title: Pressure-assisted chelation extraction of lead from contaminated soil.
abstract: Soil contamination by metallic elements including lead occurs frequently. Contaminant metals in soil pose a serious risk to public health and groundwater supplies. Extraction using chelants is seen as a remediation option; however, it is often hampered by access to the contaminants that are shielded by the soil matrix. We have developed a novel extraction technique that utilizes a mildly elevated pressure in consecutive cycles of compression and decompression along with a chelating agent for the soil slurry. Complete extraction of 3300 mg/kg of Pb from soil was achieved by 100 mM of EDTA (ethylenediaminetetraacetic acid) in 10 min using 20 pressure cycles at 150 psi (10 atm). Extraction was studied according to pressure, number of pressure cycles, chelant concentration, solid content, pH, agitation, and use of consecutive washings. Heightened extraction is attributed to fracturing of the soil particles that leads to enhanced contaminant exposure to the chelating agent.
authors.affiliation: Department of Civil and Environmental Engineering, University of Utah, 104 CME, Salt Lake City, UT 84112, USA. hong@civil.utah.edu
authors.forename: P K Andy
authors.initials: PK
authors.lastname: Hong
authors.forename: Xiaoxiao
authors.initials: X
authors.lastname: Cai
authors.forename: Zhixiong
authors.initials: Z
authors.lastname: Cha
mesh_terms: D002614:Chelating Agents / Q000737:chemistry*; D004492:Edetic Acid / Q000737:chemistry*; D052918:Environmental Restoration and Remediation / Q000379:methods; D006863:Hydrogen-Ion Concentration; D007220:Industrial Waste; D007854:Lead / Q000737:chemistry*; D009068:Movement; D011312:Pressure; D012989:Soil Pollutants / Q000737:chemistry*
chemical_list: D002614:Chelating Agents; D007220:Industrial Waste; D012989:Soil Pollutants; D007854:Lead; D004492:Edetic Acid