Revealing source signatures in ambient BTEX concentrations.
Management of ambient concentrations of Volatile Organic Compounds (VOCs) is essential for maintaining low ozone levels in urban areas where its formation is under a VOC-limited regime. The significant decrease in traffic-induced VOC emissions in many developed countries resulted in relatively comparable shares of traffic and non-traffic VOC emissions in urban airsheds. A key step for urban air quality management is allocating ambient VOC concentrations to their pertinent sources. This study presents an approach that can aid in identifying sources that contribute to observed BTEX concentrations in areas characterized by low BTEX concentrations, where traditional source apportionment techniques are not useful. Analysis of seasonal and diurnal variations of ambient BTEX concentrations from two monitoring stations located in distinct areas reveal the possibility to identify source categories. Specifically, the varying oxidation rates of airborne BTEX compounds are used to allocate contributions of traffic emissions and evaporative sources to observed BTEX concentrations.
Zalel
Amir
A
Environmental, Water and Agricultural Engineering Department, Faculty of Civil and Environmental Engineering, Israel Institute of Technology, Technion, Haifa 32000, Israel.
Yuval
Broday
David M
DM
D000393:Air Pollutants / Q000032:analysis*; D001554:Benzene / Q000032:analysis*; D001555:Benzene Derivatives / Q000032:analysis*; D004784:Environmental Monitoring / Q000379:methods; D007220:Industrial Waste; D007557:Israel; D009585:Nitrogen Dioxide / Q000032:analysis; D010083:Oxidants, Photochemical / Q000032:analysis; D010316:Particle Size; D012621:Seasons; D013995:Time; D014050:Toluene / Q000032:analysis*; D001335:Vehicle Emissions; D014992:Xylenes / Q000032:analysis*
D000393:Air Pollutants; D001555:Benzene Derivatives; D007220:Industrial Waste; D010083:Oxidants, Photochemical; D001335:Vehicle Emissions; D014992:Xylenes; D014050:Toluene; D001554:Benzene; C004912:ethylbenzene; D009585:Nitrogen Dioxide