EPR study of Cu(2+)-doped tetraaqua-di(nicotinamide)Co(II) saccharinate single crystals.
The electron paramagnetic resonance spectra of Cu(2+) impurities in [Co(nicotinamide)(2)(H(2)O)(4)](saccharinate)(2) single crystals have been studied at ambient temperature in three mutually perpendicular planes. The angular variation of the spectra shows that the Cu(2+) ion substitutes the Co(2+) site in the lattice. The EPR spectra of Cu(2+) ions are characteristic of tetragonally elongated octahedral site. The spin-Hamiltonien parameters were obtained from the single crystal EPR analysis. The ground-state wave function of Cu(2+) ion in the lattice has been constructed.
Bozkurt
Esat
E
Department of Physics, Faculty of Arts and Sciences, Ondokuz Mayis University, Kurupelit, 55139 Samsun, Turkey. esatb@omu.edu.tr
Kartal
Ibrahim
I
Karabulut
Bünyamin
B
Uçar
Ibrahim
I
D003300:Copper / Q000737:chemistry; D003460:Crystallization; D004578:Electron Spin Resonance Spectroscopy; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D012439:Saccharin / Q000031:analogs & derivatives* / Q000737:chemistry
D009942:Organometallic Compounds; D003300:Copper; D012439:Saccharin