An oxidative carbon-carbon bond formation system in cycloalkane-based thermomorphic multiphase solution.
A selective anodic oxidation system in which a carbocation intermediate is generated exclusively by use of a temperature-controlled multiphase solution to separate the different stages of the reaction from each other and from the products is described. The formation of a thermomorphic middle layer in an electrolytic solution composed of c-Hex and LPC/MeNO2 results in enhanced interaction between aliphatic alkenes and polar unstable cation.
Kim
Shokaku
S
Laboratory of Bio-organic Chemistry, Tokyo University of Agriculture and Technology, Tokyo, Japan.
Noda
Satoko
S
Hayashi
Kanako
K
Chiba
Kazuhiro
K
D000475:Alkenes / Q000737:chemistry*; D002244:Carbon / Q000737:chemistry; D002412:Cations / Q000737:chemistry*; D003516:Cycloparaffins / Q000737:chemistry*; D010084:Oxidation-Reduction; D012996:Solutions / Q000737:chemistry
D000475:Alkenes; D002412:Cations; D003516:Cycloparaffins; D012996:Solutions; D002244:Carbon