The structure of protonated acetone and its dimer: infrared photodissociation spectroscopy from 800 to 4,000 cm-1.
The infrared spectra of protonated acetone and the proton bound acetone dimer are obtained revealing vibrational resonances associated with the shared proton motions, which are in agreement with the predictions from ab initio, MP2, harmonic frequency calculations.
Douberly
Gary E
GE
Department of Chemistry, University of Georgia, Athens, GA, USA. maduncan@uga.edu
Ricks
Allen M
AM
Ticknor
Brian W
BW
Duncan
Michael A
MA
D000096:Acetone / Q000737:chemistry*; D019281:Dimerization; D013058:Mass Spectrometry; D008956:Models, Chemical; D011522:Protons; D011789:Quantum Theory; D013055:Spectrophotometry, Infrared / Q000379:methods; D014732:Vibration
D011522:Protons; D000096:Acetone