title: Synthetic studies towards the ent-labdane diterpenoids: rearrangement of ent-halimanes.
abstract: For the first time ent-labdanes have been synthetised starting from ent-halimic acid, following a route that is the reverse of the biosynthetic one leading to the former compounds.
authors.affiliation: Departamento de Química Orgánica, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008 Salamanca, Spain. ismarcos@usal.es
authors.forename: Isidro S
authors.initials: IS
authors.lastname: Marcos
authors.forename: María J
authors.initials: MJ
authors.lastname: Sexmero
authors.forename: Felix A
authors.initials: FA
authors.lastname: Hernández
authors.forename: Marta
authors.initials: M
authors.lastname: Corrales
authors.forename: Pilar
authors.initials: P
authors.lastname: Basabe
authors.forename: David
authors.initials: D
authors.lastname: Díez
authors.forename: Julio G
authors.initials: JG
authors.lastname: Urones
mesh_terms: D004224:Diterpenes / Q000138:chemical synthesis* / Q000737:chemistry*; D006027:Glycosides / Q000138:chemical synthesis / Q000737:chemistry
chemical_list: D004224:Diterpenes; D006027:Glycosides; C530795:ent-halimic acid; C495874:ent-labdane diglycoside