2,3,10,11-Tetrathiatricyclo[10.4.0.0(4,9)]hexadeca-4,6,8,12,14,16-hexaene (precession camera versus CCD).
The title compound, C(12)H(8)S(4), has crystallographic \overline{1} symmetry, the benzene groups thus being anti with respect to the plane of the four S atoms. The S-S and C-S bond lengths of the sulfur-carbon eight-membered ring were found to be similar to those in other structures containing such sulfur-carbon rings. There is evidence for pi-pi interactions between the aromatic rings of neighboring molecules, linking them into sheets.
Yearley
Eric J
EJ
Department of Chemistry, University of Toledo, Ohio 43606, USA.
Lippert
Ernest L
EL
Mitchell
Donald J
DJ
Pinkerton
A Alan
AA
D018360:Crystallography, X-Ray; D006575:Heterocyclic Compounds, 3-Ring / Q000737:chemistry*; D006586:Hexanes / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D011336:Probability
C525601:2,3,10,11-tetrathiatricyclo(10.4.0.0(4,9))hexadeca-4,6,8,12,14,16-hexaene; D006575:Heterocyclic Compounds, 3-Ring; D006586:Hexanes