The stereochemical course of bromoetherification of enynes.
Enynes undergo stereoselective syn intramolecular bromoetherification; the stereochemical course of the reaction was elucidated by X-ray crystallographic studies and by stereospecific synthesis of authentic bromoallenes.
Christopher Braddock
D
D
Department of Chemistry, Imperial College London, London, UKSW7 2AZ. c.braddock@imperial.ac.uk
Bhuva
Roshni
R
Pérez-Fuertes
Yolanda
Y
Pouwer
Rebecca
R
Roberts
Craig A
CA
Ruggiero
Andrea
A
Stokes
Elaine S E
ES
White
Andrew J P
AJ
D000466:Alkadienes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D006842:Hydrocarbons, Brominated / Q000138:chemical synthesis* / Q000737:chemistry; D008968:Molecular Conformation; D013237:Stereoisomerism
D000466:Alkadienes; D000480:Alkynes; D006842:Hydrocarbons, Brominated