Construction of N-1H,1H-perfluoroalkylated peptide bonds.
The preparation of a variety of optically pure peptides containing an N-1H,1H-perfluoroalkyl label on a selected backbone amide bond is now possible.
Lu
Changqing
C
Department of Chemistry, Clemson University, Clemson, SC 29634, USA.
DesMarteau
Darryl D
DD
D000478:Alkylation; D005461:Fluorine / Q000737:chemistry*; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D010455:Peptides / Q000138:chemical synthesis / Q000737:chemistry*; D011522:Protons; D012997:Solvents; D013696:Temperature
D010455:Peptides; D011522:Protons; D012997:Solvents; D005461:Fluorine