Assessment of Pb-slag, MSWI bottom ash and boiler and fly ash for using as a fine aggregate in cement mortar.
Three types of wastes, metallurgical slag from Pb production (SLG), the sand-sized (0.1-2 mm) fraction of MSWI bottom ash from a grate furnace (SF), and boiler and fly ash from a fluidised bed incinerator (BFA), were characterized and used to replace the fine aggregate during preparation of cement mortar. The chemical and mineralogical behaviour of these wastes along with the reactivities of the wastes with lime and the hydration behaviour of ordinary Portland cement paste with and without these wastes added were evaluated by various chemical and instrumental techniques. The compressive strengths of the cement mortars containing waste as a partial substitution of fine aggregates were also assessed. Finally, leaching studies of the wastes and waste containing cement mortars were conducted. SLG addition does not show any adverse affect during the hydration of cement, or on the compressive strengths behaviours of mortars. Formation of expansive products like ettringite, aluminium hydroxide and H2 gas due to the reaction of some constituents of BFA and SF with alkali creates some cracks in the paste as well as in the cement mortars, which lower the compressive strength of the cement mortars. However, utilization of all materials in cement-based application significantly improves the leaching behaviour of the majority of the toxic elements compared to the waste as such.
Saikia
Nabajyoti
N
Department of Chemical Engineering, Katholieke Universiteit Leuven, de Croylaan 46, 3001 Leuven, Belgium. saikianj@yahoo.co.uk
Cornelis
Geert
G
Mertens
Gilles
G
Elsen
Jan
J
Van Balen
Koenraad
K
Van Gerven
Tom
T
Vandecasteele
Carlo
C
D001151:Arsenic / Q000032:analysis; D017610:Calcium Compounds / Q000737:chemistry; D002244:Carbon / Q000032:analysis; D060729:Coal Ash; D019245:Compressive Strength; D003252:Construction Materials; D017745:Incineration; D007220:Industrial Waste / Q000032:analysis; D007854:Lead; D008669:Metallurgy; D008670:Metals / Q000032:analysis; D008903:Minerals / Q000032:analysis; D010087:Oxides / Q000032:analysis / Q000737:chemistry; D010316:Particle Size; D052638:Particulate Matter / Q000032:analysis; D014874:Water Pollutants, Chemical / Q000032:analysis
D017610:Calcium Compounds; D060729:Coal Ash; D007220:Industrial Waste; D008670:Metals; D008903:Minerals; D010087:Oxides; D052638:Particulate Matter; D014874:Water Pollutants, Chemical; D007854:Lead; D002244:Carbon; C016538:lime; D001151:Arsenic