17O NMR investigation of phosphite hydrolysis mechanisms.
The use of solution 17O NMR spectroscopy in verifying the mechanism of trialkyl phosphite hydrolysis is presented. Trimethyl phosphite was reacted with 17O-labeled H2O at different temperatures and two reactant concentrations, with the reaction being monitored by 17O NMR. Kinetic details elucidated from the NMR spectra are also discussed.
Department of Electronic and Nanostructured Materials, Sandia National Laboratories, Albuquerque, NM 87185-0886, USA.
Sarah K
SK
McIntyre
Todd M
TM
Alam
D006868:Hydrolysis; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy / Q000379:methods* / Q000592:standards; D015394:Molecular Structure; D010103:Oxygen Isotopes; D017905:Phosphites / Q000737:chemistry*; D012015:Reference Standards; D012680:Sensitivity and Specificity; D012996:Solutions / Q000737:chemistry
D010103:Oxygen Isotopes; D017905:Phosphites; D012996:Solutions