Rapid synthesis of medium-ring fused polycarbocyclic systems by rearrangement of carbenoid-derived oxonium ylides.
Tandem carbenoid generation, ylide formation and [2,3]-rearrangement is a powerful method for the construction of bicyclic and linearly fused tricyclic systems containing a seven-membered ring.
Clark
J Stephen
JS
WestCHEM, Department of Chemistry, Joseph Black Building, University of Glasgow, University Avenue, Glasgow, UKG12 8QQ. stephenc@chem.gla.ac.uk
Guérot
Carine
C
Wilson
Claire
C
Blake
Alexander J
AJ
D001688:Biological Products / Q000737:chemistry; D006838:Hydrocarbons / Q000737:chemistry; D047028:Macrocyclic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D010100:Oxygen / Q000737:chemistry*; D013997:Time Factors
D001688:Biological Products; D006838:Hydrocarbons; D047028:Macrocyclic Compounds; C030011:carbene; D008697:Methane; D010100:Oxygen