Aminocarbonylation of aryl halides using a nickel phosphite catalytic system.
The nickel and phosphite catalytic system with sodium methoxide enables a very efficient aminocarbonylation reaction to be performed between aryl iodides or bromides and N,N-dimethylformamide (DMF). Phosphite ligand 1, which is very stable to air and moisture and, furthermore, inexpensive, afforded the highest reaction yield.
Ju
Jinhun
J
Department of Chemistry, Chonnam National University, 300 Yongbong-dong, Buk-gu, Gwangju 500-757, Republic of Korea.
Jeong
Miso
M
Moon
Jeongju
J
Jung
Hyun Min
HM
Lee
Sunwoo
S