Palladium-catalyzed benzylic C-H insertion of 2-substituted N-iminopyridinium ylides.
Palladium-catalyzed direct benzylic C-H arylation of 2-alkyl substituted N-iminopyridinium ylides is described. The insertion can be conducted with several electron-poor and electron-rich aryl chlorides in good yields. This work adds to the few examples of sp3 C-H insertions that have been reported so far.
Mousseau
James J
JJ
Department of Chemistry, Université de Montréal, Montréal, Quebec, Canada.
Larivée
Alexandre
A
Charette
André B
AB
D002384:Catalysis; D010165:Palladium / Q000737:chemistry*; D011726:Pyridinium Compounds / Q000737:chemistry*
D011726:Pyridinium Compounds; D010165:Palladium