17O NMR investigation of phosphite hydrolysis mechanisms.
The use of solution 17O NMR spectroscopy in verifying the mechanism of trialkyl phosphite hydrolysis is presented. Trimethyl phosphite was reacted with 17O-labeled H2O at different temperatures and two reactant concentrations, with the reaction being monitored by 17O NMR. Kinetic details elucidated from the NMR spectra are also discussed.
McIntyre
Sarah K
SK
Department of Electronic and Nanostructured Materials, Sandia National Laboratories, Albuquerque, NM 87185-0886, USA.
Alam
Todd M
TM
D006868:Hydrolysis; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy / Q000379:methods* / Q000592:standards; D015394:Molecular Structure; D010103:Oxygen Isotopes; D017905:Phosphites / Q000737:chemistry*; D012015:Reference Standards; D012680:Sensitivity and Specificity; D012996:Solutions / Q000737:chemistry
D010103:Oxygen Isotopes; D017905:Phosphites; D012996:Solutions