Constructing magnetic molecular solids by employing three-atom ligands as bridges.
The combination of some three-atom bridges with paramagnetic 3d transition metal ions results in the systematic isolation of molecular magnetic materials, ranging from single-molecule and single-chain magnets to layered weak ferromagnets and three-dimensional porous magnets. The design strategy and role of secondary components, such as co-ligands, templates and other mixed short ligands are discussed.
Wang
Xin-Yi
XY
Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.
Wang
Zhe-Ming
ZM
Gao
Song
S