Oxidation of allylic alcohols to alpha,beta-unsaturated carbonyl compounds with aqueous hydrogen peroxide under organic solvent-free conditions.
Allylic alcohols are chemoselectively oxidized to alpha,beta-unsaturated carbonyl compounds in high yield with aqueous H(2)O(2) in the presence of Pt black catalyst under organic solvent-free conditions. The catalyst is easily recyclable and effective for at least 7 cycles.
Kon
Yoshihiro
Y
National Institute of Advanced Industrial Science and Technology, Tsukuba Central 5 Higashi 1-1-1, Tsukuba, Ibaraki, Japan.
Usui
Yoko
Y
Sato
Kazuhiko
K