Allylic phosphinates via palladium-catalyzed allylation of H-phosphinic acids with allylic alcohols.
A novel catalytic allylation of H-phosphinic acids is described. Using Pd/xantphos (2 mol %), H-phosphinic acids react directly with allylic alcohols to produce P-allylated disubstituted phosphinic acids.
Coudray
Laëtitia
L
Department of Chemistry, Box 298860, Texas Christian University, Fort Worth, Texas 76129, USA.
Bravo-Altamirano
Karla
K
Montchamp
Jean-Luc
JL
D002384:Catalysis; D010165:Palladium / Q000737:chemistry*; D010721:Phosphinic Acids / Q000737:chemistry*; D020005:Propanols / Q000737:chemistry*
D010721:Phosphinic Acids; D020005:Propanols; C006463:allyl alcohol; D010165:Palladium