title: Through-space MP-CPMAS experiments between spin-1/2 and half-integer quadrupolar nuclei in solid-state NMR.
abstract: We present a new CPMAS method that allows the acquisition of through-space 2D HETCOR spectra between spin-1/2 nuclei and half-integer quadrupolar nuclei in the solid state. It uses rotor-synchronized selective pulses on the quadrupolar nucleus and continuous-wave RF irradiation on the spin-1/2 nucleus to create hetero-nuclear dipolar coherences. The method is more robust, more efficient, and easier to set up than the standard CPMAS transfer.
authors.affiliation: UCCS, CNRS-8181, Lille University, Fr-59652 Villeneuve d'Ascq, France.
authors.forename: B
authors.initials: B
authors.lastname: Hu
authors.forename: J P
authors.initials: JP
authors.lastname: Amoureux
authors.forename: J
authors.initials: J
authors.lastname: Trébosc
authors.forename: S
authors.initials: S
authors.lastname: Hafner