Coordination chemistry of a pi-extended, rigid and redox-active tetrathiafulvalene-fused Schiff-base ligand.
A pi-extended, redox-active tetradentate tetrathiafulvalene-fused salphen [salphen = N,N'-phenylenebis(salicylideneimine)] compound (L) was prepared via a direct Schiff-base condensation of the corresponding diamine-tetrathiafulvalene (TTF) precursor with salicylaldehyde. Its chelating coordination ability has been demonstrated by the formation of the corresponding transition metal complexes in the presence of M(OAc)2.nH2O (M = Co(II), Ni(II), Cu(II)) and FeCl3.6H2O. Three complexes have been characterized by single-crystal X-ray diffraction analysis showing that the TTF-salphen ligand coordinates to the metal ions in a planar mode through the nitrogen and oxygen atoms in a N2O2 cis-configuration. In the case of Fe(III), a dinuclear oxo-bridged Fe(III) complex is formed. These paramagnetic complexes are promising building blocks for the construction of dual functional materials due to their unique structural features (planarity and rigidity) as well as their inherent redox properties.
Wu
Jin-Cai
JC
Departement für Chemie und Biochemie, Universität Bern, Freiestrasse 3, Bern, Switzerland.
Liu
Shi-Xia
SX
Keene
Tony D
TD
Neels
Antonia
A
Mereacre
Valeriu
V
Powell
Annie K
AK
Decurtins
Silvio
S