title: Triisobutylaluminium (TIBAL) promoted rearrangement of C-glycosides.
abstract: Triisobutylaluminium-promoted rearrangement of unsaturated glycosides containing electron-donating aglycons, such as C-aryl glycosides, provides direct access to highly functionalised cyclohexane derivatives.
authors.affiliation: Ecole Normale Supérieure, Département de Chimie, 75231 Paris Cedex 05, France. Matthieu.Sollogoub@ens.fr
authors.forename: Matthieu
authors.initials: M
authors.lastname: Sollogoub
authors.forename: Pierre
authors.initials: P
authors.lastname: Sinaÿ
mesh_terms: D000535:Aluminum / Q000737:chemistry*; D006027:Glycosides / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*
chemical_list: D006027:Glycosides; D009942:Organometallic Compounds; C525037:triisobutylaluminum; D000535:Aluminum