title: Field-induced metamagnetic transition in the Fe(III)-Mn(III) bimetallic chain built by a new cyanide-bearing Fe(III) precursor.
abstract: The use of a new precursor, mer-[Fe(mpzcq)(CN)3]- (1), produced a dimeric molecule, [Fe(mpzcq)(CN)3][Mn(salen)(H2O)] x H2O (2), and a one-dimensional zigzag chain, [Fe(mpzcq)(CN)3][Mn(salcy)] x MeOH x MeCN (3). Antiferromagnetic couplings are operating between magnetic centers through CN ligands, and a field-induced metamagnetic transition is observed in 3.
authors.affiliation: Department of Chemistry, Korea University, Seoul 136-713, Korea.
authors.forename: Jae Il
authors.initials: JI
authors.lastname: Kim
authors.forename: Houng Sik
authors.initials: HS
authors.lastname: Yoo
authors.forename: Eui Kwan
authors.initials: EK
authors.lastname: Koh
authors.forename: Chang Seop
authors.initials: CS
authors.lastname: Hong