title: Allylic phosphinates via palladium-catalyzed allylation of H-phosphinic acids with allylic alcohols.
abstract: A novel catalytic allylation of H-phosphinic acids is described. Using Pd/xantphos (2 mol %), H-phosphinic acids react directly with allylic alcohols to produce P-allylated disubstituted phosphinic acids.
authors.affiliation: Department of Chemistry, Box 298860, Texas Christian University, Fort Worth, Texas 76129, USA.
authors.forename: Laëtitia
authors.initials: L
authors.lastname: Coudray
authors.forename: Karla
authors.initials: K
authors.lastname: Bravo-Altamirano
authors.forename: Jean-Luc
authors.initials: JL
authors.lastname: Montchamp
mesh_terms: D002384:Catalysis; D010165:Palladium / Q000737:chemistry*; D010721:Phosphinic Acids / Q000737:chemistry*; D020005:Propanols / Q000737:chemistry*
chemical_list: D010721:Phosphinic Acids; D020005:Propanols; C006463:allyl alcohol; D010165:Palladium