Direct observation of a transient tyrosine radical competent for initiating turnover in a photochemical ribonucleotide reductase.
Reece
Steven Y
SY
Department of Chemistry, Massachusetts Institute of Technology, 77 Massachusetts Avenue, Cambridge, Massachusetts 02139-4307, USA.
Seyedsayamdost
Mohammad R
MR
Stubbe
JoAnne
J
Nocera
Daniel G
DG
D001665:Binding Sites; D004926:Escherichia coli / Q000201:enzymology; D005609:Free Radicals / Q000737:chemistry / Q000528:radiation effects; D008027:Light; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry / Q000528:radiation effects; D010777:Photochemistry; D017434:Protein Structure, Tertiary; D012211:Rhenium / Q000737:chemistry / Q000528:radiation effects; D012264:Ribonucleotide Reductases / Q000737:chemistry* / Q000528:radiation effects; D014443:Tyrosine / Q000737:chemistry* / Q000528:radiation effects
D005609:Free Radicals; D009942:Organometallic Compounds; D014443:Tyrosine; D012211:Rhenium; D012264:Ribonucleotide Reductases