Total synthesis of (+)-komarovispirone.
(+)-Komaroviquinone photolytically rearranges to (+)-komarovispirone. A rationalization of this isomerization is presented.
Majetich
George
G
Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA. majetich@chem.uga.edu
Yu
Jianhua
J
D004224:Diterpenes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D011809:Quinones / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
D004224:Diterpenes; D011809:Quinones; C508550:komaroviquinone