Micromelones A and B, noncontiguous polypropionates from Micromelo undata.
In this paper we report on the isolation and structural elucidation of two new noncontiguous polypropionates, micromelones A ( 10) and B ( 11), that have been isolated from the marine gastropod Micromelo undata. Their structures were determined through the interpretation of their spectroscopic data, and a biosynthetic pathway from a common linear precursor with other polypropionate groups has been proposed.
Napolitano
José G
JG
Instituto Universitario de Bio-Orgánica Antonio González, Universidad de La Laguna, Astrofísico Francisco Sánchez 2, 38206 La Laguna, Spain.
Souto
María L
ML
Fernández
José J
JJ
Norte
Manuel
M
D000818:Animals; D001266:Atlantic Islands; D049851:Gastropoda / Q000737:chemistry*; D008386:Marine Biology; D015394:Molecular Structure; D011422:Propionates / Q000737:chemistry / Q000302:isolation & purification* / Q000378:metabolism
D011422:Propionates; C528151:micromelone A; C528152:micromelone B