Synthesis and characterization of electron-deficient and highly soluble (Bis)indenofluorene building blocks for n-type semiconducting polymers.
New electron-deficient and soluble indenofluorene-based and bisindenofluorene-based ladder-type building blocks embedding carbonyl and dicyanovinylene functionalities were synthesized, and their optical and electrochemical properties were characterized. These derivatives exhibit optical band gaps of 1.83 to 2.44 eV and low LUMO energies of -3.24 to -4.30 eV, representing a promising new building block class for n-type polymeric electronic materials.
Usta
Hakan
H
Department of Chemistry and the Materials Research Center, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
Facchetti
Antonio
A
Marks
Tobin J
TJ