title: Optimal doping control of magnetic semiconductors via subsurfactant epitaxy.
abstract: "Subsurfactant epitaxy" is established as a conceptually new approach for introducing manganese as a magnetic dopant into germanium. A kinetic pathway is devised in which the subsurface interstitial sites on Ge(100) are first selectively populated with Mn, while lateral diffusion and clustering on or underneath the surface are effectively suppressed. Subsequent Ge deposition as a capping layer produces a novel surfactantlike phenomenon as the interstitial Mn atoms float towards newly defined subsurface sites at the growth front. Furthermore, the Mn atoms that failed to float upwards are uniformly distributed within the Ge capping layer. The resulting doping levels of order 0.25 at. % would normally be considered too low for ferromagnetic ordering, but the Curie temperature exceeds room temperature by a comfortable margin. Subsurfactant epitaxy thus enables superior dopant control in magnetic semiconductors.
authors: Department of Physics and Astronomy, The University of Tennessee, Knoxville, Tennessee 37996, USA.
authors: Changgan
authors: C
authors: Zeng
authors: Zhenyu
authors: Z
authors: Zhang
authors: Klaus
authors: K
authors: van Benthem
authors: Matthew F
authors: MF
authors: Chisholm
authors: Hanno H
authors: HH
authors: Weitering