title: Reinforcement of bone cement using zirconia fibers with and without acrylic coating.
abstract: Acrylic (polymethylmethacrylate or PMMA) bone cement was modified by the addition of high-strength zirconia fibers with average lengths of 200 microm and diameters of 15 microm or 30 microm. A novel emulsion polymerization process was developed to encapsulate individual fibers in PMMA. Improvements in tensile and compressive properties as well as in fracture toughness were investigated upon incorporation of uncoated and acrylic coated zirconia fibers. Bone cements were reinforced with 2% by volume of the 15 microm diameter and 5% by volume of the 30 microm fibers. Results indicate that elastic modulus and ultimate strength of bone cements reinforced with zirconia fibers were higher than controls, being the largest for cements reinforced with 30 microm diameter fibers. The fracture toughness of the cement increased by 23% and 41% by the addition of 15 microm and 30 microm fibers, respectively. Coating of individual zirconia fibers did not result in improved material properties of bone cements. The use of uncoated or acrylic coated 30 microm fibers is recommended based on the significant increases in ultimate strength and fracture toughness of the cements.
authors.affiliation: Biomedical Engineering Program, Mechanical Engineering Department, University of Connecticut, Storrs, Connecticut 06269, USA. skotha@engr.uconn.edu
authors.forename: Shiva
authors.initials: S
authors.lastname: Kotha
authors.forename: Chaodi
authors.initials: C
authors.lastname: Li
authors.forename: Steven
authors.initials: S
authors.lastname: Schmid
authors.forename: James
authors.initials: J
authors.lastname: Mason
mesh_terms: D001843:Bone Cements / Q000737:chemistry*; D020099:Coated Materials, Biocompatible / Q000737:chemistry*; D019245:Compressive Strength; D004548:Elasticity; D008422:Materials Testing; D015394:Molecular Structure; D019904:Polymethyl Methacrylate / Q000737:chemistry*; D013314:Stress, Mechanical; D013718:Tensile Strength; D015040:Zirconium / Q000737:chemistry*
chemical_list: D001843:Bone Cements; D020099:Coated Materials, Biocompatible; D019904:Polymethyl Methacrylate; D015040:Zirconium; C028541:zirconium oxide