Bridging the gap between solution and solid state studies in polyoxometalate chemistry: discovery of a family of [V1M17]-based cages encapsulating two {VVO4} moieties.
A family of polyoxometalates with the composition [H2V3M17O62](6-) features a Dawson-like architecture containing two tetrahedral {VVO4} templates rather than main group hetero-anions ({PO4} or {SO4} etc.) typically associated with classical heteropolyacids, situated within a mixed-metal {MVI17VIVO54} cage and these clusters were first discovered using mass spectrometry.
Miras
Haralampos N
HN
Department of Chemistry, University of Glasgow, University Avenue, UKG12 8QQ.
Long
De-Liang
DL
Kögerler
Paul
P
Cronin
Leroy
L
D018360:Crystallography, X-Ray; D007202:Indicators and Reagents; D008280:Magnetics; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D011522:Protons; D021241:Spectrometry, Mass, Electrospray Ionization; D014639:Vanadium / Q000737:chemistry*
D007202:Indicators and Reagents; D009942:Organometallic Compounds; D011522:Protons; D014639:Vanadium