Synthetic iron-oxo "diamond core" mimics structure of key intermediate in methane monooxygenase catalytic cycle.
Brunold
Thomas C
TC
Department of Chemistry, University of Wisconsin, 1101 University Avenue, Madison, WI 53706, USA. brunold@chem.wisc.edu
D001419:Bacteria / Q000378:metabolism; D001671:Biochemistry / Q000379:methods; D002384:Catalysis; D003577:Cytochrome P-450 Enzyme System / Q000737:chemistry; D005609:Free Radicals; D007501:Iron / Q000737:chemistry*; D008024:Ligands; D008954:Models, Biological; D008956:Models, Chemical; D008968:Molecular Conformation; D010100:Oxygen / Q000737:chemistry*; D010105:Oxygenases / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry; D013053:Spectrophotometry
D005609:Free Radicals; D008024:Ligands; D011166:Porphyrins; D003577:Cytochrome P-450 Enzyme System; D007501:Iron; D010105:Oxygenases; C021555:methane monooxygenase; D010100:Oxygen