Solar one-way photoisomerisation of 5',8-cyclo-2'-deoxyadenosine.
Under sunlight irradiation (5'S)-5',8-cyclo-2'-deoxyadenosine 2 photoisomerises to the (5'R) isomer 1, which is the more easily repaired damage when these cyclopurine lesions are formed in DNA.
Jimenez
Liliana B
LB
Departamento de Química/Instituto de Tecnología Química UPV-CSIC, Universidad Politécnica de Valencia, Camino de Vera s/n, 46022 Valencia, Spain.
Encinas
Susana
S
Chatgilialoglu
Chryssostomos
C
Miranda
Miguel A
MA
D003839:Deoxyadenosines / Q000737:chemistry* / Q000528:radiation effects*; D015394:Molecular Structure; D010777:Photochemistry; D013237:Stereoisomerism; D013472:Sunlight
D003839:Deoxyadenosines; C056752:8,5'-cyclo-2'-deoxyadenosine