title: Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand.
abstract: Two enantiomerically 3D chiral POM-based architectures have been constructed based on the achiral ligand bbi, [V10O26](4-) polyoxoanion and mixed valence Cu(I/II) without a chiral auxiliary, and they represent the first examples of enantiomerically 3D POM-based compounds using achiral ligands.
authors.affiliation: Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China.
authors.forename: Ya-Qian
authors.initials: YQ
authors.lastname: Lan
authors.forename: Shun-Li
authors.initials: SL
authors.lastname: Li
authors.forename: Zhong-Min
authors.initials: ZM
authors.lastname: Su
authors.forename: Kui-Zhan
authors.initials: KZ
authors.lastname: Shao
authors.forename: Jian-Fang
authors.initials: JF
authors.lastname: Ma
authors.forename: Xin-Long
authors.initials: XL
authors.lastname: Wang
authors.forename: En-Bo
authors.initials: EB
authors.lastname: Wang