Supramolecular isomerism with polythreaded topology based on [Mo8O26]4- isomers.
Two compounds, namely, [Cu(bbi)](2)[Cu(2)(bbi)(2)(delta-Mo(8)O(26))0.5][alpha-Mo(8)O(26)]0.5 (1) and [Cu(bbi)][Cu(bbi)(theta-Mo(8)O(26))0.5] (2), where bbi is 1,1'-(1,4-butanediyl)bis(imidazole), were synthesized under hydrothermal conditions at different pH values. Their crystal structures were determined by X-ray diffraction. Compounds 1 and 2 are supramolecular isomers with a polythreaded topology based on octamolybdate building blocks.
Lan
Ya-Qian
YQ
Institute of Functional Material Chemistry, Key Lab of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China.
Li
Shun-Li
SL
Wang
Xin-Long
XL
Shao
Kui-Zhan
KZ
Su
Zhong-Min
ZM
Wang
En-Bo
EB