title: Versatile direct dehydrative approach for diaryliodonium(III) salts in fluoroalcohol media.
abstract: We have found that the use of fluoroalcohol media greatly enhanced the efficiency and scope of the direct dehydrative condensation of arenes and hypervalent iodine(III) compounds; the present clean method has a broad range of applicability as well as unique selectivity in the aromatic substrates, and is highly efficient even in polymer functionalization.
authors.affiliation: Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka 565-0871, Japan.
authors.forename: Toshifumi
authors.initials: T
authors.lastname: Dohi
authors.forename: Motoki
authors.initials: M
authors.lastname: Ito
authors.forename: Koji
authors.initials: K
authors.lastname: Morimoto
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Minamitsuji
authors.forename: Naoko
authors.initials: N
authors.lastname: Takenaga
authors.forename: Yasuyuki
authors.initials: Y
authors.lastname: Kita
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D001555:Benzene Derivatives / Q000737:chemistry; D005461:Fluorine / Q000737:chemistry*; D007455:Iodine / Q000737:chemistry*; D015394:Molecular Structure; D009861:Onium Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011137:Polystyrenes / Q000737:chemistry; D012492:Salts / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry; D014867:Water / Q000737:chemistry*
chemical_list: D000438:Alcohols; D001555:Benzene Derivatives; D009861:Onium Compounds; D011137:Polystyrenes; D012492:Salts; D012821:Silanes; D014867:Water; D005461:Fluorine; C010219:mesitylene; D007455:Iodine