title: Synthesis, spectral characterization and bio-analysis of some organotin(IV) complexes.
abstract: Five novel organotin(IV) derivatives have been synthesized by refluxing trimethyl, triethyl, tributyl, and triphenyl and tribenzyltin chloride with Schiff base derived from salicylaldehyde and adenine. These compounds were characterized by spectroscopic (IR, (1)H, (13)C, (119)Sn-NMR, (119m)Sn Mössbauer) techniques and elemental analysis. Based on these results, trigonal bipyramidal geometry is suggested. The synthesized compounds were also treated with various microorganisms and found to be active.
authors.affiliation: Department of Chemistry, Hazara University, Mansehra, Pakistan. sono_waj@yahoo.com
authors.forename: Wajid
authors.initials: W
authors.lastname: Rehman
authors.forename: Musa Kaleem
authors.initials: MK
authors.lastname: Baloch
authors.forename: Amin
authors.initials: A
authors.lastname: Badshah
mesh_terms: D000818:Animals; D000900:Anti-Bacterial Agents / Q000138:chemical synthesis* / Q000737:chemistry / Q000494:pharmacology*; D000893:Anti-Inflammatory Agents / Q000138:chemical synthesis* / Q000737:chemistry / Q000627:therapeutic use*; D054697:Cytostatic Agents / Q000138:chemical synthesis* / Q000737:chemistry / Q000494:pharmacology; D005260:Female; D007249:Inflammation / Q000188:drug therapy; D009682:Magnetic Resonance Spectroscopy; D008297:Male; D051379:Mice; D050296:Microbial Viability / Q000187:drug effects; D015394:Molecular Structure; D009947:Organotin Compounds / Q000138:chemical synthesis* / Q000737:chemistry / Q000494:pharmacology*; D051381:Rats; D013055:Spectrophotometry, Infrared; D013329:Structure-Activity Relationship
chemical_list: D000900:Anti-Bacterial Agents; D000893:Anti-Inflammatory Agents; D054697:Cytostatic Agents; D009947:Organotin Compounds