Quest for zeolite-like metal-organic frameworks: on pyrimidinecarboxylate bis-chelating bridging ligands.
Two novel porous zeolitelike metal-organic frameworks (ZMOFs) were constructed via the single metal ion-based molecular building block approach from rigid and directional tetrahedral building units and pyrimidinecarboxylate bridging ligands; their ion exchange and hydrogen sorption properties were evaluated.
Sava
Dorina F
DF
Department of Chemistry, University of South Florida, 4202 East Fowler Avenue (CHE 205), Tampa, Florida 33620, USA.
Kravtsov
Victor Ch
VCh
Nouar
Farid
F
Wojtas
Lukasz
L
Eubank
Jarrod F
JF
Eddaoudi
Mohamed
M
D002104:Cadmium / Q000737:chemistry*; D002264:Carboxylic Acids / Q000737:chemistry*; D018360:Crystallography, X-Ray; D007204:Indium / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D011188:Potassium / Q000737:chemistry; D011743:Pyrimidines / Q000737:chemistry*; D012964:Sodium / Q000737:chemistry; D013696:Temperature
D002264:Carboxylic Acids; D008024:Ligands; D009942:Organometallic Compounds; D011743:Pyrimidines; D002104:Cadmium; D007204:Indium; D012964:Sodium; D011188:Potassium