Structure of water incorporated in amphoteric polymer thin films as revealed by FT-IR spectroscopy.
The structure and hydrogen bonding of water incorporated in a thin film of amphoteric terpolymers composed of various ratios of MA, DMAPMA, and BMA were analyzed using the band shapes of the O--H stretching in the IR spectra. At an early stage of sorption of water, the IR spectrum for the water incorporated in the film with comparative contents of MA and DMAPMA residues was similar to that for free water. This is consistent with the tendency for zwitterionic polymers, but is in contrast with the drastic change in the IR spectrum of water incorporated in non-ionic polymer films such as polyBMA. These results suggest a correlation between the mildness of the charge-balanced polymers to the structure of incorporated water and their blood compatibilities.
Kitano
Hiromi
H
Department of Applied Chemistry, Graduate School of Science and Engineering, University of Toyama, Toyama, Japan. kitano@eng.u-toyama.ac.jp
Nagaoka
Kyoko
K
Tada
Susumu
S
Gemmei-Ide
Makoto
M
Tanaka
Masaru
M
D000178:Acrylamides / Q000737:chemistry; D000665:Ampholyte Mixtures / Q000737:chemistry*; D008689:Methacrylates / Q000737:chemistry; D015394:Molecular Structure; D011108:Polymers / Q000138:chemical synthesis* / Q000737:chemistry; D017550:Spectroscopy, Fourier Transform Infrared; D014867:Water / Q000737:chemistry*
D000178:Acrylamides; D000665:Ampholyte Mixtures; D008689:Methacrylates; D011108:Polymers; D014867:Water; C008384:methacrylic acid; C016284:butyl methacrylate