Synthesis and dynamic structure of multinuclear Rh complexes of porphyrinoids.
Large porphyrinoids with three Rh(CO)2 groups at their dipyrrin units shows two-step metal transposition through the macrocycle in solution and the equilibrium between the C3v-isomer and the Cs-isomer depends on the solvent polarity.
Setsune
Jun-ichiro
J
Department of Chemistry, Graduate School of Science, Kobe University, 1-1 Rokkodai-cho, Nada-ku, 657-8501 Kobe, Japan. setsunej@kobe-u.ac.jp
Toda
Masayuki
M
Yoshida
Takafumi
T
D018360:Crystallography, X-Ray; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008958:Models, Molecular; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D011166:Porphyrins / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013237:Stereoisomerism
D009942:Organometallic Compounds; D011166:Porphyrins; D012238:Rhodium