Simple rhodium-chlorophosphine pre-catalysts for the ortho-arylation of phenols.
Simple chlorodiisopropylphosphine adducts of rhodium, either pre-formed or formed in situ, prove to be highly effective catalysts for the ortho-arylation of phenols.
Bedford
Robin B
RB
School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK BS8 1TS. r.bedford@bristol.ac.uk
Betham
Michael
M
Caffyn
Andrew J M
AJ
Charmant
Jonathan P H
JP
Lewis-Alleyne
Lesley C
LC
Long
Philip D
PD
Polo-Cerón
Dorian
D
Prashar
Sanjiv
S
D002384:Catalysis; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010636:Phenols / Q000138:chemical synthesis* / Q000737:chemistry; D010720:Phosphines / Q000737:chemistry*; D011407:Propane / Q000031:analogs & derivatives* / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D010636:Phenols; D010720:Phosphines; C528654:chlorodiisopropylphosphine; D012238:Rhodium; D011407:Propane