Self-assembly reactions with a bis(benzene-o-dithiolato) ligand.
Reaction of the 1,5-diamidonaphthalene bridged bis(benzene-o-dithiol) ligand H4- with Ti4+ leads to the unexpected formation of a dinuclear meso-complex anion [Ti2(B)3](4-), while the catechol analog H(4-) has been reported to yield the tetrahedral [M4(A)6](8-) cluster.
Hahn
F Ekkehardt
FE
Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 36, D-48149, Münster, Germany. fehahn@uni-muenster.de
Birkmann
Birgit
B
Pape
Tania
T
D000838:Anions / Q000737:chemistry; D001555:Benzene Derivatives / Q000737:chemistry*; D008024:Ligands; D008958:Models, Molecular; D008968:Molecular Conformation; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D013438:Sulfhydryl Compounds / Q000737:chemistry*; D014025:Titanium / Q000737:chemistry*
D000838:Anions; D001555:Benzene Derivatives; D008024:Ligands; D009942:Organometallic Compounds; D013438:Sulfhydryl Compounds; D014025:Titanium