Preparation of functionalized alkylmagnesium derivatives using an I/Mg-exchange.
Functionalized alkylmagnesium reagents bearing an acetal, a ketal, an ester, or a pyridine ring were prepared by an I/Mg-exchange using iPr2Mg.LiCl or ClMg(CH2)5MgCl.2LiCl starting from functionalized primary alkyl iodides.
Rauhut
Christian B
CB
Department Chemie und Biochemie, Ludwig-Maximilians-Universität, Butenandtstrasse 5-13, 81377, München, Germany.
Vu
Viet Anh
VA
Fleming
Fraser F
FF
Knochel
Paul
P