title: Palladium-catalysed N-annulation routes to indoles: the synthesis of indoles with sterically demanding N-substituents, including demethylasterriquinone A1.
abstract: Tandem palladium-catalysed aryl and alkenyl C-N bond formation allows the synthesis of a variety of indoles bearing sterically demanding N-substituents, including the natural product demethylasterriquinone A1.
authors.affiliation: Department of Chemistry, University of Oxford, Chemical Research Laboratory, Mansfield Road, Oxford, UK OX1 3TA.
authors.forename: Anthony J
authors.initials: AJ
authors.lastname: Fletcher
authors.forename: Matthew N
authors.initials: MN
authors.lastname: Bax
authors.forename: Michael C
authors.initials: MC
authors.lastname: Willis
mesh_terms: D001688:Biological Products / Q000737:chemistry; D002384:Catalysis; D007211:Indoles / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D001688:Biological Products; D007211:Indoles; D010165:Palladium; D009584:Nitrogen