title: Reversible addition of water to the high-hydride-content cluster [Rh6(PiPr3)6H12][BArF4]2. Synthesis and Structure of [Rh6PiPr3)6H11(OH)][BArF4]2.
abstract: The hydroxyhydrido salt [Rh(6)(P(i)Pr(3))(6)H(11)(OH)][BArF(4)](2) results from the addition of water to [Rh(6)(P(i)Pr(3))(6)H(12)][BArF(4)](2). This reaction is reversible, and the addition of dihydrogen to [Rh(6)(P(i)Pr(3))(6)H(11)(OH)][BArF(4)](2) results in the elimination of water and the regeneration of the hydride cluster.
authors.affiliation: Inorganic Research Laboratory, South Parks Road, Oxford, U.K. OX1 3QR, and Department of Chemistry, University of Bath, Bath, U.K. BA2 7AY.
authors.forename: Thomas M
authors.initials: TM
authors.lastname: Douglas
authors.forename: Simon K
authors.initials: SK
authors.lastname: Brayshaw
authors.forename: Paul R
authors.initials: PR
authors.lastname: Raithby
authors.forename: Andrew S
authors.initials: AS
authors.lastname: Weller