title: New biodegradable polyhydroxybutyrate/layered silicate nanocomposites.
abstract: Poly(hydroxybutyrate) (PHB)/layered silicate nanocomposites were prepared via melt extrusion. The nanostructure, as observed from wide-angle X-ray diffraction and transmission electron microscopy, indicates intercalated hybrids. The extent of intercalation depends on the amount of silicate and the nature of organic modifier present in the layered silicate. The nanohybrids show significant improvement in thermal and mechanical properties of the matrix as compared to the neat polymer. The silicate particles act as a strong nucleating agent for the crystallization of PHB. The biodegradability of pure PHB and its nanocomposites was studied at two different temperatures under controlled conditions in compost media. The rate of biodegradation of PHB is enhanced dramatically in the nanohybrids. The change in biodegradation is rationalized in terms of the crystallization behavior of the nanohybrids as compared to that of the neat polymer.
authors.affiliation: Department of Material Science and Engineering, and Department of Food Science, Cornell University, Ithaca, NY 14853, USA.
authors.forename: Pralay
authors.initials: P
authors.lastname: Maiti
authors.forename: Carl A
authors.initials: CA
authors.lastname: Batt
authors.forename: Emmanuel P
authors.initials: EP
authors.lastname: Giannelis
mesh_terms: D000538:Aluminum Silicates / Q000737:chemistry; D001673:Biodegradation, Environmental; D002152:Calorimetry, Differential Scanning; D000077215:Clay; D003460:Crystallization; D006885:Hydroxybutyrates / Q000737:chemistry* / Q000378:metabolism*; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D008970:Molecular Weight; D053761:Nanocomposites / Q000737:chemistry* / Q000648:ultrastructure*; D011091:Polyesters / Q000737:chemistry*; D017640:Silicates / Q000737:chemistry*; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D000538:Aluminum Silicates; D006885:Hydroxybutyrates; D011091:Polyesters; D017640:Silicates; D000077215:Clay