title: Employment of polyurethane foam for the adsorption of Methylene Blue in aqueous medium.
abstract: This work presents a detailed study about the adsorption of Methylene Blue (MB) onto polyether type polyurethane foam (PUF). The adsorption process is based on the formation of a hydrophobic ionic-pair between cationic dye MB and dodecylsulfate anion (SDS), which present high affinity by PUF. Set-up employed in the study was built up by adjusting a 200mg cylinder of PUF to the arm of an overhead stirrer. The system was characterized in relation to equilibrium, kinetic and thermodynamic aspects and it was modeled by employing Langmuir and Freundlich isotherms. Obtained results showed that the ratio between SDS and MB concentrations plays an important role on the adsorption process. According to Langmuir isotherm, a maximum adsorption capacity of 7.20 x 10(-5) mol MBg(-1) was achieved when optimized operational conditions were employed. The adsorption rate seems to be regulated by an intraparticle diffusion mechanism. Adsorption process was spontaneous (negative DeltaG) at ambient temperature and presented an endothermic characteristic (positive DeltaH). Sequential extraction experiments were carried out by changing PUF plugs in 30 min time intervals and around 96% of the MB present in solution could be removed through consecutive extractions with six 200 mg PUF cylinders.
authors.affiliation: Departamento de Química Analítica, Universidade Federal Fluminense, Outeiro de São João Batista s/n, Niterói/RJ 24020-150, Brazil.
authors.forename: Eliene E
authors.initials: EE
authors.lastname: Baldez
authors.forename: Nicolle F
authors.initials: NF
authors.lastname: Robaina
authors.forename: Ricardo J
authors.initials: RJ
authors.lastname: Cassella
mesh_terms: D000327:Adsorption; D004396:Coloring Agents / Q000737:chemistry*; D005374:Filtration; D007202:Indicators and Reagents; D008751:Methylene Blue / Q000737:chemistry*; D011140:Polyurethanes / Q000737:chemistry*; D012967:Sodium Dodecyl Sulfate / Q000737:chemistry; D012996:Solutions; D013056:Spectrophotometry, Ultraviolet; D013501:Surface-Active Agents / Q000737:chemistry; D013816:Thermodynamics; D014867:Water
chemical_list: D004396:Coloring Agents; D007202:Indicators and Reagents; D011140:Polyurethanes; D012996:Solutions; D013501:Surface-Active Agents; D014867:Water; D012967:Sodium Dodecyl Sulfate; D008751:Methylene Blue