Adsorption of chloridazon from aqueous solution on modified kerolite-rich materials.
The adsorption of chloridazon (5-amine-4-chloro-2-phenylpyridazin-3(2H)-one) on kerolite samples heated at 110 degrees C (K-110), 200 degrees C (K-200), 400 degrees C (K-400), 600 degrees C (K-600) and acid-treated with H(2)SO(4) solutions of two different concentrations (0.25 and 0.5 M) (K-0.25 and K-0.5, respectively) from pure water at 25 degrees C has been studied by using batch and column experiments. The adsorption experimental data points were fitted to the Freundlich equation in order to calculate the adsorption capacities (K(f)) of the samples; K(f) values ranged from 184.7 mg kg(-1) (K-0.5) up to 2253 mg kg(-1) (K-600). This indicated that the heat treatment given to the kerolite greatly increases its adsorption capacity for the herbicide whereas the acid treatment produces a clear decrease in the amount of chloridazon adsorbed. The removal efficiency (R) was also calculated; R values ranging from 52.8% (K-0.5) up to 88.3% (K-600). Thus, the results showed that the 600 degrees C heat-treated kerolite was more effective in relation to adsorption of chloridazon and it might be reasonably used in removing this herbicide from water.
Ureña-Amate
María D
MD
Department of Inorganic Chemistry, University of Almería, Almería, Spain. damate@ual.es
Socías-Viciana
María M
MM
González-Pradas
E
E
Cantos-Molina
A
A
Villafranca-Sánchez
M
M
López-Teruel
C
C
D000327:Adsorption; D000538:Aluminum Silicates / Q000737:chemistry* / Q000494:pharmacology; D004305:Dose-Response Relationship, Drug; D006540:Herbicides / Q000737:chemistry / Q000302:isolation & purification*; D006358:Hot Temperature; D011724:Pyridazines / Q000737:chemistry / Q000302:isolation & purification*; D013464:Sulfuric Acids / Q000737:chemistry / Q000494:pharmacology; D014874:Water Pollutants, Chemical / Q000032:analysis / Q000737:chemistry / Q000302:isolation & purification*; D018508:Water Purification / Q000379:methods*
D000538:Aluminum Silicates; D006540:Herbicides; D011724:Pyridazines; D013464:Sulfuric Acids; D014874:Water Pollutants, Chemical; C005586:pyrazon