Solvothermal vs. bench-top reactions: control over the formation of discrete complexes and coordination polymers.
The formation of discrete complexes [M(mcoe)2S2] (M = Cu, Ni; S = MeOH, H2O) vs. a nitroso-bridged ferromagnetically-coupled Cu(II) coordination polymer [Cu(mcoe)2] is influenced by the use of solvothermal reaction conditions.
Chesman
Anthony S R
AS
School of Chemistry, Monash University, Clayton, VIC 3800, Australia.
Turner
David R
DR
Price
David J
DJ
Moubaraki
Boujemaa
B
Murray
Keith S
KS
Deacon
Glen B
GB
Batten
Stuart R
SR