title: Asymmetric total synthesis of ent-sandaracopimaradiene, a biosynthetic intermediate of oryzalexins.
abstract: An asymmetric total synthesis of ent-sandaracopimaradiene, a biosynthetic intermediate of oryzalexins, via B-alkyl Suzuki-Miyaura coupling and Lewis acid-mediated B-ring formation as key steps was achieved.
authors.affiliation: Department of Fermentation Science, Faculty of Applied Biological Science, Tokyo University of Agriculture, Japan. ayaji@nodai.ac.jp
authors.forename: Arata
authors.initials: A
authors.lastname: Yajima
authors.forename: Ayumi
authors.initials: A
authors.lastname: Yamaguchi
authors.forename: Tomoo
authors.initials: T
authors.lastname: Nukada
authors.forename: Goro
authors.initials: G
authors.lastname: Yabuta
mesh_terms: D004224:Diterpenes / Q000138:chemical synthesis*; D012717:Sesquiterpenes; D013237:Stereoisomerism; D013729:Terpenes / Q000138:chemical synthesis*; D000094162:Phytoalexins
chemical_list: D004224:Diterpenes; D012717:Sesquiterpenes; D013729:Terpenes; C526354:ent-sandaracopimaradiene; D000094162:Phytoalexins