Protodesilylation of 2,6-disubstituted silyphosphinines. Experimental and theoretical study.
2,6-Disilylphosphinines react with HCl in ethereal solution to cleanly yield the corresponding 2,6-unsubstituted derivatives. DFT calculations allowed rationalization of the mechanism of this protodesilylation.
Blug
Matthias
M
Laboratoire Hétéroéléments et Coordination, Ecole Polytechnique, CNRS, Palaiseau, France.
Piechaczyk
Olivier
O
Fustier
Marie
M
Mézailles
Nicolas
N
Le Floch
Pascal
P