title: The stereochemical course of bromoetherification of enynes.
abstract: Enynes undergo stereoselective syn intramolecular bromoetherification; the stereochemical course of the reaction was elucidated by X-ray crystallographic studies and by stereospecific synthesis of authentic bromoallenes.
authors.affiliation: Department of Chemistry, Imperial College London, London, UKSW7 2AZ. c.braddock@imperial.ac.uk
authors.forename: D
authors.initials: D
authors.lastname: Christopher Braddock
authors.forename: Roshni
authors.initials: R
authors.lastname: Bhuva
authors.forename: Yolanda
authors.initials: Y
authors.lastname: Pérez-Fuertes
authors.forename: Rebecca
authors.initials: R
authors.lastname: Pouwer
authors.forename: Craig A
authors.initials: CA
authors.lastname: Roberts
authors.forename: Andrea
authors.initials: A
authors.lastname: Ruggiero
authors.forename: Elaine S E
authors.initials: ES
authors.lastname: Stokes
authors.forename: Andrew J P
authors.initials: AJ
authors.lastname: White
mesh_terms: D000466:Alkadienes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D006842:Hydrocarbons, Brominated / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D000480:Alkynes; D006842:Hydrocarbons, Brominated