title: Relationship between micrometer to submicrometer surface roughness and topography variations of natural iron oxides and trace element concentrations.
abstract: The surface area and roughness of natural iron oxide precipitations were quantified by 3D optical microscopy in order to get information about fluid-rock interface topography in high-permeability zones. Converged surface roughness data of microscale to submicroscale topography show the predominance of macroporous half-pores (>500 nm) and the occurrence of smaller half-pores (<500 nm) that dominate the BET surface area of iron oxides. A relationship was found between the occurrence of macroporous surface structures (micrometer range) and the uranium content of iron oxide encrustations. Iron-normalized uranium concentrations of an X-ray amorphous iron oxide encrustation correlate linearly with maximum topography heights of 1 to 2 mum on hand specimen subsamples. Our study shows the potential importance of micrometer- to submicrometer-size surface features, whose environmental impact is often ignored.
authors.affiliation: Department of Earth Science, Rice University, 6100 Main Street, Houston, Texas, USA. cornelius@rice.edu
authors.forename: Cornelius
authors.initials: C
authors.lastname: Fischer
authors.forename: Volker
authors.initials: V
authors.lastname: Karius
authors.forename: Peter G
authors.initials: PG
authors.lastname: Weidler
authors.forename: Andreas
authors.initials: A
authors.lastname: Lüttge
mesh_terms: D005290:Ferric Compounds / Q000737:chemistry*; D008853:Microscopy; D016062:Porosity; D013499:Surface Properties; D014131:Trace Elements / Q000737:chemistry*; D014501:Uranium
chemical_list: D005290:Ferric Compounds; D014131:Trace Elements; C000499:ferric oxide; D014501:Uranium