title: Historical profiles of chlorinated paraffins and polychlorinated biphenyls in a dated sediment core from Lake Thun (Switzerland).
abstract: A dated sediment core from Lake Thun covering the last 120 years was analyzed to get an overview of the historical trend of the chlorinated paraffin (CP) and polychlorinated biphenyl (PCB) deposition, because CPs and PCBs have/had similar applications as plasticizers and flame retardants. Total CP concentrations (sum of short chain (SCCP), medium chain (MCCP), and long chain CPs (LCCP)) showed a steep increase in the 1980s and a more-or-less stable level of 50 ng g(-1) dry weight (dw) since then. The concentration-time profile is in good agreement with the available information on global production data. The quantification of higher chlorinated SCCPs using electron capture negative ionization low resolution mass spectrometry (ECNI-LRMS) revealed an increase in recent years. In addition, the degree of chlorination of SCCPs has strongly increased during the past 40 years, which may indicate its use as an additive for plastics, paints, and coatings. Furthermore, PCBs were analyzed in dated sediment slices. The PCB concentrations (sum of the six indicator congeners) peaked around 1969 (18 ng g(-1) dw) and decreased to 1.3 ng g(-1) dw in the surface layer corresponding to 2004. The peak level of CPs exceeded those of PCBs by about a factor of 3.
authors: Empa, Swiss Federal Laboratories for Materials Testing and Research, Laboratory for Analytical Chemistry, Uberlandstrasse 129, CH-8600 Dübendorf, Switzerland.
authors: Saverio
authors: S
authors: Iozza
authors: Claudia E
authors: CE
authors: Müller
authors: Peter
authors: P
authors: Schmid
authors: Christian
authors: C
authors: Bogdal
authors: Michael
authors: M
authors: Oehme
mesh_terms: D002713:Chlorine / Q000737:chemistry*; D008401:Gas Chromatography-Mass Spectrometry; D019015:Geologic Sediments / Q000737:chemistry*; D010232:Paraffin / Q000032:analysis* / Q000737:chemistry; D011078:Polychlorinated Biphenyls / Q000032:analysis*; D021241:Spectrometry, Mass, Electrospray Ionization; D013557:Switzerland
chemical_list: D002713:Chlorine; D010232:Paraffin; D011078:Polychlorinated Biphenyls