Synthesis, crystal structure and optical properties of [Ag(UO2)3(OAc)9][Zn(H2O)4(CH3CH2OH)2]: a novel compound containing closed-shell 3d10, 4d10 and 5d10 metal ions.
[Ag(UO2)3 (OAc)9][Zn(H2O)4(CH3CH2OH)2] (, OAc = CH3COO-) crystallized from an ethanol solution and its structure was determined by IR spectroscopy, elemental analysis, 1H NMR, 13C NMR and X-ray crystallography; it is composed of [Zn(H2O)4(CH3CH2OH)2]2+ cations and [Ag(UO2)3(OAc)9]2- anions in which triuranyl [(UO2)(OAc)3]3 clusters are linked by the Ag ion.
Luo
Geng-Geng
GG
Department of chemistry, Xiamen University, Xiamen, 361005, People's Republic of China.
Lin
Li-Rong
LR
Huang
Rong-Bin
RB
Zheng
Lan-Sun
LS