title: First total syntheses and spectral data corrections of 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin.
abstract: Concise and efficient total syntheses of 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin were accomplished for the first time. The three-component linchpin coupling and intramolecular acylation reactions were key steps, in which we found the spectral data of 11-alpha-methoxycurvularin and 11-beta-methoxycurvularin, reported in the literature, were reversed with each other.
authors.affiliation: Department of Chemistry, State Key Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou, 730000, People's Republic of China.
authors.forename: Qiren
authors.initials: Q
authors.lastname: Liang
authors.forename: Yongquan
authors.initials: Y
authors.lastname: Sun
authors.forename: Binxun
authors.initials: B
authors.lastname: Yu
authors.forename: Xuegong
authors.initials: X
authors.lastname: She
authors.forename: Xinfu
authors.initials: X
authors.lastname: Pan
mesh_terms: D015394:Molecular Structure; D013237:Stereoisomerism; D015025:Zearalenone / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry
chemical_list: C526568:11-alpha-methoxycurvularin; D015025:Zearalenone; C013455:curvularin