Group 13 organoderivatives supported on a metallic oxide model.
The [{TiCp*(micro-O)}3(mu3-CH)] (1) metalloligand, (Cp* = eta5-C5Me5), coordinates in a 1:1 ratio to [AlMe3] or 9-BBN to give [{Me3Al}{(mu3-O)(mu-O)2(TiCp)2(TiCp)3(mu3-CH)}](2) or [{(C8H14)B}(mu-H) {(mu3-O)(mu-O)2(TiCp*)3(mu3-CH)}](4), respectively, partial hydrolysis of 2 leads to the new hydroxo-aluminium derivative [{MeAl} {(mu-OH)(mu3-O)}2{(mu-O)2(TiCp*)3-(mu3-CH)}2](3).
González-del Moral
Octavio
O
Departamento de Química Inorgánica, Universidad de Alcalá, 28871, Alcalá de Henares-Madrid, Spain.
Hernán-Gómez
Alberto
A
Martín
Avelino
A
Mena
Miguel
M
Santamaría
Cristina
C