Depletion potentials in colloidal mixtures of hard spheres and rods.
The depletion potential between a hard sphere and a planar hard wall, or two hard spheres, imposed by suspended rigid spherocylindrical rods is computed by the acceptance ratio method through the application of Monte Carlo simulation. The accurate results and ideal-gas approximation results of the depletion potential are determined with the acceptance ratio method in our simulations. For comparison, the depletion potentials are also studied by using both the density functional theory and Derjaguin approximations. The density profile as a function of positions and orientations of rods, used in the density functional theory, is calculated by Monte Carlo simulation. The potential obtained by the acceptance ratio method is in good agreement with that of density functional theory under the ideal-gas approximation. The comparison between our results and those of other theories suggests that the acceptance ratio method is the only efficient method used to compute the depletion potential induced by nonspherical colloids with the volume fraction beyond the ideal-gas approximation.
Li
Weihua
W
The Key Laboratory of Molecular Engineering of Polymers, Ministry of Education, and Department of Macromolecular Science, Fudan University, Shanghai 200433, China. weihuali@fudan.edu.cn
Yang
Tao
T
Ma
Hong-ru
HR