title: Persistent organic pollutants (PCBs and DDTs) in small size specimens of bluefin tuna (Thunnus thynnus) from the Mediterranean Sea (Ionian Sea).
abstract: The concentration levels and pattern distribution of polychlorinated biphenyls (PCBs) and organochlorine pesticides (DDTs), were investigated in liver of small size specimens of bluefin tuna (Thunnus thynnus) from Mediterranean Sea (Ionian Sea). PCB concentrations (average: 526 ng g(-1) lipid wt) were comparable with DDT levels (average: 435 ng g(-1) lipid wt). The specific analysis of PCB congeners revealed a profile dominated by hexa-, penta- and heptachlorinated congeners, while among DDTs, the compounds with the higher concentration was p,p'-DDE, constituting 91.9% of the total DDT. The total 2,3,7,8-TCDD toxic equivalent (TEQs) of coplanar PCBs, including mono- and non-ortho congeners, was 0.55 pg g(-1) wet weight with. The congeners with highest TEQs values were non-ortho congeners followed by mono-ortho ones.
authors.affiliation: Pharmacological-Biological Department, Chemistry and Biochemistry Section, Veterinary Medicine Faculty, University of Bari- Strada Prov. le per Casamassima Km 3, Valenzano Ba, Italy.
authors.forename: M M
authors.initials: MM
authors.lastname: Storelli
authors.forename: E
authors.initials: E
authors.lastname: Casalino
authors.forename: G
authors.initials: G
authors.lastname: Barone
authors.forename: G O
authors.initials: GO
authors.lastname: Marcotrigiano
mesh_terms: D000818:Animals; D002853:Chromatography, Liquid; D003634:DDT / Q000032:analysis*; D004781:Environmental Exposure / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry; D008099:Liver / Q000737:chemistry; D013058:Mass Spectrometry; D008522:Mediterranean Sea; D011078:Polychlorinated Biphenyls / Q000032:analysis*; D014413:Tuna
chemical_list: D003634:DDT; D011078:Polychlorinated Biphenyls