A novel chiral porous metal-organic framework: asymmetric ring opening reaction of epoxide with amine in the chiral open space.
A novel chiral metal-organic framework, [Cu(2)(5,5'-BDA)(2)] was synthesized by treating chiral 2,2'-dihydroxy-1,1'-binaphthalene-5,5'-dicarboxylic acid (5,5'-H(2)BDA) with a Cu(II) ion, in which the asymmetric ring opening reaction of an epoxide with amine proceeds efficiently under solvent-free conditions.
Tanaka
Koichi
K
Department of Chemistry and Materials Engineering, Faculty of Chemistry, Materials and Bioengineering, Kansai University, Suita, Osaka, Japan. ktanaka@ipcku.kansai-u.ac.jp
Oda
Shinji
S
Shiro
Motoo
M
D000588:Amines / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray; D004852:Epoxy Compounds / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D016062:Porosity; D033362:Powder Diffraction
D000588:Amines; D004852:Epoxy Compounds; D009942:Organometallic Compounds; D003300:Copper