Multicomponental fluorimetric determination of aluminium, gallium and indium.
For the fast characteristics of mixtures of Aluminium, Gallium and Indium the fluorimetric evaluation in the form of complexes with 8-Hydroxyquinoline-5-sulphonic acid is described at selected pH. The highly collinear correlated fluorescent spectra and their first derivation were evaluated under various experimental conditions with the Multiple Linear Regression (MLR), Partial Least Squares (PLS) methods and Kalman filtering. When comparing the results, the PLS gives the least relative prediction errors under optimal conditions, 5.6-15.9% for the concentration range of Al 0.025-0.2 microg cm(-3), Ga 0.1-0.8 microgcm(-3) and In 0.1-0.8 microg cm(-3) in the mixture.
Vojta
Simon
S
Institute of Environmental Protection, Faculty of Chemistry, Brno University of Technology, Purkynova 118, Brno, Czech Republic. vojta@fch.vutbr.cz
Jancár
Ludek
L
Sommer
Lumír
L