Nanomechanical characterization of polyaniline coated tobacco mosaic virus nanotubes.
Mechanical properties of polyaniline (PANI) coated self-assembled tobacco mosaic virus (TMV) nanotubes were measured by nanoindentation with an atomic force microscope (AFM) probe. The elastic modulus of PANI/TMV core-shell biocomposite tubes (outer diameter: 19 nm, inner diameter: 4 nm, PANI coating thickness: 0.5 nm) was measured from the AFM force-displacement curves. Structural characteristics of the PANI coating, TMV tube, and their interface were studied by comparing the mechanical properties of individual constituent materials. Results showed that coating with a thin layer of PANI can change the physical and chemical properties of TMV nanotubes. The deformation behavior of such core-shell biocomposite tubes is discussed in conjunction with the obtained AFM force-displacement curves, van der Waals interaction between PANI and TMV, and mechanical properties of individual constituent materials.
Wang
Xinnan
X
Department of Mechanical Engineering, University of South Carolina, Columbia, South Carolina, USA. wang@mail.chem
Niu
Zhongwei
Z
Li
Siqi
S
Wang
Qian
Q
Li
Xiaodong
X
D000814:Aniline Compounds / Q000737:chemistry*; D004548:Elasticity; D008422:Materials Testing; D018625:Microscopy, Atomic Force; D008958:Models, Molecular; D036103:Nanotechnology; D043942:Nanotubes / Q000737:chemistry* / Q000648:ultrastructure; D013314:Stress, Mechanical; D013499:Surface Properties; D014027:Tobacco Mosaic Virus / Q000737:chemistry / Q000648:ultrastructure*
D000814:Aniline Compounds; C416807:polyaniline