Comparative study of regioselective synthesis of beta-aminoalcohols under solventless conditions catalyzed by sulfated zirconia and SZ/MCM-41.
Sulfated zirconia and SZ/MCM-41 were used as catalysts for the synthesis of beta-aminoalcohols via epoxide aminolysis. Sulfated zirconia was prepared by sol-gel and SZ/MCM-41 was obtained by impregnation. Solid catalysts were characterized by XRD, SEM-EDS, UV-Vis, FT-IR pyridine desorption and Nitrogen physisorption. Both acid materials were useful as catalysts, even when they were recycled several times. The beta-aminoalcohols were characterized by FT-IR, (1)H- and (13)C-NMR and GC-MS.
Negrón-Silva
Guillermo
G
Departamento de Ciencias Básicas, UAM, Av. San Pablo No 180. C. P. 02200, México D. F., México. gns@correo.azc.uam.mx
Hernández-Reyes
C Xochitl
CX
Angeles-Beltrán
Deyanira
D
Lomas-Romero
Leticia
L
González-Zamora
Eduardo
E
Méndez-Vivar
Juan
J
D000605:Amino Alcohols / Q000138:chemical synthesis* / Q000737:chemistry; D004852:Epoxy Compounds / Q000737:chemistry; D008855:Microscopy, Electron, Scanning; D015394:Molecular Structure; D012822:Silicon Dioxide / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013431:Sulfates / Q000737:chemistry*; D014961:X-Ray Diffraction; D015040:Zirconium / Q000737:chemistry*
D000605:Amino Alcohols; D004852:Epoxy Compounds; C509968:MCM-41; D012997:Solvents; D013431:Sulfates; D012822:Silicon Dioxide; D015040:Zirconium; C028541:zirconium oxide