X-ray crystal structure and magnetic and photophysical properties of novel copper(II) N-oxide adduct [(4-MPyO)2(CuCl2)2(H2O)(C2H5OH)] (4-MPyO = 4-(4-methoxystyryl)pyridine N-oxide).
A new mixed adduct, (4-MPyO)2(CuCl2)2(H2O)(C2H5OH) [where 4-MPyO is the 4-(4-methoxystyryl)pyridine N-oxide], was obtained for the first time. It has been characterized by X-ray studies, IR, electronic absorption, and emission spectra, lifetime measurements, and variable-temperature magnetic susceptibility measurements in the range 80-300 K. The single-crystal X-ray diffraction shows that the geometry around both of the copper(II) ions can be described as a tetragonal pyramid with a trapezoidal base at the corners of which are two oxygen atoms of N-oxide and two chlorine atoms. The oxygen atoms of either water or ethanol are at the apex of the pyramid. Besides that, two molecules of the adduct form a double-hydrogen-bonded superdimer in which they are connected to each other through hydrogen bonds of the O-H...Cl type as formed between the chlorine atoms and ethanol molecule (Cl...O 3.22 A). The copper(II) atoms are antiferromagnetically coupled within a dimeric unit, and a singlet-triplet separation of 2 J value (1100 cm(-1)) is greater than the value expected from Hatfield's rule for the bridging angles Cu-O-Cu equal 108.9 degrees and 110.2 degrees . By means of the PM3-calculated values of vertical excitation energies, the ligand-to-metal charge-transfer (LMCT) and the metal-to-ligand charge-transfer transitions in the unresolved experimental absorption spectra of I have been revealed. From the large Stokes shift value of emission spectra in solvents of different polarity (more than 6500 cm(-1) in acetonitrile), the charge-transfer (CT) nature of the emissive (LMCT) state of I has been concluded. Biexponential decay of the excited complex in acetonitrile and frozen propanol suggests that the two different CT conformers (0.8, 4.12 ns and 1.99, 15.2 ns, respectively) are present in the excited state in solution while only one CT form is indicated by a monoexponential decay (9.0 micros) in the solid.
Nizhnik
Yakov P
YP
Department of Molecular Biology, Biological and Organic Chemistry, Petrozavodsk State University, pr. Lenina 33, 185910 Petrozavodsk, Republic Karelia, Russia. yakov_nizhnik@mail.ru
Szemik-Hojniak
Anna
A
Deperasińska
Irena
I
Jerzykiewicz
Lucjan B
LB
Korabik
Maria
M
Hojniak
Marek
M
Andreev
Vladimir P
VP
D003300:Copper / Q000737:chemistry*; D018360:Crystallography, X-Ray / Q000379:methods; D008280:Magnetics; D008956:Models, Chemical; D008958:Models, Molecular; D010087:Oxides / Q000737:chemistry; D010777:Photochemistry / Q000379:methods; D011725:Pyridines / Q000737:chemistry*
D010087:Oxides; D011725:Pyridines; D003300:Copper; C029892:cupric chloride