title: A stable, commercially available sulfenyl chloride for the activation of thioglycosides in conjunction with silver trifluoromethanesulfonate.
abstract: p-Nitrobenzenesulfenyl chloride is a stable commercially available sulfenyl chloride that, in conjunction with silver triflate, cleanly activates a wide range of thioglycosides for glycosylation at -78 degrees C in CH(2)Cl(2).
authors: Department of Chemistry, Wayne State University, Detroit, MI 48202, USA. dcrich@chem.wayne.edu
authors: David
authors: D
authors: Crich
authors: Feng
authors: F
authors: Cai
authors: Fan
authors: F
authors: Yang
mesh_terms: D006031:Glycosylation; D008698:Mesylates / Q000737:chemistry*; D009578:Nitrobenzenes / Q000737:chemistry*; D013865:Thioglycosides / Q000737:chemistry*
chemical_list: C518227:4-nitrobenzenesulfonyl chloride; D008698:Mesylates; D009578:Nitrobenzenes; D013865:Thioglycosides; C012077:trifluoromethanesulfonic acid