title: 1,5-Asymmetric induction during nucleophilic additions to arenetricarbonylchromium complexes: tricarbonyl(eta(6)-1-methyl-4-{spiro[(1R,2S)-1,7,7-trimethylbicyclo[2.2.1]heptane-3,2'-1,3-dioxolan]-2-yloxy}benzene)chromium.
abstract: The tricarbonylchromium unit bound to the arene ring of the chiral title complex, [Cr(C(19)H(26)O(3))(CO)(3)], is rotated by ca 25 degrees in agreement with the proposed mechanism for 1,5-asymmetric induction of nucleophilic attack.
authors.affiliation: Department of Chemistry, Case Western Reserve University, Cleveland, Ohio 44106, USA.
authors.forename: Harinandini
authors.initials: H
authors.lastname: Paramahamsan
authors.forename: Anthony J
authors.initials: AJ
authors.lastname: Pearson
authors.forename: Nathalie M
authors.initials: NM
authors.lastname: Pinkerton
authors.forename: A Alan
authors.initials: AA
authors.lastname: Pinkerton
mesh_terms: D001643:Bridged Bicyclo Compounds / Q000737:chemistry*; D017608:Chromium Compounds / Q000737:chemistry*; D018360:Crystallography, X-Ray; D008958:Models, Molecular; D015394:Molecular Structure
chemical_list: D001643:Bridged Bicyclo Compounds; D017608:Chromium Compounds