title: Highly active iridium(I) complexes for catalytic hydrogen isotope exchange.
abstract: Practically convenient methods have been developed for the preparation of new iridium complexes, possessing bulky N-heterocyclic carbene and phosphine ligands; these routinely handled complexes are highly active catalysts within directed hydrogen isotope exchange processes.
authors.affiliation: Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, 295 Cathedral Street, Glasgow, Scotland, UK.
authors.forename: Jack A
authors.initials: JA
authors.lastname: Brown
authors.forename: Stephanie
authors.initials: S
authors.lastname: Irvine
authors.forename: Alan R
authors.initials: AR
authors.lastname: Kennedy
authors.forename: William J
authors.initials: WJ
authors.lastname: Kerr
authors.forename: Shalini
authors.initials: S
authors.lastname: Andersson
authors.forename: Göran N
authors.initials: GN
authors.lastname: Nilsson
mesh_terms: D002384:Catalysis; D003903:Deuterium / Q000737:chemistry; D006571:Heterocyclic Compounds / Q000737:chemistry*; D006838:Hydrocarbons / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry*; D007553:Isotope Labeling; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*
chemical_list: D006571:Heterocyclic Compounds; D006838:Hydrocarbons; D008024:Ligands; D009942:Organometallic Compounds; D010720:Phosphines; C030011:carbene; D007495:Iridium; D006859:Hydrogen; D003903:Deuterium; C044646:phosphine; D008697:Methane