title: Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.
abstract: In a new type of reactivity for sodium TMP-zincate [(TMEDA)NaZn((t)Bu)(2)(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-alpha-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H).
authors: WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK.
authors: David R
authors: DR
authors: Armstrong
authors: William
authors: W
authors: Clegg
authors: Sophie H
authors: SH
authors: Dale
authors: Joaquín
authors: J
authors: García-Alvarez
authors: Ross W
authors: RW
authors: Harrington
authors: Eva
authors: E
authors: Hevia
authors: Gordon W
authors: GW
authors: Honeyman
authors: Alan R
authors: AR
authors: Kennedy
authors: Robert E
authors: RE
authors: Mulvey
authors: Charles T
authors: CT
authors: O'Hara