Synthesis and microwave assisted polymerization of fluorinated 2-phenyl-2-oxazolines: the fastest 2-oxazoline monomer to date.
The living cationic ring-opening polymerization of 2-oxazolines with fluorinated aromatic substituents was found to be strongly accelerated by o-fluoro substituents.
Lobert
Matthias
M
Laboratory of Macromolecular Chemistry and Nanoscience, Eindhoven University of Technology and Dutch Polymer Institute, PO Box 513, 5600 MB Eindhoven, The Netherlands.
Köhn
Uwe
U
Hoogenboom
Richard
R
Schubert
Ulrich S
US
D006845:Hydrocarbons, Fluorinated / Q000138:chemical synthesis* / Q000737:chemistry / Q000528:radiation effects*; D008872:Microwaves; D015394:Molecular Structure; D010080:Oxazoles / Q000138:chemical synthesis* / Q000737:chemistry / Q000528:radiation effects*; D013237:Stereoisomerism
D006845:Hydrocarbons, Fluorinated; D010080:Oxazoles