First-order derivative resolution of overlapped PAH peaks with common mass spectra in gas chromatography-mass spectrometry.
First-order derivative of 15 points smoothed chromatograms of mixtures of benzo(b)fluoranthene (BbF) and benzo(k)fluoranthene (BkF) for the m/z 252 ion obtained using two microscans has been proposed as a simple alternative to the resolution of overlapped chromatographic peaks of these two compounds which have identical mass spectra. The procedure provides limits of detection of 12 and 29ngg(-1) for BbF and BkF, respectively and offers the possibility to use the 250 and 248 ions to confirm the identity of these analytes.
Quintás
Guillermo
G
Institute for Chemical Technologies and Analytics, Vienna University of Technology, Getreidemarkt 9-164, A-1060 Vienna, Austria. guiquin@alumni.uv.es
Lendl
Bernhard
B
Pastor
Agustín
A
de la Guardia
Miguel
M