Nucleophilicities and carbon basicities of DBU and DBN.
The nucleophilicity and Lewis basicity of DBU and DBN toward C(sp(2)) centers have been measured: nucleophilicities increase in the series DMAP < DBU < DBN < DABCO while Lewis basicities are DABCO < DMAP < DBU < DBN.
Baidya
M
M
Department Chemie und Biochemie, Ludwig-Maximilians-Universität München, Butenandtstr. 5-13 (Haus F), 81377 München, Germany.
Mayr
Herbert
H