A new type of imido group donor: synthesis and characterization of sulfonylimino-lambda(3)-bromane that acts as a nitrenoid in the aziridination of olefins at room temperature under metal-free conditions.
Ochiai
Masahito
M
Graduate School of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan. mochiai@ph.tokushima-u.ac.jp
Kaneaki
Takao
T
Tada
Norihiro
N
Miyamoto
Kazunori
K
Chuman
Hiroshi
H
Shiro
Motoo
M
Hayashi
Satoko
S
Nakanishi
Waro
W
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D001388:Aziridines / Q000737:chemistry*; D017605:Bromine Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D007094:Imides / Q000737:chemistry*; D008670:Metals / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D017672:Nitrogen Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013457:Sulfur Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013696:Temperature
D000475:Alkenes; D001388:Aziridines; D017605:Bromine Compounds; D007094:Imides; D008670:Metals; D017672:Nitrogen Compounds; D013457:Sulfur Compounds; C033132:aziridine