title: New framework iodoargentates: M(en)3Ag2I4 (M=Zn, Ni) with tridymite topology.
abstract: Two novel framework compounds, Zn(en) 3Ag2I4 (1) and Ni(en) 3Ag2I4 (2), have been synthesized by a self-assembly reaction. Both of them contain an unexpected framework, Ag2I4(2-) with tridymite topology, and the discrete M(en)3(2+) cations are located in the channels. Their thermal properties and circular dichroism spectra were investigated.
authors.affiliation: Department of Chemistry, Dalian University of Technology, Dalian 116024, China.
authors.forename: Yan-Si
authors.initials: YS
authors.lastname: Jiang
authors.forename: Hua-Gang
authors.initials: HG
authors.lastname: Yao
authors.forename: Shou-Hua
authors.initials: SH
authors.lastname: Ji
authors.forename: Min
authors.initials: M
authors.lastname: Ji
authors.forename: Yong-Lin
authors.initials: YL
authors.lastname: An