title: Influences of preparative methods of humic acids on the sorption of 2,4,6-trichlorophenol.
abstract: Humic acids (HAs) are a major component of soil organic matter which strongly affects the sorption behavior of organic contaminants in soils. To assess the sorption-desorption characteristics of organic compounds on HAs, the organic adsorbent is usually isolated using an acid-base extraction method followed by air-drying or freeze-drying. In this study, a peat soil from the Yangming mountain area of Taiwan was sampled and repeatedly extracted followed by either air-drying or a non-drying treatment (denoted DHAs and NDHAs, respectively). The sorption of 2,4,6-TCP on HAs was evaluated using the batch method. Kinetic sorption results indicated that DHAs exhibited a two-step first-order sorption behavior, involving a rapid sorption followed by a slow sorption. The slow sorption may be attributed to the diffusion of 2,4,6-TCP through the condensed aromatic domains of HAs. On the contrary, the sorption of 2,4,6-TCP on NDHAs was extremely rapid, and the sorption data did not fit existing kinetic models. Each HA sample exhibited a nonlinear sorption isotherm. Sorption nonlinearity (represented by Freundlich N values) and K(oc) had a positive relationship with aliphaticity for DHAs; however, nonlinearity and K(oc) correlated positively with aromaticity when NDHAs adsorbents were used. We conclude that the air-drying technique may artificially create a more condensed area, which strongly affects the sorption characteristics of HAs. Thus, an incorrect evaluation of the sorption capacity and its relationship with the chemical composition of HAs would arise following use of the air-drying method.
authors.affiliation: Department of Soil and Environmental Sciences, National Chung Hsing University, Taichung 40227, Taiwan.
authors.forename: Ying-Ying
authors.initials: YY
authors.lastname: Huang
authors.forename: Shan-Li
authors.initials: SL
authors.lastname: Wang
authors.forename: Jen-Chyi
authors.initials: JC
authors.lastname: Liu
authors.forename: Yu-Min
authors.initials: YM
authors.lastname: Tzou
authors.forename: Rung-Rung
authors.initials: RR
authors.lastname: Chang
authors.forename: Jen-Hshuan
authors.initials: JH
authors.lastname: Chen
mesh_terms: D000327:Adsorption; D002733:Chlorophenols / Q000737:chemistry*; D006812:Humic Substances / Q000032:analysis*; D008962:Models, Theoretical
chemical_list: D002733:Chlorophenols; D006812:Humic Substances; C024564:2,4,6-trichlorophenol