title: Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative.
abstract: A new type of stable radical ligand featuring a 1,1-bis-phosphinosulfide alkene backbone has been prepared and characterized on the basis of X-ray diffraction, EPR and DFT studies.
authors.affiliation: Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique, Centre National de la Recherche Scientifique, Palaiseau Cédex, France.
authors.forename: Thibault
authors.initials: T
authors.lastname: Cantat
authors.forename: Frédéric
authors.initials: F
authors.lastname: Biaso
authors.forename: Aurélien
authors.initials: A
authors.lastname: Momin
authors.forename: Louis
authors.initials: L
authors.lastname: Ricard
authors.forename: Michel
authors.initials: M
authors.lastname: Geoffroy
authors.forename: Nicolas
authors.initials: N
authors.lastname: Mézailles
authors.forename: Pascal
authors.initials: P
authors.lastname: Le Floch