Metastable tert-butylcalix[6]arene with unusually large tunable free volume for non-threshold enclathration of volatiles.
A metastable material with tunable free volume of molecular size, vapor sorption properties of a porous sorbent and variable thermal stability was prepared from tert-butylcalix[6]arene.
Yakimov
Alexey V
AV
Institute of Chemistry, Kazan State University, Kremlevskaya 18, Kazan 420008, Russia.
Ziganshin
Marat A
MA
Gubaidullin
Aidar T
AT
Gorbatchuk
Valery V
VV