Enhancing the reactivity of 1,2,3-triazoles in "click" macrocycles by face-to-face dibenzylammonium ion binding.
A face-to-face binding motif between dibenzylammonium ions and macrocycles containing 1,2,3-triazoles was established, which operates cooperatively to enhance the reactivity of 1,2,3-triazoles in an Arbuzov-type dealkylation reaction.
Liu
Yi
Y
The Molecular Foundry, Lawrence Berkeley National Laboratory, One Cyclotron Road, MS 67R6110, Berkeley, CA 94720, USA.
Zhang
Xiyun
X
Klivansky
Liana M
LM
Koshkakaryan
Gayane
G