Changes in electronic couplings of mixed-valence systems due to through-space intramolecular interactions.
The strength of the electronic interactions between the two redox moieties in fullerene-substituted mixed-valence bis(ferrocenylethynyl)ethene derivatives is modulated by the through-space intramolecular electronic interactions of C(60) with the bridging conjugated system.
Figueira-Duarte
Teresa M
TM
Groupe de Chimie des Fullerènes et des Systèmes Conjugués, Laboratoire de Chimie de Coordination du CNRS (UPR 8241), 205 route de Narbonne, 31077, Toulouse Cedex 4, France.
Lloveras
Vega
V
Vidal-Gancedo
José
J
Gégout
Aline
A
Delavaux-Nicot
Béatrice
B
Welter
Richard
R
Veciana
Jaume
J
Rovira
Concepció
C
Nierengarten
Jean-François
JF