title: Sorption processes and XRD analysis of a natural zeolite exchanged with Pb(2+), Cd(2+) and Zn(2+) cations.
abstract: In this study the Pb(2+), Cd(2+) and Zn(2+) adsorption capacity of a natural zeolite was evaluated in batch tests at a constant pH of 5.5 by polluting this mineral with solutions containing increasing concentrations of the three cations to obtain adsorption isotherms. In addition X-ray powder diffraction (XRD) was used to investigate the changes of zeolite structure caused by the exchange with cations of different ionic radius. The zeolite adsorption capacity for the three cations was Zn>Pb>Cd. Moreover a sequential extraction procedure [H(2)O, 0.05 M Ca(NO(3))(2) and 0.02 M EDTA] was applied to zeolite samples used in the adsorption experiments to determine the chemical form of the cations bound to the sorbent. Using this approach it was shown that low concentrations of Pb(2+), Cd(2+) and Zn(2+) were present as water-soluble and exchangeable fractions (<25% of the Me adsorbed), while EDTA extracted most of the adsorbed cations from the zeolite (>27% of the Me adsorbed). The XRD pattern of zeolite, analysed according to the Rietveld method, showed that the main mineralogical phase involved in the adsorption process was clinoptilolite. Besides structure information showed that the incorporation of Pb(2+), Cd(2+) and Zn(2+), into the zeolite frameworks changed slightly but appreciably the lattice parameters. XRD analysis also showed the occurrence of some isomorphic substitution phenomena where the Al(3+) ions of the clinoptilolite framework were replaced by exchanged Pb(2+) cations in the course of the ion exchange reaction. This mechanism was instead less evident in the patterns of the samples doped with Cd(2+) and Zn(2+) cations.
authors.affiliation: Dipartimento di Scienze Ambientali Agrarie e Biotecnologie Agro-Alimentari, Sez Chimica Agraria ed Ambientale, University of Sassari, Sassari, Italy. castaldi@uniss.it
authors.forename: Paola
authors.initials: P
authors.lastname: Castaldi
authors.forename: Laura
authors.initials: L
authors.lastname: Santona
authors.forename: Stefano
authors.initials: S
authors.lastname: Enzo
authors.forename: Pietro
authors.initials: P
authors.lastname: Melis
mesh_terms: D000327:Adsorption; D002104:Cadmium / Q000737:chemistry*; D002413:Cations, Divalent; D007854:Lead / Q000737:chemistry*; D011208:Powders; D014961:X-Ray Diffraction; D017641:Zeolites / Q000737:chemistry*; D015032:Zinc / Q000737:chemistry*
chemical_list: D002413:Cations, Divalent; D011208:Powders; D002104:Cadmium; D017641:Zeolites; D007854:Lead; D015032:Zinc