The enamine intermediate may not be universal to thiamine catalysis.
Amara
Patricia
P
Laboratoire de Dynamique Moléculaire, Institut de Biologie Structurale Jean-Pierre Ebel, CEA; CNRS; UJF, 41 rue Jules Horowitz, 38027 Grenoble, France, Fax: (+33)4-3878-4217.
Fdez Galván
Ignacio
I
Fontecilla-Camps
Juan C
JC
Field
Martin J
MJ
D000588:Amines / Q000737:chemistry*; D002245:Carbon Dioxide / Q000737:chemistry; D002384:Catalysis; D003653:Decarboxylation; D005609:Free Radicals / Q000138:chemical synthesis / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D050743:Pyruvate Synthase / Q000737:chemistry; D019289:Pyruvic Acid / Q000737:chemistry; D013831:Thiamine / Q000737:chemistry*
D000588:Amines; D005609:Free Radicals; D002245:Carbon Dioxide; D019289:Pyruvic Acid; D050743:Pyruvate Synthase; D013831:Thiamine