Generation of a solid Brønsted acid site in a chiral framework.
Protonation of chiral porous materials introduces a Brønsted acid centre, the structure of which is unique to the heterogeneous phase requiring pore wall confinement for stable isolation.
Ingleson
Michael J
MJ
Department of Chemistry, University of Liverpool, Liverpool, UK.
Barrio
Jorge Perez
JP
Bacsa
John
J
Dickinson
Calum
C
Park
Hyunsoo
H
Rosseinsky
Matthew J
MJ
D000143:Acids / Q000737:chemistry*; D002384:Catalysis; D007202:Indicators and Reagents; D008958:Models, Molecular; D011522:Protons; D013055:Spectrophotometry, Infrared; D013237:Stereoisomerism; D014961:X-Ray Diffraction; D017641:Zeolites / Q000737:chemistry*
D000143:Acids; D007202:Indicators and Reagents; D011522:Protons; D017641:Zeolites