Retention of regiochemistry of monosubstituted allyl acetates in the ruthenium catalysed allylic alkylation with malonate anion.
In the RuCl2(p-cymene)/PPh3 catalysed regioselective allylic alkylation of monosubstituted allyl acetates with malonate anion, the selective substitution at the position originally substituted with acetate was observed.
Kawatsura
Motoi
M
Department of Materials Science, Faculty of Engineering, Tottori University, Koyama, Tottori, 680-8552, Japan. kawatsur@chem.tottori-u.ac.jp
Ata
Fumio
F
Hayase
Shuichi
S
Itoh
Toshiyuki
T
D000085:Acetates / Q000737:chemistry*; D000475:Alkenes / Q000138:chemical synthesis / Q000737:chemistry; D000478:Alkylation; D000498:Allyl Compounds / Q000737:chemistry*; D000838:Anions / Q000737:chemistry; D002384:Catalysis; D008314:Malonates / Q000737:chemistry*; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*; D013237:Stereoisomerism
D000085:Acetates; D000475:Alkenes; D000498:Allyl Compounds; D000838:Anions; D008314:Malonates; D009942:Organometallic Compounds; D012428:Ruthenium; C030290:malonic acid