Batch removal of malachite green from aqueous solutions by adsorption on oil palm trunk fibre: equilibrium isotherms and kinetic studies.
Oil palm trunk fibre (OPTF)--an agricultural solid waste--was used as low-cost adsorbent to remove malachite green (MG) from aqueous solutions. The operating variables studied were contact time, initial dye concentration, and solution pH. Equilibrium adsorption data were analyzed by three isotherms, namely the Freundlich isotherm, the Langmuir isotherm, and the multilayer adsorption isotherm. The best fit to the data was obtained with the multilayer adsorption. The monolayer adsorption capacity of OPTF was found to be 149.35 mg/g at 30 degrees C. Adsorption kinetic data were modeled using the Lagergren pseudo-first-order, Ho's pseudo-second-order and Elovich models. It was found that the Lagergren's model could be used for the prediction of the system's kinetics. The overall rate of dye uptake was found to be controlled by external mass transfer at the beginning of adsorption, then for initial MG concentrations of 25, 50, 100, 150, and 300 mg/L the rate-control changed to intraparticle diffusion at a later stage, but for initial MG concentrations 200 and 250 mg/L no evidence was found of intraparticle diffusion at any period of adsorption. It was found that with increasing the initial concentration of MG, the pore-diffusion coefficient increased while the film-diffusion coefficient decreased.
Hameed
B H
BH
School of Chemical Engineering, Engineering Campus, Universiti Sains Malaysia, 14300 Nibong Tebal, Penang, Malaysia. chbassim@eng.usm.my
El-Khaiary
M I
MI
D000327:Adsorption; D000383:Agriculture; D004396:Coloring Agents / Q000737:chemistry*; D005659:Fungicides, Industrial / Q000737:chemistry; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D000073878:Palm Oil; D010938:Plant Oils; D018547:Plant Stems; D012394:Rosaniline Dyes / Q000737:chemistry*; D012996:Solutions; D014865:Waste Disposal, Fluid / Q000379:methods; D014866:Waste Products; D014874:Water Pollutants, Chemical / Q000737:chemistry*; D018508:Water Purification / Q000379:methods
D004396:Coloring Agents; D005659:Fungicides, Industrial; D010938:Plant Oils; D012394:Rosaniline Dyes; D012996:Solutions; D014866:Waste Products; D014874:Water Pollutants, Chemical; C005095:malachite green; D000073878:Palm Oil