NO-disproportionation, promoted by Pd-cluster: formation and X-ray structure of Pd8(micro-CO)4(micro-OOCCMe3)8[micro-N(=O)O-]4.
Interaction of Pd-clusters [Pd(CO)(OCOR)](n) with NO was investigated, these Pd-clusters were found to promote the NO disproportionation into N(2) and NO(2)(-) in mild conditions; an eight-nuclear palladium cluster Pd(8)(micro-CO)(4)(micro-OOCCMe(3))(8)(micro-NO(2))(4) with a new type of structure and an uncommon set of ligands was characterized by X-ray diffraction analysis.
Stromnova
Tatiana A
TA
N.S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Science, Leninsky pr., 31, Moscow 119991, Russian Federation. strom@igic.ras.ru
Shishilov
Oleg N
ON
Churakov
Andrei V
AV
Kuz'mina
Lyudmila G
LG
Howard
Judith A K
JA
D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure; D009569:Nitric Oxide / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*
D009942:Organometallic Compounds; C526865:Pd(8)(micro-CO)(4)(micro-OOCCMe(3))(8)(micro-NO(2))(4); D009569:Nitric Oxide; D010165:Palladium