Use of Rhizopus oligosporus produced from food processing wastewater as a biosorbent for Cu(II) ions removal from the aqueous solutions.
Dried biomass of Rhizopus oligosporus produced from food processing wastewater was used as an adsorbent for copper ions in water. The adsorption process was carried out in a batch process and the effects of contact time (1-48 h), initial pH (2.0-6.0), initial metal ion concentration (20-100 mg L(-1)) and temperature (20-38 degrees C) on the adsorption were investigated. Experimental results showed that the maximum adsorption capacity was achieved at pH 5.0 and adsorbed Cu(II) ion concentration was increased with increasing initial metal concentration and contact time. The isothermal data could be described well by the Langmuir equations and monolayer capacity had a mean value of 79.37 mg g(-1). A pseudo-second order reaction model provided the best description of the data with a correlation coefficient 0.99 for different initial metal concentrations. Thermodynamic parameters indicated that biosorption of Cu(II) on R. oligosporus dried biomass was exothermic and spontaneous. To observe the copper pellets on the biosorbent surface after biosorption SEM was used and copper was characterized by EDX. The results of FTIR analyses indicated that amide I and hydroxyl groups of adsorbent played important role in binding Cu(II).
Ozsoy
H Duygu
HD
Department of Environmental Engineering, Engineering Faculty, Mersin University, 33360, Turkey. ozsoyhd@mersin.edu.tr
Kumbur
Halil
H
Saha
Basudeb
B
van Leeuwen
J Hans
JH
D000327:Adsorption; D001673:Biodegradation, Environmental; D003300:Copper / Q000302:isolation & purification*; D005525:Food-Processing Industry; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste; D007700:Kinetics; D008670:Metals; D008855:Microscopy, Electron, Scanning; D012233:Rhizopus / Q000378:metabolism* / Q000648:ultrastructure; D012996:Solutions; D017550:Spectroscopy, Fourier Transform Infrared; D013696:Temperature; D013816:Thermodynamics; D013997:Time Factors; D014865:Waste Disposal, Fluid
D007220:Industrial Waste; D008670:Metals; D012996:Solutions; D003300:Copper