Polymer - supported cobalt (II) catalysts for the oxidation of alkenes.
Polymer-supported heterogeneous catalysts in a form of complexes of 8-hydroxy- quinoline with cobalt acetate were synthesized. Conjugated polymers - polyaniline (PANI), poly-o-toluidine (POT), poly-o-anisidine (POA) - were used as supports. Oxidation reactions of aliphatic and aromatic hydrocarbons were carried out in the presence of molecular oxygen at atmospheric pressure and epoxides or ketones were obtained as the main products with high selectivity.
Błaz
Edyta
E
Department of Polymer Science and Technology, Krakow University of Technology, ul. Warszawska 24, 31-155 Krakow, Poland.
Pielichowski
Jan
J
D000475:Alkenes / Q000378:metabolism*; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry* / Q000494:pharmacology*; D008954:Models, Biological; D010084:Oxidation-Reduction; D011108:Polymers / Q000737:chemistry* / Q000494:pharmacology*
D000475:Alkenes; D011108:Polymers; D003035:Cobalt