Cu(I)-catalyzed intermolecular diamination of activated terminal olefins.
This paper describes a novel intermolecular diamination process with CuCl as catalyst and di-tert-butylthiadiaziridine 1,1-dioxide as nitrogen source. A variety of activated terminal olefins can be effectively diaminated in good yields under mild reaction conditions.
Zhao
Baoguo
B
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
Yuan
Weicheng
W
Du
Haifeng
H
Shi
Yian
Y
D000475:Alkenes / Q000737:chemistry*; D000586:Amination; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D003959:Diamines / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
D000475:Alkenes; D003959:Diamines; D003300:Copper; C028419:cuprous chloride