Methylation of arenes via Ni-catalyzed aryl C-O/F activation.
Aryl C-O and C-F can be transformed into C-Me via Ni-catalyzed coupling with MeMgBr under mild conditions.
Guan
Bing-Tao
BT
Beijing National Laboratory of Molecular Sciences, PKU Green Chemistry Centre and Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of Education, College of Chemistry, Peking University, Beijing 100871, China.
Xiang
Shi-Kai
SK
Wu
Tao
T
Sun
Zuo-Peng
ZP
Wang
Bi-Qin
BQ
Zhao
Ke-Qing
KQ
Shi
Zhang-Jie
ZJ
D002384:Catalysis; D004987:Ethers / Q000737:chemistry*; D006841:Hydrocarbons, Aromatic / Q000138:chemical synthesis* / Q000737:chemistry; D008745:Methylation; D015394:Molecular Structure; D009532:Nickel / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry*; D013237:Stereoisomerism
D004987:Ethers; D006841:Hydrocarbons, Aromatic; D009942:Organometallic Compounds; D009532:Nickel