Chemo-, regio- and stereoselective preparation of silyl enol ethers from thiol esters and bis(iodozincio)alkane.
Treatment of thiol ester with bis(iodozincio)alkane in the presence of palladium catalyst followed by silylation affords Z-silyl enol ether chemo-, regio- and stereoselectively.
Ooguri
Akihiro
A
Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoutodaigaku-Katsura, Nishikyo, Kyoto 615-8501, Japan.
Ikeda
Zenichi
Z
Matsubara
Seijiro
S