title: Solid-phase synthesis of graphitic carbon nanostructures from iron and cobalt gluconates and their utilization as electrocatalyst supports.
abstract: We present a novel and facile synthesis methodology for obtaining graphitic carbon structures from Fe(II) and Co(II) gluconates. The formation of graphitic carbon can be carried out in only one step by means of heat treatment of these organic salts at a temperature of 900 degrees C or 1000 degrees C under inert atmosphere. This process consists of the following steps: (a) pyrolysis of the organic gluconate and its transformation to amorphous carbon, (b) conversion of Fe(2+) and Co(2+) ions to Fe(2)O(3) and CoO and their subsequent reduction to metallic nanoparticles by the carbon and (c) conversion of a fraction of formed amorphous carbon to graphitic structures by Fe and Co nanoparticles that act as catalysts in the graphitization process. The removal of the amorphous carbon and metallic nanoparticles by means of oxidative treatment (KMnO(4) in an acid solution) allows graphitic carbon nanostructures (GCNs) to be selectively recovered. The GCNs thus obtained (i.e. nanocapsules and nanopipes) have a high crystallinity as evidenced by TEM/SAED, XRD and Raman analysis. In addition, we used these GCNs as supports for platinum nanoparticles, which were well dispersed (mean Pt size approximately 2.5-3.2 nm). Most electrocatalysts prepared in this way have a high electrocatalytical surface area, up to 90 m(2) g(-1) Pt, and exhibit high catalytic activities toward methanol electrooxidation.
authors.affiliation: Instituto Nacional del Carbón (CSIC), P.O. Box 73, 33080-Oviedo, Spain.
authors.forename: M
authors.initials: M
authors.lastname: Sevilla
authors.forename: C
authors.initials: C
authors.lastname: Salinas Martínez-de Lecea
authors.forename: T
authors.initials: T
authors.lastname: Valdés-Solís
authors.forename: E
authors.initials: E
authors.lastname: Morallón
authors.forename: A B
authors.initials: AB
authors.lastname: Fuertes
mesh_terms: D001272:Atmosphere; D002244:Carbon / Q000737:chemistry*; D002384:Catalysis; D003035:Cobalt / Q000737:chemistry*; D004563:Electrochemistry; D005942:Gluconates / Q000737:chemistry*; D006108:Graphite / Q000138:chemical synthesis* / Q000737:chemistry; D007501:Iron / Q000737:chemistry*; D000432:Methanol / Q000737:chemistry; D008968:Molecular Conformation; D049329:Nanostructures / Q000737:chemistry*; D010084:Oxidation-Reduction; D010316:Particle Size; D010984:Platinum / Q000737:chemistry; D013499:Surface Properties; D013696:Temperature
chemical_list: D005942:Gluconates; D003035:Cobalt; D010984:Platinum; D002244:Carbon; D006108:Graphite; D007501:Iron; D000432:Methanol