Origins of differences in reactivities of alkenes, alkynes, and allenes in [Rh(CO)2Cl]2-catalyzed (5 + 2) cycloaddition reactions with vinylcyclopropanes.
Yu
Zhi-Xiang
ZX
Key Laboratory of Bioorganic Chemistry and Molecular Engineering of the Ministry of Education, College of Chemistry, Peking University, Beijing 100871, PR China. yuzx@pku.edu.cn
Cheong
Paul Ha-Yeon
PH
Liu
Peng
P
Legault
Claude Y
CY
Wender
Paul A
PA
Houk
K N
KN
D000475:Alkenes / Q000737:chemistry*; D000480:Alkynes / Q000737:chemistry*; D019086:Bridged Bicyclo Compounds, Heterocyclic / Q000138:chemical synthesis* / Q000737:chemistry; D002384:Catalysis; D003500:Cyclization; D003521:Cyclopropanes / Q000737:chemistry*; D008956:Models, Chemical; D015394:Molecular Structure; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism; D014753:Vinyl Compounds / Q000737:chemistry*
D000475:Alkenes; D000480:Alkynes; D019086:Bridged Bicyclo Compounds, Heterocyclic; D003521:Cyclopropanes; D014753:Vinyl Compounds; D012238:Rhodium