A new enantiopure unsaturated dicarboxylate as a 4-connected unit in a flexible homochiral PtS-type framework.
Metal cation mediated chiral ligand transformation of (S)-camphanic acid leads to a new enantiopure unsaturated dicarboxylate that links tetrahedral Zn(2+) sites into 3-D homochiral 4-connected PtS-type framework structures, Zn(tced) (1, H(2)tced=1,2,2-trimethyl-3-cyclopentene-1,3-dicarboxylic acid) and Zn(4)(tced)(4)(4,4'-bipy) (2, 4,4'-bipy=4,4'-bipyridine).
Zhang
Jian
J
Department of Chemistry and Biochemistry, California State University, Long Beach, 1250 Bellflower Boulevard, Long Beach, CA 90840, USA.
Bu
Xianhui
X
D003998:Dicarboxylic Acids / Q000737:chemistry*; D015394:Molecular Structure; D013237:Stereoisomerism
D003998:Dicarboxylic Acids