Synthesis, characterization, spectral studies and antifungal activity of Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) complexes with 2-(4- sulphophenylazo)-1,8-dihydroxy-3,6-napthalene disulphonic acid trisodium salt.
Complexes of the type Na(6)[M(HL)(2)(H(2)O)(2)], where M= Mn(II), Fe(II), Co(II), Ni(II), Cu(II) and Zn(II) and Na(3)H(2)L= 2-(4-sulphophenylazo)-1,8-dihydroxy 3,6 naphthalene disulphonic acid trisodium salt, have been synthesized and characterized by physico-chemical (elemental analyses, solubility, electrolytic conductance, magnetic susceptibility measurement) and spectral (UV-Visible, IR, ESR, powder x-ray diffraction) techniques for their structure and studied for their antifungal activity against ten fungi. The anionic 1:2 metal:ligand complexes show octahedral geometry around M(II), a significant antifungal activity against Curvularia lunata and Alternaria triticina and a moderate activity against Alternaria brassicicola, Alternaria brassicae, Alternaria solanae, Curvularia species, Helminthosporium oryzae, Collectotrichum capsici, Aspergillus niger, Aspergillus flavus and Fusarium udum.
Pandey
Gajanan
G
Department of Applied Chemistry, Institute of Technology, Banaras Hindu University, Varanasi, India. pandeygajanan@rediffmail.com
Narang
K K
KK