Chemical Manganese Dioxide (CMD): its application to the oxidative iodination of benzene, halobenzenes and some deactivated arenes.
After comparing our previous and newer results for numerous oxidative aromatic iodination experiments using various brands of active MnO2 as the oxidants,we recommend the use of a Chemical Manganese Dioxide (Aldrich CMD; 90 +% MnO2) as the oxidant of choice, since it is satisfactorily pure and chemically active, and is notably less costly than other options.
Lulinski
Piotr
P
Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University of Warsaw, 1 Banacha Street, PL 02-097 Warsaw, Poland.
Krassowska-Swiebocka
Barbara
B
Skulski
Lech
L
D001554:Benzene / Q000737:chemistry*; D054879:Halogenation; D047028:Macrocyclic Compounds / Q000737:chemistry*; D017895:Manganese Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry*
D047028:Macrocyclic Compounds; D017895:Manganese Compounds; D010087:Oxides; D001554:Benzene; C016552:manganese dioxide