title: Prediction of frozen food properties during freezing using product composition.
abstract: Frozen water fraction (FWF), as a function of temperature, is an important parameter for use in the design of food freezing processes. An FWF-prediction model, based on concentrations and molecular weights of specific product components, has been developed. Published food composition data were used to determine the identity and composition of key components. The model proposed in this investigation had been verified using published experimental FWF data and initial freezing temperature data, and by comparison to outputs from previously published models. It was found that specific food components with significant influence on freezing temperature depression of food products included low molecular weight water-soluble compounds with molality of 50 micromol per 100 g food or higher. Based on an analysis of 200 high-moisture food products, nearly 45% of the experimental initial freezing temperature data were within an absolute difference (AD) of +/- 0.15 degrees C and standard error (SE) of +/- 0.65 degrees C when compared to values predicted by the proposed model. The predicted relationship between temperature and FWF for all analyzed food products provided close agreements with experimental data (+/- 0.06 SE). The proposed model provided similar prediction capability for high- and intermediate-moisture food products. In addition, the proposed model provided statistically better prediction of initial freezing temperature and FWF than previous published models.
authors.affiliation: Dept. of Food Science and Technology, Food Engineering Major, Faculty of Agro-Industry, Kasetsart Univ., 50 Paholyothin Rd., Jatujak, Bangkok 10900, Thailand.
authors.forename: W
authors.initials: W
authors.lastname: Boonsupthip
authors.forename: D R
authors.initials: DR
authors.lastname: Heldman
mesh_terms: D005504:Food Analysis; D005519:Food Preservation / Q000379:methods*; D005615:Freezing; D008433:Mathematics; D008956:Models, Chemical; D008970:Molecular Weight; D009994:Osmolar Concentration; D011237:Predictive Value of Tests; D013329:Structure-Activity Relationship; D013997:Time Factors; D044366:Transition Temperature; D014867:Water / Q000737:chemistry*
chemical_list: D014867:Water