title: Increasing the persistency of stable free-radicals: synthesis and characterization of a nitroxide based [1]rotaxane.
abstract: A persistent paramagnetic [1]rotaxane based on beta-cyclodextrin showing an increased persistency under reductive conditions has been prepared and characterized for the first time.
authors.affiliation: Department of Organic Chemistry A. Mangini, University of Bologna, Via San Giacomo 11, I-40126 Bologna, Italy.
authors.forename: Paola
authors.initials: P
authors.lastname: Franchi
authors.forename: Michela
authors.initials: M
authors.lastname: Fanì
authors.forename: Elisabetta
authors.initials: E
authors.lastname: Mezzina
authors.forename: Marco
authors.initials: M
authors.lastname: Lucarini
mesh_terms: D004578:Electron Spin Resonance Spectroscopy / Q000379:methods; D005609:Free Radicals / Q000138:chemical synthesis / Q000737:chemistry; D007700:Kinetics; D009682:Magnetic Resonance Spectroscopy / Q000379:methods / Q000592:standards; D008280:Magnetics; D009589:Nitrogen Oxides / Q000737:chemistry*; D012015:Reference Standards; D043862:Rotaxanes / Q000737:chemistry*; D013997:Time Factors; D047392:beta-Cyclodextrins / Q000737:chemistry
chemical_list: D005609:Free Radicals; D009589:Nitrogen Oxides; D043862:Rotaxanes; D047392:beta-Cyclodextrins; C031215:betadex