Alkenol-alkyne cross metathesis.
Allyl alcohols and their homologues were used in the enyne cross metathesis to prepare hydroxy-functionalized dienes. An isomerization was found to occur under prolonged heating, and a method for conversion to ( E)-diene product is also reported.
Clark
Daniel A
DA
Department of Chemistry, University at Buffalo, The State University of New York, Amherst, New York 14260, USA.
Clark
Joseph R
JR
Diver
Steven T
ST
D000466:Alkadienes / Q000138:chemical synthesis* / Q000737:chemistry; D000480:Alkynes / Q000737:chemistry*; D015394:Molecular Structure; D020005:Propanols / Q000737:chemistry*; D013237:Stereoisomerism
D000466:Alkadienes; D000480:Alkynes; D020005:Propanols; C006463:allyl alcohol