Ligand- and anion-directed assembly of exo-coordinated mercury(II) halide complexes with O2S2-donor macrocycles.
Assembly reactions of mercury(II) halides (Cl, Br, and I) with two O2S2 macrocycles (L(1) and L(2)) having different interdonor (S...S) distances were investigated, and four types of supramolecular complexes (1-4b) were obtained depending on the S...S distances as well as the size of the halide anions. Photoluminescence of these compounds was also studied.
Lee
So Young
SY
Department of Chemistry (BK21) and Research Institute of Natural Science, Gyeongsang National University, Jinju 660-701, South Korea.
Park
Sunhong
S
Kim
Hyun Jee
HJ
Jung
Jong Hwa
JH
Lee
Shim Sung
SS