Nonlinear thermal control in an N-terminal junction.
We demonstrate control over heat flow in an N -terminal molecular junction. Using simple model Hamiltonians we show that the heat current through two terminals can be tuned by the temperature and coupling parameters of external gating reservoirs. We discuss two models: A fully harmonic system and a model incorporating anharmonic interactions. For both models the control reservoirs induce thermal fluctuations of the transition elements between molecular vibrational states. We find that a fully harmonic model does not show any controllability, while for an anharmonic system the conduction properties of the junction strongly depend on the parameters of the gates. Realizations of the model system within nanodevices and macromolecules are discussed.
Segal
Dvira
D
Chemical Physics Theory Group, Department of Chemistry, University of Toronto. Toronto, ON, Canada.