Hydrogen transfer from guest molecule to radical in adjacent hydrate-cages.
Electron spin resonance measurement of gamma-ray-irradiated propane hydrates shows that the normal propyl radical withdraws hydrogen from the adjacent propane molecule through the hexagonal planes of the hydrate cage without water molecule bridging.
Ohgaki
Kazunari
K
Division of Chemical Engineering, Graduate School of Engineering Science, Osaka University, 1-3 Machikaneyama, Toyonaka, Osaka 560-8531, Japan. ohgaki@cheng.es.osaka-u.ac.jp
Nakatsuji
Kentaro
K
Takeya
Kei
K
Tani
Atsushi
A
Sugahara
Takeshi
T
D004578:Electron Spin Resonance Spectroscopy; D005609:Free Radicals / Q000737:chemistry / Q000528:radiation effects; D005720:Gamma Rays; D006859:Hydrogen / Q000737:chemistry* / Q000528:radiation effects; D011407:Propane / Q000737:chemistry* / Q000528:radiation effects; D013696:Temperature; D013997:Time Factors; D014867:Water / Q000737:chemistry
D005609:Free Radicals; D014867:Water; D006859:Hydrogen; D011407:Propane