title: Gold(I)-catalyzed glycosidation of 1,2-anhydrosugars.
abstract: Being able to increase the yield by >20% compared to the conventional use of anhydrous zinc chloride (>1 equiv) as a promoter, Ph 3PAuOTf is disclosed to be a superior catalyst for the well-established glycosylation reaction with 1,2-anhydrosugars as donors.
authors.affiliation: State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai, China.
authors.forename: Yao
authors.initials: Y
authors.lastname: Li
authors.forename: Pingping
authors.initials: P
authors.lastname: Tang
authors.forename: Youxi
authors.initials: Y
authors.lastname: Chen
authors.forename: Biao
authors.initials: B
authors.lastname: Yu
mesh_terms: D002241:Carbohydrates / Q000737:chemistry*; D002384:Catalysis; D002853:Chromatography, Liquid; D006027:Glycosides / Q000737:chemistry*; D006046:Gold / Q000737:chemistry*
chemical_list: D002241:Carbohydrates; D006027:Glycosides; D006046:Gold