title: Inhibition of humic substances mediated photooxygenation of furfuryl alcohol by 2,4,6-trimethylphenol. Evidence for reactivity of the phenol with humic triplet excited states.
abstract: To probe the reactivity of 2,4,6-trimethylphenol with humic triplet excited states, we investigated its influence on the humic substances-mediated photooxygenation offurfuryl alcohol. Elliott soil humic and fulvic acids were employed for these experiments. When added in the concentration range of 10(-4) - 10(-3) M, 2,4,6-trimethylphenol inhibited furfuryl alcohol photooxygenation to an extent depending on its concentration. The inhibiting effect decreased as the oxygen concentration was increased. By postulating that 2,4,6-trimethylphenol competes with oxygen for reaction with humic triplet excited states and with furfuryl alcohol for reaction with singlet oxygen, we obtained kinetic laws describing the consumption profiles of furfuryl alcohol and 2,4,6-trimethylphenol. Experimental rates of 2,4,6-trimethylphenol and furfuryl alcohol loss could be satisfactorily fitted with 1.09-1.16 for the ratio k2/k3, where k2 and k3 are the reaction rate constants of humic triplet excited states with oxygen and 2,4,6-trimethylphenol, respectively. These types of experiments could be extended to a variety of substrates to measure their reaction rate constants with humic triplet excited states.
authors.affiliation: Laboratoire de Photochimie Moléculaire et Macromoléculaire, UMR 6505 CNRS-Université Blaise Pascal, 63177 Aubière Cedex, France.
authors.forename: Sabrina
authors.initials: S
authors.lastname: Halladja
authors.forename: Alexandra
authors.initials: A
authors.lastname: Ter Halle
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Aguer
authors.forename: Abdelaziz
authors.initials: A
authors.lastname: Boulkamh
authors.forename: Claire
authors.initials: C
authors.lastname: Richard
mesh_terms: D003408:Cresols / Q000737:chemistry*; D005663:Furans / Q000737:chemistry*; D006812:Humic Substances; D007700:Kinetics; D010100:Oxygen / Q000737:chemistry*; D010777:Photochemistry; D026082:Singlet Oxygen / Q000737:chemistry; D012989:Soil Pollutants / Q000737:chemistry*
chemical_list: D003408:Cresols; D005663:Furans; D006812:Humic Substances; D012989:Soil Pollutants; D026082:Singlet Oxygen; C012986:furfuryl alcohol; C505148:2,4,6-trimethylphenol; D010100:Oxygen