title: Preliminary evaluation of new polymer matrix for solid-phase extraction of nonylphenol from water samples.
abstract: Molecularly imprinted (MIP) and blank polymers with affinity for nonylphenol were designed using computational modelling. Chromatographic tests demonstrated higher affinity of imprinted polymers towards the template nonylphenol as compared with blank polymers. The performance of both polymers in solid-phase extraction was however very similar. Both blank and imprinted polymers appeared to be suitable for the removal and pre-concentration of nonylphenol from contaminated water samples with 99% efficiency of the recovery. The commercial resins PH(EC) (Biotage) and C18 (Varian) tested in the same conditions used for comparative purposes had recovery rate <84%. The polymer capacity for nonylphenol was 231 mg g(-1) for blank and 228 mg g(-1) for MIP. The synthesised materials can have significance for sample pre-concentration and environmental analysis of this class of compounds.
authors.affiliation: Cranfield Health, Cranfield University, Silsoe, Bedfordshire MK45 4DT, UK. a.guerreiro@cranfield.ac.uk
authors.forename: António
authors.initials: A
authors.lastname: Guerreiro
authors.forename: Ana
authors.initials: A
authors.lastname: Soares
authors.forename: Elena
authors.initials: E
authors.lastname: Piletska
authors.forename: Bo
authors.initials: B
authors.lastname: Mattiasson
authors.forename: Sergey
authors.initials: S
authors.lastname: Piletsky
mesh_terms: D002851:Chromatography, High Pressure Liquid; D010636:Phenols / Q000302:isolation & purification*; D011108:Polymers / Q000737:chemistry*; D014874:Water Pollutants, Chemical / Q000302:isolation & purification*
chemical_list: D010636:Phenols; D011108:Polymers; D014874:Water Pollutants, Chemical; C025256:nonylphenol