title: Preparation and characterization of N-S-codoped TiO(2) photocatalyst and its photocatalytic activity.
abstract: N-S-codoped anatase nanosized TiO(2) photocatalyst (NSTO) was successfully prepared by one-step hydrothermal method from a mixed aqueous solution of Ti(SO(4))(2) and thiourea. The samples were characterized by XRD, UV-vis, XPS, FT-IR and EA. From results of UV-vis, a red shift of the absorption edge was brought out owing to N and S codoping, and the extension for photoabsorption range of NSTO occurred. XRD, XPS, EA and FT-IR studies revealed that N and S were in situ codoped in the lattice of TiO(2) and N concentration decreased from the surface to the center of NSTO. Especially, the photocatalytic tests indicated that NSTO exhibited a high activity for decompositions of methyl orange both under UV-light and vis-light irradiation comparing to S-doped TiO(2) (STO) and undoped TiO(2) (TO). The high activity of NSTO can be related to the results of the synergetic effects of strong absorption in the UV-vis region, red shift in adsorption edge, oxygen vacancies and the enhancement of surface acidity induced by N and S codoping.
authors.affiliation: School of Chemical Engineering, Hefei University of Technology, Hefei, PR China. weifyliuj@yahoo.com.cn
authors.forename: Fengyu
authors.initials: F
authors.lastname: Wei
authors.forename: Liangsuo
authors.initials: L
authors.lastname: Ni
authors.forename: Peng
authors.initials: P
authors.lastname: Cui
mesh_terms: D002384:Catalysis; D009584:Nitrogen / Q000737:chemistry*; D010777:Photochemistry; D013056:Spectrophotometry, Ultraviolet; D017550:Spectroscopy, Fourier Transform Infrared; D013455:Sulfur / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: C009495:titanium dioxide; D013455:Sulfur; D014025:Titanium; D009584:Nitrogen