Transamination chemistry of sodium TMP-zincate: synthesis and crystal structure of a chiral amidozincate.
In a new type of reactivity for sodium TMP-zincate [(TMEDA)NaZn((t)Bu)(2)(TMP)] (1), transamination reactions with the amines diisopropylamine, DA(H), hexamethyldisilazane, HMDS(H) and chiral (R)-N-benzyl-alpha-methylbenzylamine have produced new sodium amido-di-tert-butyl zincates (all structurally characterised) with concomitant loss of TMP(H).
Armstrong
David R
DR
WestCHEM, Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK.
Clegg
William
W
Dale
Sophie H
SH
García-Alvarez
Joaquín
J
Harrington
Ross W
RW
Hevia
Eva
E
Honeyman
Gordon W
GW
Kennedy
Alan R
AR
Mulvey
Robert E
RE
O'Hara
Charles T
CT