Dilute anionic surfactant solution route to polyaniline rectangular sub-microtubes as a novel nanostructure.
A facile and low-cost approach has been developed for tailoring polyaniline rectangular sub-microtubes as a novel nanostructure of a conducting polymer in dilute sodium dodecyl sulfate (SDS) solution by the oxidation polymerization of aniline at room temperature. It was found that the size and uniformity of polyaniline rectangular sub-microtubes could be appropriately adjusted by tuning the concentration of aniline and the molar ratio of oxidant to aniline, respectively. The morphological evolution of rectangular sub-microtubes under different reaction times has been followed, and a possible formation mechanism has also been discussed in this report. The directing role of other anionic surfactants with -SO3(-) as the hydrophilic group for constructing polyaniline rectangular sub-microtubes has been investigated in detail.
Zhou
Chuanqiang
C
School of Chemistry and Chemical Engineering, Yangzhou University, Jiangsu Province 225002, PR China.
Han
Jie
J
Guo
Rong
R
D000814:Aniline Compounds / Q000737:chemistry*; D000838:Anions / Q000737:chemistry; D007201:Indicator Dilution Techniques; D008855:Microscopy, Electron, Scanning; D046529:Microscopy, Electron, Transmission; D049329:Nanostructures / Q000737:chemistry* / Q000648:ultrastructure*; D012996:Solutions; D013053:Spectrophotometry; D013501:Surface-Active Agents / Q000737:chemistry*
D000814:Aniline Compounds; D000838:Anions; D012996:Solutions; D013501:Surface-Active Agents; C416807:polyaniline