Thermal rearrangement of phosphine-B(C6F5)3 adducts.
A series of tertiary and secondary phosphine-B(C6F5)3 adducts are shown to undergo facile, thermal-induced rearrangement to give zwitterionic species of the form R3P(C6F4)BF(C6F5)2 and R2PH(C6F4)BF(C6F 5)2, respectively.
Welch
Gregory C
GC
Department of Chemistry and Biochemistry, University of Windsor, Windsor, Ontario, Canada N9B 3P4.
Holtrichter-Roessmann
Thorsten
T
Stephan
Douglas W
DW