Electrochemical behavior of an aminotrithioether ligand: copper(II)-mediated oxidative C-C bond formation.
A neutral aminotrithioether interacts with CuI, generating a coordination polymer in the solid state. Electrochemical studies indicate that the ligand is prone to oxidation by CuII, which results in a novel C-C bond formation reaction.
Huerta
Raúl
R
Instituto de Química and Facultad de Química, División de Estudios de Posgrado, Universidad Nacional Autónoma de México, Ciudad Universitaria, México D.F., 04510 Mexico.
Flores-Figueroa
Aarón
A
Ugalde-Saldívar
Víctor M
VM
Castillo
Ivan
I
D002244:Carbon / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004563:Electrochemistry; D004987:Ethers / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D010084:Oxidation-Reduction
D004987:Ethers; D008024:Ligands; D002244:Carbon