"Schizoid" reactivity of 1,1'-diisocyanoferrocene.
The two chemically equivalent functional groups of 1,1'-diisocyanoferrocene each undergo a different specific reaction with the gold(I) acetylide [Au(C=C-Fc)], viz. ordinary coordination and extraordinary 1,1-insertion.
Siemeling
Ulrich
U
Institute of Chemistry, University of Kassel, D-34109, Kassel, Germany. siemeling@uni-kassel.de
Rother
Dag
D
Bruhn
Clemens
C
D000480:Alkynes / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry
C526988:1,1'-diisocyanoferrocene; D000480:Alkynes; D005296:Ferrous Compounds; D009942:Organometallic Compounds; D006046:Gold