title: Hydrogen-bonded chains of rings in 1-(4-chloroanilinomethyl)-5-(4-chlorophenyl)-1,3,5-triazinane-2-thione and hydrogen-bonded sheets in 1-anilinomethyl-5-phenyl-1,3,5-triazinane-2-thione.
abstract: In 1-(4-chloroanilinomethyl)-5-(4-chlorophenyl)-1,3,5-triazinane-2-thione, C(16)H(16)Cl(2)N(4)S, there are two independent molecules in the asymmetric unit which form inversion dimers via two weak N-H...S hydrogen bonds. The dimers are then linked into C(9)C(14) chains by a C-H...S hydrogen bond and a C-H...Cl contact. In 1-(anilinomethyl)-5-phenyl-1,3,5-triazinane-2-thione, C(16)H(18)N(4)S, molecules are linked into complex sheets via a combination of N-H...S and C-H...pi hydrogen bonds.
authors.affiliation: College of Chemistry and Environmental Science, Henan Normal University, Xinxiang 453007, People's Republic of China. zzf5188@sohu.com
authors.forename: Zhenfeng
authors.initials: Z
authors.lastname: Zhang
authors.forename: Dong
authors.initials: D
authors.lastname: Xian
authors.forename: Jianping
authors.initials: J
authors.lastname: Li
authors.forename: Guisheng
authors.initials: G
authors.lastname: Zhang
mesh_terms: D003461:Crystallography; D003500:Cyclization; D019281:Dimerization; D006860:Hydrogen Bonding; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D014227:Triazines / Q000737:chemistry*
chemical_list: D014227:Triazines