Kinetically stabilized dibenzoborole as an electron-accepting building unit.
A synthetic route to a dibenzoborole, kinetically stabilized by the 2,4,6-tri-tert-butylphenyl group, was developed, and a series of pi-extended derivatives were synthesized, which show orange-red emissions and stable electrochemical redox properties.
Wakamiya
Atsushi
A
Department of Chemistry, Graduate School of Science, Nagoya University, and SORST, Japan Science and Technology Agency, Chikusa, Nagoya 464-8602, Japan.
Mishima
Kotaro
K
Ekawa
Kanako
K
Yamaguchi
Shigehiro
S
D001896:Boron Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004563:Electrochemistry; D004583:Electrons; D008958:Models, Molecular; D015394:Molecular Structure; D010084:Oxidation-Reduction; D013050:Spectrometry, Fluorescence
D001896:Boron Compounds; C521463:dibenzoborole