Synthesis and characterization of processable multi-walled carbon nanotubes-sulfonated polydiphenylamine graft copolymers.
Water soluble and processable nanocomposites composed of multi-walled carbon nanotubes (MWNTs) and poly(diphenylamine sulfonic acid) (PDPASA) are synthesized and characterized. Two types of methodologies are adopted. MWNTs are covalently functionalized with 2,5-diaminobenzene sulfonic acid (DABSA) and further in situ polymerized with diphenylamine-4-sulfonic acid (DPASA). This results in the formation of nanocomposites, MWNT(DABSA)-g-PDPASA, in which PDPASA is presented as the graft chains onto MWNTs. In another approach, DPASA is in situ polymerized in presence of unfunctionalized MWNTs, results in a nanocomposite in which MWNTs are present as entrapped mass in PDPASA matrix. Both nanocomposites are found to be water soluble and can form free standing films. The conductivity of MWNT(DABSA)-g-PDPASA and MWNT/PDPASA is found to be 1.25 mS x cm(-1) and 0.65 mS x cm(-1), respectively, which is higher than that of pristine PDPASA (0.25 x 10(-5) S x cm(-1)). The nanocomposites are characterized for their structure, morphology, optical and thermal properties.
Lee
Kwang-Pill
KP
Department of Chemistry Graduate School, Kyungpook National University, Daegu 702-701, South Korea.
Gopalan
Anantha Iyengar
AI
Kim
Kyu Soo
KS
Santhosh
Padmanabhan
P
D001557:Benzenesulfonates / Q000737:chemistry*; D003102:Colloids / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D004159:Diphenylamine / Q000031:analogs & derivatives* / Q000737:chemistry; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D036103:Nanotechnology / Q000379:methods*; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000648:ultrastructure*; D010316:Particle Size; D011108:Polymers / Q000737:chemistry*; D013499:Surface Properties
D001557:Benzenesulfonates; D003102:Colloids; D046911:Macromolecular Substances; D037742:Nanotubes, Carbon; D011108:Polymers; C510648:sulfodiphenylamine; D004159:Diphenylamine