Autothermal reforming of propane over hydrotalcite-like catalysts containing promotor.
Hydrotalcite-like catalysts were synthesized by co-precipitation and then these were promoted by the addition of noble metals, alkaline earth metals and ceria. Reaction tests were conducted using a feed of H2O/C/O2 = 3/1/0.37 at a temperature range from 300 degrees C to 700 degrees C. Catalysts were characterized by XRD, TEM, FESEM, TPR, and BET. Reaction test results confirmed an enhancement of the catalytic activity of the promotor-modified catalysts due to low carbon deposition. Among the alkaline earth metals tested, those with larger atomic number exhibited higher activity at a lower temperature range.
Department of Material Chemical and Biochemical Engineering, Center for Functional Nano Fine Chemicals, Chonnam National University, 300 Yongbong-dong, Buk-gu, Gwangju 500-757, Korea.
You-Soon
YS
Lim
Dong-Ju
DJ
Moon
Nam-Cook
NC
Park
Jae-Soon
JS
Shin
Jong-Ho
JH
Kim
Young-Chul
YC
Kim
D000536:Aluminum Hydroxide / Q000737:chemistry*; D002384:Catalysis; D003460:Crystallization / Q000379:methods*; D006358:Hot Temperature; D046911:Macromolecular Substances / Q000737:chemistry; D008276:Magnesium Hydroxide / Q000737:chemistry*; D008422:Materials Testing; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D036103:Nanotechnology / Q000379:methods*; D010316:Particle Size; D044367:Phase Transition; D011407:Propane / Q000737:chemistry*; D013499:Surface Properties
D046911:Macromolecular Substances; C010467:hydrotalcite; D000536:Aluminum Hydroxide; D008276:Magnesium Hydroxide; D011407:Propane