Azide monoliths as convenient flow reactors for efficient Curtius rearrangement reactions.
The preparation and use of an azide-containing monolithic reactor is described for use in a flow chemistry device and in particular for conducting Curtius rearrangement reactions via acid chloride inputs.
Baumann
Marcus
M
Innovative Technology Centre, Department of Chemistry, University of Cambridge, Lensfield Road, Cambridge, UK.
Baxendale
Ian R
IR
Ley
Steven V
SV
Nikbin
Nikzad
N
Smith
Christopher D
CD
D001386:Azides / Q000737:chemistry*; D002219:Carbamates / Q000138:chemical synthesis* / Q000737:chemistry; D002851:Chromatography, High Pressure Liquid / Q000295:instrumentation* / Q000379:methods*; D004867:Equipment Design; D007475:Ion Exchange Resins / Q000737:chemistry; D013058:Mass Spectrometry / Q000295:instrumentation / Q000379:methods; D015394:Molecular Structure; D010316:Particle Size; D016062:Porosity; D000644:Quaternary Ammonium Compounds / Q000737:chemistry; D012680:Sensitivity and Specificity; D013499:Surface Properties; D014508:Urea / Q000031:analogs & derivatives / Q000138:chemical synthesis* / Q000737:chemistry
D001386:Azides; D002219:Carbamates; D007475:Ion Exchange Resins; D000644:Quaternary Ammonium Compounds; D014508:Urea