title: One-pot terminal alkene homologation using a tandem olefin cross-metathesis/allylic carbonate reduction sequence.
abstract: A one-carbon homologation of terminal alkenes has been developed utilizing an olefin cross-metathesis followed by a palladium-mediated allylic carbonate reduction; various substrates were used to demonstrate the scope of the reaction, with yields ranging from 65 to 86%.
authors.affiliation: Department of Chemistry, North Carolina State University, Raleigh, NC, USA. Daniel_Comins@ncsu.edu
authors.forename: Daniel L
authors.initials: DL
authors.lastname: Comins
authors.forename: Jason M
authors.initials: JM
authors.lastname: Dinsmore
authors.forename: Lucas R
authors.initials: LR
authors.lastname: Marks
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002254:Carbonates / Q000737:chemistry*; D003432:Cross-Linking Reagents / Q000737:chemistry*; D046529:Microscopy, Electron, Transmission; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013057:Spectrum Analysis; D017186:Titrimetry
chemical_list: D000475:Alkenes; D002254:Carbonates; D003432:Cross-Linking Reagents