Combining organic photochromism with inorganic paramagnetism--optical tuning of the iron(II) electronic structure.
The crystalline photochromism of a diarylethene pyridyl ligand is applied to the modulation of the electronic environment of a high-spin Fe(II) metal ion.
Sénéchal-David
K
K
ICMMO-Equipe Chimie Inorganique, UMR 8182, Univ. Paris-Sud, 91405, Orsay Cedex, France.
Zaman
N
N
Walko
M
M
Halza
E
E
Rivière
E
E
Guillot
R
R
Feringa
B L
BL
Boillot
M-L
ML
D018360:Crystallography, X-Ray; D004583:Electrons; D005296:Ferrous Compounds / Q000737:chemistry*; D008024:Ligands; D008280:Magnetics; D008958:Models, Molecular; D015394:Molecular Structure; D010777:Photochemistry; D011725:Pyridines / Q000737:chemistry; D013861:Thiocyanates / Q000737:chemistry
D005296:Ferrous Compounds; D008024:Ligands; D011725:Pyridines; D013861:Thiocyanates