Ligand-field treatment for the optical and electron paramagnetic resonance spectra of ZnO:V(3+).
In this work, a full ligand-field energy matrix (45 x 45) diagonalization treatment for 3d(2) ions in trigonal symmetry C(3v) is performed on the basis of a central metal ion-ligand covalency model including the ligand spin-orbit (SO) coupling. Optical fine structure and electron paramagnetic resonance (EPR) spectra of ZnO:V(3+) are uniformly explained.
Lin-Hua
Xie
X
Physics Department, Sichuan Normal University, No. 5 Jing'An Road, Sichuan, Chengdu 610066, China. xielh1974@163.com
D003460:Crystallization; D004578:Electron Spin Resonance Spectroscopy; D008024:Ligands; D008956:Models, Chemical; D012666:Semiconductors; D013053:Spectrophotometry; D055672:Static Electricity; D014639:Vanadium / Q000737:chemistry*; D015034:Zinc Oxide / Q000737:chemistry*
D008024:Ligands; D014639:Vanadium; D015034:Zinc Oxide