Direct C-H bond arylation of arenes with aryltin reagents catalysed by palladium complexes.
Direct C-H bond arylation of simple arenes with aryltin reagents has been successfully catalysed by PdCl2 in the presence of CuCl2. CuCl2 proved to be an activator for a palladium intermediate as well as an oxidant.
Kawai
Hiroshi
H
Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, Sendai 980-8579, Japan.
Kobayashi
Yasuhiro
Y
Oi
Shuichi
S
Inoue
Yoshio
Y
D002384:Catalysis; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis* / Q000737:chemistry; D007202:Indicators and Reagents; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D009947:Organotin Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
D006841:Hydrocarbons, Aromatic; D007202:Indicators and Reagents; D009942:Organometallic Compounds; D009947:Organotin Compounds; D010165:Palladium