New water-soluble polyanionic dendrimers and binding to acetylcholine in water by means of contact ion-pairing interactions.
A new water-soluble polyanionic dendrimer containing 81 benzoate termini (diameter: 11+/-1 nm from DOSY NMR spectroscopy) has been synthesized; it interacts with acetylcholine cations in water-soluble assemblies in which each carboxylate terminus reversibly forms contact ion pairs and aggregates at the tether termini, as shown by 1H NMR spectroscopy.
Ornelas
Cátia
C
Institut des Sciences Moléculaires, UMR CNRS N 5255, Université Bordeaux 1, 33405 Talence Cedex, France.
Boisselier
Elodie
E
Martinez
Victor
V
Pianet
Isabelle
I
Ruiz Aranzaes
Jaime
J
Astruc
Didier
D
D000109:Acetylcholine / Q000737:chemistry*; D000838:Anions / Q000737:chemistry; D050091:Dendrimers / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D012995:Solubility; D014867:Water / Q000737:chemistry*
D000838:Anions; D050091:Dendrimers; D014867:Water; D000109:Acetylcholine