title: Catalyst deterioration over the lifetime of small utility engines.
abstract: In this paper, the deterioration of catalysts in small, four-stroke, spark-ignition engines is described. The laboratory testing performed followed a proven test method that mimics the lifetime of a small air-cooled utility engine operating under normal field conditions. The engines used were single-cylinder, 6.5-hp, side-valve engines. These engines have a nominal 125-hr lifetime. The effectiveness of the catalysts was determined by testing exhaust emissions before and after the catalyst to determine the catalyst's efficiency. This was done several times during the lifetime of the engines to determine the deterioration in the performance of the catalysts at lowering pollutant emissions. Additional testing was performed on the catalysts to determine wear patterns, contamination, and recoverable activity. The results indicate that considerable catalyst deterioration is occurring over the lifetime of the engine. The results reveal that soot buildup, poisons, and active surface loss appear to be the contributing factors to the deterioration. These results were determined after analyzing the exhaust emissions data, scanning electron microscope results analysis, and the impact of regeneration attempts. An ANOVA statistical analysis was performed, and it was determined that the emissions are also impacted, to some degree, by time and the engine itself.
authors.affiliation: Center for Alternative Fuels, Mechanical Engineering Department, University of Wisconsin-Milwaukee, Milwaukee, WI 53211, USA.
authors.forename: Nicholas J
authors.initials: NJ
authors.lastname: Doll
authors.forename: John R
authors.initials: JR
authors.lastname: Reisel
mesh_terms: D000393:Air Pollutants / Q000032:analysis*; D006838:Hydrocarbons / Q000032:analysis; D009589:Nitrogen Oxides / Q000032:analysis; D053260:Soot / Q000032:analysis*; D001335:Vehicle Emissions / Q000032:analysis*
chemical_list: D000393:Air Pollutants; D006838:Hydrocarbons; D009589:Nitrogen Oxides; D053260:Soot; D001335:Vehicle Emissions