title: A highly efficient non-heme manganese complex in oxygenation reactions.
abstract: A non-heme manganese(II) complex shows a high catalytic activity in the epoxidation of olefins by iodosyl benzene and in the oxidation of olefins, alcohols and alkanes by peracetic acid; a mechanism involving metal-based oxidants is proposed for the oxidation reactions.
authors.affiliation: Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womans University, Seoul, Korea.
authors.forename: Kasi
authors.initials: K
authors.lastname: Nehru
authors.forename: Soo Jeong
authors.initials: SJ
authors.lastname: Kim
authors.forename: In Young
authors.initials: IY
authors.lastname: Kim
authors.forename: Mi Sook
authors.initials: MS
authors.lastname: Seo
authors.forename: Youngmee
authors.initials: Y
authors.lastname: Kim
authors.forename: Sung-Jin
authors.initials: SJ
authors.lastname: Kim
authors.forename: Jinheung
authors.initials: J
authors.lastname: Kim
authors.forename: Wonwoo
authors.initials: W
authors.lastname: Nam
mesh_terms: D000438:Alcohols / Q000737:chemistry; D000473:Alkanes / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry; D002384:Catalysis; D007462:Iodobenzenes / Q000737:chemistry; D007659:Ketones / Q000138:chemical synthesis / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010463:Peracetic Acid / Q000737:chemistry
chemical_list: D000438:Alcohols; D000473:Alkanes; D000475:Alkenes; D007462:Iodobenzenes; D007659:Ketones; D009942:Organometallic Compounds; D008345:Manganese; D010463:Peracetic Acid; D010100:Oxygen