Hydrothermal synthesis, structures, and photoluminescent properties of benzenepentacarboxylate bridged networks incorporating zinc(II)-hydroxide clusters or zinc(II)-carboxylate layers.
The first coordination compounds of partially or wholly deprotonated benzenepentacarboxylic acid (H5L) were synthesized in the presence or absence of auxiliary 2,2'-bipyridyl (2,2'-bpy) and 1,10-phenanthroline (phen) ligands, and their crystal structures and photoluminescent properties were characterized. Their formulas are [Zn6(mu3-OH)2(L)2(H2O)6]n (1), [Zn5(mu3-OH)2(HL)2(2,2'-bpy)2]n (2), [Zn2(HL)(phen)2(H2O)2]n (3), and [Zn5(L)2(phen)4(H2O)3]n.2nH2O (4). Both 1 and 2 are three-dimensional (3D) zinc(II)-hydroxide cluster based coordination frameworks. 1 contains distorted chairlike hexanuclear Zn6(mu3-OH)2 cluster units as secondary building blocks. Each Zn6(mu3-OH)2 unit connects six others through the three-connected nodes of L5- ligands into a 3D rigid and condensed coordination network, whereas in 2, each pentanuclear Zn5(mu3-OH)2 unit connects the other six ones through the three-connected [HL]4- nodes into a 3D network in the simple cubic packing mode. 3 has two-dimensional (2D) Zn(II)-carboxylate supramolecular layers constructed from a one-dimensional (1D) coordination chain structure by hydrogen bonds of the water and mu5-[HL]4- bridges, whereas 4 has 2D coordination layers composed of Zn(II) and mu8-L5- bridges. The adjacent coordination assemblies in 3 and 4 are further extended by hydrogen bonds and pi...pi interactions into 3D supramolecular architectures. 1-4 are photoluminescent active materials, and their photofluorescent properties are closely related to their intrinsic structure arrangements.
Wang
Jing
J
MOE Key Laboratory of Synthetic Bioinorganic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, PR China.
Lin
Zhuojia
Z
Ou
Yong-Cong
YC
Yang
Nai-Liang
NL
Zhang
Yue-Hua
YH
Tong
Ming-Liang
ML
D001555:Benzene Derivatives / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D049449:Luminescence; D008163:Luminescent Measurements / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry; D010777:Photochemistry; D013696:Temperature; D015032:Zinc / Q000737:chemistry*
D001555:Benzene Derivatives; D002264:Carboxylic Acids; D008024:Ligands; D009942:Organometallic Compounds; D015032:Zinc