title: Effect of phosphine dose on sorption in wheat.
abstract: BACKGROUND
  In spite of the extensive use of phosphine fumigation around the world to control insects in stored grain, and the knowledge that grain sorbs phosphine, the effect of concentration on sorption has not been quantified. A laboratory study was undertaken, therefore, to investigate the effect of phosphine dose on sorption in wheat. Wheat was added to glass flasks to achieve filling ratios of 0.25-0.95, and the flasks were sealed and injected with phosphine at 0.1-1.5 mg L(-1) based on flask volume. Phosphine concentration was monitored for 8 days at 25 degrees C and 55% RH.
  
  
  RESULTS
  When sorption occurred, phosphine concentration declined with time and was approximately first order, i.e. the data fitted an exponential decay equation. Percentage sorption per day was directly proportional to filling ratio, and was negatively correlated with dose for any given filling ratio. Based on the results, a tenfold increase in dose would result in a halving of the sorption constant and the percentage daily loss. Wheat was less sorptive if it was fumigated for a second time.
  
  
  CONCLUSIONS
  The results have implications for the use of phosphine for control of insects in stored wheat. This study shows that dose is a factor that must be considered when trying to understand the impact of sorption on phosphine concentration, and that there appears to be a limit to the capacity of wheat to sorb phosphine.
authors.affiliation: Queensland Department of Primary Industries and Fisheries, 80 Meiers Road, Indooroopilly, Queensland 4068, Australia. greg.daglish@dpi.qld.gov.au
authors.forename: Gregory J
authors.initials: GJ
authors.lastname: Daglish
authors.forename: Hervoika
authors.initials: H
authors.lastname: Pavic
mesh_terms: D000327:Adsorption; D005651:Fumigation / Q000592:standards*; D007306:Insecticides / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D014908:Triticum / Q000737:chemistry* / Q000469:parasitology
chemical_list: D007306:Insecticides; D010720:Phosphines; C044646:phosphine