Anti-Markovnikov addition of both primary and secondary amines to terminal alkynes catalyzed by the TpRh(C2H4)2/PPh3 system.
Fukumoto
Yoshiya
Y
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan. fukumoto@chem.eng.osaka-u.ac.jp
Asai
Harumi
H
Shimizu
Masaki
M
Chatani
Naoto
N
D000480:Alkynes / Q000737:chemistry*; D000586:Amination; D000588:Amines / Q000737:chemistry*; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D007097:Imines / Q000138:chemical synthesis / Q000737:chemistry; D015394:Molecular Structure; D009025:Morpholines / Q000138:chemical synthesis / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*
D000480:Alkynes; D000588:Amines; D007097:Imines; D009025:Morpholines; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; C061896:triphenylphosphine; D012238:Rhodium