title: Spectroscopic evidence for a high-spin Br-Fe(IV)-oxo intermediate in the alpha-ketoglutarate-dependent halogenase CytC3 from Streptomyces.
authors.affiliation: Department of Biological Chemistry and Molecular Pharmacology, Harvard Medical School, Cambridge, MA 02115, USA.
authors.forename: Danica Galonić
authors.initials: DG
authors.lastname: Fujimori
authors.forename: Eric W
authors.initials: EW
authors.lastname: Barr
authors.forename: Megan L
authors.initials: ML
authors.lastname: Matthews
authors.forename: Gretchen M
authors.initials: GM
authors.lastname: Koch
authors.forename: J Ryan
authors.initials: JR
authors.lastname: Yonce
authors.forename: Christopher T
authors.initials: CT
authors.lastname: Walsh
authors.forename: J Martin
authors.initials: JM
authors.lastname: Bollinger
authors.forename: Carsten
authors.initials: C
authors.lastname: Krebs
authors.forename: Pamela J
authors.initials: PJ
authors.lastname: Riggs-Gelasco
mesh_terms: D001966:Bromine / Q000737:chemistry*; D002384:Catalysis; D003574:Cytochrome c Group / Q000737:chemistry*; D005290:Ferric Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D054879:Halogenation; D007656:Ketoglutaric Acids / Q000737:chemistry*; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D010088:Oxidoreductases / Q000737:chemistry*; D013057:Spectrum Analysis / Q000379:methods*; D013237:Stereoisomerism; D013302:Streptomyces / Q000201:enzymology*; D014965:X-Rays
chemical_list: D003574:Cytochrome c Group; D005290:Ferric Compounds; D007656:Ketoglutaric Acids; C017165:cytochrome c(3); D010088:Oxidoreductases; D001966:Bromine