Gold(I) ethylene and copper(I) ethylene complexes supported by a polyhalogenated triazapentadienyl ligand.
A rare gold(I) ethylene complex and the closely related copper(I) ethylene adduct have been isolated using [N{(C3F7)C(2,6-Cl2C6H3)N}2]- as the supporting ligand. [N{(C3F7)C(2,6-Cl2C6H3)N}2]Au(C2H4) (1) is an air-stable solid. It features a U-shaped triazapentadienyl ligand backbone and a three-coordinate, trigonal-planar gold center. The copper(I) adduct [N{(C3F7)C(2,6-Cl2C6H3)N}2]Cu(C2H4) (2) also has a similar structure. The 13C NMR signal corresponding to the ethylene carbons of 1 appears at about 64 ppm upfield from the free ethylene, while the ethylene carbons of 2 show a relatively smaller (39 ppm) upfield shift. [N{(C3F7)C(2,6-Cl2C6H3)N}2]M(C2H4) (M=Cu, Au) mediate carbene-transfer reactions from ethyl diazoacetate to saturated and unsaturated hydrocarbons.
Flores
Jaime A
JA
Department of Chemistry and Biochemistry, The University of Texas at Arlington, Arlington, TX 76019, USA.
Dias
H V Rasika
HV