title: Enantioselective synthesis of cyclic sulfamidates via Pd-catalyzed hydrogenation.
abstract: Using Pd(CF3CO2) 2/(S,S)-f-binaphane as the catalyst, an efficient enantioselective synthesis of cyclic sulfamidates was developed via asymmetric hydrogenation of the corresponding cyclic imines in 2,2,2-trifluoroethanol at room temperature with high enantioselectivities (up to 99% ee).
authors.affiliation: State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian 116023, China.
authors.forename: You-Qing
authors.initials: YQ
authors.lastname: Wang
authors.forename: Chang-Bin
authors.initials: CB
authors.lastname: Yu
authors.forename: Da-Wei
authors.initials: DW
authors.lastname: Wang
authors.forename: Xiao-Bing
authors.initials: XB
authors.lastname: Wang
authors.forename: Yong-Gui
authors.initials: YG
authors.lastname: Zhou
mesh_terms: D002384:Catalysis; D006865:Hydrogenation; D015394:Molecular Structure; D009942:Organometallic Compounds / Q000737:chemistry*; D010165:Palladium / Q000737:chemistry*; D013237:Stereoisomerism; D013449:Sulfonamides / Q000138:chemical synthesis* / Q000737:chemistry
chemical_list: D009942:Organometallic Compounds; D013449:Sulfonamides; D010165:Palladium