Strongly coupled zinc phthalocyanine-tin porphyrin dyad performing ultra-fast single step charge separation over a 34 A distance.
A zinc(II) phthalocyanine-tin(IV) porphyrin dyad with a strong electronic coupling was synthesized and upon light excitation shown to exhibit ultra-fast, long-range electron transfer in a single step.
Fortage
Jérôme
J
Laboratoire de Synthèse Organique, UMR 6513 CNRS & FR CNRS 2465, Université de Nantes, Faculté des Sciences et des Techniques de Nantes, BP 92208, 2 rue de la Houssinière, 44322, Nantes Cedex 03, France.
Göransson
Erik
E
Blart
Errol
E
Becker
Hans-Christian
HC
Hammarström
Leif
L
Odobel
Fabrice
F
D004583:Electrons; D007211:Indoles / Q000737:chemistry*; D054833:Isoindoles; D008665:Metalloporphyrins / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D014001:Tin / Q000737:chemistry*; D017967:Zinc Compounds
D007211:Indoles; D054833:Isoindoles; D008665:Metalloporphyrins; D009942:Organometallic Compounds; D017967:Zinc Compounds; C052159:Zn(II)-phthalocyanine; D014001:Tin