Novel neutral octanuclear copper(I) complexes stabilized by pyridine linked bis(pyrazolate) ligands.
Two novel, neutral, octanuclear copper(I) complexes displaying twisted-boat Cu(8) conformations and short Cu-Cu interactions have been synthesized from hydrothermal reactions; the complexes show unusual multiple band emissions.
Zhou
Yongbo
Y
Department of Chemistry, Zhejiang University, Xixi campus, Hangzhou 310028, China.
Chen
Wanzhi
W
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011720:Pyrazoles / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D011720:Pyrazoles; D011725:Pyridines; C031280:pyrazole; D003300:Copper; C023666:pyridine