title: Palladium-catalyzed 1,3-diol fragmentation: synthesis of omega-dienyl aldehydes.
abstract: 2-(1'-Hydroxy-2'-propenyl)cycloalkan-1-ols undergo dehydrative C1-C2 bond cleavage and provide omega-dienyl aldehydes under the catalysis of Pd(0) and 9-phenyl-9-BBN.
authors.affiliation: Graduate School of Science and Technology, Nagasaki University, 1-14 Bunkyo-Machi, Nagasaki 852-8521, Japan.
authors.forename: Masanari
authors.initials: M
authors.lastname: Kimura
authors.forename: Masahiko
authors.initials: M
authors.lastname: Mori
authors.forename: Yoshinao
authors.initials: Y
authors.lastname: Tamaru
mesh_terms: D000447:Aldehydes / Q000138:chemical synthesis*; D001880:Boranes / Q000737:chemistry; D002384:Catalysis; D003516:Cycloparaffins / Q000737:chemistry; D006018:Glycols / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry; D011090:Polyenes / Q000138:chemical synthesis*
chemical_list: D000447:Aldehydes; D001880:Boranes; D003516:Cycloparaffins; D006018:Glycols; D011090:Polyenes; D010165:Palladium