Supramolecular PhanePhos-analogous ligands through hydrogen-bonding for asymmetric hydrogenation.
PhanePhos-analogous phosphorous ligands have been generated via self-assembly through hydrogen-bonding, and studied in rhodium-catalyzed asymmetric hydrogenation (up to 99% ee).
Laungani
Andy Ch
ACh
Institut für Organische Chemie und Biochemie, Albert-Ludwigs-Universität Freiburg, Albertstrasse 21, Freiburg, Germany.
Breit
Bernhard
B
D002384:Catalysis; D018360:Crystallography, X-Ray; D006860:Hydrogen Bonding; D006865:Hydrogenation; D008024:Ligands; D046911:Macromolecular Substances / Q000138:chemical synthesis* / Q000737:chemistry; D008958:Models, Molecular; D008968:Molecular Conformation; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry
D008024:Ligands; D046911:Macromolecular Substances; D009943:Organophosphorus Compounds; D012238:Rhodium