title: Highly ortho-selective cross-coupling of dichlorobenzene derivatives with Grignard reagents.
abstract: Highly ortho-selective cross-coupling of dichlorobenzene derivatives with Grignard reagents was realized using a combination of Pd2(dba)3 and PCy3. Use of hydroxylated terphenylphosphines further improved the reactions of dichlorophenol and dichloroaniline.
authors.affiliation: RIKEN, 2-1 Hirosawa, Wako 351-0198, Japan.
authors.forename: Shunpei
authors.initials: S
authors.lastname: Ishikawa
authors.forename: Kei
authors.initials: K
authors.lastname: Manabe