V4O10: spectroscopic fingerprint of a well-defined, molecular metaloxo aggregate.
V4O10 can be considered as a molecular model for oxovanadium clusters deposited on the surfaces of corresponding heterogeneous catalysts, and here its generation, matrix isolation, and comprehensive characterization by IR, Raman, and UV/vis spectroscopy are described.
Herwig
Christian
C
Institut fuer Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Strasse 2, Berlin, Germany.
Limberg
Christian
C