title: NO-disproportionation, promoted by Pd-cluster: formation and X-ray structure of Pd8(micro-CO)4(micro-OOCCMe3)8[micro-N(=O)O-]4.
abstract: Interaction of Pd-clusters [Pd(CO)(OCOR)](n) with NO was investigated, these Pd-clusters were found to promote the NO disproportionation into N(2) and NO(2)(-) in mild conditions; an eight-nuclear palladium cluster Pd(8)(micro-CO)(4)(micro-OOCCMe(3))(8)(micro-NO(2))(4) with a new type of structure and an uncommon set of ligands was characterized by X-ray diffraction analysis.
authors.affiliation: N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, Leninsky pr., 31, Moscow 119991, Russian Federation. strom@igic.ras.ru
authors.forename: Tatiana A
authors.initials: TA
authors.lastname: Stromnova
authors.forename: Oleg N
authors.initials: ON
authors.lastname: Shishilov
authors.forename: Andrei V
authors.initials: AV
authors.lastname: Churakov
authors.forename: Lyudmila G
authors.initials: LG
authors.lastname: Kuz'mina
authors.forename: Judith A K
authors.initials: JA
authors.lastname: Howard
mesh_terms: D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009569:Nitric Oxide / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
chemical_list: D009942:Organometallic Compounds; C526865:Pd(8)(micro-CO)(4)(micro-OOCCMe(3))(8)(micro-NO(2))(4); D009569:Nitric Oxide; D010165:Palladium