title: Synthesis of substituted furoates from acrylates and aldehydes by Pd(OAc)(2)/HPMoV/CeCl(3)/O(2) system.
abstract: A new synthetic method of substituted furoates from acrylates and aldehydes was developed by Pd(OAc)2 combined with molybdovanadophosphoric acid and Lewis acid under atmospheric dioxygen. The reaction was found to proceed through the palladium-catalyzed acetalization of acrylates with methanol followed by the reaction of the resulting acetals with aldehydes.
authors.affiliation: Department of Chemistry and Material Engineering, Faculty of Chemistry, Materials and Bioengineering and High Technology Research Center, Kansai University, Suita, Osaka, Japan.
authors.forename: Ken-ichi
authors.initials: K
authors.lastname: Tamaso
authors.forename: Yuji
authors.initials: Y
authors.lastname: Hatamoto
authors.forename: Yasushi
authors.initials: Y
authors.lastname: Obora
authors.forename: Satoshi
authors.initials: S
authors.lastname: Sakaguchi
authors.forename: Yasutaka
authors.initials: Y
authors.lastname: Ishii
mesh_terms: D000085:Acetates / Q000737:chemistry*; D000179:Acrylates / Q000737:chemistry*; D000447:Aldehydes / Q000737:chemistry*; D002384:Catalysis; D002563:Cerium / Q000737:chemistry*; D020650:Combinatorial Chemistry Techniques; D005663:Furans / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D010756:Phosphoric Acids / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000085:Acetates; D000179:Acrylates; D000447:Aldehydes; D005663:Furans; D009942:Organometallic Compounds; D010756:Phosphoric Acids; C516071:palladium(II) acetate; D002563:Cerium; D008982:Molybdenum; D010100:Oxygen; C026690:cerous chloride