Group VI metal aminoborylene complex-catalyzed demercuration reactions of bis(alkynyl)mercurials.
The first catalytic application of the Group VI metal borylene complexes [(CO)(5)M[double bond]BN(SiMe(3))(2)] involves the demercuration reaction of bis(alkynyl)mercurials, [Hg(C[triple bond]CR)(2)], with formation of a series of buta-1,3-diynes.
Apostolico
Leonardo
L
Institut für Anorganische Chemie, Julius-Maximilians-Universität, Würzburg, Am Hubland, 97074, Würzburg, Germany.
Braunschweig
Holger
H
Crawford
Andrew G
AG
Herbst
Thomas
T
Rais
Daniela
D