Sila morita-Baylis-Hillman reaction of cyclopropenes.
The first example of sila-Morita-Bayis-Hillman reaction between 1-silylcyclopropenes and carbonyl compounds has been demonstrated. This novel phosphine-catalyzed transformation features a 1,3-Brook rearrangement/elimination cascade and provides convenient access to a variety of 1-(silyloxymethyl)cyclopropenes, which are not easily available via traditional methods.
Chuprakov
Stepan
S
Department of Chemistry, University of Illinois at Chicago, Chicago, Illinois 60607, USA.
Malyshev
Denis A
DA
Trofimov
Alexander
A
Gevorgyan
Vladimir
V