Development of general catalytic allylation of acylhydrazones with pinacolyl allylboronate using an indium(I) catalyst.
Catalytic allylation of various acylhydrazones using a group 13 metal reagent (boron) in combination with a group 13 metal catalyst in its low-oxidation state (indium) has been developed. This operationally simple carbon-carbon bond-forming reaction displays remarkable substrate scope and functional group tolerance.
Schneider
Uwe
U
Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, Japan Science and Technology Agency, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Chen
I-Hon
IH
Kobayashi
Shū
S
D000475:Alkenes / Q000737:chemistry*; D001897:Boronic Acids / Q000737:chemistry*; D002073:Butanes / Q000737:chemistry*; D002384:Catalysis; D006835:Hydrazones / Q000737:chemistry*; D007204:Indium / Q000737:chemistry*; D015394:Molecular Structure
D000475:Alkenes; D001897:Boronic Acids; D002073:Butanes; D006835:Hydrazones; C523175:pinacolyl allylboronate; D007204:Indium