[Re2(micro-1,2,4-triazolate)2(micro-OH)(CO)6]-: a novel metalloligand for the construction of flexible porous coordination networks.
The [Re2(micro-trz-kappaN1:kappaN2)2(micro-OH)(CO)6]- (trz = 1,2,4-triazolate) organometallic anion reacts with Ag+ to afford a 2D organometallic/coordination network, [Ag[Re2(micro3-trz-kappaN1:kappaN2:kappaN4)2(micro3-OH)(CO)6]]n x 4nCH3OH, which shows dynamic structural changes triggered by solid-liquid guest exchange processes.
Barea
Elisa
E
Dipartimento di Chimica Inorganica, Metallorganica e Analitica, Università degli Studi di Milano and ISTM-CNR, Via Venezian 21, 20133, Milano, Italy. ebaream@ugr.es
Rodríguez-Diéguez
Antonio
A
Navarro
Jorge A R
JA
D Alfonso
Giuseppe
G
Sironi
Angelo
A
D002248:Carbon Monoxide / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008024:Ligands; D008958:Models, Molecular; D009942:Organometallic Compounds / Q000737:chemistry*; D016062:Porosity; D012211:Rhenium / Q000737:chemistry*; D012834:Silver / Q000737:chemistry*; D013499:Surface Properties; D014230:Triazoles / Q000737:chemistry*
D008024:Ligands; D009942:Organometallic Compounds; D014230:Triazoles; C045575:1,2,4-triazole; D012834:Silver; D012211:Rhenium; D002248:Carbon Monoxide