title: Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide.
abstract: A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N3)2].MeCN (1.MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.
authors: Department of Chemistry, Korea University, Seoul, Korea.
authors: Houng Sik
authors: HS
authors: Yoo
authors: Jae Il
authors: JI
authors: Kim
authors: Namgeun
authors: N
authors: Yang
authors: Eui Kwan
authors: EK
authors: Koh
authors: Je-Geun
authors: JG
authors: Park
authors: Chang Seop
authors: CS
authors: Hong
mesh_terms: D001386:Azides / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008280:Magnetics; D008958:Models, Molecular
chemical_list: D001386:Azides; D003300:Copper; D007501:Iron