catena-Poly[[aquacopper(II)]-mu-hydroxido-mu-naphthalene-1-carboxylato-kappa2O:O']: effect of a bulky aromatic skeleton in self-assembly.
In the title coordination polymer, [Cu(C11H7O2)(OH)(H2O)]n, the Cu(II) center is five-coordinated by two O atoms from two different naphthalene-1-carboxylate (L) ligands, one O atom from one coordinated water molecule and two O atoms from two hydroxide anions. L ligands and hydroxide anions jointly bridge adjacent Cu(II) centers to generate a one-dimensional chain along the b-axis direction. The results reveal that the steric bulk of the naphthalene ring system in L may play an important role in the formation of the title complex.
Zhengzhou University of Light Industry, Henan Provincial Key Laboratory of Surface and Interface Science, Henan, Zhengzhou 450002, People's Republic of China. chunsenliu@mail.nankai.edu.cn
Chun-Sen
CS
Liu
Ze
Z
Chang
Jun-Jie
JJ
Wang