Manganese and iron flavonolates as flavonol 2,4-dioxygenase mimics.
Mononuclear manganese(II) and iron(III) flavonolates were synthesized as synthetic enzyme-substrate complexes, and their oxygenation reactions as biomimetic functional models with relevance to flavonol 2,4-dioxygenases are briefly described.
Kaizer
József
J
Department of Chemistry, University of Pannonia, Veszprém, Hungary.
Baráth
Gábor
G
Pap
József
J
Speier
Gábor
G
Giorgi
Michel
M
Réglier
Marius
M
D002384:Catalysis; D018360:Crystallography, X-Ray; D049308:Dioxygenases / Q000737:chemistry*; D005419:Flavonoids / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D007700:Kinetics; D008345:Manganese / Q000737:chemistry*; D008954:Models, Biological; D008958:Models, Molecular; D018716:Molecular Mimicry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D005419:Flavonoids; D009942:Organometallic Compounds; D008345:Manganese; D007501:Iron; D049308:Dioxygenases; C121201:flavonol 2,4-dioxygenase