title: A whiff of oxygen before the great oxidation event?
abstract: High-resolution chemostratigraphy reveals an episode of enrichment of the redox-sensitive transition metals molybdenum and rhenium in the late Archean Mount McRae Shale in Western Australia. Correlations with organic carbon indicate that these metals were derived from contemporaneous seawater. Rhenium/osmium geochronology demonstrates that the enrichment is a primary sedimentary feature dating to 2501 +/- 8 million years ago (Ma). Molybdenum and rhenium were probably supplied to Archean oceans by oxidative weathering of crustal sulfide minerals. These findings point to the presence of small amounts of O2 in the environment more than 50 million years before the start of the Great Oxidation Event.
authors: School of Earth and Space Exploration, Arizona State University, Tempe, AZ 85287, USA. anbar@asu.edu
authors: Ariel D
authors: AD
authors: Anbar
authors: Yun
authors: Y
authors: Duan
authors: Timothy W
authors: TW
authors: Lyons
authors: Gail L
authors: GL
authors: Arnold
authors: Brian
authors: B
authors: Kendall
authors: Robert A
authors: RA
authors: Creaser
authors: Alan J
authors: AJ
authors: Kaufman
authors: Gwyneth W
authors: GW
authors: Gordon
authors: Clinton
authors: C
authors: Scott
authors: Jessica
authors: J
authors: Garvin
authors: Roger
authors: R
authors: Buick
mesh_terms: D001315:Australia; D019015:Geologic Sediments / Q000737:chemistry*; D007554:Isotopes / Q000032:analysis; D008982:Molybdenum / Q000032:analysis; D009792:Oceans and Seas; D009992:Osmium / Q000032:analysis; D010084:Oxidation-Reduction; D010100:Oxygen / Q000032:analysis; D012211:Rhenium / Q000032:analysis; D012623:Seawater / Q000737:chemistry; D013455:Sulfur / Q000032:analysis; D013460:Sulfur Isotopes / Q000032:analysis; D013696:Temperature; D014501:Uranium / Q000032:analysis
chemical_list: D007554:Isotopes; D013460:Sulfur Isotopes; D009992:Osmium; D014501:Uranium; D013455:Sulfur; D012211:Rhenium; D008982:Molybdenum; D010100:Oxygen