Palladium-catalyzed dehydrogenative cis double phosphorylation of alkynes with H-phosphonate leading to (Z)-bisphosphoryl-1-alkenes.
Dehydrogenative cis double phosphorylation of terminal alkynes with H-phosphonate took place efficiently in the presence of a divalent palladium catalyst to afford (Z)-bisphosphoryl-1-alkenes selectively.
Han
Li-Biao
LB
National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba, Ibaraki, Japan. libiao-han@aist.go.jp
Ono
Yutaka
Y
Shimada
Shigeru
S
D000475:Alkenes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D006865:Hydrogenation; D015394:Molecular Structure; D063065:Organophosphonates / Q000737:chemistry*; D009943:Organophosphorus Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D010165:Palladium / Q000737:chemistry*; D010766:Phosphorylation; D013237:Stereoisomerism
D000475:Alkenes; D000480:Alkynes; D063065:Organophosphonates; D009943:Organophosphorus Compounds; D010165:Palladium