Uranyl stabilized Schiff base complex.
Uranyl Schiff base complex [(UO(2))(2)(Salpro)(OH)(Solvent)(2)] (1) in the presence of excess of ethylenediamine (EDA) does not undergo nucleophilic addition (hydrolysis) and substitution (transamination) reactions due to an extended chelation [2N, 3O + OH] by the flexible backbone.
Bharara
Mohan S
MS
Auburn University, Auburn, AL 36849, USA.
Tonks
Stephen A
SA
Gorden
Anne E V
AE
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D012545:Schiff Bases / Q000737:chemistry; D012997:Solvents; D013053:Spectrophotometry; D017974:Uranium Compounds / Q000737:chemistry*
D012545:Schiff Bases; D012997:Solvents; D017974:Uranium Compounds