title: Seasonal and spatial distribution of metals in surface sediment of an urban estuary.
abstract: Aquatic pollution by metals is of concern because of various toxic effects to marine life. The Tolka Estuary, Co. Dublin, Ireland, is a typical Irish urban estuary. It has a significant metal loading originating from the urban environment. Results of a 25 month analysis of cadmium, copper, lead and zinc spatial and temporal distribution over 10 sample locations in this estuary are presented in this paper. Metal concentrations were analysed using differential pulse polarography. Significant seasonal and spatial trends in metal distribution were observed over the 25 months. Sediment metal concentrations gradually increased (30-120%) in spring to a maximum at the end of summer which was followed by a decrease in winter months (30-60%). Sediment organic matter (OM) concentrations exhibited similar seasonal trends and a positive correlation between OM and metal distributions was observed, implying OM had an influence on metal distributions over time.
authors.affiliation: School of Biotechnology, Dublin City University, Glasnevin, Dublin 9, Ireland.
authors.forename: Conor J
authors.initials: CJ
authors.lastname: Buggy
authors.forename: John M
authors.initials: JM
authors.lastname: Tobin
mesh_terms: D002104:Cadmium / Q000032:analysis; D002947:Cities; D003300:Copper / Q000032:analysis; D004784:Environmental Monitoring / Q000379:methods; D005618:Fresh Water; D019015:Geologic Sediments / Q000032:analysis; D007494:Ireland; D007854:Lead / Q000032:analysis; D008670:Metals / Q000032:analysis*; D012621:Seasons; D012623:Seawater; D014874:Water Pollutants, Chemical / Q000032:analysis*; D015032:Zinc / Q000032:analysis
chemical_list: D008670:Metals; D014874:Water Pollutants, Chemical; D002104:Cadmium; D007854:Lead; D003300:Copper; D015032:Zinc