Tuning mechanism in a two-component columnar host system composed of 1,2-diphenylethylenediamine and 1,1'-binaphthyl-2,2'-dicarboxylic acid.
In a two-component columnar host system composed of racemic (rac)-1,2-diphenylethylenediamine and rac-1,1'-binaphthyl-2,2'-dicarboxylic acid, a cavity tuning mechanism resulted from changes in the structure of the columns using a specific combination of the following four molecules: (1R,2R)-1, (1S,2S)-1, (R)-2, and (S)-2.
Imai
Yoshitane
Y
Department of Applied Chemistry, Faculty of Science and Engineering, Kinki University, 3-4-1 Kowakae, Higashi-Osaka 577-8502, Japan. y-imai@apch.kindai.ac.jp
Kawaguchi
Kakuhiro
K
Murata
Katuzo
K
Sato
Tomohiro
T
Kuroda
Reiko
R
Matsubara
Yoshio
Y
D018360:Crystallography, X-Ray; D003998:Dicarboxylic Acids / Q000737:chemistry*; D005029:Ethylenediamines / Q000737:chemistry*; D008968:Molecular Conformation; D015394:Molecular Structure; D009281:Naphthalenes / Q000737:chemistry*; D013237:Stereoisomerism
C527917:1,1'-binaphthyl-2,2'-dicarboxylic acid; D003998:Dicarboxylic Acids; D005029:Ethylenediamines; D009281:Naphthalenes; C007305:1,2-dianilinoethane