Synthesis and asymmetric mono-cyclopalladation of 1,1'-di(alpha-dimethylamino)ethylferrocene.
Two-step synthesis of 1,1'-di(alpha-dimethylamino)ethylferrocene is described in details. Cyclopalladation of this diamine involving one or two amino groups is reported and the product of asymmetric mono-cyclopalladation is fully characterized.
Sokolov
Viatcheslav I
VI
Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28, Vavilov Street, 119991 Moscow, Russian Federation. sokol@ineos.ac.ru
Troitskaya
Ludmila L
LL
Bondareva-Don
Veronica L
VL
D003500:Cyclization; D003959:Diamines / Q000737:chemistry*; D019281:Dimerization; D005296:Ferrous Compounds / Q000138:chemical synthesis*; D009942:Organometallic Compounds / Q000138:chemical synthesis; D010165:Palladium / Q000737:chemistry*
D003959:Diamines; D005296:Ferrous Compounds; D009942:Organometallic Compounds; C053523:ethylferrocene; D010165:Palladium