Palladium-catalyzed stereospecific substitution of alpha,beta-unsaturated gamma,delta-epoxy esters by alcohols with double inversion of configuration: synthesis of 4-alkoxy-5-hydroxy-2-pentenoates.
Yu
Xiao-Qiang
XQ
Division of Chemistry, Graduate School of Science, Hokkaido University, 060-0810 Sapporo, Japan.
Yoshimura
Fumihiko
F
Ito
Fumito
F
Sasaki
Minoru
M
Hirai
Atsushi
A
Tanino
Keiji
K
Miyashita
Masaaki
M
D000438:Alcohols / Q000737:chemistry*; D002384:Catalysis; D004852:Epoxy Compounds / Q000737:chemistry*; D004952:Esters / Q000737:chemistry*; D008968:Molecular Conformation; D010165:Palladium / Q000737:chemistry*; D010422:Pentanones / Q000138:chemical synthesis* / Q000737:chemistry; D012680:Sensitivity and Specificity; D013237:Stereoisomerism
D000438:Alcohols; D004852:Epoxy Compounds; D004952:Esters; D010422:Pentanones; D010165:Palladium