Reversibility in the protonolysis of a beta-diketiminate stabilised calcium bis(trimethylsilyl)amide with benzylamine.
Protonolysis of the beta-diketiminate calcium bis(trimethylsilyl)amide [{ArNC(Me)CHC(Me)NAr}Ca{N(SiMe3)2}(THF)] with benzylamine is reversible and forms a quantifiable equilibrium mixture.
Barrett
Anthony G M
AG
Department of Chemistry, Imperial College London, Exhibition Road, South Kensington, London, UK.
Crimmin
Mark R
MR
Hill
Michael S
MS
Kociok-Köhn
Gabriele
G
Lachs
Jennifer R
JR
Procopiou
Panayiotis A
PA
D001596:Benzylamines / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007649:Ketamine / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D011522:Protons; D014297:Trimethylsilyl Compounds / Q000737:chemistry*
D001596:Benzylamines; D011522:Protons; D014297:Trimethylsilyl Compounds; C531871:calcium bis(trimethylsilyl)amide; D007649:Ketamine; C030796:benzylamine