title: A [3]rotaxane with two porphyrinic plates acting as an adaptable receptor.
abstract: Following a multistep procedure, the copper(I)-templated strategy allowed preparation of a multifunctional [3]rotaxane. The dumbbell consists of a central two-bidentate chelate unit and two terminal stoppers. The two rings threaded on the rotaxane axis consist each of a 1,10-phenanthroline-incorporating macrocycle, rigidly connected to an appended zinc-complexed porphyrin. The copper(I) template can be removed, affording a free rotaxane whose two rings can glide freely along the axis and spin around it. The dumbbell being very long (approximately 85 A in its extended conformation from one stopper to the other), the porphyrin-porphyrin distance can be varied over a wide range. The two porphyrinic plates constitute the key elements of a receptor able to complex various guests between the plates. The ability of the threaded rings to move freely makes the host perfectly adjustable, allowing capture of geometrically very different guests. The copper(I)-complexed rotaxane also acts as an efficient receptor, although its adaptability is obviously more limited than that of its free rotaxane counterpart.
authors.affiliation: Laboratoire de Chimie Ogano-Minérale, LC3 UMR 7177 du CNRS, Université Louis Pasteur, Institut de Chimie, 4 rue Blaise Pascal, 67070 Strasbourg Cedex, France.
authors.forename: Julien
authors.initials: J
authors.lastname: Frey
authors.forename: Christian
authors.initials: C
authors.lastname: Tock
authors.forename: Jean-Paul
authors.initials: JP
authors.lastname: Collin
authors.forename: Valérie
authors.initials: V
authors.lastname: Heitz
authors.forename: Jean-Pierre
authors.initials: JP
authors.lastname: Sauvage