Metal-mediated transformation of a triazinephenanthridinium ligand leading to a {Pd5} coordination complex observed crystallographically and by cryospray mass spectrometry.
The formation of a pentanuclear palladium(II) complex with a phenanthridinonetriazine-based ligand system, which itself is formed by a metal-mediated rearrangement of a triazinephenanthridinium proligand, is described.
Kitson
Phil J
PJ
WestChem Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, UK.
Song
Yu-Fei
YF
Gamez
Patrick
P
de Hoog
Paul
P
Long
De-Liang
DL
Parenty
Alexis D C
AD
Reedijk
Jan
J
Cronin
Leroy
L
D018360:Crystallography, X-Ray / Q000379:methods; D005615:Freezing; D007700:Kinetics; D008024:Ligands; D013058:Mass Spectrometry / Q000379:methods; D008958:Models, Molecular; D010165:Palladium / Q000737:chemistry*; D010617:Phenanthridines / Q000737:chemistry*; D014227:Triazines / Q000737:chemistry*
D008024:Ligands; D010617:Phenanthridines; D014227:Triazines; D010165:Palladium