title: Cu(I)-catalyzed intermolecular diamination of activated terminal olefins.
abstract: This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions.
authors.affiliation: Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
authors.forename: Baoguo
authors.initials: B
authors.lastname: Zhao
authors.forename: Weicheng
authors.initials: W
authors.lastname: Yuan
authors.forename: Haifeng
authors.initials: H
authors.lastname: Du
authors.forename: Yian
authors.initials: Y
authors.lastname: Shi
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D000586:Amination; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003959:Diamines / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
chemical_list: D000475:Alkenes; D003959:Diamines; D003300:Copper; C028419:cuprous chloride