An electron transfer approach to the preparation of highly functionalized anthraquinones.
A series of highly functionalized quinones was prepared by an original reaction of 2,3-bis(chloromethyl)-1,4-dimethoxyanthraquinone (6) with various nitronate anions under electron transfer reaction conditions.
Beziane
Abdelouahab
A
Laboratoire de Chimie Organique Pharmaceutique, CNRS-UMR 6517, Faculté de Pharmacie, 27 Bd Jean Moulin, 13385 Marseille Cx 5, France.
Terme
Thierry
T
Vanelle
Patrice
P
D018943:Anthracyclines / Q000138:chemical synthesis / Q000737:chemistry; D000880:Anthraquinones / Q000138:chemical synthesis* / Q000737:chemistry; D003500:Cyclization; D004583:Electrons; D008954:Models, Biological
D018943:Anthracyclines; D000880:Anthraquinones