Stereoselective synthesis of (Z)-alpha-halo-alpha,beta-unsaturated esters, and amides from aldehydes and trihaloesters or amides promoted by manganese.
Preliminary results of a Mn-promoted sequential process directed toward the stereoselective synthesis of different (Z)-alpha-halo-alpha,beta-unsaturated compounds are described.
Concellón
José M
JM
Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, Julián Clavería 8, 33071 Oviedo, Spain. jmcg@uniovi.es
Rodríguez-Solla
Humberto
H
Díaz
Pamela
P
D000447:Aldehydes / Q000737:chemistry*; D000577:Amides / Q000138:chemical synthesis* / Q000737:chemistry*; D004952:Esters / Q000138:chemical synthesis* / Q000737:chemistry*; D008345:Manganese / Q000737:chemistry*; D012680:Sensitivity and Specificity; D013237:Stereoisomerism
D000447:Aldehydes; D000577:Amides; D004952:Esters; D008345:Manganese