title: Activity coefficients at infinite dilution of organic compounds in 1-(meth)acryloyloxyalkyl-3-methylimidazolium bromide using inverse gas chromatography.
abstract: Activity coefficients at infinite dilution, gammainfinity, of organic compounds in two new room-temperature ionic liquids (n-methacryloyloxyhexyl-N-methylimidazolium bromide (C10H17O2MIM)(Br) at 313.15 and 323.15 K and n-acryloyloxypropyl-N-methylimidazolium bromide(C6H11O2MIM)(Br)) were determined using inverse gas chromatography. Phase loading studies of the net retention volume per gram of packing as a function of the percent phase loading were used to estimate the influence of concurrent retention mechanisms on the accuracy of activity coefficients at infinite dilution of solutes in both ionic liquids. It was found that most of the solutes were retained largely by partition with a small contribution from adsorption and that n-alkanes were retained predominantly by interfacial adsorption on ionic liquids studied in this work. The solvation characteristics of the two ionic liquids were evaluated using the Abraham solvation parameter model.
authors.affiliation: Laboratoire de Thermodynamique des Milieux Polyphasés, Nancy-Université, 1 rue Grandville, BP 20451 4001 Nancy, France. mutelet@ensic.inpl-nancy.fr
authors.forename: Fabrice
authors.initials: F
authors.lastname: Mutelet
authors.forename: Jean-Noël
authors.initials: JN
authors.lastname: Jaubert
authors.forename: Marek
authors.initials: M
authors.lastname: Rogalski
authors.forename: Julie
authors.initials: J
authors.lastname: Harmand
authors.forename: Michèle
authors.initials: M
authors.lastname: Sindt
authors.forename: Jean-Luc
authors.initials: JL
authors.lastname: Mieloszynski