Synthesis of cyclopropanes via organoiron methodology: preparation of rac-dysibetaine CPa.
The cyclopropane containing betaine, rac-dysibetaine CPa, was prepared from (1-methoxycarbonylpentadienyl)-Fe(CO)2PPh3+ by nucleophilic addition of nitromethane anion followed by oxidatively induced reductive elimination.
Siddiquee
Tasneem A
TA
Department of Chemistry, Marquette University, P.O. Box 1881, Milwaukee, Wisconsin 53201-1881, USA.
Lukesh
Julie M
JM
Lindeman
Sergey
S
Donaldson
William A
WA
D001622:Betaine / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry; D018360:Crystallography, X-Ray; D003521:Cyclopropanes / Q000138:chemical synthesis* / Q000737:chemistry; D005290:Ferric Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods / Q000592:standards; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D012015:Reference Standards; D013237:Stereoisomerism
D003521:Cyclopropanes; D005290:Ferric Compounds; D009942:Organometallic Compounds; C526564:rac-dysibetaine CPa; D001622:Betaine