Preparation of an eight-membered sesquiterpene lactone resulting from sequential Gif System GoAgg(III) and MCPBA oxidation of (+)-10beta,14-dihydroxy-allo-aromadendrane.
Studies aimed at a comparison of chemical, biomimetic (Gif system GoAgg(III))and enzymatic (CHMO) transformations of natural (+)-10beta,14-dihydroxy-allo-aromadendrane have led to preparation of an eight-member sesquiterpene lactone.
de Bodas
Márcia M L
MM
Universidade Federal de Mato Grosso do Sul, Departamento de Química / CCET - CP 549 - 79070-900 - Campo Grande (MS) - Brazil.
Marques
Maria Rita
MR
Beatriz
Adilson
A
de Lima
Dênis P
DP
D040761:Biomimetic Materials / Q000737:chemistry*; D002723:Chlorobenzoates / Q000737:chemistry*; D007536:Isomerism; D007783:Lactones / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D010105:Oxygenases / Q000378:metabolism; D012717:Sesquiterpenes / Q000737:chemistry*; D045789:Sesquiterpenes, Guaiane
C525040:10,14-dihydroxyaromadendrane; D002723:Chlorobenzoates; D007783:Lactones; D012717:Sesquiterpenes; D045789:Sesquiterpenes, Guaiane; C519959:aromadendrane; D010105:Oxygenases; C019961:cyclohexanone oxygenase; C000433:3-chloroperbenzoic acid