Effect of fluorine on palladium-catalyzed cross-coupling reactions of aryl bromides with trifluoromethyl aryl ketones via difluoroenol silyl or monofluoroenol silyl ethers.
Palladium-catalyzed cross-coupling reactions of alpha-aryl-beta,beta-difluoroenol silyl and alpha-aryl-beta-fluoroenol silyl ethers with aryl bromides proceed smoothly with good functional compatibility.
Guo
Yong
Y
Department of Chemistry, University of Idaho, Moscow, Idaho, 83844-2343, USA.
Shreeve
Jean'ne M
JM
D001969:Bromobenzenes / Q000737:chemistry*; D002384:Catalysis; D003432:Cross-Linking Reagents; D004987:Ethers / Q000737:chemistry*; D005030:Ethylenes / Q000737:chemistry; D005461:Fluorine / Q000737:chemistry*; D007659:Ketones / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*
D001969:Bromobenzenes; D003432:Cross-Linking Reagents; D004987:Ethers; D005030:Ethylenes; D007659:Ketones; D012821:Silanes; D005461:Fluorine; D010165:Palladium