Spontaneous resolution of a 3D chiral polyoxometalate-based polythreaded framework consisting of an achiral ligand.
Two enantiomerically 3D chiral POM-based architectures have been constructed based on the achiral ligand bbi, [V10O26](4-) polyoxoanion and mixed valence Cu(I/II) without a chiral auxiliary, and they represent the first examples of enantiomerically 3D POM-based compounds using achiral ligands.
Lan
Ya-Qian
YQ
Institute of Functional Material Chemistry, Key Laboratory of Polyoxometalate Science of Ministry of Education, Faculty of Chemistry, Northeast Normal University, Changchun, 130024, China.
Li
Shun-Li
SL
Su
Zhong-Min
ZM
Shao
Kui-Zhan
KZ
Ma
Jian-Fang
JF
Wang
Xin-Long
XL
Wang
En-Bo
EB