title: Modeling cation diffusion in compacted water-saturated sodium bentonite at low ionic strength.
abstract: Sodium bentonites are used as barrier materials for the isolation of landfills and are under consideration for a similar use in the subsurface storage of high-level radioactive waste. The performance of these barriers is determined in large part by molecular diffusion in the bentonite pore space. We tested two current models of cation diffusion in bentonite against experimental data on the relative apparent diffusion coefficients of two representative cations, sodium and strontium. On the "macropore/nanopore" model, solute molecules are divided into two categories, with unequal pore-scale diffusion coefficients, based on location: in macropores or in interlayer nanopores. On the "surface diffusion" model, solute molecules are divided into categories based on chemical speciation: dissolved or adsorbed. The macropore/nanopore model agrees with all experimental data at partial montmorillonite dry densities ranging from 0.2 (a dilute bentonite gel) to 1.7 kg dm(-3) (a highly compacted bentonite with most of its pore space located in interlayer nanopores), whereas the surface diffusion model fails at partial montmorillonite dry densities greater than about 1.3 kg dm(-3).
authors.affiliation: Civil and Environmental Engineering, University of California, Berkeley, California 94720-1710, USA. ibourg@nature.berkeley.edu
authors.forename: Ian C
authors.initials: IC
authors.lastname: Bourg
authors.forename: Garrison
authors.initials: G
authors.lastname: Sposito
authors.forename: Alain C M
authors.initials: AC
authors.lastname: Bourg
mesh_terms: D001546:Bentonite / Q000737:chemistry*; D002412:Cations / Q000737:chemistry*; D004058:Diffusion; D004784:Environmental Monitoring / Q000379:methods; D008962:Models, Theoretical; D012964:Sodium / Q000737:chemistry*; D013324:Strontium / Q000032:analysis
chemical_list: D002412:Cations; D001546:Bentonite; D012964:Sodium; D013324:Strontium