Addition to electron deficient olefins of alpha-oxy carbon- centered radicals, generated from cyclic ethers and acetals by the reaction with alkylperoxy- lambda(3)-iodane.
Thermal decomposition of 1-tert-butylperoxy-1,2-benziodoxol-3(1H)-one in cyclic ethers and acetals at 50 degrees C generates alpha-oxy carbon-centered radicals, which undergo an addition reaction with vinyl sulfones and unsaturated esters.
Sueda
Takuya
T
Faculty of Pharmaceutical Sciences, University of Tokushima, 1-78 Shomachi, Tokushima 770-8505, Japan.
Takeuchi
Yasunori
Y
Suefuji
Takashi
T
Ochiai
Masahito
M
D000080:Acetals / Q000737:chemistry*; D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry*; D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000494:pharmacology*; D002244:Carbon / Q000737:chemistry*; D004583:Electrons; D004988:Ethers, Cyclic / Q000737:chemistry*; D017613:Iodine Compounds / Q000494:pharmacology*; D008954:Models, Biological; D013450:Sulfones / Q000737:chemistry
D000080:Acetals; D000475:Alkenes; D019086:Bridged Bicyclo Compounds, Heterocyclic; D004988:Ethers, Cyclic; D017613:Iodine Compounds; D013450:Sulfones; C526015:tert-butylperoxy-lambda(3)-iodane; C512310:phenyl vinyl sulfone; D002244:Carbon