Mild synthesis of organophosphorus compounds: reaction of phosphorus-containing carbenoids with organoboranes.
Organoboranes react with phosphorus-containing carbenoids to produce a variety of functionalized organophosphorus compounds under mild conditions. In some cases, selective migration of one group attached to boron can be observed. Phosphonite-borane complexes are introduced as novel synthons for the synthesis of phosphinic esters.
Antczak
Monika I
MI
Department of Chemistry, Box 298860, Texas Christian University, Fort Worth, Texas 76129, USA.
Montchamp
Jean-Luc
JL
D001880:Boranes / Q000737:chemistry*; D004952:Esters; D006838:Hydrocarbons / Q000737:chemistry; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D015394:Molecular Structure; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010758:Phosphorus / Q000737:chemistry*
D001880:Boranes; D004952:Esters; D006838:Hydrocarbons; D009943:Organophosphorus Compounds; C030011:carbene; D010758:Phosphorus; D008697:Methane