catena-Poly[[[aqua[3-(2-pyridylsulfanyl)propionato N-oxide-kappaO1]copper(II)]-mu-[3-(2-pyridylsulfanyl)propionato N-oxide-kappa3O3:O1,O1'] dihydrate].
In the title complex, {[Cu(C8H8NO3S)2(H2O)] x 2 H2O}n, the Cu(II) cation has a distorted square-pyramidal coordination environment consisting of five O atoms, one from a water molecule, one from an N-O group and the other three from the carboxylate groups of two 3-(2-pyridylsulfanyl)propionate N-oxide anions. The aqua[3-(2-pyridylsulfanyl)propionato N-oxide]copper(II) moieties are bridged by 3-(2-pyridylsulfanyl)propionate N-oxide anions to form an infinite three-dimensional coordination polymer with a zigzag chain structure. The crystal structure is stabilized by hydrogen bonds.
Indrani
Murugan
M
Department of Chemistry, Manonmaniam Sundaranar University, Tamil Nadu, India.
Ramasubramanian
Ramasamy
R
Kumaresan
Sudalaiandi
S
Hu
Mao-Lin
ML
Soriano-García
Manuel
M
D002413:Cations, Divalent / Q000737:chemistry; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006573:Heterocyclic Compounds, 1-Ring / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D011108:Polymers / Q000737:chemistry*
D002413:Cations, Divalent; D006573:Heterocyclic Compounds, 1-Ring; D009942:Organometallic Compounds; D011108:Polymers; C527953:catena-poly((aqua(3-(2-pyridylsulfanyl)propionato N-oxide-kappaO1)copper(II))-mu-(3-(2-pyridylsulfanyl)propionato N-oxide-kappa3O3-O1,O1') dihydrate); D003300:Copper