title: Quantum dynamics of an excited alkali atom in a noble gas cluster: lithium attached to a helium cluster.
abstract: An alkali atom-noble gas cluster system is considered as a model for solvation effects in optical spectra, within a quantum-classical description based on the density operator of a many-atom system and its partial Wigner transform. This leads to an eikonal-time-dependent molecular orbital treatment suitable for a time-dependent description of the coupling of light emission and atom dynamics in terms of the time-dependent electric dipole of the whole system. As an application, we consider an optically excited lithium atom as the dopant in a helium cluster at 0.5 K. We describe the motions of the excited Li atom interacting with a cluster of He atoms and calculate the time-dependent electric dipole of the Li-He(99) system during the dynamics. The electronic Hamiltonian is taken as a sum of three-body Li-He diatomic potentials including electronic polarization and repulsion, with l-dependent atomic pseudopotentials for Li and He, while we use a modified pair potential for He-He. The calculations involve the coupling of 12 quantum states with 300 classical degrees of freedom. We present results for the dynamics and spectra of a Li atom interacting with a model cluster surface of He atoms and also interacting with a droplet of He. We have found that the Li atom is attracted or repulsed from the He surface, depending on the orientation of its 2p orbitals. The spectra and dynamics of Li inside and at the surface of a cluster are found to be strongly dependent on its electronic states, its velocity direction, and whether light is present during emission or not.
authors.affiliation: Quantum Theory Project, Departments of Chemistry and Physics, University of Florida, Gainesville, Florida 32611-8435, USA.
authors.forename: Alexander B
authors.initials: AB
authors.lastname: Pacheco
authors.forename: Brian
authors.initials: B
authors.lastname: Thorndyke
authors.forename: Andrés
authors.initials: A
authors.lastname: Reyes
authors.forename: David A
authors.initials: DA
authors.lastname: Micha