title: Substituent effects, reactant preorganization, and ligand exchange control the reactivity in Rh(I)-catalyzed (5+2) cycloadditions between vinylcyclopropanes and alkynes.
authors.affiliation: Department of Chemistry and Biochemistry, University of California, Los Angeles, Los Angeles, CA 90095-1569, USA.
authors.forename: Peng
authors.initials: P
authors.lastname: Liu
authors.forename: Paul Ha-Yeon
authors.initials: PH
authors.lastname: Cheong
authors.forename: Zhi-Xiang
authors.initials: ZX
authors.lastname: Yu
authors.forename: Paul A
authors.initials: PA
authors.lastname: Wender
authors.forename: Kendall N
authors.initials: KN
authors.lastname: Houk
mesh_terms: D000480:Alkynes / Q000737:chemistry*; D002384:Catalysis; D003500:Cyclization; D003521:Cyclopropanes / Q000737:chemistry*; D008024:Ligands; D008956:Models, Chemical; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000138:chemical synthesis* / Q000737:chemistry*; D012238:Rhodium / Q000737:chemistry*; D013329:Structure-Activity Relationship; D014753:Vinyl Compounds / Q000737:chemistry*
chemical_list: D000480:Alkynes; D003521:Cyclopropanes; D008024:Ligands; D009942:Organometallic Compounds; D014753:Vinyl Compounds; D012238:Rhodium