title: Mo-Au combo catalysis for rapid 1,3-rearrangement of propargyl alcohols into alpha,beta-unsaturated carbonyl compounds.
abstract: The combination of Mo and cationic Au catalysts dramatically accelerated the rearrangement of diverse propargyl alcohols, which includes a short reaction time, mild conditions, and high product yields. A practical application to the highly challenging primary propargyl alcohols and the N-alkynyl amides is achieved.
authors.affiliation: School of Pharmaceutical Sciences, University of Shizuoka, Shizuoka, Japan.
authors.forename: Masahiro
authors.initials: M
authors.lastname: Egi
authors.forename: Yoshiko
authors.initials: Y
authors.lastname: Yamaguchi
authors.forename: Noboru
authors.initials: N
authors.lastname: Fujiwara
authors.forename: Shuji
authors.initials: S
authors.lastname: Akai
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D006046:Gold / Q000737:chemistry*; D008982:Molybdenum / Q000737:chemistry*; D020005:Propanols / Q000737:chemistry*
chemical_list: D000480:Alkynes; D020005:Propanols; D006046:Gold; D008982:Molybdenum; C028255:propargyl alcohol