A versatile electronic hole in one-electron oxidized NiIIbis-salicylidene phenylenediamine complexes.
The nickel complexes 1(+)-3(+) exhibit a delocalized radical character, the extent of which depends on the electronic properties of the phenolate para-substituent.
Rotthaus
Olaf
O
Département de Chimie Moléculaire - Chimie Inorganique Redox Biomimétique (CIRE) - UMR CNRS 5250, Université J. Fourier, B. P. 53, 38041 Grenoble cedex 9, France.
Jarjayes
Olivier
O
Perez Del Valle
Carlos
C
Philouze
Christian
C
Thomas
Fabrice
F
D004583:Electrons; D008958:Models, Molecular; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D012459:Salicylates / Q000737:chemistry*
D009942:Organometallic Compounds; D012459:Salicylates; C090416:salophen; D009532:Nickel