Bowl-shaped Cu(I) metallamacrocyclic ethylene and carbonyl adducts as structural analogues of organic calixarenes.
Three novel Cu(I) metallacalixarenes with C(2)H(4) and CO legs, in which an anion is accommodated in the inside cavity, were self-assembled by anion templation and have been structurally characterized.
Research Institute for Science and Technology, Kinki University, Kowakae, Higashi-Osaka, Osaka, Japan. maekawa@rist.kindai.ac.jp
Masahiko
M
Maekawa
Hisashi
H
Konaka
Toshie
T
Minematsu
Takayoshi
T
Kuroda-Sowa
Megumu
M
Munakata
Susumu
S
Kitagawa
D047250:Calixarenes / Q000737:chemistry*; D002248:Carbon Monoxide / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005030:Ethylenes / Q000737:chemistry*; D047028:Macrocyclic Compounds / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy / Q000379:methods / Q000592:standards; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012015:Reference Standards
D005030:Ethylenes; D047028:Macrocyclic Compounds; D009942:Organometallic Compounds; D047250:Calixarenes; D003300:Copper; D002248:Carbon Monoxide