title: Effect of carbon nanofiber functionalization on the adsorption properties of volatile organic compounds.
abstract: The effect of the chemical activation, using HNO3, of a commercial carbon nanofiber (CNF) on its surface chemistry and adsorption properties is studied in this work. The adsorption of different alkanes (linear and cyclic), aromatic compounds and chlorohydrocarbons on both the parent and the oxidized CNF were compared. Temperature-programmed desorption results, in agreement with X-ray photoelectron spectroscopy experiments, reveal the existence of oxygen groups on the surface of the treated CNF. Capacity of adsorption was derived from the adsorption isotherms, whereas thermodynamic properties (enthalpy of adsorption, surface free energy characteristics) have been determined from chromatographic retention data. Both the capacity and the strength of adsorption decrease after the oxidant treatment of the carbon nanofibers, although in the case of chlorinated compounds the specific component of the surface energy shows an important increase. For n-alkanes and cyclic compounds, it was demonstrated that the presence of oxygen surface groups does not affect their interaction, the morphology of the surface being the key parameter. The oxidation of the nanofiber leads to steric limitations of the adsorption. In the adsorption of aromatic compounds, these limitations are compensated by the nucleophilic interactions between the aromatic ring and surface oxygenated groups, leading to similar performances of both materials. The absence of nucleophilic groups in the chlorinated compounds hinders their adsorption on the activated nanofibers.
authors.affiliation: Department of Chemical Engineering and Environmental Technology, University of Oviedo, Julián Clavería s/n, 33006 Oviedo, Spain.
authors.forename: Montserrat R
authors.initials: MR
authors.lastname: Cuervo
authors.forename: Esther
authors.initials: E
authors.lastname: Asedegbega-Nieto
authors.forename: Eva
authors.initials: E
authors.lastname: Díaz
authors.forename: Aurelio
authors.initials: A
authors.lastname: Vega
authors.forename: Salvador
authors.initials: S
authors.lastname: Ordóñez
authors.forename: Eva
authors.initials: E
authors.lastname: Castillejos-López
authors.forename: Inmaculada
authors.initials: I
authors.lastname: Rodríguez-Ramos
mesh_terms: D000327:Adsorption; D002244:Carbon / Q000737:chemistry*; D002849:Chromatography, Gas; D008855:Microscopy, Electron, Scanning; D049329:Nanostructures / Q000737:chemistry*; D017942:Nitric Acid / Q000737:chemistry; D009930:Organic Chemicals / Q000032:analysis / Q000737:chemistry*; D010084:Oxidation-Reduction; D013696:Temperature; D013816:Thermodynamics; D014835:Volatilization; D014961:X-Ray Diffraction
chemical_list: D009930:Organic Chemicals; D017942:Nitric Acid; D002244:Carbon