Rapid access to polyprenylated phloroglucinols via alkylative dearomatization-annulation: total synthesis of (+/-)-clusianone(1).
Qi
Ji
J
Department of Chemistry and Center for Chemical Methodology and Library Development (CMLD-BU), Boston University, Boston, MA 02215, USA.
Porco
John A
JA
D001577:Benzophenones; D016227:Benzoquinones; D001671:Biochemistry / Q000379:methods; D001643:Bridged Bicyclo Compounds / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D002625:Chemistry, Organic / Q000379:methods; D031251:Clusia; D008956:Models, Chemical; D008962:Models, Theoretical; D008968:Molecular Conformation; D010696:Phloroglucinol / Q000737:chemistry*; D010940:Plant Proteins / Q000378:metabolism; D054876:Prenylation; D013696:Temperature
C118110:7-epiclusianone; D001577:Benzophenones; D016227:Benzoquinones; D001643:Bridged Bicyclo Compounds; D010940:Plant Proteins; D002244:Carbon; D010696:Phloroglucinol