title: A novel organotin-substituted polyoxomolybdate cluster.
abstract: A novel organotin-substituted polyoxomolybdate cluster (H(3)O)(16)[(H(2)O)(2)Mo(V)O(OH)](2){Mo(VI)(28)Mo(II)(4)(NO)(4)(BuSnO)(2)[BuSn(OH)(2)](2)O(102)(H(2)O)(12)}.18H(2)O was synthesized in a 'one-pot' reaction by adopting the reduction-oxidation-reconstitution self-assembly process, which shows a {Mo(34)(NO)(4)Sn(4)} mixed metal skeleton, which is constructed from two {Mo(16)(NO)(2)Sn(2)} subunits being linked by two MoO(6) octahedra.
authors.affiliation: Department of Chemistry, Northeast Normal University, Changchun, 130024, People's Republic of China.
authors.forename: Shun-Li
authors.initials: SL
authors.lastname: Li
authors.forename: Yong-Mei
authors.initials: YM
authors.lastname: Zhang
authors.forename: Jian-Fang
authors.initials: JF
authors.lastname: Ma
authors.forename: Ya-Qian
authors.initials: YQ
authors.lastname: Lan
authors.forename: Jin
authors.initials: J
authors.lastname: Yang