Functionalized polyesters from organocatalyzed ROP of gluOCA, the O-carboxyanhydride derived from glutamic acid.
Well-controlled poly(alpha-hydroxyacids) featuring pendant carboxylic acid groups were prepared under mild conditions via DMAP-catalyzed ROP of the O-carboxyanhydrides derived from glutamic and lactic acids.
Thillaye du Boullay
Olivier
O
Laboratoire Hétérochimie Fondamentale et Appliquée du CNRS (UMR 5069), Equipe Ligands Bifonctionnels et Polymères Biodégradables, Université Paul Sabatier, 118 route de Narbonne, 31062, Toulouse Cedex 09, France.
Bonduelle
Colin
C
Martin-Vaca
Blanca
B
Bourissou
Didier
D
D000812:Anhydrides / Q000737:chemistry*; D002384:Catalysis; D018698:Glutamic Acid / Q000737:chemistry*; D011091:Polyesters / Q000737:chemistry*
D000812:Anhydrides; D011091:Polyesters; D018698:Glutamic Acid