Lead and strontium isotopes as indicators for mixing processes of waters in the former mine 'Himmelfahrt Fundgrube', Freiberg (Germany).
To pinpoint the origin and mixing processes of mine waters, different mine water types from the polymetallic sulphide ore deposit 'Himmelfahrt Fundgrube' (Freiberg, Germany) were analysed by thermal ionisation mass spectrometry using lead and strontium isotope ratios. Results show that the lead isotope composition of different mine waters results from a mixture of at least two sources: released lead from oxidised sulphide ores (mainly galena) and anthropogenic lead from groundwater. Furthermore, there are indications for an additional lead source. Strontium isotopes in mine waters identify at least three different sources: released strontium from weathered host rock (Grey Gneisses), released strontium from weathered gangue carbonates, and probably strontium from anthropogenic inputs. Contrary to former oxygen and sulphur isotope studies, strontium isotope compositions as well as hydrochemical parameters show the important role of gangue carbonates as an element source in mine waters.
Heidel
Claudia
C
Institute of Mineralogy, Technische Universität Bergakademie Freiberg, Freiberg, Germany. claudia.heidel@mineral.tu-freiberg.de
Tichomirowa
Marion
M
Matschullat
Jörg
J
D004784:Environmental Monitoring / Q000379:methods*; D005858:Germany; D007854:Lead / Q000032:analysis*; D008906:Mining; D010084:Oxidation-Reduction; D013324:Strontium / Q000032:analysis*; D013325:Strontium Isotopes / Q000032:analysis; D013440:Sulfides / Q000737:chemistry; D014872:Water Movements; D014874:Water Pollutants, Chemical / Q000032:analysis*
D013325:Strontium Isotopes; D013440:Sulfides; D014874:Water Pollutants, Chemical; D007854:Lead; D013324:Strontium