title: Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel (Cu8) cluster.
abstract: An unprecedented (3,6)-connected 3-D framework constructed from sandwich-type polyoxometalate building blocks containing a (Cu8) cluster, [Cu(H(2)O)(2)]H(2)[Cu(8)(dap)(4)(H(2)O)(2)(alpha-B-GeW(9)O(34))(2)] (dap = 1,2-diaminopropane) has been hydrothermally made, which provides a novel topological structure in transition metal substituted polyoxometalates.
authors.affiliation: State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter and Graduate School of the Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.
authors.forename: Jun-Wei
authors.initials: JW
authors.lastname: Zhao
authors.forename: Jie
authors.initials: J
authors.lastname: Zhang
authors.forename: Shou-Tian
authors.initials: ST
authors.lastname: Zheng
authors.forename: Guo-Yu
authors.initials: GY
authors.lastname: Yang