title: Palladium-catalyzed cross-coupling reaction of tricyclopropylbismuth with aryl halides and triflates.
abstract: The palladium-catalyzed cross-coupling reaction of tricyclopropylbismuth with aryl and heterocyclic halides and triflates is reported. The reaction tolerates numerous functional groups and does not require anhydrous conditions. The method was successfully extended to the cross-coupling of triethylbismuth.
authors: Boehringer Ingelheim Canada Ltd., Research and Development, 2100 Cunard Street, Laval, Québec, Canada H7S 2G5. agagnon@lav.boehringer-ingelheim.com
authors: Alexandre
authors: A
authors: Gagnon
authors: Martin
authors: M
authors: Duplessis
authors: Pamela
authors: P
authors: Alsabeh
authors: Francis
authors: F
authors: Barabé
mesh_terms: D001729:Bismuth / Q000737:chemistry*; D002384:Catalysis; D003432:Cross-Linking Reagents / Q000737:chemistry*; D003521:Cyclopropanes / Q000737:chemistry*; D054879:Halogenation; D008698:Mesylates / Q000737:chemistry*; D015394:Molecular Structure; D010165:Palladium / Q000737:chemistry*
chemical_list: D003432:Cross-Linking Reagents; D003521:Cyclopropanes; D008698:Mesylates; D010165:Palladium; C030797:cyclopropane; D001729:Bismuth