Zn-catalyzed asymmetric allylation for the synthesis of optically active allylglycine derivatives. Regio- and stereoselective formal alpha-addition of allylboronates to hydrazono esters.
Fujita
Mari
M
Department of Chemistry, School of Science and Graduate School of Pharmaceutical Sciences, The University of Tokyo, The HFRE Division, ERATO, Japan Science Technology Agency, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Nagano
Takashi
T
Schneider
Uwe
U
Hamada
Tomoaki
T
Ogawa
Chikako
C
Kobayashi
Shū
S
D000478:Alkylation; D000501:Allylglycine / Q000031:analogs & derivatives* / Q000138:chemical synthesis* / Q000737:chemistry; D001897:Boronic Acids / Q000737:chemistry*; D002384:Catalysis; D004952:Esters / Q000737:chemistry*; D015394:Molecular Structure; D055095:Optics and Photonics; D013237:Stereoisomerism; D015032:Zinc / Q000737:chemistry*
D001897:Boronic Acids; D004952:Esters; D000501:Allylglycine; D015032:Zinc