Asymmetric synthesis of (+)-cis-nemorensic acid from a chiral Diels-Alder adduct of 2,5-dimethylfuran.
(+)-cis-Nemorensic acid was synthesized from a chiral Diels-Alder adduct prepared by a catalytic enantioselective Diels-Alder reaction with 2,5-dimethylfuran and 2,2,2-trifluoroethyl acrylate.
Department of Chemistry, Sungkyunkwan University, Suwon 440-746, Korea.
Jae Yi
JY
Sim
Geum-Sook
GS
Hwang
Kyung Hwa
KH
Kim
Eun Mi
EM
Ko
Do Hyun
DH
Ryu
D005663:Furans / Q000138:chemical synthesis* / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D011763:Pyrrolizidine Alkaloids / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D005663:Furans; D011763:Pyrrolizidine Alkaloids; C458241:nemorensic acid; C037555:2,5-dimethylfuran