title: Development of mesoporosity during phosphoric acid activation of wood in steam atmosphere.
abstract: Oak and birch were used as precursors to produce the activated carbons (ACs) with well-developed mesoporosity by phosphoric acid-promoted activation in a steam atmosphere. The effect of experimental variables such as the amount of activating agent, the soaking time and the type of wood on the development of porous structure upon heating at 480 degrees C was investigated. The materials were characterized by N2 adsorption at 77K, mercury porosimetry and elemental analysis. It was demonstrated that increasing impregnation ratio favors the development of micropores and small mesopores of 2-5nm, whereas the soaking time promotes the creation of large mesopores, between 10 and 50nm. Compared to birch, the oak activation using phosphoric acid in the same conditions gives ACs with lower mesopore volume and higher contribution of small mesopores that reflects the differences between both precursors in their biopolymer composition. The presence of steam in the H3PO4 activation process compared to nitrogen facilitates the development of mesoporosity to much higher extent for the birch than that of oak. The ACs prepared in this work show the BET surface area ranging from 800 to 2250m2g(-1), the total pore volume of 0.35-2.04cm3g(-1) with mesopore fraction between 0.06 and 0.68.
authors.affiliation: Wrocław University of Technology, Faculty of Chemistry, Department of Polymer and Carbonaceous Materials, Gdańska 7/9, 50-344 Wrocław, Poland.
authors.forename: Aleksandra
authors.initials: A
authors.lastname: Klijanienko
authors.forename: Ewa
authors.initials: E
authors.lastname: Lorenc-Grabowska
authors.forename: Grazyna
authors.initials: G
authors.lastname: Gryglewicz
mesh_terms: D010756:Phosphoric Acids / Q000737:chemistry*; D013227:Steam; D014934:Wood
chemical_list: D010756:Phosphoric Acids; D013227:Steam; C030242:phosphoric acid