title: An unusual polyoxometalate-encapsulating 3D polyrotaxane framework formed by molecular squares threading on a twofold interpenetrated diamondoid skeleton.
abstract: Threading molecular square "beads" on a twofold interpenetrated diamondoid skeleton gives a new type of 3D metal-organic polyrotaxane framework with large channels, in which nanosized Keggin anions as guests are encapsulated for the first time.
authors.affiliation: Key Laboratory of Polyoxometalates Science of Ministry of Education, Northeast Normal University, Changchun 130024, China.
authors.forename: Xin-Long
authors.initials: XL
authors.lastname: Wang
authors.forename: Chao
authors.initials: C
authors.lastname: Qin
authors.forename: En-Bo
authors.initials: EB
authors.lastname: Wang
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Su
mesh_terms: D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D043862:Rotaxanes / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; D043862:Rotaxanes; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates