title: Palladium-catalyzed benzylic C-H insertion of 2-substituted N-iminopyridinium ylides.
abstract: Palladium-catalyzed direct benzylic C-H arylation of 2-alkyl substituted N-iminopyridinium ylides is described. The insertion can be conducted with several electron-poor and electron-rich aryl chlorides in good yields. This work adds to the few examples of sp3 C-H insertions that have been reported so far.
authors: Department of Chemistry, Université de Montréal, Montréal, Quebec, Canada.
authors: James J
authors: JJ
authors: Mousseau
authors: Alexandre
authors: A
authors: Larivée
authors: André B
authors: AB
authors: Charette
mesh_terms: D002384:Catalysis; D010165:Palladium / Q000737:chemistry*; D011726:Pyridinium Compounds / Q000737:chemistry*
chemical_list: D011726:Pyridinium Compounds; D010165:Palladium