Organocatalyzed cyclizations of pi-allylpalladium complexes: a new method for the construction of five- and six-membered rings.
Synergic combination of organotransition metal catalysis and organocatalysis allows, for the first time, the Tsuji-Trost cyclization of aldehydes. A catalytic asymmetric variant of the reaction is also possible.
Bihelovic
Filip
F
Faculty of Chemistry, University of Belgrade, Studentski trg 16, P. O. Box. 158, 11000 Belgrade, Serbia.
Matovic
Radomir
R
Vulovic
Bojan
B
Saicic
Radomir N
RN
D000447:Aldehydes / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D020650:Combinatorial Chemistry Techniques; D003500:Cyclization; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D011759:Pyrrolidines / Q000737:chemistry*; D013237:Stereoisomerism
D000447:Aldehydes; D009942:Organometallic Compounds; D011759:Pyrrolidines; D010165:Palladium; C032519:pyrrolidine