title: Structure-dependent fluorescence efficiencies of individual single-walled carbon nanotubes.
abstract: Single-nanotube photometry was used to measure the product of absorption cross section and fluorescence quantum yield for 12 (n,m) structural species of semiconducting single-walled carbon nanotubes in aqueous SDBS suspension. These products ranged from 1.7 to 4.5 x 10(-19) cm(2)/C atom, generally increasing with optical band gap as described by the energy gap law. The findings suggest fluorescent quantum yields of approximately 8% for the brightest, (10,2) species and introduce the empirical calibration factors needed to deduce quantitative (n,m) distributions from bulk fluorimetric intensities.
authors: Department of Chemistry, Richard E. Smalley Institute for Nanoscale Science and Technology, Center for Biological and Environmental Nanotechnology, Rice University, 6100 Main Street, Houston, Texas 77005, USA.
authors: Dmitri A
authors: DA
authors: Tsyboulski
authors: John-David R
authors: JD
authors: Rocha
authors: Sergei M
authors: SM
authors: Bachilo
authors: Laurent
authors: L
authors: Cognet
authors: R Bruce
authors: RB
authors: Weisman
mesh_terms: D003198:Computer Simulation; D008422:Materials Testing; D008956:Models, Chemical; D008958:Models, Molecular; D008968:Molecular Conformation; D036103:Nanotechnology / Q000379:methods*; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D012680:Sensitivity and Specificity; D013050:Spectrometry, Fluorescence / Q000379:methods*; D013499:Surface Properties
chemical_list: D037742:Nanotubes, Carbon