title: Spectroscopic and electrochemical properties of organic framework of macrocylic OONNOO-donor ligand with its metal organic framework: host/guest stability measurements.
abstract: In this study, we synthesized 1,2-di(o-aminophenoxy)ethane, as the starting material, used in the preparation of a novel hexadentate OONNOO-donor macrocyclic ligand-1,4,11,14-tetraoxo-7,8-diaza-5,6:9,10;15,16:19,20-terabezocyclododeca-8,17-iene. It has twenty membered organic framework (OF), which has been designed, synthesized and characterized. Our main findings of this paper are related to the organic framework of ligand, its capacity to digest the metal ions and the stability of metal organic framework (MOFs) with cobalt(II), nickel(II) and manganese(II). The authenticity of the used organic framework and its metal complexes have been detected and observed in solid state as well as in aqueous solutions. The main observations were made on the basis of physiochemical measurements viz.: elemental analyses, molar conductance measurements, magnetic susceptibility measurements, IR, 1H NMR, 13C NMR, mass spectroscopy, electronic, ESR spectroscopy. In addition, the magnetic susceptibility and electrochemistry measurements have been made. The 1H NMR spectra suggest stereochemistry and proton movement interaction. Considering the used organic framework there are a lot of carbon atoms in the molecule reflected by the 13C NMR spectrum. All these observations gave a clear view to confirming the encapsulation; arrive at the composition, structure and geometry of encapsulated complexes. In simple words, it confirms the host/guest coordination and its stability. Electrochemical properties of the complexes have been investigated to confirm the various changes in oxidation state of metals with change in potentials with respect to current at different scan rate.
authors.affiliation: Department of Chemistry, University of Delhi, New Delhi 110007, India. chemistry_rajiv@hotmail.com
authors.forename: Rajiv
authors.initials: R
authors.lastname: Kumar
authors.forename: R P
authors.initials: RP
authors.lastname: Singh
authors.forename: R P
authors.initials: RP
authors.lastname: Singh
mesh_terms: D004563:Electrochemistry; D008024:Ligands; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008670:Metals / Q000737:chemistry*; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D026361:Reactive Nitrogen Species / Q000737:chemistry*; D013057:Spectrum Analysis
chemical_list: D008024:Ligands; D047028:Macrocyclic Compounds; D008670:Metals; D009942:Organometallic Compounds; D026361:Reactive Nitrogen Species