H14[NaP5W30O110] as a heterogeneous recyclable catalyst for the air oxidation of thiols under solvent free conditions.
The catalytic oxidation of thiols to the corresponding disulfides using Preyssler's catalyst H(14)[NaP(5)W(30)O(110)] has been studied. These highly selective oxidations gave good yields of the target disulfides.
Hekmatshoar
Rahim
R
Department of Chemistry, School of Science, Alzahra University, Vanak, Tehran, Iran. rhekmatus@yahoo.com
Sajadi
Sodeh
S
Heravi
Majid M
MM
Bamoharram
Fatemeh F
FF
D000148:Acids, Noncarboxylic / Q000737:chemistry*; D000388:Air; D002384:Catalysis; D004220:Disulfides / Q000737:chemistry; D010084:Oxidation-Reduction; D012997:Solvents / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*
D000148:Acids, Noncarboxylic; D004220:Disulfides; C524703:H14(NaP5W30O110); D012997:Solvents; D013438:Sulfhydryl Compounds; D017973:Tungsten Compounds