Visible light-induced photopolymerization of an in situ macroporous sol-gel monolith.
A one-step, in situ, photopolymerization of a mixture of methacryloxypropyltrimethoxysilane in the presence of an acid catalyst, water, and toluene is accomplished in a 75 microm id polyimide-coated capillary using visible light (460 nm) for a 15 min irradiation time. The mixture is a two-component photosystem comprising Irgacure 784 photosensitizer and diphenyliodonium chloride photoinitiator. The visible photopolymerized sol-gel (vis-PSG) column shows RP chromatographic behavior. The analytical potential of these columns is demonstrated with the isocratic separation of small, neutral alkyl phenyl ketones. Operational parameters, such as mobile phase composition, field strength, and column temperature were varied to assess how they affect the separation performance of the monolith.
Dulay
Maria T
MT
Department of Chemistry, Stanford University, Stanford, CA 94305-5080, USA.
Choi
Han Nim
HN
Zare
Richard N
RN
D005782:Gels / Q000138:chemical synthesis / Q000737:chemistry; D007094:Imides / Q000737:chemistry; D007659:Ketones / Q000032:analysis; D008027:Light; D008689:Methacrylates / Q000138:chemical synthesis* / Q000737:chemistry / Q000528:radiation effects*; D015394:Molecular Structure; D010316:Particle Size; D044367:Phase Transition; D010777:Photochemistry; D016062:Porosity; D015203:Reproducibility of Results; D012680:Sensitivity and Specificity; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry / Q000528:radiation effects*; D012996:Solutions / Q000737:chemistry; D013056:Spectrophotometry, Ultraviolet / Q000295:instrumentation / Q000379:methods; D013499:Surface Properties; D013696:Temperature; D013997:Time Factors
D005782:Gels; D007094:Imides; D007659:Ketones; D008689:Methacrylates; D012821:Silanes; D012996:Solutions; C017492:methacryloxypropyltrimethoxysilane