[V(IV)15Sb(III)6O42]6-: an antimony analogue of the molecular magnet [V15As6O42(H2O)]6-.
A hydrothermal approach employing an amine as reducing agent enables synthesis of an analogue of the arsenato(iii)-oxovanadate {V(15)As(6)}, representing the first systematic variation of this intensely studied magnetic system.
Kiebach
Ragnar
R
Christian-Albrechts-Universität zu Kiel, Institut für Anorganische Chemie, D-24098, Kiel, Germany. wbensch@ac.uni-kiel.de
Näther
Christian
C
Kögerler
Paul
P
Bensch
Wolfgang
W