title: An efficient and straightforward access to sulfur substituted [2.2]paracyclophanes: application to stereoselective sulfenate salt alkylation.
abstract: A straightforward and high-yielding access to various [2.2]paracyclophanes possessing a sulfur-based functional group is reported, the key step being a SEAr reaction mediated by a sulfonium salt. The versatility of the methodology was exemplified by an original application in sulfenate salt chemistry, from which a remarkable chirality transfer was observed.
authors.affiliation: Laboratoire de Chimie Moléculaire et Thio-organique, ENSICAEN, Université de Caen Basse-Normandie, CNRS, 6 Boulevard du Maréchal Juin, 14050 Caen, France.
authors.forename: Jean-François
authors.initials: JF
authors.lastname: Lohier
authors.forename: Florian
authors.initials: F
authors.lastname: Foucoin
authors.forename: Paul-Alain
authors.initials: PA
authors.lastname: Jaffrès
authors.forename: José I
authors.initials: JI
authors.lastname: Garcia
authors.forename: Jana
authors.initials: J
authors.lastname: Sopková-de Oliveira Santos
authors.forename: Stéphane
authors.initials: S
authors.lastname: Perrio
authors.forename: Patrick
authors.initials: P
authors.lastname: Metzner
mesh_terms: D000478:Alkylation; D047028:Macrocyclic Compounds / Q000737:chemistry*; D008958:Models, Molecular; D013237:Stereoisomerism; D013455:Sulfur / Q000737:chemistry*
chemical_list: D047028:Macrocyclic Compounds; D013455:Sulfur