New framework iodoargentates: M(en)3Ag2I4 (M=Zn, Ni) with tridymite topology.
Two novel framework compounds, Zn(en) 3Ag2I4 (1) and Ni(en) 3Ag2I4 (2), have been synthesized by a self-assembly reaction. Both of them contain an unexpected framework, Ag2I4(2-) with tridymite topology, and the discrete M(en)3(2+) cations are located in the channels. Their thermal properties and circular dichroism spectra were investigated.
Jiang
Yan-Si
YS
Department of Chemistry, Dalian University of Technology, Dalian 116024, China.
Yao
Hua-Gang
HG
Ji
Shou-Hua
SH
Ji
Min
M
An
Yong-Lin
YL