title: Doping-induced structure variation of 1,3-cyclohexane- bis(methylamine)-templated zinc-phosphorus open structures.
abstract: By using 1,3-cyclohexane-bis(methylamine) (CHBMA) as the template, a novel zinc phosphatophosphite (TJPU-3) with extra-large 20-ring channels was synthesized. Cobalt doping produced a bimetallic phosphite (TJPU-6) with 12-ring apertures. While the templates sit in the cis configuration in TJPU-3, they are in the trans configuration in TJPU-6. This result has the potential for separation and recognition of CHBMA isomers.
authors.affiliation: Institute of Nanostructured Materials, College of Materials Science and Chemical Engineering and Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University, Tianjin 300160, China.
authors.forename: Yang
authors.initials: Y
authors.lastname: Yang
authors.forename: Yongnan
authors.initials: Y
authors.lastname: Zhao
authors.forename: Jianguo
authors.initials: J
authors.lastname: Yu
authors.forename: Shizhen
authors.initials: S
authors.lastname: Wu
authors.forename: Ruji
authors.initials: R
authors.lastname: Wang