O2,1'-anhydro-(beta-D-psicofuranosyl)thymine and 1-(1',4'-O-anhydro-beta-D-psicofuranosyl)thymine: the crystal structures versus the 1H NMR and ab initio data.
The crystal structures of the title compounds 1 and 2 have been determined. Relation between the stereochemistry of both nucleosides in the crystal state and the (1)H NMR data in solution as well as the ab initio calculations is discussed.
Roivainen
Jarkko
J
Department of Pharmaceutical Chemistry, University of Kuopio, Kuopio, Finland.
Mikhailopulo
Igor A
IA
Eickmeier
Henning
H
Reuter
Hans
H
D002942:Circular Dichroism; D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D012996:Solutions; D013936:Thymidine / Q000031:analogs & derivatives* / Q000138:chemical synthesis / Q000737:chemistry
D012996:Solutions; D013936:Thymidine