Advances in the metallotropic [1,3]-shift of alkynyl carbenoids.
Metal complexes of alkynyl carbenes undergo a [1,3]-bond shift known as a metallotropic shift. Since the discovery of the metallotropic [1,3]-shift of Rh-carbenoid, many more alkynyl carbene complexes with Ti, Cr, Mn, Mo, Ru, W, Re, Pt, and Au have been discovered to show metallotropic shift behavior. This article briefly summarizes the [1,3]-bond shift of alkynyl carbenes and their metal complexes.
Lee
Daesung
D
Department of Chemistry, University of Illinois at Chicago, 845 West Taylor St., Chicago, IL 60607, USA. dsunglee@uic.edu
Kim
Mansuk
M
D000480:Alkynes / Q000737:chemistry*; D002857:Chromium / Q000737:chemistry; D003300:Copper / Q000737:chemistry; D006838:Hydrocarbons / Q000737:chemistry; D019216:Metals, Heavy / Q000737:chemistry*; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D008982:Molybdenum / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D014414:Tungsten / Q000737:chemistry
D000480:Alkynes; D006838:Hydrocarbons; D019216:Metals, Heavy; D009942:Organometallic Compounds; D002857:Chromium; C030011:carbene; D003300:Copper; D008982:Molybdenum; D008697:Methane; D014414:Tungsten