title: The role of cross-linking structures to the formation of one-dimensional nano-organized polyaniline and their Raman fingerprint.
abstract: In the present work, the resonance Raman, UV-vis-NIR and scanning electron microscopic (SEM) data of nanorods (about approximately 300 nm in diameter) and nanofibers (about approximately 93 nm in diameter) of PANI are presented and compared. The PANI samples were synthesized in aqueous media with dodecybenzenesulfonic acid (DBSA) and beta-naphtalenesulfonic acid (beta-NSA) as dopants, respectively. The presence of bands at 578, 1400 and 1, 632 cm(-1) in the Raman spectra of PANI-NSA and PANI-DBSA shows that the formation of cross-linking structures is a general feature of the PANI chains prepared in micellar media. It is proposed that these structures are responsible for the one-dimensional PANI morphology formation. In addition, the Raman band at 609 cm(-1) of PANI fibers is correlated with the extended PANI chain conformation.
authors.affiliation: Departamento de Química Fundamental, Instituto de Química, Universidade de São Paulo, CP 26.077, CEP 05513-970, São Paulo, SP, Brazil. morari@yahoo.com
authors.forename: Gustavo M
authors.initials: GM
authors.lastname: do Nascimento
authors.forename: Claudio H B
authors.initials: CH
authors.lastname: Silva
authors.forename: Celly M S
authors.initials: CM
authors.lastname: Izumi
authors.forename: Marcia L A
authors.initials: ML
authors.lastname: Temperini
mesh_terms: D000814:Aniline Compounds / Q000138:chemical synthesis / Q000737:chemistry*; D001557:Benzenesulfonates; D003432:Cross-Linking Reagents; D008855:Microscopy, Electron, Scanning; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry / Q000648:ultrastructure; D036103:Nanotechnology; D043942:Nanotubes / Q000737:chemistry* / Q000648:ultrastructure; D009282:Naphthalenesulfonates; D013053:Spectrophotometry; D013056:Spectrophotometry, Ultraviolet; D019265:Spectroscopy, Near-Infrared; D013059:Spectrum Analysis, Raman
chemical_list: D000814:Aniline Compounds; D001557:Benzenesulfonates; D003432:Cross-Linking Reagents; D009282:Naphthalenesulfonates; C416807:polyaniline; C001114:dodecylbenzenesulfonic acid