The synthesis, crystal structure and spectroscopic properties of luminescent Zn(II) complex.
A luminescent Zn(II) complex 1, ZnL2Cl2.2H2O has been synthesized where L=2,2',2''-(1,3,5-benzenetriyltrimethylidyne) as a yellow crystal. Single crystal X-ray analysis of the compound 1 shows a distorted tetrahedral structure. The compound 1 crystallizes in monoclinic, space group C2/c with a = 20.3151(19), b = 8.7299(9), c = 24.626(2) angstroms, beta = 107.474(2) degrees , V = 4165.9(7) A3. At room temperature, the complex 1 exhibits an intense blue emission at 474 nm upon 380 nm excitation.
Cai
Ping
P
Department of Chemistry, Wuhan University, Wuhan 430072, China.
Hou
Jing-Ran
JR
Liu
Tian-Shu
TS
Cheng
Gong-Zhen
GZ
Peng
Tian-You
TY
Peng
Zheng-He
ZH
D018360:Crystallography, X-Ray; D005456:Fluorescent Dyes / Q000138:chemical synthesis* / Q000737:chemistry; D006860:Hydrogen Bonding; D008958:Models, Molecular; D015394:Molecular Structure; D017967:Zinc Compounds / Q000138:chemical synthesis* / Q000737:chemistry
D005456:Fluorescent Dyes; D017967:Zinc Compounds