An unprecedented co-crystal including a cis-high-spin and a trans-low-spin FeII complex molecule.
Two structurally and magnetically nonequivalent isomeric molecules, a cis-high-spin and a trans-low-spin isomer constitute the unit cell of a new iron(II) complex {cis-[FeL(B5)(NCS)(2)].trans-[FeL(B5)(NCS)(2)]}.CH(3)OH, , (L(B5) = N,N'-bis((2-N-methylimidazol-1-yl)methylene))-2,2-dimethylpropane-1,3-diamine); the synthesis, X-ray structure, and magnetic and Mössbauer study of this unique example of co-crystallised geometric, conformational and electronic isomers are reported.
Bréfuel
Nicolas
N
Laboratoire de Chimie de Coordination du CNRS, UPR 8241, 205 route de Narbonne, Toulouse, France.
Duhayon
Carine
C
Shova
Sergiu
S
Tuchagues
Jean-Pierre
JP
D018360:Crystallography, X-Ray; D003959:Diamines / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry*; D007093:Imidazoles / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D015204:Spectroscopy, Mossbauer; D013237:Stereoisomerism
C526884:(N,N'-bis((2-N-methylimidazol-1-yl)methylene))-2,2-dimethylpropane-1,3-diamine; D003959:Diamines; D005296:Ferrous Compounds; D007093:Imidazoles; D008024:Ligands; D009942:Organometallic Compounds