Ligands that enforce unnatural stereospinomers.
Computational evidence is provided for the existence of combinations of a stereoisomer and a spin state not previously observed in d(4) and d(8) complexes, achieved by means of encapsulating ligands that enforce a tetrahedral coordination.
Maganas
Dimitrios
D
Inorganic Chemistry Laboratory, Department of Chemistry, University of Athens, GR-15771, Athens, Greece.
Kyritsis
Panayotis
P
Aullón
Gabriel
G
Alvarez
Santiago
S