Zwitterionic pi-radical involving EDT-TTF-imidazole and F4TCNQ: redox properties and self-assembled structure by hydrogen-bonds and multiple S...S interactions.
The reaction between an imidazole-functionalized EDT-TTF and F(4)TCNQ produced a zwitterionic pi-radical, which formed a self-assembled structure by the cooperation of hydrogen-bonds and multiple S...S interactions and exhibited three-step oxidation processes and a high electrical conductivity as a single-component organic molecule.
Murata
Tsuyoshi
T
Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka, 560-0043, Japan.
Morita
Yasushi
Y
Yakiyama
Yumi
Y
Nishimura
Yoshie
Y
Ise
Tomoaki
T
Shiomi
Daisuke
D
Sato
Kazunobu
K
Takui
Takeji
T
Nakasuji
Kazuhiro
K