Enantioselective hydrogenations with chiral titanocenes.
In this review article chiral titanocenes and their application for the enantioselective hydrogenations of different unsaturated compounds are discussed, with a special emphasis on the kinetics and the practicality of the developed systems. The nature of enantioselectivity and the hydrogenation mechanisms are reviewed as well. Catalyst immobilization and the different immobilization techniques are examined.
Vassylyev
Oleksiy
O
Department of Chemical and Biochemical Engineering, Rutgers University, Piscataway, NJ 08854-8058, USA.
Panarello
Anthony
A
Khinast
Johannes G
JG
D002384:Catalysis; D006865:Hydrogenation; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism; D014025:Titanium / Q000737:chemistry
D009942:Organometallic Compounds; C406884:titanocene; D014025:Titanium