Regioselective (12)CO/(13)CO exchange activity of a mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase.
A mixed-valent Fe(ii)Fe(i) model of the H(ox) state of [FeFe]-hydrogenase is shown, under certain conditions, to exhibit regioselective (12)CO/(13)CO exchange activity similar to that observed for H(ox).
Thomas
Christine M
CM
Department of Chemistry, Texas A&M University, College Station, TX 77843, USA.
Liu
Tianbiao
T
Hall
Michael B
MB
Darensbourg
Marcetta Y
MY
D002247:Carbon Isotopes; D002248:Carbon Monoxide / Q000737:chemistry*; D005296:Ferrous Compounds / Q000737:chemistry*; D006864:Hydrogenase / Q000737:chemistry*; D007506:Iron-Sulfur Proteins / Q000737:chemistry*; D008024:Ligands; D008968:Molecular Conformation; D010084:Oxidation-Reduction; D013237:Stereoisomerism
D002247:Carbon Isotopes; D005296:Ferrous Compounds; D007506:Iron-Sulfur Proteins; D008024:Ligands; D002248:Carbon Monoxide; C118830:iron hydrogenase; D006864:Hydrogenase