Versatile direct dehydrative approach for diaryliodonium(III) salts in fluoroalcohol media.
We have found that the use of fluoroalcohol media greatly enhanced the efficiency and scope of the direct dehydrative condensation of arenes and hypervalent iodine(III) compounds; the present clean method has a broad range of applicability as well as unique selectivity in the aromatic substrates, and is highly efficient even in polymer functionalization.
Dohi
Toshifumi
T
Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka 565-0871, Japan.
Ito
Motoki
M
Morimoto
Koji
K
Minamitsuji
Yutaka
Y
Takenaga
Naoko
N
Kita
Yasuyuki
Y
D000438:Alcohols / Q000737:chemistry*; D001555:Benzene Derivatives / Q000737:chemistry; D005461:Fluorine / Q000737:chemistry*; D007455:Iodine / Q000737:chemistry*; D015394:Molecular Structure; D009861:Onium Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011137:Polystyrenes / Q000737:chemistry; D012492:Salts / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry; D014867:Water / Q000737:chemistry*
D000438:Alcohols; D001555:Benzene Derivatives; D009861:Onium Compounds; D011137:Polystyrenes; D012492:Salts; D012821:Silanes; D014867:Water; D005461:Fluorine; C010219:mesitylene; D007455:Iodine