The first side-on bound metal complex of diazene, HN[double bond]NH.
The side-on bound metal complex of diazene cis-[Fe(NH[double bond]NH)(dmpe)(2)] was synthesised by reaction of [Fe(dmpe)(2)Cl(2)] with hydrazine in the presence of potassium graphite and characterised by (15)N NMR spectroscopy and X-ray crystallography.
Field
Leslie D
LD
School of Chemistry, University of New South Wales, NSW 2052, Australia. l.field@unsw.edu.au
Li
Hsiu L
HL
Dalgarno
Scott J
SJ
Turner
Peter
P
D018360:Crystallography, X-Ray; D006108:Graphite / Q000737:chemistry; D006834:Hydrazines / Q000737:chemistry; D006859:Hydrogen / Q000737:chemistry*; D007094:Imides / Q000737:chemistry*; D007501:Iron / Q000737:chemistry*; D009682:Magnetic Resonance Spectroscopy; D008958:Models, Molecular; D015394:Molecular Structure; D009584:Nitrogen / Q000737:chemistry*; D009942:Organometallic Compounds / Q000737:chemistry
D006834:Hydrazines; D007094:Imides; D009942:Organometallic Compounds; C029424:hydrazine; D006108:Graphite; D006859:Hydrogen; D007501:Iron; C038867:diazene; D009584:Nitrogen