Synthesis and electrochemical study of the first tetrazolate hexanuclear rhenium cluster complex.
The linkage isomers [Re(6)Se(8)(PEt(3))(5)(1,5-MeN(4)C)](+) and [Re(6)Se(8)(PEt(3))(5)(2,5-MeN(4)C)](+) were generated upon reaction of tetrabutylammonium azide with the corresponding acetonitrile complex, [Re(6)Se(8)(PEt(3))(5)(NCCH(3))](2+); these are the first (tetrazolato)rhenium complexes reported to date.
Szczepura
Lisa F
LF
Department of Chemistry, Illinois State University, Campus Box 4160, Normal, IL 61790, USA. lfszcze@ilstu.edu
Oh
Meghan K
MK
Knott
Stanley A
SA
D018360:Crystallography, X-Ray; D004563:Electrochemistry; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012211:Rhenium / Q000737:chemistry*; D013777:Tetrazoles / Q000737:chemistry*
D009942:Organometallic Compounds; D013777:Tetrazoles; D012211:Rhenium