title: Establishment of heterolytic and homolytic Y-NO2 bond dissociation energy scales of nitro-containing compounds in acetonitrile: chemical origin of NO2 release and capture.
abstract: The first heterolytic and homolytic N(O)-NO(2) bond dissociation energy scales of three types Y-nitro (Y = N, O) compounds and corresponding radical anions in acetonitrile were established by using titration calorimetry combined with relevant electrochemical data through proper thermodynamic cycles.
authors.affiliation: State Key Laboratory of Elemento-Organic Chemistry, Department of Chemistry, Nankai University, Tianjin 300071, China.
authors.forename: Xin
authors.initials: X
authors.lastname: Li
authors.forename: Xiao-Qing
authors.initials: XQ
authors.lastname: Zhu
authors.forename: Fan
authors.initials: F
authors.lastname: Zhang
authors.forename: Xiao-Xiao
authors.initials: XX
authors.lastname: Wang
authors.forename: Jin-Pei
authors.initials: JP
authors.lastname: Cheng
mesh_terms: D000097:Acetonitriles / Q000737:chemistry*; D009574:Nitro Compounds / Q000737:chemistry*; D009585:Nitrogen Dioxide / Q000737:chemistry*; D013816:Thermodynamics
chemical_list: D000097:Acetonitriles; D009574:Nitro Compounds; D009585:Nitrogen Dioxide