title: Self-assembly of monolayer-thick alumina particle-epoxy composite films.
abstract: Monolayer-thick composite films composed of alpha-alumina and Spurr's epoxy were prepared via a self-assembly process known as fluid forming. The process makes use of a high-spreading-tension fluid composed of volatile and nonvolatile components to propel particles across the air-water interface within a water bath. Continuous addition of the particle suspension builds a 2D particle film at the air-water interface. The spreading fluid compresses the film into a densely packed array against a submerged substrate. The assembled monolayer is deposited onto the substrate by removing the substrate from the bath. A dispersion containing a narrow size distribution, 10 microm alpha-alumina particles, light mineral oil, and 2-propanol was spread at the air-water interface and the alumina particles were assembled into densely packed arrays with an aerial packing fraction (APF) of 0.88. However, when mineral oil was replaced by Spurr's epoxy nonuniform films with low packing density resulted. It was found that replacing 2-propanol with a mixture of 2-propanol and 1-butanol with a volume ratio of 4:1 produced uniform, densely packed alumina/epoxy composite films. The role of the solvent mixture will be discussed.
authors.affiliation: Department of Materials Science and Engineering, Rutgers, The State University of New Jersey, 607 Taylor Road, Piscataway, New Jersey 08854, USA.
authors.forename: Bryan R
authors.initials: BR
authors.lastname: Jackson
authors.forename: Xiangyuan
authors.initials: X
authors.lastname: Liu
authors.forename: Elizabeth F
authors.initials: EF
authors.lastname: McCandlish
authors.forename: Richard E
authors.initials: RE
authors.lastname: Riman