title: Alkenol-alkyne cross metathesis.
abstract: Allyl alcohols and their homologues were used in the enyne cross metathesis to prepare hydroxy-functionalized dienes. An isomerization was found to occur under prolonged heating, and a method for conversion to ( E)-diene product is also reported.
authors.affiliation: Department of Chemistry, University at Buffalo, The State University of New York, Amherst, New York 14260, USA.
authors.forename: Daniel A
authors.initials: DA
authors.lastname: Clark
authors.forename: Joseph R
authors.initials: JR
authors.lastname: Clark
authors.forename: Steven T
authors.initials: ST
authors.lastname: Diver
mesh_terms: D000466:Alkadienes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D015394:Molecular Structure; D020005:Propanols / Q000737:chemistry*; D013237:Stereoisomerism
chemical_list: D000466:Alkadienes; D000480:Alkynes; D020005:Propanols; C006463:allyl alcohol