Self-assembled monolayer electrode of a diiron complex with a phenoxo-based dinucleating ligand: observation of molecular oxygen adsorptionldesorption in aqueous media.
The phenoxo-based dinucleating ligand, 2,6-bis[bis(6-pivalamido-2-pyridylmethyl)amino-methyl-4-aminophenol (1), and its Fe2(II) complex, [Fe2(II)(1)(PhCOO)2](CF3SO3) (2), were prepared and 2 deposited on the Au surface (2/Au) is much more stable than in solution and exhibits redox behavior in aqueous media as well as reversible adsorption/desorption of oxygen at room temperature.
Inomata
Tomohiko
T
Department of Applied Chemistry, Nagoya Institute of Technology, Gokiso-cho, Showa-ku, Nagoya, 466-8555, Japan.
Shinozaki
Kazuma
K
Hayashi
Yuya
Y
Arii
Hidekazu
H
Funahashi
Yasuhiro
Y
Ozawa
Tomohiro
T
Masuda
Hideki
H