Uncommon ferromagnetic interactions in a homometallic Co(II) chain bridged by a single end-to-end azide.
A new one-dimensional heterochiral coordination polymer [Co(bmdt)(N3)2].MeCN (1.MeCN) with well-isolated chains was prepared via a self-assembly process. Magnetic data show that intrachain ferromagnetic couplings via the single end-to-end azide group are observed, which is an extraordinary case among the azide-bridged Co(II) systems.
Yoo
Houng Sik
HS
Department of Chemistry, Korea University, Seoul, Korea.
Kim
Jae Il
JI
Yang
Namgeun
N
Koh
Eui Kwan
EK
Park
Je-Geun
JG
Hong
Chang Seop
CS
D001386:Azides / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D008280:Magnetics; D008958:Models, Molecular
D001386:Azides; D003300:Copper; D007501:Iron