Chemo- and enantioselective sulfoxidation of bis(ethylenedithio)-tetrathiafulvalene (BEDT-TTF) into chiral BEDT-TTF-sulfoxide.
Selective sulfoxidation of BEDT-TTF (bis(ethylenedithio)-tetrathiafulvalene) with enantiopure (camphoryl-sulfonyl)oxaziridine derivatives provided the inner monosulfoxide, as demonstrated using single crystal X-ray analysis, with an enantiomeric excess of 44% (up to 74% after recrystallization).
Chas
Marcos
M
Laboratoire Chimie, Ingénierie Moléculaire et Matériaux (CIMMA), UMR 6200 CNRS-Université d'Angers, UFR Sciences, Bât. K, 2 Bd. Lavoisier, 49045 Angers, France.
Lemarié
Margareth
M
Gulea
Mihaela
M
Avarvari
Narcis
N