title: Cobalt-catalyzed intermolecular C-H amination with bromamine-T as nitrene source.
abstract: Cobalt, supported by porphyrin ligands, is capable of catalyzing intermolecular nitrene insertion of sp(3) C-H bonds with bromamine-T as the nitrene source, forming the desired tosyl-protected amines with NaBr as the by-product.
authors.affiliation: Department of Chemistry, University of South Florida, Tampa, FL 33620-5250, USA.
authors.forename: Jeremiah D
authors.initials: JD
authors.lastname: Harden
authors.forename: Joshua V
authors.initials: JV
authors.lastname: Ruppel
authors.forename: Guang-Yao
authors.initials: GY
authors.lastname: Gao
authors.forename: X Peter
authors.initials: XP
authors.lastname: Zhang
mesh_terms: D000586:Amination; D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D020650:Combinatorial Chemistry Techniques; D007097:Imines / Q000737:chemistry*; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D013237:Stereoisomerism; D013449:Sulfonamides / Q000737:chemistry*
chemical_list: D000588:Amines; D007097:Imines; D008024:Ligands; D009942:Organometallic Compounds; D011166:Porphyrins; D013449:Sulfonamides; C017621:phenylnitrene; D003035:Cobalt; C048239:bromamine T