Triisobutylaluminium (TIBAL) promoted rearrangement of C-glycosides.
Triisobutylaluminium-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons, such as C-aryl glycosides, provides direct access to highly functionalised cyclohexane derivatives.
Sollogoub
Matthieu
M
Ecole Normale Supérieure, Département de Chimie, 75231 Paris Cedex 05, France. Matthieu.Sollogoub@ens.fr
Sinaÿ
Pierre
P
D000535:Aluminum / Q000737:chemistry*; D006027:Glycosides / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*
D006027:Glycosides; D009942:Organometallic Compounds; C525037:triisobutylaluminum; D000535:Aluminum