Versatile approach toward the self-assembly of heteromultimetallic salen structures.
A general route is presented toward the template-directed preparation of self-assembled heteromultimetallic salen structures using noncovalent coordinative metal-ligand interactions. Various higher order assemblies have been studied in detail using a combination of NMR spectroscopy and X-ray crystallography.
Wezenburg
Sander J
SJ
Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, Tarragona, Spain
Escudero-Adán
Eduardo C
EC
Benet-Buchholz
Jordi
J
Kleij
Arjan W
AW
D018360:Crystallography, X-Ray; D004798:Enzymes / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D008667:Metalloproteins / Q000737:chemistry*; D008958:Models, Molecular; D008968:Molecular Conformation; D015394:Molecular Structure; D014961:X-Ray Diffraction
D004798:Enzymes; D008667:Metalloproteins