Synthetic studies towards the ent-labdane diterpenoids: rearrangement of ent-halimanes.
For the first time ent-labdanes have been synthetised starting from ent-halimic acid, following a route that is the reverse of the biosynthetic one leading to the former compounds.
Marcos
Isidro S
IS
Departamento de Química Orgánica, Universidad de Salamanca, Plaza de los Caídos 1-5, 37008 Salamanca, Spain. ismarcos@usal.es
Sexmero
María J
MJ
Hernández
Felix A
FA
Corrales
Marta
M
Basabe
Pilar
P
Díez
David
D
Urones
Julio G
JG
D004224:Diterpenes / Q000138:chemical synthesis* / Q000737:chemistry*; D006027:Glycosides / Q000138:chemical synthesis / Q000737:chemistry
D004224:Diterpenes; D006027:Glycosides; C530795:ent-halimic acid; C495874:ent-labdane diglycoside