Mercury(II) triflate-catalyzed cycloisomerization of allenynes to allenenes.
Cycloisomerizations of allenynes to allenenes have been studied in the presence of catalytic amounts of [Hg(OTf)2] in acetonitrile. The catalytic system is quite effective for terminal 1,6-allenynes: allenenes were obtained in reasonable to high yields. However, treatment of allenynes with disubstituents at the allenic terminal carbon yielded a triene and/or allenene as a major product(s) depending upon the substituents.
Sim
So Hee
SH
Intelligent Textile System Research Center, Department of Chemistry, College of Natural Sciences, Seoul National University, Seoul 151-747, Korea.
Lee
Sang Ick
SI
Seo
Junhyeok
J
Chung
Young Keun
YK
D000466:Alkadienes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D003500:Cyclization; D017669:Mercury Compounds / Q000737:chemistry*; D008698:Mesylates / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D013237:Stereoisomerism
D000466:Alkadienes; D000480:Alkynes; D017669:Mercury Compounds; D008698:Mesylates; C510262:mercuric triflate