Interpenetrated nano-capsule networks based on the alkali metal assisted assembly of p-carboxylatocalix[4]arene-O-methyl ether.
Reaction of p-carboxylatocalix[4]arene-O-methyl ether with either rubidium or caesium hydroxide results in the formation of interpenetrated nano-capsule networks with the calixarene in the 1,3-alternate conformation.
Dalgarno
Scott J
SJ
Department of Chemistry, University of Missouri-Columbia, 601 S. College Avenue, Columbia, MO 65211, USA. S.J.Dalgarno@hw.ac.uk
Claudio-Bosque
Karla M
KM
Warren
John E
JE
Glass
Timothy E
TE
Atwood
Jerry L
JL
D047250:Calixarenes / Q000737:chemistry*; D018360:Crystallography, X-Ray; D006878:Hydroxides / Q000737:chemistry; D008672:Metals, Alkali / Q000737:chemistry*; D008958:Models, Molecular; D015394:Molecular Structure; D049329:Nanostructures / Q000737:chemistry*; D009942:Organometallic Compounds / Q000138:chemical synthesis / Q000737:chemistry*
C529138:4-carboxylatocalix(4)arene-O-methyl ether; D006878:Hydroxides; D008672:Metals, Alkali; D009942:Organometallic Compounds; D047250:Calixarenes