Completing the circuit: direct-observe 13C,15N double-quantum spectroscopy permits sequential resonance assignments near a paramagnetic center in acireductone dioxygenase.
Pochapsky
Susan Sondej
SS
Department of Chemistry, Brandeis University, MS 015, 415 South Street, Waltham, Massachusetts 02454-9110, USA.
Sunshine
Joel C
JC
Pochapsky
Thomas C
TC
D001665:Binding Sites; D002247:Carbon Isotopes; D049308:Dioxygenases / Q000737:chemistry*; D008280:Magnetics; D008958:Models, Molecular; D009532:Nickel / Q000737:chemistry; D009587:Nitrogen Isotopes; D019906:Nuclear Magnetic Resonance, Biomolecular / Q000379:methods*
D002247:Carbon Isotopes; D009587:Nitrogen Isotopes; D009532:Nickel; D049308:Dioxygenases; C083734:aci-reductone oxidase (CO-forming)