Dual role of azide in the formation of a 3D coordination polymer containing bridging 5-pyrimidinecarboxylate.
A new 3D framework [Mn4(5-pmc)4(1,1-N3)4]n () composed of a rare MnII4 square as the repeating secondary building unit, representing the first coordination polymer of 5-pyrimidinecarboxylate (5-pmc) has been successfully synthesized and characterized by X-ray single crystal structure analysis.
Sengupta
Oindrila
O
Inorganic and Physical Chemistry Department, Indian Institute of Science, Bangalore, 560012, India.
Chakrabarty
Rajesh
R
Mukherjee
Partha Sarathi
PS