Transport and crystallization of colloidal particles in a thin nematic cell.
In a thin planar nematic cell, the application of an AC electric field induces a macroscopic transport of micrometer-sized colloidal particles along the nematic director. We have analyzed the dependence of particle velocities on the electric-field amplitude and frequency and found that it decreases exponentially with increasing frequency. Using specially designed electrodes we have observed that colloidal particles could be pumped and accelerated across the field-no-field interface, and measured the structural force and the corresponding potential, which is of the order of 10000 kBT for 4 microm particles. We demonstrate that spatially periodic close-packed crystalline colloidal structures can be obtained, which are thermodinamically metastable for many days after turning off the electric field and slowly decay into linear chains. Above the nematic-isotropic phase transition, such crystalline structures are non-stable and decay in few minutes.
Skarabot
M
M
J. Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia.
Tkalec
U
U
Musevic
I
I
D002627:Chemistry, Physical / Q000379:methods; D003102:Colloids / Q000737:chemistry*; D003460:Crystallization; D004563:Electrochemistry / Q000379:methods*; D004566:Electrodes; D050866:Liquid Crystals; D008855:Microscopy, Electron, Scanning; D008956:Models, Chemical; D010316:Particle Size; D044367:Phase Transition; D013499:Surface Properties; D013816:Thermodynamics
D003102:Colloids