Suzuki-Miyaura cross-coupling of potassium trifluoroboratohomoenolates.
Ketone-, ester-, and amide-containing potassium trifluoroboratohomoenolates were prepared in good to excellent yields from the corresponding unsaturated carbonyl compounds. They were shown to be effective coupling partners in the Suzuki-Miyaura reaction with a variety of electrophiles including electron-rich and electron-poor aryl bromides and -chlorides.
Molander
Gary A
GA
Roy and Diana A. Vagelos Laboratories, Department of Chemistry, University of Pennsylvania, Philadelphia, PA 19104-6323, USA. gmolandr@sas.upenn.edu
Petrillo
Daniel E
DE
D001881:Borates / Q000737:chemistry; D001896:Boron Compounds / Q000138:chemical synthesis* / Q000737:chemistry; D001965:Bromides / Q000737:chemistry; D002712:Chlorides / Q000737:chemistry; D009930:Organic Chemicals / Q000138:chemical synthesis* / Q000737:chemistry; D011188:Potassium / Q000737:chemistry
D001881:Borates; D001896:Boron Compounds; D001965:Bromides; D002712:Chlorides; D009930:Organic Chemicals; D011188:Potassium