title: Palladium-catalyzed trans- and cis-carboboration of alkynes tethered to chloroborane with organozirconium reagents: ligand-dependent complementary stereoselectivity.
authors.affiliation: Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University Katsura, Nishikyo-ku, Kyoto 615-8510, Japan.
authors.forename: Masaki
authors.initials: M
authors.lastname: Daini
authors.forename: Akihiko
authors.initials: A
authors.lastname: Yamamoto
authors.forename: Michinori
authors.initials: M
authors.lastname: Suginome
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D001881:Borates / Q000138:chemical synthesis* / Q000737:chemistry*; D002384:Catalysis; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D015040:Zirconium / Q000737:chemistry*
chemical_list: D000480:Alkynes; D001881:Borates; D008024:Ligands; D009942:Organometallic Compounds; D010165:Palladium; D015040:Zirconium