Three-dimensional homochiral transition-metal camphorate architectures directed by a flexible auxiliary ligand.
Reported here are four homochiral and one racemic chiral compounds assembled from transition metals (Fe2+, Co2+, and Ni2+), rigid enantiopure camphoric acid, and flexible 4,4'-trimethylenedipyridine; they feature an unusual homochiral three-dimensional supramolecular assembly (resulting from catenation of 4-connected bilayers) as well as a homochiral 3-fold interpenetrating diamond net and a noninterpenetrating primitive cubic net.
Zhang
Jian
J
Department of Chemistry and Biochemistry, California State University-Long Beach, 1250 Bellflower Boulevard, Long Beach, CA 90840, USA.
Chew
Emily
E
Chen
Shumei
S
Pham
Jimmy T H
JT
Bu
Xianhui
X
D002164:Camphor / Q000031:analogs & derivatives* / Q000737:chemistry; D003035:Cobalt / Q000737:chemistry; D005296:Ferrous Compounds / Q000737:chemistry; D008024:Ligands; D019216:Metals, Heavy / Q000737:chemistry*; D008958:Models, Molecular; D009532:Nickel / Q000737:chemistry; D009942:Organometallic Compounds / Q000737:chemistry*; D011725:Pyridines / Q000737:chemistry; D013237:Stereoisomerism
C520106:4,4-trimethylenedipyridine; D005296:Ferrous Compounds; D008024:Ligands; D019216:Metals, Heavy; D009942:Organometallic Compounds; D011725:Pyridines; D003035:Cobalt; D002164:Camphor; D009532:Nickel