title: Synthesis, characterization and photophysics of a new series of anionic C,N,C cyclometalated platinum complexes.
abstract: A novel series of anionic mononuclear terdentate dicyclometalated complexes (NBu4)[Pt(CwedgeNwedgeC)X] (HCwedgeNwedgeCH=2,6-diphenylpyridine) containing acetylide (X=C[triple bond]CR, R=tBu, 1; Ph, 2; Tol, 3; (4-OMe)C6H4, 4) or another anionic ligand (X=CN, 5; S-2Py, 6; CH2COCH3, 7) have been synthesized and fully characterized. The solid-state structures of complexes 1 and 4-6 have also been determined by X-ray diffraction studies, showing, in all the cases, the presence of several types of weak hydrogen interactions, leading to the generation of supramolecular 2D (1) or 3D (4-6) architectures. All the complexes (1-7) are intensely luminescent at low temperature (solid and glassy CH2Cl2), exhibiting concentration dependence in the emissions of the glassy CH2Cl2 matrix.
authors.affiliation: Departamento de Química, Grupo de Síntesis Química de La Rioja, UA-C.S.I.C. Universidad de La Rioja, 26006 Logroño, Spain.
authors.forename: Jesús R
authors.initials: JR
authors.lastname: Berenguer
authors.forename: Elena
authors.initials: E
authors.lastname: Lalinde
authors.forename: Javier
authors.initials: J
authors.lastname: Torroba