Determination of the weight percentage gain and of the acetyl group content of acetylated wood by means of different infrared spectroscopic methods.
The weight percentage gain (WPG) and the acetyl group content of wood due to acetylation with acetic anhydride have been analyzed by means of Fourier transform infrared spectroscopy (FTIR) and near-infrared spectroscopy (NIR). Band height ratios (BHR) (1240/1030 (1230/1030) and 1745/1030 (1740/1030)) of the bands at 1745 (1740), 1240 (1230), and 1030 cm-1 were calculated from FTIR-KBr and FTIR-ATR (attenuated total reflection) spectra. The good linear correlation with a coefficient of determination of about 0.94 over a range from 0 to 27% WPG existing between BHRs and WPG and acetyl group content, respectively, requires only a few samples to calibrate FTIR. Partial least-squares regression models based on second derivatives of the NIR spectra in the wavenumber range from 6080 to 5760 cm-1 resulted in a R2 value of 0.99, number of PLS components (rank) between 3 and 5, root-mean-square error of cross-validation between 0.6 and 0.79%, and a residual prediction deviation up to 10. Although a wide range of input parameters (i.e., various wood species and different procedures of acetylation) was used, highly satisfactory results were obtained. Both FTIR and NIR spectroscopic means fulfill the need for determining the WPG and the acetyl content of acetylated wood. By reason of its additional potential for on-line process control, the NIR method may even outperform the FTIR method.
Stefke
Barbara
B
Competence Centre for Wood Composites and Wood Chemistry (Wood K plus), St. Peter Strasse 25, A-4021 Linz, Austria.
Windeisen
Elisabeth
E
Schwanninger
Manfred
M
Hinterstoisser
Barbara
B
D000089:Acetic Anhydrides / Q000737:chemistry*; D000107:Acetylation; D006801:Humans; D016018:Least-Squares Analysis; D008970:Molecular Weight; D012044:Regression Analysis; D017550:Spectroscopy, Fourier Transform Infrared / Q000379:methods; D019265:Spectroscopy, Near-Infrared / Q000379:methods*; D014934:Wood / Q000032:analysis* / Q000737:chemistry
D000089:Acetic Anhydrides; C031800:acetic anhydride