Asymmetrical polar modification of a bivanadium-capped Keggin POM by multiple Cu-N coordination polymeric chains.
An unprecedented asymmetrically modified bivanadium-capped Keggin polyoxometalate (POM), {AsMo12O40(VO)[VO(H2O)]}.[Cu(4,4'-bipy)]5.H2O (1) (bipy = bipyridine), has been hydrothermally synthesized and structurally characterized by a routine technique. Single-crystal X-ray diffraction analysis reveals that compound 1 exhibits a unique (3,4,6)-connected 3D framework with a (6(2).8(1))2(8(3))2(6(4).8(2))2(6(1).8(14)) topology, constructed from {AsMo12O40(VO)[VO(H2O)]}5- polyoxoanions modified by six {Cu(bipy)}n coordination polymeric chains. The asymmetrical polar coordination mode has never been found in the POM chemistry hitherto. It is also the first example of the bivanadium-capped POM as an anionic template to construct a 3D framework with the highest connection number of bicapped POMs. Additionally, by just changing the length of the organic ligand, a new compound {[AsMo12O40(VO)2][Cu(bpe)]2}.[Cu(bpe)].[H2bpe].H2O (2) (bpe = bis(4-pyridyl)ethylene), has been obtained, in which the {AsMo12O40(VO)2} sections are modified by double monotrack {Cu(bpe)}n coordination polymeric chains to form a "rail-like" 1D structure.
Sha
Jing-Quan
JQ
Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, Jilin, PR China.
Peng
Jun
J
Liu
Hong-Sheng
HS
Chen
Jing
J
Tian
Ai-Xiang
AX
Zhang
Peng-Peng
PP
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry*; D009584:Nitrogen / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*; D013053:Spectrophotometry; D013237:Stereoisomerism; D017973:Tungsten Compounds / Q000737:chemistry*; D014639:Vanadium / Q000737:chemistry*; D017968:Vanadium Compounds / Q000737:chemistry*
D011108:Polymers; D017973:Tungsten Compounds; D017968:Vanadium Compounds; D014639:Vanadium; D003300:Copper; D008982:Molybdenum; D009584:Nitrogen