Diaquabis(quinoxaline-2-carboxylato-kappa2N1,O)copper(II).
In the title compound, [Cu(C9H5N2O2)2(H2O)2], the Cu(II) ion lies on an inversion centre and has an elongated centrosymmetric octahedral environment, equatorially trans-coordinated by two N,O-bidentate quinoxaline-2-carboxylate ligands and axially coordinated by two water O atoms. Symmetry-related molecules are linked by strong O-H...O hydrogen bonds, involving the uncoordinated carboxyl O atom of the carboxylate group and the coordinated water molecules, to form a two-dimensional network. Weak intermolecular C-H...N interactions also stabilize the crystal structure.
Feng
Yue
Y
School of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, People's Republic of China.
Liu
Gang
G
Tian
Xiu-Mei
XM
Wang
Ji-De
JD
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D008024:Ligands; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010100:Oxygen / Q000737:chemistry*; D014867:Water / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; C525572:diaquabis(quinoxaline-2-carboxylato-kappa2N1,O)copper(II); D014867:Water; D003300:Copper; D009584:Nitrogen; D010100:Oxygen