title: Simple rhodium-chlorophosphine pre-catalysts for the ortho-arylation of phenols.
abstract: Simple chlorodiisopropylphosphine adducts of rhodium, either pre-formed or formed in situ, prove to be highly effective catalysts for the ortho-arylation of phenols.
authors.affiliation: School of Chemistry, University of Bristol, Cantock's Close, Bristol, UK BS8 1TS. r.bedford@bristol.ac.uk
authors.forename: Robin B
authors.initials: RB
authors.lastname: Bedford
authors.forename: Michael
authors.initials: M
authors.lastname: Betham
authors.forename: Andrew J M
authors.initials: AJ
authors.lastname: Caffyn
authors.forename: Jonathan P H
authors.initials: JP
authors.lastname: Charmant
authors.forename: Lesley C
authors.initials: LC
authors.lastname: Lewis-Alleyne
authors.forename: Philip D
authors.initials: PD
authors.lastname: Long
authors.forename: Dorian
authors.initials: D
authors.lastname: Polo-Cerón
authors.forename: Sanjiv
authors.initials: S
authors.lastname: Prashar
mesh_terms: D002384:Catalysis; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010636:Phenols / Q000138:chemical synthesis* / Q000737:chemistry; D010720:Phosphines / Q000737:chemistry*; D011407:Propane / Q000031:analogs & derivatives* / Q000737:chemistry; D012238:Rhodium / Q000737:chemistry*
chemical_list: D008024:Ligands; D009942:Organometallic Compounds; D010636:Phenols; D010720:Phosphines; C528654:chlorodiisopropylphosphine; D012238:Rhodium; D011407:Propane