Supramolecule-regulated photophysics of oligo(p-phenyleneethynylene)-based rod-coil block copolymers: effect of molecular architecture.
Three new topology-varied rod-coil block copolymers, comprising the same oligo(p-phenyleneethynylene) (OPE) rod components and the same coil components, were synthesized by atom-transfer radical polymerization. Their photophysical properties were systematically studied and compared in consideration of their solid-state structures and self-assembly abilities. These copolymers have similar intrinsic photophysical properties to the OPE rods, as reflected in dilute solution. However, their photophysical properties in the solid state are manipulated to be dissimilar by supramolecular organization. Wide-angle X-ray diffraction (WAXD) and atomic force microscopy (AFM) data demonstrate that these copolymers possess different self-assembly abilities due to the molecular-architecture-dependent pi-pi interactions of the rods. Hence, the aggregates in the solid state are formed with a different mechanism for these copolymers, bringing about the discrepancy in the solid-state luminescent properties.
Pu
Kan-Yi
KY
Institute of Advanced Materials, Nanjing University of Posts and Telecommunications, 66 XinMoFan Road, Nanjing 210003, China.
Qi
Xiao-Ying
XY
Yang
Yan-Lian
YL
Lu
Xiao-Mei
XM
Li
Ting-Cheng
TC
Fan
Qu-Li
QL
Wang
Chen
C
Liu
Bin
B
Chan
Hardy Sze On
HS
Huang
Wei
W