A Hall effect angle detector for solid-state NMR.
We describe a new method for independent monitoring of the angle between the spinning axis and the magnetic field in solid-state NMR. A Hall effect magnetic flux sensor is fixed to the spinning housing, so that a change in the stator orientation leads to a change in the angle between the Hall plane and the static magnetic field. This leads to a change in the Hall voltage generated by the sensor when an electric current is passed through it. The Hall voltage may be measured externally by a precision voltmeter, allowing the spinning angle to be measured non-mechanically and independent of the NMR experiment. If the Hall sensor is mounted so that the magnetic field is approximately parallel to the Hall plane, the Hall voltage becomes highly sensitive to the stator orientation. The current angular accuracy is around 10 millidegrees. The precautions needed to achieve higher angular accuracy are described.
Mamone
Salvatore
S
School of Chemistry, University of Southampton, Southampton SO17 1BJ, UK.
Dorsch
André
A
Johannessen
Ole G
OG
Naik
Manoj V
MV
Madhu
P K
PK
Levitt
Malcolm H
MH