phosphoric Acids / Q000737:chemistry; D012235:Rhodamines / Q000737:chemistry*; D014865:Waste Disposal, Fluid / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods*
D004396:Coloring Agents; D010756:Phosphoric Acids; D012235:Rhodamines; D014874:Water Pollutants, Chemical; D005557:Formaldehyde; C030242:phosphoric acid; C029773:rhodamine B