title: A simple method for the removal of thiols on gold surfaces using an NH4OH-H2O2-H2O solution.
abstract: The removal behavior of self-assembled monolayers (SAMs) of thiol molecules on a gold substrate by an NH(4)OH-H(2)O(2)-H(2)O solution was studied using attenuated total reflectance infrared spectroscopy (ATR-IR) and atomic force microscopy (AFM). Furthermore, the impact of the concentration of NH(4)OH and H(2)O(2) in the solution and reaction temperature on the SAM removal rate and efficiency was explored. The SAM removal rate and efficiency were significantly influenced by the concentration of NH(4)OH rather than H(2)O(2). The solution containing the 2 : 1 molar ratio of NH(4)OH : H(2)O(2) among three different solutions showed the highest removal rate and efficiency in the removal of 11-mercapto-1-undecanol. The increase in the reaction temperature resulted in the enhancement on the SAM removal rate, but it led to the fast delamination of the gold layer. These results may be useful in the regeneration of sensor surfaces relying on gold/thiol chemistry.
authors.affiliation: Department of Chemistry and Biochemistry, Texas Tech University, Lubbock, Texas 79409, USA.
authors.forename: Dae Jung
authors.initials: DJ
authors.lastname: Kim
authors.forename: Rajasekar
authors.initials: R
authors.lastname: Pitchimani
authors.forename: David E
authors.initials: DE
authors.lastname: Snow
authors.forename: Louisa J
authors.initials: LJ
authors.lastname: Hope-Weeks