title: Chemical composition of the volatile extract and antioxidant activities of the volatile and nonvolatile extracts of Egyptian corn silk (Zea mays L.).
abstract: A total of 36 compounds, which comprised 99.4% of the extract, were identified by gas chromatography and mass spectrometry (GC-MS) in the volatile dichloromethane extract obtained from Egyptian corn silk. The main constituents of the volatile extract were cis-alpha-terpineol (24.22%), 6,11-oxidoacor-4-ene (18.06%), citronellol (16.18%), trans-pinocamphone (5.86%), eugenol (4.37%), neo-iso-3-thujanol (2.59%), and cis-sabinene hydrate (2.28%). Dried Egyptian corn silk was also directly extracted with petroleum ether, ethanol, and water. All extracts from solvent extraction and the volatile extract described above exhibited clear antioxidant activities at levels of 50-400 microg/mL in the 2,2-diphenyl-1-picrylhydrazyl (DPPH)/linoleic acid assay. The ethanol extract inhibited DPPH activity by 84% at a level of 400 microg/mL. All samples tested via the beta-carotene bleaching assay also exhibited satisfactory antioxidant activity with clear dose responses. This study indicates that corn silk could be used to produce novel natural antioxidants as well as a flavoring agent in various food products.
authors.affiliation: Flavor and Aroma Department, National Research Center, Dokki, Cairo, Egypt.
authors.forename: Ahmed
authors.initials: A
authors.lastname: El-Ghorab
authors.forename: Khaled F
authors.initials: KF
authors.lastname: El-Massry
authors.forename: Takayuki
authors.initials: T
authors.lastname: Shibamoto
mesh_terms: D000080462:Acyclic Monoterpenes; D000975:Antioxidants / Q000494:pharmacology; D000081005:Cyclohexane Monoterpenes; D053138:Cyclohexenes / Q000032:analysis; D004534:Egypt; D008401:Gas Chromatography-Mass Spectrometry; D039821:Monoterpenes / Q000032:analysis; D010936:Plant Extracts / Q000737:chemistry* / Q000494:pharmacology; D012997:Solvents; D014835:Volatilization; D003313:Zea mays / Q000737:chemistry*
chemical_list: D000080462:Acyclic Monoterpenes; D000975:Antioxidants; D000081005:Cyclohexane Monoterpenes; D053138:Cyclohexenes; D039821:Monoterpenes; D010936:Plant Extracts; D012997:Solvents; C016775:alpha-terpineol; C007078:citronellol