Functionalization of silicon surfaces with catalytically active Pd complexes and application to the aerobic oxidation of benzylic alcohols.
A single-crystal silicon surface was modified with a bisoxazoline-Pd molecular layer and utilized as a highly efficient (catalyst turnover number up to 780,000, 110 degrees C, 72 h) and recyclable catalyst in the aerobic oxidation of benzylic alcohols.
Hara
Kenji
K
Department of Chemistry, Faculty of Science, Hokkaido University, Sapporo, 060-0810, Japan. hara@sci.hokudai.ac.jp
Tayama
Shinobu
S
Kano
Hidekazu
H
Masuda
Takuya
T
Takakusagi
Satoru
S
Kondo
Toshihiro
T
Uosaki
Kohei
K
Sawamura
Masaya
M
D001592:Benzyl Alcohols / Q000737:chemistry*; D002384:Catalysis; D007659:Ketones / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010080:Oxazoles / Q000737:chemistry; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D012825:Silicon / Q000737:chemistry*; D013499:Surface Properties
D001592:Benzyl Alcohols; D007659:Ketones; D009942:Organometallic Compounds; D010080:Oxazoles; D010165:Palladium; D010100:Oxygen; D012825:Silicon