Exact solution for anisotropic diffusion-controlled reactions with partially reflecting conditions.
We investigate a generalization of the model of Solc and Stockmayer to describe the diffusion-controlled reactions between chemically anisotropic reactants taking into account the partially reflecting conditions on two parts of the reaction surface. The exact solution of the relevant mixed boundary-value problem was found for different ratios of the intrinsic rate constants. The results obtained may be used to test numerical programs that describe diffusion-controlled reactions in real systems of particles with anisotropic reactivity.
Traytak
Sergey D
SD
Institute of Applied Mechanics, Russian Academy of Sciences, 32a Lenin Avenue, GSP-1, 119991 Moscow, Russia.
Price
William S
WS