title: Degradation of 2,4-dichlorophenol with a novel TiO2/Ti-Fe-graphite felt photoelectrocatalytic oxidation process.
abstract: Degradation of 2,4-dichlorophenol (2,4-DCP) was studied in a novel three-electrode photoelectrocatalytic (PEC) integrative oxidation process, and the factors influencing the degradation rate, such as applied current, flow speed of O2, pH, adscititious voltage and initial 2,4-DCP concentration were investigated and optimized. H2O2 was produced nearby cathode and Fe2+ continuously generated from Fe anode in solution when current and O2 were applied, so, main reactions, H2O2-assisted TiO2 PEC oxidation and E-Fenton reaction, occurred during degradation of 2,4-DCP in this integrative system. The degradation ratio of 2,4-DCP was 93% in this integrative oxidation process, while it was only 31% in E-Fenton process and 46% in H2O2-assisted TiO2 PEC process. So, it revealed that the degradation of 2,4-DCP was improved greatly by photoelectrical cooperation effect. By the investigation of pH, it showed that this integrative process could work well in a wide pH range from pH 3 to pH 9.
authors.affiliation: School of Municipal and Environmental Engineering, Harbin Institute of Technology, Harbin 150090, China. zhaobaoxiuhit@163.com
authors.forename: Bao-xiu
authors.initials: BX
authors.lastname: Zhao
authors.forename: Xiang-zhong
authors.initials: XZ
authors.lastname: Li
authors.forename: Peng
authors.initials: P
authors.lastname: Wang
mesh_terms: D002384:Catalysis; D002733:Chlorophenols / Q000737:chemistry* / Q000528:radiation effects*; D004563:Electrochemistry; D006108:Graphite / Q000737:chemistry*; D006861:Hydrogen Peroxide / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007501:Iron / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry; D010777:Photochemistry; D014025:Titanium / Q000737:chemistry*; D014466:Ultraviolet Rays; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000528:radiation effects; D018508:Water Purification / Q000379:methods
chemical_list: D002733:Chlorophenols; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; D006108:Graphite; D006861:Hydrogen Peroxide; D014025:Titanium; D007501:Iron; C004762:2,4-dichlorophenol; D010100:Oxygen