Tandem RCM-isomerization approach to glycals of desoxyheptoses from a common precursor.
Ring closing metathesis and tandem RCM-isomerization have been applied to the synthesis of six- to eight-membered oxacycles, starting from a common precursor. The products of the tandem RCM-isomerization sequence are glycals of 3-deoxyheptoses of varying ring size.
Schmidt
Bernd
B
Institut fuer Chemie, Organische Chemie II, Universitaet Potsdam, Karl-Liebknecht-Strasse 24-25, D-14476 Golm, Germany. bernd.schmidt@uni-potsdam.de
Biernat
Anne
A
D003500:Cyclization; D004988:Ethers, Cyclic / Q000138:chemical synthesis* / Q000737:chemistry; D006539:Heptoses / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
D004988:Ethers, Cyclic; D006539:Heptoses