Synthesis, structure and physical properties of the manganese(ii) selenide/selenolate cluster complexes [Mn(32)Se(14)(SePh)(36)(PnPr(3))(4)] and [Na(benzene-15-crown-5)(C(4)H(8)O)(2)](2)[Mn(8)Se(SePh)(16)].
The synthesis, molecular structures, and magnetic and optical properties of [Mn(32)Se(14)(SePh)(36)(PnPr(3))(4)] and [Na(benzene-15-crown-5)(C(4)H(8)O)(2)](2)[Mn(8)Se(SePh)(16)] have been investigated which are the first examples of manganese chalcogenide cluster complexes, despite known manganese oxo compounds, which comprise more than four manganese atoms.
Eichhöfer
Andreas
A
Institut für Nanotechnologie, Forschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, Germany. eichhoefer@int.fzk.de
Wood
Paul T
PT
Viswanath
Raghavan N
RN
Mole
Richard A
RA
D008345:Manganese / Q000737:chemistry*; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D016566:Organoselenium Compounds / Q000737:chemistry*; D012964:Sodium / Q000737:chemistry*; D013056:Spectrophotometry, Ultraviolet / Q000379:methods; D013696:Temperature
D009942:Organometallic Compounds; D016566:Organoselenium Compounds; D008345:Manganese; D012964:Sodium