Intramolecular pi-pi stacking in diaquabis(2-hydroxybenzoato-kappaO)bis(1,10-phenanthroline-kappa2N,N')strontium(II).
In the title compound, [Sr(C7H5O3)2(C12H8N2)2(H2O)2], the Sr(II) ion is located on a twofold rotation axis and assumes a distorted square-antiprism SrN4O4 coordination geometry, formed by two phenanthroline (phen) ligands, two 2-hydroxybenzoate anions and two water molecules. Within the mononuclear complex molecule, intramolecular pi-pi stacking is observed between nearly parallel coordinated phen ligands, while normal intermolecular pi-pi stacking occurs between parallel phen ligands of adjacent complex molecules. Classic O-H...O and weak C-H...O hydrogen bonding helps to stabilize the crystal structure.
Xu
Duan-Jun
DJ
Department of Chemistry, Zhejiang University, People's Republic of China.
Zhang
Bing-Yu
BY
Su
Jian-Rong
JR
Nie
Jing-Jing
JJ
D018360:Crystallography, X-Ray; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D013324:Strontium / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; C525577:diaquabis(2-hydroxybenzoato-kappaO)bis(1,10-phenanthroline-kappa2N,N')strontium(II); D014867:Water; D013324:Strontium