Palladium-catalyzed 1,3-diol fragmentation: synthesis of omega-dienyl aldehydes.
2-(1'-Hydroxy-2'-propenyl)cycloalkan-1-ols undergo dehydrative C1-C2 bond cleavage and provide omega-dienyl aldehydes under the catalysis of Pd(0) and 9-phenyl-9-BBN.
Kimura
Masanari
M
Graduate School of Science and Technology, Nagasaki University, 1-14 Bunkyo-Machi, Nagasaki 852-8521, Japan.
Mori
Masahiko
M
Tamaru
Yoshinao
Y
D000447:Aldehydes / Q000138:chemical synthesis*; D001880:Boranes / Q000737:chemistry; D002384:Catalysis; D003516:Cycloparaffins / Q000737:chemistry; D006018:Glycols / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry; D011090:Polyenes / Q000138:chemical synthesis*
D000447:Aldehydes; D001880:Boranes; D003516:Cycloparaffins; D006018:Glycols; D011090:Polyenes; D010165:Palladium