title: 4-(N,N-diethylamino) benzaldehyde thiosemicarbazone in the spectrophotometric determination of palladium.
abstract: 4-(N,N-diethylamino)benzaldehyde thiosemicarbazone(DEABT) is proposed as a sensitive and selective analytical reagent for the spectrophotometric determination of palladium(II). The reagent reacts with palladium (II) in a potassium hydrogen phthalate-hydrochloric acid buffer of pH 3.0, to form a yellow complex. Beer's law is obeyed in the concentration range up to 3.60 microgmL(-1). The optimum concentration range for minimum photometric error as determined by Ringbom plot method is 0.36 - 3.24 microg mL(-1). The yellow Pd(II)-DEABT complex shows a maximum absorbance at 408 nm, with molar absorptivity of 3.33 x 10(4) dm3 mol(-1) cm(-1) and Sandell's sensitivity of the complex from Beer's data, for D = 0.001, is 0.0032 microg cm(-2). The composition of the Pd(II)-DEABT complex is found to be 1:2 (M:L). The interference of various cations and anions in the method were studied. The proposed method was successfully used for the determination of Pd(II) in alloys, catalysts, complexes and model mixtures with a fair degree of accuracy.
authors.affiliation: Department of Chemistry, National Institute of Technology Karnataka, Surathkal, Srinivasnagar - 575 025, Karnataka, India.
authors.forename: P
authors.initials: P
authors.lastname: Parameshwara
authors.forename: J
authors.initials: J
authors.lastname: Karthikeyan
authors.forename: A Nityananda
authors.initials: AN
authors.lastname: Shetty
authors.forename: Prakash
authors.initials: P
authors.lastname: Shetty
mesh_terms: D001547:Benzaldehydes / Q000737:chemistry*; D004048:Diethylamines / Q000737:chemistry*; D007202:Indicators and Reagents; D010165:Palladium / Q000032:analysis*; D012663:Semicarbazides / Q000737:chemistry*; D013053:Spectrophotometry / Q000379:methods
chemical_list: D001547:Benzaldehydes; D004048:Diethylamines; D007202:Indicators and Reagents; D012663:Semicarbazides; C055506:4-(diethylamino)benzaldehyde; C010059:carbamylhydrazine; D010165:Palladium; C005151:thiosemicarbazide; C032175:benzaldehyde