Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes.
Palladium(II) aryliodo complexes bearing chelating diphosphine ligands react with XeF2, giving iodoarene and rare palladium(II) difluoro complexes. The reaction is general with regard to the aryl group, with even C6F5-I undergoing facile reductive elimination from a Pd center.
School of Chemistry, The Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv, Israel.
Ariela W
AW
Kaspi
Anette
A
Yahav-Levi
Israel
I
Goldberg
Arkadi
A
Vigalok
D018360:Crystallography, X-Ray; D005459:Fluorides / Q000737:chemistry*; D006847:Hydrocarbons, Iodinated / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D014978:Xenon / Q000737:chemistry*
D006847:Hydrocarbons, Iodinated; D009942:Organometallic Compounds; D014978:Xenon; D010165:Palladium; C048007:xenon fluoride; D005459:Fluorides