Total synthesis of (-)-salviasperanol.
The achiral enynone shown cyclized to produce a tricyclic dienone that was converted in six steps to (-)-salviasperanol.
Majetich
George
G
Department of Chemistry, University of Georgia, Athens, Georgia 30602, USA. majetich@chem.uga.edu
Zou
Ge
G
Grove
Jeremy
J
D003500:Cyclization; D004224:Diterpenes / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D010946:Plants, Medicinal / Q000737:chemistry; D027544:Salvia / Q000737:chemistry; D013237:Stereoisomerism
D004224:Diterpenes; C518470:salviasperanol