Porous metal-organic frameworks based on metal-organic polyhedra with nanosized cavities as supramolecular building blocks: two-fold interpenetrating primitive cubic networks of [Cu6L8]12+ nanocages.
Discrete metal-organic polyhedra (MOP) with nanosized cavities and/or clusters of MOP could be prepared when C3-symmetric facial ligands and a potential hexatopic Cu(II) ion are combined in the presence of perchlorate as a weak linker, while similar reaction conditions in the presence of a nitrate linker led to extended metal-organic frameworks made of MOP as supramolecular building blocks.
Park
Jaejoon
J
Department of Chemistry and Applied Chemistry, College of Science and Technology, Hanyang University, Ansan, Kyunggi-Do 426-791, Korea.
Hong
Seunghee
S
Moon
Dohyun
D
Park
Mira
M
Lee
Kyungjin
K
Kang
Sangmi
S
Zou
Yang
Y
John
Rohith P
RP
Kim
Ghyung Hwa
GH
Lah
Myoung Soo
MS