title: The homogeneous nucleation of 1-pentanol in a laminar flow diffusion chamber: the effect of pressure and kind of carrier gas.
abstract: The influence of total pressure and kind of carrier gas on homogeneous nucleation rates of 1-pentanol was investigated using experimental method of laminar flow diffusion chamber in this study. Two different carrier gases (helium and argon) were used in the total pressure range from 50 to 400 kPa. Nucleation temperatures ranged from 265 to 290 K for 1-pentanol-helium and from 265 to 285 K for 1-pentanol-argon. Nucleation rates varied between 10(1) and 10(6) cm(-3) s(-1) for 1-pentanol-helium and between 10(2) and 10(5) cm(-3) s(-1) for 1-pentanol-argon. Both positive and slight negative pressure effects were observed depending on temperature and carrier gas. The trend of pressure effect was found similar for both carrier gases. Error analysis on thermodynamic properties was conducted, and the lowering of surface tension due to adsorption of argon on nucleated droplets was estimated. A quantitative overview of pressure effect is provided.
authors.affiliation: Finnish Meteorological Institute, Erik Palménin aukio 1, P.O. Box 503, FI-00101 Helsinki, Finland. brus@icpf.cas.cz
authors.forename: D
authors.initials: D
authors.lastname: Brus
authors.forename: A-P
authors.initials: AP
authors.lastname: Hyvärinen
authors.forename: J
authors.initials: J
authors.lastname: Wedekind
authors.forename: Y
authors.initials: Y
authors.lastname: Viisanen
authors.forename: M
authors.initials: M
authors.lastname: Kulmala
authors.forename: V
authors.initials: V
authors.lastname: Zdímal
authors.forename: J
authors.initials: J
authors.lastname: Smolík
authors.forename: H
authors.initials: H
authors.lastname: Lihavainen