title: Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids.
abstract: Large porphyrinoids with three Rh(CO)2 groups at their dipyrrin units shows two-step metal transposition through the macrocycle in solution and the equilibrium between the C3v-isomer and the Cs-isomer depends on the solvent polarity.
authors.affiliation: Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, 657-8501 Kobe, Japan. setsunej@kobe-u.ac.jp
authors.forename: Jun-ichiro
authors.initials: J
authors.lastname: Setsune
authors.forename: Masayuki
authors.initials: M
authors.lastname: Toda
authors.forename: Takafumi
authors.initials: T
authors.lastname: Yoshida
mesh_terms: D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D009942:Organometallic Compounds; D011166:Porphyrins; D012238:Rhodium