title: Neutral photodissociation of superexcited states of molecular iodine.
abstract: The formation of high-n Rydberg atoms from the neutral dissociation of superexcited states of I(2) formed by resonant two-photon excitation of molecular iodine using an ArF laser has been investigated. The high-n Rydberg atoms I* are formed by predissociation of the optically excited molecular Rydberg states I*(2)[R(B (2)Sigma(g) (+))] converging on the I(2) (+)(B (2)Sigma(g) (+)) state of the ion. Measurement of the kinetic energy release of the Rydberg I* fragments allowed the identification of the asymptotic channels as I*[R((3)P(J))]+I((2)P(32)), where the I*[R((3)P(J))] are Rydberg atoms converging on the I(+)((3)P(J)) states of the ion with J=2, 1, and 0. In the case of the I*[R((3)P(2))] fragments, the average Rydberg lifetime is observed to be 325+/-25 micros. Based on experiments on the variation of the Rydberg atom signal with the field ionizing strength, the distribution of Rydberg levels peaks at about 25-50 cm(-1) below the ionization limit.
authors.affiliation: Dipartimento di Chimica, Università La Sapienza, Piazzale A. Moro 5, Rome I-00185, Italy.
authors.forename: P
authors.initials: P
authors.lastname: O'Keeffe
authors.forename: D
authors.initials: D
authors.lastname: Stranges
authors.forename: P L
authors.initials: PL
authors.lastname: Houston