Synthesis and properties of alkynethiolate gold(I) complexes.
A series of alkynethiolate gold(I) derivatives have been synthesised by the cleavage of 4-monosubstituted 1,2,3-thiadiazoles in the presence of strong bases. The syntheses of the 1.2,3-thiadiazoles with p-cyanophenyl, p-tolyl, 2-thienyl, 3-thienyl and 9,9-dimethylfluoren-2-yl fragments are also described. All the complexes have been characterised by spectroscopic techniques and the complexes [Au(p-CH3-C6H4-C[triple bond]C-S)PPh3], [Au(3-C4H3S-C[triple bond]C-S)PPh3] and PPN[Au(p-CH3-C6H4-C[triple bond]C-S)(C6F5)] by X-ray analysis. The electrochemically polymerizable mononuclear bis(alkynethiolate) gold(I) complex PPN[Au(3-C4H3S-C[triple bond]C-S)2] is also described, including its electropolymerization and electrochemical properties.
Lardiés
Nora
N
Departamento de Química Inorganica, Instituto de Ciencia de Materiales de Aragón, Universidad de Zaragoza-CSIC, Zaragoza, Spain.
Romeo
Inocencio
I
Cerrada
Elena
E
Laguna
Mariano
M
Skabara
Peter J
PJ
D006046:Gold / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D013055:Spectrophotometry, Infrared; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D014961:X-Ray Diffraction
D013438:Sulfhydryl Compounds; D006046:Gold