title: A highly stereoselective synthesis of the C10-C23 fragment of (-)-dictyostatin.
abstract: A highly stereoselective synthesis of the C10-C23 fragment of (-)-dictyostatin has been achieved using a Carreira alkynylation and a Marshall-Tamaru allenylzinc addition as key steps.
authors.affiliation: Dipartimento di Chimica Organica e Industriale, Centro di Eccellenza C.I.S.I., Università degli Studi di Milano, Via G. Venezian, 21, 20133 Milano, Italy.
authors.forename: Chiara
authors.initials: C
authors.lastname: Monti
authors.forename: Ofer
authors.initials: O
authors.lastname: Sharon
authors.forename: Cesare
authors.initials: C
authors.lastname: Gennari
mesh_terms: D018942:Macrolides / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation; D013237:Stereoisomerism
chemical_list: D018942:Macrolides; C470814:dictyostatin