An efficient synthesis of 7-functionalized 7-deazapurine beta-D- Or beta-L-ribonucleosides: glycosylation of pyrrolo[2,3-D]pyrimidines with 1-O-acetyl-2,3,5-tri-O-benzoyl-D-Or L-ribofuranose.
The glycosylation reaction performed with 7-halogenated 7-deazapurines employing commercially available 1-O-acetyl-2,3,5-tri-O-benzoyl-D- or L-ribofuranoses is described.
Peng
Xiaohua
X
Laboratorium für Organische und Bioorganische Chemie, Universität Osnabrück, Osnabrück, Germany.
Seela
Frank
F
D002384:Catalysis; D006031:Glycosylation; D009005:Monosaccharides / Q000737:chemistry*; D010165:Palladium; D011687:Purines / Q000138:chemical synthesis* / Q000737:chemistry; D011743:Pyrimidines / Q000737:chemistry*; D012263:Ribonucleosides / Q000138:chemical synthesis* / Q000737:chemistry
C511842:1-O-acetyl-2,3,5-tri-O-benzoyl-D-ribofuranose; C512929:7-deazapurine; D009005:Monosaccharides; D011687:Purines; D011743:Pyrimidines; D012263:Ribonucleosides; D010165:Palladium