title: Atropisomeric phosphinines: design and synthesis.
abstract: The first atropisomeric phosphinine was designed and prepared by introducing substituents into specific positions of the heterocyclic framework; the presence of axial chirality was predicted by means of DFT calculations and experimentally verified by chiral HPLC analysis, derivatization experiments as well as temperature dependent 31P{1H} NMR spectroscopy.
authors.affiliation: Schuit Institute of Catalysis, Department of Chemical Engineering and Chemistry, Eindhoven University of Technology, 5600 MB Eindhoven, The Netherlands. c.mueller@tue.nl
authors.forename: Christian
authors.initials: C
authors.lastname: Müller
authors.forename: Evgeny A
authors.initials: EA
authors.lastname: Pidko
authors.forename: Daniel
authors.initials: D
authors.lastname: Totev
authors.forename: Martin
authors.initials: M
authors.lastname: Lutz
authors.forename: Anthony L
authors.initials: AL
authors.lastname: Spek
authors.forename: Rutger A
authors.initials: RA
authors.lastname: van Santen
authors.forename: Dieter
authors.initials: D
authors.lastname: Vogt
mesh_terms: D001555:Benzene Derivatives / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011789:Quantum Theory; D013237:Stereoisomerism
chemical_list: D001555:Benzene Derivatives; D009943:Organophosphorus Compounds; C519090:phosphinine