Efficient preparation of monohydrosilanes using palladium-catalyzed Si-C bond formation.
The arylation of dihydrosilanes with aryl iodides or heteroaryl iodides in the presence of a palladium catalyst provides the corresponding monohydrosilanes in good to high yield. Moderate to good yields are obtained even in the presence of a variety of reactive functional groups, such as -NH2, -OH, or -CN, without their protection.
Yamanoi
Yoshinori
Y
Department of Chemistry, School of Science, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-0033, Japan. yamanoi@chem.s.u-tokyo.ac.jp
Taira
Takafumi
T
Sato
Jun-ichi
J
Nakamula
Ikuse
I
Nishihara
Hiroshi
H