The role of temperature on the structure and dimensionality of MOFs: an illustrative study of the formation of manganese oxy-bis(benzoate) structures.
Three new manganese oxy-bis(benzoate) compounds, synthesized by increasing the reaction temperature, with increasing dimensionality and decreasing Mn-Mn distances, indicate a possible pathway through an entropy driven dehydration route.
Mahata
Partha
P
Framework Solids Laboratory, Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore 560 012, India. snatarajan@sscu.iisc.ernet.in.
Sundaresan
A
A
Natarajan
Srinivasan
S