title: A versatile electronic hole in one-electron oxidized NiIIbis-salicylidene phenylenediamine complexes.
abstract: The nickel complexes 1(+)-3(+) exhibit a delocalized radical character, the extent of which depends on the electronic properties of the phenolate para-substituent.
authors.affiliation: Département de Chimie Moléculaire - Chimie Inorganique Redox Biomimétique (CIRE) - UMR CNRS 5250, Université J. Fourier, B. P. 53, 38041 Grenoble cedex 9, France.
authors.forename: Olaf
authors.initials: O
authors.lastname: Rotthaus
authors.forename: Olivier
authors.initials: O
authors.lastname: Jarjayes
authors.forename: Carlos
authors.initials: C
authors.lastname: Perez Del Valle
authors.forename: Christian
authors.initials: C
authors.lastname: Philouze
authors.forename: Fabrice
authors.initials: F
authors.lastname: Thomas
mesh_terms: D004583:Electrons; D008958:Models, Molecular; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D012459:Salicylates / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D012459:Salicylates; C090416:salophen; D009532:Nickel