title: Sorption and degradation of bisphenol A by aerobic activated sludge.
abstract: Laboratory-scale batch experiments were conducted to investigate the sorption and degradation of bisphenol A (BPA) at microg/L range in an aerobic activated sludge system. The sorption isotherms and thermodynamics indicated that the sorption of BPA on sludge was mainly a physical process in which partitioning played a dominating role. The values of sorption coefficient Koc were between 621 and 736 L/kg in the temperature range of 10-30 degrees C. Both mixed liquor suspended solid (MLSS) and temperature influenced BPA sorption on sludge. The degradation of BPA by acclimated activated sludge could be described by first-order reaction equation with the first-order degradation rate constant of 0.80 h(-1) at 20 degrees C. The decrease of initial COD concentration and the increase of MLSS concentration and temperature enhanced BPA degradation rate. The removal of BPA in the activated sludge system was characterized by a quick sorption on the activated sludge and subsequent biodegradation.
authors.affiliation: State Key laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China.
authors.forename: Junming
authors.initials: J
authors.lastname: Zhao
authors.forename: Yongmei
authors.initials: Y
authors.lastname: Li
authors.forename: Chaojie
authors.initials: C
authors.lastname: Zhang
authors.forename: Qingling
authors.initials: Q
authors.lastname: Zeng
authors.forename: Qi
authors.initials: Q
authors.lastname: Zhou
mesh_terms: D000327:Adsorption; D000332:Aerobiosis; D001559:Benzhydryl Compounds; D001673:Biodegradation, Environmental; D010636:Phenols / Q000737:chemistry / Q000378:metabolism; D012722:Sewage / Q000737:chemistry / Q000382:microbiology; D013696:Temperature; D014865:Waste Disposal, Fluid / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000737:chemistry / Q000378:metabolism; D000098826:Bisphenol A Compounds
chemical_list: D001559:Benzhydryl Compounds; D010636:Phenols; D012722:Sewage; D014874:Water Pollutants, Chemical; C006780:bisphenol A; D000098826:Bisphenol A Compounds