title: New chiral diamino-bis(tert-thiophene): an effective ligand for Pd- and Zn-catalyzed asymmetric transformations.
abstract: Enantiomerically pure diamino-bis(tert-thiophene) proved to be a valuable and flexible chiral ligand for Pd- and Zn-catalyzed transformations, allowing for high levels of stereocontrol in asymmetric allylic alkylation (ee up to 99%) and hydrosilylations of prochiral carbonyls (ee up to 97%).
authors.affiliation: Dipartimento di Chimica G. Ciamician, Università di Bologna, via Selmi 2, 40126, Bologna, Italy. marco.bandini@unibo.it
authors.forename: Marco
authors.initials: M
authors.lastname: Bandini
authors.forename: Manuela
authors.initials: M
authors.lastname: Melucci
authors.forename: Fabio
authors.initials: F
authors.lastname: Piccinelli
authors.forename: Riccardo
authors.initials: R
authors.lastname: Sinisi
authors.forename: Simona
authors.initials: S
authors.lastname: Tommasi
authors.forename: Achille
authors.initials: A
authors.lastname: Umani-Ronchi