O2,1'-anhydro-(beta-D-psicofuranosyl)thymine and 1-(1',4'-O-anhydro-beta-D-psicofuranosyl)thymine: the crystal structures versus the 1H NMR and ab initio data.
The crystal structures of the title compounds 1 and 2 have been determined. Relation between the stereochemistry of both nucleosides in the crystal state and the (1)H NMR data in solution as well as the ab initio calculations is discussed.
Department of Pharmaceutical Chemistry, University of Kuopio, Kuopio, Finland.
Jarkko
J
Roivainen
Igor A
IA
Mikhailopulo
Henning
H
Eickmeier
Hans
H
Reuter
D002942:Circular Dichroism; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D012996:Solutions; D013936:Thymidine / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry
D012996:Solutions; D013936:Thymidine