Bioactive constituents from chinese natural medicines. XXIX. Monoterpene and monoterpene glycosides from the roots of Rhodiola sachalinensis.
A new monoterpene, sachalol, and three new monoterpene glycosides, sachalosides VI, VII, VIII, were isolated from Rhodiolae Radix, the roots of Rhodiola sachalinensis. The absolute stereostructures of new monoterpenes were elucidated on the basis of chemical and physicochemical evidence including the application of the modified Mosher's method.
Li
Xuezheng
X
Kyoto Pharmaceutical University, Kyoto, Japan.
Nakamura
Seikou
S
Matsuda
Hisashi
H
Yoshikawa
Masayuki
M
D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D002851:Chromatography, High Pressure Liquid; D002855:Chromatography, Thin Layer; D006026:Glycoside Hydrolases / Q000737:chemistry; D006868:Hydrolysis; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D008969:Molecular Sequence Data; D009097:Multienzyme Complexes / Q000737:chemistry; D018517:Plant Roots / Q000737:chemistry; D029771:Rhodiola / Q000737:chemistry*; D013055:Spectrophotometry, Infrared; D017550:Spectroscopy, Fourier Transform Infrared; D013729:Terpenes / Q000737:chemistry* / Q000302:isolation & purification; D001617:beta-Glucosidase / Q000737:chemistry
D007202:Indicators and Reagents; D009097:Multienzyme Complexes; D013729:Terpenes; D006026:Glycoside Hydrolases; C039827:naringinase; D001617:beta-Glucosidase