Synthesis of glycosyl boranophosphates and their applications as precursors of glycosyl phosphate analogues.
Glycosyl boranophosphate triesters were synthesized via a boranophosphorylation of reducing sugars. The usefulness of the resultant glycosyl boranophosphates as versatile chemically stable precursors of various glycosyl phosphate derivatives is demonstrated.
Matsumura
Fumiko
F
Department of Medical Genome Sciences, Graduate School of Frontier Sciences, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba, Japan.
Oka
Natsuhisa
N
Wada
Takeshi
T
D001896:Boron Compounds / Q000138:chemical synthesis*; D005947:Glucose / Q000737:chemistry*
D001896:Boron Compounds; D005947:Glucose