The O-acylation of ketone enolates by allyl 1H-imidazole-1-carboxylate mediated with boron trifluoride etherate: a convenient procedure for the synthesis of substituted allyl enol carbonates.
A convenient access to substituted allyl enol carbonates was established through the reaction of ketone enolates with the complex of allyl 1H-imidazole-1-carboxylates and boron trifluoride etherate.
Trost
Barry M
BM
Department of Chemistry, Stanford University, Stanford, CA 94305-5080, USA. bmtrost@stanford.edu
Xu
Jiayi
J
D000215:Acylation; D000498:Allyl Compounds / Q000737:chemistry*; D001880:Boranes / Q000737:chemistry*; D002254:Carbonates / Q000138:chemical synthesis*; D002264:Carboxylic Acids / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D008956:Models, Chemical; D013237:Stereoisomerism
D000498:Allyl Compounds; D001880:Boranes; D002254:Carbonates; D002264:Carboxylic Acids; D007093:Imidazoles; D007659:Ketones; C101707:boron trifluoride etherate