Chiral N-heterocyclic carbene--Pd(0)-catalyzed asymmetric diamination of conjugated dienes and triene.
Studies show that a variety of conjugated dienes and triene can be enantioselectively diaminated using di-tert-butyldiaziridinone as nitrogen source and chiral N-heterocyclic carbene-Pd(0) complex as catalyst in good enantioselectivity (62-91% ee) with high regio- and diastereoselectivity.
Xu
Liang
L
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
Shi
Yian
Y
D000475:Alkenes / Q000737:chemistry*; D000586:Amination; D001388:Aziridines / Q000737:chemistry; D002384:Catalysis; D006571:Heterocyclic Compounds / Q000737:chemistry*; D006838:Hydrocarbons / Q000737:chemistry; D007659:Ketones / Q000138:chemical synthesis / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
D000475:Alkenes; D001388:Aziridines; D006571:Heterocyclic Compounds; D006838:Hydrocarbons; D007659:Ketones; C527442:di-tert-butyldiaziridinone; C030011:carbene; D010165:Palladium; D008697:Methane