title: Multivalency iodine doped TiO2: preparation, characterization, theoretical studies, and visible-light photocatalysis.
abstract: Multivalency iodine (I(7)+/I(-)) doped TiO(2) were prepared via a combination of deposition-precipitation process and hydrothermal treatment. The as-prepared samples were characterized by X-ray diffraction, transmission electron microscopy, Brunauer-Emmett-Teller surface area, UV-vis diffuse reflectance spectra, X-ray photoelectron spectroscopy, surface photovoltage spectroscopy, and electric-field-induced surface photovoltage spectroscopy. The electronic structure calculations based on the density functional theory revealed that upon doping, new states that originated from the I atom of the IO(4) group are observed near the conduction-band bottom region of TiO(2), and the excitation from the valence band of TiO(2) to the surface IO(4-) is responsible for the visible-light response of the I-doped TiO(2). The as-prepared I-doped TiO(2) showed high efficiency for the photocatalytic decomposition of gaseous acetone under visible light irradiation (lambda > 420 nm). A possible mechanism for the photocatalysis on this multivalency iodine (I(7)+/I(-)) doped TiO(2) under visible light was also proposed.
authors.affiliation: Research Institute of Photocatalysis, State Key Laboratory Breeding Base of Photocatalysis, Fuzhou University, Fuzhou 350002, PR China.
authors.forename: Wenyue
authors.initials: W
authors.lastname: Su
authors.forename: Yongfan
authors.initials: Y
authors.lastname: Zhang
authors.forename: Zhaohui
authors.initials: Z
authors.lastname: Li
authors.forename: Ling
authors.initials: L
authors.lastname: Wu
authors.forename: Xuxu
authors.initials: X
authors.lastname: Wang
authors.forename: Junqian
authors.initials: J
authors.lastname: Li
authors.forename: Xianzhi
authors.initials: X
authors.lastname: Fu
mesh_terms: D002384:Catalysis; D007455:Iodine / Q000737:chemistry*; D046529:Microscopy, Electron, Transmission; D010777:Photochemistry; D013057:Spectrum Analysis; D014025:Titanium / Q000737:chemistry*; D014961:X-Ray Diffraction
chemical_list: C009495:titanium dioxide; D007455:Iodine; D014025:Titanium