A highly efficient non-heme manganese complex in oxygenation reactions.
A non-heme manganese(II) complex shows a high catalytic activity in the epoxidation of olefins by iodosyl benzene and in the oxidation of olefins, alcohols and alkanes by peracetic acid; a mechanism involving metal-based oxidants is proposed for the oxidation reactions.
Nehru
Kasi
K
Department of Chemistry, Division of Nano Sciences, and Center for Biomimetic Systems, Ewha Womans University, Seoul, Korea.
Kim
Soo Jeong
SJ
Kim
In Young
IY
Seo
Mi Sook
MS
Kim
Youngmee
Y
Kim
Sung-Jin
SJ
Kim
Jinheung
J
Nam
Wonwoo
W
D000438:Alcohols / Q000737:chemistry; D000473:Alkanes / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry; D002384:Catalysis; D007462:Iodobenzenes / Q000737:chemistry; D007659:Ketones / Q000138:chemical synthesis / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010463:Peracetic Acid / Q000737:chemistry
D000438:Alcohols; D000473:Alkanes; D000475:Alkenes; D007462:Iodobenzenes; D007659:Ketones; D009942:Organometallic Compounds; D008345:Manganese; D010463:Peracetic Acid; D010100:Oxygen