title: Surface analysis of cryofixation-vacuum-freeze-dried polyaluminum chloride-humic acid (PACl-HA) flocs.
abstract: The powder of polyaluminum chloride-humic acid (PACl-HA) flocs was prepared by cryofixation-vacuum-freeze-drying method. The FTIR spectra show that some characteristic functional groups in polyaluminum chloride (PACl), humic acid (HA), and kaolin still existed in the dried flocs. X-ray diffractometry (XRD) patterns indicate that these flocs are amorphous. Nitrogen adsorption-desorption isotherms were obtained for different samples of the dried PACl-HA flocs. The BET specific surface area, BJH cumulative absorbed volume and BJH desorption average pore diameter of them were determined. The peak values of 8.4-11.2 nm (pore diameter) for pore size distribution (PSD) curves indicate that the pores of the dried flocs are mostly mesopores. The surface fractal dimensions D(s) and the corresponding fractal scales determined from both SEM images and nitrogen adsorption-desorption data sets reveal the multi-scale surface fractal properties of the dried PACl-HA flocs, which exhibited two distinct fractal regimes: a regime of low fractal dimensions (2.07-2.26) at higher scales (23-387 nm), mainly belonging to exterior surface scales, and a higher fractal dimensions (2.24-2.37) at lower scales (0.80-7.81 nm), falling in pore surface scales. Both HA addition and kaolin reduction in dried floc can decrease the irregularity and roughness of external surface. However, for the irregularity and roughness of pore surface, the addition of HA or kaolin in dried floc can increase them. Furthermore, some difference was found between the pore surface fractal dimensions D(s) calculated from nitrogen adsorption and desorption data. The pore surface D(s) values calculated through thermodynamic model were much greater than three.
authors: Environmental Science, College of Environmental Science and Engineering, The Key Laboratory for Silviculture and Conservation of Ministry of Education, Beijing Forestry University, Beijing 100083, PR China. wangyilimail@126.com
authors: Yili
authors: Y
authors: Wang
authors: Baiyu
authors: B
authors: Du
authors: Jie
authors: J
authors: Liu
authors: Jia
authors: J
authors: Lu
authors: Baoyou
authors: B
authors: Shi
authors: Hongxiao
authors: H
authors: Tang
mesh_terms: D000077410:Aluminum Chloride; D017607:Aluminum Compounds / Q000737:chemistry*; D002712:Chlorides / Q000737:chemistry*; D003460:Crystallization; D005615:Freezing; D006812:Humic Substances; D010316:Particle Size; D011108:Polymers / Q000737:chemistry*; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods; D013499:Surface Properties; D014618:Vacuum; D014867:Water / Q000737:chemistry; D014961:X-Ray Diffraction
chemical_list: D017607:Aluminum Compounds; D002712:Chlorides; D006812:Humic Substances; D011108:Polymers; D014867:Water; D000077410:Aluminum Chloride