title: Spectroscopic, thermal and voltammetric studies of crystalline complex trans-N,N'-bis(salicylidene)-1',2'-cyclohexanediamine with Cu(II).
abstract: The dimeric complex, [C20H20CuN2O2]2, has been prepared and characterized by thermal analysis, IR spectroscopy and single-crystal X-ray diffraction techniques. The Cu atom in the binuclear complex exists in a distorted square-pyramidal configuration, defined by three O atoms and two N atoms. The crystal structure is stabilized by intermolecular C-H...O hydrogen bonding interaction. The electrochemical property of the complex was investigated in CH2Cl2 by cyclic voltammetry at 100 mV s(-1) scan rate.
authors.affiliation: Department of Physics, Kahramanmaras Sutcuimam University, 46100 Kahramanmaras, Turkey. aslantas@ksu.edu.tr
authors.forename: Mehmet
authors.initials: M
authors.lastname: Aslantas
authors.forename: Mehmet
authors.initials: M
authors.lastname: Tümer
authors.forename: Ertan
authors.initials: E
authors.lastname: Sahin
mesh_terms: D003300:Copper / Q000737:chemistry*; D003460:Crystallization; D018360:Crystallography, X-Ray / Q000379:methods; D003510:Cyclohexanes / Q000737:chemistry; D003514:Cyclohexylamines / Q000737:chemistry*; D003959:Diamines / Q000737:chemistry*; D019281:Dimerization; D004563:Electrochemistry / Q000379:methods; D008024:Ligands; D008670:Metals / Q000737:chemistry; D008956:Models, Chemical; D008968:Molecular Conformation; D012997:Solvents / Q000737:chemistry; D013053:Spectrophotometry / Q000379:methods*; D013696:Temperature; D014961:X-Ray Diffraction
chemical_list: D003510:Cyclohexanes; D003514:Cyclohexylamines; D003959:Diamines; D008024:Ligands; D008670:Metals; C533174:N,N'-bis(salicylidene)-1',2'-cyclohexanediamine; D012997:Solvents; C506365:Cyclohexane; D003300:Copper