Satellite transitions acquired in real time by magic angle spinning (STARTMAS): "ultrafast" high-resolution MAS NMR spectroscopy of spin I=3/2 nuclei.
The satellite transitions acquired in real time by magic angle spinning (STARTMAS) NMR experiment combines a train of pulses with sample rotation at the magic angle to refocus the first- and second-order quadrupolar broadening of spin I=3/2 nuclei in a series of echoes, while allowing the isotropic chemical and quadrupolar shifts to evolve. The result is real-time isotropic NMR spectra at high spinning rates using conventional MAS equipment. In this paper we describe in detail how STARTMAS data can be acquired and processed with ease on commercial equipment. We also discuss the advantages and limitations of the approach and illustrate the discussion with numerical simulations and experimental data from four different powdered solids.
Thrippleton
Michael J
MJ
Department of Chemistry and WestCHEM, University of Glasgow, Glasgow G12 8QQ, United Kingdom.
Ball
Thomas J
TJ
Wimperis
Stephen
S