An unusual polyoxometalate-encapsulating 3D polyrotaxane framework formed by molecular squares threading on a twofold interpenetrated diamondoid skeleton.
Threading molecular square "beads" on a twofold interpenetrated diamondoid skeleton gives a new type of 3D metal-organic polyrotaxane framework with large channels, in which nanosized Keggin anions as guests are encapsulated for the first time.
Wang
Xin-Long
XL
Key Laboratory of Polyoxometalates Science of Ministry of Education, Northeast Normal University, Changchun 130024, China.
Qin
Chao
C
Wang
En-Bo
EB
Su
Zhong-Min
ZM
D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D011108:Polymers / Q000737:chemistry*; D043862:Rotaxanes / Q000737:chemistry*; D017973:Tungsten Compounds / Q000737:chemistry*; D000099294:Polyoxometalates
D008024:Ligands; D009942:Organometallic Compounds; D011108:Polymers; D043862:Rotaxanes; D017973:Tungsten Compounds; C102296:polyoxometalate I; D000099294:Polyoxometalates