Substituent effects, reactant preorganization, and ligand exchange control the reactivity in Rh(I)-catalyzed (5+2) cycloadditions between vinylcyclopropanes and alkynes.
Liu
Peng
P
Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095-1569, USA.
Cheong
Paul Ha-Yeon
PH
Yu
Zhi-Xiang
ZX
Wender
Paul A
PA
Houk
Kendall N
KN
D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D003521:Cyclopropanes / Q000737:chemistry*; D008024:Ligands; D008956:Models, Chemical; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013329:Structure-Activity Relationship; D014753:Vinyl Compounds / Q000737:chemistry*
D000480:Alkynes; D003521:Cyclopropanes; D008024:Ligands; D009942:Organometallic Compounds; D014753:Vinyl Compounds; D012238:Rhodium