title: Solubilization of single-wall carbon nanotubes in Organic solvents without sidewall functionalization.
abstract: Single walled carbon nanotubes (SWNTs) may be made soluble in a range of organic solvents without sidewall functionalization via their reduction by Na/Hg amalgam in the presence of dibenzo-18-crown-6. The [Na(dibenzo-18-crown-6)]n[SWNT] complex has been characterized by UV-Visible, Raman, and AFM and is consistent with no additional sidewall functionalization as compared with raw SWNTs, while MALDI-MS shows the presence of the [Na(dibenzo-18-crown-6)]+ ion. Solubility is greatest in CH2Cl2 and DMF being comparable to surfactant dispersed SWNTs, however, measurable solubilities are also observed in hexane, toluene, and alcohols. Reaction with alkyl halides (bromohexane, 1-iodododecane) yields alkyl functionalized SWNTs (i.e., C6H11-SWNTs and C12H25-SWNTs) with an C(SWNT):alkyl ratio (ca. 40:1) significantly lower than that observed by the analogous reaction of alkyl halides with reduced SWNTs formed by the Billups method in liquid ammonia.
authors.affiliation: Richard E. Smalley Institute for Nanoscale Science and Technology, Rice University, Houston, Texas 77005, USA.
authors.forename: Robin E
authors.initials: RE
authors.lastname: Anderson
authors.forename: Andrew R
authors.initials: AR
authors.lastname: Barron
mesh_terms: D003102:Colloids / Q000737:chemistry*; D003460:Crystallization / Q000379:methods*; D046911:Macromolecular Substances / Q000737:chemistry; D008422:Materials Testing; D008968:Molecular Conformation; D036103:Nanotechnology / Q000379:methods*; D037742:Nanotubes, Carbon / Q000737:chemistry* / Q000648:ultrastructure*; D009930:Organic Chemicals / Q000737:chemistry*; D010316:Particle Size; D012995:Solubility; D012997:Solvents / Q000737:chemistry*; D013499:Surface Properties
chemical_list: D003102:Colloids; D046911:Macromolecular Substances; D037742:Nanotubes, Carbon; D009930:Organic Chemicals; D012997:Solvents