title: Membrane properties change in fine-pore aeration diffusers: full-scale variations of transfer efficiency and headloss.
abstract: Fine-pore diffusers are the most common aeration system in municipal wastewater treatment. Punched polymeric membranes are often used in fine-pore aeration due to their advantageous initial performance. These membranes are subject to fouling and scaling, resulting in increased headloss and reduced oxygen transfer efficiency, both contributing to increased plant energy costs. This paper describes and discusses the change in material properties for polymeric fine-pore diffusers, comparing new and used membranes. Three different diffuser technologies were tested and sample diffusers from two wastewater treatment facilities were analysed. The polymeric membranes analysed in this paper were composed of ethylene-propylene-diene monomer (EPDM), polyurethane, and silicon. Transfer efficiency is usually lower with longer times in operation, as older, dilated orifices produce larger bubbles, which are unfavourable to mass transfer. At the same time, headloss increases with time in operation, since membranes increase in rigidity and hardness, and fouling and scaling phenomena occur at the orifice opening. Change in polymer properties and laboratory test results correlate with the decrease in oxygen transfer efficiency.
authors.affiliation: Civil and Environmental Engineering Department, University of California, Irvine, Irvine, CA 92697-2175, USA. bidui@ucla.edu
authors.forename: Diego
authors.initials: D
authors.lastname: Rosso
authors.forename: Judy A
authors.initials: JA
authors.lastname: Libra
authors.forename: Wolfgang
authors.initials: W
authors.lastname: Wiehe
authors.forename: Michael K
authors.initials: MK
authors.lastname: Stenstrom
mesh_terms: D000332:Aerobiosis; D004058:Diffusion; D020724:Elastomers / Q000737:chemistry; D005030:Ethylenes / Q000737:chemistry; D008567:Membranes, Artificial; D010100:Oxygen; D011140:Polyurethanes / Q000737:chemistry; D016062:Porosity; D011312:Pressure; D012825:Silicon / Q000737:chemistry; D018508:Water Purification
chemical_list: D020724:Elastomers; D005030:Ethylenes; D008567:Membranes, Artificial; D011140:Polyurethanes; C505585:ethylene-propylene-diene-monomer; D010100:Oxygen; D012825:Silicon