title: Photodegradation of acetaminophen in TiO(2) suspended solution.
abstract: This study investigated the photocatalytic degradation of acetaminophen (APAP) in TiO(2) suspended solution under a 250 W metal halide lamp. The influence of some parameters on the degradation of acetaminophen was studied and described in details, such as initial APAP concentration, initial pH value and TiO(2) dosage. After 100 min irradiation, about 95% of APAP is decomposed in the 1.0 g L(-1) TiO(2) aqueous solution with an initial concentration of 100 micromol L(-1). The effect of adsorption at three different pH values has also been analyzed and it has been conducted that pH 3.5, at which APAP was readily adsorbed also degraded at a faster rate. Reaction rate at pH 6.9 and pH 9.5 was 2.84 and 2.96 microM min(-1), respectively. Direct hole (h(+)) oxidation and ipso-substitution was found to be the main initial step for APAP degradation. Main reaction intermediates and products were identified by GC/MS analysis. The mechanism of acetaminophen photocatalytic degradation in TiO(2) suspended solution was studied not only experimentally but also theoretically by calculating the frontier electron density of APAP. The results obtained indicated that TiO(2) photocatalytic degradation is a highly effective way to remove APAP from wastewater and drinking water without any generation of more toxic products.
authors.affiliation: School of Resources and Environmental Science, Hubei Key Laboratory of Biomass-Resources, Wuhan University, Wuhan, PR China.
authors.forename: Xu
authors.initials: X
authors.lastname: Zhang
authors.forename: Feng
authors.initials: F
authors.lastname: Wu
authors.forename: Xuwei
authors.initials: X
authors.lastname: Wu
authors.forename: Pengyu
authors.initials: P
authors.lastname: Chen
authors.forename: Nansheng
authors.initials: N
authors.lastname: Deng
mesh_terms: D000082:Acetaminophen / Q000737:chemistry*; D000327:Adsorption; D002384:Catalysis; D004867:Equipment Design; D006863:Hydrogen-Ion Concentration; D015394:Molecular Structure; D019999:Pharmaceutical Solutions / Q000737:chemistry*; D010777:Photochemistry; D014025:Titanium / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000737:chemistry*
chemical_list: D019999:Pharmaceutical Solutions; D014874:Water Pollutants, Chemical; C009495:titanium dioxide; D000082:Acetaminophen; D014025:Titanium