Heterogeneous reactions of ozone and D-limonene on activated carbon.
If released in significant amounts, products formed by reactions between ozone (O3) and volatile organic compounds (VOCs) sorbed on activated carbon (AC) filters could degrade indoor air quality (IAQ). Heterogeneous reactions were investigated in laboratory experiments aimed at characterizing reaction products. Effluent air of AC loaded with limonene and exposed to O3 (5.8 ppm) yielded unreacted limonene (501+/-197 microg/m3), low levels of 4-acetyl-1-methylcyclohexene (AMCH) (20+/-2 microg/m3), and limonene oxides (25+/-7 microg/m3). Most of the O3-limonene products remained on the AC, and most (58%) of the limonene remained unreacted on the AC after exposure to a stoichiometric excess of O3 for 48 h. Thus, in addition to known homogenous reactions, O3-limonene reactions occur heterogeneously on AC but to a much lesser extent. However, the fate of 95% of the depleted limonene was not determined; much of the missing portion was attributed to desorption from the AC, but the formation of other secondary indoor air pollutants is possible. VOC-loaded AC air filters exposed to O3 seem unlikely, however, to constitute a significant emission source of reaction products. More studies are necessary to investigate other pollutants, effects of environmental conditions, and VOC releases from AC that may be enhanced by O3 exposure.


CONCLUSIONS
Reactions between ozone and certain volatile organic compounds such as limonene (a common ingredient of many consumer products) occurring on the surface of ventilation filters could impact indoor air quality if products are released in significant amounts. This study suggests that although very small amounts of limonene adsorbed on a filter will react with O3, ventilation filters are not likely to be significant sources of ozone oxidation products. More studies are needed to investigate whether ozone exposure enhances desorption of pollutants from ventilation filters and to measure the formation of formaldehyde and other products that are not easily retained by charcoal filters.
Metts
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Department of Environmental Health, East Tennessee State University, Johnson City, TN 37614-1709, USA. metts@etsu.edu
Batterman
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D000327:Adsorption; D016902:Air Pollution, Indoor; D002606:Charcoal; D000081005:Cyclohexane Monoterpenes; D003510:Cyclohexanes / Q000138:chemical synthesis; D053138:Cyclohexenes / Q000494:pharmacology*; D004305:Dose-Response Relationship, Drug; D004347:Drug Interactions; D000077222:Limonene; D039821:Monoterpenes / Q000138:chemical synthesis; D010126:Ozone / Q000008:administration & dosage / Q000494:pharmacology*; D013729:Terpenes / Q000494:pharmacology*; D013997:Time Factors
C525009:4-acetyl-1-methylcyclohexene; D000081005:Cyclohexane Monoterpenes; D003510:Cyclohexanes; D053138:Cyclohexenes; D039821:Monoterpenes; D013729:Terpenes; C028940:limonene-1,2-epoxide; D002606:Charcoal; D010126:Ozone; D000077222:Limonene