Adsorption removal of phosphate from aqueous solution by active red mud.
Red mud is the waste of alumina industry and has high TiO2 and Fe2O3 content which are active components for the adsorption of anion pollutants. In this study, the uptake of phosphate by red mud activated by heat treatment and acid-heat treatment was investigated. The factors influencing the adsorption were also investigated. The result showed that the red mud sample treated using acid-heat method at 80 degrees C with 0.25 mol/L HCl for 2 h achieved the highest phosphate removal. For the heat-activated red mud, the sample heated at 700 degrees C for 2 h preformed better than the other heat treatment. Phosphate removal by the activated red mud was significantly pH dependent, and pH 7 was the optimal pH for phosphate removal. The adsorption fits Langmuir isotherm model well and the maximum adsorption capacities of the acid-heat activated red mud and the heat activated samples were 202.9 mgP/g and 155.2 mgP/g, respectively.
State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China. liuchangjun@china.com
Chang-jun
CJ
Liu
Yan-zhong
YZ
Li
Zhao-kun
ZK
Luan
Zhao-yang
ZY
Chen
Zhong-guo
ZG
Zhang
Zhi-ping
ZP
Jia
D000327:Adsorption; D000537:Aluminum Oxide / Q000737:chemistry; D006358:Hot Temperature; D006863:Hydrogen-Ion Concentration; D008277:Magnesium Oxide / Q000737:chemistry; D010087:Oxides / Q000737:chemistry; D010710:Phosphates / Q000737:chemistry* / Q000302:isolation & purification; D017680:Potassium Compounds / Q000737:chemistry; D015203:Reproducibility of Results; D012822:Silicon Dioxide / Q000737:chemistry; D017670:Sodium Compounds / Q000737:chemistry; D013997:Time Factors; D014025:Titanium / Q000737:chemistry; D014874:Water Pollutants, Chemical / Q000737:chemistry* / Q000302:isolation & purification; D018508:Water Purification / Q000379:methods*
D010087:Oxides; D010710:Phosphates; D017680:Potassium Compounds; D017670:Sodium Compounds; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; C096707:sodium oxide; D008277:Magnesium Oxide; C068440:potassium oxide; D012822:Silicon Dioxide; D014025:Titanium; D000537:Aluminum Oxide