Regio- and stereoselective hydrostannation of allenes using dibutyliodotin hydride (Bu2SnIH) and successive coupling with aromatic halides.
Regio- and stereoselective hydrostannation of allenes by using di-n-butyliodotin hydride (Bu2SnIH) was accomplished to give alpha,beta-disubstituted vinyltins, which induced the synthesis of multi-substituted alkenes in a one-pot procedure.
Hayashi
Naoki
N
Department of Applied Chemistry, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871, Japan.
Kusano
Kazunao
K
Sekizawa
Shingo
S
Shibata
Ikuya
I
Yasuda
Makoto
M
Baba
Akio
A