Solvent-induced configuration mixing and triplet excited state inversion exemplified in a Pt(II) complex.
The present study provides clear-cut experimental evidence for solvent-induced configuration mixing and complete triplet state inversion at room temperature in a Pt(ii) charge transfer complex bearing a combination of energetically proximate charge transfer and intraligand triplet excited states.
Goeb
Sébastien
S
Department of Chemistry and Center for Photochemical Sciences, Bowling Green State University, Bowling Green, OH 43403, USA.
Rachford
Aaron A
AA
Castellano
Felix N
FN
D001554:Benzene / Q000737:chemistry*; D008752:Methylene Chloride / Q000737:chemistry*; D009944:Organoplatinum Compounds / Q000737:chemistry*; D012997:Solvents / Q000737:chemistry; D013050:Spectrometry, Fluorescence / Q000379:methods; D013056:Spectrophotometry, Ultraviolet / Q000379:methods; D013696:Temperature
D009944:Organoplatinum Compounds; D012997:Solvents; D008752:Methylene Chloride; D001554:Benzene