A straightforward asymmetric synthesis of 1,2-disubstituted ferrocenylalkyl amines with the unusual (S(Fc),S) configuration.
A useful synthesis of rare 1,2-disubstituted ferrocenylalkyl amines with (S(Fc),S) configuration has been achieved in a sequential one-pot methodology from (S)-p-tolylsulfinylferrocene.
Grach
Guillaume
G
Laboratoire de Chimie Moléculaire et Thio-organique, ENSICAEN, Université de Caen Basse-Normandie, CNRS, 6 boulevard du Maréchal Juin, 14050 Caen, France.
Lohier
Jean-François
JF
Santos
Jana Sopkova-de Oliveira
JS
Reboul
Vincent
V
Metzner
Patrick
P
D000588:Amines / Q000138:chemical synthesis* / Q000737:chemistry; D018360:Crystallography, X-Ray; D005296:Ferrous Compounds / Q000138:chemical synthesis*; D007202:Indicators and Reagents; D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D013237:Stereoisomerism
D000588:Amines; D005296:Ferrous Compounds; D007202:Indicators and Reagents; D008024:Ligands