Catena-poly[[dinitratocadmium(II)]bis[mu-bis(2-methyl-1H-imidazol-1-yl)methane-kappa(2)N(3):N(3')]].
The title compound, [Cd(NO(3))(2)(C(9)H(12)N(4))(2)](n), has a one-dimensional double-bridged chain polymer structure with a 16-membered macrometallacyclic tetragonal structural motif. The Cd(II) ion occupies a crystallographic inversion centre and is coordinated by four equatorial N atoms from four distinct bis(2-methylimidazol-1-yl)methane ligands and two apical nitrate O atoms to form a slightly distorted octahedral coordination geometry.
Jin
Chuan Ming
CM
Hubei Key Laboratory of Bioanalytical Techniques, Department of Chemistry and Environmental Engineering, Hubei Normal University, Huangshi 435002, People's Republic of China. cmjin@email.hbnu.edu.cn
Chen
Cai Yuan
CY
Wang
Wei Dong
WD
Wu
Ling Yan
LY
D019187:Cadmium Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*
D019187:Cadmium Compounds; D009942:Organometallic Compounds; C525533:catena-poly((dinitratocadmium(II))bis(mu-bis(2-methyl-1H-imidazol-1-yl)methane-kappa(2)N(3)-N(N')))