title: Synthesis of cyclic peroxides containing the Si-gem-bisperoxide fragment. 1,2,4,5,7,8-Hexaoxa-3-silonanes as a new class of peroxides.
abstract: A method was developed for the synthesis of the previously unknown class of organic peroxides, 1,2,4,5,7,8-hexaoxa-3-silonanes, based on the reaction of dialkyldichlorosilanes with 1,1'-dihydroperoxyperoxides. 1,2,4,5,7,8-Hexaoxa-3-silonanes are rather stable under ambient conditions and were characterized by NMR spectroscopy, X-ray diffraction, and elemental analysis. Their yields are in a range of 59-96%. The attempts were made to prepare 1,2,4,5-tetraoxa-3-silinanes by the reaction of dialkyldichlorosilanes with gem-bishydroperoxides. 1,2,4,5-Tetraoxa-3-silinanes were detected by NMR spectroscopy; these compounds rapidly decompose upon isolation.
authors.affiliation: ND Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation. terentev@ioc.ac.ru
authors.forename: Alexander O
authors.initials: AO
authors.lastname: Terent'ev
authors.forename: Maxim M
authors.initials: MM
authors.lastname: Platonov
authors.forename: Anna I
authors.initials: AI
authors.lastname: Tursina
authors.forename: Vladimir V
authors.initials: VV
authors.lastname: Chernyshev
authors.forename: Gennady I
authors.initials: GI
authors.lastname: Nikishin