Asymmetric synthesis of bicyclic amidines via rhodium-catalyzed [2+2+2] cycloaddition of carbodiimides.
Yu
Robert T
RT
Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, USA.
Rovis
Tomislav
T
D000480:Alkynes / Q000737:chemistry; D000578:Amidines / Q000138:chemical synthesis* / Q000737:chemistry; D001643:Bridged Bicyclo Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D002234:Carbodiimides / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D008024:Ligands; D015394:Molecular Structure; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D000480:Alkynes; D000578:Amidines; D001643:Bridged Bicyclo Compounds; D002234:Carbodiimides; D008024:Ligands; D012238:Rhodium