Highly active iridium(I) complexes for catalytic hydrogen isotope exchange.
Practically convenient methods have been developed for the preparation of new iridium complexes, possessing bulky N-heterocyclic carbene and phosphine ligands; these routinely handled complexes are highly active catalysts within directed hydrogen isotope exchange processes.
Brown
Jack A
JA
Department of Pure and Applied Chemistry, WestCHEM, University of Strathclyde, 295 Cathedral Street, Glasgow, Scotland, UK.
Irvine
Stephanie
S
Kennedy
Alan R
AR
Kerr
William J
WJ
Andersson
Shalini
S
Nilsson
Göran N
GN
D002384:Catalysis; D003903:Deuterium / Q000737:chemistry; D006571:Heterocyclic Compounds / Q000737:chemistry*; D006838:Hydrocarbons / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D007495:Iridium / Q000737:chemistry*; D007553:Isotope Labeling; D008024:Ligands; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008697:Methane / Q000031:analogs & derivatives* / Q000737:chemistry; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*
D006571:Heterocyclic Compounds; D006838:Hydrocarbons; D008024:Ligands; D009942:Organometallic Compounds; D010720:Phosphines; C030011:carbene; D007495:Iridium; D006859:Hydrogen; D003903:Deuterium; C044646:phosphine; D008697:Methane