Synthesis and complexation properties towards the ammonium cation of aza-coronand analogues containing sucrose.
1',2,3,3',4,4'-Hexa-O-benzyl-sucrose was converted in good yields into the macrocyclic receptors containing two and three nitrogen atoms in the ring. Their complexation properties towards the ammonium cation were significantly higher than for receptors without any nitrogen atoms in the ring.
Jarosz
Slawomir
S
Institute of Organic Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224 Warsaw, Poland. sljar@icho.edu.pl
Lewandowski
Bartosz
B
D001555:Benzene Derivatives / Q000138:chemical synthesis / Q000737:chemistry; D002853:Chromatography, Liquid; D047248:Crown Compounds / Q000138:chemical synthesis / Q000737:chemistry; D043844:Crown Ethers / Q000138:chemical synthesis* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D015394:Molecular Structure; D011188:Potassium / Q000737:chemistry; D000644:Quaternary Ammonium Compounds / Q000737:chemistry*; D021241:Spectrometry, Mass, Electrospray Ionization; D013395:Sucrose / Q000031:analogs & derivatives / Q000138:chemical synthesis* / Q000737:chemistry
D001555:Benzene Derivatives; D047248:Crown Compounds; D043844:Crown Ethers; D000644:Quaternary Ammonium Compounds; D013395:Sucrose; D011188:Potassium