title: A convenient method for the assignment of relative configuration of acyclic alpha-alkyl-beta-hydroxy carbonyl compounds by (1)H NMR.
abstract: The relative configuration of acyclic alpha-alkyl-beta-hydroxy carbonyl compounds can be determined by using (1)H NMR spectroscopy. The assignment can be achieved by recording the (1)H NMR spectrum of the syn-anti mixture. The upfield carbinol hydrogen signal belongs to the anti whereas the downfield to the syn stereoisomer.
authors.affiliation: Department of Chemistry, University of Crete, Crete, Greece.
authors.forename: Dimitris
authors.initials: D
authors.lastname: Kalaitzakis
authors.forename: Ioulia
authors.initials: I
authors.lastname: Smonou