title: Development of active and diffusive sampling methods for determination of 3-methoxybutyl acetate in workplace air.
abstract: Monitoring of the workplace concentration of 3-methoxybutyl acetate (MBA), which is used in printer's ink and thinner for screen-printing and as an organic solvent to dissolve various resins, is important for health reasons. An active and a diffusive sampling method, using a gas chromatograph equipped with a flame ionization detector, were developed for the determination of MBA in workplace air. For the active sampling method using an activated charcoal tube, the overall desorption efficiency was 101%, the overall recovery was 104%, and the recovery after 8 days of storage in a refrigerator was more than 90%. For the diffusive sampling method using the 3M 3500 organic vapor monitor, the MBA sampling rate was 19.89 cm(3) min(-1). The linear range was from 0.01 to 96.00 microg ml(-1), with a correlation coefficient of 0.999, and the detection limits of the active and diffusive samplers were 0.04 and 0.07 microg sample(-1), respectively. The geometric mean of stationary sampling and personal sampling in a screen-printing factory were 12.61 and 16.52 ppm, respectively, indicating that both methods can be used to measure MBA in workplace air.
authors.affiliation: Department of Public Health, Okayama University, Graduate School of Medicine, Dentistry and Pharmaceutical Sciences, 2-5-1, Shikata-cho, Okayama, 700-8558, Japan.
authors.forename: Akito
authors.initials: A
authors.lastname: Takeuchi
authors.forename: Tomoko
authors.initials: T
authors.lastname: Takigawa
authors.forename: Yaeko
authors.initials: Y
authors.lastname: Kawasumi
authors.forename: Tomojiro
authors.initials: T
authors.lastname: Yasugi
authors.forename: Yoko
authors.initials: Y
authors.lastname: Endo
authors.forename: Da-Hong
authors.initials: DH
authors.lastname: Wang
authors.forename: Jiro
authors.initials: J
authors.lastname: Takaki
authors.forename: Haruhiko
authors.initials: H
authors.lastname: Sakurai
authors.forename: Keiki
authors.initials: K
authors.lastname: Ogino
mesh_terms: D000085:Acetates / Q000032:analysis*; D000395:Air Pollutants, Occupational / Q000032:analysis*; D002849:Chromatography, Gas / Q000379:methods*; D004058:Diffusion
chemical_list: D000085:Acetates; D000395:Air Pollutants, Occupational; C527130:3-methoxybutyl acetate