New supramolecular isomers with 2D 4(4) square-grid and 3D 6(5).8 frameworks in a one-pot synthesis; reversible solvent uptake and intriguing luminescence properties.
Two supramolecular isomers of [Ni(4-bpd)(2)(NCS)(2)] (4-bpd = 1,4-bis(4-pyridyl)-2,3-diaza-1,3-butadiene) with 2D 4(4) square-grid and 3D 6(5).8 frameworks are co-crystallized in a one-pot reaction, both of which exhibit interesting luminescence properties and reversible adsorption-desorption with respect to guest solvents.
Wang
Chih-Chieh
CC
Department of Chemistry, Soochow University, Taipei 111, Taiwan. ccwang@scu.edu.tw
Lin
Wei-Zeng
WZ
Huang
Wei-Ting
WT
Ko
Mei-Ju
MJ
Lee
Gene-Hsiang
GH
Ho
Mei-Lin
ML
Lin
Chun-Wei
CW
Shih
Chun-Wei
CW
Chou
Pi-Tai
PT