Hydrothermal synthesis and structural characterization of the first mixed molybdenum-tungsten capped-keggin polyoxometal complex: {[Co(dien)]4[(AsVO4)MoV8WVI4O33(micro2-OH)3]}.2H2O.
The first polyoxometal complex possessing affirmatory mixed molybdenum-tungsten capped Keggin-type structure has been hydrothermally synthesized.
Yu
Hai-Hui
HH
College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, PR China.
Cui
Xiao-Bing
XB
Cui
Ji-Wen
JW
Kong
Li
L
Duan
Wei-Jie
WJ
Xu
Ji-Qing
JQ
Wang
Tie-Gang
TG
D001151:Arsenic / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D008968:Molecular Conformation; D008982:Molybdenum / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010084:Oxidation-Reduction; D014414:Tungsten / Q000737:chemistry*
D007202:Indicators and Reagents; D009942:Organometallic Compounds; D008982:Molybdenum; D001151:Arsenic; D014414:Tungsten