Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies.
The first examples of base free lithium-organoaluminate and the corresponding gallium compound [LM(Me)OLi]3 (M = Al (3), Ga (4); L = HC{C(Me)N-2,6-iPr2C6H3}2) have been prepared by the reaction of Li[N(SiMe3)2] with the corresponding metal hydroxides LM(Me)OH (M = Al (1), Ga(2)); the oxygen atom in the M-O-Li fragment exists as oxide ion and is involved in the central Li3O3 six-membered ring formation.
Singh
Sanjay
S
Institut für Anorganische Chemie der Georg-August-Universität Göttingen, Tammannstrasse 4, D-37077 Göttingen, Germany.
Chai
Jianfang
J
Pal
Aritra
A
Jancik
Vojtech
V
Roesky
Herbert W
HW
Herbst-Irmer
Regine
R