Superacid promoted reactions of N-acyliminium salts and evidence for the involvement of superelectrophiles.
Experimental and theoretical studies suggest the involvement of dicationic, superelectrophilic N-acyliminium ions in conversions catalyzed by superacids.
Zhang
Yiliang
Y
Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, Illinois 60115, USA.
DeSchepper
Daniel J
DJ
Gilbert
Thomas M
TM
Sai
Kiran Kumar S
KK
Klumpp
Douglas A
DA
D002412:Cations / Q000737:chemistry*; D004583:Electrons; D007097:Imines / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D019800:Phenol / Q000737:chemistry; D012492:Salts / Q000737:chemistry*; D013237:Stereoisomerism
D002412:Cations; D007097:Imines; D012492:Salts; D019800:Phenol