Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel (Cu8) cluster.
An unprecedented (3,6)-connected 3-D framework constructed from sandwich-type polyoxometalate building blocks containing a (Cu8) cluster, [Cu(H(2)O)(2)]H(2)[Cu(8)(dap)(4)(H(2)O)(2)(alpha-B-GeW(9)O(34))(2)] (dap = 1,2-diaminopropane) has been hydrothermally made, which provides a novel topological structure in transition metal substituted polyoxometalates.
Zhao
Jun-Wei
JW
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter and Graduate School of the Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.
Zhang
Jie
J
Zheng
Shou-Tian
ST
Yang
Guo-Yu
GY