Total synthesis of (+/-)-phomactin B2 via an intramolecular cyclohexadienone annulation of a chromium carbene complex.
Huang
Jie
J
Department of Chemistry, Michigan State University, East Lansing, MI 48824, USA.
Wu
Chunrui
C
Wulff
William D
WD
D002857:Chromium / Q000737:chemistry*; D003500:Cyclization; D003510:Cyclohexanes / Q000737:chemistry*; D053138:Cyclohexenes; D004852:Epoxy Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D006575:Heterocyclic Compounds, 3-Ring / Q000138:chemical synthesis* / Q000737:chemistry; D006838:Hydrocarbons / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D003510:Cyclohexanes; D053138:Cyclohexenes; D004852:Epoxy Compounds; D006575:Heterocyclic Compounds, 3-Ring; D006838:Hydrocarbons; D009942:Organometallic Compounds; C507608:cyclohexadienone; C525606:phomactin B2; D002857:Chromium; C030011:carbene; D008697:Methane