Experiment and theory reveal the fundamental difference between two-state and single-state reactivity patterns in nonheme Fe(IV)=O versus Ru(IV)=O oxidants.
Dhuri
Sunder N
SN
Department of Chemistry, Division of Nano Sciences, and Centre for Biomimetic Systems, Ewha Womans University, Seoul 120-750, Korea.
Seo
Mi Sook
MS
Lee
Yong-Min
YM
Hirao
Hajime
H
Wang
Yong
Y
Nam
Wonwoo
W
Shaik
Sason
S
D007287:Inorganic Chemicals / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D016877:Oxidants / Q000737:chemistry*; D012428:Ruthenium / Q000737:chemistry*
D007287:Inorganic Chemicals; D016877:Oxidants; D012428:Ruthenium; D007501:Iron