Xenon difluoride induced aryl iodide reductive elimination: a simple access to difluoropalladium(II) complexes.
Palladium(II) aryliodo complexes bearing chelating diphosphine ligands react with XeF2, giving iodoarene and rare palladium(II) difluoro complexes. The reaction is general with regard to the aryl group, with even C6F5-I undergoing facile reductive elimination from a Pd center.
Kaspi
Ariela W
AW
School of Chemistry, The Raymond and Beverly Sackler Faculty of Exact Sciences, Tel Aviv University, Tel Aviv, Israel.
Yahav-Levi
Anette
A
Goldberg
Israel
I
Vigalok
Arkadi
A
D018360:Crystallography, X-Ray; D005459:Fluorides / Q000737:chemistry*; D006847:Hydrocarbons, Iodinated / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D014978:Xenon / Q000737:chemistry*
D006847:Hydrocarbons, Iodinated; D009942:Organometallic Compounds; D014978:Xenon; D010165:Palladium; C048007:xenon fluoride; D005459:Fluorides