The heteronuclear bonding between heavier Group 14 elements and transition metals: a novel trioxystannate-iron complex with an unusual stannate fragment.
A new trioxystannate-transition metal complex, {[Li][(Me(2)NCH(2)CH(2)O)(3)Sn-Fe(CO)(4)]}(2) (3), exhibiting an unusual type of the heteronuclear bonding between heavier Group 14 elements and transition metals, has been synthesised and completely characterised by NMR, Raman and IR spectroscopy in solution as well as by Raman spectroscopy and X-ray diffraction analysis in the solid state.
Khrustalev
Victor N
VN
A. N. Nesmeyanov Institute of Organoelement Compounds of RAS, Vavilov Str., 28, Moscow, 119991, Russian Federation. vkh@xray.ineos.ac.ru
Chernov
Oleg V
OV
Aysin
Rinat R
RR
Portnyagin
Ivan A
IA
Nechaev
Mikhail S
MS
Bukalov
Sergey S
SS