A pillared discrete bilayer formed from guanidinium and ferrocenedisulfonate ions: synthesis, crystal structure, and initial electrochemical properties.
The solid salt [C(NH2)3]2[Fe(eta5-C5H4SO3)2] forms a two-dimensional network based upon pillared discrete bilayers formed via charge-assisted hydrogen bonds and is electrochemically active when adhered to a glassy carbon electrode.
Xie
Jingli
J
School of Chemistry and Bio21 Molecular Science and Biotechnology Institute, The University of Melbourne, Parkville, Victoria 3052, Australia. xij@unimelb.edu.au
Ma
Michelle T
MT
Abrahams
Brendan F
BF
Wedd
Anthony G
AG
D004563:Electrochemistry / Q000379:methods*; D005296:Ferrous Compounds / Q000737:chemistry*; D019791:Guanidine / Q000737:chemistry*; D007477:Ions; D000075163:Metallocenes; D015394:Molecular Structure; D013451:Sulfonic Acids / Q000737:chemistry*
D005296:Ferrous Compounds; D007477:Ions; D000075163:Metallocenes; D013451:Sulfonic Acids; D019791:Guanidine; C004998:ferrocene