Stereocontrol mechanism in CO/p-methylstyrene copolymerisation catalysed by aryl-alpha-diimine Pd(II) complexes.
Structural analysis of the first steps of isotactic CO/p-methylstyrene copolymerisation, catalysed by aryl-alpha-diimine Pd(II) complexes, highlights the influence of steric effects on the stereoselectivity of olefin insertion.
Carfagna
Carla
C
Istituto di Scienze Chimiche F. Bruner, Università di Urbino, Piazza Rinascimento, 6 - 61029, Urbino, Italy. schim@uniurb.it
Gatti
Giuseppe
G
Mosca
Luca
L
Passeri
Alessandra
A
Paoli
Paola
P
Guerri
Annalisa
A