Total synthesis of (+)-aquaticol by biomimetic phenol dearomatization: double diastereofacial differentiation in the diels-alder dimerization of orthoquinols with a c(2)-symmetric transition state.
Gagnepain
Julien
J
Institut Européen de Chimie et Biologie, 2 rue Robert Escarpit, 33607 Pessac Cedex, France, Fax: (+33)5-4000-2215.
Castet
Frédéric
F
Quideau
Stéphane
S
D032701:Biomimetics; D003500:Cyclization; D019281:Dimerization; D006873:Hydroquinones / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D010636:Phenols / Q000737:chemistry*; D013237:Stereoisomerism; D014315:Triterpenes / Q000138:chemical synthesis* / Q000737:chemistry
D006873:Hydroquinones; D010636:Phenols; D014315:Triterpenes; C409886:aquaticol