A new application for an old concept: Constant time (CT)-REDOR for an accurate determination of second moments in multiple spin systems with strong heteronuclear dipolar couplings.
In this contribution we present a constant time version of the well known REDOR pulse sequence which enables us to determine the second moments in multiple spin systems with strong dipolar couplings. From the resulting dipolar evolution curves, accurate values for the second moments can be obtained without the need to incorporate the full information about the detailed spin geometry of the multiple spin systems into the simulation protocol.
Echelmeyer
Thomas
T
Institut für Physikalische Chemie, Westfälische Wilhelms-Universität Münster, Corrensstr. 28-30, D-48149 Münster, Germany.
van Wüllen
Leo
L
Wegner
Sebastian
S