Molecular tectonics: polymorphism and enhancement of network dimensionality by a combination of primary and secondary hydrogen bond sites.
A dicationic tecton bearing four NH and two OH groups, as primary and secondary hydrogen bond donor sites, respectively, leads, in the presence of [M(CN)(4)](2-) anions, to the formation of polymorphic 2- and 3-D hydrogen-bonded networks.
Dechambenoit
Pierre
P
Laboratoire de Chimie de Coordination Organique, UMR CNRS 7140, Université Louis Pasteur, Institut Le Bel, 4 rue Blaise Pascal, F-67000, Strasbourg, France.
Ferlay
Sylvie
S
Hosseini
Mir Wais
MW
Kyritsakas
Nathalie
N