The mechanism of TBD-catalyzed ring-opening polymerization of cyclic esters.
Triazabicyclodecene (TBD) has recently been shown to be an effective organocatalyst for the ring-opening polymerization (ROP) of cyclic esters. Using DFT methods, we have studied possible mechanisms of this reaction. Our studies explain not only the narrow polydispersity index (PDI) observed in the ROP of six-membered ring lactones, but also the surprising failure of the ROP for the more reactive butyrolactone.
Simón
Luis
L
Unilever Centre for Molecular Science Informatics, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge CB2 1EW, United Kingdom.
Goodman
Jonathan M
JM
D000438:Alcohols / Q000138:chemical synthesis / Q000737:chemistry; D001372:Aza Compounds / Q000737:chemistry*; D053961:Azabicyclo Compounds / Q000737:chemistry*; D002384:Catalysis; D006574:Heterocyclic Compounds, 2-Ring / Q000737:chemistry*; D007783:Lactones / Q000737:chemistry*; D015394:Molecular Structure
D000438:Alcohols; D001372:Aza Compounds; D053961:Azabicyclo Compounds; D006574:Heterocyclic Compounds, 2-Ring; D007783:Lactones; C526482:triazabicyclodecene