Preparation and characterization of chemically derived (Pb,La)TiO (3) thin films.
Ferroelectric lead lanthanum titanate (PLT) thin films with composition varying from pure PbTiO(3) to PLT 25/100 (0 to 25 mol.% La) were prepared by spin-casting 0.25M solutions containing metallo-organic precursors of Pb, La, and Ti. The dielectric and ferroelectric properties of the thin (410-nm) films were characterized. The dielectric constants of the films varied from ~80 to ~690 for La contents varying from 0 to 25 mol%, respectively. Dissipation factors varied from ~0.03 to ~0.09 over the same compositional range. The temperature dependence of the dielectric properties was also studied to determine the effects of La content on the Curie point (T(c)). As expected, T(c ) was found to decrease with increasing La concentration. Coercive field and remanent polarization also decreased with increased La concentration.
Schwartz
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Sandia Nat. Lab., Albuquerque, NM.
Tuttle
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Doughty
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Land
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Goodnow
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Hernandez
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Zender
T J
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Martinez
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