Novel and efficient synthesis of N,N-dialkylamino-O-alkyl-2-(1-methyl-2-oxopropylidene)phosphorohydrazido oximes. Part 3.
A novel and efficient method has been developed for the synthesis of N,N-dialkylamino-O-alkyl-2-(1-methyl-2-oxopropylidene)phosphorohydrazido oximes 5. The reactions involve the condensation of diacetylmonoxime and N,N-dialkylamino-O- alkylphosphorohydrazides in the presence of activated silica and give the corresponding target oximes in excellent yields under mild conditions.
Kumar
Rajesh
R
Process Technology Development Division, Defence R and D Establishment, Jhansi Road, Gwalior-474002 (MP), India.
Gupta
Arvind K
AK
Kaushik
Mahabir P
MP
D006834:Hydrazines / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010091:Oximes / Q000138:chemical synthesis* / Q000737:chemistry; D010759:Phosphorus Isotopes
D006834:Hydrazines; D009943:Organophosphorus Compounds; D010091:Oximes; D010759:Phosphorus Isotopes