title: Kinetic resolution of donor-functionalised tertiary alcohols by Cu-H-catalysed stereoselective silylation using a strained silicon-stereogenic silane.
abstract: A series of propargylic tertiary alcohols decorated with an sp2-hybridised nitrogen donor were kinetically resolved by reagent-controlled dehydrogenative Si-O coupling with a strained, highly reactive silicon-stereogenic cyclic silane.
authors.affiliation: Organisch-Chemisches Institut, Westfälische Wilhelms-Universität, Corrensstrasse 40, D-48149, Münster, Germany.
authors.forename: Betül
authors.initials: B
authors.lastname: Karatas
authors.forename: Sebastian
authors.initials: S
authors.lastname: Rendler
authors.forename: Roland
authors.initials: R
authors.lastname: Fröhlich
authors.forename: Martin
authors.initials: M
authors.lastname: Oestreich
mesh_terms: D000438:Alcohols / Q000737:chemistry*; D002384:Catalysis; D003300:Copper / Q000737:chemistry*; D007700:Kinetics; D008968:Molecular Conformation; D009584:Nitrogen / Q000737:chemistry*; D012821:Silanes / Q000138:chemical synthesis* / Q000737:chemistry*; D012825:Silicon / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000438:Alcohols; D012821:Silanes; D003300:Copper; D009584:Nitrogen; D012825:Silicon