[Ethanol electrooxidation on carbon supported PtSn catalyst: in situ TRFTIR study].
Carbon supported PtSn catalyst (PtSn/C) was prepared by a modified polyol method and characterized by means of XRD. It was showed that the metal particle size was 2.2 nm and the unit cell parameter increased compared with Pt/C. In situ time-resolved Fourier transform infrared spectroscopy (TRFTIRS) was used to study the electrooxidation of ethanol on PtSn/C catalyst. COL was the main poison species adsorbed on the active sites to inhibit the further reaction of ethanol electrooxidation. Acetaldehyde and acetic acid were found to be the products of ethanol electrooxidation as competing reactions with ethanol dissociation when the potential was up to 0.3 V, which reduced the poisoning effect. The selectivity of acetic acid among the products was improved with the increase in the potential and reaction time. CO2, which appeared at 0.4 V, was the final product and yielded from the oxidation of COL. The catalytic mechanism of PtSn/C towards ethanol electrooxidation was analyzed based on the results.
Wang
Qi
Q
Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
Sun
Gong-Quan
GQ
Jiang
Lu-Hua
LH
Zhu
Ming-Yuan
MY
Wang
Guo-Xiong
GX
Xin
Qin
Q
Sun
Shi-Gang
SG
Chen
Qing-Song
QS
Jiang
Yan-Xia
YX
Chen
Sheng-Pei
SP