Eight coordination with bis(bidentate) bridging ligands: zeolitic topology versus square grid networks.
The assembly of the asymmetric bis(bidentate) 2-pyrimidinecarboxylate ligand with Cd(II) produces a metal-organic framework with the RHO zeolitic topology, while 5-(2'-pyrimidyl)tetrazolate with Cd(II) leads to square grid networks.
Zhang
Jian-Yong
JY
Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai, China.
Cheng
Ai-Ling
AL
Yue
Qi
Q
Sun
Wei-Wei
WW
Gao
En-Qing
EQ