title: Improved method for the determination of benzene in soft drinks at sub-ppb levels.
abstract: An automated, simple, and reproducible method based on isotope dilution headspace gas chromatography/mass spectrometry developed previously for the determination of benzene in soft drinks was further improved by adding sodium sulfate to samples, lowering the gas chromatography oven starting temperature to narrow benzene peak width, and increasing sample injection volume. This improved method had a lower detection limit (0.016 microg l(-1)) and good repeatability, and was used in a follow-up survey to assess benzene levels in 139 samples of soft drink products. Benzene was detected in 67% of the 139 products tested. Compared with the previous survey, the average benzene concentrations in most products from this survey were lower, and only a few products had benzene at elevated levels.
authors.affiliation: Food Research Division, Bureau of Chemical Safety, Ottawa, Ontario, Canada K1A 0L2. Xu-Liang_Cao@hc-sc.gc.ca
authors.forename: X-L
authors.initials: XL
authors.lastname: Cao
authors.forename: V
authors.initials: V
authors.lastname: Casey
mesh_terms: D001554:Benzene / Q000032:analysis*; D002253:Carbonated Beverages / Q000032:analysis*; D003257:Consumer Product Safety; D005504:Food Analysis / Q000379:methods*; D005506:Food Contamination / Q000032:analysis*; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods*; D006801:Humans; D015203:Reproducibility of Results; D013431:Sulfates / Q000737:chemistry; D013696:Temperature
chemical_list: D013431:Sulfates; C012036:sodium sulfate; D001554:Benzene