title: Chemical Manganese Dioxide (CMD): its application to the oxidative iodination of benzene, halobenzenes and some deactivated arenes.
abstract: After comparing our previous and newer results for numerous oxidative aromatic iodination experiments using various brands of active MnO2 as the oxidants,we recommend the use of a Chemical Manganese Dioxide (Aldrich CMD; 90 +% MnO2) as the oxidant of choice, since it is satisfactorily pure and chemically active, and is notably less costly than other options.
authors.affiliation: Laboratory of Organic Chemistry, Faculty of Pharmacy, Medical University of Warsaw, 1 Banacha Street, PL 02-097 Warsaw, Poland.
authors.forename: Piotr
authors.initials: P
authors.lastname: Lulinski
authors.forename: Barbara
authors.initials: B
authors.lastname: Krassowska-Swiebocka
authors.forename: Lech
authors.initials: L
authors.lastname: Skulski
mesh_terms: D001554:Benzene / Q000737:chemistry*; D054879:Halogenation; D047028:Macrocyclic Compounds / Q000737:chemistry*; D017895:Manganese Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D010087:Oxides / Q000737:chemistry*
chemical_list: D047028:Macrocyclic Compounds; D017895:Manganese Compounds; D010087:Oxides; D001554:Benzene; C016552:manganese dioxide