title: Bridging the gap between solution and solid state studies in polyoxometalate chemistry: discovery of a family of [V1M17]-based cages encapsulating two {VVO4} moieties.
abstract: A family of polyoxometalates with the composition [H2V3M17O62](6-) features a Dawson-like architecture containing two tetrahedral {VVO4} templates rather than main group hetero-anions ({PO4} or {SO4} etc.) typically associated with classical heteropolyacids, situated within a mixed-metal {MVI17VIVO54} cage and these clusters were first discovered using mass spectrometry.
authors: Department of Chemistry, University of Glasgow, University Avenue, UKG12 8QQ.
authors: Haralampos N
authors: HN
authors: Miras
authors: De-Liang
authors: DL
authors: Long
authors: Paul
authors: P
authors: Kögerler
authors: Leroy
authors: L
authors: Cronin
mesh_terms: D018360:Crystallography, X-Ray; D007202:Indicators and Reagents; D008280:Magnetics; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D010084:Oxidation-Reduction; D011522:Protons; D021241:Spectrometry, Mass, Electrospray Ionization; D014639:Vanadium / Q000737:chemistry*
chemical_list: D007202:Indicators and Reagents; D009942:Organometallic Compounds; D011522:Protons; D014639:Vanadium