title: Lewis acid promoted carbon-carbon bond cleavage of gamma-silyloxy-beta-hydroxy-alpha-diazoesters.
abstract: Cyclic gamma-silyloxy-beta-hydroxy-alpha-diazoesters undergo efficient rupture of the Cbeta-Cgamma bond when treated with tin tetrachloride to provide tethered aldehyde ynoate products in high yield.
authors.affiliation: The University of Vermont, Department of Chemistry, 82 University Place, Burlington, Vermont 05405, USA.
authors.forename: Cristian
authors.initials: C
authors.lastname: Draghici
authors.forename: Matthias
authors.initials: M
authors.lastname: Brewer