CuCl2-catalyzed one-pot formation of tetrahydroquinolines from N-methyl-N-alkylanilines and vinyl ethers in the presence of t-butylhydroperoxide.
Tetrahydroquinoline skeletons can be formed by a CuCl2-catalyzed one-pot reaction of N-methyl-N-alkylanilines and vinyl ethers in the presence of t-butyl-hydroperoxide.
Yang
Xianghua
X
Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, PR China. yxh04@mails.tsinghua.edu.cn
Xi
Chanjuan
C
Jiang
Yanfeng
Y
D000814:Aniline Compounds / Q000737:chemistry*; D002384:Catalysis; D002623:Chemistry Techniques, Analytical / Q000379:methods*; D003300:Copper / Q000737:chemistry*; D011804:Quinolines / Q000138:chemical synthesis*; D014753:Vinyl Compounds / Q000737:chemistry*; D020122:tert-Butylhydroperoxide / Q000737:chemistry*
D000814:Aniline Compounds; D011804:Quinolines; D014753:Vinyl Compounds; C100195:vinyl ether; D003300:Copper; D020122:tert-Butylhydroperoxide; C029892:cupric chloride