Degradation of the fungicide carbendazim in aqueous solutions with UV/TiO(2) process: optimization, kinetics and toxicity studies.
An attempt was made to investigate the potential of UV-photocatalytic process in the presence of TiO(2) particles for the degradation of carbendazim (C(9)H(9)N(3)O(2)), a fungicide with a high worldwide consumption but considered as a "priority hazard substance" by the Water Framework Directive of the European Commission (WFDEC). A circulating upflow photo-reactor was employed and the influence of catalyst concentration, pH and temperature were investigated. The results showed that degradation of this fungicide can be conducted in the both processes of only UV-irradiation and UV/TiO(2); however, the later provides much better results. Accordingly, a degradation of more than 90% of fungicide was achieved by applying the optimal operational conditions of 70 mgL(-1) of catalyst, natural pH of 6.73 and ambient temperature of 25 degrees C after 75 min irradiation. Under these mild conditions, the initial rate of degradation can be described well by the Langmuir-Hinshelwood kinetic model. Toxicological assessments on the obtained samples were also performed by measurement of the mycelium growth inhibition of Fusarium oxysporum fungus on PDA medium. The results indicate that the kinetics of degradation and toxicity are in reasonably good agreement mainly after 45 min of irradiation; confirming the effectiveness of photocatalytic process.
Saien
J
J
Department of Applied Chemistry, Bu-Ali Sina University, Hamedan, Iran. saien@basu.ac.ir <saien@basu.ac.ir>
Khezrianjoo
S
S
D001562:Benzimidazoles / Q000737:chemistry* / Q000528:radiation effects / Q000633:toxicity; D002219:Carbamates / Q000737:chemistry* / Q000528:radiation effects / Q000633:toxicity; D002384:Catalysis; D005659:Fungicides, Industrial / Q000737:chemistry* / Q000528:radiation effects / Q000633:toxicity; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D012996:Solutions; D013696:Temperature; D014025:Titanium / Q000737:chemistry*; D014466:Ultraviolet Rays; D014865:Waste Disposal, Fluid / Q000379:methods*; D014874:Water Pollutants, Chemical / Q000737:chemistry* / Q000528:radiation effects
D001562:Benzimidazoles; D002219:Carbamates; D005659:Fungicides, Industrial; D012996:Solutions; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; D014025:Titanium; C006698:carbendazim