title: Self-terminating, oxidative radical cyclizations.
abstract: The recently discovered novel concept of self-terminating, oxidative radical cyclizations, through which alkynes can be converted into carbonyl compounds under very mild reaction conditions using O-centered inorganic and organic radicals as oxidants, is described.
authors.affiliation: Institut für Organische Chemie, Universität Kiel, Olshausenstr, 40, 24098 Kiel, Germany.
authors.forename: Tim
authors.initials: T
authors.lastname: Dreessen
authors.forename: Christian
authors.initials: C
authors.lastname: Jargstorff
authors.forename: Lars
authors.initials: L
authors.lastname: Lietzau
authors.forename: Christian
authors.initials: C
authors.lastname: Plath
authors.forename: Arne
authors.initials: A
authors.lastname: Stademann
authors.forename: Uta
authors.initials: U
authors.lastname: Wille
mesh_terms: D000480:Alkynes / Q000737:chemistry; D003500:Cyclization; D005609:Free Radicals / Q000737:chemistry*; D017665:Hydroxyl Radical / Q000737:chemistry; D008956:Models, Chemical; D015394:Molecular Structure; D009566:Nitrates / Q000737:chemistry; D016877:Oxidants / Q000737:chemistry*; D010084:Oxidation-Reduction; D017382:Reactive Oxygen Species / Q000737:chemistry
chemical_list: D000480:Alkynes; D005609:Free Radicals; D009566:Nitrates; D016877:Oxidants; D017382:Reactive Oxygen Species; D017665:Hydroxyl Radical