Selective carbon-carbon bond cleavage of 2,2'-dibromotolane via photolysis of its appropriate (diphosphine)Pt0 complex in the solid state.
By irradiating crystals of a (diphosphine)Pt(0) complex containing 2,2'-dibromotolane as ligand with sunlight, a rare example of selective carbon-carbon bond cleavage in the solid state could be observed.
Petzold
Holm
H
Institut für Anorganische und Analytische Chemie, Friedrich-Schiller-Universität, 07743, Jena, Germany.
Weisheit
Thomas
T
Görls
Helmar
H
Breitzke
Hergen
H
Buntkowsky
Gerd
G
Escudero
Daniel
D
González
Leticia
L
Weigand
Wolfgang
W