title: Self-assembled monolayer electrode of a diiron complex with a phenoxo-based dinucleating ligand: observation of molecular oxygen adsorptionldesorption in aqueous media.
abstract: The phenoxo-based dinucleating ligand, 2,6-bis[bis(6-pivalamido-2-pyridylmethyl)amino-methyl-4-aminophenol (1), and its Fe2(II) complex, [Fe2(II)(1)(PhCOO)2](CF3SO3) (2), were prepared and 2 deposited on the Au surface (2/Au) is much more stable than in solution and exhibits redox behavior in aqueous media as well as reversible adsorption/desorption of oxygen at room temperature.
authors.affiliation: Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, 466-8555, Japan.
authors.forename: Tomohiko
authors.initials: T
authors.lastname: Inomata
authors.forename: Kazuma
authors.initials: K
authors.lastname: Shinozaki
authors.forename: Yuya
authors.initials: Y
authors.lastname: Hayashi
authors.forename: Hidekazu
authors.initials: H
authors.lastname: Arii
authors.forename: Yasuhiro
authors.initials: Y
authors.lastname: Funahashi
authors.forename: Tomohiro
authors.initials: T
authors.lastname: Ozawa
authors.forename: Hideki
authors.initials: H
authors.lastname: Masuda