Stoichiometry and structure of uranylVI hydroxo dimer and trimer complexes in aqueous solution.
We studied the structure and stoichiometry of aqueous uranylVI hydroxo dimers and trimers by spectroscopic (EXAFS, FTIR, UV-vis) and quantum chemical (DFT) methods. FTIR and UV-vis spectroscopy were used for the speciation of uranyl complexes in aqueous solution. DFT calculations show that (UO2)2(OH)22+ has two bridging hydroxo groups with a U-U distance of 3.875 A. This result is in good agreement with EXAFS, where a U-U distance of 3.88 A was found. For the hydroxo trimer complex, DFT calculations show that the species (UO2)3(O)(OH)3+ with oxo bridging in the center is energetically favored in comparison to its stoichiometric equivalent (UO2)3(OH)5+. This is again in line with the EXAFS result, where a shorter U-U distance of 3.81-3.82 A and evidence for oxo bridging in the center were found. Several stable intermediates which lie several tens of kJ/mol above that of (UO2)3(O)(OH)3+ were identified, and their structures, energies, and intramolecular proton-transfer reaction are discussed.
Tsushima
Satoru
S
Institut für Radiochemie, Forschungszentrum Dresden-Rossendorf (FZD), Bautzner Landstrasse 128, D-01328, Dresden, Germany. S.Tsushima@fzd.de
Rossberg
André
A
Ikeda
Atsushi
A
Müller
Katharina
K
Scheinost
Andreas C
AC