An unusual dianion equivalent from acylsilanes for the synthesis of substituted beta-keto esters.
The reaction of lithiated diazo esters with acylsilanes generates a remarkable intermediate en route to highly substituted beta-keto esters.
Galliford
Chris V
CV
Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA.
Scheidt
Karl A
KA
D000215:Acylation; D000478:Alkylation; D000838:Anions / Q000737:chemistry; D004952:Esters / Q000138:chemical synthesis* / Q000737:chemistry; D015394:Molecular Structure; D012821:Silanes / Q000737:chemistry*
D000838:Anions; D004952:Esters; D012821:Silanes