A novel palladium-catalyzed hydroalkoxylation of alkenes with a migration of double bond.
A novel palladium-catalyzed addition of alcohols to olefins was developed, in which a migration of double bond was involved. By this new method, a variety of allylic ethers were prepared with moderate to high yields under mild conditions.
Tan
Jiajing
J
Hefei National Laboratory for Physical Science at Microscale, Joint Laboratory of Green Synthetic Chemistry and Department of Chemistry, University of Science and Technology of China, Hefei 230026, PR China.
Zhang
Zuhui
Z
Wang
Zhiyong
Z
D000438:Alcohols / Q000737:chemistry; D000475:Alkenes / Q000737:chemistry*; D000478:Alkylation; D002384:Catalysis; D004987:Ethers / Q000138:chemical synthesis* / Q000737:chemistry; D006900:Hydroxylation; D008024:Ligands; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism
D000438:Alcohols; D000475:Alkenes; D004987:Ethers; D008024:Ligands; D009942:Organometallic Compounds; D010165:Palladium