title: Volatile magnesium octahydrotriborate complexes as potential CVD precursors to MgB2. Synthesis and characterization of Mg(B3H8)2 and its etherates.
abstract: The solid-state reaction of MgBr2 and NaB3H8 at 20 degrees C, followed by sublimation at 80 degrees C and 0.05 Torr, affords Mg(B3H8)2 as a white solid. Similar reactions with MgBr2(Et2O) and MgBr2(Me2O)1.5 afford the crystalline ether adducts Mg(B3H8)2(Et2O)2 and Mg(B3H8)2(Me2O)2, respectively. In contrast, reactions of MgBr2 with NaB3H8, the presence of excess solvent result in the formation of nonvolatile, probably ionic, magnesium compounds of the type [MgLx][B3H8]2. The adducts Mg(B3H8)2(Et2O)2 and Mg(B3H8)2(Me2O)2 are the first crystallographically characterized magnesium complexes of the B3H8- ligand; in both structures, the magnesium center adopts a distorted cis-octahedral geometry with two bidentate B3H8 groups and two Et2O ligands. Owing to their volatility, Mg(B3H8)2(Et2O)2 and Mg(B3H8)2(Me2O)2 are potential precursors for the deposition of MgB2 thin films, although preliminary efforts to employ them as chemical vapor deposition sources produce boron-rich MgBx films instead, with x approximately 7. Finally, the synthesis and structure of Cp2Mg(thf) are described: this mono-thf adduct of Cp2Mg bears two eta5-Cp groups, unlike other Lewis base adducts of Cp2Mg, which contain one eta5-Cp group and one eta1- or eta2-Cp group.
authors.affiliation: School of Chemical Sciences, Department of Materials Science and Engineering, University of Illinois at Urbana-Champaign, 600 South Mathews Avenue, Urbana, IL 61801, USA.
authors.forename: Do Young
authors.initials: DY
authors.lastname: Kim
authors.forename: Yu
authors.initials: Y
authors.lastname: Yang
authors.forename: John R
authors.initials: JR
authors.lastname: Abelson
authors.forename: Gregory S
authors.initials: GS
authors.lastname: Girolami