Solvatomagnetic effect and spin-glass behavior in a 1D coordination polymer constructed from EE-azido bridged MnIII3O units.
The non-uniform chain manganese(III) complex constructed from EE-azido bridged MnIII3O units, [MnIII3O(Brppz)3-(MeOH)3(N3)] 2MeOH [1, Brppz = 3-(5-bromo-2-phenolate)-pyrazolate], is the first example of 1D azido-bridged coordination polymer showing both solvatomagnetic effect and spin-glass behavior.
Liu
Cai-Ming
CM
Beijing National Laboratory for Molecular Sciences, Center for Molecular Science, Institute of Chemistry, CAS, Beijing, 100080, P. R. China. cmliu@iccas.ac.cn
Zhang
De-Qing
DQ
Zhu
Dao-Ben
DB