Degree of cure and fracture properties of experimental acid-resin modified composites under wet and dry conditions.
OBJECTIVE
Evaluate the effects of core structure and storage conditions on the mechanical properties of acid-resin modified composites and a control material by three point bending and conversion measurements 15min and 24h after curing.


METHODS
The monomers pyromellitic dimethacrylate (PMDM), biphenyldicarboxylic-acid dimethacrylate (BPDM), (isopropylidene-diphenoxy)bis(phthalic-acid) dimethacrylate (IPDM), oxydiphthalic-acid dimethacrylate (ODPDM), and Bis-GMA were mixed with triethyleneglycol dimethacrylate (TEGDMA) in a 40/60 molar ratio, and photo-activated. Composite bars (Barium-oxide-glass/resin=3/1 mass ratio, (2mmx2mmx25mm), n=5) were light-cured for 1min per side. Flexural strength (FS), elastic modulus (E), and work-of-fracture (WoF) were determined in three-point bending after 15min (stored dry); and after 24h under dry and wet storage conditions at 37 degrees C. Corresponding degrees of conversion (DC) were evaluated by Fourier transform infrared spectroscopy. Data was statistically analyzed (2-way analysis of variance, ANOVA, Holm-Sidak, p<0.05).


RESULTS
Post-curing significantly increased FS, E and DC in nearly all cases. WoF did not change, or even decreased with time. For all properties ANOVA found significant differences and interactions of time and material. Wet storage reduced the moduli and the other properties measured with the exception of FS and WoF of ODPDM; DC only decreased in BPDM and IPDM composites.


CONCLUSIONS
Differences in core structure resulted in significantly different physical properties of the composites studied with two phenyl rings connected by one ether linkage as in ODPDM having superior FS, WoF and DC especially after 24h under wet conditions. As expected, post-curing significantly contributed to the final mechanical properties of the composites, while wet storage generally reduced the mechanical properties.
López-Suevos
Francisco
F
American Dental Association Foundation, Paffenbarger Research Center, NIST, Gaithersburg, MD 20899, USA.
Dickens
Sabine H
SH
D000475:Alkenes / Q000737:chemistry; D001565:Benzoates / Q000737:chemistry; D017438:Bisphenol A-Glycidyl Methacrylate / Q000737:chemistry; D020770:Compomers / Q000737:chemistry*; D003188:Composite Resins / Q000737:chemistry; D003764:Dental Materials / Q000737:chemistry*; D003890:Desiccation; D005898:Glass / Q000737:chemistry; D006801:Humans; D008422:Materials Testing; D008689:Methacrylates / Q000737:chemistry; D010636:Phenols / Q000737:chemistry; D010795:Phthalic Acids / Q000737:chemistry; D018583:Pliability; D011092:Polyethylene Glycols / Q000737:chemistry; D011108:Polymers / Q000737:chemistry; D011109:Polymethacrylic Acids / Q000737:chemistry; D019279:Resin Cements / Q000737:chemistry; D013314:Stress, Mechanical; D013499:Surface Properties; D013997:Time Factors; D014867:Water / Q000737:chemistry*
D000475:Alkenes; D001565:Benzoates; D020770:Compomers; D003188:Composite Resins; D003764:Dental Materials; D008689:Methacrylates; D010636:Phenols; D010795:Phthalic Acids; D011108:Polymers; D011109:Polymethacrylic Acids; D019279:Resin Cements; C043042:pyromellitic acid dianhydride-2-hydroxyethyl methacrylate adduct; D014867:Water; C020946:triethylene glycol dimethacrylate; D011092:Polyethylene Glycols; D017438:Bisphenol A-Glycidyl Methacrylate; C005044:hydroxyethyl methacrylate; C032279:phthalic acid; C013658:propylene