Asymmetric hydroamination of non-activated carbon-carbon multiple bonds.
The catalysed enantioselective formation of carbon-nitrogen bonds by the hydroamination reaction is reviewed. All examples deal with substrates containing non-activated carbon-carbon multiple bonds which are transformed either via intramolecular or intermolecular reactions. Structurally different complexes already provided nitrogen containing compounds/heterocycles with high enantioselectivities.
Aillaud
Isabelle
I
Laboratoire de Catalyse Moléculaire, ICMMO, UMR CNRS 8182, Université Paris Sud 11, Bat 420, 91405 Orsay Cedex, France.
Collin
Jacqueline
J
Hannedouche
Jérôme
J
Schulz
Emmanuelle
E
D000586:Amination; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D008670:Metals / Q000737:chemistry*; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D008670:Metals; D009942:Organometallic Compounds; D002244:Carbon; D009584:Nitrogen