title: Synthesis and electrochemical study of the first tetrazolate hexanuclear rhenium cluster complex.
abstract: The linkage isomers [Re(6)Se(8)(PEt(3))(5)(1,5-MeN(4)C)](+) and [Re(6)Se(8)(PEt(3))(5)(2,5-MeN(4)C)](+) were generated upon reaction of tetrabutylammonium azide with the corresponding acetonitrile complex, [Re(6)Se(8)(PEt(3))(5)(NCCH(3))](2+); these are the first (tetrazolato)rhenium complexes reported to date.
authors.affiliation: Department of Chemistry, Illinois State University, Campus Box 4160, Normal, IL 61790, USA. lfszcze@ilstu.edu
authors.forename: Lisa F
authors.initials: LF
authors.lastname: Szczepura
authors.forename: Meghan K
authors.initials: MK
authors.lastname: Oh
authors.forename: Stanley A
authors.initials: SA
authors.lastname: Knott
mesh_terms: D018360:Crystallography, X-Ray; D004563:Electrochemistry; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012211:Rhenium / Q000737:chemistry*; D013777:Tetrazoles / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; D013777:Tetrazoles; D012211:Rhenium