Solubility of CO2, CH4, C2H6, C2H4, O2, and N2 in 1-hexyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide: comparison to other ionic liquids.
The solubilities of gases in ionic liquids are important in evaluating ionic liquids as solvents for reactions involving permanent gases, as gas storage media, and as solvents for gas separations. Gas solubilities are also important in developing methods to separate solutes from ionic liquid solutions. Here we describe our measurements of the solubilities of CO2, CH4, C2H 6, C2H 4, O2, and N2 in 1-hexyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide and compare these results to our previous investigations. In addition, focus is placed on efforts to tailor ionic liquids to enhance the solubilities of some gases, with particular emphasis on carbon dioxide.
Anderson
Jessica L
JL
Department of Chemical and Biomolecular Engineering, University of Notre Dame, Notre Dame, Indiana 46556, USA.
Dixon
Janeille K
JK
Brennecke
Joan F
JF
D002245:Carbon Dioxide / Q000737:chemistry*; D003198:Computer Simulation; D004980:Ethane / Q000737:chemistry*; D007094:Imides / Q000737:chemistry*; D052578:Ionic Liquids / Q000737:chemistry*; D008697:Methane / Q000737:chemistry*; D008956:Models, Chemical; D009584:Nitrogen / Q000737:chemistry*; D010100:Oxygen / Q000737:chemistry*; D011726:Pyridinium Compounds / Q000737:chemistry*; D012995:Solubility; D013499:Surface Properties
C522513:1-n-hexyl-3-methylpyridinium bis(trifluoromethylsulfonyl)imide; D007094:Imides; D052578:Ionic Liquids; D011726:Pyridinium Compounds; D002245:Carbon Dioxide; D004980:Ethane; D009584:Nitrogen; D008697:Methane; D010100:Oxygen