Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane-borane adduct.
A four-membered cyclic intramolecular phosphane-borane adduct activates dihydrogen to yield the respective ethylene-bridged zwitterionic phosphonium-hydridoborate system, which reduces benzaldehyde.
Spies
Patrick
P
Organisch-Chemisches Institut, Universität Münster, Corrensstrasse 40, D-48149 Münster, Germany.
Erker
Gerhard
G
Kehr
Gerald
G
Bergander
Klaus
K
Fröhlich
Roland
R
Grimme
Stefan
S
Stephan
Douglas W
DW
D001880:Boranes / Q000737:chemistry*; D003460:Crystallization; D004583:Electrons; D006571:Heterocyclic Compounds / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D013997:Time Factors
D001880:Boranes; D006571:Heterocyclic Compounds; D006859:Hydrogen