title: Morphology evolution via self-organization and lateral and vertical diffusion in polymer:fullerene solar cell blends.
abstract: Control of blend morphology at the microscopic scale is critical for optimizing the power conversion efficiency of plastic solar cells based on blends of conjugated polymer with fullerene derivatives. In the case of bulk heterojunctions of regioregular poly(3-hexylthiophene) (P3HT) and a soluble fullerene derivative ([6,6]-phenyl C61-butyric acid methyl ester, PCBM), both blend morphology and photovoltaic device performance are influenced by various treatments, including choice of solvent, rate of drying, thermal annealing and vapour annealing. Although the protocols differ significantly, the maximum power conversion efficiency values reported for the various techniques are comparable (4-5%). In this paper, we demonstrate that these techniques all lead to a common arrangement of the components, which consists of a vertically and laterally phase-separated blend of crystalline P3HT and PCBM. We propose a morphology evolution that consists of an initial crystallization of P3HT chains, followed by diffusion of PCBM molecules to nucleation sites, at which aggregates of PCBM then grow.
authors.affiliation: Department of Physics, Blackett Laboratory, Imperial College London, Prince Consort Road, London SW7 2BW, UK. M.Campoy@imperial.ac.uk
authors.forename: Mariano
authors.initials: M
authors.lastname: Campoy-Quiles
authors.forename: Toby
authors.initials: T
authors.lastname: Ferenczi
authors.forename: Tiziano
authors.initials: T
authors.lastname: Agostinelli
authors.forename: Pablo G
authors.initials: PG
authors.lastname: Etchegoin
authors.forename: Youngkyoo
authors.initials: Y
authors.lastname: Kim
authors.forename: Thomas D
authors.initials: TD
authors.lastname: Anthopoulos
authors.forename: Paul N
authors.initials: PN
authors.lastname: Stavrinou
authors.forename: Donal D C
authors.initials: DD
authors.lastname: Bradley
authors.forename: Jenny
authors.initials: J
authors.lastname: Nelson