Effective free-energy method for nematic liquid crystals in contact with structured substrates.
We study the phase behavior of a nematic liquid crystal confined between a flat substrate with strong anchoring and a patterned substrate whose structure and local anchoring strength we vary. By first evaluating an effective surface free-energy function characterizing the patterned substrate, we derive an expression for the effective free energy of the confined nematic liquid crystal. Then we determine phase diagrams involving a homogeneous state in which the nematic director is almost uniform and a hybrid aligned nematic state in which the orientation of the director varies through the cell. Direct minimizations of the free-energy functional were performed in order to test the predictions of the effective free-energy method. We find remarkably good agreement between the phase boundaries calculated from the two approaches. In addition, the effective free-energy method allows one to determine the energy barriers between two states in a bistable nematic device.
Harnau
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L
Max-Planck-Institut für Metallforschung, Heisenbergstrasse 3, D-70569 Stuttgart, Germany.
Kondrat
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Poniewierski
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