title: Raman spectroscopy for the characterization of the polymerization rate in an acrylamide-based photopolymer.
abstract: Investigations of polymerization rates in an acrylamide-based photopolymer are presented. The polymerization rate for acrylamide and methylenebisacrylamide was determined by monitoring the changes in the characteristic vibrational peaks at 1284 and 1607 cm(-1) corresponding to the bending mode of the CH bond and CC double bonds of acrylamide and in the characteristic peak at 1629 cm(-1) corresponding to the carbon-carbon double bond of methylenebisacrylamide using Raman spectroscopy. To study the dependence of the polymerization rate on intensity and to find the dependence parameter, the polymerization rate constant is measured at different intensities. A comparison with a commercially available photopolymer shows that the polymerization rate in this photopolymer is much faster.
authors.affiliation: School of Physics, Dublin Institute of Technology, Dublin 8, Ireland. j.raghavendra@dit.ie
authors.forename: Raghavendra
authors.initials: R
authors.lastname: Jallapuram
authors.forename: Izabela
authors.initials: I
authors.lastname: Naydenova
authors.forename: Hugh J
authors.initials: HJ
authors.lastname: Byrne
authors.forename: Suzanne
authors.initials: S
authors.lastname: Martin
authors.forename: Robert
authors.initials: R
authors.lastname: Howard
authors.forename: Vincent
authors.initials: V
authors.lastname: Toal
mesh_terms: D020106:Acrylamide / Q000737:chemistry*; D000465:Algorithms; D006244:Hardness; D008422:Materials Testing / Q000379:methods*; D015203:Reproducibility of Results; D012542:Scattering, Radiation; D012680:Sensitivity and Specificity; D013059:Spectrum Analysis, Raman / Q000379:methods*
chemical_list: D020106:Acrylamide