Microwave-assisted preparations of dihydropyrroles from alkenone O-phenyl oximes.
Microwave irradiation of alkenone O-phenyl oximes produces iminyl radicals that ring close to yield dihydropyrrole derivatives; pyrroles and pyridines can be obtained from related precursors.
Portela-Cubillo
Fernando
F
University of St. Andrews, School of Chemistry, EaStChem, St. Andrews, Fife, UK KY16 9ST.
Scott
Jackie S
JS
Walton
John C
JC
D000473:Alkanes / Q000737:chemistry*; D005609:Free Radicals / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D008872:Microwaves; D015394:Molecular Structure; D010091:Oximes / Q000737:chemistry*; D011758:Pyrroles / Q000138:chemical synthesis* / Q000737:chemistry
D000473:Alkanes; D005609:Free Radicals; D010091:Oximes; D011758:Pyrroles; C013231:pyrroline; D006859:Hydrogen