title: The synthesis, crystal structure and spectroscopic properties of luminescent Zn(II) complex.
abstract: A luminescent Zn(II) complex 1, ZnL2Cl2.2H2O has been synthesized where L=2,2',2''-(1,3,5-benzenetriyltrimethylidyne) as a yellow crystal. Single crystal X-ray analysis of the compound 1 shows a distorted tetrahedral structure. The compound 1 crystallizes in monoclinic, space group C2/c with a = 20.3151(19), b = 8.7299(9), c = 24.626(2) angstroms, beta = 107.474(2) degrees , V = 4165.9(7) A3. At room temperature, the complex 1 exhibits an intense blue emission at 474 nm upon 380 nm excitation.
authors.affiliation: Department of Chemistry, Wuhan University, Wuhan 430072, China.
authors.forename: Ping
authors.initials: P
authors.lastname: Cai
authors.forename: Jing-Ran
authors.initials: JR
authors.lastname: Hou
authors.forename: Tian-Shu
authors.initials: TS
authors.lastname: Liu
authors.forename: Gong-Zhen
authors.initials: GZ
authors.lastname: Cheng
authors.forename: Tian-You
authors.initials: TY
authors.lastname: Peng
authors.forename: Zheng-He
authors.initials: ZH
authors.lastname: Peng
mesh_terms: D018360:Crystallography, X-Ray; D005456:Fluorescent Dyes / Q000138:chemical synthesis* / Q000737:chemistry; D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D017967:Zinc Compounds / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D005456:Fluorescent Dyes; D017967:Zinc Compounds