Conversion of a porous material based on a Mn(II)-TCNQF(4) honeycomb net to a molecular magnet upon desolvation.
Removal of methanol molecules from the interstices of a metal-organic framework based on a 2-D hexagonal Mn(II)-TCNQF(4) net results in stronger magnetic interactions and leads to a glassy magnetically ordered state; the magnetic behavior can be reversibly cycled upon solvation-desolvation of the material.
Lopez
Nazario
N
Department of Chemistry, Texas A&M University, College Station, TX 77842, USA.
Zhao
Hanhua
H
Prosvirin
Andrey V
AV
Chouai
Abdellatif
A
Shatruk
Michael
M
Dunbar
Kim R
KR
D018360:Crystallography, X-Ray; D008280:Magnetics; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009570:Nitriles / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D012995:Solubility; D013696:Temperature
D009570:Nitriles; D009942:Organometallic Compounds; C013703:tetracyanoquinodimethane; D008345:Manganese