The catalytic dehydrogenation of ammonia-borane involving an unexpected hydrogen transfer to ligated carbene and subsequent carbon-hydrogen activation.
Yang
Xinzheng
X
Department of Chemistry, Texas A&M University, College Station, Texas 77843-3255, USA.
Hall
Michael B
MB
D000641:Ammonia / Q000737:chemistry*; D001880:Boranes / Q000737:chemistry*; D002384:Catalysis; D003198:Computer Simulation; D006838:Hydrocarbons / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D006865:Hydrogenation; D008024:Ligands; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008956:Models, Chemical; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D011789:Quantum Theory
C527894:2,2'-bis(1,3,4-triphenyl-4,5-dihydro-1H-1,2,4-triazol-5-ylidene)nickel(0); D001880:Boranes; D006838:Hydrocarbons; D008024:Ligands; D009942:Organometallic Compounds; C030011:carbene; D000641:Ammonia; D009532:Nickel; D006859:Hydrogen; D008697:Methane