A novel tetrakis(pyrazolyl)borate ligand bearing triphenylphosphine oxide substituents.
A new tetrakis(pyrazolyl)borate ligand bearing triphenylphosphine oxide moieties appended to the 3-position of the pyrazolyl rings is reported and shown to display varied coordination chemistry from tridentate N(2)O coordination with thallium to hexadentate N(3)O(3) coordination with europium.
Kealey
Steven
S
Department of Chemistry, Imperial College London, South Kensington, London, UK SW7 2AZ.
Long
Nicholas J
NJ
White
Andrew J P
AJ
Gee
Antony D
AD
D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000737:chemistry*; D011720:Pyrazoles / Q000138:chemical synthesis* / Q000737:chemistry
D001896:Boron Compounds; D008024:Ligands; D009943:Organophosphorus Compounds; D011720:Pyrazoles; C063888:triphenylphosphine oxide