title: Metal-mediated transformation of a triazinephenanthridinium ligand leading to a {Pd5} coordination complex observed crystallographically and by cryospray mass spectrometry.
abstract: The formation of a pentanuclear palladium(II) complex with a phenanthridinonetriazine-based ligand system, which itself is formed by a metal-mediated rearrangement of a triazinephenanthridinium proligand, is described.
authors.affiliation: WestChem Department of Chemistry, University of Glasgow, Glasgow G12 8QQ, UK.
authors.forename: Phil J
authors.initials: PJ
authors.lastname: Kitson
authors.forename: Yu-Fei
authors.initials: YF
authors.lastname: Song
authors.forename: Patrick
authors.initials: P
authors.lastname: Gamez
authors.forename: Paul
authors.initials: P
authors.lastname: de Hoog
authors.forename: De-Liang
authors.initials: DL
authors.lastname: Long
authors.forename: Alexis D C
authors.initials: AD
authors.lastname: Parenty
authors.forename: Jan
authors.initials: J
authors.lastname: Reedijk
authors.forename: Leroy
authors.initials: L
authors.lastname: Cronin
mesh_terms: D018360:Crystallography, X-Ray / Q000379:methods; D005615:Freezing; D007700:Kinetics; D008024:Ligands; D013058:Mass Spectrometry / Q000379:methods; D008958:Models, Molecular; D010165:Palladium / Q000737:chemistry*; D010617:Phenanthridines / Q000737:chemistry*; D014227:Triazines / Q000737:chemistry*
chemical_list: D008024:Ligands; D010617:Phenanthridines; D014227:Triazines; D010165:Palladium