Self-terminating, oxidative radical cyclizations.
The recently discovered novel concept of self-terminating, oxidative radical cyclizations, through which alkynes can be converted into carbonyl compounds under very mild reaction conditions using O-centered inorganic and organic radicals as oxidants, is described.
Dreessen
Tim
T
Institut für Organische Chemie, Universität Kiel, Olshausenstr, 40, 24098 Kiel, Germany.
Jargstorff
Christian
C
Lietzau
Lars
L
Plath
Christian
C
Stademann
Arne
A
Wille
Uta
U
D000480:Alkynes / Q000737:chemistry; D003500:Cyclization; D005609:Free Radicals / Q000737:chemistry*; D017665:Hydroxyl Radical / Q000737:chemistry; D008956:Models, Chemical; D015394:Molecular Structure; D009566:Nitrates / Q000737:chemistry; D016877:Oxidants / Q000737:chemistry*; D010084:Oxidation-Reduction; D017382:Reactive Oxygen Species / Q000737:chemistry
D000480:Alkynes; D005609:Free Radicals; D009566:Nitrates; D016877:Oxidants; D017382:Reactive Oxygen Species; D017665:Hydroxyl Radical