Cp(Pri2MeP)FeH2SiR3: nonclassical iron silyl dihydride.
Reactions of a new borohydride complex 2 with hydrosilanes afford half-sandwich dihydride silyl complexes 3a-f. According to X-ray and DFT evidence complexes 3 have unprecedented double H...Si...H interligand interactions.
Gutsulyak
Dmitry V
DV
Chemistry Department, Brock University, 500 Glenridge Avenue, St. Catharines, ON, L2S 3A1, Canada.
Kuzmina
Lyudmila G
LG
Howard
Judith A K
JA
Vyboishchikov
Sergei F
SF
Nikonov
Georgii I
GI
D005290:Ferric Compounds / Q000737:chemistry*; D006859:Hydrogen / Q000737:chemistry*; D008956:Models, Chemical; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D012821:Silanes / Q000737:chemistry*; D013237:Stereoisomerism
D005290:Ferric Compounds; D009942:Organometallic Compounds; D012821:Silanes; D006859:Hydrogen