title: [Ethanol electrooxidation on carbon supported PtSn catalyst: in situ TRFTIR study].
abstract: Carbon supported PtSn catalyst (PtSn/C) was prepared by a modified polyol method and characterized by means of XRD. It was showed that the metal particle size was 2.2 nm and the unit cell parameter increased compared with Pt/C. In situ time-resolved Fourier transform infrared spectroscopy (TRFTIRS) was used to study the electrooxidation of ethanol on PtSn/C catalyst. COL was the main poison species adsorbed on the active sites to inhibit the further reaction of ethanol electrooxidation. Acetaldehyde and acetic acid were found to be the products of ethanol electrooxidation as competing reactions with ethanol dissociation when the potential was up to 0.3 V, which reduced the poisoning effect. The selectivity of acetic acid among the products was improved with the increase in the potential and reaction time. CO2, which appeared at 0.4 V, was the final product and yielded from the oxidation of COL. The catalytic mechanism of PtSn/C towards ethanol electrooxidation was analyzed based on the results.
authors.affiliation: Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China.
authors.forename: Qi
authors.initials: Q
authors.lastname: Wang
authors.forename: Gong-Quan
authors.initials: GQ
authors.lastname: Sun
authors.forename: Lu-Hua
authors.initials: LH
authors.lastname: Jiang
authors.forename: Ming-Yuan
authors.initials: MY
authors.lastname: Zhu
authors.forename: Guo-Xiong
authors.initials: GX
authors.lastname: Wang
authors.forename: Qin
authors.initials: Q
authors.lastname: Xin
authors.forename: Shi-Gang
authors.initials: SG
authors.lastname: Sun
authors.forename: Qing-Song
authors.initials: QS
authors.lastname: Chen
authors.forename: Yan-Xia
authors.initials: YX
authors.lastname: Jiang
authors.forename: Sheng-Pei
authors.initials: SP
authors.lastname: Chen