Bis[1-(2-hydroxyethyl)-4,10-diazapyrazolo[4,3-b]fluoren-5(1H)-one thiosemicarbazonato]zinc(II) dimethylformamide trisolvate monohydrate.
In the title Schiff base complex, [Zn(C15H12N7OS)2] x 3 C3H7NO x H2O, each Zn(II) atom is six-coordinated in a distorted octahedral environment by two ligands acting in a tridentate chelating mode through two N atoms and one S atom. The coordination mode of the ligand is nearly planar. There are three dimethylformamide molecules and one water molecule solvating the complex. The coordination behavior of the ligand is compared with that of related ligands in similar complexes.
Che
Xi-Quan
XQ
Department of Chemistry, Tonghua Normal University, Tonghua 134002, People's Republic of China. chexiquan@163.com
D000900:Anti-Bacterial Agents / Q000138:chemical synthesis / Q000737:chemistry; D000998:Antiviral Agents / Q000138:chemical synthesis / Q000737:chemistry; D006576:Heterocyclic Compounds, 4 or More Rings / Q000138:chemical synthesis / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D012545:Schiff Bases / Q000138:chemical synthesis / Q000737:chemistry; D012663:Semicarbazides / Q000138:chemical synthesis / Q000737:chemistry; D015032:Zinc / Q000737:chemistry*
D000900:Anti-Bacterial Agents; D000998:Antiviral Agents; D006576:Heterocyclic Compounds, 4 or More Rings; D009942:Organometallic Compounds; D012545:Schiff Bases; D012663:Semicarbazides; C527952:bis(1-(2-hydroxyethyl)-4,10-diazapyrazolo(4,3-b)fluoren-5(1H)-one thiosemicarbazonato)zinc(II); C005151:thiosemicarbazide; D015032:Zinc