title: The first side-on bound metal complex of diazene, HN[double bond]NH.
abstract: The side-on bound metal complex of diazene cis-[Fe(NH[double bond]NH)(dmpe)(2)] was synthesised by reaction of [Fe(dmpe)(2)Cl(2)] with hydrazine in the presence of potassium graphite and characterised by (15)N NMR spectroscopy and X-ray crystallography.
authors: School of Chemistry, University of New South Wales, NSW 2052, Australia. l.field@unsw.edu.au
authors: Leslie D
authors: LD
authors: Field
authors: Hsiu L
authors: HL
authors: Li
authors: Scott J
authors: SJ
authors: Dalgarno
authors: Peter
authors: P
authors: Turner
mesh_terms: D018360:Crystallography, X-Ray; D006108:Graphite / Q000737:chemistry; D006834:Hydrazines / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D007094:Imides / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry
chemical_list: D006834:Hydrazines; D007094:Imides; D009942:Organometallic Compounds; C029424:hydrazine; D006108:Graphite; D006859:Hydrogen; D007501:Iron; C038867:diazene; D009584:Nitrogen