title: Hollow waveguide quantum cascade laser spectrometer as an online microliter sensor for gas chromatography.
abstract: An optical absorption sensor for gas chromatography (GC) is presented. It consists of a quantum cascade laser along with a long piece of Hollow Waveguide for Infrared (HWIR) transmission inserted into the GC line. It measures the infrared absorption in each individual gas peak after separation by the GC column, and maintains the shapes of gas peaks after the HWIR sensor, making the gas samples further available for other sensors. By adding an inline combustion module before the HWIR sensor, the concentrations of many carbon containing compounds can be acquired by measuring CO2 absorption in their peaks. The HWIR sensor detects isotopologues of CO2 separately, and therefore can be used to measure carbon isotope ratios of heavy compounds. Application of the HWIR sensor to the detection of 13CO2 and CDH3 is described.
authors.affiliation: PEER Center, Caltech, 738 Arrow Grand Circle, Covina, CA 91722, USA. sheng@its.caltech.edu
authors.forename: Sheng
authors.initials: S
authors.lastname: Wu
authors.forename: Andrei
authors.initials: A
authors.lastname: Deev
authors.forename: Mark
authors.initials: M
authors.lastname: Haught
authors.forename: Yongchun
authors.initials: Y
authors.lastname: Tang
mesh_terms: D002247:Carbon Isotopes; D002849:Chromatography, Gas / Q000295:instrumentation*; D054023:Lasers, Semiconductor; D009862:Online Systems; D010084:Oxidation-Reduction; D013057:Spectrum Analysis / Q000295:instrumentation*; D013814:Thermal Conductivity
chemical_list: D002247:Carbon Isotopes