Synthesis of the sporolide ring framework through a cascade sequence involving an intramolecular [4+2] cycloaddition reaction of an o-quinone.
Nicolaou
K C
KC
Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, 10550 North Torrey Pines Road, La Jolla, CA 92037, USA. kcn@scripps.edu
Wang
Jianhua
J
Tang
Yefeng
Y
D006571:Heterocyclic Compounds / Q000737:chemistry*; D018942:Macrolides / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D011809:Quinones / Q000138:chemical synthesis / Q000737:chemistry*; D013696:Temperature
D006571:Heterocyclic Compounds; D018942:Macrolides; D011809:Quinones