title: Polyoxometalate embedding of a tetraruthenium(IV)-oxo-core by template-directed metalation of [gamma-SiW10O36]8-: a totally inorganic oxygen-evolving catalyst.
abstract: Solid state and solution evidence confirms the embedding of an adamantane-like, Ru4O6 fragment by the divacant, gamma-decatungstosilicate ligand. The resulting complex catalyzes water oxidation to oxygen with TON up to 500 and TOF > 450 h-1.
authors.affiliation: ITM-CNR and Department of Chemical Sciences, University of Padova, Via F. Marzolo 1, 35131 Padova, Italy. a.sartorel@itm.cnr.it
authors.forename: Andrea
authors.initials: A
authors.lastname: Sartorel
authors.forename: Mauro
authors.initials: M
authors.lastname: Carraro
authors.forename: Gianfranco
authors.initials: G
authors.lastname: Scorrano
authors.forename: Rita
authors.initials: R
authors.lastname: De Zorzi
authors.forename: Silvano
authors.initials: S
authors.lastname: Geremia
authors.forename: Neal D
authors.initials: ND
authors.lastname: McDaniel
authors.forename: Stefan
authors.initials: S
authors.lastname: Bernhard
authors.forename: Marcella
authors.initials: M
authors.lastname: Bonchio