Barrier scattering with complex-valued quantum trajectories: taxonomy and analysis of isochrones.
To facilitate the search for isochrones when using complex-valued trajectory methods for quantum barrier scattering calculations, the structure and shape of isochrones in the complex plane were studied. Isochrone segments were categorized based on their distinguishing features, which are shared by each situation studied: High and low energy wave packets, scattering from both thick and thin Gaussian and Eckart barriers of varying height. The characteristic shape of the isochrone is a trifurcated system: Trajectories that transmit the barrier are launched from the lower branch (T), while the middle and upper branches form the segments for reflected trajectories (F and B). In addition, a model is presented for the curved section of the lower branch (from which transmitted trajectories are launched), and important features of the complex extension of the initial wave packet are identified.
David
Julianne K
JK
Department of Chemistry and Biochemistry, The University of Texas at Austin, Austin, Texas 78712, USA. jkdavid@mail.utexas.edu
Wyatt
Robert E
RE