Water-soluble and stable dinitrogen phosphine complexes trans-[ReCl(N2)(PTA-H)n(PTA)4-n]n+ (n = 0-4), the first with 1,3,5-triaza-7-phosphaadamantane.
The first dinitrogen complexes with the hydrosoluble PTA ligand, or its protonated form PTA-H, trans-[ReCl(N2)(PTA-H)n(PTA)(4-n)]n+ (n = 0-4), are prepared, shown to be soluble and stable in water, interconvertible by stepwise protonation/deprotonation and to form, upon N2 loss, the corresponding penta-coordinate compounds. Dinitrogen displacement by CO affords trans-[ReCl(CO)(PTA)4].
Smoleński
Piotr
P
Centro de Química Estrutural, Complexo I Instituto Superior Técnico, TU-Lisbon, Av. Rovisco Pais, 1049-001, Lisbon, Portugal.
Pombeiro
Armando J L
AJ
D000218:Adamantane / Q000031:analogs & derivatives* / Q000737:chemistry; D009682:Magnetic Resonance Spectroscopy; D015394:Molecular Structure; D009584:Nitrogen / Q000378:metabolism*; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D009943:Organophosphorus Compounds / Q000737:chemistry*; D010720:Phosphines / Q000737:chemistry*; D012211:Rhenium / Q000378:metabolism*; D012995:Solubility; D013237:Stereoisomerism; D014867:Water / Q000737:chemistry
C501763:1,3,5-triaza-7-phosphaadamantane; D009942:Organometallic Compounds; D009943:Organophosphorus Compounds; D010720:Phosphines; D014867:Water; D012211:Rhenium; D009584:Nitrogen; D000218:Adamantane