Helical chirality transmission through a p-phenylene fragment in a hexa-lambda5-phosphazene.
The helical chirality of a conformationally stable macrobicyclic tri-lambda5-phosphazene is propagated through to its C3 symmetry axis and causes a measurable stereoinduction in the formation process of a second macrobicyclic tri-lambda5-phosphazene unit connected to the former one by a p-phenylene linker.
Alajarín
Mateo
M
Departamento de Química Orgánica, Facultad de Química, Universidad de Murcia, Campus de Espinardo, 30100 Murcia, Spain. alajarin@um.es
López-Leonardo
Carmen
C
Berná
José
J