Effective nonenzymatic kinetic resolution of racemic m-nitro-substituted inherently chiral aminocalix[4]arenes.
Effective nonenzymatic kinetic resolution of racemic m-nitro-substituted inherently chiral aminocalix[4]arenes with Boc-l-proline as the acylating reagent is described, which provides an efficient and convenient method for the enantioselective synthesis of meta-substituted aminocalix[4]arenes.
Xu
Zhen-Xiang
ZX
Beijing National Laboratory for Molecular Sciences, Center for Chemical Biology, Institute of Chemistry, Graduate School, Chinese Academy of Sciences, Beijing 100049, China.
Zhang
Chun
C
Yang
Yong
Y
Chen
Chuan-Feng
CF
Huang
Zhi-Tang
ZT
D047250:Calixarenes / Q000737:chemistry*; D002384:Catalysis; D007700:Kinetics; D015394:Molecular Structure; D009574:Nitro Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011392:Proline / Q000031:analogs & derivatives / Q000737:chemistry; D013237:Stereoisomerism
D009574:Nitro Compounds; D047250:Calixarenes; D011392:Proline