Biosynthesis of polyacetylenes in Ambrosia maritima hairy roots.
Thiophene A and thiophene A diol are the major polyacetylenes isolated from the hairy roots of Ambrosia maritima (Asteraceae) cultured under continuous light irradiation. The biosynthesis of thiophene A was studied using [1-(13)C]-, [2-(13)C]-, [1,2-(13)C]-acetates. The biosynthesis of thiarubrine A, produced by hairy roots cultured in the dark, was studied using [1,2-(13)C]-acetates and [18-(13)C]-linoleic acid. Our results suggest a catabolic pathway for polyacetylenes biosynthesis from linoleic acid in hairy roots of Ambrosia maritima.
AbouZid
Sameh
S
Department of Pharmacognosy, Faculty of Pharmacy, Beni-Sueif University, Beni-Sueif, Egypt. wssmd3000@yahoo.com
Orihara
Yutaka
Y
D031164:Ambrosia / Q000378:metabolism*; D019787:Linoleic Acid / Q000378:metabolism; D018517:Plant Roots / Q000378:metabolism*; D053279:Polyynes / Q000378:metabolism*
D053279:Polyynes; D019787:Linoleic Acid