Rhodium-catalyzed oxidative coupling of triarylmethanols with internal alkynes via successive C-H and C-C bond cleavages.
The rhodium-catalyzed oxidative coupling of triarylmethanols with internal alkynes effectively proceeds in a 1:2 manner via cleavage of C-H and C-C bonds to produce the corresponding naphthalene derivatives. Addition of tri- or tetraphenylcyclopentadiene as a ligand is crucial for the reaction to occur efficiently.
Uto
Toshihiko
T
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
Shimizu
Masaki
M
Ueura
Kenji
K
Tsurugi
Hayato
H
Satoh
Tetsuya
T
Miura
Masahiro
M
D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D000432:Methanol / Q000031:analogs & derivatives* / Q000737:chemistry*; D015394:Molecular Structure; D009281:Naphthalenes / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D000480:Alkynes; D009281:Naphthalenes; C031721:naphthalene; D012238:Rhodium; D000432:Methanol