title: Hydrothermal method of preparation of actinide(IV) phosphate hydrogenphosphate hydrates and study of their conversion into actinide(IV) phosphate diphosphate solid solutions.
abstract: Several compositions of Th2-x/2AnIVx/2(PO4)2(HPO4).H2O (An=U, Np, Pu) were prepared through hydrothermal precipitation from a mixture of nitric solutions containing cations and concentrated phosphoric acid. All the samples were fully characterized by X-ray diffraction, UV-vis, and infrared spectroscopies to check for the existence of thorium-actinide(IV) phosphate hydrogenphosphate hydrates solid solutions. Such compounds were obtained as single phases, up to x=4 for uranium, x=2 for neptunium, and x<4 for plutonium, the cations being fully maintained in the tetravalent oxidation state. In a second step, the samples obtained after heating crystallized precursors at high temperature (1100 degrees C) were characterized. Single-phase thorium-actinide(IV) phosphate-diphosphate solid solutions were obtained up to x=0.8 for Np(IV) and x=1.6 for Pu(IV). For higher substitution rates, polyphase systems composed by beta-TAnPD, An2O(PO4)2, and/or alpha-AnP2O7 were formed. Finally, this hydrothermal route of preparation was applied successfully to the synthesis of an original phosphate-based compound incorporating simultaneously tetravalent uranium, neptunium and plutonium.
authors.affiliation: Groupe de Radiochimie, Institut de Physique Nucléaire d'Orsay, Bât. 100, Université Paris-Sud-11, 91406 Orsay, France. dacheux@ipno.in2p3.fr
authors.forename: N
authors.initials: N
authors.lastname: Dacheux
authors.forename: S
authors.initials: S
authors.lastname: Grandjean
authors.forename: J
authors.initials: J
authors.lastname: Rousselle
authors.forename: N
authors.initials: N
authors.lastname: Clavier