Adsorption of toluene on carbon nanofibers prepared by electrospinning.
This paper reports the novel results of activated carbon nanofibers (ACNF) used to improve the toluene adsorption capacity. The ACNF was prepared by stabilization, carbonization and activation after electrospinning the polymer solution of polyacrylonitrile (PAN) in N, N-dimethylformamide. The average diameter of the ACNF was approximately 300 nm, ranging from 200 to 500 nm. The toluene adsorption capacity of ACNF10 activated at 1000 degrees C increased to 65 g-toluene/100 g-ACNF. This was attributed to the high specific surface area (1403 m(2)/g), large micropore volume (0.505 cm(3)/g), and narrow average pore diameter (6.0 A). The oxygen to carbon ratio (O/C ratio) in ACNF10 was 1.8%. This O/C ratio appears to induce a higher toluene adsorption capacity, which originates from a non-polar interaction between the ACNF surface and toluene. In conclusion, the electrospun ACNF prepared in this study promotes the adsorption of toluene through the high specific surface area, large pore volume, narrow pore diameter and low O/C ratio.
Oh
Gil-Young
GY
Faculty of Applied Chemical Engineering, Chonnam National University, Buk-Gu, Gwangju, Republic of Korea.
Ju
Young-Wan
YW
Kim
Mi-Young
MY
Jung
Hong-Ryun
HR
Kim
Hyung Jin
HJ
Lee
Wan-Jin
WJ
D000180:Acrylic Resins / Q000737:chemistry; D000327:Adsorption; D000393:Air Pollutants / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D000077482:Carbon Fiber; D049329:Nanostructures / Q000737:chemistry*; D016062:Porosity; D014050:Toluene / Q000737:chemistry*
D000180:Acrylic Resins; D000393:Air Pollutants; D000077482:Carbon Fiber; C010504:polyacrylonitrile; D014050:Toluene; D002244:Carbon