title: Intermolecular Cope-type hydroamination of alkynes using hydrazines.
abstract: Metal-free, intermolecular hydroaminations are performed upon heating aryl acetylenes and MeNHNH(2) at 140 degrees C, with preferential formation of the linear, "anti-Markovnikov" hydrazones.
authors.affiliation: Centre for Catalysis Research and Innovation, Department of Chemistry, University of Ottawa, Ottawa, ON, Canada.
authors.forename: Pamela H
authors.initials: PH
authors.lastname: Cebrowski
authors.forename: Jean-Grégoire
authors.initials: JG
authors.lastname: Roveda
authors.forename: Joseph
authors.initials: J
authors.lastname: Moran
authors.forename: Serge I
authors.initials: SI
authors.lastname: Gorelsky
authors.forename: André M
authors.initials: AM
authors.lastname: Beauchemin
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D000586:Amination; D006834:Hydrazines / Q000737:chemistry*; D013816:Thermodynamics
chemical_list: D000480:Alkynes; D006834:Hydrazines; C029424:hydrazine