title: Direct synthesis of porous organosilicas containing chiral organic groups within their framework and a new analytical method for enantiomeric purity of organosilicas.
abstract: Organosilica porous solids containing chiral organic moieties in the framework with an enantiomeric purity of 95% ee, estimated by eluting organic constituent units from chiral organosilicas, were synthesized from a newly designed chiral (R)-(+)-1,2-bis(trimethoxysilyl)phenylethane precursor via a surfactant-mediated self-assembly approach.
authors: Toyota Central R&D Labs., Inc., Nagakute, Aichi 480-1192, Japan. inagaki@mosk.tytlabs.co.jp
authors: Shinji
authors: S
authors: Inagaki
authors: Shiyou
authors: S
authors: Guan
authors: Qihua
authors: Q
authors: Yang
authors: Mahendra P
authors: MP
authors: Kapoor
authors: Toyoshi
authors: T
authors: Shimada