title: Active peroxo titanium complexes: syntheses, characterization and their potential in the photooxidation of 2-propanol.
abstract: Two novel peroxo titanium complexes, Li(2)(NH(4))(4)[Ti(2)(O(2))(2)(cit)(Hcit)](2).5H(2)O and Zn(NH(4))(4)[Ti(4)(O(2))(4)(Hcit)(2)(cit)(2)].12H(2)O (cit = citrate), show encouraging results in the photochemical oxidation of 2-propanol.
authors.affiliation: Anorganische Chemie I, Ruhr-Universität Bochum, Universitätsstrasse 150, Bochum, Germany.
authors.forename: Markus
authors.initials: M
authors.lastname: Rohe
authors.forename: Klaus
authors.initials: K
authors.lastname: Merz
mesh_terms: D019840:2-Propanol / Q000737:chemistry* / Q000528:radiation effects; D002245:Carbon Dioxide / Q000737:chemistry / Q000528:radiation effects; D008094:Lithium / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D010084:Oxidation-Reduction; D010100:Oxygen / Q000737:chemistry*; D010545:Peroxides / Q000737:chemistry*; D010777:Photochemistry; D014025:Titanium / Q000737:chemistry*; D014466:Ultraviolet Rays; D015032:Zinc / Q000737:chemistry
chemical_list: D009942:Organometallic Compounds; D010545:Peroxides; D002245:Carbon Dioxide; D008094:Lithium; D014025:Titanium; D015032:Zinc; D019840:2-Propanol; D010100:Oxygen