title: Conversion of a porous material based on a Mn(II)-TCNQF(4) honeycomb net to a molecular magnet upon desolvation.
abstract: Removal of methanol molecules from the interstices of a metal-organic framework based on a 2-D hexagonal Mn(II)-TCNQF(4) net results in stronger magnetic interactions and leads to a glassy magnetically ordered state; the magnetic behavior can be reversibly cycled upon solvation-desolvation of the material.
authors.affiliation: Department of Chemistry, Texas A&M University, College Station, TX 77842, USA.
authors.forename: Nazario
authors.initials: N
authors.lastname: Lopez
authors.forename: Hanhua
authors.initials: H
authors.lastname: Zhao
authors.forename: Andrey V
authors.initials: AV
authors.lastname: Prosvirin
authors.forename: Abdellatif
authors.initials: A
authors.lastname: Chouai
authors.forename: Michael
authors.initials: M
authors.lastname: Shatruk
authors.forename: Kim R
authors.initials: KR
authors.lastname: Dunbar
mesh_terms: D018360:Crystallography, X-Ray; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D012995:Solubility; D013696:Temperature
chemical_list: D009570:Nitriles; D009942:Organometallic Compounds; C013703:tetracyanoquinodimethane; D008345:Manganese