title: Multiconfigurational g tensor calculations as a probe for the covalency of the copper-ligand bonds in copper(II) complexes: [CuCl4]2-, [Cu(NH3)4]2+, and plastocyanin.
abstract: Calculations of the g tensor of three copper(II) complexes [Cu(NH3)4]2+, [CuCl4]2-, and plastocyanin are presented. Two different sum-over-states-based approaches are considered, making use of the multistate CASPT2 method for excitation energies and PMCAS (perturbation modified CAS) wave functions for the computation of the angular momentum and spin-orbit coupling matrix elements. Test calculations on [Cu(NH3)4]2+ and [CuCl4]2- point to the need of including in the MS-CASPT2 treatment the specific charge-transfer state with an electron excited out of the bonding counterpart of the ground-state SOMO. The computed g shifts for these two molecules present a considerable improvement with respect to the results obtained from our previous g tensor calculations based instead on CASSCF/CASPT2. This is shown to be related to an improved description of the covalency of the Cu-L bonds. For the calculations on plastocyanin, different models are used, taken from a recent (QM/MM) DFT study by Sinnecker and Neese. The effect of the surrounding protein is taken into account by surrounding the central cluster either with a dielectric continuum (epsilon = 4) or with a set of point charges. The second approach is found to be indispensable for an accurate description of environmental effects. With this approach, the calculated g values compare to within 30 ppt with the experimental data of plastocyanin.
authors.affiliation: Department of Chemistry, University of Leuven Celestijnenlaan, 200F B-3001 Heverlee-Leuven, Belgium.
authors.forename: Steven
authors.initials: S
authors.lastname: Vancoillie
authors.forename: Kristine
authors.initials: K
authors.lastname: Pierloot
mesh_terms: D001665:Binding Sites; D002712:Chlorides / Q000737:chemistry*; D003300:Copper / Q000737:chemistry*; D008024:Ligands; D010970:Plastocyanin / Q000737:chemistry* / Q000378:metabolism; D011789:Quantum Theory
chemical_list: D002712:Chlorides; D008024:Ligands; D003300:Copper; D010970:Plastocyanin