title: Glycosidations of 2-deoxy glycosyl dithiophosphates using a tagged iodine(III)-promoter for simple purification.
abstract: The preparation of the 4-i-butylsulfonate derivative of the Zefirov reagent (5) and its use in a novel purification strategy for iodine(III)-promoted glycosidations of 2-deoxy diethyldithiophosphate glycosides is described.
authors.affiliation: Institut für Organische Chemie and Zentrum für Biomolekulare Wirkstoffe (BMWZ), Leibniz Universität Hannover, Schneiderberg 1b, 30167 Hannover, Germany.
authors.forename: Eike
authors.initials: E
authors.lastname: Kunst
authors.forename: Florian
authors.initials: F
authors.lastname: Gallier
authors.forename: Gilles
authors.initials: G
authors.lastname: Dujardin
authors.forename: Andreas
authors.initials: A
authors.lastname: Kirschning
mesh_terms: D017738:Alkanesulfonic Acids / Q000138:chemical synthesis / Q000737:chemistry; D006027:Glycosides / Q000138:chemical synthesis* / Q000737:chemistry; D006031:Glycosylation; D006847:Hydrocarbons, Iodinated / Q000737:chemistry*; D015394:Molecular Structure; D010710:Phosphates / Q000138:chemical synthesis* / Q000737:chemistry; D013237:Stereoisomerism
chemical_list: D017738:Alkanesulfonic Acids; D006027:Glycosides; D006847:Hydrocarbons, Iodinated; D010710:Phosphates; C035638:thiophosphoric acid