Light-induced aggregation of colloidal gold nanoparticles capped by thymine derivatives.
The colloid stability of thymine-coated gold nanoparticles under light irradiation as a function of particle size, surface charge, and exposure time was investigated in alkaline, aqueous solutions as well as in a 0.5 vol % of DMF in H(2)O mixture. With increasing exposure to light irradiation at 280 nm, more and more particles coagulated. Light-induced aggregation of colloidal gold nanoparticles was attributed to reorientation of thymine terminal groups tethered on gold particle surfaces. A smaller particle size and negatively charged surface reduced the rate of photodimerization or even inhibited the photoreaction. UV-vis and FTIR spectroscopy confirmed the photodimerization of terminal thymine molecules under 280 nm light irradiation. The reaction kinetics of thymine photodimerization appears to be a combination of first-order reactions, each having different rates, reflecting the inhomogeneity and high curvature of the gold nanoparticle surfaces.
Zhou
Jingfang
J
Ian Wark Research Institute, University of South Australia, Mawson Lakes, Adelaide, South Australia 5095.
Sedev
Rossen
R
Beattie
David
D
Ralston
John
J
D017979:Gold Colloid / Q000737:chemistry*; D008027:Light; D053768:Metal Nanoparticles / Q000737:chemistry*; D013053:Spectrophotometry; D013941:Thymine / Q000737:chemistry*
D017979:Gold Colloid; D013941:Thymine