title: Optimization of basic dye removal by oil palm fibre-based activated carbon using response surface methodology.
abstract: Oil palm fibre was used to prepare activated carbon using physiochemical activation method which consisted of potassium hydroxide (KOH) treatment and carbon dioxide (CO(2)) gasification. The effects of three preparation variables: the activation temperature, activation time and chemical impregnation (KOH:char) ratio on methylene blue (MB) uptake from aqueous solutions and activated carbon yield were investigated. Based on the central composite design (CCD), a quadratic model and a two factor interaction (2FI) model were respectively developed to correlate the preparation variables to the MB uptake and carbon yield. From the analysis of variance (ANOVA), the significant factors on each experimental design response were identified. The optimum activated carbon prepared from oil palm fibre was obtained by using activation temperature of 862 degrees C, activation time of 1h and chemical impregnation ratio of 3.1. The optimum activated carbon showed MB uptake of 203.83 mg/g and activated carbon yield of 16.50%. The equilibrium data for adsorption of MB on the optimum activated carbon were well represented by the Langmuir isotherm, giving maximum monolayer adsorption capacity as high as 400mg/g at 30 degrees C.
authors.affiliation: School of Chemical Engineering, Universiti Sains Malaysia, Engineering Campus, 14300 Nibong Tebal, Penang, Malaysia. chbassim@eng.usm.my
authors.forename: B H
authors.initials: BH
authors.lastname: Hameed
authors.forename: I A W
authors.initials: IA
authors.lastname: Tan
authors.forename: A L
authors.initials: AL
authors.lastname: Ahmad
mesh_terms: D000327:Adsorption; D028023:Arecaceae / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry*; D004396:Coloring Agents / Q000302:isolation & purification*; D012044:Regression Analysis; D013499:Surface Properties
chemical_list: D004396:Coloring Agents; D002244:Carbon