catena-Poly[[aquacopper(II)]-mu-hydroxido-mu-naphthalene-1-carboxylato-kappa2O:O']: effect of a bulky aromatic skeleton in self-assembly.
In the title coordination polymer, [Cu(C11H7O2)(OH)(H2O)]n, the Cu(II) center is five-coordinated by two O atoms from two different naphthalene-1-carboxylate (L) ligands, one O atom from one coordinated water molecule and two O atoms from two hydroxide anions. L ligands and hydroxide anions jointly bridge adjacent Cu(II) centers to generate a one-dimensional chain along the b-axis direction. The results reveal that the steric bulk of the naphthalene ring system in L may play an important role in the formation of the title complex.
Liu
Chun-Sen
CS
Zhengzhou University of Light Industry, Henan Provincial Key Laboratory of Surface and Interface Science, Henan, Zhengzhou 450002, People's Republic of China. chunsenliu@mail.nankai.edu.cn
Chang
Ze
Z
Wang
Jun-Jie
JJ