title: An oxidative carbon-carbon bond formation system in cycloalkane-based thermomorphic multiphase solution.
abstract: A selective anodic oxidation system in which a carbocation intermediate is generated exclusively by use of a temperature-controlled multiphase solution to separate the different stages of the reaction from each other and from the products is described. The formation of a thermomorphic middle layer in an electrolytic solution composed of c-Hex and LPC/MeNO2 results in enhanced interaction between aliphatic alkenes and polar unstable cation.
authors: Laboratory of Bio-organic Chemistry, Tokyo University of Agriculture and Technology, Tokyo, Japan.
authors: Shokaku
authors: S
authors: Kim
authors: Satoko
authors: S
authors: Noda
authors: Kanako
authors: K
authors: Hayashi
authors: Kazuhiro
authors: K
authors: Chiba
mesh_terms: D000475:Alkenes / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D002412:Cations / Q000737:chemistry*; D003516:Cycloparaffins / Q000737:chemistry*; D010084:Oxidation-Reduction; D012996:Solutions / Q000737:chemistry
chemical_list: D000475:Alkenes; D002412:Cations; D003516:Cycloparaffins; D012996:Solutions; D002244:Carbon