title: Iron isotope fractionation by biogeochemical processes in mine tailings.
abstract: Iron isotope ratios were determined for the pore water, the 1 M HCl/1 M hydroxylamine hydrochloride (HAH)-extractable solid phase, and the total extractable solid phase from sulfidic mine tailings in Impoundment 1, Kristineberg mine, northern Sweden. Within the tailings, pyrite oxidation occurs in a distinct Fe-depleted oxidation zone, and the greatest number of Fe(II)-oxidizing bacteria in the profile occur close to the boundary between oxidized and unoxidized tailings. Above the oxidation front in the oxidized tailings, a large iron isotope fractionation (-1.3 to -2.4% per hundred) is measured between the pore water and the HAH-extractable solid phase. This isotope fractionation is explained by aqueous Fe(II)-Fe(III) equilibrium, microbial Fe(II) oxidation, and Fe(III) oxyhydroxide precipitation. The data suggests that pyrite in the tailings is enriched in 56Fe relative to Fe-rich silicates in the same material, such that pyrite oxidation results in a decrease in the mean delta56Fe value for the bulk tailings in the oxidized zone: a change in isotope composition that is not attributable to isotope fractionation. Iron isotope analyses yield valuable information on iron cycling in mine wastes, and they have the potential for becoming a tool for the prediction and control of acid mine drainage.
authors: Department of Earth Sciences, Uppsala University, Villavädgen 16, 75236 Uppsala, Sweden. roger.herbert@geo.uu.se
authors: Roger B
authors: RB
authors: Herbert
authors: Axel
authors: A
authors: Schippers
mesh_terms: D007503:Iron Isotopes / Q000302:isolation & purification*; D008906:Mining; D011786:Quality Control; D013548:Sweden
chemical_list: D007503:Iron Isotopes