title: Crystallization induced chiral locking of a central labile core in a star-shaped tetra-nuclear complex.
abstract: The central labile Al(III) core of a star-shaped tetra-nuclear metal complex, [{Delta-Ru(III)(acac)(2)(taet)}(3)Al(III)] (acac = acetylacetonato; taet = tetraacetylethanato), which was synthesized by reacting Delta-[Ru(III)(acac)(2)(taetH)] (taetH = singly protonated taet) with an Al(III) ion in solution, was found to be locked as a Lambda-form in the solid state.
authors.affiliation: The University of Tokyo, Tokyo, Japan and PRESTO, JST, Japan. h-sato@eps.u-tokyo.ac.jp
authors.forename: Hisako
authors.initials: H
authors.lastname: Sato
authors.forename: Yuka
authors.initials: Y
authors.lastname: Furuno
authors.forename: Yutaka
authors.initials: Y
authors.lastname: Fukuda
authors.forename: Kentaro
authors.initials: K
authors.lastname: Okamoto
authors.forename: Akihiko
authors.initials: A
authors.lastname: Yamagishi