title: Ion-neutral reactions in the ion source of a mixture of CO2/CH3OH, CO2/C2H5OH, and CO2/2-C3H7OH by packed capillary supercritical fluid chromatography-mass spectrometry (SFC-MS).
abstract: Ion neutral reactions in the gas phase in mixtures of ROH/CO(2), R = CH(3), C(2)H(5), and 2-C(3)H(7) were studied by supercritical fluid chromatography-mass spectrometry (SFC-MS). Three main reaction series were found for this system; ionization followed by alpha-cleavage, formation of clusters, and formation of protonated dialkyl ethers from the corresponding alcohol. The ion chemistries were similar for the three alcohols, but that of 2-propanol was somewhat more complex.
authors.affiliation: Department of Chemistry, Biotechnology, and Food Science, University of Life Sciences, As , Norway. Dag.ekeberg@umb.no
authors.forename: Dag
authors.initials: D
authors.lastname: Ekeberg
authors.forename: Anja M
authors.initials: AM
authors.lastname: Jablonska-Jentoft