Synthesis of a stable radical anion via the one electron reduction of a 1,1-bis-phosphinosulfide alkene derivative.
A new type of stable radical ligand featuring a 1,1-bis-phosphinosulfide alkene backbone has been prepared and characterized on the basis of X-ray diffraction, EPR and DFT studies.
Cantat
Thibault
T
Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique, Centre National de la Recherche Scientifique, Palaiseau Cédex, France.
Biaso
Frédéric
F
Momin
Aurélien
A
Ricard
Louis
L
Geoffroy
Michel
M
Mézailles
Nicolas
N
Le Floch
Pascal
P