On the origin of ferromagnetism in oximato-based [Mn3O]7+ triangles.
DFT calculations reveal the unusual ferromagnetic exchange observed in an oxo-centered Mn(III) triangle may originate from a combination of the 'non-planarity' of the bridging oxime ligands and the non-parallel alignment of the Jahn-Teller axes.
Cano
Joan
J
Departament de Química Inorgànica and Institut de Recerca en Química Teórica i Computacional, Universitat de Barcelona, Diagonal 647, 08028, Barcelona, Spain. joan.cano@qi.ub.es
Cauchy
Thomas
T
Ruiz
Eliseo
E
Milios
Constantinos J
CJ
Stoumpos
Constantinos C
CC
Stamatatos
Theocharis C
TC
Perlepes
Spyros P
SP
Christou
George
G
Brechin
Euan K
EK