title: Controlling carbon monoxide binding at di-iron units related to the iron-only hydrogenase sub-site.
abstract: Carbon monoxide binding by displacement of a pendant hemi-labile ligand at a di-iron site can be substantially 'switched-on' via a ligand protonation pathway which is competitive with metal-metal bond protonation.
authors.affiliation: Department of Chemistry, Nanchang University, Nanchang, 330031, China.
authors.forename: Fenfen
authors.initials: F
authors.lastname: Xu
authors.forename: Cédric
authors.initials: C
authors.lastname: Tard
authors.forename: Xiufeng
authors.initials: X
authors.lastname: Wang
authors.forename: Saad K
authors.initials: SK
authors.lastname: Ibrahim
authors.forename: David L
authors.initials: DL
authors.lastname: Hughes
authors.forename: Wei
authors.initials: W
authors.lastname: Zhong
authors.forename: Xirui
authors.initials: X
authors.lastname: Zeng
authors.forename: Qiuyan
authors.initials: Q
authors.lastname: Luo
authors.forename: Xiaoming
authors.initials: X
authors.lastname: Liu
authors.forename: Christopher J
authors.initials: CJ
authors.lastname: Pickett
mesh_terms: D001665:Binding Sites; D001667:Binding, Competitive; D002248:Carbon Monoxide / Q000737:chemistry*; D018360:Crystallography, X-Ray; D005290:Ferric Compounds / Q000737:chemistry*; D006864:Hydrogenase / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D017550:Spectroscopy, Fourier Transform Infrared; D013237:Stereoisomerism
chemical_list: D005290:Ferric Compounds; D008024:Ligands; D002248:Carbon Monoxide; D006864:Hydrogenase