Bismesitylmagnesium: a thermally stable and non-nucleophilic carbon-centred base reagent for the efficient preparation of silyl enol ethers.
Bismesitylmagnesium has been established as an accessible, practical, convenient, and non-nucleophilic carbon-centred base reagent for efficient access to silyl enol ethers from a series of ketone substrates at readily utilisable temperatures.
Kerr
William J
WJ
Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, 295 Cathedral Street, Glasgow, Scotland, UK. w.kerr@strath.ac.uk
Watson
Allan J B
AJ
Hayes
Douglas
D
D002244:Carbon / Q000737:chemistry*; D004987:Ethers / Q000737:chemistry*; D017616:Magnesium Compounds / Q000737:chemistry*; D015394:Molecular Structure; D011427:Propiophenones / Q000737:chemistry; D011522:Protons; D013696:Temperature
D004987:Ethers; D017616:Magnesium Compounds; D011427:Propiophenones; D011522:Protons; D002244:Carbon