title: Ligand-field treatment for the optical and electron paramagnetic resonance spectra of ZnO:V(3+).
abstract: In this work, a full ligand-field energy matrix (45 x 45) diagonalization treatment for 3d(2) ions in trigonal symmetry C(3v) is performed on the basis of a central metal ion-ligand covalency model including the ligand spin-orbit (SO) coupling. Optical fine structure and electron paramagnetic resonance (EPR) spectra of ZnO:V(3+) are uniformly explained.
authors.affiliation: Physics Department, Sichuan Normal University, No. 5 Jing'An Road, Sichuan, Chengdu 610066, China. xielh1974@163.com
authors.forename: Xie
authors.initials: X
authors.lastname: Lin-Hua
mesh_terms: D003460:Crystallization; D004578:Electron Spin Resonance Spectroscopy; D008024:Ligands; D008956:Models, Chemical; D012666:Semiconductors; D013053:Spectrophotometry; D055672:Static Electricity; D014639:Vanadium / Q000737:chemistry*; D015034:Zinc Oxide / Q000737:chemistry*
chemical_list: D008024:Ligands; D014639:Vanadium; D015034:Zinc Oxide