(N-{[4-(1,3-benzothiazol-2-yl)anilino]carbonylmethyl-kappaO}iminodiacetato-kappa(3)O,N,O')(1,10-phenanthroline-kappa(2)N,N')cobalt(II) pentahydrate.
The title compound, [Co(C(19)H(15)N(3)O(5)S)(C(12)H(8)N(2))] x 5 H(2)O, has a moderately distorted octahedral coordination environment composed of two N atoms of a 1,10-phenanthroline ligand and one N and three O atoms of an N-{[4-(1,3-benzothiazol-2-yl)anilino]carbonylmethyl}iminodiacetate (ZL-5(2-)) ligand. The ring systems of the phenanthroline and ZL-5(2-) ligands are coplanar and the complexes pack in layers parallel to the ab plane with the rings of adjacent complexes facing one another. The layers stack along the c axis and are linked by hydrogen bonds involving the five water solvent molecules in the asymmetric unit and O atoms of the acetate groups of the ZL-5(2-) ligand. This is believed to be the first crystal structure of a complex of a 2-(4-aminophenyl)benzothiazole ligand.
Lin
Guo-Wu
GW
College of Basic Science, China Pharmaceutical University, Nanjing 210009, People's Republic of China.
Wang
Yue
Y
Lu
Tao
T
D003035:Cobalt / Q000737:chemistry*; D003461:Crystallography; D006860:Hydrogen Bonding; D015394:Molecular Structure; D010618:Phenanthrolines / Q000737:chemistry*
D010618:Phenanthrolines; D003035:Cobalt; C025205:1,10-phenanthroline