A new pd-catalyzed cascade reaction for the synthesis of strained aromatic polycycles.
Two new palladium catalyzed cascade reactions involving a 4-exo-dig cyclocarbopalladation are described. These processes are shown to convert bromoenediynes and bromodienynes into strained aromatic compounds in a single step.
Blond
Gaëlle
G
Université Louis Pasteur de Strasbourg (LC01 UMR 7175 CNRS/ULP), Faculté de Pharmacie, 74 route du Rhin, Illkirch-Cedex, France.
Bour
Christophe
C
Salem
Bahaâ
B
Suffert
Jean
J
D002384:Catalysis; D009682:Magnetic Resonance Spectroscopy; D010165:Palladium / Q000737:chemistry*; D011083:Polycyclic Compounds / Q000737:chemistry*
D011083:Polycyclic Compounds; D010165:Palladium