Synthesis and oxidative rearrangement of selenenylated dihydropyrans.
Selenenylated dihydropyrans prepared by inverse demand hetero-Diels-Alder reactions undergo oxidative rearrangement when treated with H(2)O(2), leading to tetrahydrofuran-2-ones by ring contraction.
Redon
Sébastien
S
Université de Rouen, INSA de Rouen, CNRS UMR 6014, COBRA - IRCOF, 1 Rue Tesnière, 76131, Mont-Saint-Aignan cedex, France.
Pannecoucke
Xavier
X
Franck
Xavier
X
Outurquin
Francis
F