High uptakes of CO2 and CH4 in mesoporous metal-organic frameworks MIL-100 and MIL-101.
Mesoporous MOFs MIL-100 and MIL-101 adsorb huge amounts of CO2 and CH4. Characterization was performed using both manometry and gravimetry in different laboratories for isotherms coupled with microcalorimetry and FTIR to specify the gas-solid interactions. In particular, the uptake of carbon dioxide in MIL-101 has been shown to occur with a record capacity of 40 mmol g(-1) or 390 cm3STP cm(-3) at 5 MPa and 303 K.
Llewellyn
Philip L
PL
Laboratoire Chimie Provence, Université de Provence - CNRS (UMR 6264), Centre de St Jérôme, 13397 Marseille Cedex 20, France. philip.llewellyn@univ-provence.fr
Bourrelly
Sandrine
S
Serre
Christian
C
Vimont
Alexandre
A
Daturi
Marco
M
Hamon
Lomig
L
De Weireld
Guy
G
Chang
Jong-San
JS
Hong
Do-Young
DY
Kyu Hwang
Young
Y
Hwa Jhung
Sung
S
Férey
Gérard
G