State-selected imaging of HCCO radical photodissociation dynamics.
We present a dc sliced ion imaging study of HCCO radical photodissociation to CH and CO at 230 nm. The measurements were made using a two-color reduced Doppler probe strategy. The CO rotational distribution was consistent with a Boltzmann distribution at 3500 K. Using the dc slice ion imaging approach, we obtained CO images for various rotational levels of CO (v=0). The results are largely consistent with earlier work, albeit with a significant 0.9 eV peak seen previously in the translational energy distributions absent in our state-selected imaging study.
Huang
Cunshun
C
Department of Chemistry, Wayne State University, Detroit, Michigan 48202, USA.
Estillore
Armando D
AD
Suits
Arthur G
AG