Formation of two (6,3) networks showing structural diversity, Borromean topology and conformational chirality in the same crystal.
Reaction of two tripodal ligands, 2,4,6-tris(4-((2-methyl-benzimidazol-1-yl)methyl)phenyl)-1,3,5-triazine (L1) and 1,3,5-tris(4-((2-methyl-benzimidazol-1-yl)methyl)phenyl)benzene (L2), with AgSbF6 led to formation of two types (6,3) networks in one single crystal, of which one is three-fold Borromean topologically entangled while the other is independent, showing the same chirality and sandwiched Borromean stacking.
Zhang
Xue-Li
XL
MOE Laboratory of Bioinorganic and Synthetic Chemistry, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou, 510275, China.
Guo
Cui-Ping
CP
Yang
Qing-Yuan
QY
Wang
Wei
W
Liu
Wei-Sheng
WS
Kang
Bei-Sheng
BS
Su
Cheng-Yong
CY
D000965:Antimony / Q000737:chemistry*; D001555:Benzene Derivatives / Q000737:chemistry; D001562:Benzimidazoles / Q000737:chemistry*; D003460:Crystallization; D018360:Crystallography, X-Ray; D005461:Fluorine / Q000737:chemistry*; D006860:Hydrogen Bonding; D008024:Ligands; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012834:Silver / Q000737:chemistry*; D014227:Triazines / Q000737:chemistry*
C526990:1,3,5-tris(4-((2-methylbenzimidazol-1-yl)methyl)phenyl)benzene; C526989:2,4,6-tris(4-((2-methylbenzimidazol-1-yl)methyl)phenyl)-1,3,5-triazine; D001555:Benzene Derivatives; D001562:Benzimidazoles; D008024:Ligands; D009942:Organometallic Compounds; D014227:Triazines; D005461:Fluorine; D012834:Silver; D000965:Antimony