title: Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies.
abstract: The first examples of base free lithium-organoaluminate and the corresponding gallium compound [LM(Me)OLi]3 (M = Al (3), Ga (4); L = HC{C(Me)N-2,6-iPr2C6H3}2) have been prepared by the reaction of Li[N(SiMe3)2] with the corresponding metal hydroxides LM(Me)OH (M = Al (1), Ga(2)); the oxygen atom in the M-O-Li fragment exists as oxide ion and is involved in the central Li3O3 six-membered ring formation.
authors: Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.
authors: Sanjay
authors: S
authors: Singh
authors: Jianfang
authors: J
authors: Chai
authors: Aritra
authors: A
authors: Pal
authors: Vojtech
authors: V
authors: Jancik
authors: Herbert W
authors: HW
authors: Roesky
authors: Regine
authors: R
authors: Herbst-Irmer