Anomalous thermal conduction in one dimension: a quantum calculation.
In this paper, we study the thermal conductivity of an anharmonically coupled chain of atoms. Numerical studies using classical dynamics have shown that the conductivity of a chain with nearest neighbor couplings diverges with chain length L as L(alpha); earlier studies found alpha approximately = 0.4 under a range of conditions, but a recent study on longer chains claims alpha = 1/3. Analytically, this problem has been studied by calculating the relaxation rate gamma(q) of the normal modes of vibration as a function of its wave vector q. Two theoretical studies of classical chains, one using the mode-coupling formulation and the other the Boltzmann equation method, led to gamma(q) proportional to q(5/3), which is consistent with alpha = 0.4. Here we study the problem for a quantum anharmonic chain with quartic anisotropy. We develop a low-temperature expansion for gamma(q) and find that, in the regime Dirac's constant omega(q) << k(B)T, gamma(q) is proportional to q(5/3)T2, where omega(q) is the frequency of the mode. In our analysis, the relaxation arises due to umklapp scattering processes. We further evaluate the thermal conductivity of the chain using the Kubo formula, which enables us to take into account the transport relaxation time through vertex corrections for the current-current correlator. This calculation also yields alpha = 0.4.
Santhosh
G
G
School of Physical Sciences, Jawaharlal Nehru University, New Delhi 110067, India.
Kumar
Deepak
D