Why is random close packing reproducible?
We link the thermodynamics of colloidal suspensions to the statistics of regular and random packings. Random close packing has defied a rigorous definition yet, in three dimensions, there is near universal agreement on the volume fraction at which it occurs. We conjecture that the common value of phi{rcp} approximately 0.64 arises from a divergence in the rate at which accessible states disappear. We relate this rate to the equation of state for a hard-sphere fluid on a metastable, noncrystalline branch.
Kamien
Randall D
RD
Department of Physics and Astronomy, University of Pennsylvania, Philadelphia, Pennsylvania 19104, USA.
Liu
Andrea J
AJ