Part 3. Triethylborane-air: a suitable initiator for intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins.
Under carefully controlled conditions, the triethylborane-air combination proves to be an efficient radical initiator that allows intermolecular radical additions of S-2-oxoalkyl-thionocarbonates (S-xanthates) to olefins. Depending on both the structures of the xanthate and the olefin, the addition process can be achieved at room temperature or slightly higher.
Boivin
Jean
J
Institut de Chimie des Substances Naturelles, C,N,R,S,, Avenue de la Terrasse, 91198 Gif-sur-Yvette, France. jean.boivin@icsn.cnrs-gif.fr
Nguyen
Van Tai
VT