title: Trifluoromethylation of salicyl aldimines.
abstract: A method for the nucleophilic trifluoromethylation of salicyl aldimines, which do not contain an activating group at the nitrogen atom, has been described. The reaction proceeds through the initial generation of intramolecular boron complex followed by interaction with Me3SiCF3 activated by sodium acetate.
authors.affiliation: N. D. Zelinsky Institute of Organic Chemistry, 119991 Moscow, Leninsky prosp. 47, Russian Federation. adil25@mail.ru
authors.forename: Alexander D
authors.initials: AD
authors.lastname: Dilman
authors.forename: Dmitry E
authors.initials: DE
authors.lastname: Arkhipov
authors.forename: Vitalij V
authors.initials: VV
authors.lastname: Levin
authors.forename: Pavel A
authors.initials: PA
authors.lastname: Belyakov
authors.forename: Alexander A
authors.initials: AA
authors.lastname: Korlyukov
authors.forename: Marina I
authors.initials: MI
authors.lastname: Struchkova
authors.forename: Vladimir A
authors.initials: VA
authors.lastname: Tartakovsky
mesh_terms: D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D054879:Halogenation; D006845:Hydrocarbons, Fluorinated / Q000737:chemistry*; D007097:Imines / Q000737:chemistry*; D008745:Methylation; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000588:Amines; D006845:Hydrocarbons, Fluorinated; D007097:Imines