title: Identification of characteristic aroma components of Thai fried chili paste.
abstract: Three forms of Thai fried chili pastes (CP) were prepared, consisting of an unheated CP (UH-CP), a CP heated at 100 degrees C for 25 min (H25-CP, typical product), and a CP excessively heated for 50 min (H50-CP). The potent odorants in the CPs were investigated by two gas chromatography-olfactometry methods: dynamic headspace dilution analysis (DHDA) and aroma extract dilution analysis (AEDA). DHDA revealed that the predominant odorants in heated CPs were mainly sulfur-containing compounds, followed by lipid-derived compounds, Strecker aldehydes, and Maillard reaction products. Dimethyl sulfide, allyl mercaptan, 2- (or 3-) methylbutanal, ally methyl sulfide, 2,3-butanedione, 3,3'-thiobis(1-propene), and methyl propyl disulfide were among the most potent headspace odorants detected by DHDA. By AEDA, 2-vinyl-4 H-1,3-dithiin and diallyl trisulfide had the highest FD factors in H25-CP. On the basis of their high FD factors by both GCO methods, the predominant odorants in H25-CP were 3-vinyl-4 H-1,2-dithiin, allyl methyl disulfide, and allyl methyl trisulfide. Furthermore, dimethyl trisulfide and diallyl disulfide had the highest odor activity values in H25-CP, suggesting that these were also potent odorants in CP. In addition, methional, 3-methylbutanoic acid, 4-hydroxy-2,5-dimethyl-3-(2 H)-furanone, and 3-hydroxy-4,5-dimethyl-2( 5H)-furanone (sotolon) were indicated as potent thermally derived odorants of H25-CP.
authors.affiliation: Department of Food Science and Technology, Kasetsart University, 50 Phahonyothin Road, Chatuchak, Bangkok 10900, Thailand.
authors.forename: Premsiri
authors.initials: P
authors.lastname: Rotsatchakul
authors.forename: Siree
authors.initials: S
authors.lastname: Chaiseri
authors.forename: Keith R
authors.initials: KR
authors.lastname: Cadwallader
mesh_terms: D000447:Aldehydes / Q000032:analysis; D000490:Allium / Q000737:chemistry*; D002212:Capsicum / Q000737:chemistry*; D002849:Chromatography, Gas; D005223:Fats / Q000032:analysis; D005396:Fish Products / Q000032:analysis; D006358:Hot Temperature; D009812:Odorants / Q000032:analysis*; D012903:Smell; D013457:Sulfur Compounds / Q000032:analysis; D013785:Thailand
chemical_list: D000447:Aldehydes; D005223:Fats; D013457:Sulfur Compounds