Temperature and heat capacity of atomic clusters as estimated in terms of kinetic-energy release of atomic evaporation.
The temperature and heat capacity of isolated atomic clusters are studied in terms of an ab initio statistical theory of kinetic energy distribution by atomic evaporation. Two definitions of canonical temperature are examined and numerically compared: One is based on the most probable kinetic energy release (KER), whereas the other is determined with use of the entire distribution of the KER. The mutual relationship and their advantages are discussed.
Fujii
Mikiya
M
Department of Basic Science, Graduate School of Arts and Sciences, University of Tokyo, Komaba, Tokyo, Japan. futofuji@mns2.c.u-tokyo.ac.jp
Takatsuka
Kazuo
K