Oxidation reactivity channels for 2-(pyridin-2-yl)-N,N-diphenylacetamides.
Synthetic routes to 2-(pyridin-2-yl)-N,N-diphenylacetamide and 2-(6-methylpyridin-2-yl)-N,N-diphenyl-acetamide are described along with results from the chemical oxidation of these compounds with peracetic acid, m-chloroperbenzoic acid, and OXONE. In each case, oxidations generate four products in varying amounts depending on the oxidant and reaction conditions. Each product has been characterized by spectroscopic methods and the molecular structures of several of the new compounds have been confirmed by X-ray crystallography.
Pailloux
Sylvie
S
Department of Chemistry, University of New Mexico, Albuquerque, NM 87131, USA.
Binyamin
Iris
I
Deck
Lorraine M
LM
Rapko
Brian M
BM
Hay
Benjamin P
BP
Duesler
Eileen N
EN
Paine
Robert T
RT