title: Determination of Pd, Pt and Rh in vehicles escape fumes by GF-AAS and ICP-OES.
abstract: Automotive exhaust gases from vehicles using catalytic converters were filtered through cellulose filter papers to collect suspended particles expulsed along with the engine's escape fumes. A specially designed sample collector was used for supporting the filter papers during collection. The collector was manufactured from a new car's exhaust pipe. A cellulose circular paper filter, 11 cm diameter, was attached to one end of the pipe and kept centered by pressing it against the borders of the pipe by means of a perforated aluminum cap, slightly wider than the pipe, used to cover this end of the collector. Filter papers loaded with the solid particles were acid-digested using a modified domestic microwave oven to bring the solid material into solution. The resulting solutions were analyzed for Pt by graphite furnace atomic absorption spectrometry (GF-AAS) and for Pd and Rh by inductively coupled plasma (ICP-OES). Results indicate that concentration of these analytes in the particulate is higher for new vehicles, having new catalytic converters, than for old ones. Maximum Pd, Pt and Rh in the samples analyzed were found to be 5.36, 12.60 and 1.03 microg g(-1), respectively.
authors: Laboratorio de Espectroscopía Atómica, Departamento de Química, Universidad Simón Bolívar, Caracas 1080A, Venezuela.
authors: Antonio
authors: A
authors: Goncalves
authors: José R
authors: JR
authors: Domínguez
authors: José
authors: J
authors: Alvarado
mesh_terms: D010165:Palladium / Q000032:analysis*; D010984:Platinum / Q000032:analysis*; D012211:Rhenium / Q000032:analysis*; D013054:Spectrophotometry, Atomic / Q000379:methods*; D001335:Vehicle Emissions / Q000032:analysis*
chemical_list: D001335:Vehicle Emissions; D010984:Platinum; D010165:Palladium; D012211:Rhenium