Establishment of heterolytic and homolytic Y-NO2 bond dissociation energy scales of nitro-containing compounds in acetonitrile: chemical origin of NO2 release and capture.
The first heterolytic and homolytic N(O)-NO(2) bond dissociation energy scales of three types Y-nitro (Y = N, O) compounds and corresponding radical anions in acetonitrile were established by using titration calorimetry combined with relevant electrochemical data through proper thermodynamic cycles.
Li
Xin
X
State Key Laboratory of Elemento-Organic Chemistry, Department of Chemistry, Nankai University, Tianjin 300071, China.
Zhu
Xiao-Qing
XQ
Zhang
Fan
F
Wang
Xiao-Xiao
XX
Cheng
Jin-Pei
JP
D000097:Acetonitriles / Q000737:chemistry*; D009574:Nitro Compounds / Q000737:chemistry*; D009585:Nitrogen Dioxide / Q000737:chemistry*; D013816:Thermodynamics
D000097:Acetonitriles; D009574:Nitro Compounds; D009585:Nitrogen Dioxide