title: Use of the electrochromic behaviour of lanthanide phthalocyanine films for nicotinamide adenine dinucleotide detection.
abstract: Electrochromic properties of spun films of bis[octakis(hexylthio)phthalocyaninato] dysprosium(III) were investigated for determining nicotinamide adenine dinucleotide hydride (NADH) in water solutions. A spin-coated film deposited on indium tin oxide electrode displays only one redox couple (at E1/2=0.78V). The films of [(C6H13S)8Pc]2Dy were modified chemically or electrochemically for the detection of reduced NADH in water solution. The modified film in the oxidized ([(C6H13S)8Pc]2Dy)+ form is believed to be reduced to its neutral form on interaction with NADH.
authors.affiliation: Institute of Inorganic Chemistry, Lavrentiev Prospect 3, Novosibirsk 630090, Russia. tbasova@mail.ru
authors.forename: T
authors.initials: T
authors.lastname: Basova
authors.forename: I
authors.initials: I
authors.lastname: Jushina
authors.forename: A G
authors.initials: AG
authors.lastname: Gürek
authors.forename: V
authors.initials: V
authors.lastname: Ahsen
authors.forename: A K
authors.initials: AK
authors.lastname: Ray
mesh_terms: D004563:Electrochemistry / Q000379:methods; D004566:Electrodes; D007211:Indoles / Q000737:chemistry*; D054833:Isoindoles; D028581:Lanthanoid Series Elements / Q000737:chemistry*; D008567:Membranes, Artificial; D009243:NAD / Q000032:analysis*; D010084:Oxidation-Reduction; D017971:Tin Compounds / Q000737:chemistry*
chemical_list: D007211:Indoles; D054833:Isoindoles; D028581:Lanthanoid Series Elements; D008567:Membranes, Artificial; D017971:Tin Compounds; D009243:NAD; C109984:indium tin oxide; C013647:phthalocyanine